塞尔维亚Mali Krivelj斑岩型铜矿床热液蚀变作用及元素迁移规律

位于特提斯成矿域西段塞尔维亚Bor成矿带内的Mali Krivelj铜矿床是一大型斑岩型矿床。为揭示该矿床热液蚀变作用过程及元素迁移规律,文章对新鲜安山岩及不同蚀变带典型样品进行了微量元素分析及元素迁移质量平衡计算。研究结果表明,绢英岩化带及绿泥石-绢云母化带显示类似元素迁移规律,REE、Sr、Ba、Zr、Th、U、Ti、Co、Ni等元素显示一定程度迁出,而Rb、Cs等元素显示一定程度迁入,绿泥石-绢云母化带发育大量磁铁矿,而绢英岩化带则大量出现石英+绢云母+黄铁矿组合,这表明随着流体的持续演化,流体的还原性逐渐增强。青磐岩化带蚀变较弱,其元素迁移程度较低。研究区Cu与Cr、Rb、Ti/Sr、Rb/Ba、Cr/Zn比值等具较好的正相关性,Cu与REE、Ba、Zn、Mn、Sr等元素具有一定的负相关性,表明该矿床全岩元素迁移规律在一定程度上也能作为地球化学勘查指标为寻找斑岩矿化中心提供依据。     

Geochemistry of Trace Elements during Ore-Forming Processes in Yinshan Deposit

ＩＮＴＲＯＤＵＣＴＩＯＮＴｈｅＹｉｎｓｈａｎｄｅｐｏｓｉｔｉｎｔｈｅｎｏｒｔｈｅａｓｔｅｒｎＪｉａｎｇｘｉＰｒｏｖｉｎｃｅｏｆＣｈｉｎａｉｓａｌａｒｇｅ ｓｕｐｅｒｌａｒｇｅｐｏｌｙｍｅｔａｌｌｉｃＣｕ Ｚｎ Ｐｂ Ａｇ Ａｕｄｅ ｐｏｓｉｔ.Ｔｈｏｕｇｈｔｈｅｒｅａｒｅｍａｎｙｄｉｆｆｅｒｅｎｔａｒｇｕｍｅｎｔｓａｂｏｕｔｔｈｅｇｅｎｅｓｅｓｏｆｔｈｅｄｅｐｏｓｉｔ(Ｈａｏ ,1998;Ｚｈａｎｇ ,1997;ＪｉａｎｇｘｉＧｅｏ ｌｏｇｉｃＥｘｐｌｏｒａｔｉｏｎＢｕｒｅａｕ ,1996 ;Ｚｈａｎｇ ,1996 ;Ｈｕａ ,1987;Ｙ…     

塔里木地台南缘发现钾镁煌斑岩

首次在塔里木地台南缘皮山县境内找到钾镁煌斑岩,它们呈脉状产出,围岩为白云母石英片岩。该钾镁煌斑岩的岩石化学成分与亚洲钾镁煌斑岩的平均岩石化学成分接近,与澳大利亚西金伯利地区钾镁煌斑岩一致,稀土元素及其配分模式位于世界钾镁煌斑岩的范围之内,其中大多数标本具有已知世界钾镁煌斑岩的共同微量元素特征：具Ｂａ、Ｋ、Ｌａ和Ｃｅ的正异常及Ｔａ、Ｎｂ、Ｓｒ和Ｔｉ的负异常。该钾镁煌斑岩的发现对研究区金刚石找矿和深部地质过程研究均具深远意义。     

Mineral chemistry of a zircon-bearing, composite, veined and metasomatised upper-mantle peridotite xenolith from kimberlite

Zircon-bearing veins in a harzburgite xenolith from kimberlite have imposed Ca-metasomatism on the harzburgite wall rock, in addition to adding K, Fe, Ti and OH. The zircon, previously dated to have an age similar to that of the xenolith-hosting kimberlite, shows higher Y, Nb, Ba, REE, Th and U contents than other mantle-derived zircons. Peripheral alteration of the zircon to baddeleyite and zirconolite, and alteration of vein ilmenite to perovskite suggest reaction with an evolving carbonatitic kimberlite melt. The high Cr₂O₃ content (0.77 wt%) of the zirconolite extends the compositional range of terrestrial zirconolite.     

