1: Subduction,slab detachment and mineralization: The Neogene in the Apuseni Mountains and Carpathians

The Inner Carpathians comprise several distinct Neogene late-stage orogenic Pb–Zn–Cu–Ag–Au ore districts. The mineral deposits in these districts are closely related to volcanic and subvolcanic rocks, and represent mainly porphyry and epithermal vein deposits, which formed within short periods of time in each district. Here, we discuss possible geodynamic and structural controls that suggest why some of the Neogene volcanic districts within the Carpathians comprise abundant mineralization, while others are barren. The Neogene period has been characterized by an overall geodynamic regime of subduction, where primary roll-back of the subducted slab and secondary phenomena, like slab break-off and the development of slab windows, could have contributed to the evolution, location and type of volcanic activity. Structural features developing in the overlying lithosphere and visible in the Carpathian crust, such as transtensional wrench corridors, block rotation and relay structures due to extrusion tectonics, have probably acted in focusing hydrothermal activity. As a result of particular events in the geodynamic evolution and the development of specific structural features, mineralization formed during fluid channelling within transtensional wrench settings and during periods of extension related to block rotation.In the Slovakian ore district of the Western Carpathians, Neogene volcanism and associated mineralization were localized by sinistral, NE-trending wrench corridors, which formed part of the extruding Alcapa block. The Baia Mare ore district, in the Eastern Carpathians, reflects a transtensional wrench setting on distributed oversteps close to the termination of the Dragos Voda fault. There, mineralization was spatially controlled by the transtensional Dragos Voda master fault and associated cross-fault systems. The Golden Quadrangle Cu–Au ore district of the Southern Apuseni Mountains reflects an unusual rotated transtensional/extensional setting close to the termination of a graben system. There, fluid flow was probably localized by fault propagation at the inner tip of the graben system.The spatial and temporal evolution of the magmatism and its changing geochemical signature from (N)W to (S)E strongly suggests a link with the contemporaneous northeastward roll-back of the subducted slab and a progressive southeastward detachment during accelerating roll-back. This geodynamic evolution is further supported by the present-day overall and detailed mantle lithospheric density images, the present-day heat flow patterns, the crustal architecture and its interpreted evolution, and the spatial and temporal evolution of depocentres around the Carpathian arc. In contrast to all these features, the mineral deposits in the West Carpathians, East Carpathians and Apuseni Mountains are too synchronous with respect to their individual volcanic history and contrast too much with younger volcanics of similar style, but barren, in southeastern parts of the Carpathians to simply link them directly to the slab evolution. In all three districts, the presence of magmatic fluids released from shallow plutons and their mixing with meteoric water were critical for mineralization, requiring transtensional or extensional local regimes at the time of mineralization, possibly following initial compressional regimes.These three systems show that mineralization was probably controlled by the superposition of favourable mantle lithospheric conditions and partly independent, evolving upper crustal deformation conditions.In the 13 to 11 Ma period the dominant mineralization formed all across the Carpathians, and was superimposed on structurally favourable crustal areas with, at that time, volcanic–hydrothermal activity. The period may reflect the moment when the (upper part of the) crust failed under lithospheric extension imposed by the slab evolution. This crustal failure would have fragmented the overriding plate, possibly breaking up the thermal lid, to provoke intensive fluid flow in specific areas, and allowed subsequent accelerated tectonic development, block rotation and extrusion of a “family of sub-blocks” that are arbitrarily regarded as the Tisia–Dacia or Alcapa blocks, even though they have lost their internal entity.     

Interplay of tectonics and neogene post-collisional magmatism in the intracarpathian region

Distribution of the Neogene calc-alkaline magmatism of the Carpathian arc is directly related in space and time to the kinematics of the two major terranes of the Intracarpathian area (Alcapa, Tisia-Getia) along the south-eastern border of the European plate. In the West Carpathians and adjacent areas, the volcanic activity occurred between 20–11 Ma, with large volumes of both acidic and intermediate rocks, generally distributed randomly, sometimes transversally to the orogenic belt and as rare small occurrences along the Flysch belt. In the East Carpathians, the volcanic rocks are distributed along the northern margin of the Zemplin block, the north–easternmost part of the Alcapa and eastward along the front of the Getic block, at the contact with European plate. Between Tokaj-Slanské-Vihorlat up to northern Cãlimani Mountains, the magmatism occurred between 14–9 Ma, and along the Cãlimani-Harghita chain between 9–0.2 Ma. The calc-alkaline magmatic rocks of the Apuseni Mountains are located in the interior of the Tisia block and occurred between 14–9 Ma. The generation of the calc-alkaline magmatism is considered here as the result of complex interplay between plate roll-back and lithospheric detachment tectonic processes and the break-off of the subducted plate, mostly in a post-collisional setting. (1) The magmatites of the Western Carpathians and the Pannonian basin were generated in direct relation to subduction roll-back processes, over the downgoing slab, during the period of lateral extrusion and back-arc extension. In this area, characterized by maximum crustal shortening, we can infer further delamination processes to explain the generation of magmas. (2) The magmatic rocks from the northern sector of the East Carpathians (Tokaj-Slanské-Vihorlat up to the Northern Cãlimani Mountains), resulted after subduction roll-back processes and an almost simultaneous break-off of the descending plate all along the arc segment during main clockwise rotation of the Intracarpathian terranes. (3) In the eastern sector of the East Carpathians (Cãlimani up to Harghita Mountains), the magmatic rocks were generated through partial melting of the subducted slab followed by gradual break-off of the subducted plate along strike (north to south). (4) The Apuseni Mts. magmatic activity resulted in transtensional tectonic regime by decompressional melting of lithospheric mantle, during the translation and rotation of Tisia-Getia block.     

