云南省中部富碱斑岩成矿机理探讨

云南富碱斑岩由地壳深部的源岩分离熔融形成，该源岩则由早期侵入陆壳的幔源超基性岩与陆壳组分混合而成。斑岩成矿作用的成矿物质主要来源于岩浆，铅同位素资料表明它们有深部流体相、早期陆壳和幔源岩浆三种来源，但归根结底可能本区存在异常上地幔。地质地球化学综合分析认为，铜金等元素主要来源于幔源组分，铅锌等元素来源于陆壳组分，源岩重熔和岩浆演化使成矿元素得到进一步的富集。在不同的构造单元中，源岩的壳幔组分比、重熔程度等存在差异，因而富碱斑岩特征及成矿作用有别，出现两个成矿亚系列。     

哀牢山南段长安金矿床岩浆岩的岩石学特征及其与成矿关系探讨

长安大型金矿床位于哀牢山成矿带南段,矿区内出露煌斑岩、辉长岩、辉绿岩、正长花岗岩、正长花岗斑岩等岩株和岩脉,矿体均与脉岩共生或相互切穿。各类岩浆岩和矿石的地质、岩相学、岩石地球化学的系统研究表明,矿区内岩浆岩可能为同源岩浆演化产物,但煌斑岩、辉绿岩与矿化关系更为密切。金成矿物质具有壳幔混源的特点,成矿流体由岩浆水与地层变质水混合而成。在喜山期,强烈的壳幔相互作用过程导致了区内的岩浆和热液活动,大规模富碱岩浆上侵的热驱使岩浆水循环并与矿区地层在造山作用下脱水产生的富CO2的变质水混合,萃取地层及略早形成的脉岩中的Au等成矿元素,在适宜的物理化学条件下和成矿空间内卸载并富集成矿。     

新疆东准噶尔松喀尔苏铜金矿区斑岩型矿床成因研究

松喀尔苏铜金矿区位于卡拉麦里石炭纪陆相火山岩带。文章通过矿床地质、围岩蚀变、含矿斑岩、流体包裹体和同位素研究,探讨了矿床成因类型。研究表明,松喀尔苏矿床具斑岩型矿床的特征,铜金矿化体产于岩体接触带,围岩蚀变具有分带性,从岩体向围岩依次发育绢英岩化带、高岭石化带和青磐岩化带,绢英岩化带与成矿相关。含矿斑岩复式岩体系同期陆相火山活动产物,成矿作用在时间、空间和成因上与复式岩体中晚期花岗斑岩有关。花岗斑岩具有富水、富挥发性组分和岩浆爆破作用的氧化性岩浆特点,具有后碰撞花岗岩类的地球化学亲缘性,其岩浆起源于后碰撞挤压-伸展转换期的壳-幔岩浆过渡带。幔源岩浆注入、软流圈地幔底侵作用和壳-幔岩浆混合作用是形成含矿斑岩岩浆的主导因素。流体包裹体包括液相包裹体、气相包裹体和含子晶多相包裹体,激光拉曼探针分析表明,气相成分以CO₂和CH₄为主。成矿流体具有从高温、高盐度岩浆体系向低温、低盐度与大气降水混合的演化过程,流体沸腾或不混溶作用及温度、盐度降低是导致流体中成矿物质沉淀的主要因素。氢、氧同位素组成表明成矿流体以岩浆水为主,在成矿晚期混有大气降水。硫同位素具幔源硫的特征。铅同位素组成显示成矿作用起源于下地壳-上地幔过渡带的岩浆作用。综上所述,该矿床属于与陆相火山-侵入岩有关的斑岩型铜金矿床。     

大兴安岭南段敖仑花斑岩钼(铜)矿床成矿流体来源与成矿作用:稳定同位素C、H、O、S和放射性Pb同位素约束

基于稳定同位素C、H、O、S和放射性Pb同位素的测试和分析,对大兴安岭南段敖仑花斑岩钼(铜)矿床成矿流体的来源进行了示踪,探讨了流体演化与成矿作用过程。新的稳定同位素数据显示:敖仑花矿床成矿热液具有混合来源性质;脉石矿物石英中流体的C、H、O同位素和矿石硫化物的S同位素组成指示成矿络合剂主要来自地幔,同时在热液期经历了地壳流体参与的过程;辉钼矿中放射性成因的Pb同位素组成表明,成矿物质(Mo)主要来自造山带物质,部分来自深部幔源。根据H、O同位素组成变化和已有流体包裹体资料,认为敖仑花矿床早、中阶段两次矿化的成矿机制不同:早阶段金属矿化主要与岩浆水和大气降水的流体混合有关,而中阶段大规模成矿作用主要是由流体沸腾所致。综合区域地质演化认为:敖仑花矿床是大兴安岭南段在晚侏罗世—早白垩世时期演化为弧后伸展背景、陆内造山带物质重新活化、壳幔岩浆-热液相互作用的产物,同时暗示壳幔作用强烈的地区利于内生金属矿床成矿。     

