Hydrocarbons in the Bay of Bengal and Central Indian Basin bottom sediments: indicators of geochemical processes in the lithosphere

A study on the bulk distributions and molecular structures of n-alkanes and polycyclic aromatic hydrocarbons (PAH) in organic matter of the sediments from the Bay of Bengal and the Eastern and Central Indian Basins was undertaken. The former two regions represent areas characterised by “normal” sedimentation while the third one mainly represents a region of “active tectonism”. Content of the hydrocarbons in the sediments of “normal” sedimentation ranges between 4.6 and 10.5 μg/g and aromatic hydrocarbons ranges between 0 and 0.38 μg/g. n-Alkanes in the sediments of the northern deep part of the Bay of Bengal consist mostly of long-chain structures (total C₂₅–C₃₃ up to 70%) with a high carbon preference index (CPI=3.01–3.43), indicating a large contribution of organic matter from terrigenous sources. The sediments from the Eastern Indian Basin have n-alkane distributions in which the long-chain components did not exceed 52.5% and the CPI was 1.7–1.90, indicating that the hydrocarbons are mostly derived from marine sources. Sharp increases of hydrocarbons are found in the vicinity of the tectonically active region of the Central Indian Basin, particularly in the sediments collected from the fracture zone. The total concentration of hydrocarbons increase to 170 μg/g and the aromatic hydrocarbons fraction to 156.3 μg/g. The proportion of short-chain n-alkanes increases up to 70%, CPI decreases to 0.76–1.12, and high concentrations of n-C₁₆ (16–40%) occur, all of which are absent in the other samples. The molecular content of PAH includes the unsubstituted individual structures: biphenyl, fluorene, pyrene, perylene, benzo(ghi)perylene, and the groups of homologues of naphthalene, benzofluorene, phenanthrene and chrysene. The association of the PAH and composition of paraffin hydrocarbons in the surficial sediments of deformation zone indicate that these are the resultant products of hydrothermal processes. It is, therefore, suggested that the association and composition of the hydrocarbons in sediments can be utilised as a paleoceanographic parameter to decipher the history of tectonism of an area.     

Recent developments in “added-mass” planing theory

The results of several recent isolated investigations in planing theory are consolidated in this paper, together with new insights generated by a recent numerical solution of the vertically impacting wedge problem by Zhao and Faltinsen [(1992), Water entry of two-dimensional bodies. J. Fluid Mech. 246, 593–612]. As a result, in contrast to some earlier studies, it is found that the “wetted width” associated with the added mass is not that of the intersection of the wedge with the undisturbed water surface, but the wetted width of the splashed-up water, as originally proposed by Wagner [(1932), Uber Stoss-und Gleitvorgange an der Oberflache von Flussig-Keiten, Zeitschrift für Angewandte Mathematik und Mechanik, Band 12, Heft 4 (August)]. However, the splash-up ratio is not the value of (π/2–1) which he proposed, but a value which decreases with increasing deadrise, originally proposed in the late-1940s by Pierson (“Pierson's hypothesis” in the paper). For 30° deadrise, for example, Pierson's splash-up ratio is two-thirds that of Wagner's.The new equations are employed to determine the increase in the “added mass” of prismatic hull sections due to chine immersion, using experimental data. If m_o^′ is the added amss of the hull section whose chines are just wetted, Payne [(1988), Design of High-speed Boats. Volume 1: Planing. Fishergate, Inc., Annapolis, Maryland, U.S.A.] postulated that the increase in added mass due to a chine submergence (z_c) would be

where b is the chine beam and k is a constant which Payne [(1988), Design of High-speed Boats. Volume 1: Planing. Fishergate, Inc., Annapolis, Maryland, U.S.A.] gave as .The present analysis includes the “one-sided flow” correction introduced in Payne [(1990), Planing and impacting forces at large trim angels. Ocean Engng 17, 201–234]. Partly for that reason and partly because of the more precise analysis of the experimental data, the present paper revises the value to k = 2 for wetted length to beam ratios normally employed. For deadrise angles in excess of 40° and wetted keel to beam ratios in excess of 2.0, there is some evidence that k < 2.0.The revised theoretical formulation is compared with eight different sets of experimental data for flat plate and prismatic hull forms and is found to be in excellent agreement when the speed is high enough for “dynamic suction” (a loss of buoyancy at low speeds and low wetted lenghts) to be unimportant. This is true for “chines-dry” operation with deadrise angles up to 50° and chines-wet operation at length to beam ratios far in excess of the most extreme conventional practice.The research involved in performing this analysis led to the realization that different towing tanks measure different wetted chine lengths for the same hulls and test conditions. Some consistently measure more splash-up than “theory” (based on Pierson's splash-up hypothesis) predicts and others measure somewhat less than the theory. Some examples are given in Appendix B. The reason for this is not understood.     