Geochemical response of magmas to Neogene–Quaternary continental collision in the Carpathian–Pannonian region: A review

The Carpathian–Pannonian Region contains Neogene to Quaternary magmatic rocks of highly diverse composition (calc-alkaline, shoshonitic and mafic alkalic) that were generated in response to complex microplate tectonics including subduction followed by roll-back, collision, subducted slab break-off, rotations and extension. Major element, trace element and isotopic geochemical data of representative parental lavas and mantle xenoliths suggests that subduction components were preserved in the mantle following the cessation of subduction, and were reactivated by asthenosphere uprise via subduction roll-back, slab detachment, slab-break-off or slab-tearing. Changes in the composition of the mantle through time are evident in the geochemistry, supporting established geodynamic models.Magmatism occurred in a back-arc setting in the Western Carpathians and Pannonian Basin (Western Segment), producing felsic volcaniclastic rocks between 21 to 18 Ma ago, followed by younger felsic and intermediate calc-alkaline lavas (18–8 Ma) and finished with alkalic-mafic basaltic volcanism (10–0.1 Ma). Volcanic rocks become younger in this segment towards the north. Geochemical data for the felsic and calc-alkaline rocks suggest a decrease in the subduction component through time and a change in source from a crustal one, through a mixed crustal/mantle source to a mantle source. Block rotation, subducted roll-back and continental collision triggered partial melting by either delamination and/or asthenosphere upwelling that also generated the younger alkalic-mafic magmatism.In the westernmost East Carpathians (Central Segment) calc-alkaline volcanism was simultaneously spread across ca. 100 km in several lineaments, parallel or perpendicular to the plane of continental collision, from 15 to 9 Ma. Geochemical studies indicate a heterogeneous mantle toward the back-arc with a larger degree of fluid-induced metasomatism, source enrichment and assimilation on moving north-eastward toward the presumed trench. Subduction-related roll-back may have triggered melting, although there may have been a role for back-arc extension and asthenosphere uprise related to slab break-off.Calc-alkaline and adakite-like magmas were erupted in the Apuseni Mountains volcanic area (Interior Segment) from15–9 Ma, without any apparent relationship with the coeval roll-back processes in the front of the orogen. Magmatic activity ended with OIB-like alkali basaltic (2.5 Ma) and shoshonitic magmatism (1.6 Ma). Lithosphere breakup may have been an important process during extreme block rotations (60°) between 14 and 12 Ma, leading to decompressional melting of the lithospheric and asthenospheric sources. Eruption of alkali basalts suggests decompressional melting of an OIB-source asthenosphere. Mixing of asthenospheric melts with melts from the metasomatized lithosphere along an east–west reactivated fault-system could be responsible for the generation of shoshonitic magmas during transtension and attenuation of the lithosphere.Voluminous calc-alkaline magmatism occurred in the Cãlimani-Gurghiu-Harghita volcanic area (South-eastern Segment) between 10 and 3.5 Ma. Activity continued south-eastwards into the South Harghita area, in which activity started (ca. 3.0–0.03 Ma, with contemporaneous eruption of calc-alkaline (some with adakite-like characteristics), shoshonitic and alkali basaltic magmas from 2 to 0.3 Ma. Along arc magma generation was related to progressive break-off of the subducted slab and asthenosphere uprise. For South Harghita, decompressional melting of an OIB-like asthenospheric mantle (producing alkali basalt magmas) coupled with fluid-dominated melting close to the subducted slab (generating adakite-like magmas) and mixing between slab-derived melts and asthenospheric melts (generating shoshonites) is suggested. Break-off and tearing of the subducted slab at shallow levels required explaining this situation.     

