Effects of Holocene climatic change on some tropical geomorphic processes

Man's interference with the landscape process places him in the role of a “paraglacial” agent: He tends to duplicate ice-age stresses such as deforestation, accelerated erosion, and climate alteration. Against a background climatic control dictated by the Milankovich mechanisms, the 10,000-year history of the Holocene has seen very large secondary modulations that must be better understood so that they may be distinguished from anthropogenic effects. If they are exogenetically controlled, as it seems, then they are probably predictable from astronomic data. Four geomorphic type areas are selected for demonstrating Holocene changes in tropical regions, because they have been somewhat neglected within the framework of Quaternary science and because they include some of the most fragile and easily disrupted environments: lakes, semiarid desert margins, coastlines, and coral reefs. In a nutshell, the tropical Holocene has seen three major changes: (a) the evolution from the hyperaridity of the last pleniglacial stage to the “postglacial pluvial”; (b) the “climatic optimum,” which was highly diachronous and strongly retarded as it shifted from low latitudes to high; (c) the postoptimum “deterioration” that has involved desiccation of lakes, readvances of the deserts, fall of sea level, and truncation of coral reefs. While this deterioration is predictable in terms of an interglacial-glacial climatic transition, strong natural climatic oscillations, not yet well understood, together with man's activities, make the future a cause for concern.     

Geoarchaeological evidence for multidecadal natural climatic variability and ancient Peruvian fisheries

Understanding the influence of natural climatic variability on modern fisheries is complicated by over a century of industrial fishing. Archaeological data provide unique opportunities for assessing precolonial and preindustrial fisheries. Records show that anchoveta-vs sardine-dominated fisheries correlate with 20th-century climate change in the Pacific Basin and are linked to multidecadal climatic variability. The “anchovy regime” is characterized by cooler conditions and lower frequency El Niño/Southern Oscillation (ENSO) events, while the “sardine regime” is associated with warmer conditions and higher frequency ENSO. Fish remains excavated at Lo Demás, an Inca-period (ca. A.D. 1480–1540) fishing site at 13°25′S on the Peruvian coast, document a shift from an anchoveta-to a sardine-dominated fishery at about A.D. 1500. This shift correlates with records for increasing ENSO frequency at the same time. Middle and late Holocene sites have archaeofish assemblages that also suggest regime changes. Here we show that changes in fish regimes can result from natural variability and we support the potential role of archaeological assemblages in tracking multidecadal climate change in the Pacific Basin throughout the Holocene (0–11,500 cal yr B.P.).     

Quaternary coastal evolution and vegetation history of northern New South Wales, Australia, based on dinoflagellates and pollen

The Richmond River Valley of northern N.S.W. contains a late Pleistocene succession dating back to approximately 250,000 yr B.P. Dinoflagellate and spore-pollen assemblages from the lowest interval, the lower “Dungarubba Clay” of Drury (1982), indicate deposition in a restricted estuarine environment at approximately 250,000 yr. Deposition in the overlying interval, the upper “Dungarubba Clay” and “Gundurimba Clay”, at approximately 120,000 yr B.P., began in a restricted estuary, but rising sea level caused inundation and deposition in a more open, marine-dominated environment. Dinoflagellate cyst assemblages from the last interglaciation (stage 5) are interpreted by analogy with those from the morphologically similar, modern Broken Bay, N.S.W. They are indicative of an open, marine-dominated environment and imply that barrier formation in the Richmond River Valley, and possibly elsewhere in northern N.S.W., did not commence until after the initial postglacial transgression. Synchronous changes in sea level and rainforest development suggest that there was no significant time lag between climate and sea-level change.     

