Tracing contributions to hydro‐isotopic differences between two adjacent lakes in the southern Tibetan Plateau

Hydrological processes of lakes in the Tibetan Plateau are an important indicator of climate change. Due to the high elevation, inaccessibility and limited availability of historical observations, water budget evaluation of typical lake basins has been inadequate. In this study, stable isotopes are used to trace the multiple water sources contributing to two adjacent lakes on the north slope of the Himalayas, Gongmo‐tso and Drem‐tso. The two lakes have nearly the same elevation, lake area and climatic condition. However, the isotopic composition of the two lakes presents significant differences. Qualitative observations attribute the differences to hydrological discrepancies: Gongmo‐tso is a through‐flow lake, whereas Drem‐tso is a terminal lake. Quantitative analyses, including water and isotope mass balance modelling, clarify the fluxes and isotopic compositions among the various hydrological elements. The isotopic composition of input water, calculated as the summation of rainfall and upstream runoff, is estimated using the local meteoric water line (LMWL) combined with the time series of lake water isotope values. The isotopic composition of evaporation is calculated with a linear resistance model using local meteorological data. The results show that Drem‐tso is a closed lake in a hydrological steady state with relatively more enriched lake water isotope values resulting mainly from evaporation. In contrast, through‐flow accounts for more than 88% of the water input into Gongmo‐tso. The large amount of upstream runoff with lower isotopic composition and enrichment due to evaporation are the major contributions to the observed lake water isotope values. Isotopic modelling of the two neighbouring lakes is effective for isotopic and hydrological research in this region with limited in situ observations. Copyright © 2013 John Wiley & Sons, Ltd.     

Towards hydrological model calibration and validation: simulation of stable water isotopes using the isoWATFLOOD model

Calibration and validation of hydrological models is a challenge, particularly in remote regions that are minimally gauged. This paper develops a novel methodology for large‐scale (>1000 km²) hydrological model calibration and validation using stable water isotopes founded on the rigorous constraints imposed by the need to conserve both water mass and stable isotopes simultaneously. The isoWATFLOOD model is applied to five basins within the Fort Simpson, Northwest Territories region of northern Canada to simulate stream discharge and oxygen‐18 signals over a 3‐year period. The isotopic variation of river discharge, runoff components, and evaporative fractionation are successfully simulated on both a seasonal and continual basis over the watershed domain to demonstrate the application of isotope tracers to regional hydrologic calibration. The intended application of this research is to remote, large‐scale basins, showing promise for improving predictions in minimally gauged basins and climate change research where traditional, rigorous approaches to constraining parameter uncertainty may be impractical. This coupled isotope‐hydrological (i.e. iso‐hydrological) approach to modelling reduces the number of possible parameterizations, resulting in potentially more physically‐based hydrological predictions. isoWATFLOOD provides a tool for water resource managers and utilities to use operationally for water use, allocation, and runoff generation estimations. Copyright © 2012 John Wiley & Sons, Ltd.     

Estimating Runoff Using Hydro-Geodetic Approaches

Given the continuous decline in global runoff data availability over the past decades, alternative approaches for runoff determination are gaining importance. When aiming for global scale runoff at a sufficient temporal resolution and with homogeneous accuracy, the choice to use spaceborne sensors is only a logical step. In this respect, we take water storage changes from Gravity Recovery And Climate Explorer (grace) results and water level measurements from satellite altimetry, and present a comprehensive assessment of five different approaches for river runoff estimation: hydrological balance equation, hydro-meteorological balance equation, satellite altimetry with quantile function-based stage–discharge relationships, a rudimentary instantaneous runoff–precipitation relationship, and a runoff–storage relationship that takes time lag into account. As a common property, these approaches do not rely on hydrological modeling; they are either purely data driven or make additional use of atmospheric reanalyses. Further, these methods, except runoff–precipitation ratio, use geodetic observables as one of their inputs and, therefore, they are termed hydro-geodetic approaches. The runoff prediction skill of these approaches is validated against in situ runoff and compared to hydrological model predictions. Our results show that catchment-specific methods (altimetry and runoff–storage relationship) clearly outperform the global methods (hydrological and hydro-meteorological approaches) in the six study regions we considered. The global methods have the potential to provide runoff over all landmasses, which implies gauged and ungauged basins alike, but are still limited due to inconsistencies in the global hydrological and hydro-meteorological datasets that they use.     

