Early Tertiary fluid flow and pressure–temperature conditions in the Shimanto accretionary complex of south-west Japan: constraints from fluid inclusions

The pressure and temperature history of the Tertiary Shimanto belt of south-west Japan has been elucidated by analysing fluids trapped in quartz crystals which grew syn-kinematically along late-stage brittle faults. The samples come from three areas that span the Paleogene exposures on the Muroto Peninsula of Shikoku Island. Applying microthermometric and laser Raman microsampling techniques to coeval water-rich and carbonic fluid inclusions, we have constrained the pressure and temperature conditions that accompanied a widespread and kinematically distinct phase of deformation. The results suggest elevated geothermal gradients during late-stage deformation, conditions that are in disaccord with previous plate reconstructions that have depicted old, thermally mature Pacific crust subducting beneath Eurasia during the early to middle Tertiary. These conditions can most easily be accounted for by including an additional plate boundary in the western Pacific during Paleogene time. Plate reconstructions that include the Kula plate in this region are therefore consistent with our findings. In addition, our results provide clues to the conditions that likely accompany seismogenic deformation at active convergent plate boundaries.     

Provenance analysis of the Cretaceous Laiyang Group on Lingshan Island (western Yellow Sea,China) and its tectono-sedimentary implications

Abstract

Longstanding debates on the tectonic setting and provenance of the Lower Cretaceous Lingshandao Formation have hindered basin analysis and tectonic studies of the collision of the Yangtze Craton and the North China Craton, and thus the evolution of the Sulu Orogen. Thin-section analysis, identification of rock particles, cathodoluminescence, heavy minerals and trace-element analysis have, in addition to field investigations, been applied to reconstruct the source area and transport pathways of the sediments that build the Lower Cretaceous Laiyang Group on the Lingshan Island, western Yellow Sea. These analyses indicate that the Laiyang Group consists mainly of material derived from a recycled orogen and from transitional continental sediments. The Laiyang Group on Lingshan Island has been sourced from igneous and metamorphic rocks. Comparing analyses of detrital minerals with rocks from surrounding areas leads to the conclusion that the main source area is the Sulu Orogen that supplied sediment to rift basin rather than a residual basin between the Yangtze Craton and the North China Craton.

1. A recycled orogenic belt is the source area for the Laiyang Group on Linshan Island.

2. Felsic metamorphic and igneous rocks form the most probable sources.

3. The rift basin was filled by sediments supplied from the Sulu Orogen on both sides.

     

The youngest blueschist belt in SW Japan: implication for the exhumation of the Cretaceous Sanbagawa high-P/T metamorphic belt

The tectonic evolution of the Northern Shimanto belt, central Shikoku, Japan, was examined based on petrological and geochronological studies in the Oboke area, where mafic schists of the Kawaguchi Formation contain sodic amphibole (magnesioriebeckite). The peak P–T conditions of metamorphism are estimated as 4–4.5 kbar (15–17 km depth), and 240–270 °C based on available phase equilibria and sodic amphibole compositions. These metamorphic conditions are transitional between blueschist, greenschist and pumpellyite–actinolite facies. Phengite K–Ar ages of 64.8 ± 1.4 and 64.4 ± 1.4 Ma were determined for the mafic schists, and 65.0 ± 1.4, 61.4 ± 1.3 and 63.6 ± 1.4 Ma for the pelitic schists. The metamorphic temperatures in the Oboke area are below the closure temperature of the K–Ar phengite system, so the K–Ar ages date the metamorphic peak in the Northern Shimanto belt. In the broad sense of the definition of blueschist facies, the highest‐grade part of the Northern Shimanto belt belongs to the blueschist facies. Our study and those of others identify the following constraints on the possible mechanism that led to the exhumation of the overlying Sanbagawa belt: (i) the Sanbagawa belt is a thin tectonic slice with a structural thickness of 3–4 km; (ii) within the belt, metamorphic conditions varied from 5 to 25 kbar, and 300 to 800 °C, with the grade of metamorphism decreasing symmetrically upward and downward from a structurally intermediate position; and (iii) the Sanbagawa metamorphic rocks were exhumed from ～60 km depth and emplaced onto the Northern Shimanto metamorphic rocks at 15–17 km depth and 240–270 °C. Integration of these results with those of previous geological studies for the Sanbagawa belt suggests that the most probable exhumation mechanism is wedge extrusion.     