The Cenomanian/Turonian Boundary Event (CTBE) at Wunstorf, north-west Germany, as reflected by marine palynology

The Cenomanian/Turonian Boundary Event (CTBE) at Wunstorf, north-west Germany, has been analysed palynologically by high resolution sampling to reconstruct changes in relative sea-level and water mass character within photic zone waters. Based on changes in the ratio of terrigenous sporomorphs to marine palynomorphs (t/m index), the distribution of the organic-walled algal taxa as well as of selected dinocyst taxa and groups the section can largely be subdivided into pre-“plenus-bed” and post-“plenus-bed” intervals, reflecting different stages of third-order relative sea-level cycles and/or changes in water mass influence in the photic zone. Accordingly, the pre-“plenus-bed” interval is placed in a transgressive systems tract starting at the “facies change” event (C. guerangeri/M. geslinianum ammonite Zone boundary) with the maximum flooding surface at the top of the “Chondrites II” bed (top of R. cushmani Biozone). A highstand systems tract is suggested from the base of the “plenus-bed” up the base of the “fish-shale” event. Within the “fish-shale” event interval, a transgressive systems tract is suggested to start at the base of the thin, grey-green marly interbed. The Cenomanian/Turonian boundary proper, as defined by the first occurrence of Mytiloides spp., as well as the lowermost Turonian are located within the initial phase of a transgressive systems tract. With respect to water mass characteristics within photic-zone waters, the pre-“plenus-bed” interval is predominantly characterized by warm water masses that changed gradually towards the deposition of the “Chondrites II” bed, where a strong influence of cool and/or salinity-reduced waters is indicated by various palynological proxies. Within the post-“plenus-bed” interval a mixture and/or alternation of warmer and cooler waters is indicated, with the warmer water influence increasing gradually towards and within the Lower Turonian stage. The increased proportions of prasinophytes within the “Chondrites II” bed and parts of the “fish-shale” interval may indicate availability of reduced nitrogen chemospecies, especially ammonium, within photic-zone waters as a function of a vertical expansion of the oceanic O₂-minimum zone.     

Nomenclature and resolution in Holocene glacial chronologies

Most Quaternary research in Canada during the first half of the twentieth century focused on Pleistocene glaciation. Given the dramatic shifts in climate during the Pleistocene, it is not surprising that the Holocene was viewed as a time of benign climate. Holocene climate variability was first recognized around the middle of the century when paleoecologists found evidence that the early part of the epoch was warmer and drier than the later part. In 1970s and 1980s, another generation of geologists, geographers, and botanists began to recognize more complexity in Holocene climate and vegetation in western Canada. Several millennial-scale glacier “advances” postdating the early Holocene warm interval were defined, including the Garibaldi Phase (6.9–5.6 ka), the Tiedemann–Peyto Advance (3.5–1.9 ka), and the Little Ice Age (AD 1200–1900). Subsequently, application of dendrochronological techniques and stratigraphic studies in glacier forefields showed that the Little Ice Age was itself more complex than previously thought. During that 700-year period, glaciers repeatedly advanced and retreated in response to climatic variability on time scales ranging from centuries to decades. Recent work shows that the glacier record of the Garibaldi Phase and the Tiedemann and Peyto advances are similar in complexity to the Little Ice Age, with multiple advances of glaciers separated by intervals of more restricted ice cover. Researchers have also identified other times in the Holocene when glaciers expanded from restricted positions – 8.20, 4.90–3.80, and 1.70–1.40 ka. Continued research undoubtedly will reveal additional complexities, but with what is currently known the appropriateness of terms such as “Tiedemann Advance,” “Peyto Advance,” and “Little Ice Age” can be questioned. Only short periods of time separate these episodes as currently defined, and it seems likely that intervals of restricted glacier cover within each of these millennial-length intervals are just as long as the intervals separating them.     

Effects of Climate Change on Soils in Glacial Deposits, Wind River Basin, Wyoming

Soil chronofunctions are often quasilinear, but those relationships may be only gross, fortuitous generalizations that ignore changes in soils resulting from climatic and other cyclic external influences that govern soil formation or soil degradation. In the Rocky Mountains, soil development has been extensively used to estimate the age of sediments, but the number of soils is usually few, and large ranges in values for soil data may be dismissed as “normal variation.” In a detailed study of soils in the Wind River Range and Wind River Basin, characteristics of near-surface horizons do not follow age trends. However, the underlying carbonate-bearing horizons do have age-related characteristics. This “soil paradox” may be related to glacial–interglacial cycles in which (1) wind erodes near-surface horizons and then provides new parent material and (2) cryoturbation disrupts carbonate horizons, remobilizing carbonate and changing carbonate morphology but with only minimal loss of carbonate from the soil.     

A Kaapvaal craton debate: Nucleus of an early small supercontinent or affected by an enhanced accretion event?