From precipitation to runoff: stable isotopic fractionation effect of glacier melting on a catchment scale

Stable isotope variability and fractionation associated with transformation of precipitation/accumulation to firn to glacial river water is critical in a variety of climatic, hydrological and paleoenvironmental studies. This paper documents the modification of stable isotopes in water from precipitation to glacier runoff in an alpine catchment located in the central Tibetan Plateau. Isotopic changes are observed by sampling firnpack profiles, glacier surface snow/ice, meltwater on the glacier surface and catchment river water at different times during a melt season. Results show the isotopic fractionation effects associated with glacier melt processes. The slope of the δD‐δ¹⁸O regression line and the deuterium excess values decreased from the initial precipitation to the melt‐impacted firnpack (slope from 9.3 to 8.5 and average d‐excess from 13.4‰ to 7.4‰). The slope of the δD‐δ¹⁸O line further decreased to 7.6 for the glacier runoff water. The glacier surface snow/ice from different locations, which produces the main runoff, had the same δD‐δ¹⁸O line slope but lower deuterium excess (by 3.9‰) compared to values observed in the firnpack profile during the melt season. The δD‐δ¹⁸O regression line for the river water exhibited a lower slope compared to the surface snow/ice samples, although they were closely located on the δD‐δ¹⁸O plot. Isotope values for the river and glacier surface meltwater showed little scatter around the δD‐δ¹⁸O regression line, although the samples were from different glaciers and were collected on different days. Results indicate a high consistency of isotopic fractionation in the δD‐δ¹⁸O relationships, as well as a general consistency and temporal covariation of meltwater isotope values at the catchment scale. Copyright © 2013 John Wiley & Sons, Ltd.     

Evaporation in Mediterranean conditions: Estimations based on isotopic approaches at the watershed scale

In Mediterranean regions, the marked climatic seasonality and uneven precipitation distribution complicate the application of isotope mass balances to obtain meaningful basin-wide annual average evaporation rates. In the present study, a mass balance approach carried out on the Tavignanu River watershed in Corsica (France), showed unrealistic evaporation rate estimates: 10% for 2017–2018 and 1% for 2018–2019. This suggests that not only does evaporation alter the seasonal isotopic composition in the river, but that there is complex variability of the dominant water reservoirs contributing to the streamflow. Therefore, we propose a modified mass balance approach, including monthly quantifications of different water sources contributing to the river discharge. This allows the discrimination of isotopic variation occurring by evaporation from that originating by mixing processes. By applying this modified approach, we estimated evaporation rates on the Tavignanu River watershed that were in good agreement with results obtained by hydrological modelling: 40% for 2017–2018 and 46% for 2018–2019, respectively. An uncertainty analysis showed that evaporation rates obtained with the modified isotopic approach are close to those obtained with the non-modified approach. Therefore, we recommend using this modified isotope mass balance approach to estimate evaporation rates in such regions as the Mediterranean with high seasonality in hydrological processes.     

Spatial and temporal variability of stable isotopes (δ18O and δ2H) in surface waters of arid,mountainous Central Asia

Characterization of spatial and temporal variability of stable isotopes (δ¹⁸O and δ²H) of surface waters is essential to interpret hydrological processes and establish modern isotope–elevation gradients across mountainous terrains. Here, we present stable isotope data for river waters across Kyrgyzstan. River water isotopes exhibit substantial spatial heterogeneity among different watersheds in Kyrgyzstan. Higher river water isotope values were found mainly in the Issyk‐Kul Lake watershed, whereas waters in the Son‐Kul Lake watershed display lower values. Results show a close δ¹⁸O–δ²H relation between river water and the local meteoric water line, implying that river water experiences little evaporative enrichment. River water from the high‐elevation regions (e.g., Naryn and Son‐Kul Lake watershed) had the most negative isotope values, implying that river water is dominated by snowmelt. Higher deuterium excess (average d = 13.9‰) in river water probably represents the isotopic signature of combined contributions from direct precipitation and glacier melt in stream discharge across Kyrgyzstan. A significant relationship between river water δ¹⁸O and elevation was observed with a vertical lapse rate of 0.13‰/100 m. These findings provide crucial information about hydrological processes across Kyrgyzstan and contribute to a better understanding of the paleoclimate/elevation reconstruction of this region.     