Mesoscale eddies off Peru in altimeter records: Identification algorithms and eddy spatio-temporal patterns

Relatively little is known about coherent vortices in the eastern South-Pacific along the Peruvian coast, even with regard to basic facts about their frequency of occurrence, longevity and structure. This study addresses these issues with nearly 15 years of relatively high-resolution satellite altimetry measurements.We first compare two distinct automated methods for eddy identification. The objective validation protocol shows that the rarely-used geometrical or “winding-angle method”, based on the curvature of the streamline functions, is more accurate than the commonly-used “Okubo–Weiss algorithm”, which defines a vortex as a simple connected region with values of Okubo–Weiss parameter weaker than a given threshold.We then investigate vortices off Peru using more than 20,000 mesoscale eddies identified by the winding-angle method. Coherent eddies, characterized by a high ratio of vorticity to deformation rate, are typically formed along the coast and propagate westward at 3–6 cm s⁻¹. The vortices have a mean radius of 80 km, increasing northward, and are most frequently observed off of Chimbote (9°S) and south of San Juan (15°S). The mean eddy lifetime is about 1 month, but if eddies survive at least 2 months, the probability for surviving an additional week (or month) is constant at 90% (or 67%). Anticyclonic eddies tend to propagate northwestward whereas cyclonic vortices migrate southwestward. In general, cyclones and anticyclones are similar, except for eddies surviving at least 6 months. In this case, after a similar 3–4 months of radius and amplitude growth, amplitudes (or sizes) decay particularly rapidly for anticyclonic (or cyclonic) eddies. In terms of intensity, cyclonic eddies show a rapid decay during the first 3 months before arriving at a quasi-constant value, whereas anticyclones exhibit steady decline. Finally, eddy temporal variations were examined at seasonal and interannual scales in the “coastal” region favorable to the formation of energetic mesoscale structures. On seasonal scales, eddy activity is maximal in fall and minimum in spring. At interannual scales, the eddy activity index was maximal during the strong El Niño of 1997–1998 but another strong maximum of eddy activity also occurred late in 2004. These temporal variations are probably associated with the intensification of the upwelling thermal front and with the passage of coastal-trapped waves which generate baroclinic instabilities. Further investigation of the mechanisms involved on the eddy genesis is needed.     

A rational approach to intact ship stability assessment

In this study, asymptotic and total stability of the non-linear free and forced pure rolling motions of a ship are investigated. A ship performing a rolling motion is taken as a dynamical system. Lyapunov's direct method is employed in the analysis. By generating a time-invariant Lyapunov function, conditions and the domain of asymptotic stability are obtained for free rolling motion. Results of the work on “boundedness” and “uniform boundedness” of the solutions of the equation of forced rolling motion, done by Özkan (1977), that is, conditions of total (practical) stability and its domain in the phase-plane are given and illustrated.     

A study of natural and artificially generated light hydrocarbons (C4–C13) in source rocks and petroleum fluids from offshore Mid-Norway and the southernmost Norwegian and Danish sectors