Incorporation of the Kaapvaal craton within a speculative Neoarchaean–Palaeoproterozoic supercontinent has long been debated, and this idea provides a potential solution to solving the apparently enigmatic provenance of the huge quantities of gold within the famous Witwatersrand auriferous deposits of Kaapvaal. Within a framework of a postulated Neoarchaean “Kenorland” (“northern”; present-day reference) supercontinent, we examine possible “southern” cratons that may have been contiguous with Kaapvaal: Pilbara, Zimbabwe, Dharwar, São Francisco, Amazon, Congo. Brief reviews of their basic geology and inferred evolution in syn-Witwatersrand basin times (c. 3.1–2.8 Ga) show no obvious support for any such supercontinental amalgamations. An alternative idea to explain a measure of gross similarity amongst several Neoarchaean cratons is through global events, such as a c. 3125–3000 Ma cratonic-scale erosive event interpreted for both Pilbara and Kaapvaal, and a much more widespread magmatic event at c. 2760–2680 Ma. We postulate that a global superplume event at c. 3.0 Ga included a plume beneath the Kaapvaal cratonic nucleus, thus halting any subduction around that terrane due to the thermal anomaly. Such a speculative global magmatic event is assumed to have enhanced production of juvenile oceanic crust at mid-ocean ridges, including those “offshore” of the thermally elevated Kaapvaal nucleus. Intra-oceanic obduction complexes may have built up fairly rapidly under such conditions, globally, and once the plume event had abated, “normal” plate tectonics would have resulted in composite (greenstone-tonalite, possibly also including granite) terranes accreting with nuclei such as Kaapvaal. This enhanced plume-related cratonic growth can be seen as a rapid accretion event. Formation of the envisaged ophiolite complexes possibly encompassed deformation-related first-order concentration of gold, and once accretion occurred around Kaapvaal's nucleus, from north and west (present-day frame of reference), a second-order (deformation-related) gold concentration may have resulted. The third order of gold concentration would logically have occurred once placer systems reworked detritus derived from the orogens along the N and W margins of Kaapvaal. Such conditions and placer gold deposits are known from many Neoarchaean cratons. The initial source of gold was presumably from the much hotter Mesoarchaean mantle and may have been related to major changes in Earth's tectonic regime at c. 3.0 Ga. The unique nature of Kaapvaal is probably its early stabilization, enabling formation of a complex flexural foreland basin system, in which vast quantities of placer sediments and heavy minerals could be deposited, and preserved from younger denudation through a unique post-Witwatersrand history.     

A comparison of evidence for late Holocene summer temperature variations in the northern hemisphere

Data on glacier, tree-line, tree-ring, pollen, and ice-core variations in North America, Greenland, and Europe during the last 2000 yr (up to A.D. 1800) are compared in detail on the century time scale. Only data that may be indicative of summer temperature changes are included, since these comprise most of the available paleoclimatic information, although some variations (especially of glaciers) may have been in response to precipitation changes instead. Radiocarbon dates and ¹⁴C-dated records are converted to calendar (dendrochronological) years using the calibration of M. Stuiver (1982, Radiocarbon 24, 1–26). Despite the basic uncertainties in dating, interpretation, response times, and “noise level” of proxy climatic data, there is at times good agreement among different kinds of evidence from within a region to suggest an episode of generally warmer or cooler summers. Three previously identified episodes find expression in records from all of the regions considered: the “Little Ice Age” of the last few centuries, a “Medieval Warm Period” around the 12th century A.D., and an earlier cold period some time between the 8th and 10th centuries. However, the timing of minima and maxima within these episodes seems to have varied from region to region (although the evidence is consistent within regions). In the 15th century, summers were warm in the eastern Canadian Arctic and southern Greenland while there was a cold episode in Europe and western North America.     