Spatiotemporal dynamics of water sources in a mountain river basin inferred through δ2H and δ18O of water

In mountainous river basins of the Pacific Northwest, climate models predict that winter warming will result in increased precipitation falling as rain and decreased snowpack. A detailed understanding of the spatial and temporal dynamics of water sources across river networks will help illuminate climate change impacts on river flow regimes. Because the stable isotopic composition of precipitation varies geographically, variation in surface water isotope ratios indicates the volume-weighted integration of upstream source water. We measured the stable isotope ratios of surface water samples collected in the Snoqualmie River basin in western Washington over June and September 2017 and the 2018 water year. We used ordinary least squares regression and geostatistical Spatial Stream Network models to relate surface water isotope ratios to mean watershed elevation (MWE) across seasons. Geologic and discharge data was integrated with water isotopes to create a conceptual model of streamflow generation for the Snoqualmie River. We found that surface water stable isotope ratios were lowest in the spring and highest in the dry, Mediterranean summer, but related strongly to MWE throughout the year. Low isotope ratios in spring reflect the input of snowmelt into high elevation tributaries. High summer isotope ratios suggest that groundwater is sourced from low elevation areas and recharged by winter precipitation. Overall, our results suggest that baseflow in the Snoqualmie River may be relatively resilient to predicted warming and subsequent changes to snowpack in the Pacific Northwest.     

Water source dynamics of high Arctic river basins

Arctic river basins are amongst the most vulnerable to climate change. However, there is currently limited knowledge of the hydrological processes that govern flow dynamics in Arctic river basins. We address this research gap using natural hydrochemical and isotopic tracers to identify water sources that contributed to runoff in river basins spanning a gradient of glacierization (0–61%) in Svalbard during summer 2010 and 2011. Spatially distinct hydrological processes operating over diurnal, weekly and seasonal timescales were characterized by river hydrochemistry and isotopic composition. Two conceptual water sources (‘meltwater’ and ‘groundwater’) were identified and used as a basis for end‐member mixing analyses to assess seasonal and year‐to‐year variability in water source dynamics. In glacier‐fed rivers, meltwater dominated flows at all sites (typically >80%) with the highest contributions observed at the beginning of each study period in early July when snow cover was most extensive. Rivers in non‐glacierized basins were sourced initially from snowmelt but became increasingly dependent on groundwater inputs (up to 100% of total flow volume) by late summer. These hydrological changes were attributed to the depletion of snowpacks and enhanced soil water storage capacity as the active layer expanded throughout each melt season. These findings provide insight into the processes that underpin water source dynamics in Arctic river systems and potential future changes in Arctic hydrology that might be expected under a changing climate. Copyright © 2013 John Wiley & Sons, Ltd.     

Under‐ice salinity and stable isotope distribution of Saroma‐ko Lagoon,Hokkaido, northern Japan

In winter, lakes and lagoons at high altitudes or high latitudes have interesting hydrological cycles that differ from those in other seasons or in other regions, because water surfaces are covered with ice. Hydrological balances of lakes and lagoons are complex dynamic systems, and to elucidate them, isotopic tracers of water have been used as effective tools along with observations of precipitation, evaporation, inflows, and outflows. Here, to understand hydrological processes during freezing periods in the brackish Saroma‐ko Lagoon, Hokkaido, northern Japan, we examined horizontal and vertical distributions of salinity and isotope compositions of lagoon water and ice in 2005 and 2006. Horizontal and vertical gradients of salinity and isotope compositions were observed from the river mouth to the sea channel, and factors determining these distributions were considered. The mixing of freshwater and seawater and a freezing effect were presumed to be factors in relationships between salinity and isotopes and in relationships between surface waters and ice just above the water. A simple box model for water balance was constructed based on these putative factors to reproduce the distributions of salinity and isotope compositions of surface waters and ice. An evaluation of the model revealed that this hydrological system is controlled primarily by horizontal advection of the epilimnion, freshwater influx, and the ice growth rate. Copyright © 2009 John Wiley & Sons, Ltd.     