松潘-甘孜褶皱带南部上三叠统物源及构造抬升: 碎屑锆石年代学和Hf同位素证据

碎屑锆石年代学不但能够限定地层沉积开始的最大时限,还能为示踪沉积物源区提供关键信息。中国西南部的松潘-甘孜褶皱带广泛出露一套巨厚的三叠纪复理石沉积,其物源区和可能存在的同期抬升与剥蚀历史并未得到很好约束。本文获得的松潘-甘孜褶皱带南部雅江地区上三叠统四套地层（由老至新分别为侏倭组、新都桥组、两河口组和雅江组）5件砂岩样品的碎屑锆石U-Pb年龄和锆石Hf同位素数据表明,最年轻锆石年龄指示侏倭组从~229Ma后开始沉积,新都桥组则从~223Ma后开始沉积。碎屑锆石年龄频谱图显示四套地层都具有中奥陶世-早泥盆世（465~398Ma）和中二叠世-晚三叠世（271~225Ma）的年龄峰。除两河口组外的其他三套地层还具有较强的古元古代（1.90~1.86Ga）和新元古代（872~712Ma）的年龄峰。锆石Hf同位素显示松潘-甘孜褶皱带南部上三叠统小于300Ma的锆石颗粒主要来自峨眉山大火成岩省和义敦岩浆弧。本文物源区示踪结果表明,华南板块和义敦地体可能为松潘-甘孜褶皱带南部地层的主要物源区。晚三叠世由于周缘地体的强烈汇聚,松潘-甘孜褶皱带在小于~18Myr的时间内经历了快速的隆升和剥蚀作用,剥蚀产生的碎屑物质被搬运至四川盆地的西缘再沉积。

     

The transition from brittle to ductile deformation in the Sambagawa metamorphic belt, Japan

The dominant deformation mechanism during the Sambagawa metamorphism changes from brittle to ductile with increasing metamorphic temperature. The magnitude of plastic strains inferred from the shapes of deformed radiolaria in metachert increases sharply across the boundary between the epidote-pumpellyite-actinolite zone and the epidote-actinolite zone. The synmetamorphic crack density of metachert is an indicator of the contemporaneous brittle strain of rocks, and it decreases sharply as the grade reaches the epidote-actinolite zone. Hence, the ratio of the ductile strain to the brittle strain of metachert decreases rapidly across the transition to the epidote-actinolite zone of the Sambagawa metamorphic belt.
The sharp change of the ductile strain magnitude also takes place at the epidote-actinolite grade in the Shimanto metamorphic belt of Japan, an example of the intermediate pressure facies series of metamorphism. It is concluded that the transition from brittle to ductile deformation takes place at about 300-400°C. and is independent of pressure of metamorphism.     

Geologic correlation between the Neoproterozoic Sergipano belt (NE Brazil) and the Yaoundé belt (Cameroon, Africa)

The Yaoundé belt (Cameroon) and the Sergipano belt (NE Brazil) belonged to a major and continuous Neoproterozoic orogen at the northern margin of the ancient Congo-São Francisco craton. The Yaoundé belt comprises schists, quartzites, gneisses and migmatitic gneisses grouped into three domains; the low-grade Mbalmayo Group in south and the medium- to high-grade Yaoundé and Bafia Group in north. The Sergipano belt is divided into six domains, the three southernmost of which are mostly made up of clastic and chemical metasedimentary rocks whereas the others are more diverse with a migmatite–gneiss complex, and two metavolcanicplutonic complexes. In general, the two belts show structural vergence and decrease of metamorphic grade towards the craton; three main deformation phases are recognized in the Sergipano belt in contrast with two described in the Yaoundé belt. The minimum age of Pan-African-Brasiliano collision in the Sergipano belt is constrained at 628 ± 12 Ma on syn-collision granites, whereas in the Yaoundé belt collision took place between 620 and 610 Ma, i.e. the age of granulite facies metamorphism. Sm–Nd isotope geochemistry and U–Pb age dating indicate that most clastic metasedimentary rocks in both belts were derived from sources to the north and, to a lesser degree, from the cratons to the south.     