Magnetic overprints in granitoids and metamorphic rocks from Limousin (France): evidence for Late Variscan rotations, crustal folding and tilting

Generally, the lack of bedding criteria in basement units hampers the interpretation of paleomagnetic results in terms of geotectonics. Nevertheless, this work demonstrates that successive remagnetizations recorded in Early Carboniferous metamorphic and plutonic units, without clear bedding criteria, can be used to constrain a polyphased tectonic evolution consisting of a regional clockwise rotation, followed by a folding phase, a tilting phase and a second regional clockwise rotation.Metamorphic, ultrabasic, tonalitic and granitic rocks from different parts of Limousin (western French Massif central; 45.5°N/1.25°E), which underwent metamorphism during Devonian–Early Carboniferous or were intruded in the Early–Middle Carboniferous, were sampled in order (a) to identify the magnetic overprinting phases and the related tectono-magmatic events and (b) to constrain the regional and plate tectonic evolution of Limousin. Paleomagnetic results from 32 new and 26 sites investigated previously show that at least 90% of the magnetization isolated in rocks older than 330 Ma are overprints. In agreement with results from adjacent areas of the Variscan belt, the major overprinting phases occurred: (a) in the last stages of the major exhumation phase [332–328 Ma; mean Virtual Geomagnetic Pole (VGP) “Cp”: 37°N/70.5°E], (b) during the post-collisional syn-orogenic extension (325–315 Ma; VGP “B”: 11°N/114°E), (c) in the Latest Carboniferous and Early Permian (VGP “A1”: 27°N/149°E) and (d) in the Late Permian (VGP “A”: 48°N/146°E). The Middle–Late Carboniferous overprints “Cp” and “B” are contemporaneous with emplacement of leucogranitic, crustal derived plutons, and probably result from the hydro-thermal activity related to the magmatism. The drift from “Cp” directions to “B” directions implies that after 330 Ma, Limousin underwent a clockwise rotation by 65°, together with the Central Europe Variscides. The “Bt” components, the VGPs of which deviate from the mean apparent polar wander path (APWP) of the belt, are interpreted as “B” overprints tilted during Late Variscan tectonics, that is, in the time range 325–315 Ma. The first and most important generation of “Bt” overprints was tilted during NW–SE folding associated with NE–SW shortening, updoming and emplacement of leucogranitic plutons. The second generation reveals southeastward tilting due to NE-striking normal faulting. The drift from “B” to “A1” directions implies that Limousin has participated to the second clockwise rotation by 40° of the whole belt in Westphalian times.     

Tethyan, Mediterranean, and Pacific analogues for the Neoproterozoic–Paleozoic birth and development of peri-Gondwanan terranes and their transfer to Laurentia and Laurussia

Modern Tethyan, Mediterranean, and Pacific analogues are considered for several Appalachian, Caledonian, and Variscan terranes (Carolina, West and East Avalonia, Oaxaquia, Chortis, Maya, Suwannee, and Cadomia) that originated along the northern margin of Neoproterozoic Gondwana. These terranes record a protracted geological history that includes: (1) 1 Ga (Carolina, Avalonia, Oaxaquia, Chortis, and Suwannee) or 2 Ga (Cadomia) basement; (2) 750–600 Ma arc magmatism that diachronously switched to rift magmatism between 590 and 540 Ma, accompanied by development of rift basins and core complexes, in the absence of collisional orogenesis; (3) latest Neoproterozoic–Cambrian separation of Avalonia and Carolina from Gondwana leading to faunal endemism and the development of bordering passive margins; (4) Ordovician transport of Avalonia and Carolina across Iapetus terminating in Late Ordovician–Early Silurian accretion to the eastern Laurentian margin followed by dispersion along this margin; (5) Siluro-Devonian transfer of Cadomia across the Rheic Ocean; and (6) Permo-Carboniferous transfer of Oaxaquia, Chortis, Maya, and Suwannee during the amalgamation of Pangea. Three potential models are provided by more recent tectonic analogues: (1) an “accordion” model based on the orthogonal opening and closing of Alpine Tethys and the Mediterranean; (2) a “bulldozer” model based on forward-modelling of Australia during which oceanic plateaus are dispersed along the Australian plate margin; and (3) a “Baja” model based on the Pacific margin of North America where the diachronous replacement of subduction by transform faulting as a result of ridge–trench collision has been followed by rifting and the transfer of Baja California to the Pacific Plate. Future transport and accretion along the western Laurentian margin may mimic that of Baja British Columbia. Present geological data for Avalonia and Carolina favour a transition from a “Baja” model to a “bulldozer” model. By analogy with the eastern Pacific, we name the oceanic plates off northern Gondwana: Merlin (≡Farallon), Morgana (≡Pacific), and Mordred (≡Kula). If Neoproterozoic subduction was towards Gondwana, application of this combined model requires a total rotation of East Avalonia and Carolina through 180° either during separation (using a western Transverse Ranges model), during accretion (using a Baja British Columbia “train wreck” model), or during dispersion (using an Australia “bulldozer” model). On the other hand, Siluro-Devonian orthogonal transfer (“accordion” model) from northern Africa to southern Laurussia followed by a Carboniferous “Baja” model appears to best fit the existing data for Cadomia. Finally, Oaxaquia, Chortis, Maya, and Suwannee appear to have been transported along the margin of Gondwana until it collided with southern Laurentia on whose margin they were stranded following the breakup of Pangea. Forward modeling of a closing Mediterranean followed by breakup on the African margin may provide a modern analogue. These actualistic models differ in their dictates on the initial distribution of the peri-Gondwanan terranes and can be tested by comparing features of the modern analogues with their ancient tectonic counterparts.     