New geological and geochemical data on the granitoids of the Uspensky massif in Southern Primorye

New geological, petrochemical, mineralogical, and geochemical data are presented on the Uspensky granitoid massif in Southern Primorye. The massif consists of the rocks of two associations: (1) the early association (103.3 ± 2.4 Ma) consisting of garnet-bearing biotite and two-mica granite-leucogranites and (2) the late association (99 ± 2 Ma) represented by biotite (±amphibole) granodiorites, melanogranites, and granites. The granitoids of both associations have moderate potassic alkalinity and elevated alumina contents but differ in the proportions of alumina, calcium, and alkalis. The garnet-bearing granite-leucogranites are characterized by the highest Rb, Th, and U contents and the lowest Sr, Ba, Hf, and Zr contents. The REE distribution patterns have a quasi-symmetric shape and deep Eu minimums. The melanogranites show higher Sr and Ba contents and, as granites, are characterized by asymmetric REE spectrums with an insignificant negative Eu anomaly. The porphyraceous granodiorites and granites are peculiar in their lowered Sr and Ba contents, while the granodiorites have lowered contents of K, REE, Zr, Hf, Th, and U; elevated Nb contents; and a distinctive Eu minimum.     

New data on carbonatites of the Il’mensky-Vishnevogorsky alkaline complex,the southern Urals,Russia

Carbonatites that are hosted in metamorphosed ultramafic massifs in the roof of miaskite intrusions of the Il’mensky-Vishnevogorsky alkaline complex are considered. Carbonatites have been revealed in the Buldym, Khaldikha, Spirikha, and Kagan massifs. The geological setting, structure of carbonatite bodies, distribution of accessory rare-metal mineralization, typomorphism of rock-forming minerals, geochemistry, and Sr and Nd isotopic compositions are discussed. Dolomite-calcite carbonatites hosted in ultramafic rocks contain tetraferriphlogopite, richterite, accessory zircon, apatite, magnetite, ilmenite, pyrrhotite, pyrite, and pyrochlore. According to geothermometric data and the composition of rock-forming minerals, the dolomite-calcite carbonatites were formed under K-feldspar-calcite, albite-calcite, and amphibole-dolomite-calcite facies conditions at 575–300°C. The Buldym pyrochlore deposit is related to carbonatites of these facies. In addition, dolomite carbonatites with accessory Nb and REE mineralization (monazite, aeschynite, allanite, REE-pyrochlore, and columbite) are hosted in ultramafic massifs. The dolomite carbonatites were formed under chlorite-sericite-ankerite facies conditions at 300–200°C. The Spirikha REE deposit is related to dolomite carbonatite and alkaline metasomatic rocks. It has been established that carbonatites hosted in ultramafic rocks are characterized by high Sr, Ba, and LREE contents and variable Nb, Zr, Ti, V, and Th contents similar to the geochemical attributes of calcio-and magnesiocarbonatites. The low initial ⁸⁷Sr/⁸⁶Sr = 0.7044?0.7045 and εNd ranging from 0.65 to ?3.3 testify to their derivation from a deep mantle source of EM₁ type.     

赣南白面石铀矿区花岗岩的锆石年代学、地球化学及成因研究

赣南白面石铀矿区花岗岩的锆石年代学、 地球化学及成因研究     

Isotopic-geochemical study of zircons from metabasites of the Kontokki dike complex: Age of regional metamorphism in the Kostomuksha structure

Results of local isotopic-geochemical and chemical examination of zircons from metabasites of the Kontokki dike complex in the Kostomuksha structure, western Karelia, Russia, make it possible to interpret the concordant U-Pb zircon age of 2674 ± 13 Ma as the boundary between regional amphibolite-facies metamorphism and accompanying metasomatism. Zircons from the metabasites arte heterogeneous and consist of central parts with relict magmatic cores, metamorphic intermediate zones (which are pale in CL), and younger metasomatically altered zones (dark in BSE images), which development along boundaries between zones and lengthwise arrays of cracks permeable to fluids. The dark altered zones are characterized by high (for zircons) concentrations of LREE, MREE, Th, U, Ca, Sr, Ba, Fe, and Al. The REE distribution in the zircons was proved to be much less susceptible to overprinted metasomatic processes than the U-Pb system of the same zircons. Characteristics of the REE distribution in the zircons makes these zircons comparable with metasomatic zircons. Genetically, the metasomatic processes that affected the geochemistry of the zircons could be related to synmetamorphic granitoid intrusions (Bibikova et al., 2005).     

