松潘-甘孜地体内花岗岩锆石SHRIMP U-Pb定年及其构造意义

松潘-甘孜地体总体上是一个三角状褶皱带,其北侧、东南侧及东侧分别与东昆仑-西秦岭构造带、金沙江构造带及龙门山构造带相邻。地体内几乎全部被三叠系浊积岩所覆盖,其中侵位了很多花岗岩体。显然,这些花岗岩的岩浆特征、来源与侵位时代,对研究松潘-甘孜地体基底性质、构造演化等问题具有重要意义。本文报道利用SHRIMP定年技术对一些花岗岩岩体锆石所进行的精确测年数据。测试结果表明:(1)松潘-甘孜地体内的花岗岩体主要形成于晚三叠世,但岩浆活动可延续到早侏罗世晚期;(2)早期花岗岩浆活动与三叠纪系褶皱变形大致同期,指示这一时期的花岗岩浆的形成可能与三叠系下部大型拆离滑脱构造相关;(3)花岗岩结晶锆石普遍具有浑圆状或不规则状较老的继承锆石核,这些核部继承锆石可能代表花岗岩浆在上升过程中从不同地层内捕获的碎屑锆石,或者是下地壳岩石深熔残留锆石。根据SHRING U-Pb定年,这些继承锆石的年龄分别为二叠纪、加里东期、晚元古代和早元古代。元古代碎屑锆石的存在也可能指示松潘-甘孜地体具前寒武系基底。     

云南大坪金矿床赋矿闪长岩锆石SHRIMP U-Pb定年及其地质意义

云南大坪金矿床是哀牢山金矿带中最重要的金矿之一,主要赋存在受到强烈剪切和水-岩反应的闪长岩中,是典型的喜马拉雅期造山型金矿。本文对大坪金矿床赋矿闪长岩中锆石进行了SHRIMP U-Pb定年,得出闪长岩围岩的年龄为773±12Ma,为晚元古代,显示该岩体为华南地区晋宁-澄江期大规模基性到酸性岩浆活动的产物,是Rodinia 超大陆形成、裂解后冈瓦纳大陆形成过程的响应,而不是前人普遍认为的加里东期岩体。该岩体侵入年龄与大坪金矿脉石英流体包裹体⁴⁰Ar-³⁹Ar 年龄测定给出的高温坪年龄(765.5±7.0Ma)基本一致,显示大坪金矿床具有多期成矿的特征,其主体形成于喜马拉雅期碰撞造山运动,但早在晋宁造山运动中就有金的初步富集。在闪长岩中还发现了年龄为33.7±1.1Ma的锆石,其时代与大坪金矿床含金石英脉中热液绢云母的⁴⁰Ar-³⁹Ar定年结果(33.76Ma)基本一致,显示它们很可能为该区强烈的韧性剪切和局部岩浆部分熔融作用的产物。     

U-Pb SHRIMP dating of zircons from metamorphic complexes in eastern Kamchatka

The metamorphic complexes of eastern Kamchatka exposed on the Khavyven Highland and Karaginsky Island, as well as on the Kamchatka and Ozernoi peninsulas, compose large (up to 1.5 km) elongated blocks spatially associated with ophiolitic peridotite and gabbroic rock bodies (the Khavyven Highland and Karaginsky Island) or make up isolated fragments and blocks among serpentinite melange (the Ozernoi and Kamchatka peninsulas). The degree of metamorphism of the primary rocks varies from the greenschist/amphibolite boundary facies (Karaginsky Island and the Khavyven Highland) to the high-pressure amphibolite facies (the Ozernoi and Kamchatka peninsulas).     

桂东北大宁岩体锆石SHRIMP年代学和地球化学研究

大宁岩体位于扬子板块与华夏板块结合带,岩性组合为二长闪长岩-花岗闪长岩-二长花岗岩-钾长花岗岩.岩体中广泛存在壳幔混合包体.本文利用锆石sHRIMPU-Pb法,获得大宁岩体成岩年龄上限为(419.1±6.4)Ma(MSWD=1.03),属加里东晚期.岩体的地球化学研究显示,大宁岩体属弱过铝高钾钙碱性岩石,富大离子亲石元素和轻稀土,显Nb、Ba、Sr、Eu组合异常.岩石具有较高的I_(Sr)值(0.7112～0.7196),较低的εNd(t)值(-6.77～-7.53)和T_(DM)值(1.40～1.71Ga).结合邻区加里东花岗岩壳幔混合特征,本文认为,大宁岩体为幔源岩浆底侵诱发的下地壳变砂屑岩部分熔融形成,形成过程中有显著的幔源组分加入.     

