The O(1S) quantum yield from O2+ dissociative recombination

Recent laboratory studies show that the $\text{O}\text{(}{}^1\text{S}\text{)}$ quantum yield, $\text{f}\text{(}{}^1\text{S}\text{)}$, from O₂⁺ dissociative recombination varies considerably with the degree r of vibrational excitation. However, the suggestion that the high values for $\text{f}\text{(}{}^1\text{S}\text{)}$ deduced from airglow and auroral observations can be explained by invoking vibrational excitation, creates a number of problems. Firstly, the rapid vibrational deactivation of O₂⁺ ions by collisions with O atoms will keep r too low to account for the magnitude of $\text{f}\text{(}{}^1\text{S}\text{)}$; secondly, r varies considerably from one atmospheric source to another but its relative values (which should be reliable) do not co-vary with those of $\text{f}\text{(}{}^1\text{S}\text{)}$; thirdly, because r increases markedly above the peak of the $\text{X5577}\text{A}\text{?}$ dissociative recombination layer, the fits which theorists have obtained to the observed volume emission rate profiles would have to be regarded as fortuitious. It is tentatively suggested that $\text{f}\text{(}{}^1\text{S}\text{)}$ is higher in the airglow and aurora than in the laboratory plasma studied by Zipf (1980) because of the electron temperature dependence of the $\text{O}\text{(}{}^1\text{S}\text{)}$ specific recombination coefficient for O₂⁺(v^' ? 3) ions.The repulsive ${}^1\text{Σ}{}_{\mathrm{<mtext>u</mtext>}}\text{[}{}^1\text{D}\text{+}{}^1\text{s}\text{]}$ state of O₂ does not provide a suitable channel for the dissociative recombination. A possible alternative is the bound ${}^3\text{Π}{}_{\mathrm{<mtext>u</mtext>}}\text{[}{}^5\text{S}\text{+}{}^3\text{s}\text{]}$ state with predissociation to the repulsive ${}^3\text{Π}{}_{\mathrm{<mtext>u</mtext>}}\text{[}{}^3\text{P}\text{+}{}^1\text{s}\text{]}$ state.     

Colliding stellar winds in WR+O binary systems

Two-dimensional calculations in the model of two colliding stellar winds are provided. The effects of energy losses on free-free emission and Comptonization are investigated. The expected X-ray emission of a typical WR+O binary system is calculated.     

The H2O maser toward IRAS 06308+0402

We present the monitoring results for the H₂O maser toward the infrared source IRAS 06308+0402 associated with a dense cold molecular cloud. The observations were carried out with the 22-m radio telescope at the Pushchino Radio Astronomy Observatory (Russia) during 1992–2003. The H₂O maser was discovered in May 1992 (Pashchenko 1992) during a survey of IRAS sources associated with dense cold clouds with bipolar molecular outflows. The H₂O spectrum contains many emission features, suggesting the fragmentation of the envelope around a young star. The star has a low peculiar velocity relative to the CO molecular cloud (～2.2 km s^?1). We found a cyclic variability of the total maser flux with a period from 1.8 to 3.1 yr.     

IRAS 02232+6138的13CO、C18O、HCO+和N2H+的观测研究

利用中国科学院紫金山天文台德令哈观测站13．7米望远镜在IRAS 02232 6138方向进行了13CO,C18O,HCO 和N2H 的观测．随着探针分子的激发密度从13CO到N2H 逐渐增加, IRAS02232 6138云核的尺度从13CO的2．40 pc减小到N2H 的0．54pc,云核的维里质量从13CO的2．2×103M⊙减小到N2H 的5．1×102M⊙．研究发现,该方向区域内存在双极分子外流．对云核的空间密度结构用幂函数n(r)αr-α的形式进行拟合分析,得到α=2．3-1．2;随着探测密度的增加,该指数逐渐变平．分析得到, 13CO／C18O分子丰度比值为12．4±6．9,与暗云的11．8±5．9及大质量核的9．0-15．6值一致;N2H 丰度是3．5±2．5×10-10,与暗云核的1．0-5．0×10-10和大质量核的1．2-12．8×10-10值一致;HCO 丰度为0．9±0．5×10-9,接近大质量核的1．6-2．4×10-9值,没有发现HCO 丰度增长．结合IRAS数据,得到云核的光度质量比范围为37-163(L／M)⊙,由IRAS光度估计, IRAS 02232 6138方向云核内嵌埋的大约是一颗主序O7．5星．     

H2O + ions in comets: models and observations

An improved magnetohydrodynamic (MHD) model with chemistry is presented. The analysis of the source and sink terms for H₂O ⁺ shows that for small comets up to 11% of water molecules are finally ionized. For large comets (such as Halley) this fraction decreases to less than 3%. From the MHD scaling laws a similarity law for the individual ion densities is deduced which takes into account that the mother molecules are depleted by dissociation. This is applied to H₂O ⁺ ions. Radial density profiles from model calculations, observations by Giotto near comet Halley, and ground based observations of three comets confirm this scaling law for H₂O ⁺ ions. From the similarity law for the density a scaling law for the column density is derived which is more convenient to apply for ground based observations. From these scaling laws methods are derived which allow the determination of the water production rate from the ground based images of the H₂O ⁺ ions. Finally, the two dimensional images of model column densities are compared with observations.     