西天山喇嘛苏铜矿成矿斑岩的岩石学、地球化学特征及成因探讨

位于西天山别珍套-科古琴晚古生代岛弧西段的喇嘛苏铜矿床是区内最大的铜矿床,与成矿作用有着密切关系的斑岩体为英云闪长斑岩、花岗闪长斑岩,是同源岩浆分异演化的产物,且花岗闪长斑岩可能属于岩浆演化晚期的产物。本区成矿斑岩的主量、微量元素和Sr-Nd同位素地球化学特征表明,其富集大离子亲石元素,而相对亏损高场强元素,出现了较为明显的Ta、Nb负异常,初始锶同位素ISr和εNd(t=390Ma)值分别为0.7072～0.7076和-0.32～0.17,显示壳幔混合源的特征,利用Sr和Nd同位素估算其源区物质约有50%来源于地壳。岩石地球化学特征指示了其为典型钙碱性火山弧花岗岩,暗示其形成于大陆弧环境。结合区域地质背景,推测本区成矿斑岩是在洋壳俯冲作用下发生部分熔融,交代原先的地幔楔,并混合了部分下地壳的物质,经历分离结晶作用的产物,其形成可能与晚古生代准噶尔洋板块向南的俯冲作用有关。结合东西天山的成矿斑岩的地球化学特征对比研究,岩浆源区的差别可能导致不同类型斑岩型矿床的形成,斑岩型铜矿床的形成较斑岩型钼矿床可能有更少的地壳物质贡献。     

澜沧老厂多金属矿床叠加成矿系统稳定同位素对比研究

云南澜沧老厂多金属矿床是"三江"成矿带南段重要的多金属矿床之一,属于多种构造环境演变过程中形成的火山喷流沉积+隐伏斑岩热液成因为主的矿床,多因复成矿特征典型。本文在对不同成矿系统典型矿物/岩石开展S、Pb、H、O、Sm-Nd、Rb-Sr同位素分析研究的基础上,对比了不同成矿系统在矿床地球化学特征上的异同。研究表明,两个成矿系统的成矿物质来源既有继承性,又有新生性,多源特征明显。其中,火山喷流沉积成矿系统的S主要来源于火山热液,Pb主要来源于古陆壳基底和火山岩,成矿流体主要为海水与岩浆水的混合。斑岩型矿石矿物的S、Pb同位素组成也具壳幔混合源的特征,金属成矿物质来源主要与岩浆有关,成矿流体主要来源于岩浆水及大气降水,晚期成矿流体向大气降水漂移的特征相对明显。斑岩热液成矿系统中花岗斑岩的~(87)Sr/~(86)Sr比值介于地壳与地幔岩石平均值之间,Sm-Nd同位素数据接近EMⅡ地幔端员,指示岩浆源区处于壳-幔组分过渡区。     

大青山地区中生代玄武质火山岩岩石地球化学特征

对满洲里地区大青山盆地中生代玄武质火山岩类地球化学特征进行讨论,结合野外观察和前人资料,对其岩浆演化、成因及成岩构造环境进行探讨,为下一步工作提供依据。分析可知,该区玄武质火山岩类岩浆源于富集不相容元素的富集地幔,后有壳源物质参与,是岩石圈伸展背景下早期流体交代岩石圈地幔发生部分熔融的产物。通过火山岩地球化学特征分析以及和邻区产铀火山岩特征类比可知,本区具备较好的火山热液型铀及多金属成矿的构造环境及火山岩浆演化系列。     

胶东金矿床碳酸盐矿物的碳-氧和锶-钕同位素地球化学研究

对胶东四类金矿床(盆地边缘砾岩型、斑岩型-浅成热液型、石英脉型和破碎带蚀变岩型)矿石中的碳酸盐矿物开展了系统的碳-氧同位素和锶-钕同位素地球化学研究。研究结果表明，与宏观的成矿地质条件和矿床地质特征相对应，山东金矿床可能有亲岩浆岩和亲沉积盆地两个不同的成矿系统。前者包括斑岩型-浅成热液型、石英脉型和破碎带蚀变岩型三类金矿床，后者指盆地边缘砾岩型金矿床，二者具有不同的碳-氧和锶-钕同位素地球化学特征。山东亲岩浆岩系列的金矿床，其锶-钕同位素与同时代的幔源岩浆岩一致，碳同位素显示幔源碳和岩浆碳的特征，氧同位素则显示初生水与大气降水不同比例混合的可能性，因此有可能是以CO2为主、富合成矿金属的地幔流体与浅部下渗大气降水相互作用的结果。而与岩浆岩关系不密切、主要受盆地边缘断裂控制的盆地边缘砾岩型金矿床，其碳-氧和锶-钕同位素组成均较分散，可能主要与地壳浅部下渗大气降水对上地壳各种岩石淋滤萃取演化而成的成矿流体有关。     