江苏省海州式磷矿岩石地球化学特征及成矿背景

本文对苏北地区锦屏组磷矿石及地层样品进行了岩相学及地球化学分析,研究了磷矿初始沉积环境和源区特征。磷矿类微量元素富集Ba、Pb、U、Sr,贫Th、Ta、Nb、Ti;REE配分曲线为LREE富集型,Ce负异常,表明成矿环境为陆缘海,且成矿过程受深海热水沉积和生物作用影响。Sr、Nd同位素初始值判断磷灰岩物质来源为年轻的地壳物质。绿片岩类微量元素富集Rb、Th、K,贫Th、U、Ta、Nb、Sr、Ti;REE配分曲线为LREE富集型,判断其原岩为陆源碎屑岩。（混合）片麻岩类微量元素富集Pb、Th、K,亏损Ba、Ta、Nb、Sr、Ti;REE配分曲线为LREE富集型,具地幔源区特征。     

Mineralogy and petrology of cretaceous subsurface lamproite sills, southeastern Kansas, USA

Cores and cuttings of lamproite sills and host sedimentary country rocks in southeastern Kansas from up to 312 m depth were analyzed for major elements in whole rocks and minerals, certain trace elements in whole rocks (including the REE) and Sr isotopic composition of the whole rocks. The lamproites are ultrapotassic (K₂O/Na₂O = 2.0–19.9), alkalic [molecular (K₂O/Na₂O)/Al₂O₃ = 1.3-2.8], enriched in mantle-incompatible elements (light REE, Ba, Rb, Sr, Th, Hf, Ta) and have nearly homogeneous initial Sr isotopic compositions (0.707764-0.708114).

These lamproites could have formed by variable degrees of partial melting of harzburgite country rock and cross-cutting veins composed of phlogopite, K-Ti richterite, titanite, diopside, K-Ti silicates, or K-Ba-phosphate under high H₂O/CO₂ ratios and reducing conditions. Variability in melting of veins and wall rock and variable composition of the metasomatized veins could explain the significantly different composition of the Kansas lamproites.

Least squares fractionation models preclude the derivation of the Kansas lamproites by fractional crystallization from magmas similar in composition to higher silica phlogopite-sanidine lamproites some believe to be primary lamproite melts found elsewhere. In all but one case, least squares fractionation models also preclude the derivation of magmas similar in composition to any of the Kansas lamproites from one another. A magma similar in composition to the average composition of the higher SiO₂ Ecco Ranch lamproite (237.5–247.5 m depth) could, however, have marginally crystallized about 12% richterite, 12% sanidine, 7% diopside and 6% phlogopite to produce the average composition of the Guess lamproite (305–312 m depth).

Lamproite from the Ecco Ranch core is internally fractionated in K₂O, Al₂O₃, Ba, MgO, Fe₂O₃, Co and Cr most likely by crystal accumulation-removal of ferromagnesian minerals and sanidine. In contrast, the Guess core (305–312 m depth) has little fractionation throughout most of the sill except in several narrow zones. Lamproite in the Guess core has large enrichments in TiO₂, Ba, REE, Th, Ta and Sc and depletions in MgO, Cr, Co and Rb possibly concentrated in these narrow zones during the last dregs of crystallization of this magma.

The Ecco Ranch sill did not show any evidence of loss of volatiles or soluble elements into the country rock. This contrasts to the previously studied, shallow Silver City lamproite which did apparently lose H₂O-rich fluid to the country rock. Perhaps a greater confining pressure and lesser amount of H₂O-rich fluid prevented it from escaping.     