ISO SWS Spectroscopy of WR 146 (WC6+O)

We have obtained ISO SWS spectroscopy of WR 146 (WC6+O) covering the wavelength range 2.6-20 μm. WC6 wind emission is observed in numerous lines of He II and C IV, as well as in the [Ne III] 15.5 μm line, but not in [Ne II] 12.81 or [Ne V] 14.32 μm. An analysis of these spectra (and complementary radio and optical data) yields for the WC6 star: v∞ = 2700 km s-1; M=2.6×10-5M⊙yr-1; C/He = 0.15; and a neon abundance bound of 3.4×10-3≤Ne/He≤6.8×10-3. The neon abundance is close to that predicted in stellar evolution models of WC stars. This revised version was published online in August 2006 with corrections to the Cover Date.     

Kaitianite,Ti3+2Ti4+O5, a new titanium oxide mineral from Allende

Kaitianite, Ti³⁺₂Ti⁴⁺O₅, is a new titanium oxide mineral discovered in the Allende CV3 carbonaceous chondrite. The type grain coexists with tistarite (Ti₂O₃) and rutile. Corundum, xifengite, mullite, osbornite, and a new Ti,Al,Zr‐oxide mineral are also present, although not in contact. The chemical composition of type kaitianite is (wt%) Ti₂O₃ 56.55, TiO₂ 39.29, Al₂O₃ 1.18, MgO 1.39, FeO 0.59, V₂O₃ 0.08 (sum 99.07), yielding an empirical formula of (Ti³⁺_1.75Al_0.05Ti⁴⁺_0.10Mg_0.08Fe_0.02)(Ti⁴⁺_1.00)O₅, with Ti³⁺ and Ti⁴⁺ partitioned, assuming a stoichiometry of three cations and five oxygen anions pfu. The end‐member formula is Ti³⁺₂Ti⁴⁺O₅. Kaitianite is the natural form of γ‐Ti₃O₅ with space group C2/c and cell parameters a = 10.115 Å, b = 5.074 Å, c = 7.182 Å, β = 112°, V = 341.77 Å³, and Z = 4. Both the type kaitianite and associated rutile likely formed as oxidation products of tistarite at temperatures below 1200 K, but this oxidation event could have been in a very reducing environment, even more reducing than a gas of solar composition. Based on experimental data on the solubility of Ti³⁺ in equilibrium with corundum from the literature, the absence of tistarite in or on Ti³⁺‐rich corundum (0.27–1.45 mol% Ti₂O₃) suggests that these grains formed at higher temperatures than the kaitianite (>1579–1696 K, depending on the Ti concentration). The absence of rutile or kaitianite in or on corundum suggests that any exposure to the oxidizing environment producing kaitianite in tistarite was too short to cause the precipitation of Ti‐oxides in or on associated corundum.     

3D models of radiatively driven colliding winds in massive O+O star binaries – I. Hydrodynamics

The dynamics of the wind–wind collision in massive stellar binaries are investigated using 3D hydrodynamical models which incorporate gravity, the driving of the winds, the orbital motion of the stars and radiative cooling of the shocked plasma. In this first paper, we restrict our study to main-sequence O+O binaries. The nature of the wind–wind collision region is highly dependent on the degree of cooling of the shocked plasma, and the ratio of the flow time-scale of the shocked plasma to the orbital time-scale. The pre-shock wind speeds are lower in close systems as the winds collide prior to their acceleration to terminal speeds. Radiative inhibition may also reduce the pre-shock wind speeds. Together, these effects can lead to rapid cooling of the post-shock gas. Radiative inhibition is less important in wider systems, where the winds are accelerated to higher speeds before they collide, and the resulting collision region can be largely adiabatic. In systems with eccentric orbits, cold gas formed during periastron passage can persist even at apastron, before being ablated and mixed into its surroundings and/or accelerated out of the system.     