柴达木盆地北缘构造带早古生代造山后作用初探：泥盆纪沉积物物源示踪

柴达木盆地北缘(柴北缘)泥盆系牦牛山组以发育冲积扇沉积体系的粗碎屑岩和中酸性火山岩的岩石组合为特征,记录了柴北缘构造带从碰撞造山进入造山后阶段的核部岩石剥露过程。尕海南山牦牛山组地层顶部和底部的凝灰岩锆石LA-ICP-MS U-Pb加权平均年龄分别为396.6±2.4 Ma(MSWD=0.39,n=14)和396.9±2.5 Ma(MSWD=0.052,n=14),指示了牦牛山组沉积时代大致为早泥盆世末期。不同出露点牦牛山组砂岩碎屑锆石LA-ICP-MS U-Pb年龄谱具有不同的峰值特征：尕海南山调查点A,样品20QH-19具有532～505 Ma、935～891 Ma、1136～1064 Ma和3110～1309 Ma多峰特征;尕海南山调查点B,样品20QH-21具有537～443 Ma、1073～798 Ma和2463～1785 Ma多峰及20QH-22以明显的单一峰值～420 Ma为特征;牦牛山调查点C,20QH-26以明显的～418 Ma单峰为特征。多样的年龄组分指示了牦牛山组沉积物质主要来源于柴北缘志留纪—泥盆纪同造山岩浆岩、寒武系—奥陶系滩间山群、沙柳河群及欧龙布鲁克地块。...     

Timing of Metamorphism and Provenance of the Metamorphic Basement of the Xiangshan Uranium Orefield,Jiangxi Province,China

The origin, age and evolution of the Precambrian metamorphic basement of southern China provide useful insights into early crustal development. Here, we present new laser ablation–inductively coupled plasma–mass spectrometry(LA–ICP–MS) U–Pb age data for detrital zircons from five samples of the Precambrian metamorphic basement of the Xiangshan uranium orefield. Two of these samples, from the northern Xiangshan volcanic basin, yielded a total of 140 U–Pb ages that cluster within the Neoproterozoic(773–963 Ma; 79.3% of data points), with the rest being scattered through the Paleoproterozoic and Mesoproterozoic, along with a single Archean age. These ages indicate that this basement material is associated with the Cathaysia Block. In comparison, the 172 concordant ages from the other three samples from the southern part of the Xiangshan volcanic basin cluster within the Neoproterozoic(767–944 Ma; 59.8%) as well as the Proterozoic(37.8%) and the Archean(2502–2712 Ma; 14.5%). These samples are also free of zircons with Grenvillian ages, indicating that these units are associated with the southeastern Yangtze Block. Combining these data with the geochemistry of these units, which suggests that the metamorphosed sedimentary rocks within the northern and southern parts of the Xiangshan basin have a common component from a magmatic island arc that formed during the early Neoproterozoic, we infer that the basin was located along the boundary between the Cathaysian and Yangtze blocks. In addition, the zircons within the samples from the southern and northern parts of the Xiangshan basin show different pre-Neoproterozoic(963 Ma) age populations but similar postNeoproterozoic zircon populations, indicating that the amalgamation of the Cathaysian and Yangtze blocks occurred after the Neoproterozoic(960 Ma), with magmatism peaking at 830 Ma and rifting starting at ～770 Ma, leading to the subsequent deposition(from bottom to top) of the Shenshan, Kuli, and Shangshi formations.     

冈底斯-喜马拉雅碰撞造山带前陆盆地系统及构造演化

碰撞带前陆盆地的建立是大陆碰撞的直接标志和随后造山带构造变形的忠实记录。本文对欧亚板块与印度板块碰撞前后发育在拉萨地块上的冈底斯弧背前陆盆地,同碰撞产生的雅鲁藏布江周缘前陆盆地,以及碰撞后陆内变形产生的喜马拉雅前陆盆地的沉积地层演化以及碎屑锆石物源特征等进行了系统分析,结合前人及我们近些年的研究成果,认为冈底斯岛弧北侧发育一个典型的弧背前陆盆地系统而不是以前普遍接受的伸展盆地。除传统认为的喜马拉雅前陆盆地系统外,在碰撞造山带中还发育一个雅鲁藏布江前陆盆地系统,它是欧亚板块与印度板块碰撞以后,欧亚板块加载到印度被动大陆边缘产生的典型周缘前陆盆地。上述2个造山带前陆盆地系统的识别,大大提高了对新特提斯洋俯冲、碰撞过程的认识。造山带前陆盆地证据指示,新特提斯洋至少于140 Ma以前就已开始俯冲, 110 Ma俯冲速度开始提高,在65 Ma前后印度大陆与欧亚大陆发生碰撞,喜马拉雅山于40 Ma开始隆升,其剥蚀物质大量堆积在喜马拉雅前陆盆地中。     