Plate tectonic evolution of the southern margin of Eurasia in the Mesozoic and Cenozoic

Thirteen time interval maps were constructed, which depict the Triassic to Neogene plate tectonic configuration, paleogeography and general lithofacies of the southern margin of Eurasia. The aim of this paper is to provide an outline of the geodynamic evolution and position of the major tectonic elements of the area within a global framework. The Hercynian Orogeny was completed by the collision of Gondwana and Laurussia, whereas the Tethys Ocean formed the embayment between the Eurasian and Gondwanian branches of Pangea. During Late Triassic–Early Jurassic times, several microplates were sutured to the Eurasian margin, closing the Paleotethys Ocean. A Jurassic–Cretaceous north-dipping subduction boundary was developed along this new continental margin south of the Pontides, Transcaucasus and Iranian plates. The subduction zone trench-pulling effect caused rifting, creating the back-arc basin of the Greater Caucasus–proto South Caspian Sea, which achieved its maximum width during the Late Cretaceous. In the western Tethys, separation of Eurasia from Gondwana resulted in the formation of the Ligurian–Penninic–Pieniny–Magura Ocean (Alpine Tethys) as an extension of Middle Atlantic system and a part of the Pangean breakup tectonic system. During Late Jurassic–Early Cretaceous times, the Outer Carpathian rift developed. The opening of the western Black Sea occurred by rifting and drifting of the western–central Pontides away from the Moesian and Scythian platforms of Eurasia during the Early Cretaceous–Cenomanian. The latest Cretaceous–Paleogene was the time of the closure of the Ligurian–Pieniny Ocean. Adria–Alcapa terranes continued their northward movement during Eocene–Early Miocene times. Their oblique collision with the North European plate led to the development of the accretionary wedge of the Outer Carpathians and its foreland basin. The formation of the West Carpathian thrusts was completed by the Miocene. The thrust front was still propagating eastwards in the eastern Carpathians.During the Late Cretaceous, the Lesser Caucasus, Sanandaj–Sirjan and Makran plates were sutured to the Iranian–Afghanistan plates in the Caucasus–Caspian Sea area. A north-dipping subduction zone jumped during Paleogene to the Scythian–Turan Platform. The Shatski terrane moved northward, closing the Greater Caucasus Basin and opening the eastern Black Sea. The South Caspian underwent reorganization during Oligocene–Neogene times. The southwestern part of the South Caspian Basin was reopened, while the northwestern part was gradually reduced in size. The collision of India and the Lut plate with Eurasia caused the deformation of Central Asia and created a system of NW–SE wrench faults. The remnants of Jurassic–Cretaceous back-arc systems, oceanic and attenuated crust, as well as Tertiary oceanic and attenuated crust were locked between adjacent continental plates and orogenic systems.     

A rapid method to map the crustal and lithospheric thickness using elevation, geoid anomaly and thermal analysis. Application to the Gibraltar Arc System, Atlas Mountains and adjacent zones

We present a method based on the combination of elevation and geoid anomaly data together with thermal field to map crustal and lithospheric thickness. The main assumptions are local isostasy and a four-layered model composed of crust, lithospheric mantle, sea water and the asthenosphere. We consider a linear density gradient for the crust and a temperature dependent density for the lithospheric mantle. We perform sensitivity tests to evaluate the effect of the variation of the model parameters and the influence of RMS error of elevation and geoid anomaly databases. The application of this method to the Gibraltar Arc System, Atlas Mountains and adjacent zones reveals the presence of a lithospheric thinning zone, SW–NE oriented. This zone affects the High and Middle Atlas and extends from the Canary Islands to the eastern Alboran Basin and is probably linked with a similarly trending zone of thick lithosphere constituting the western Betics, eastern Rif, Rharb Basin, and Gulf of Cadiz. A number of different, even mutually opposite, geodynamic models have been proposed to explain the origin and evolution of the study area. Our results suggest that a plausible slab-retreating model should incorporate tear and asymmetric roll-back of the subducting slab to fit the present-day observed lithosphere geometry. In this context, the lithospheric thinning would be caused by lateral asthenospheric flow. An alternative mechanism responsible for lithospheric thinning is the presence of a hot magmatic reservoir derived from a deep ancient plume centred in the Canary Island, and extending as far as Central Europe.     

The lithospheric geodynamics of plate boundary transpression in New Zealand: Initiating and emplacing subduction along the Hikurangi margin, and the tectonic evolution of the Alpine Fault system