Kimberlitic zircons — A possible aid in prospecting for kimberlites

Kimberlitic zircons from 16 intrusions in Lesotho, the Republic of South Africa, and Tanzania have been investigated. The following characteristics distinguish the kimberlitic zircons from the zircons derived from most other sources: 1. Rounded to subrounded grains predominate; euhedral zircons are very rare. 2. Perfect parting in several directions, mainly (100) and (111). 3. Lattice distortions occur (decreasing molar volume). 4. High abundancy of fluid inclusions, occupying healed fractures. 5. Uranium contents less than 30 ppm U. Low contents of Th, Y, P, REE. 6. Whitish alteration rims composed of monoclinic and tetragonal zirconia in varying proportions are common. — The use of zircons in order to identify and trace kimberlite intrusives is discussed, as there may be a possible connection between some properties of the kimberlitic zircons and the diamond grade of their host rocks.     

辽西医巫闾山地区晚侏罗世花岗岩脉中热液锆石的成因与定年

辽西医巫闾山变质核杂岩经历过两阶段演化,晚侏罗世发育了围绕核部医巫闾山岩体周缘展布的长环形韧性剪切带(称为医巫闾山剪切带),早白垩世西侧叠加了北北东走向瓦子峪伸展韧性剪切带.在医巫间山剪切带及其变形下盘中侵入了大量的晚侏罗世花岗岩脉,其所含的锆石包括古老继承锆石、新生岩浆锆石、热液锆石等多种类型.根据锆石阴极发光图像、...     

Zircon from the polymigmatites of the northwestern Ladoga region: Morphology and geochemistry

This paper reports the results of a geochemical investigation of zircon from a migmatized aluminous gneiss (gn), melanosome (M), and sequential leucosome generations (Lc₂, Lc₃, Lc₄, and Lc₅) from an outcrop in the northwestern Ladoga region. The contents of REE, Y, Ti, Hf, Th, U, and P were determined using a Cameca IMS-4f ion microprobe in 12 zircon grains from the aforementioned rocks, in two-three spots in each grain. All of the specimens show rather uniform REE distribution patterns. More significant variations were observed in the light and medium REE (at smaller variations in the heavy REE), as well as in Ti, Y, Th, and U contents between zircons from the host rocks and from the leucosomes. It was supposed that REE-rich zircons from the gneiss and melanosome (without oscillatory zoning) are relics, whereas rhythmically zoned zircons with lower REE contents crystallized in the gneiss in the presence of dispersed anatectic melt. The contents of most REE and Y increase from core to rim in zircons from the gneiss, melanosome, Lc₂, Lc₄, and Lc₅, which is opposite to the compositional trend of zircons from Lc₃. It was shown that the decrease of HREE and Y content in zircon in the sequence Lc₅ → gn → Lc₂, Lc₃, Lc₄ is related to a decrease in the abundance of these elements in the rocks. The leucosomes do not correspond to a differentiation series of a single melt (there is no variation trends of Rb/Sr, K/Rb, and Rb/Ba in the rock series). The lower Lu/Hf and Sm/Nd values in the leucosomes relative to the host rocks allowed us to suppose that their protolith was gneisses (for Lc₂) and migmatites (for Lc₄ and Lc₃). The similarity of the early migmatites and gneisses to Lc₃ with respect to major and some trace elements and almost identical Lu/Hf and Sm/Nd values support the possibility of the formation of this leucosome generation during the beginning of the diatexis of migmatites, which was promoted by a temperature increase. This resulted in a specific trend in the content of some elements during zircon growth in Lc₃, which is different from the trend of zircons from other leucosomes.     

