塔里木板块北缘活动陆缘型侵入岩带的岩石学与地球化学

在塔里木板块北缘,断续出露一条侵入岩带,总长度800多公里。岩石组合是橄榄辉长岩-辉长岩-辉长闪长岩-闪长岩-石英闪长岩-花岗岩。各种类型岩石的化学组成显示了清晰的钙碱性岩浆演化趋势。稀土元素配分曲线均为轻稀土富集型,而且,重稀土元素配分曲线相对平坦。Sr、K、Rb、Ba、Th等大离子亲石元素强烈富集,而Ta、Nb、Zr、Hf、Ti等高场强元素显著贫化。这些岩石学与地球化学特征均证明,该侵入岩带形成于活动大陆边缘。     

内蒙古朱日和地区早古生代岩浆岩年代学、地球化学特征及其构造意义

中亚造山带早古生代的构造演化一直存在不同的认识,特别是其俯冲转为碰撞的时限.内蒙古朱日和南部的额尔登陶勒盖地区出露的早古生代岩浆岩,对于限定白乃庙岛弧的延伸方向、岛弧演化和拼贴时间具有重要意义.对额尔登地区出露的火山岩和侵入岩进行了精确的锆石SHRIMP和LA-ICP-MS U-Pb定年、锆石Lu-Hf同位素和地球化学分析以确定其时代和成因.研究获得4个岩浆岩年龄,1件英安岩年龄为434.0±4.4 Ma,2件花岗岩年龄分别为432.8±2.6 Ma和428.1±1.8 Ma,此3件样品形成于早中志留世;另有1件流纹岩年龄为411.8±1.0 Ma,形成于早泥盆世.早中志留世侵入岩为低钾、过铝质钙碱性中酸性岩石,富集Rb、Th,弱富集Zr、Hf,明显亏损Nb、Ta、P、Ti.在稀土配分曲线上,侵入岩均不存在Eu的负异常.其中2件花岗岩样品的锆石基本为正ε_Hf（t）值（-1.19~11.51,3.32~10.28）,T_DM2为684~1 493 Ma及759~1 202 Ma,主要来自新生地壳;早中志留世火山岩具有中-低钾、偏铝质-过铝质、钙碱性酸性岩石特征,富集Rb、Th,弱富集Zr、Hf,明显亏损Nb、Ta、P、Ti.在稀土配分曲线上,多数火山岩不存在Eu负异常.英安岩中的锆石具有正ε_Hf（t）值（3.70~7.94）,T_DM2为912~1 183 Ma,主要来自新生地壳;而早泥盆世流纹岩（411 Ma）存在明显的Eu负异常,其锆石具有负ε_Hf（t）值（-14.95~-7.07）,T_DM2为1.8~2.3 Ga,应为古老地壳再循环的产物,与早中志留世岩浆岩源区明显不同,可能代表构造环境的转变.综合区域地质和前人研究资料表明,早志留世英安岩和花岗岩形成于俯冲岛弧环境,白乃庙岛弧向东可延伸至本区,而早泥盆世流纹岩可能形成于后碰撞环境.      