The “free” or “natural” light hydrocarbon composition obtained by thermal extraction-GC of source rock samples is compared with the light fraction generated by pyrolysis products of the kerogens. Even though there are large differences between the composition of the “free” C₄–C₁₃ hydrocarbon fraction and the same fraction generated by pyrolysis, some characteristics have been detected which can be used interchangeably for both data types. Visual inspection of gas chromatograms from thermal extracts and pyrolysates indicates that in particular the relative content of m+p xylene corresponds well between these two analytical methods. The source rock samples used are Upper Jurassic marine shales and Middle and Lower Jurassic coals and coaly shales from offshore Mid-Norway and Denmark. More detailed analysis of the data shows that the most effective parameter which can distinguish between different source rock types in both thermal extracts and pyrolysates is the m+p xylene/nC₈ ratio. This parameter has been used to derive classification diagrams for interpreting the source of light hydrocarbons of both natural petroleum fluids analysed by gas chromatography and the same fraction generated by pyrolysis of asphaltenes from the fluids.The model was first tested on 17 natural petroleum fluids from Mid-Norway since a comprehensive study of light hydrocarbon distributions already has been published. Further, the parameter was applied to correlate with asphaltene pyrolysates of the fluids from Mid-Norway and a total of 22 natural oils and condensates from the southernmost Norwegian and Danish sectors.     

Black carbon in marine particulate organic carbon: Inputs and cycling of highly recalcitrant organic carbon in the Gulf of Maine

To increase our understanding of the roles of black carbon (BC), a highly sorptive and recalcitrant material, we measured BC concentrations and fluxes in marine particulate organic carbon (POC) out of the water column in the Gulf of Maine (GoM), a representative coastal area downwind of important BC sources of the Northeastern United States. Concentrations ranged from < 0.1 to 16 μg/L in the spring and late summer, typically contributing between 1 and 20% of the POC. Water-column export fluxes were near 10 g_BC/m²∙yr. These observations suggest that (a) up to 50% of the “molecularly uncharacterized” POC in this region's seawater is combustion-derived BC, and (b) the “bioavailabilities” of hydrophobic pollutants like polycyclic aromatic hydrocarbons (PAHs) would be influenced substantially by sorption to BC. The observed BC spatial distributions imply that a large part of the BC was carried offshore by wind and that much of it is accumulated in the coastal sediments. On a global scale, these results suggest the GoM and other coastal areas with similar BC loadings accumulate significant amounts of highly recalcitrant organic carbon that remineralizes on geological time scales in the world's oceans.     

The marine ecosystem off Peru: What are the secrets of its fishery productivity and what might its future hold?

The marine ecosystem located off the coast of central and northern Peru has stood as the “world’s champion” producer, by far, of exploitable fish biomass, generally yielding more than 20 times the tonnage of fishery landings produced by other comparable regional large marine ecosystems of the world’s oceans that operate under similar dynamic contexts and are characterized by comparable, or even greater, basic primary production. Two potentially contributing aspects are discussed from a framework of interregional comparative pattern recognition: (1) the advantageous low-latitude situation that combines strong upwelling-based nutrient enrichment with low wind-induced turbulence generation and relatively extended mean “residence times” within the favorable upwelling-conditioned near-coastal habitat and (2) the cyclic “re-setting” of the system by ENSO perturbations that may tend to interrupt malignant growth of adverse self-amplifying feedback loops within the nonlinear biological dynamics of the ecosystem.There is a developing scientific consensus that one of the more probable consequences of impending global climate changes will be a general slowing of the equatorial Pacific Walker Circulation and a consequent weakening of the Pacific trade wind system. Since the upwelling-favorable winds off Peru tend to flow directly into the Pacific southeast trade winds, a question arises as to the likely effect on the upwelling-producing winds that power the productivity of the regional coastal ecosystems of the Peru–Humboldt Current zone. It is argued that the effects will in fact be decoupled to the extent that upwelling-favorable winds will actually tend to increase off Peru. Data demonstrative of this decoupling are presented. A tendency for less intense El Niño episodes in the future is also suggested. These conclusions provide a framework for posing certain imponderables as to the future character of the Peruvian marine ecosystem and of the fisheries it supports.     