苏北盆地高邮凹陷马家嘴地区古近系戴南组物源分析

综合运用碎屑岩类分析法、重矿物法、沉积法三类物源分析方法对苏北盆地高邮凹陷马家嘴地区戴南组的物源进行了分析。马家嘴地区母岩岩性以火成岩为主,其次为变质岩和沉积岩,其中中酸性火成岩的分布范围要比基性火成岩分布范围广,变质岩以中—低级变质岩为主,深成岩较少。对研究区内各层段砂岩类型、岩屑类型及含量变化、砂岩百分含量、地层厚度、沉积相展布、重矿物稳定系数、重矿物组合、ZTR指数和重矿物指数等资料的研究结果表明,戴南组沉积时期马家嘴地区各个区块具有不同的物源方向,马8区块沉积物主要来自菱塘桥低凸起方向,部分来自通扬隆起;马31区块沉积物来自菱塘桥低凸起方向,古河流发生迁移;马33区块沉积物来自通扬隆起。     

Geochemistry of Sediments from the Lopare Basin (Bosnia and Herzegovina): Implications for Paleoclimate, Paleosalinity, Paleoredox and Provenance

A combined inorganic and organic geochemical study was carried out on marls and mudstones collected from the Lower Miocene Lopare Basin, Bosnia and Herzegovina. A total of 46 samples collected from two boreholes, Pot 1 (depth of 193 m) and Pot 3 (depth of 344 m), showed that element abundances like boron (B), lithium (Li), strontium (Sr), uranium (U), chromium (Cr), nickel (Ni), magnesium (Mg), sodium (Na) and calcium (Ca) are much higher than average than in the upper continental crust (UCC). Chemical composition indicates at least two sources: (i) Mesozoic ophiolites occurring in the north of the investigated area, and (ii) dacito-andesitic pyroclastics (Mesozoic to Cenozoic). Lopare Basin sedimentation was influenced by strong evaporation resulting in a partly hypersaline lake, which formed during a warm climatic period, probably during the Miocene Climatic Optimum. A brief episode of humid climate conditions resulted in the basin filling-up and deposition of felsic sediments enriched in thorium (Th). Organic geochemistry shows that the majority of studied sediments contains predominantly immature to marginally mature algal organic matter (OM). The biomarker patterns are generally in agreement with the geological history of the Lopare Basin and inorganic and mineralogical data. Conversely, the molecular distribution of n-alkanes as reliable climatic and δ-MTTC as paleosalinity indicators do not support this conclusion.     

陕西省成矿区(带)的划分

通过系统总结,将陕西省成矿区(带)进行了统一划分,该省与4个 级成矿区(带)、4个 级成矿区(带)和7个 级成矿区(带)有关;在 级成矿区(带)中,共划分出19个 级成矿区(带);在 级成矿区(带)中,共划分出44个 级成矿区(带).     

Deformation Style of Slickenlines on Mélange Foliations and Change in Deformation Mechanisms Along Subduction Interface: Example from the Cretaceous Shimanto Belt, Shikoku, Japan

Accretionary complexes record the histories of changes in physical properties of sediments from unlithified sediments to lithified rocks through the deformation processes along subduction interface. The trench sediment suffered various deformation of particulate flow, pressure solution deformation and cataclastic faultings from ductile to brittle regime during accretion in subduction zone. Tectonic mélange is a characteristic rock in on-land accretionary complexes. The dominant deformation mechanism of tectonic mélange formation is pressure solution on the basis of microscopic observation. However, brittle slickenlines are also commonly observed on mélange foliations at the outcrop scale. Although the slickenlines as a brittle failure is common on the surface of the pressure solution foliation, the relationship of their kinetic are still uncertain. Detailed observations of slickenlines suggest that they are formed by reactivation of the mélange foliations, which indicates that the slickenlines are developed after formation of block in matrix texture characterized in mélange. In addition, mélange foliations are cut by faults related to underplating of oceanic materials. Therefore, formation of slickenlines occur before underplating in a relatively deep portion along subduction interface. On the basis of P-T conditions reported from other parts of the Cretaceous Shimanto Belt, the mélange formation and underplating is inferred to have occurred around the seismic front or within the seismogenic zone. The change in deformation mechanisms from pressure solution to brittle failure may be the first change in physical properties from plastic to brittle around seismic front.     