In contrast to the normal ‘Wilson cycle’ sequence of subduction leading to continental collision and associated mountain building, the evolution of the New Zealand plate boundary in the Neogene reflects the converse—initially a period of continental convergence that is followed by the emplacement of subduction. Plate reconstructions allow us to place limits on the location and timing of the continental convergence and subduction zones and the migration of the transition between the two plate boundary regimes. Relative plate motions and reconstructions since the Early to Mid-Miocene require significant continental convergence in advance of the emplacement of the southward migrating Hikurangi subduction—a sequence of tectonism seen in the present plate boundary geography of Hikurangi subduction beneath North Island and convergence in the Southern Alps along the Alpine Fault. In contrast to a transition from subduction to continental convergence where the leading edge of the upper plate is relatively thin and deformable, the transition from a continental convergent regime, with its associated crustal and lithospheric thickening, to subduction of oceanic lithosphere requires substantial thinning (removal) of upper plate continental lithosphere to make room for the slab. The simple structure of the Wadati–Benioff zone seen in the present-day geometry of the subducting Pacific plate beneath North Island indicates that this lithospheric adjustment occurs quickly. Associated with this rapid lithospheric thinning is the development of a series of ephemeral basins, younging to the south, that straddle the migrating slab edge. Based on this association between localized vertical tectonics and slab emplacement, the tectonic history of these basins records the effects of lithospheric delamination driven by the southward migrating leading edge of the subducting Pacific slab. Although the New Zealand plate boundary is often described as simply two subduction zones linked by the transpressive Alpine Fault, in actuality the present is merely a snapshot view of an ongoing and complex evolution from convergence to subduction.     

Oligocene–Miocene geodynamic evolution of the central part of Urumieh-Dokhtar Arc of Iran

Basic volcanic rocks from Tafresh, west Kashan, and west Nain volcanic successions in the central part of Urumieh-Dokhtar Magmatic Assemblage (UDMA) of Iran yield K–Ar ages ranging from 26.8 to 18.2 Ma. These ages indicate significant Late Oligocene–Early Miocene basic volcanism in the UDMA. These ages, combined with K–Ar ages of 26.0 and 14.1 Ma, respectively, for associated low-silica and high-silica adakites, help constrain reconstructions of the UDMA geodynamic evolution. Late Oligocene–Early Miocene slab roll-back associated with an asthenospheric mantle influx are suggested as the major processes responsible for concurrent volcanism showing Nb–Ta-depleted, Nb–Ta-enriched and low-silica adakite signatures. Slab roll-back, the likely consequence of a decrease in subduction velocity, led to partial melting of the subducted slab and produced Early–Middle Miocene high-silica (dacitic) adakites. Oligocene to Miocene volcanic rocks do not conform to the Oligocene continental collisional model for the UDMA, rather they suggest a decrease in the subduction rate that prompted the asthenospheric mantle influx.     

Lead isotope signatures of epithermal and porphyry-type ore deposits from the Romanian Carpathian Mountains

Lead isotope analyses have been performed on the two major Miocene mining districts of Romania, Baia Mare and Apuseni Mountains. These two districts have different non-overlapping ²⁰⁶Pb/²⁰⁴Pb isotopic signatures ranging from 18.752 to 18.876 and 18.497 to 18.740. In the Baia Mare district, epithermal deposits are overall homogeneous in their lead isotopic compositions and have values similar to the average of the calc-alkaline volcanic rocks. These results suggest a magmatic signature for the Pb (and possibly other metals) in the hydrothermal fluids. However, magmas in this district show isotopic evidence of crustal assimilation. In the southern Apuseni Mountains, the lead isotope compositions of sulfide minerals in porphyry copper deposits are clustered, confirming that Pb, and probably other metals, were derived principally from associated porphyry stocks. On the other hand, lead isotope data on sulfides in epithermal ore deposits are much more scattered, indicating a notable contribution of Pb from local country rocks. In the Apuseni Mountains, 'fertile' volcanics are few and appear to come from a more primitive mantle-derived source. Most of the analysed volcanic rocks seem 'barren'. Differences in lead isotopic compositions between the Baia Mare district and the Apuseni Mountains are due to a different basement, and probably to variations in crustal assimilation superimposed on variations in the mantle source composition. In the Apuseni Mountains, Pb may be partly inherited from the previous Mesozoic magmatic-hydrothermal stage. From a geodynamic point of view, it seems that the nature and the source of volcanic rocks and their position related to the collision area of the Carpathian arc are not the only factors controlling the 'fertility' of a volcanic district.     

湘南中生代花岗质岩石成岩成矿的时限

位于南岭中段的湘南地区,中生代花岗质岩石广泛分布;该区W、Sn、Pb、Zn、Mo、Bi等金属矿床密集产出,很多钨、锡矿床达到大型、超大型规模,且找矿潜力巨大,构成一个世界级的有色金属矿集区。最近大量的同位素年代学研究表明,南岭中段钨、锡、铅锌等金属的成矿是一个爆发性、区域性的地质事件,成矿时间高度集中,成矿时限主要在150~160 Ma之间,与该区主要花岗岩的成岩时间相当吻合;对单个钨、锡矿床而言,其矿区的成岩、成矿存在着一种准同期性,即成矿与矿区花岗岩的成岩基本上是同时的、或稍晚于花岗岩的成岩作用。因此,该区中生代的花岗岩与钨锡成矿作用具有明显的时、空联系。南岭中段花岗岩大规模的侵入和钨、锡等金属的爆发性成矿均形成于一种岩石圈伸展减薄、地壳拉张的构造环境,可能与华南中生代第二幕岩石圈伸展事件密切相关。     