The differences between a wing and a planing plate in two-dimensional flow

The normal force coefficient on a flat planing surface having arbitrary heave and pitch motion in two-dimensional flow is compared with the lift coefficient of a thin wing in an infinite fluid. Despite the totally different derivations, they are found to be identical (at large Froude numbers and low trim angles and allowing for the wing's interaction with twice as much fluid) at low reduced frequencies. For higher frequency motions, the wing's angle of attack induced lift and its pitch and heave damping are less than those of a planing surface, but the acceleration terms remain identical. The differences at the higher reduced frequencies are due to the fact that, in invisad irrotational flow, the planning plate cannot leave a vortex wake, whereas a wing does.It seems to follow that the “virtual mass” planing hull analysis can be applied to “quasi-static” problems involving wings and bodies in an infinite fluid without the slenderness restriction originally imposed by Jones (1946). Certainly, it is remarkable that the so called “quasi-steady” forces on a two-dimensional wing can be obtained in a few lines of elementary analysis. On the other hand, the method fails entirely when used to compute the pitching moment on a two-dimensional plate, even though it has been found to give good results for the three-dimensional case (Payne, 1981c).This work is offered as a very incomplete study of an intriguing relationship between two very different bodies of analysis. Much more work will need to be done before the relationship between the two approaches will be fully understood.     

The discrete methods for free vibration analyses of an immersed beam carrying an eccentric tip mass with rotary inertia

In this paper, a beam without contact with water is called the “dry” beam and the one in contact with water is called the “wet” beam. For a partially (or completely) immersed uniform beam carrying an eccentric tip mass possessing rotary inertia, the conventional analytical (closed-form) solution is achieved by considering the inertial forces and moments of the tip mass and rotary inertia as the boundary conditions at the tip end of the beam. However, it has been found that the approximate solution for the last problem may be achieved by two techniques: Method 1 and Method 2. In Method 1, the basic concept is the same as the conventional analytical method; but in Method 2, the tip end of the beam is considered as a free end, while the inertial forces and moments induced by the tip mass and rotary inertia are considered as the external loads applied at the tip end of the beam. The main differences between the formulation of Method 1 and that of Method 2 are: In Method 1, the “normal” shapes of the “dry” beam are functions of the frequency-dependent boundary conditions but the external loads at the tip end are equal to zero; On the contrary, in Method 2, the “normal” mode shapes of the “dry” beam are determined based on the zero boundary conditions at the tip end of the beam but the external loads at the tip end due to the inertial effects of the tip mass and rotary inertia must be taken into consideration for the free vibration analysis of the “wet” beam. Numerical results reveal that the approximate solution obtained from Method 2 are very close to that from Method 1 if the tip mass moment of inertia is negligible. Besides, the two approximate solutions are also very close to the associated analytical (closed-form) solution or the finite element solution. In general, it is hoped that there exist several methods for tackling the same problem so that one may have more choices to incorporate with the specified cases. It is believed that the two approximate methods presented in this paper will be significant from this point of view.     

Beyond fisheries management: The Phronetic dimension

This paper has two main sources of inspiration. Firstly, building on Flyvbjerg's “Making Social Science Matter”[Flyvbjerg B. Making social science matter: why social inquiry fails and how it can succeed again. Cambridge: Cambridge University Press; 2003], I argue that the contribution of the social sciences to fisheries resource management must essentially be “phronetic” (after Aristotle's phronesis, i.e. practical wisdom), in contrast to the “scientific” (Aristotle: episteme) contribution of the natural sciences. Secondly, inspired by the recent publication “Fish for Life: Interactive Governance for Fisheries” [Kooiman J, Jentoft S, Pullin R, Bavinck M, editors. Fish for life: interactive governance for fisheries. Amsterdam: Amsterdam University Press; 2005], I hold that phronesis is basically what the notion of governance adds to management. Governance is the broader concept, inviting a more reflexive, deliberative and value-rational methodology than the instrumental, means-end oriented management concept. I claim that for interdisciplinarity to work in fisheries it is essential to recognize the fundamental methodological differences that exist between the social and natural sciences.     