Evidence for cyclic reactions between andalusite, “sericite” and sillimanite, mount franks area, willyama complex N.S.W

In the Mt. Franks area of the Willyama Complex, microfabric evidence suggests that the alteration of andalusite to sillimanite has taken place by a process similar to that suggested by Carmichael (1969). Andalusite is pre- to syn-S₂ in age. Alteration to “sericite” has resulted in the formation of “sericite” laths, some of which are crenulated about S₂, and some which are syn- and post-S₂. “Fibrolite” occurs in these andalusite—“sericite” aggregates within the sillimanite zone and is wholly embedded in “sericite”. “Fibrolite” is pre- to syn-S₂ in age. This evidence is interpreted as suggesting that the formation of sillimanite from andalusite took place via a “sericite” phase.Further microfabric observations are interpreted to imply constant volume for the reaction aluminosilicate → “sericite”. This suggests a situation in which Al³⁺ is relatively mobile but Al⁴⁺ is relatively immobile. This suggestion differs from Carmichael's (1969) idea of Al³⁺ immobility.     

Porphyry copper deposits of the CIS and the models of their formation

Deposits of the “porphyry” family (essentially porphyry copper and gold-porphyry copper, gold-bearing porphyry molybdenum-copper, gold-containing porphyry copper-molybdenum and porphyry molybdenum deposits) are associated in time and space with granitoid magmatism mainly in Phaerozoic volcano-plutonic belts. Whatever their age, the deposits belong to two types of belts: basaltic belts, representing axial zones of island arcs, or andesitic belts formed within active continental (Andean-type) margins.The petrochemistry of ore-bearing magmatism related to the nature of the substratum of volcano-plutonic belts, reveals a number of essential characteristics, both in composition and zonation of wallrock alteration and ore mineralization. These characterisics enabled previous researchers to establish four models of porphyry copper deposits based on their lithologic associations, e.g., “diorite”, “granodiorite”, “monzonite” and “granite”.Pophyry copper deposits are thought to be the product of self-generating “two-fluid mixing” ore-magmatic systems. Porphyry intrusions are pathways for energy and metals from deep-seated magma chambers, of which the upper mineralized parts are accessible for observation. The relationship between magmatic fluids and meteoric water participating in the ore-forming processes (dependent on the structural-petrophysical conditions of formation), provide a subdivision for the porphyry copper ore-magmatic systems into three types: “open”, “closed” and “transitional”.Concurrently, a common trend in the evolution of the systems has been established, from a nearly autoclave regime of structural-and ore-forming processes to a gradual increase in the importance of hydrothermal recycling. The completeness of the OMS (ore-magmatic system) development according to this scheme, which determines the existence of various OMS types, depends on many factors, the most important being the depth of formation of porphyry intrusive bodies, the petrophysical peculiarities of the host rocks and the palaeohydrogeological conditions of ore deposition.Although rock fracturing (especially defluidization: second boiling) and contraction are caused by the same mechanisms, the stockwork growth in “open” and “closed” systems, relative to the wall rock, takes place in opposite directions, primarily due to different petrophysical parameters of the near-stock environment.In “open” systems structural and ore metasomatic processes are finalized. Fractures extend progressively from porhyry stocks into the marginal parts of the intrusive framework and extension of large-scale recycling of magmatic and activated meteoric water, in the same direction, result in the formation of ore-bearing stockworks. These are large in all dimensions, cover mainly hanging-wall zones and are characterized by clearly defined concentric mineral zoning and extensive geochemical haloes.In a “closed” OMS with centripetal growing fractures, hydrothermal convection is stunted. The vertical extension of recycling cells is restricted and the volume of meteoric water involved in circulation during the period of ore deposition is relatively small. As a result, relatively small intra-intrusive lenticular stockworks are developed which are characterized by close co-existence of several generations of mineralization with fragmentary preservation of the earliest ones. These are characterized by the elements of “reverse” zoning, increased density of the veinlets and metal content, as well as poorly developed hanging-wall dispersion haloes.     