Estimation of uncertainty sources in the projections of Lithuanian river runoff

Particular attention is given to the reliability of hydrological modelling results. The accuracy of river runoff projection depends on the selected set of hydrological model parameters, emission scenario and global climate model. The aim of this article is to estimate the uncertainty of hydrological model parameters, to perform sensitivity analysis of the runoff projections, as well as the contribution analysis of uncertainty sources (model parameters, emission scenarios and global climate models) in forecasting Lithuanian river runoff. The impact of model parameters on the runoff modelling results was estimated using a sensitivity analysis for the selected hydrological periods (spring flood, winter and autumn flash floods, and low water). During spring flood the results of runoff modelling depended on the calibration parameters that describe snowmelt and soil moisture storage, while during the low water period—the parameter that determines river underground feeding was the most important. The estimation of climate change impact on hydrological processes in the Merkys and Neris river basins was accomplished through the combination of results from A1B, A2 and B1 emission scenarios and global climate models (ECHAM5 and HadCM3). The runoff projections of the thirty-year periods (2011–2040, 2041–2070, 2071–2100) were conducted applying the HBV software. The uncertainties introduced by hydrological model parameters, emission scenarios and global climate models were presented according to the magnitude of the expected changes in Lithuanian rivers runoff. The emission scenarios had much greater influence on the runoff projection than the global climate models. The hydrological model parameters had less impact on the reliability of the modelling results.     

Effects of land‐use changes on hydrological processes in the middle basin of the Heihe River,northwest China

The effects of land‐use changes on the runoff process in the midstream plain of this arid inland river basin are a key factor in the rational allocation of water resources to the middle and lower reaches. The question is whether and by how much increasingly heavy land use impacts the hydrological processes in such an arid inland river basin. The catchment of the Heihe River, one of the largest inland rivers in the arid region of northwest China, was chosen to investigate the hydrological responses to land‐use change. Flow duration curves were used to detect trends and variations in runoff between the upper and lower reaches. Relationships among precipitation, upstream runoff, and hydrological variables were identified to distinguish the effects of climatic changes and upstream runoff changes on middle and downstream runoff processes. The quantitative relation between midstream cultivated land use and various parameters of downstream runoff processes were analysed using the four periods of land‐use data since 1956. The Volterra numerical function relation of the hydrological non‐linear system response was utilized to develop a multifactor hydrological response simulation model based on the three factors of precipitation, upstream runoff, and cultivated land area. The results showed that, since 1967, the medium‐ and high‐coverage natural grassland area in the midstream region has decreased by 80·1%, and the downstream runoff has declined by 27·32% due to the continuous expansion of the cultivated land area. The contribution of cultivated land expansion to the impact on the annual total runoff is 14–31%, on the annual, spring and winter base flow it is 44–75%, and on spring and winter discharge it is 23–64%. Once the water conservation plan dominated by land‐use structural adjustments is implemented over the next 5 years, the mean annual discharge in the lower reach could increase by 8·98% and the spring discharge by 26·28%. This will significantly alleviate the imbalance between water supply and demand in both its quantity and temporal distribution in the middle and lower reaches. Copyright © 2006 John Wiley & Sons, Ltd.     

Hydrological processes in the different landscape zones of alpine cold regions in the wet season,combining isotopic and hydrochemical tracers