Facies and provenance analysis of Paleogene‐age alluvial conglomerates from the northern part of the Mesta Basin,SW Bulgaria

The Mesta Basin in southwest Bulgaria is a graben that contains a Paleogene‐age siliciclastic and volcaniclastic succession deposited in alluvial and fluvial settings. A sedimentological analysis has shed light on conglomerate provenance, and the links between deposition and tectonic setting. Petrographical and chemical analysis of conglomerate clasts and matrix from the Dobrinishka, Gradinishka, Osikovo (or Osenovo) and Zlataritsa formations reveal both local, and more distal source provenance ages. The basal conglomerates are subdivided into three types, a lower and upper polymictic and a middle granitic conglomerate type. Petrographical and chemical analysis reveals granite, gneiss and amphibolite clasts that were sourced from the Sidironero–Mesta Unit of the Middle Allochthon of the Rhodope Metamorphic Complex, and the Rila–Rhodope Batholith to the east of the basin. Cathodoluminescence analysis of quartz sand grains reveals an increased input of red‐ and violet‐luminescent volcanic grains. Volcanic quartz in the oldest conglomerates indicates a hitherto unknown early (pre‐Oligocene) phase of volcanic activity in the vicinity of the Mesta Basin. The conglomerates were deposited in association with movement on the Ribnovo low‐angle normal fault during the Late Eocene, creating subsidence and the development of considerable accommodation space. The establishment of a fluvial environment followed subsequent Oligocene‐age volcanic activity. Copyright © 2012 John Wiley & Sons, Ltd.     

兴蒙造山带南缘早—中二叠世砂岩碎屑锆石U-Pb年龄、Hf同位素组成及其构造意义

利用LA-MC-ICP-MS 分析技术,对兴蒙造山带南缘下二叠统三面井组和中二叠统额里图组砂岩中的碎屑锆石进行了U-Pb 年龄和Hf 同位素研究。结果显示,三面井组砂岩记录了3 组碎屑锆石年龄：280~369Ma（4 颗）、1800~2271Ma（43 颗,峰值1877Ma）和2507~2711Ma（9 颗）。额里图组砂岩碎屑锆石年龄集中分布在271~371Ma（9 颗）、1258~1395Ma（18 颗,峰值1326Ma）和1695~2454Ma（34 颗,峰值1864Ma）3 个年龄区间。对比研究发现,样品中的元古宙和太古宙碎屑锆石是华北克拉通古老基底的反映;晚古生代锆石具有较低的εHf(t)值（-5.3~-23.7）和较老的Hf 模式年龄（1124~3039Ma）,与华北克拉通北缘晚古生代岩浆岩具有一致性,而明显区别于兴蒙造山带内岩浆岩Hf 同位素特征,说明前者是其物源供给区。结合区域资料认为,华北克拉通北缘在早―中二叠世期间不存在类似安第斯型的俯冲大陆边缘,三面井组和额里图组砂岩是在伸展背景下沉积形成的。     

Application of electron spin resonance (ESR) dating to ductile shearing: Examples from the Qinling orogenic belt,China

Shear zones are common structures in orogenic belts and elucidation of the tectonic evolution of these orogenic belts to a large degree depends on understanding the kinematics and timing of shear deformation. However, there is a lack of an accurate, fast and convenient way to determine the timing of deformation. In this paper, we apply the ESR (electron spin-resonance spectroscopy) dating method to three syntectonic quartz veins from the Funiushan tectonic belt in the Qinling orogenic belt in central China. The results agree well with the available ages of deformation in the area obtained through other dating methods. This demonstrates the accuracy and feasibility of using the ESR method to date quartz crystals formed during deformation. The method is fast and convenient, and satisfies the accuracy requirement. It is an effective means for determining the timing of deformation, especially in areas with intensive fluid activity during deformation.     