浙西北萧山—诸暨地区晚中生代侵入岩地球化学特征及构造意义

浙西北萧山—诸暨地区晚侏罗世末期花岗(石英)闪长岩与早白垩世末期(辉石)闪长岩具有以下地球化学特征:低硅、贫碱、富钙镁铁,弱负铕异常,稀土配分曲线右倾,富集K,Rb,Ba,Th,U等,亏损Nb,Ta等,Sr,Ti亏损不明显。晚侏罗世末期花岗岩与早白垩世末期花岗(斑)岩均具有高硅、富碱、贫钙镁,强负铕异常的特征;晚侏罗世侵入岩具"V"型稀土配分曲线,强富集K,Rb,Th,U等,相对富集Nb,Ta,强亏损Ba,Sr,Ti等特征;早白垩世侵入岩具右倾稀土配分曲线,富集K,Rb,Th,U等,亏损Nb,Ta,Sr,Ti,Ba不亏损等特征。岩石构造地球化学图解分析表明,晚侏罗世末期I-A型花岗岩类成岩构造环境具有从俯冲挤压碰撞作用向后碰撞或后造山作用演化的特征;早白垩世末期(高分异)I型花岗岩类岩石主要与火山-次火山喷发-侵入作用关系密切,成岩构造环境主要与区域伸展作用有关。     

Geochemical Records of Mantle Processes in Mantle Xenoliths from Three Cenozoic Basaltic Volcanoes in Eastern China

Rare earth element (REE) contents, and Sr and Nd isotopic compositions were measured for three suites of mantle xenoliths from the Kuandian, Hannuoba and Huinan volcanoes in the north of the Sino-Korean Platform. From the correlations of Yb contents with Al/Si and Ca/Si ratios, the peridotites are considered to be the residues of partial melting of the primitive mantle. The chondrite-normalized REE compositions are diverse, varying from strongly LREE-depleted to LREE-enriched, with various types of REE patterns. Metasomatic alteration by small-volume silicate melts, of mantle peridotites previously variably depleted due to fractional melting in the spinel peridotite field, can account for the diversity of REE patterns. The Sr/ Ba versus La/Ba correlation indicates that the metasomatic agent was enriched in Ba over Sr and La, suggestive of its volatile-rich signature and an origin by fluid-triggered melting in an ancient subduction zone. The Sr and Nd isotopic compositions of these xenoliths, even from     

Geochemical features of zircons from migmatites of the Nimnyr block,Aldan shield

This paper reports the results of chemical and structural study (electron microscopy and ion microprobe) of zircons from different-age generations of migmatite leucosomes in the basement rocks and Kurumkan Formation within the Nimnyr block, Aldan shield. The studied zircons show REE distribution pattern with a positive slope from LREE to HREE and positive Ce anomaly, which is typical of magmatic zircons, but have elevated LREE contents, which implies their crystallization from migmatite melt with subsequent fluid reworking. The transformations of the zircons were caused by fluid, which was separated during crystallization of the last LILE-enriched portions of the melt and inherited the geochemical features of the host rock—leucosome.     

陕西商州地区丹凤变质火山岩的地球化学特征

陕西商州地区丹凤变质火山岩具有洋内岛弧火山岩地球化学特征,它们是分别来自不同源区的拉斑玄武和钙碱性2个系列共存的一套变质火山岩。其Th/Ta比值高及Ni、Ta、Ti、Y和Yb含量低,表明岩石受到消减带组分的影响。种种证据表明,丹凤变质火山岩是早古生代华北地块南缘消减带之上洋内岛弧环境的产物。     

Effects of alteration on element distributions in archean tholeiites from the Barberton greenstone belt,South Africa

Major and trace element and modal analyses are presented for unaltered, epidotized, and carbonated tholeiite flows from the Barberton greenstone belt. Au, As, Sb, Sr, Fe⁺³, Ca, Br, Ga, and U are enriched and H₂O, Na, Mg, Fe⁺², K, Rb, Ba, Si, Ti, P, Ni, Cs, Zn, Nb, Cu, Zr, and Co are depleted during epidotization. CO₂, H₂O, Fe⁺², Ti, Zn, Y, Nb, Ga, Ta, and light REE are enriched and Na, Sr, Cr, Ba, Fe⁺³, Ca, Cs, Sb, Au, Mn, and U are depleted during carbonization-chloritization. The elements least affected by epidotization are Hf, Ta, Sc, Cr, Th, and REE; those least affected by carbonization-chloritization are Hf, Ni, Co, Zr, Th, and heavy REE. Both alteration processes can significantly change major element concentrations (and ratios) and hence caution should be used in distinguishing tholeiites from komatiites based on major elements alone. The amount of variation of many of the least mobile trace elements in the altered flows is approximately the same as allowed by magma model calculations. Hence, up to about 10% carbonization and 60% epidotization of tholeiite do not appreciably affect the interpretation of trace-element models for magma generation.     