东昆仑祁漫塔格早中生代大陆地壳增生过程中的岩浆活动与成矿作用

东昆仑祁漫塔格地区位于青藏高原北缘,为典型的大陆边缘增生造山带,经历了漫长的古生代—早中生代增生造山过程,其中以早中生代岩浆活动与成矿作用最为发育。文章系统总结了区内早中生代侵入岩分布及成因,对与其相关矿床地质、成矿流体特征及成矿物质来源进行分析,进一步探讨了祁漫塔格地区早中生代大陆地壳增生过程中的壳幔混合岩浆活动与成矿作用的关联。研究结果认为,中二叠世—早三叠世以俯冲阶段的侧向增生为主,中-晚三叠世以碰撞-后碰撞阶段的垂向增生为主,与成矿有关的岩浆岩主要为中-晚三叠世石英闪长岩、花岗闪长岩、二长花岗岩、正长花岗岩、花岗斑岩等,以I型、A型花岗岩为主,且多见暗色包体,Sr-Nd-Hf同位素组成表明其源于古陆壳物质的重熔,有地幔物质的参与,由地幔底侵古老陆壳,幔源基性岩浆与壳源花岗质岩浆发生不同程度混合作用而形成。与该时期岩浆活动关系密切的主要为斑岩型铜钼矿床、矽卡岩型铁多金属矿床、层控矽卡岩型铅锌矿床、与碱性花岗岩有关稀有金属矿化等。成矿时代集中于248~210 Ma,成矿流体主要来源于岩浆热液,成矿物质具有壳幔混合来源,区内中-晚三叠世大陆垂向增生过程中的壳-幔岩浆混合作用为区域大规模金属成矿提供大量热能、成矿流体及成矿物质。     

浙闽相邻区白垩纪上下火山岩系成因与壳幔作用对比研究

浙闽相邻区广泛出露的白垩纪火山岩划分为上下火山岩系。下火山岩系为大面积展布的早白垩世早期长英质火山岩,属弱过铝质高钾钙碱性系列,富集大离子亲石元素Cs、Rb、Ba、Pb等和LREE,无明显Eu异常,亏损高场强元素Nb、Ta、Ti、P等,εHf(t)值较低(-20.43~-6.39),锆石Hf同位素二阶段模式年龄TDM2集中在1.8~2.2Ga之间。上火山岩系为局限于断陷盆地内的早白垩世晚期长英质火山岩,属偏铝质高钾钙碱性系列,相对贫硅贫碱但同样富集LREE和大离子亲石元素,负Eu异常明显,εHf(t)值较高(-10.00~-4.51)。研究表明,上下火山岩系均表现出随时代变新ΣREE和LREE分异程度降低的趋势,均形成于活动大陆边缘环境,主要为幔源岩浆底侵导致古元古代陆壳基底部分熔融形成的低Sr流纹岩类,但上火山岩系成岩过程中经历了更强烈的壳幔作用;例外的是下火山岩系西山头组上部熔岩,属东南沿海罕见的橄榄玄粗岩系列高Sr粗面英安岩,以富集Sr、Ti、Co、Ni和低的εHf(t)为特征,推断由幔源基性岩浆结晶分异形成。区域晚中生代火山岩的综合对比表明,东南沿海深部壳幔作用具有从中—晚侏罗世到早白垩世晚期逐渐增强、自南往北依次减弱的时空演化规律。     

The terrestrial fauna of the Late Triassic Pant-y-ffynnon Quarry fissures,South Wales,UK and a new species of Clevosaurus (Lepidosauria: Rhynchocephalia)

Pant-y-ffynnon Quarry in South Wales yielded a rich cache of fossils in the early 1950s, including articulated specimens of new species (the small sauropodomorph dinosaur Pantydraco caducus and the crocodylomorph Terrestrisuchus gracilis), but no substantial study of the wider fauna of the Pant-y-ffynnon fissure systems has been published. Here, our overview of existing specimens, a few described but mostly undescribed, as well as freshly processed material, provides a comprehensive picture of the Pant-y-ffynnon palaeo-island of the Late Triassic. This was an island with a relatively impoverished fauna dominated by small clevosaurs (rhynchocephalians), including a new species, Clevosaurus cambrica, described here from a partially articulated specimen and isolated bones. The new species has a dental morphology that is intermediate between the Late Triassic Clevosaurus hudsoni, from Cromhall Quarry to the east, and the younger C. convallis from Pant Quarry to the west, suggesting adaptive radiation of clevosaurs in the palaeo-archipelago. The larger reptiles on the palaeo-island do not exceed 1.5?m in length, including a small carnivorous crocodylomorph, Terrestrisuchus, and a possible example of insular dwarfism in the basal dinosaur Pantydraco.     