Biological interactions between microorganisms in the sea

Marine ecosystems, like terrestrial biological communities, are generally considered to depend, regarding their structure and functioning, upon the trophic and sexual relationships between organisms, either “horizontally”, between individuals at the same level, or “vertically”, all the way down the various levels of the food chains. Nevertheless, the functioning of biosystems is mostly governed by their structure, i.e., the qualitative and quantitative distribution of individuals within biocenoses, as well as the relationships with one another and with the environment. Therefore, it is vital to get to know how these connections work in order to outline the main causes of microbiological equilibrium in the sea. Actually, the major problem remains that of communication between individuals in biocenoses. This is a general problem as far as life is concerned, but it proves especially acute when it comes to microbial life because of its importance in the oceanic cycles.Data available in the literature, together with the results of our own studies in this field, led us to the assumption that some of the dissolved organic substances present in seawater might well be responsible for the control of the relationships between species. These substances would be active at various degrees of concentration, after they have been released into the medium by certain species. This theory, already adumbrated by Lucas (1938, 1947, 1955), Nigrelli (1958) and Fontaine (1970) concerning direct relationships between marine species or groups of organisms, was resumed and generalized by M. Aubert (1971) who called these substances “telemediators”.Such chemical communication plays a major role in a variety of fields including sexual behaviour, nutrition and predation, as well as defense mechanisms, mobility and migration.Remote connection of two organisms through a chemical mediation involves a sequence of actions and reactions which raises a number of problems of biochemical microecology. The organism that produces the telemediator must synthesize it — either spontaneously or in an induced way — and release it into the medium, during its active growth or after cell lysis. Next, the mediator is conveyed to the remote receiving organism, which it should reach without being degraded or chemically modified (or after such a modification. Its concentration must remain equal to or higher than its activity threshold. The receptor detects it, with or without absorption, and reacts by modifying its own metabolism or behaviour. This may go as far as causing the receptor the receptor to die. In even more complex situations, another mediator will be synthesized and released into the medium.Theoretical as it may be, such a pattern is a useful guide to explain the microbial interactions in a marine environment. It involves a number of complex microecological phenomena, some phases of which begin to be known. One specific problem is chemoreception in microorganisms, hence chemotaxis. Telemediator activity threshold and turnover in the natural environment must also be investigated.One should also take account of the physical context in which the phenomena take place. For instance, it is a known fact that an important fraction of the bacterial flora in the sea is adsorbed on solid or particulate substrates. Thus, the relationships with which they are concerned are much more probable in a sphere of a few fractions of a millimeter: this emphasizes the significance of the biochemical processes which cause the microorganisms to colonize substrates and to compete with one another in so doing. Another point of interest is how they modify the substrate until they are replaced by higher organisms.In the microbial field, communication between species has been described at various levels. Horizontally, it can take place between different bacteria or between various species of algae. Vertically, it may involve bacteria and planktonic algae, bacteria and protozoa, or algae and zooplanktonic organisms.Besides, the communication may be “positive”, if the mediator enhances the growth of the receiving organism — then, it is used as a source of carbon or nitrogen, or as a growth factor — or “negative” whenever the mediator is toxic (antibiotic, antiseptic or toxin) or induces a lethal metabolic modification in the receiver.In fact, there are various telemediation mechanisms, which correspond to increasing degrees of complexity in the biological systems: a primary mechanism, in which the mediator is synthetized by a species and controls (or modifies) the metabolism of another species in one step, and a secondary mechanism, where the mediator is synthetized by a species, and modifies the metabolism of another species; the latter, in turn, releases a primary mediator which controls the functions of a third species. This might be a longer sequence, involving a higher number of species.If the mechanism becomes cyclic, feedback may occur: as far as we know, such feedback may be either positive or negative ecologically, depending on whether it speeds up or slows down a biological process.A conception of a marine universe whose equilibrium would be controlled by the interaction of organisms within a more or less dense biotic network, with meshes made up of the relationship functions as a whole, is highly suggestive of an homology with cybernetic structures. Then, each marine organism can be considered as a separate functional unit characterized by some particular properties, its functions, which govern its activity. These units are involved in the functioning of complex and varying systems in which they intervene locally to channel up the flow of energy and matter to a given extent and in a given direction.The analogy is still more pronounced as there are feedbacks, which can control various sectors of the system. In a series of studies based on biological systems regulated by various chemical mediators, authors were able to demonstrate that the introduction of varied chemical pollutants into the marine environment entails modifications in the structure of the biological components of seawater and results in either the modification or the destruction of the mediating metabolites or “signals”. The result could be a more or less pronounced ecological drift, that varies according to the activity of the pollutant.     