激光焦平面变化对LA-ICPMS锆石U-Pb定年准确度的影响

元素分馏是影响LA-ICPMS锆石U-Pb定年准确度的重要因素之一,通常利用标样进行校正。激光聚焦位置变化会引起剥蚀坑形貌及U-Pb分馏的改变,标样和样品聚焦条件不一致将导致标样难以准确校正样品,并最终影响定年结果的准确性,但影响的程度、机制及可容忍范围目前尚不清楚。为此,文章以91500为标样、GJ-1为样品,详细研究了聚焦偏离30μm范围内剥蚀标样与样品锆石的剥蚀坑形貌变化以及由此导致的U-Pb定年误差。实验表明,在距离锆石表面30μm范围内,标样和样品焦平面同步变化时,二者U-Pb分馏形式及程度基本一致,激光焦平面偏离所引起的样品年龄与TIMS推荐值的偏差小于1%;当二者聚焦不同步时,标样与样品的U-Pb分馏差别显著,年龄偏差最大可超过3%。激光聚焦不同步导致的标样与样品剥蚀坑纵横比差异是引起年龄误差的根本原因,激光焦平面偏离锆石表面超过15μm,剥蚀坑坑口明显变大,纵横比减小,U-Pb分馏形式及程度发生改变。通过预剥蚀锆石,观察剥蚀坑轮廓,使激光焦平面在距离锆石样品表面15μm范围内,可确保标样与样品剥蚀坑形貌及U-Pb分馏状态一致,提高LA-ICPMS定年的准确度。     

苏鲁-大别超高压岩石中锆石SHRIMP U-Pb定年研究——综述和最新进展

如何建立苏鲁-大别超高压岩石深俯冲-超高压-快速折返过程连续而完整的P-T-t轨迹及精细的年代谱系,是目前地学界研究的热点。而变质锆石是否记录深俯冲石英榴辉岩相进变质阶段的年代学信息和超高压峰期变质时代的准确归属,是目前苏鲁-大别超高压变质带需要深入研究的核心问题。本文在对前人同位素年代学方面所取得的成果进行系统总结的基础上。采用锆石中矿物包体激光拉曼和电子探针测试、锆石阴极发光图像成因分析以及SHRIMP U-Pb定年等综合研究手段,确定苏鲁-大别地体榴辉岩及其强退变质围岩在深俯冲-构造折返过程中主要经历了四个阶段的变质演化:深俯冲石英榴辉岩相进变质(Ⅰ)、超高压峰期变质(Ⅱ)、构造折返初期石英榴辉岩相退变质(Ⅲ)和构造折返晚期角闪岩相退变质(Ⅳ)。研究发现,扬子板块(中)新元古代巨量的陆壳物质在早三叠纪(246～244Ma)俯冲到华北板块之下约65km的深处。发生了石英榴辉岩相进变质,相应的变质温压条件为T=542～693℃,P=1.7～2.02GPa。这些高压石英榴辉岩相岩石在中-新三叠纪继续向下俯冲,在235～225Ma期间,俯冲的深度至少达到了170km的地幔深处,并发生了峰期柯石英榴辉岩相超高压变质,相应的变质温压条件为T=722～866℃,P>5.5GPa。苏鲁-大别超高压地体自石英榴辉岩相进变质阶段到超高压峰期变质阶段的俯冲速率为7.0km/Myr。这些超高压岩石在219～216Ma期间,发生了第一次构造抬升至75km的深处,并经历了石英榴辉岩相退变质作用的改造,退变质温压条件为T=730～780℃,P=1.7～2.6GPa。这些退变质岩石在212～205Ma期间,又经历了第二次抬升至25km中-下地壳深处,并叠加了角闪岩相退变质作用,该阶段变质温压条件为T=610～710℃,P=0.7～1.2GPa。苏鲁-大别超高压地体两次构造抬升的速率大致相同,为5.6km/Myr。该项成果不仅确定了苏鲁-大别榴辉岩及其强退变质岩石深俯冲过程石英榴辉岩相进变质-超高压峰期变质、构造折返过程石英榴辉岩相-角闪岩相退变质连续而完整的变质演化P-T-t轨迹及精细的年代谱系,而且对于重新建立苏鲁-大别巨量陆壳物质快速超深俯冲-快速折返的动力学模式有着重要的科学意义。     

First data on U-Pb SHRIMP-II isotopic dating based on zircons of ash sediments from Cenozoic depressions in Southwest of Primorie

U-Pb (SHRIMP-II) isotopic dating has been conducted for zircons of the ash sediments of the Ust’-Suifun Suite, which was the final stage of Late Cenozoic explosive volcanism in Southwest Primorskii krai. These pyroclastic units are widespread within sediments that fill in Cenozoic depressions including large coalfields. The concordant dates (23.7–24.6 Ma) are in line with the results of the K-Ar determinations for volcanic tephra (23.6–27.1 Ma) and correspond to the beginning of the active phase of spreading and taphrogenesis in the neighboring Trench of the Sea of Japan. These processes started as early as the Eocene and are reflected in the continental vicinity with the formation of riftogenic depressions and the occurrence of a peculiar gas volcanism.     