Metamorphic growth and recrystallization of zircon: Distinction by simultaneous in-situ analyses of trace elements,U–Th–Pb and Lu–Hf isotopes in zircons from eclogite-facies rocks in the Sulu orogen

Simultaneous in-situ analyses of trace elements, U–Th–Pb and Lu–Hf isotopes were carried out on distinct domains of zircons in ultrahigh-pressure (UHP) eclogite-facies metamorphic rocks from the main hole of the Chinese Continental Scientific Drilling (CCSD) in the Sulu orogen. For the first time, trace elements are directly linked to Lu–Hf isotopes in metamorphic zircons with reference to their U–Pb dates. This enables methodological integration to distinguish four types of metamorphic zircon: solid-state, replacement and dissolution recrystallizations of protolith zircons, and new growth from the aqueous fluid. Metamorphically grown zircons are characterized by concordant U–Pb ages for the metamorphism, flat HREE patterns typical of the garnet effect, low contents of REE (especially HREE), Y, Nb + Ta and Th + U, high contents of Hf, low (Lu/Gd)_N, Lu/Hf and Th/U (< 0.1) ratios, and elevated ¹⁷⁶Hf/¹⁷⁷Hf ratios relative to solid-state recrystallized zircons. This suggests the effects of both garnet and fluid on the growth of metamorphic zircons. In contrast, metamorphic recrystallization has reset the U–Th–Pb isotope system of protolith zircons to different extents, depending on the extents of fluid action during metamorphism. Solid-state recrystallized zircons exhibit the lowest degrees of resetting and thus almost inherit all geochemical features from the protolith zircons, which are characterized by discordant U–Pb ages close to or below the protolith age, steep MREE–HREE patterns typical of magmatic origin, high contents of trace elements and their ratios, and low ¹⁷⁶Hf/¹⁷⁷Hf ratios. On the other hand, dissolution recrystallized zircons show the highest degrees of reworking and thus have concordant or nearly concordant U–Pb ages for the metamorphism, steep MREE–HREE patterns, lowered contents of trace elements such as REE, Th, U, Y, Nb, Ta and Ti relative to the protolith zircons, and almost unchanged Hf isotope ratios. Replacement recrystallized zircons display intermediate degrees of reworking and thus have their many features of elements and isotopes in between. While the metamorphic growth in the presence of both garnet and fluid is characterized by both depletion of HREE with flat pattern and the low contents of trace elements, the metamorphic recrystallization in the presence of aqueous fluid is indicated by gradual decreases of MREE to HREE without the flat HREE pattern. Therefore, the simultaneous in-situ analyses of metamorphic zircons have the advantage over single-term analyses in making distinction between the new growth and the different types of recrystallization.     

武当地块耀岭河群中两类不同性质的酸性火山岩研究

耀岭河群火山岩中可划分出两类不同性质的酸性火山岩:酸性岩A主要属碱流岩-白碱流岩类,酸性岩B主要属流纹英安岩/英安岩类。总体上看二者主量元素组成差异不大:SiO2含量为65.00%～79.85%,(Na2O+K2O)为5.26%～9.68%。强烈富集Th、Nb、Ta、La、Ce、Nd、Zr、Sm和Hf等微量元素,强烈亏损Ba、K、Sr、P、Ti等元素,稀土元素特征表现为∑REE很高(339.94～1152.85μg/g),具有强烈的铕负异常(δEu=0.18～0.32),与典型的大陆裂谷流纹岩的稀土曲线一致。酸性火山岩B显示K、Rb、Ba、Th和LREE的正异常和Sr、P、Ti和Nb的负异常,Eu具弱负异常(δEu=0.64～0.88),表现出与酸性火山岩A迥然不同的微量元素及稀土元素特征,而与耀岭河群基性火山岩相似,显示其成因可能与之有相同源区。