The PAH composition of surface sediments from Stagnone coastal lagoon, Marsala (Italy)

This paper examines the presence, distribution, nature and sources of 22 Aromatic Hydrocarbons (PAHs), which are important environmentally and toxicologically, in sediments from the Stagnone coastal lagoon at Marsala (Italy). Analysis was performed by gas chromatography/mass spectrometry (GC/MS) with selected ion monitoring (SIM). The total concentration of polycyclic aromatic hydrocarbons ranged from 72 to 18381 μg/kg of dry matrix. The relative standard deviation (RSD) of the replicates on the concentrations of individual compounds ranged from 5% to 20%. The accuracy of method was estimated by analyzing “blank” samples added of known quantities of analytes and the recover percentage was 88 ± 9%. The detection limit (LOD) of analytical procedure was less than 0.2 μg/kg d.w. for all analytes. The quantification limit (LOQ) of analytical procedure was less than 0.7 μg/kg d.w.The resulting distributions and weight ratios of specific compounds are discussed in terms of sampling location and origin of organic matter. A comparison with other studies of total PAHs suggests that the levels are within the concentration ranges already reported by other authors. From an eco-toxicological point of view, total PAH concentrations at seven out of the eight sites studied represent a relatively clean environment when compared to other sites.Organic matter content and PAH concentrations were found to be correlated and the compounds present in Stagnone sediments were shown to be mainly of pyrolitic origin, while a negligible quantity of PAHs may derive from biogenic sources since all the sediments contain perylene traces. There is no evidence of coal-tar contamination.Cluster analysis was carried out in order to discriminate between different PAH origins.     

An experimental method for determining the frequency-dependent added mass and added mass moment of inertia for a floating body in heave and pitch motions

Most of the existing relevant materials have been obtained from experiments, in which evaluating the added mass at the resonant frequency corresponding to the peak of a frequency-response curve obtained from the “forced” vibration analysis is the most popular technique. In this paper, a simple experimental method was presented where the “free” vibration responses instead of the “forced” ones were used to determine the values of m_ah and I_ap. The main part of the experimental system is composed of a floating body (model) and a spring–shaft shaker. The “free” vibration of this main part was induced by imposing on it an initial displacement (and/or an initial velocity), and from the time histories of displacements information such as the “damped” natural frequencies, damping ratios, sectional added mass coefficients (C_V and C_P) were obtained. Since the displacements of the spring–shaft shaker are “translational” and those of the floating body due to pitch motions are “angular”, a technique for the transformation between the associated parameters of the two components of the main part was presented.     

Planing and impacting plate forces at large trim angles

Added mass theory has been shown to give excellent agreement with experimental measurements on planing surfaces at normal planing angles [e.g. Payne, P.R. (1982, Ocean Engng9, 515–545; 1988, Design of High-Speed Boats, Volume 1: Planning. Fishergate. Inc., Annapolis, Maryland)] and to agree exactly with more complex conformal transformations where such a comparison is possible. But at large trim angles, it predicts non-transient pressures that are greater than the free-stream dynamic pressure and so cannot be correct. In this paper, I suggest that the reason is because, unlike a body or a wing in an infinite fluid, a planing plate only has fluid on one side—the “high pressure” side. So the fluid in contact with the plate travels more slowly as the plate trim angle (and therefore static pressure) increases. This results in lower added mass forces than Munk, M. (1924) The Aerodynamic Forces on Airship Hulls (NACA TR-184) and Jones, R. T. (1946) Properties of Low-Aspect-Ratio Pointed Wings at Speeds Below and Above the Speed of Sound (NACA TR-835) originally calculated for wings and other bodies in an infinite fluid.For simplicity of presentation, I have initially considered the example of a triangular (vertex forward) planning plate. This makes the integration of elemental force very simple and so the various points are made without much trouble. But the penalty is that there seem to be no experimental data for such a configuration; at least none that I have been able to discover. But at least the equations obtained in the limits of zero and infinite aspect ratio, small trim angles (τ) and τ = 90° all agree with established concepts and the variation of normal force with trim angle looks like what we would expect from our knowledge of how delta wings behave in air.I then employed the new equation to calculate the force on a rectangular planing surface at a trim angle τ, having a constant horizontal velocity u_o and a vertical impact velocity of ż. This happens to have been explored experimentally by Smiley, R. F. [(1951) An Experimental Study of Water Pressure-Distributions During Landings and Planing of a Heavily Loaded Rectangular Flat Plate Model (NACA TM 2453)] up to trim angles of τ = 45°, and so a comparison between theory and experiment is possible. The results of this comparison are encouraging, as is also a comparison with the large trim angle planing plate measurements of Shuford, C. L. [(1958) A Theoretical and Experimental Study of Planing Surfaces Including Effects of Cross Section and Plan Form (NACA Report)].As two practical applications, I first employed the new equations to calculate the “design pressures” needed to size the plating of a transom bow on a high-speed “Wavestrider” hull. The resulting pressures were significantly different to those obtained using semi-empirical design rules in the literature. Then I used the theory to critically review data obtained from tank tests of a SES bow section during water impact to identify how the “real world” of resilient deck plating diverged from the “model world” of extreme structural rigidity.     