Terrane assembly and geodynamic evolution of central–western Hoggar: a synthesis

After a review of the rock sequences and evolution of the eastern and central terranes of Hoggar, this paper focusses on the Neoproterozoic subduction-related evolution and collision stages in the central–western part of the Tuareg shield. Rock sequences are described and compared with their counterparts identified in the western and the eastern terranes exposed in Hoggar and northern Mali. The Pharusian terrane that is described in detail, is floored in the east by the Iskel basement, a Mesoproterozoic arc-type terrane cratonized around 840 Ma and in the southeast by Late Paleoproterozoic rock sequences (1.85–1.75 Ga) similar to those from northwestern Hoggar. Unconformable Late Neoproterozoic volcanosedimentary formations that mainly encompass volcanic greywackes were deposited in troughs adjacent to subduction-related andesitic volcanic ridges during the c. 690–650 Ma period. Abundant arc-related pre-collisional calc-alkaline batholiths (650–635 Ma) intruded the volcanic and volcaniclastic units at rather shallow crustal levels prior to collisional processes. The main E–W shortening in the Pharusian arc-type crust occurred through several stages of transpression and produced overall greenschist facies regional metamorphism and upright folding, thus precluding significant crustal thickening. It was accompanied by the shallow emplacement of calc-alkaline batholiths and plutons. Ages of syn-collisional granitoids range from 620 Ma in the western terranes, to 580 Ma in the Pharusian terrane, thus indicating a severe diachronism. After infill of molassic basins unconformable above the Pan-African greenschists, renewed dextral transpression took place in longitudinal domains such as the Adrar fault. The lithology, volcanic and plutonic suites, deep greenschist facies metamorphism, structures and kinematics from the Adrar fault molassic belt previously considered as Neoproterozoic are described in detail. The younger late-kinematic plutons emplaced in the Pharusian terrane at 523 Ma [Lithos 45 (1998) 245] relate to a Cambrian tectonic pulse that post-dates molasse deposition. The new geodynamic scenario presented considers several paleosubductions. The major east-dipping subduction, corresponding to the closure of a large Pan-African oceanic domain in the west (680–620 Ma) post-dates an older west-dipping “Pharusian” subduction (690–650 Ma?) to the east of the eastern Pharusian terrane. Such a diachronism is suggested by the 690 Ma old eclogites of the western part of the LATEA terrane of central Hoggar [J. African Earth Sci. this volume (2003)] that are nearly synchronous with the building up of the Pharusian terrane, thus suggesting that the 4°50^′ lithospheric fault represents a reactivated cryptic suture.     

Temperature and density of the Tyrrhenian lithosphere and slab and new interpretation of gravity field in the Tyrrhenian Basin

The gravity anomaly field of the Tyrrhenian basin and surrounding regions reflects the complex series of geodynamic events active in this area since the Oligocene–Miocene. They can resume in lithospheric thinning and asthenospheric rising beneath the Tyrrhenian Basin, coexisting with the roll-back subduction of the African plate margin westward sinking beneath the Calabrian Arc. The geographic closeness between these processes implies an intense perturbation of the mantle thermal regime and an interference at regional scale between the related gravity effects.A model of the litho-asthenospheric structure of this region is suggested, showing a reasonable agreement with both the evidences in terms of regional gravity anomaly pattern and the results concerning thermal state and petro-physical features of the mantle. The first phase of this study consisted of the computation of the isotherms in the crust–mantle system beneath the Tyrrhenian Basin and, afterwards, of the density distribution within the partially melted upwelling asthenosphere. The second phase consisted of a temperature/density modelling of the slab subducting beneath the Calabrian Arc. Finally, a 2^1 / 2 interpretation of gravity data was carried out by including as constraints the results previously obtained. Thus, the final result depicts a model matching both gravity, thermal and petrographic data. They provide (a) a better definition of the thermal regime of the passive mantle rise beneath the Tyrrhenian basin by means of the estimation of the moderate asthenospheric heating and (b) a model of lithospheric slab subducting with rates that could be smaller than generally suggested in previous works.     