Auroral implications of recent measurements on O(1S) and O(1S) formation in the reaction of N+ with O2

Recent flowing afterglow measurements have shown that the reaction of N⁺ with O₂ produces 70 ± 30% of the oxygen atom product as $\text{O}\text{(}{}^1\text{D}\text{)}$ and < 0.1% as $\text{O}\text{(}{}^1\text{S}\text{)}$. These results indicate that this reaction does not contribute to the auroral green line emission (5577 Å), but can account for ～10% of the observed red line (6300 Å) auroral emission.     

Venus O+ pickup ions: Collected PVO results and expectations for Venus Express

Observations of oxygen pickup ions by the plasma analyzer on the Pioneer Venus Orbiter (PVO) Mission arguably launched broad interest in solar wind erosion of unmagnetized planet atmospheres, and its potential evolutionary effects. Oxygen pickup ions may play key roles in the removal of the oxygen excess left behind from the photodissociation of water vapor by enabling direct escape, additional sputtering of oxygen when they impact the exobase, and escape as energetic neutrals produced in charge exchange reactions with the ambient exospheric oxygen and hydrogen. Although the PVO observations were compromised by an ∼8 keV energy limit for O⁺ detection, a lack of ion composition capability, and the limited sampling and data rate of the plasma analyzer which was designed for solar wind monitoring, these measurements provide our best information about the extended O⁺ exosphere and wake at Venus. Here we show the full picture of the spatial distribution and energies of the O⁺ ion observations collected by the plasma analyzer during PVO's ∼5000 orbit tour. A model of O⁺ test particles launched in the circum-Venus fields described by an MHD simulation of the solar wind interaction is used to help interpret the PVO observations and to anticipate the expanded view of Venus O⁺ escape that will be provided by the ASPERA-4 experiment on Venus Express.     

A first detailed study of the colliding wind WR+O binary WR 30a

We present a detailed, extensive investigation of the photometric and spectroscopic behaviour of WR 30a. This star is definitely a binary system with a period around 4.6 d. We propose the value         . The identification of the components as WO4+O5((f)) indicates a massive evolved binary system; the O5 component is a main-sequence or, more likely, a giant star. The radial velocities of the O star yield a circular orbit with an amplitude         and a mass function of 0.013     . The spectrum of WR 30a exhibits strong profile variations of the broad emission lines that are phase-locked with the orbital period. We report the detection of the orbital motion of the WO component with     , but this should be confirmed by further observations. If correct, it implies a mass ratio     . The star exhibits sinusoidal light variations of amplitude 0.024 mag peak-to-peak with the minimum of light occurring slightly after the conjunction with the O star in front. On the basis of the phase-locked profile variations of the C  iv λ 4658 blend in the spectrum of the WO, we conclude that a wind–wind collision phenomenon is present in the system. We discuss some possibilities for the geometry of the interaction region.     

Physical parameters of the O6.5V+B1V eclipsing binary system LS 1135

The 'All Sky Automated Survey' (ASAS) photometric observations of LS 1135, an O-type single-lined binary (SB1) system with an orbital period of 2.7 d, show that the system is also eclipsing performing a numerical model of this binary based on the Wilson–Devinney method. We obtained an orbital inclination     . With this value of the inclination, we deduced masses   M ₁∼ 30 ± 1 M_⊙  and   M ₂∼ 9 ± 1 M_⊙  , and radii   R ₁∼ 12 ± 1 R_⊙  and   R ₂∼ 5 ± 1 R_⊙  for primary and secondary components, respectively. Both the components are well inside their respective Roche lobes. Fixing the T _eff of the primary to the value corresponding to its spectral type (O6.5V), the T _eff obtained for the secondary component corresponds approximately to a spectral type of B1V. The mass ratio   M ₂/ M ₁∼ 0.3  is among the lowest known values for spectroscopic binaries with O-type components.     

The problem of auroral NO+ concentration and the intensity of 1·27μ bands of O2

The problem of the theoretical computation of the emission intensities and ion composition in a weak aurora which has been preceded by a stronger event is examined. For this purpose a model auroral precipitation consisting of biexponential primaries is considered. The softer of the two components is brighter, and begins to decay after remaining steady for ten to fifteen minutes. The other, harder component starts to build up at that instant. Our results suggest that at least a part of the high $\text{n(}\text{NO}{}^{\mathrm{+}}\text{)}\text{n(}\text{O}{}_2{}^{\mathrm{+}}\text{)}\text{or}\text{I}\text{(1·27 μ)}\text{I}\text{(3914}\text{A}\text{?}\text{)}$ ratios could be attributed to the retention, by the atmosphere, of the memory of previous auroral precipitations. Thus, the serious energy paradox in the context of 1·27 μ intensity need not arise, and, in the context of the large NO⁺ density, it may perhaps be unnecessary to invoke any major conversion of O₂ to NO thus avoiding the associated energy problem.