Studies on hydrological processes are often emphasized in resource and environmental studies. This paper identifies the hydrological processes in different landscape zones during the wet season based on the isotopic and hydrochemical analysis of glacier, snow, frozen soil, groundwater and other water sources in the headwater catchment of alpine cold regions. Hydrochemical tracers indicated that the chemical compositions of the water are typically characterized by: (1) Ca? HCO₃ type in glacier snow zone, (2) Mg? Ca? SO₄ type for surface runoff and Ca? Mg? HCO₃ type for groundwater in alpine desert zone, (3) Ca? Mg? SO₄ type for surface water and Ca? Mg? HCO₃ type for groundwater in alpine shrub zone, and (4) Ca? Na? SO₄ type in surface runoff in the alpine grassland zone. The End‐Members Mixing Analysis (EMMA) was employed for hydrograph separation. The results showed that the Mafengou River in the wet season was mainly recharged by groundwater in alpine cold desert zones and shrub zones (52%), which came from the infiltration and transformation of precipitation, thawed frozen soil water and glacier‐snow meltwater. Surface runoff in the glacier‐snow zone accounted for 11%, surface runoff in alpine cold desert zones and alpine shrub meadow zones accounted for 20%, thawed frozen soil water in alpine grassland zones accounted for 9% of recharge and precipitation directly into the river channel (8%). This study suggested that the whole catchment precipitation did not produce significant surface runoff directly, but mostly transformed into groundwater or interflow, and finally arrived in the river channel. Copyright © 2011 John Wiley & Sons, Ltd.     

Spatio‐temporal variability of the isotopic input signal in a partly forested catchment: Implications for hydrograph separation

The isotopic composition of precipitation (D and ¹⁸O) has been widely used as an input signal in water tracer studies. Whereas much recent effort has been put into developing methodologies to improve our understanding and modelling of hydrological processes (e.g., transit‐time distributions or young water fractions), less attention has been paid to the spatio‐temporal variability of the isotopic composition of precipitation, used as input signal in these studies. Here, we investigated the uncertainty in isotope‐based hydrograph separation due to the spatio‐temporal variability of the isotopic composition of precipitation. The study was carried out in a Mediterranean headwater catchment (0.56 km²). Rainfall and throughfall samples were collected at three locations across this relatively small catchment, and stream water samples were collected at the outlet. Results showed that throughout an event, the spatial variability of the input signal had a higher impact on hydrograph separation results than its temporal variability. However, differences in isotope‐based hydrograph separation determined preevent water due to the spatio‐temporal variability were different between events and ranged between 1 and 14%. Based on catchment‐scale isoscapes, the most representative sampling location could also be identified. This study confirms that even in small headwater catchments, spatio‐temporal variability can be significant. Therefore, it is important to characterize this variability and identify the best sampling strategy to reduce the uncertainty in our understanding of catchment hydrological processes.     

Delineating extent and magnitude of river flooding to lakes across a northern delta using water isotope tracers

Hydrological monitoring in complex, dynamic northern floodplain landscapes is challenging, but increasingly important as a consequence of multiple stressors. The Peace-Athabasca Delta in northern Alberta, Canada, is a Ramsar Wetland of International Importance reliant on episodic river ice-jam flood events to recharge abundant perched lakes and wetlands. Improved and systematic monitoring of landscape-scale hydrological connectivity among freshwater ecosystems (rivers, channels, wetlands, and lakes) is needed to guide stewardship decisions in the face of climate change and upstream industrial development. Here, we use water isotope compositions, supplemented by measurements of specific conductivity and field observations, from 68 lakes and 9 river sites in May 2018 to delineate the extent and magnitude of spring ice-jam induced flooding along the Peace and Athabasca rivers. Lake-specific estimates of input water isotope composition (δ_I) were modelled after accounting for influence of evaporative isotopic enrichment. Then, using the distinct isotopic signature of input water sources, we develop a set of binary mixing models and estimate the proportion of input to flooded lakes attributable to river floodwater and precipitation (snow or rain). This approach allowed identification of areas and magnitude of flooding that were not captured by other methods, including direct observations from flyovers, and to demarcate flow pathways in the delta. We demonstrate water isotope tracers as an efficient and effective monitoring tool for delineating spatial extent and magnitude of an important hydrological process and elucidating connectivity in the Peace-Athabasca Delta, an approach that can be readily adopted at other floodplain landscapes.     