A review of the geodynamic setting of large-scale Late Mesozoic gold mineralization in the North China Craton: an association with lithospheric thinning

Abundant gold deposits are distributed along the margins of the North China Craton (NCC). Occurring throughout the Precambrian basement and located in or proximal to Mesozoic granitoids, these deposits show a consistent spatial–temporal association with Late Jurassic–Early Cretaceous magmatism and are characterized by quartz lode or disseminated styles of mineralization with extensive alteration of wall rock. Their ages are mainly Early Cretaceous (130–110 Ma) and constrain a very short period of metallogenesis. Sr–Nd–Pb isotopic tracers of ores, minerals and associated rocks indicate that gold and associated metals mainly were derived from multi-sources, i.e., the wall rocks (Precambrian basement and Mesozoic granites) and associated mafic rocks.Previous studies, including high surface heat flow, uplift and later basin development, slow seismic wave speeds in the upper mantle, and a change in the character of mantle xenoliths sampled by Paleozoic to Cenozoic magmas, have been used to suggest that ancient, cratonic mantle lithosphere was removed from the base of the NCC some time after the Ordovician, and replaced by younger, less refractory lithospheric mantle. The geochemistry and isotopic compositions of the mafic rocks associated with gold mineralization (130–110 Ma) indicate that they were derived from an ancient enriched lithospheric mantle source; whereas, the mafic dikes and volcanic rocks younger than 110 Ma were derived from a relatively depleted mantle source, i.e., asthenospheric mantle. According to their age and sources, relation to magmatism and geodynamic framework, the gold deposits were formed during lithospheric thinning. The removal of lithospheric mantle and the upwelling of new asthenospheric mantle induced partial melting and dehydration of the lithospheric mantle and lower crust due to an increase of temperature. The fluids derived from the lower crust were mixed with magmatic and meteoric waters, and resulted in the deposition of gold and associated metals.     

New lead isotope determination from five Proterozoic sulfide deposits,Skellefte district,Sweden

Lead isotope analyses of 25 sulfide samples (galenas, iron sulfides, and sulfosalts) from five different mines of the Skellefte district, northern Sweden, demonstrate that the Pb-isotopic composition of galenas and other sulfides rich in lead varies between individual deposits within the district. This contrasts with many other base-metal districts, where ore lead is isotopically homogeneous on a regional basis. Although all of the Skellefte leads are depleted in ²⁰⁷Pb relative to average global lead evolution models, thus suggesting a large mantle-derived component in their sources, the Nasliden deposit lying at the contact of the host volcanic rocks and the overlying metasediments contains a significant component of crustal lead. It is concluded that while the Pb-isotope data are consistent with a volcanic exhalative origin of the ores of the Skellefte district, they also demonstrate that older crustal lead was incorporated into the sulfides during their emplacement and the subsequent period of magmatic and metamorphic activity which followed their deposition.     

安徽铜陵矿集区石英闪长岩—花岗闪长岩成因的Sr-Nd-Hf-O同位素制约

安徽铜陵矿集区是我国长江中下游构造—岩浆—成矿带中一个重要的铜金多金属成矿区,区内广泛发育晚中生代以石英闪长岩和花岗闪长岩为主的中酸性闪长质侵入岩体,且其与成矿关系密切。关于铜陵矿集区侵入岩的成因,前人已有大量研究成果发表,但仍存有一定争议。本文在广泛收集前人研究资料和成果的基础上,选择区内铜官山石英闪长岩体和新屋里、胡村花岗闪长岩体开展全岩Sr-Nd同位素和锆石原位Hf-O同位素分析,以进一步探讨其成因机制。研究表明,石英闪长岩和花岗闪长岩的结构构造和矿物组成特征相似,全岩主量元素、微量元素和稀土元素组成特征也基本一致,均属高钾钙碱性岩石系列,并具有埃达克质岩石特征。石英闪长岩I_Sr值为0.707 2～0.709 0,ε_Nd（t）值为-13.0～-8.3,锆石ε_Hf（t）值为-23.5～-8.7,δ¹⁸O值为6.5‰～7.4‰;花岗闪长岩ISr值0.707 7～0.709 8,ε_Nd（t）值为-13.6～-8.5,锆石ε_Hf（t）值为-19.0～-7.4,δ¹⁸O值为6.7‰～8.1‰。石英闪长岩和花岗闪长岩Sr-Nd同位素组成特征和锆石Hf-O同位素组成特征亦基本一致,指示它们具有相同的成岩物质来源。结合区域地质背景和构造演化,本文认为,铜陵矿集区石英闪长岩和花岗闪长岩为富集岩石圈地幔岩浆与壳源埃达克质岩浆混合并上升侵位所形成,富集岩石圈地幔岩浆并非起源于古太平洋俯冲洋壳或俯冲洋壳析出流体交代的富集岩石圈地幔,而是新元古代华夏洋俯冲析出流体交代扬子板块岩石圈地幔所形成,壳源埃达克质岩浆为新元古代华夏板块与扬子板块碰撞之后形成的新生地壳熔融而成。铜陵矿集区晚中生代大规模岩浆作用的诱因是大陆板内构造背景下富集岩石圈地幔部分熔融岩浆上涌加热以及受古太平洋板块挤压和地壳加厚再转向拉张应力下的减压熔融。     