Metamorphic record of the Asemi‐gawa eclogite unit in the Sanbagawa belt,southwest Japan: Constraints from inclusions study in garnet porphyroblasts

The Sanbagawa belt is one of the famous subduction‐related high‐pressure (HP) metamorphic belts in the world. However, spatial distributions of eclogite units in the belt have not yet satisfactorily established, except within the Besshi region, central Shikoku, southwest Japan because most eclogitic rocks were affected by lower pressure overprinting during exhumation. In order to better determine the areal distribution of the eclogite units and their metamorphic features, inclusion petrography of garnet porphyroblasts using a combination of electron probe microanalyser and Raman spectroscopy was applied to pelitic and mafic schists from the Asemi‐gawa region, central Shikoku. All pelitic schist samples are highly retrogressed, and include no index HP minerals such as jadeite, omphacite, paragonite, or glaucophane in the matrix. Garnet porphyroblasts in pelitic schists occur as subhedral or anhedral crystals, and show compositional zoning with irregular‐shaped inner segments and overgrown outer segments, the boundary of which is marked by discontinuous changes in spessartine. This feature suggests that a resorption process of the inner segment occurred prior to the formation of the outer segment, indicating discontinuous crystallization between the two segments. The inner segment of some composite‐zoned garnet grains displays Mn oscillations, implying infiltration of metamorphic fluid during the initial exhumation stage. Evidence for an early eclogite facies event was determined from mineral inclusions (e.g., jadeite, paragonite, glaucophane) in the garnet inner segments. Mafic schists include no index HP minerals in the matrix as with pelitic schists. Garnet grains in mafic schists show simple normal zoning, recording no discontinuous growth during crystal formation. There are no index HP mineral inclusions in the garnet, and thus no evidence suggesting eclogite facies conditions. Quartz inclusions in garnet of the pelitic and mafic schists show residual pressure values (?ω₁) of >8.5 cm^?1 and <8.5 cm^?1 respectively. The combination of Raman geobarometry and conventional thermodynamic calculations gives peak P–T conditions of 1.6–2.1 GPa at 460–520°C for the pelitic schists. The ?ω₁ values of quartz inclusions in mafic schists are converted to a metamorphic pressure of 1.2–1.4 GPa at 466–549°C based on Raman geothermometry results. These results indicate that a pressure gap definitely exists between the mafic schists and the almost adjacent pelitic schists, which have experienced a different metamorphic history. Furthermore, the peak P–T values of the Asemi‐gawa eclogite unit are compatible with those of Sanbagawa eclogite unit in the Besshi region of central Shikoku, suggesting that these eclogite units share a similar P–T trajectory. The Asemi‐gawa eclogite unit exists in a limited area and is composed of mostly pelitic schists. We infer that these abundant pelitic schists played a key role in buoyancy‐driven exhumation by reducing bulk rock density and strength.     

Tectonic incorporation of the upper part of oceanic crust to overriding plate of a convergent margin: An example from the Cretaceous–early Tertiary Mugi Mélange, the Shimanto Belt, Japan

A tectonic mélange exposed on land is examined to reveal relationships between mélange formation, underplating, and deformation mechanisms, focusing on the deformation of basaltic rocks. The studied Mugi Mélange of the Shimanto Belt is composed of a shale matrix surrounding various blocks of sandstone, pelagic sediments, and basalts. The mélange was formed during Late Cretaceous to early Tertiary times in a subduction zone under P–T conditions of 150–200 °C and 6–7 km depth as estimated from vitrinite reflectance and quartz veins fluid inclusions. The mélange represents a range of deformation mechanisms; pressure solution with micro-scale cataclasis in the shale matrix, brittle tension cracking in the blocks, and ubiquitous strong cataclasis in the basal portion of basaltic layers. The cataclastic deformation in the basalts suggests a breakage of a topographic high in the seismogenic depth.     

西藏羌塘盆地古近纪康托组沉积物源及构造背景分析

沉积岩中的主微量元素和稀土元素特征可以指示其物源、构造背景和沉积环境等.康托组地层沉积时代为古近纪,是青藏高原早期隆升后首先沉积的陆相碎屑岩,对该地层的物源信息及构造背景分析对于研究羌塘盆地新生代演化和高原隆升过程具有积极意义.本文对羌塘盆地半岛湖地区康托组地层进行了地层学、岩石学、元素地球化学和黏土含量分析,研究了其...