The time length of formation of the Angara-Vitim batholite: Results of U-Pb geochronological studies

This paper describes the results of geochronological studies (U-Pb method over micro lots and single grains of zircon) of autochtonous and allochtonous granitoids of the Barguzinskii complex of the Angara-Vitim batolite of the petrotypical area in the basin of the Dzhirga and Kovyli rivers (tributaries of the Barguzin River). The age of crystallization of gneissose granitoids is 297 ± 5 Ma, and that of intrusive leucocratic biotite granites is 291 ± 1 Ma. The estimates of the age finalize the discussion on the age of granitoids of the Barguzin complex and cannot be considered as ??rejuvenated.?? The analyses of the geochronological data that have been obtained up to the present for granitoids of the Angara-Vitim batolite with the SHRIMP and U-Pb methods for large samples of zircons show that in the majority of cases they cannot be used for precise estimation of the age of their crystallization. The geochronological data obtained with use of the U-Pb method over micro samples and single grains of zircon allow one to make a conclusion on the formation of granitoids of the described complexes of the Angara-Vitim batholite that occurred within 303 ± 7?C281 ± 1 Ma. Thus, the time length of formation of the largest in the eastern segment of the Central Asian belt of the Angara-Vitim batholite is not more than 22 Ma (minimum 6 Ma), which allows us to consider it as a large granitic province and is a boundary condition for development of the geodynamic models of its formation.     

LA-ICP-MS标准锆石原位微区U-Pb定年及微量元素的分析测定

利用长安大学成矿作用及其动力学实验室Agilent 7700X四极杆等离子体质谱(ICP-MS)和Photo Machines Analyte Excite 193nm激光,在激光频率为5Hz,束斑直径为35μm条件下,对91500、GJ-1、Ple?ovice和Qinghu 4个标准锆石进行了原位微区U-Pb同位素和微量元素测定。结果显示,91500标准锆石20个测试点的~(206)Pb/~(238)U年龄范围为1059~1070Ma,~(206)Pb/~(238)U年龄加权平均值为1063.8±6.6Ma;GJ-1标准锆石28个测试点的~(206)Pb/~(238)U年龄范围为601~610Ma,~(206)Pb/~(238)U年龄加权平均值为605.4±3.0Ma;Ple?ovice标准锆石28个测试点的~(206)Pb/~(238)U年龄范围为336~341Ma,~(206)Pb/~(238)U年龄加权平均值为338.8±1.4Ma;Qinghu标准锆石40个测试点的~(206)Pb/~(238)U年龄范围为158~165Ma,~(206)Pb/~(238)U年龄加权平均值为159.9±0.7Ma。上述结果表明,91500、GJ-1、Ple?ovice和Qinghu 4个标准锆石的~(206)Pb/~(238)U年龄都在误差范围内,且年龄加权平均值与前人报道的年龄在误差范围内一致。同时,4个标准锆石的微量元素结果基本落在前人文献报道的范围内。从4个标准锆石的稀土元素球粒陨石标准化曲线可以看出,稀土元素的相对含量较准确。以上结果表明,建立的测试方法实现了对锆石原位微区U-Pb定年及微量元素的同时测定,分析数据结果准确、可靠。     

U-Pb dating and provenance of detrital zircons from the Upper Precambrian deposits of North Timan

Timan comprises the southwest edge of the Pechora Plate. The plate basement is composed of variably metamorphosed sedimentary, mainly terrigenous, and igneous rocks of the Late Precambrian age that are generally overlain by Ordovician-Cenozoic platform cover. Poor exposition and discontinuous distribution of the Upper Precambrian outcrops of dominantly fossil-free sedimentary rocks cause considerable disagreements in stratigraphic correlation. This applies equally to North Timan, which represents an uplifted block of basement, in which sedimentary-metamorphic rocks form the Barminskaya Group (～5000 m thick), previously dated as Early Riphean to Vendian. Earlier Rb-Sr and Sm-Nd isotope dating of schist and cross-cutting gabbro-dolerite and dolerite established the timing of greenschist facies metamorphism at 700 Ma. Thus, Late Riphean age of the Barminskaya Group has been suggested. Results of local U-Pb dating of detrital zircon from silty sandstones of the Malochernoretskaya Formation, which constitutes the middle part of the outcropping section of the Barminskaya Group, confirm this conclusion. Age data for 95 zircon grains cover the range of 1035–2883 Ma with age peaks at 1150, 1350, 1550, 1780, and 1885 Ma. The minimum age of zircons, considered as the lower age constraint on sediment deposition, provides grounds to date the Barminskaya Group as Late Riphean and indicates eroded rock complexes of the Fennoscandian Shield as the possible provenance areas.     