华北地台北缘火山岩型铀钼矿床找矿模型研究

460铀钼矿床具有很好的火山岩型铀钼矿找矿前景。460铀钼矿早期为斑岩型矿化,晚期叠加火山热液型矿化,成矿时代为晚白垩世及新近纪。铀源层(体)为张家口组三段酸性火山岩及次流纹斑岩,由壳源重熔岩浆作用形成。以460矿床区域地质背景、成矿环境、矿床地质特征及找矿标志研究为重点,总结归纳了火山岩型铀钼找矿方法,建立了华北地台北缘火山岩型铀钼矿床的找矿模型。     

9: Processes of tectonism, magmatism and mineralization: Lessons from Europe

Metallogenic provinces in Europe range in age from the Archaean to the Neogene. Deposit types include porphyry copper and epithermal Cu–Au, volcanic-hosted massive sulphide (VMS), orogenic gold, Fe-oxide–Cu–Au, anorthosite Fe–Ti-oxide and sediment-hosted base-metal deposits. Most of them formed during short-lived magmatic events in a wide range of tectonic settings; many can be related to specific tectonic processes such as subduction, hinge retreat, accretion of island arcs, continental collision, lithosphere delamination or slab tear. In contrast, most sediment-hosted deposits in Europe evolved in extensional, continental settings over significant periods of time. In Europe, as elsewhere, ore formation is an integral part of the geodynamic evolution of the Earth's crust and mantle. Many tectonic settings create conditions conducive to the generation of water-rich magma, but the generation of ore deposits appears to be restricted to locations and short periods of change in temperature and stress, imposed by transitory plate motions. Crustal influence is evident in the strong structural controls on the location and morphology of many ore deposits in Europe. Crustal-scale fault–fracture systems, many involving strike-slip elements, have provided the fabric for major plumbing systems. Rapid uplift, as in metamorphic core complexes, and hydraulic fracturing can generate or focus magmatic–hydrothermal fluid flow that may be active for time spans significantly less than a million years. Once a hydrologically stable flow is established, ore formation is strongly dependent on the steep temperature and pressure gradients experienced by the fluid, particularly within the upper crust. In Europe, significant fracture porosity deep in the crystalline basement (1%) is not only important for magmatic–hydrothermal systems, but allows brines to circulate down through sedimentary basins and then episodically upward, expelled seismically to produce sediment-hosted base-metal deposits and Kupferschiefer copper deposits. Emerging research, stimulated by GEODE, can improve the predicting power of numerical simulations of ore-forming processes and help discover the presence of orebodies beneath barren overburden.     

Permian volcanism in the Central Western Carpathians (Slovakia): Basin-and-Range type rifting in the southern Laurussian margin

The 1,500- to 2,000-m-thick Permian volcano-sedimentary Malu?iná Formation of the uppermost nappe of the Central Western Carpathians (a segment of the Alpine-Carpathian orogenic belt) occurs in several fault blocks distributed across Slovakia. This unit is a part of a post-Variscan overstep suite that followed accretion of the Gothic terranes to Laurussia. It consists of three upward-fining megacycles of semi-arid/arid, fluvial-lacustrine clastic redbeds and local dolomites and evaporites. Abundant intercalated volcanic rocks are predominantly mafic lava flows; volcaniclastic rocks and dykes are subordinate. Felsic rocks are represented by rare volcaniclastics and dykes. Compositionally, the mafic rocks are rift-related continental tholeiites with enriched light REE patterns having (La/Yb)_n ratios between 2 and 5.5 and with mantle-normalized patterns characterized by negative Nb-Ta anomalies. The rocks were derived from subcontinental lithospheric mantle and were affected by crustal contamination. It is inferred that the volcanism of the Malu?iná Formation formed in a Basin and Range tectonic setting in which rifting followed collision of the Palaeo-Tethys ridge with the trench bordering southern Laurussia. This model can be applied to other Permian volcanic suites of rift basins in the Eastern Alps and Carpathians over a strike-length of about 1,000 km, which indicates the width of the slab window.     

Cenozoic Island Arc Magmatism in Java Island (Sunda Arc, Indonesia): Clues on Relationships between Geodynamics of Volcanic Centers and Ore Mineralization