The effect of water on accessory phase solubility in subaluminous and peralkaline granitic melts

The solubilities of columbite, tantalite, wolframite, rutile, zircon and hafnon were determined as a function of the water contents in peralkaline and subaluminous granite melts. All experiments were conducted at 1035 °C and 2 kbar and the water contents of the melts ranged from nominally dry to approximately 6 wt.% H₂O. Accessory phase solubilities are not affected by the water content of the peralkaline melt. By contrast, solubilities are affected by the water content of the subaluminous melt, where the solubilities of all the accessory phases examined increase with the water content of the melt, up to 2 wt.% H₂O. At higher water contents, solubilities are nearly constant. It can be concluded that water is not an important control of accessory phase solubility, although the water content will affect diffusivities of components in the melt, thus whether or not accessory phases will be present as restite material. The solubility behaviour in the subaluminous and peralkaline melts supports previous spectroscopic studies, which have observed differences in the coordination of high field strength elements in dry vs. wet subaluminous granitic glasses, but not for peralkaline granitic glasses. Lastly, the fact that wolframite solubility increases with increasing water content in the subaluminous melt suggests that tungsten dissolved as a hexavalent species.     

Quaternary stresses revealed by calcite twinning inversion: insights from observations in the Savonnières underground quarry (eastern France)

Calcite samples were extracted both from the rock matrix and the superficial coating of a karstified fault plane of an underground quarry, located in the eastern border of the Paris basin. The karstification is dated as Quaternary. Analysis of mechanical calcite twinning reveals that only the calcite matrix has also undergone a compression trending WNW that can be attributed to the Mio-Pliocene alpine collision. Both coating and matrix have undergone a strike-slip regime with σ₁ roughly trending north–south, that could correspond to the regional present-day state of stress, a strike-slip compression rather trending NNW, modified by local phenomena. To cite this article: M. Rocher et al., C. R. Geoscience 335 (2003).     

HYDROGEOLOGY

正20141756 Chen Ruige(Mathematical College,China University of Geosciences,Beijing100083,China);Zhou Xun Numerical Simulation of Groundwater Level Fluctuation in a Coastal Confined Aquifer with Sloping Initial Groundwater Level Induced by the Tide(Geological Bulletin of China,ISSN1671-2552,CN11-4648/P,32(7),2013,p.1099-1104,6 illus.,16 refs.) Key words:confined water,groundwater level     

METAMORPHIC PETROLOGY

正20141408 Cai Jia(Institute of Geology,Chinese Academy of Geological Sciences,Beijing100037,China);Liu Fulai Petrogenesis and Metamorphic P-T Conditions of Garnet-Spinel-Biotitebearing Paragneiss in Danangou Area,Daqingshan-Wulashan Metamorphic Complex Belt(Acta Petrologica Sinica,ISSN1000-0569,CN11-1922/P,29(7),     

SERIALS

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GEOPHYSICAL EXPLORATION

正20142386An Guoying(China Aero Geophysical Survey and Remote Sensing Center for Land and Resources,Beijing 100083,China)Application of Satellite Remote Sensing in Regional Hydrogeological Investigation:Taking Cenozoic Strata in Wenquan Sheet(1∶250 000)of Karakoram Range as an Example(Geosci-     

QUATERNARY GEOLOGY & GEOMORPHOLOGY

正20141016An Chengbang(Key Laboratory of Western China’s Environmental Systems,Ministry of Education,Lanzhou University,Lanzhou 730000,China);Zhao Yongtao Lake Records during the Last Glacial Maximum from Xinjiang,NW China and Their Climatic Impli-     

PETROLEUM GEOLOGY

正20141538 Cao Qing(School of Earth Sciences and Engineering,Xi’an Petroleum University,Xi’an 710065,China);Zhao Jingzhou Characteristics and Significance of Fluid Inclusions from Majiagou Formation,Yichuan Huangling Area,Ordos Basin(Advances in Earth Science,ISSN1001-8166,CN62-1091/P,28(7),2013,p.819-828,7 illus.,3 tables,43 refs.)     

GEOCHEMISTRY

正20142002 Wei Hualing(Institute of Geophysical and Geochemical Exploration,Chinese Academy of Geological Sciences,Langfang065000,China);Zhou Guohua Element Content and Mineral Compositions in Different Sizes of Soil in Tongling Area,Anhui Province(Geological Bulletin of China,ISSN1671-2552,CN11-4648/P,32(11),2013,p.1861