Forced vibration analysis of an offshore tower carrying an eccentric tip mass with rotary inertia due to support excitation

Dynamic responses of structures due to earthquake excitation are the important problems in engineering, thus, the information concerned is plenty. However, most of the literature is relating to the discrete methods, particularly to the finite element method (FEM), and the one relating to the method combining both the “continuous” and “discrete” models is rare. The objective of this paper is to provide some information in this respect. First, the analytical solution for the natural frequencies and normal mode shapes of a “continuous” tower, without contacting water (or “dry” tower), carrying an eccentric tip mass possessing rotary inertia is determined. Next, the partial differential equation of motion for the forced vibration of the tower, contacting water (or “wet” tower), subjected to support excitation is transformed into a matrix equation by using the last natural frequencies and normal modes shape of the freely vibrating dry tower. Finally, the numerical integration method is used to solve the matrix equation to yield the seismic response of the wet tower. In theory, the mode superposition method is correct only if the total number of modes considered approaches infinity, however, numerical results of this paper reveal that superposition of only the lowest six modes will yield excellent results to be very close to the corresponding ones obtained from the conventional FEM. For this reason, the CPU time required by the presented approach is less than 5% of that required by the conventional FEM.     

Study on the dynamic characteristic of a U-type tuned liquid damper

By means of Lagrange's equation, the “coupled” equations of motion for a horizontal plate carrying a U-type tuned liquid damper (TLD) are derived. The “uncoupled” equations of motion for the liquid (in the TLD) and the structural system are then obtained by decoupling the “coupled” ones. Unlike the existing literature to indirectly determine the natural frequencies of a damped vibrating system by using the resonant method, the “complex” eigenvalues of the coupled damped system are obtained directly from the associated eigenvalue equations. Besides, the pressure intensities in the two air chambers and the sizes of the two vertical tanks together with the horizontal conduit are arbitrary in the formulation of this paper. The influence of some key parameters of the TLD on the dynamic responses of the structural system is studied.     

Analytical intercomparison results from the 1990 Intergovernmental Oceanographic Commission open-ocean baseline survey for trace metals: Atlantic Ocean

“Dissolved” (< 0.4 μm filtered) and “total dissolvable” (unfiltered) trace element samples were collected using “clean” sampling techniques from four vertical profiles in the eastern Atlantic Ocean on the first IOC Trace Metals Baseline expedition. The analytical results obtained by 9 participating laboratories for Mn, Fe, Co, Ni, Cu, Zn, Cd, Pb, and Se on samples from station 4 in the northeast Atlantic have been evaluated with respect to accuracy and precision (intercomparability). The data variability among the reporting laboratories was expressed as 2 × SD for a given element and depth, and was comparable to the 95% confidence interval reported for the NASS seawater reference standards (representing analytical variability only). The discrepancies between reporting laboratories appear to be due to inaccuracies in standardization (analytical calibration), blank correction, and/or extraction efficiency corrections.Several of the sampling bottles used at this station were not adequately pre-cleaned (anomalous Pb results). The sample filtration process did not appear to have been a source of contamination for either dissolved or particulate trace elements. The trace metal profiles agree in general with previously reported profiles from the Atlantic Ocean. We conclude that the sampling and analytical methods we have employed for this effort, while still in need of improvement, are sufficient for obtaining accurate concentration data on most trace metals in the major water masses of the oceans, and to enable some evaluation of the biogeochemical cycling of the metals.     