Abstract. Java island, regarded as a classic example of island arcs, is built through multi events of Cenozoic arc magmatism produced by the subduction of Indian‐Australian oceanic crusts along the southern margin of Eurasian plate. Regional crustal compositions, subducted slabs, and tectonics determined the spatial‐geochemical evolution of arc magmatism and regional metallogeny. Tertiary geodynamics of island arc was dominated by backarc‐ward migrations of volcanic centers. Only after the Miocene‐Pliocene roll‐back effects of retreating slab, slab detachment, and backarc magmatism took place in central Java. The source of arc magmas is mainly partial melting of mantle wedge, triggered by fluids released from dehydrated slabs. Increasing potassium contents of arc magmas towards the backarc‐side and younger magmas is typical for all magmas, while alkali and incompatible trace elements ratios are characteristics for different settings of volcanic centers. The oceanic nature of crust and the likely presence of hot slab subducted beneath the eastern Java determine the occurrences of adakitic magmas. Backarc magmatism has a deeper mantle source with or without contributions from subduction‐related materials. The domination of magnetite‐series magmatism determines the sulfide mineralization for the whole island. District geology, geodynamics, and magma compositions in turn control particular styles and scales of precious metals concentrations. Deep‐seated crustal faults have focused the locations of overlapping volcanic centers and metalliferous fluids into few major gold districts. Porphyry deposits are mostly concentrated within Lower Tertiary (early stage) volcanic centers in eastern Java which are not covered by younger volcanic centers, and whose sulfides are derived from partial melting of basaltic parental materials. On the other hand, high‐grade low‐sulfidation epithermal gold deposits formed in later stages of arc development and are spatially located within younger volcanic centers (Upper Miocene‐Pliocene) that overlap the older ones. Gold in low‐sulfidation epithermal system is likely to be derived from crustal materials. The overall interacting factors resulting in the petrochemical systematics that are applicable for exploration: 1) early‐stage volcanic centers with high Sr/Y and Na₂O/K₂O ratios are more prospective for porphyry mineralization, while 2) later‐stage volcanic centers with high K₂O, total alkali, and K₂O/Na₂O ratios are more prospective for low‐sulfidation epithermal mineralization.     

Depleted arc volcanism in the Alboran Sea and shoshonitic volcanism in Morocco: geochemical and isotopic constraints on Neogene tectonic processes

Samples of volcanic rocks from Alborán Island, the Alboran Sea floor and from the Gourougou volcanic centre in northern Morocco have been analyzed for major and trace elements and Sr–Nd isotopes to test current theories on the tectonic geodynamic evolution of the Alboran Sea. The Alborán Island samples are low-K tholeiitic basaltic andesites whose depleted contents of HFS elements (0.5×N-MORB), especially Nb (0.2×N-MORB), show marked geochemical parallels with volcanics from immature intra-oceanic arcs and back-arc basins. Several of the submarine samples have similar compositions, one showing low-Ca boninite affinity. ¹⁴³Nd/¹⁴⁴Nd ratios fall in the same range as many island-arc and back-arc basin samples, whereas ⁸⁷Sr/⁸⁶Sr ratios (on leached samples) are somewhat more radiogenic. Our data point to active subduction taking place beneath the Alboran region in Miocene times, and imply the presence of an associated back-arc spreading centre. Our sea floor suite includes a few more evolved dacite and rhyolite samples with (⁸⁷Sr/⁸⁶Sr)₀ up to 0.717 that probably represent varying degrees of crustal melting. The shoshonite and high-K basaltic andesite lavas from Gourougou have comparable normalized incompatible-element enrichment diagrams and Ce/Y ratios to shoshonitic volcanics from oceanic island arcs, though they have less pronounced Nb deficits. They are much less LIL- and LREE-enriched than continental arc analogues and post-collisional shoshonites from Tibet. The magmas probably originated by melting in subcontinental lithospheric mantle that had experienced negligible subduction input. Sr–Nd isotope compositions point to significant crustal contamination which appears to account for the small Nb anomalies.

The unmistakable supra-subduction zone (SSZ) signature shown by our Alboran basalts and basaltic andesite samples refutes geodynamic models that attribute all Neogene volcanism in the Alboran domain to decompression melting of upwelling asthenosphere arising from convective thinning of over-thickened lithosphere. Our data support recent models in which subsidence is caused by westward rollback of an eastward-dipping subduction zone beneath the westernmost Mediterranean. Moreover, severance of the lithosphere at the edges of the rolling-back slab provides opportunities for locally melting lithospheric mantle, providing a possible explanation for the shoshonitic volcanism seen in northern Morocco and more sporadically in SE Spain.     

豫西矿集区成矿系统初步研究

豫西矿集区以矿产种类多,规模大,分布密集为主要特征;可分为斑岩热液成矿系统、脉状钼矿成矿系统、火山热液成矿系统、浅成热液成矿系统、叠加改造成矿系统和陆相砂岩成矿系统六种。成矿系统时间结构显示,矿集区内存在元古代、印支、燕山期成矿作用,后期的成矿作用叠加到前期的成矿作用之上,形成叠加改造型矿床;成矿空间结构体现出受地幔亚热柱构造、地球化学块体和热点严格控制,各成矿系统的物质结构复杂,彼此显示出相似性、同源性,矿石矿物种类多,共(伴)生元素多样。豫西矿集区是在豫西地壳剧烈的、多期次的演化过程中形成的,成矿系统的时空结构与区域地壳演化历史十分吻合,其成矿机制上具有内在的密切联系。