The optical features and hydrocarbon-generating model of “barkinite” from Late Permian coals in South China

Leping coal is known for its high content of “barkinite”, which is a unique liptinite maceral apparently found only in the Late Permian coals of South China. “Barkinite” has previously identified as suberinite, but on the basis of further investigations, most coal petrologists conclude that “barkinite” is not suberinite, but a distinct maceral. The term “barkinite” was introduced by (State Bureau of Technical Supervision of the People's Republic of China, 1991, GB 12937-91 (in Chinese)), but it has not been recognized by ICCP and has not been accepted internationally.In this paper, elemental analyses (EA), pyrolysis-gas chromatography, Rock-Eval pyrolysis and optical techniques were used to study the optical features and the hydrocarbon-generating model of “barkinite”. The results show that “barkinite” with imbricate structure usually occurs in single or multiple layers or in a circular form, and no definite border exists between the cell walls and fillings, but there exist clear aperture among the cells.“Barkinite” is characterized by fluorescing in relatively high rank coals. At low maturity of 0.60–0.80%R_o, “barkinite” shows strong bright orange–yellow fluorescence, and the fluorescent colors of different cells are inhomogeneous in one sample. As vitrinite reflectance increases up to 0.90%R_o, “barkinite” also displays strong yellow or yellow–brown fluorescence; and most of “barkinite” lose fluorescence at the maturity of 1.20–1.30%R_o. However, most of suberinite types lose fluorescence at a vitrinite reflectance of 0.50% Ro, or at the stage of high volatile C bituminous coal. In particular, the cell walls of “barkinite” usually show red color, whereas the cell fillings show yellow color under transmitted light. This character is contrary to suberinite.“Barkinite” is also characterized by late generation of large amounts of liquid oil, which is different from the early generation of large amounts of liquid hydrocarbon. In addition, “barkinite” with high hydrocarbon generation potential, high elemental hydrogen, and low carbon content. The pyrolysis products of “barkinite” are dominated by aliphatic compounds, followed by low molecular-weight aromatic compounds (benzene, toluene, xylene and naphthalene), and a few isoprenoids. The pyrolysis hydrocarbons of “barkinite” are mostly composed of light oil (C₆–C₁₄) and wet gas (C₂–C₅), and that heavy oil (C₁₅⁺) and methane (C₁) are the minor hydrocarbon.In addition, suberinite is defined only as suberinized cell walls—it does not include the cell fillings, and the cell lumens were empty or filled by corpocollinites, which do not show any fluorescence. Whereas, “barkinite” not only includes the cell walls, but also includes the cell fillings, and the cell fillings show bright yellow fluorescence.Since the optical features and the hydrocarbon-generating model of “barkinite” are quite different from suberinite. We suggest that “barkinite” is a new type of maceral.     

The use of bisnorhopane as a stratigraphic marker in the Oseberg Back Basin, North Viking Graben, Norwegian North Sea

This paper discusses the occurrence of 28,30-dinor-17α,18α,21β-hopane (bisnorhopane) in stratigraphically, fairly well preserved Viking Group sections from wells in local depressions in the North Viking Graben Area. The results show the presence of high relative amounts of bisnorhopane in the “Syn-rift sections”, whilst the “Post-rift sections” contain little or no bisnorhopane. Since most exploration wells are drilled on structural highs, primarily penetrating the “Post-rift Draupne”, this may explain why many analyzed source rock sections in this area contain little bisnorhopane.As a correlation of Draupne sections using the vertical, relative bisnorhopane distributions, it is suggested to be a potential stratigraphic marker for the area, indicating the presence of “Syn-rift Draupne” sediments.The relative bisnorhopane amounts follow a logarithmic reduction with depth and thermal maturity. The bisnorhopane signal is nearly extinguished at 3700 m depth at a maturity of R_o = 0.9–1.0%.     