Hydrothermal plumes in the eastern Manus Basin, Bismarck Sea: CH4, Mn, Al and pH anomalies

We present evidence for strong hydrothermal activity in the eastern Manus Basin (depth: 1700–2100 m), the existence of large scale triple-layered buoyant plumes at depths of 1100 m (“shallow plume”), 1700 m (“deep plume”), and 1400 m (“middle plume” with less extent than the other two plumes) that were revealed from water column anomalies of CH₄, Mn, Al and pH observed in November to December 1990. Judging from the horizontal distribution of these parameters, the deep plume seems to originate from two distinct hydrothermal sites (eastern and western sites) in the research area, the eastern site being visually ascertained with deep-tow observations at the same time. The CH₄/Mn ratio (mol mol⁻¹) of the deep plume (0.02–0.05) is the lowest yet observed in hydrothermal plumes. The order of magnitude difference of CH₄/Mn ratios between the shallow plume and the deep plume suggests that different kinds of fluid-rock interaction occurred to make the hydrothermal end members for the deep and shallow plumes. The shallow plume, which had an areal extent of more than 50 km, may be an episodic “megaplume”, because it was not recognized in the previous CH₄ profiles in 1986, and because it has a similar CH₄/Mn ratio as the megaplume observed in the North Fiji Basin. We found that the eastern deep plume is characterized by enormously high aluminium concentrations (0.6– 1.5 μmol kg⁻¹), pH anomalies (0.1) and high Al/Mn ratios (10–17). The endmember fluid for the eastern deep plume may have an unusually low pH value to dissolve this much aluminum during fluid-rock interaction, or this plume may originate from an eruption-influenced fluid.     

Transient effects in wave-current boundary layer flow

Previous studies of combined wave and current bottom boundary layer flow have concentrated on the final converged state of the flow following the addition of waves to a current. While this final state is of primary interest to modellers and engineers, it pre-supposes that such a state is actually attained in reality, and this may not always be the case. In addition, it overlooks the interesting and complicated transient effects which occur as a wave-current flow evolves from one state to another. The present study concentrates attention on the transient effects predicted by a “one-equation” turbulence closure model. Results of case studies are presented in which waves are superimposed co-linearly on a current (“forward problem”), and are then removed from the converged wave-current flow (“backward problem”). Two formulations of the “forward” and “backward” problems are discussed. In the first the steady component of the pressure gradient driving the mean flow is held constant throughout, and in the second the steady component of the mass flux is held constant. In each case the detailed evolution of the profiles of mean velocity, turbulent energy, mixing length, eddy viscosity and shear stress are discussed. More generally, the question of the convergence timescale of a combined wave-current flow is considered, and a convergence criterion is proposed.     

Coastal management in Brazil – A political riddle

Brazilian legislation defines coastal zone as a national patrimony – the geographic space of interaction of air, sea and land formed by the counties directly influenced, but not necessarily by those located in the coastline; also included are those distant until 50 km from the coastline, holding activities of great impact for the coastal zone or its ecosystems. The definition includes also the territorial sea of 12 nautical miles. Coastal management is conducted by a national plan legally enforced, complemented by states and counties plans, and a coastal ecologic-economic zoning limited to small portions of the coastal zone. A resolution of the “Environmental National Council” defines as “permanent preservation areas”, of very restricted use, coastal ecosystems as mangroves, sand dunes, and reproduction sites of wild fauna. One could expect that the Brazilian coast should be more protected and properly managed than other countries where a national management plan is lacking (Argentina) or where the guidelines exist but are not yet legally enforced (South Africa). Notwithstanding, we note today in Brazil an intensification of conflicts opposing small-scale vs. industrial fishermen; shrimp farming vs. mangrove crab harvesting; resorts installation vs. native communities; oil and gas activities vs. NGOs; and conflicts on environmental permit between federal and state governmental agencies. This paper evaluates the possible reasons for the failure of the complex legal suite available in Brazil and suggests that participatory management and concerted actions with relevant stakeholders are the key elements for the successful cases.