冈底斯中段厅宫地区比马组碎屑锆石U-Pb年龄

桑日群广泛分布于冈底斯火山岩浆弧的中东段,是新特提斯洋俯冲作用的代表性记录。本文对冈底斯中段厅宫地区桑日群比马组开展了碎屑锆石U-Pb同位素测年和地球化学特征研究,结果表明：比马组所含的碎屑锆石具有85.7~143.5Ma、160.2~191.2Ma、334.4~364.1Ma和904Ma四个年龄段,其中最年轻的碎屑锆石年龄为85.7±1.9Ma,结合古生物资料,认为比马组形成于早—晚白垩世,其物源主要来自于拉萨地块,尤其是冈底斯岩基剥蚀源区;岩石地球化学特征显示,比马组沉积主要来源于长英质岩石,是上地壳源区物质经风化剥蚀后搬运沉积形成。     

北大别黄土岭麻粒岩锆石U—Pb离子探针定年

阴极发光显微结构分析表明 ,北大别黄土岭麻粒岩中存在三种类型的锆石 :原岩锆石、麻粒岩相锆石和残留锆石。对它们分别进行离子探针定年 ,得到黄土岭麻粒岩的原岩年龄约为 2 70 0 Ma、麻粒岩相变质事件的年龄为 2 0 5 2± 10 0 Ma、残留锆石的年龄为约 3.4 Ga。以上研究表明黄土岭麻粒岩为残存的扬子板块的结晶基底 ,而约 3.4 Ga残留锆石的发现 ,则首次证明大别山地区存在古太古代的陆壳物质     

黑龙江多宝山花岗闪长岩的锆石SHRIMP U-Pb年龄及其地质意义

采用锆石SHRIMP U-Pb测年方法对多宝山花岗闪长岩进行定年,结果为479.5±4.6 Ma,据多宝山、铜山铜(钼)矿床中辉钼矿的Re-Os同位素等时线年龄(506±14 Ma),结合区域地质资料,认为多宝山花岗闪长岩侵位年龄为前奥陶纪,被多宝山花岗闪长岩岩体侵位的矿区地层时代、多宝山铜矿成矿主期、与成矿有关的多宝山北西向控矿、容矿构造应属于前奥陶纪,且多宝山花岗闪长岩形成于火山岛弧或活动的陆缘构造环境,岩浆来源以幔源物质为主,同熔了部份壳源物质.     

德兴矿集区花岗闪长斑岩锆石U-Pb年龄、Hf同位素特征及其意义

德兴矿集区位于赣东北地区,是中国东部中生代钦杭成矿带中的大型铜金铅锌矿集区之一,集中了铜厂、富家坞和朱砂红斑岩铜钼(金)矿、银山银铜铅锌多金属矿和金山金矿等大型、超大型矿床。本文在系统的野外地质调查与样品采集的基础上,对铜厂、富家坞、朱砂红及银山花岗闪长斑岩进行了LA-MC-ICP-MS锆石U-Pb定年和原位Hf同位素分析。德兴矿集区花岗闪长斑岩的LA-MC-ICP-MS锆石U-Pb的4组年龄分别为:(171±1.2)Ma(铜厂)、(172±0.68)Ma(富家坞)、(173±1.3)Ma(朱砂红)、(176±1.5)Ma(银山),表明这些岩体均为中侏罗世的产物。样品Hf两阶段模式年龄平均值分别为861 Ma、876 Ma、904 Ma和941 Ma,正的εHf(t)平均值在4.34-5.54,Zr/Hf比值接近于上地幔的Zr/Hf比值。锆石Hf同位素组成显示,岩浆源区主要来源于亏损地幔组分,但在岩浆演化中遭受了古老地壳物质的混染,幔源物质在德兴矿集区花岗闪长斑岩的形成过程中发挥了重要作用。德兴矿集区4个矿床成岩成矿的最重要时期在170-175 Ma,该矿集区岩浆热液系统持续活动可能是该大型矿集区形成的重要原因。     