The influence of groundwater representation on hydrological simulation and its assessment using satellite‐based water storage variation

The interaction between surface water and groundwater is an important aspect of hydrological processes. Despite its importance, groundwater is not well represented in many land surface models. In this study, a groundwater module with consideration of surface water and groundwater dynamic interactions is incorporated into the distributed biosphere hydrological (DBH) model in the upstream of the Yellow River basin, China. Two numerical experiments are conducted using the DBH model: one with groundwater module active, namely, DBH_GW and the other without, namely, DBH_NGW. Simulations by two experiments are compared with observed river discharge and terrestrial water storage (TWS) variation from the Gravity Recovery and Climate Experiment (GRACE). The results show that river discharge during the low flow season that is underestimated in the DBH_NGW has been improved by incorporating the groundwater scheme. As for the TWS, simulation in DBH_GW shows better agreement with GRACE data in terms of interannual and intraseasonal variations and annual changing trend. Furthermore, compared with DBH_GW, TWS simulated in DBH_NGW shows smaller decreases during autumn and smaller increases in spring. These results suggest that consideration of groundwater dynamics enables a more reasonable representation of TWS change by increasing TWS amplitudes and signals and as a consequence, improves river discharge simulation in the low flow seasons when groundwater is a major component in runoff. Additionally, incorporation of groundwater module also leads to wetter soil moisture and higher evapotranspiration, especially in the wet seasons.     

Contemporary processes of environmental information in the atmosphere-glacier-runoff system in an area of typical monsoon temperate glacier

Sampling was carried out at Baishui No. 1, the largest glacier on Mt. Yulong, China, during the summers of 1999 and 2000, to investigate the spatial variations of oxygen isotopes in the atmosphere-glacier-river system. The results confirm that there is an inverse relation between the oxygen isotopic composition of precipitation and air temperature/precipitation amount. This suggests that a strong “precipitation amount effect” exists in this typical monsoon temperate-glacier region. There are marked differences of the δ¹⁸O values of winter-accumulated snow, glacial meltwater, summer precipitation and the glacier-fed river water. Spatial and temporal variations of isotopic composition are controlled by climatic conditions. Isotopic fractionation and differentiation occur during phase changes, snow-to-ice and ice-to-meltwater transformations, and runoff processes. Variations of stable isotopes in glacier runoff can indicate variations of sources of supply, as well as different discharge-related processes. Ionic changes occur as a result of meltwater contact with glacier bed materials.

     

Differing controls on river‐ and lake‐water hydrogen and oxygen isotopic values in the western United States

Surface water oxygen and hydrogen isotopic values are commonly used as proxies of precipitation isotopic values to track modern hydrologic processes while proxies of water isotopic values preserved in lake and river sediments are used for paleoclimate and paleoaltimetry studies. Previous work has been able to explain variability in USA river‐water and meteoric‐precipitation oxygen isotope variability with geographic variables. These studies show that in the western United States, river‐water isotopic values are depleted relative to precipitation values. In comparison, the controls on lake‐water isotopic values are not well constrained. It has been documented that western United States lake‐water input values, unlike river water, reflect the monthly weighted mean isotopic value of precipitation. To understand the differing controls on lake‐ and river‐water isotopic values in the western United States, we examine the seasonal distribution of precipitation, evaporation and snowmelt across a range of seasonality regimes. We generate new predictive equations based on easily measured factors for western United States lake‐water, which are able to explain 69–63% of the variability in lake‐water hydrogen and oxygen isotopic values. In addition to the geographic factors that can explain river and precipitation values, lake‐water isotopic values need factors related to local hydrologic and climatic characteristics to explain variability. Study results suggest that the spring snowmelt runs off the landscape via rivers and streams, depleting river and stream‐water isotopic values. By contrast, lakes receive seasonal contributions of precipitation in proportion to the seasonal fraction of total annual precipitation within their watershed. Climate change may alter the ratio of snow to rain fall, affecting water resource partitioning between rivers and lakes and by implication of groundwater. Paleolimnological studies must account for the multiple drivers of water isotopic values; likewise, studies based on the isotopic composition of fossil material need to distinguish between species that are associated with rivers versus lakes. Copyright © 2010 John Wiley & Sons, Ltd.     