Heightened sensitivity of a poorly buffered high arctic lake to late-Holocene climatic change

A diatom-based paleolimnological investigation was conducted on late Holocene sediments from a poorly buffered lake, informally named “Rock Basin Lake”, on Ellesmere Island, Arctic Canada. The fossil diatom record is unlike any other obtained thus far from high arctic regions, exhibiting dynamic assemblage shifts over the entire 3300 yr sedimentary record. Multiple proxies (i.e., diatoms, pH reconstructions, biogenic silica, C/N ratios, total organic carbon) appear to sensitively track rapid limnological changes, which are associated with distinct climate intervals as inferred from other regional proxy records. The highly responsive nature of the diatom assemblages in Rock Basin Lake, relative to those recorded from nearby alkaline sites, appears to be related to this lake's limited ability to buffer changes in pH. The dynamic species responses suggest that the diatoms in Rock Basin Lake are faithfully tracking climatic changes, and that low-alkalinity lakes may provide the most sensitive diatom-based paleolimnological records from high arctic regions.     

SHRIMP U–Pb zircon geochronology and geochemistry of metavolcanic and metasedimentary rocks in Northwestern Fujian, Cathaysia block, China: Tectonic implications and the need to redefine lithostratigraphic units

Northwestern Fujian Province is one of the most important Pre-Palaeozoic areas in the Cathaysia Block of South China. Metavolcano-sedimentary and metasedimentary rocks of different types, ages and metamorphic grades (granulite to upper greenschist facies) are present, and previously were divided into several Formations and Groups. Tectonic contacts occur between some units, whereas (deformed) unconformities have been reported between others. New SHRIMP U–Pb zircon ages presented here indicate that the original lithostratigraphy and the old “Group” and “Formation” terminology should be abandoned. Thus the “Tianjingping Formation” was not formed in the Archaean or Palaeoproterozoic, as previously considered, but must be younger than its youngest detrital zircons (1790 Ma) but older than regional metamorphism (460 Ma). Besides magmatic zircon ages of 807 Ma obtained from metavolcano-sedimentary rocks of the “Nanshan Formation” and 751–728 Ma for the “Mamianshan Group”, many inherited and detrital zircons with ages ranging from 1.0 to 0.8 Ga were also found in them. These ages indicate that the geological evolution of the study area may be related to the assembly and subsequent break-up of the Rodinia supercontinent. The new zircon results poorly constrain the age of the “Mayuan Group” as Neoproterozoic to early Palaeozoic (728–458 Ma), and not Palaeoproterozoic as previously thought. Many older inherited and detrital zircons with ages of 3.6, 2.8, 2.7, 2.6–2.5, 2.0–1.8 and 1.6 Ga were found in this study. A 3.6 Ga detrital grain is the oldest one so far identified in northwestern Fujian Province as well as throughout the Cathaysia Block. Nd isotope t_DM values of eight volcano-sedimentary and clastic sedimentary rock samples centre on 2.73–1.68 Ga, being much older than the formation ages of their protoliths and thus showing that the recycling of older crust played an important role in their formation. These rocks underwent high grade metamorphism in the early Palaeozoic (458–425 Ma) during an important tectono-thermal event in the Cathaysia Block.     

Petrologic and geochemical characteristics of “barkinite” from the Dahe mine, Guizhou Province, China

Although “barkinite” has long been studied by many geologists, its geochemical characteristics and environment of deposition are still not known in detail. In order to study the petrography and geochemical characteristics of “barkinite”, coal samples from two Permian coal seams were taken from the Dahe mine, Guizhou Province. The samples were separated into maceral fractions, and then analyzed by microscopical, isotopic, Rock-Eval, and geochemical methods. The microscopical results indicate that “barkinite” occurs as four main types. According to their relationship to other maceral groups, “barkinite” is ostensibly formed under variably dry–wet or oxidizing–reducing conditions. The extract yield, isotope data and Rock-Eval values of “barkinite” are different from other macerals. Microscopical and geochemical results indicate that “barkinite” forms part of the liptinite group.     