天山中西段古生代花岗岩TIMS法锆石U-Pb同位素定年及岩石地球化学特征研究

通过对天山中西段古生代花岗岩的锆石TIMS法U-Pb同位素定年,表明中天山托克逊南—库米什北侵入于奥陶纪可可乃克群中的碱长花岗岩形成时代为395.1±0.9Ma,花岗闪长岩体形成于393.5±2.7Ma,石英闪长岩体形成于327.3±0.9Ma,斜长花岗岩体形成时代为424.1±1.1Ma,并揭示出中天山中段库米什地区的3期构造岩浆事件,分别相当于早志留世、中泥盆世和早石炭世。中天山哈希勒根大坂黑云母花岗岩形成于286.8±0.8Ma。对伊犁石炭—二叠纪裂谷带中花岗侵入岩类的锆石TIMS法U-Pb同位素定年,表明霍城果子沟角闪花岗岩形成于351.9±1.6Ma,昭苏煤矿花岗闪长岩体形成时代为348.4±0.8Ma,新源则克台角闪辉长岩体形成于308.2±1.2Ma。南天山巴音布鲁克地区侵入于巴音布鲁克群中的石英闪长岩体形成时代为446.8±1.2Ma,独—库公路南段库尔干道班14.6km和15.2km处的角闪斜长花岗岩体与黑云母花岗岩体分别形成于426.3±1.9Ma和425.1±1.8Ma。对花岗岩的岩石地球化学研究表明,中天山托克逊南—库米什北志留纪—早泥盆世花岗岩为钙碱系列,轻稀土富集,微量元素洋脊花岗岩标准化具有Rb、Th、Ba富集,Ta、Nb亏损的分配型式,形成于火山弧环境;石炭—二叠纪花岗岩为钙碱系列,准铝—过铝质花岗岩,轻稀土富集程度较前者低,微量元素洋脊花岗岩标准化具有Rb、Th富集,Ba略亏损和高场强元素亏损的特点,形成于后碰撞(post-collision)构造环境。伊犁石炭—二叠纪裂谷带中石炭—二叠纪花岗岩为过铝质花岗岩,轻稀土富集,微量元素洋脊花岗岩标准化分配型式同样具有Rb、Th富集,Ba明显亏损和高场强元素亏损的特点,亦形成于后碰撞(post-collision)构造环境。南天山库尔干花岗岩为Al2O3含量高的钙碱性系列、过铝质花岗岩,稀土元素含量中等(157.89×10-6~81.81×10-6),轻稀土富集,Eu负异常明显,微量元素洋脊花岗岩标准化呈现出K、Rb、Th、Ba富集和Nb、Ta、Zr、Hf高场强元素亏损的特点,其形成时代与天山古生代洋盆俯冲时限相当,为岛弧构造环境。依据Sr-Nd-Pb同位素回时计算结果,本次研究所取的花岗岩初始锶同位素比值高,介于0.70435~0.70982,εNd(t)值多小于零或为很低的正值,T2DM或TDM均远大于岩体形成年龄,δ18O‰多大于10,个别为6.7,显示出古老壳源物质在花岗岩浆的形成过程中起了重要作用。同时,鉴于花岗岩的εNd(t)均在0左右变动,同样说明,新生地壳在花岗岩浆的形成过程中同样起着重要作用。花岗岩的εNd(t)值与前寒武纪岩石的εNd(t)对比研究表明,中天山库米什北志留纪斜长花岗岩体可能是中新元古界斜长角闪岩部分熔融的产物,而石炭—二叠纪花岗岩既有中新元古界片麻岩或片岩部分熔融生成,亦有新生地壳部分熔融受到古老地壳混染后岩浆结晶产物。伊犁石炭—二叠纪花岗岩和南天山库尔干志留纪花岗岩均显示出新生地壳部分熔融,并受古老地壳混染的Nd同位素信息。     

藏南拿日雍错片麻岩穹窿中新世淡色花岗岩的形成过程:变泥质岩部分熔融与分离结晶作用

拿日雍错片麻岩穹窿位于特提斯喜马拉雅带的东部,穹窿边部淡色花岗岩脉形成于21.8±0.3Ma,穹窿核部主体淡色花岗岩的结晶年龄为20.1±0.1Ma,其中1件样品记录了~17.3Ma热液蚀变事件。大部分淡色花岗岩具有以下特征:(1)较高的Si O2(72.9%),Al2O3(14.7%)和A/CNK(1.1),较低的Fe O、Mg O、Mn O和Ti O2;(2)高度变化的大离子亲石元素(如Rb、Sr、Ba)和高场强元素(如Nb、Ta、Hf、Th)和Rb/Sr、Nb/Ta、Zr/Hf比值;(3)富集轻稀土元素,亏损重稀土元素,Eu和Nd都显示负异常(Eu/Eu*0.7,Nd/Nd*=0.5~0.8);(4)Sr同位素比值变化范围较大(87Sr/86Sr(t)=0.7132~0.7330),但Nd同位素比值一致(εNd(t)=-12.4~-10.9)。这些特征表明:拿日雍错淡色花岗岩形成于20Ma,是变泥质岩部分熔融作用的产物,经历了不同程度的斜长石、锆石、独居石、磷灰石、富Ti矿物等的分离结晶作用。     

北阿尔金西段正长花岗岩和闪长岩地球化学、锆石U-Pb定年及Hf同位素特征

北阿尔金西段出露大量中酸性侵入岩,为探讨西段地区花岗质岩石的成因、形成环境以及北阿尔金地区岩浆活动特点,本文选取北阿尔金西段的正长花岗岩体和闪长岩体作为研究对象,进行了岩石学、地球化学、锆石U-Pb年代学及Hf同位素等方面的研究。研究结果表明,正长花岗岩体形成时代为495.7～502.0Ma,铝饱和指数A/CNK为0.86～1.09小于1.1,P_2O_5与Si O_2含量呈负相关,具I型花岗岩特征。轻稀土富集而重稀土亏损,具有明显的负Eu异常,微量元素特征显示富集Rb、Ba、Th、U、K等元素,相对亏损Nb、Ta、P、Ti等元素。岩石地球化学及锆石Hf同位素特征暗示其源区物质成分不均一,源岩主要为0.95～1.4Ga的新生地壳(变中基性岩),并有1.42～1.83Ga的古老地壳物质的参与。闪长岩体的侵位时代为497.1±3Ma,轻稀土富集而重稀土亏损,较弱的负Eu异常,相对富集Rb、Ba、Th、U、K等元素,而亏损Nb、Ta、P、Ti。锆石ε_(Hf)(t)值为-1.61～+2.16,二阶段模式年龄t_(DM2)为1.34～1.56Ga,暗示其源岩可能主要为新生地壳,并有古老地壳物质参与成岩。北阿尔金西段正长花岗岩、闪长岩均形成于早古生代,具弧型花岗岩特点,结合区域构造背景,认为其形成可能与北阿尔金洋壳俯冲有关,产于陆弧环境。     