Continuous fluorescence assessment of organic matter variability on the Bournbrook River,Birmingham, UK

Continuous monitoring of dissolved organic matter (DOM) character and concentration at hourly resolution is rare, despite the importance of analysing organic matter variability at high‐temporal resolution to evaluate river carbon budgeting, river water health by detecting episodic pollution and to determine short‐term variations in chemical and ecological function. The authors report a 2‐week experiment performed on DOM sampled from Bournbrook, Birmingham, UK, an urban river for which spectrophotometric (fluorescence, absorbance), physiochemical (dissolved organic carbon [DOC], electrical conductivity, pH) and isotopic (D/H) parameters have been measured at hourly frequency. Our results show that the river had sub‐daily variations in both organic matter concentration and characteristics. In particular, after relatively high‐magnitude precipitation events, organic carbon concentration increased, with an associated increase in intensity of both humic‐like and tryptophan‐like fluorescence. D/H isotopic ratio demonstrates different hydrological responses to different rainfall events, and organic matter character reflects this difference. Events with precipitation < 2 mm typically yielded isotopically heavy water with relatively hydrophilic DOM and relatively low specific absorbance. Events with precipitation > 2 mm had isotopically lighter water with higher specific absorbance and a decrease in the proportion of microbially derived to humic‐like fluorescence. In our heavily urbanized catchment, we interpret these signals as one where riverine DOM is dominated by storm sewer‐derived ‘old’ organic matter at low‐rainfall amounts and a mixed signal at high‐precipitation amounts where ‘event’ surface runoff‐derived organic matter dominate during storm sewer and combined sewer overflow routed DOM. Copyright © 2009 John Wiley & Sons, Ltd.     

Impact of land-use change on hydrological processes in the Maying River basin, China

Since the 1960s, dramatic changes have taken place in land-use patterns characterized by the persistent expansion of cultivated land and a continuous decrease in natural woodland and grassland in the arid inland river basins of China. It is very important to assess the effects of such land-use changes on the hydrological processes so vital for water resource management and sustainable development on the catchment scale. The Maying River catchment, a typical arid inland watershed located in the middle of the Hexi Corridor in northwest China, was the site chosen to investigate the hydrological responses to land-use changes. The annual runoff, base flow, maximum peak flow, and typical seasonal runoff in both spring and autumn flood periods were selected as the variables in the hydrological processes. Statistical-trend analysis and curvilinear regression were utilized to detect the trends in hydrological variables while eliminating the climatic influence. The relationship between cultivated land-use and hydrological variables was analyzed based on four periods of land-use variation data collected since 1965. A runoff model was established composed of two factors, i.e., cultivated land use and precipitation. The impact of land use changes, especially in the large ar- eas of upstream woodland and grassland turned into cultivated lands since 1967, has resulted in a mean annual runoff decrease of 28.12%, a base flow decline of 35.32%, a drop in the maximum peak discharge of 35.77%, and mean discharge decreases in spring and autumn of 36.05% and 24.87% respectively, of which the contribution of cultivated land expansion to the influence of annual runoff amounts to 77%-80%, with the contribution to the influence of spring discharge being 73%-81%, and that to the influence of base flow reaching 62%-65%. Thus, a rational regulation policy of land use patterns is vitally important to the sustainable use of water resources and the proper development of the entire catchment.     

Sampling for isotopic responses in surface waters

This paper considers situations in which stable isotopes may be used as natural tracers of precipitation through to surface waters. Two aspects affecting the applicability of the technique are highlighted: first, the variance through time of isotope concentrations in precipitation, i.e. the isotope input signal, and second, the attenuation or damping of this signal during the transmission of water downwards through the hydrological system. Both factors affect the likelihood of obtaining an isotope response, i.e. a variation of isotope concentrations in a surface water which may be related to variations in the precipitation input. Analysis of precipitation over the Malham area, U.K., reveals large isotopic variations through time. These variations, however, are only poorly correlated with meteorological variables (temperature, precipitation amount, and air mass type). Snowmelt and occluded frontal rainfall are suggested as providing the most reliable ‘spikes’ for an isotopic response at the output in tracing studies. In most hydrological systems, a high degree of signal attenuation is noted. In the Malham area of karst, 57 per cent of the total range of input variation was lost in surface waters, whilst 74 per cent was lost in mobile soil moisture. An isotopic response can only reasonably be expected in a system with rapid throughput, where there is little opportunity for mixing and storage of waters.