Dislocation generation, slip systems, and dynamic recrystallization in experimentally deformed plagioclase single crystals

Three samples of gem quality plagioclase crystals of An60 were experimentally deformed at 900 °C, 1 GPa confining pressure and strain rates of 7.5–8.7×10⁻⁷ s⁻¹. The starting material is effectively dislocation-free so that all observed defects were introduced during the experiments. Two samples were shortened normal to one of the principal slip planes (010), corresponding to a “hard” orientation, and one sample was deformed with a Schmid factor of 0.45 for the principal slip system [001](010), corresponding to a “soft” orientation. Several slip systems were activated in the “soft” sample: dislocations of the [001](010) and 110(001) system are about equally abundant, whereas 110{111} and [101] in ( 31) to ( 42) are less common. In the “soft” sample plastic deformation is pervasive and deformation bands are abundant. In the “hard” samples the plastic deformation is concentrated in rims along the sample boundaries. Deformation bands and shear fractures are common. Twinning occurs in close association with fracturing, and the processes are clearly interrelated. Glissile dislocations of all observed slip systems are associated with fractures and deformation bands indicating that deformation bands and fractures are important sites of dislocation generation. Grain boundaries of tiny, defect-free grains in healed fracture zones have migrated subsequent to fracturing. These grains represent former fragments of the fracture process and may act as nuclei for new grains during dynamic recrystallization. Nucleation via small fragments can explain a non-host-controlled orientation of recrystallized grains in plagioclase and possibly in other silicate materials which have been plastically deformed near the semi-brittle to plastic transition.     

The effects of radioactive decay of uranium on elemental and isotopic ratios of Alum shale kerogen

The organic matter in the Alum Shale of Sweden is believed to have been affected post-depositionally by irradiation from the natural decay of U. Alum Shale kerogen H/C ratios are inversely proportional to the natural log of the U concentration, presumably as a result of the liberation of H by irradiation of the organic matter. Stable isotopic ratios of¹³C/¹²C in Alum Shale kerogen are directly proportional to the natural log of the U concentration. Experimental irradiation of Green River shale generated hydrocarbon gases 18% lighter than the parent organic matter, which demonstrates the possibility that irradiation induced generation of isotopically light gases could lower¹³C/¹²C ratios in parent organic matter. Irradiation may be a factor governing the relation between¹³C/¹²C ratios in the Alum Shales. Alum Shale O/C ratios generally increase with increasing U concentration and it is suggested that irradiation of organic matter may facilitate oxidation. The “Rock-Eval” maturity parameters “P.I.” and “Tmax” decrease with increasing U concentration. “P.I.” is presumed to decrease as a result of bitumen destruction or polymerization by irradiation.     

Assessing meteoric water composition and relative humidity fromO andH in wood cellulose: paleoclimatic implications for southern Ontario, Canada

An empirical model is presented that derives the initial isotopic composition of water used by terrestrial plants and the relative humidity that prevailed during photosynthesis from the isotopic composition of oxygen and carbon-bound hydrogen in the plant cellulose. The model uses fixed values for the fractionation factors that describe the evapotranspirative isotopic enrichment of leaf waters and the biochemical fractionations occurring during cellulose synthesis. When applied to cellulose extracted from fossil plant matter, the model can be used to generate quantitative estimates of the temperature and moisture regimes of the past. The application of the model is demonstrated by consideration of δ¹⁸O and δ²H results on cellulose from fossil wood collected at Brampton, Ontario.The Brampton data yield records of systematic changes in the temperature and moisture regimes of the eastern Great Lakes region over the past 11 500 a. Both mean annual temperature and photosynthetic humidity increased substantially from values much lower than the present at the end of the Wisconsin Stage, to values higher than the present in the mid-Holocene. The phase relation of the paleotemperature and paleohumidity curves engenders differentiation of the climatic history at Brampton into four characteristic zones: (I) a period of ameliorating climate predominantly much colder and drier than now, lasting until about 7400 B.P.; (II) an “early Hypsithermal” period of warm and dry conditions, that transformed after 6000 a B.P. into (III) the “main Hypsithermal” time of warmth and pronounced moistness. Subsequent climatic detrioration led to establishment of (IV) cool, moist conditions like the present sometime within the last few thousand years.