小秦岭华山复式岩基大夫峪岩体锆石U-Pb年龄、Hf同位素和地球化学特征

大夫峪岩体位于华北陆块南缘小秦岭地区,是小秦岭地区华山复式岩基的重要组成部分,其LA-ICPMS锆石U-Pb定年结果显示:粗粒黑云母二长花岗岩和中细粒黑云母二长花岗岩的成岩年龄分别为(142.6±1.4)Ma和(140.1±1.2)Ma。岩体的w(Si O2)=69.12%~73.58%,w(Na2O)=3.95%~4.40%,大于3.2%,K2O/Na2O=0.92~1.22,A/CNK=1.03~1.04,小于1.1,属于弱过铝质高钾钙碱性I型花岗岩。岩石的ΣREE含量较高,LREE富集,LREE、HREE分馏明显,有较弱的负Eu异常。此外,岩石富集K、Rb、Ba、Sr等大离子亲石元素,而相对亏损Nb、Ta、Hf、Ti、P等高场强元素。粗粒黑云母二长花岗岩的εHf(t)主要为-24~-18,TDM2主要为2.3~2.7 Ga;中细粒黑云母二长花岗岩的εHf(t)主要为-26~-16,其TDM2主要为2.3~2.9 Ga。岩石地球化学和Hf同位素组成特征表明,岩体主要由古老下地壳部分熔融形成,源区物质可能为新太古宙太华群,并在成岩过程中有幔源或新生地壳组分的参与。根据区域地质和动力地质背景的演化历史,笔者认为,大夫峪岩体的形成时代,与东秦岭地区的其他岩体的形成时代基本一致,均形成于晚侏罗世—早白垩世,与华北克拉通东部以及华南、长江中下游等地区晚中生代岩浆作用的时间基本一致,说明整个中国东部晚中生代岩浆活动可能受控于统一的大地构造背景,即古太平洋板块俯冲欧亚板块,从而使整个中国东部发生了构造体制的大转变。大夫峪岩体就是在这种构造体制转换过程中形成的。     

Isotope stratigraphy and U-Pb dating of detrital zircons from the Vendian-Cambrian deposits of the North Muya block

U-Pb dating of detrital zircons from the sandstones of the Mamakan Formation has been made. Geochemical and isotope parameters of the carbonate deposits of the Yanguda Formation in the Vendian-Cambrian cover of the North Muya continental block have been estimated. It has been established that only the Neoproterozoic (630-915 Ma) rocks of the North Muya block were the provenances of terrigenous material. In the least altered carbonate rocks of the Yanguda Formation, the ⁸⁷Sr/⁸⁶Sr ratio is within 0.70814-0.70879 and δ¹³C varies from -0.4 to + 1.9‰. Comparison of the evaluated isotope parameters with those of carbonate rocks of typical Vendian-Cambrian sections shows that the carbonate deposits of the Yanguda Formation accumulated in the Early Cambrian, about 520 Ma. Sedimentation of the Mamakan and Yanguda Formations took place in the local sedimentary basin in the Vendian-Early Cambrian, in the absence of tectonic activity within the North Muya block. Detrital material that formed during the destruction of the rocks of the Siberian Platform basement and cover was not supplied into the basin.     

桂东南永安岩体锆石U-Pb测年、Hf同位素特征及其地质意义

永安岩体位于钦杭结合带南部,属桂东南十万大山-大容山复式岩体的一部分,其岩石类型为斑状堇青黑云花岗闪长岩。对永安岩体斑状堇青黑云花岗闪长岩进行了LA-ICPMS锆石U-Pb测年,获得其年龄为252. 8±3. 3Ma,为晚二叠世花岗岩。对永安岩体花岗岩进行的全岩地球化学分析结果表明,岩石富Al、高K,铝饱和指数A/CNK均大于1. 1,标准矿物分子刚玉均大于1%;岩石富集轻稀土元素,亏损重稀土元素,轻重稀土元素分馏明显,稀土元素的球粒陨石标准化配分曲线为轻稀土元素富集的右倾型,具弱负铕异常;岩石富集大离子亲石元素(Rb、Ba、K、Sr),亏损高场强元素(Nb、P、Ti、Ta)和Ba、Sr。花岗岩的锆石εHf(t)=-14～-8,tDM2=2. 3～1. 8 Ga。通过本文工作,结合前人关于永安岩体矿物学、全岩地球化学、Hf同位素和锆石微量元素的分析资料,认为永安岩体岩石为强过铝质S型壳源花岗岩,地幔组分没有提供成岩物质,但地幔底侵作用为成岩提供了热能,花岗岩形成于后碰撞阶段的拉张环境中。