东昆仑阿克楚克塞地区辉长岩地球化学特征、锆石U-Pb年龄及其构造意义

东昆仑地区基性-超基性岩石的研究较薄弱,缺乏对东昆仑幔源岩浆活动及岩浆演化的整体认识。对阿克楚克塞辉长岩进行了地球化学、锆石U-Pb年代学及Hf同位素研究,结果显示,该岩石形成于晚三叠世早期(219.3±1.1Ma,MSWD=0.80);岩石SiO2含量为49.03%~57.26%,Mg#值为49~57,属于钙碱性系列岩石;稀土元素配分曲线为轻稀土元素富集的右倾型,富集大离子亲石元素Rb、Ba、K,相对亏损高场强元素Nb、Ta、Ti;εHf(t)=-1.81~3.25,锆石Hf模式年龄大于锆石结晶年龄。地球化学特征显示,阿克楚克塞辉长岩岩浆源区应为受俯冲板片流体交代的岩石圈地幔。结合区域构造背景分析,阿克楚克塞辉长岩形成于印支期造山后伸展的构造环境,继承了早期板片俯冲改造的地幔源区特征。     

萨吾尔山松树沟地层形成时代及火山岩地球化学研究

西准噶尔松树沟地区地层主要由碎屑沉积岩和火山岩组成,以玄武岩、安山岩和火山碎屑岩为主,其中玄武岩属于钙碱性系列,安山岩属于拉斑系列。对岩石中锆石开展LA-ICP-MS锆石U-Pb年代学研究,安山岩锆石年龄表明其形成于(317.1±6.4)Ma,粗砂岩56颗锆石中仅有1颗锆石年龄((389±9)Ma)属于中泥盆世,其余主要集中在319~359 Ma,最小年龄(319±6)Ma。因此,该套地层并非形成于中泥盆世,很可能形成于晚石炭世早期。地球化学研究表明,玄武岩和安山岩具有相似的稀土配分曲线,轻稀土富集的右倾REE分配模式,富集大离子亲石元素K、Rb、Ba、Sr等,亏损高场强元素Nb、Ta、Th、Zr、Hf等,呈现出Ta、Nb、Ti负异常,认为该火山岩形成于岛弧环境,岩浆来源于俯冲板片脱水产生的流体不均一交代的地幔楔。该套岛弧火山岩的形成时代限定了斋桑洋盆的关闭时限(晚于317.1 Ma)。     

甘肃北山明舒井岩体形成年龄、地球化学特征及其地质意义

北山明舒井岩体为一由辉长岩、闪长岩和花岗岩构成的岩浆杂岩体。LA-ICP-MS锆石U-Pb定年分别获得辉长岩442.9±1.2Ma、闪长岩437.0±2.3Ma、花岗岩435.9±2.2Ma的形成年龄。其中,辉长岩为富钙、高铁和镁的钙碱性岩,相对富集LREE和LILE、贫化HFSE,亏损Nb、Ta、Ti、Zr和P,Pb正异常,具中等偏高的(87Sr/86Sr)i(0.705892)、高放射性成因Pb,低εNd(t)(0.1),锆石εHf(t)变化大(-7.1~+8.3)。闪长岩和花岗岩富钠、低钙、铁和镁,为准铝质钙碱性岩;它们富集LREE和LILE、亏损HFSE,Nb、Ta及Sr、P、Ti明显负异常;也显示中等偏高的(87Sr/86Sr)i(0.705951~0.706196)和高放射性成因Pb、低εNd(t)(-0.2~-0.1),但锆石εHf(t)明显偏正(-1.1~+12.0)。不同岩类的地球化学特征及其相对一致的Sr-Nd-Pb同位素及明显不同的锆石Hf同位素,指示它们形成于板块消减带构造环境,为源自受流体交代和陆壳物质改造的幔源岩浆与新元古代陆壳物质部分熔融的岩浆混合和分离结晶演化的产物,代表北山南部早古生代晚奥陶世-早志留世晚期与大洋俯冲消减作用有关的构造岩浆事件。     

海南岛抱伦金矿床双峰式侵入杂岩地球化学特征及对金成矿作用的启示

位于海南岛西南部的抱伦金矿产于尖峰岩体外接触带,与辉绿岩脉密切伴生,这些侵入岩蕴含了金矿成矿作用与岩浆活动-构造演化-成矿体系关系的重要信息。文章报道了对抱伦尖峰花岗岩和辉绿岩开展岩石学、锆石U-Pb年代学、元素和Sm-Nd同位素地球化学研究的成果。本次工作获得了尖峰花岗岩的LA-ICP-MS方法锆石U-Pb年龄为(234.9±2.8)Ma,与辉绿岩构成双峰式侵入杂岩组合。辉绿岩属亚碱性玄武岩系列,相对富集Th、Nb、Ta等强不相容元素,无Nb、Ta、Ti亏损,显示与富集洋中脊玄武岩(E-MORB)相似的地球化学特征,其ε_Nd(t)值为4.11,指示了亏损的源区性质;尖峰花岗岩属高钾钙碱性岩系的铝质A型花岗岩,相对富集K、Rb、Th、Ce等元素,相对亏损Sr、Ba、Nb、Ta、P、Ti等元素,其ε_Nd(t)值为-7.61～-7.80,指示了再循环地壳源区。抱伦辉绿岩为交代型地幔降压熔融的产物,而尖峰花岗岩起源于中元古界泥质和杂砂岩地壳源岩于低压、高温环境下的部分熔融,该双峰式侵入杂岩与金成矿作用形成于造山后伸展-减薄构造背景。双峰式侵入杂岩的...     

中天山卡瓦布拉克地区中-基性岩脉的年代学及岩石成因

中天山卡瓦布拉克地区侵入岩类广泛发育,并多处被中-基性岩脉穿插。LA-ICP-MS锆石U-Pb测年获得闪长岩和辉长岩脉年龄分别为296.1±2.5 Ma(MSWD=1.4),299.5±2 Ma(MSWD=1.07),均侵位于早二叠世。岩石学和岩石地球化学分析结果表明该区中-基性岩脉具有富集轻稀土元素(LREE)和大离子亲石元素(Rb,U,Th)、亏损高场强元素(Nb,Ta,Ti)的地球化学特征,SREE为69.19~234.62,LREE/HREE=3.97~11.18。闪长岩脉锆石(176Hf/177Hf)值为0.280 618~0.283 329,对应的εHf(t)值为-14.57^+25.06。研究数据表明,该区中-基性岩脉可能起源于亏损岩石圈地幔,原始岩浆在侵位过程中发生了分离结晶作用,同时还受到了地壳混染作用的影响。基于卡瓦布拉克地区中-基性岩脉的野外地质特征和地球化学分析结果,并结合区域地质资料,认为它们形成于南天山洋闭合之后的后碰撞伸展构造背景。     

Wavelength-dispersive X-ray fluorescence spectrometric determination of Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites

Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.     

硅酸盐类样品中硅、铁、铝、钛、锰、钙、镁、钾、钠和磷的x射线荧光光谱测定

本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。     

高压微波消解法测定醋酸纤维过滤器采集的微尘粒子中的砷镉钴铬铜铁锰镍铅钒锌

最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

Viscous, cohesive, non-Newtonian, depositing, radial slurry flow

Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.     

硅酸盐中铁、锰、钛、钙、钾、磷、硅、铝、镁、钠、锶、铷、钡的X-射线荧光光谱定量测定

本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。     

Mercury,arsenic, antimony,and selenium contents of sediment from the Kuskokwim River,Bethel, Alaska,USA

The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources.     

滇东南花岗岩与锡、银、铜、铅、锌多金属矿床的成因关系

滇东南锡、银、铅、锌多金属矿床主要分布在个旧、白牛厂、都龙3个矿区,而滇东南较大的3个花岗岩体又分别出露在3个矿区或附近.花岗岩体均形成于燕山晚期,岩石化学、矿物成分相似,富含锡、银、铅、锌、钨、铜等成矿元素.矿床主金属元素组合与岩体之间的距离由远而近出现由锡、钨、(铍、铌、钽)→锡、钨、(铁)、铜、铟→锡、铅、锌、银、铟、(锑)有规律的变化.花岗岩浆是成矿物质来源和成矿热源.岩浆侵入初期使上覆地层隆起产生背斜(凹陷部位成向斜);同时使地层产生一系列裂隙、压性断层或层间断裂;岩浆侵入晚期,这些断层再次活动,表现为张性,岩浆产生的含矿热液沿由其活动所造成的断裂迁移、充填、交代、沉淀而形成矿床.     

岩石密度和超高压岩石折返速率

在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。     

Bellechester,Minnesota, USA,lagoon collapses

Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×10⁶ 1 of partially treated effluent and about 600 m³ of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes.