Oxidation state of the atmosphere and crust of Venus from pioneer Venus results

Recent spacecraft observations of Venus permit a detailed model of sulfur chemistry in the atmosphere-lithosphere system. Pioneer Venus experiments confirm that, as predicted, COS and H₂S are dominant over SO₂ in the lower atmosphere, and that the equilibrium concentrations of S₂ and S₃ are significant. Many criteria serve to bracket the oxidation state of the crust: it is nearly certain that the S₂^2?/SO₄^2? buffer regulates the oxygen fucagity, and that FeO is at least as abundant as Fe₂O₃ in crustal silicates. A highly oxidized crust (as, for example, would result from O₂ absorption complementary to escape of vast amounts of H₂) is incompatible with the gas-phase sulfur chemistry. If the Pioneer Venus mass spectrometer estimates of the abundance of sulfur gases are correct, Earth-like models for the bulk composition of Venus are seriously in error, and a far lower FeO content is required for Venus.     

Production of nitrogen and carbon species by thunderstorms on Venus

The effects of the newly discovered thunderstorms on Venus upon the nitrogen and carbon species in its atmosphere were calculated. An Earth-like lightning frequency of 100 sec^?1 was used for Venus, in accord with recent optical measurements by Pioneer-Venus (W. J. Borucki, J. W. Dyer, G. Z. Thomas, J. C. Jordon, and D. A. Comstock, submitted for publication). The rate of NO production by thunder shock waves, 2.5 × 10¹¹ g year^?1, is about an order of magnitude smaller than on the Earth. But on Venus, in the absence of precipitation, which is the major removal mechanism of odd nitrogen from the Earth's atmosphere, the mixing ratios of odd nitrogen species might be considerably higher. The global CO production is governed by CO₂ photolysis rather than by CO₂ pyrolysis by lightning. However, thunderstorms produce about 2.5 × 10¹¹ g year^?1 of CO in the cloud layer, far from the high altitude CO₂ photolysis region.     

Effects of impacts on the atmospheric evolution: Comparison between Mars, Earth, and Venus

Classified as a terrestrial planet, Venus, Mars, and Earth are similar in several aspects such as bulk composition and density. Their atmospheres on the other hand have significant differences. Venus has the densest atmosphere, composed of CO₂ mainly, with atmospheric pressure at the planet's surface 92 times that of the Earth, while Mars has the thinnest atmosphere, composed also essentially of CO₂, with only several millibars of atmospheric surface pressure. In the past, both Mars and Venus could have possessed Earth-like climate permitting the presence of surface liquid water reservoirs. Impacts by asteroids and comets could have played a significant role in the evolution of the early atmospheres of the Earth, Mars, and Venus, not only by causing atmospheric erosion but also by delivering material and volatiles to the planets. Here we investigate the atmospheric loss and the delivery of volatiles for the three terrestrial planets using a parameterized model that takes into account the impact simulation results and the flux of impactors given in the literature. We show that the dimensions of the planets, the initial atmospheric surface pressures and the volatiles contents of the impactors are of high importance for the impact delivery and erosion, and that they might be responsible for the differences in the atmospheric evolution of Mars, Earth and Venus.     

On the internal structure and magnetic fields of

First, a sequence of four-zone models for the interior of Venus is constructed under the assumption of hydrostatic equilibrium. While the equation of state for each zone is taken to be the Bullen's relation with its coefficients consistent with the PREM Earth model (Dziewonski and Anderson, 1981), the position of core-mantle boundary is determined by matching solutions of the Emden's equation in different regions. The results of hydrostatic models indicate the presence of a reasonably large molten iron core in Venus, broadly similar to the Earth. It is also found that the position of the core-mantle interface is nearly model-independent. Second, we focus on the question why Venus does not possess a significant global magnetic field and on what we can learn from this fact. Solutions of magnetohydrodynamic equations appropriate for the molten core of Venus are discussed. It is argued that, because the Elsasser number measuring the relative importance of Coriolis and Lorentz forces satisfies 1, equations for the problem of thermal convection in the Venusian fluid core must be nearly uncoupled with the dynamo equation. The existence of a global magnetic field, though small, then suggests that the size of the magnetic Reynolds numberR _m must beR _m =O(10), sustaining a dynamo action near its marginal state but not an active dynamo in the Venusian molten core. On the basis of asymptotic relations for finite amplitude convection, a useful constraint on important physical parameters for the liquid core of Venus is derived and discussed.     

The maximal runaway temperature of Earth-like planets

In Simpson’s (Simpson, G.C. [1927]. Mem. R. Meteorol. Soc. II (16), 69–95) classical derivation of the temperature of the Earth in the semi-gray model, the surface temperature diverges as the fourth root of the thermal radiation’s optical depth. No resolution to this apparent paradox was yet obtained under the strict semi-gray approximation. Using this approximation and a simplified approach, we study the saturation of the runaway greenhouse effect.First we generalize the problem of the semi-gray model to cases in which a non-negligible fraction of the stellar radiation falls on the long-wavelength range, and/or that the planetary long-wavelength emission penetrates into the transparent short wavelength domain of the absorption.Second, applying the most general assumptions and independently of any particular properties of an absorber, we show that the greenhouse effect saturates and that any Earth-like planet has a maximal temperature which depends on the type of and distance to its main-sequence star, its albedo and the primary atmospheric components which determine the cutoff frequency below which the atmosphere is optically thick. For example, a hypothetical convection-less planet similar to Venus, that is optically thin in the visible, could have at most a surface temperature of 1200–1300 K irrespective of the nature of the greenhouse gas.We show that two primary mechanisms are responsible for the saturation of the runaway greenhouse effect, depending on the value of λ_cut, the wavelength above which the atmosphere becomes optically thick. Unless λ_cut is small and resides in the optical region, saturation is achieved by radiating the thermal flux of the planet through the short wavelength tail of the thermal distribution. This has an interesting observational implication, the radiation from such a planet should be skewed towards the NIR. Otherwise, saturation takes place by radiating through windows in the FIR.     

Stream Interactions and Interplanetary Coronal Mass Ejections at 0.72 AU

We present comprehensive surveys of 203 stream interaction regions (SIRs) and 124 interplanetary CMEs (ICMEs) during 1979 – 1988 using Pioneer Venus Orbiter (PVO) in situ solar-wind observations at 0.72 AU and examine the solar-cycle variations of the occurrence rate, shock association rate, duration, width, maximum total perpendicular pressure (P _t), maximum dynamic pressure, maximum magnetic field intensity, and maximum velocity change of these two large-scale solar-wind structures. The medians, averages, and histogram distributions of these parameters are also reported. Furthermore, we sort ICMEs into three groups based on the temporal profiles of P _t, and we investigate the variations of the fractional occurrence rate of three groups of ICMEs with solar activity. We find that the fractional occurrence rate of magnetic-cloud-like ICMEs declined with solar activity, consistent with our former 1-AU results. This study at 0.72 AU provides a point of comparison in the inner heliosphere for examining the radial evolution of SIRs and ICMEs. The width of SIRs and ICMEs increases by 0.04 and 0.1 AU, respectively, and the maximum P _t decreases to about 1/3 from Venus to Earth orbit. In addition, our work establishes the statistical properties of the solar-wind conditions at 0.72 AU that control the solar-wind interaction with Venus and its atmosphere loss by related processes. Electronic Supplementary Material The online version of this article () contains supplementary material, which is available to authorized users.     

Frozen orbits for satellites close to an Earth-like planet

We say that a planet is Earth-like if the coefficient of the second order zonal harmonic dominates all other coefficients in the gravity field. This paper concerns the zonal problem for satellites around an Earth-like planet, all other perturbations excluded. The potential contains all zonal coefficientsJ ₂ throughJ ₉. The model problem is averaged over the mean anomaly by a Lie transformation to the second order; we produce the resulting Hamiltonian as a Fourier series in the argument of perigee whose coefficients are algebraic functions of the eccentricity — not truncated power series. We then proceed to a global exploration of the equilibria in the averaged problem. These singularities which aerospace engineers know by the name of frozen orbits are located by solving the equilibria equations in two ways, (1) analytically in the neighborhood of either the zero eccentricity or the critical inclination, and (2) numerically by a Newton-Raphson iteration applied to an approximate position read from the color map of the phase flow. The analytical solutions we supply in full to assist space engineers in designing survey missions. We pay special attention to the manner in which additional zonal coefficients affect the evolution of bifurcations we had traced earlier in the main problem (J ₂ only). In particular, we examine the manner in which the odd zonalJ ₃ breaks the discrete symmetry inherent to the even zonal problem. In the even case, we find that Vinti's problem (J ₄+J ₂ ² =0) presents a degeneracy in the form of non-isolated equilibria; we surmise that the degeneracy is a reflection of the fact that Vinti's problem is separable. By numerical continuation we have discovered three families of frozen orbits in the full zonal problem under consideration; (1) a family of stable equilibria starting from the equatorial plane and tending to the critical inclination; (2) an unstable family arising from the bifurcation at the critical inclination; (3) a stable family also arising from that bifurcation and terminating with a polar orbit. Except in the neighborhood of the critical inclination, orbits in the stable families have very small eccentricities, and are thus well suited for survey missions.     

Response of Earth's atmosphere to increases in solar flux and implications for loss of water from Venus

A one-dimensional radiative-convective model is used to compute temperature and water vapor profiles as functions of solar flux for an Earth-like atmosphere. The troposphere is assumed to be fully saturated, with a moist adiabatic lapse rate, and changes in cloudiness are neglected. Predicted surface temperatures increase monotonically from ?1 to 111°C as the solar flux increased from 0.81 to 1.45 times its present value. Surface temperatures corresponding to high solar fluxes may be underestimated, however, owing to neglect of H₂O continuum absorption outside of the 8- to 12-μm window region. These results imply that the surface temperature of a primitive water-rich Venus should have been at least 80–100°C and may have been much higher. The existence of liquid water at the surface depends on poorly known aspects of H₂O continuum absorption and on uncertainties concerning relative humidity and cloudiness. In any case, water vapor should have been a major atmospheric constituent at all altitudes, leading to the rapid hydrodynamic escape of hydrogen. The oxygen left behind by this process was presumably consumed by reactions with reduced minerals in the crust. Both the loss of oxygen and the presently observed enrichment of the deuterium-to-hydrogen ratio are most easily explained if oceans of liquid water were initially present.     

Longevity of fluorine-bearing tremolite on Venus

There is a general belief that hydrous minerals cannot exist on Venus under current surface conditions. This view was challenged when Johnson and Fegley (2000, Icarus 146, 301-306) showed that tremolite (Ca₂Mg₅Si₈O₂₂(OH)₂), a hydrous mineral, is stable against thermal decomposition at current Venus surface temperatures, e.g., 50% decomposition in 4 Ga at 740 K. To further explore hydrous mineral thermal stability on Venus, we experimentally determined the thermal decomposition kinetics of fluorine-bearing tremolite. Fluor-tremolite is thermodynamically more stable than OH-tremolite and should decompose more slowly. However how much slower was unknown. We measured the decomposition rate of fluorine-bearing tremolite and show that its decomposition is several times to greater than ten times slower than that of OH-tremolite. We also show that F-bearing tremolite is depleted in fluorine after decomposition and that fluorine is lost as a volatile species such as HF gas. If tremolite ever formed on Venus, it would probably also contain fluorine. The exceptional stability of F-bearing tremolite strengthens our conclusions that if hydrous minerals ever formed on Venus, they could still be there today.     

Are the clouds of venus sulfuric acid?

Water solutions of sulfuric acid, containing about 75% H₂SO₄ by weight, have a refractive index within 0.01 of the values deduced from polarimetric observations of the Venus clouds. These solutions remain liquid at the cloud temperature, thus explaining the spherical shape of the cloud particles (droplets). The equilibrium vapor pressure of water above such solutions is 0.01 that of liquid water or ice, which accounts for the observed dryness of the cloud region. Furthermore, H₂SO₄ solutions of such concentration have spectra very similar to Venus in the 8–13 μm region; in particular, they explain the 11.2 μm band. Cold sulfuric acid solutions also seem consistent with Venus spectra in the 3–4 μm region. The amount of acid required to make the visible clouds is quite small, and is consistent with both the cosmic abundance of sulfur and the degree of out-gassing of the planet indicated by known atmospheric constituents. Sulfuric acid occurs naturally in volcanic gases, along with known constituents of the Venus atmosphere such as CO₂, HCl, and HF ; it is produced at high temperature by reactions between these gases and common sulfate rocks. The great stability and low vapor pressure of H₂SO₄ and its water solutions explain the lack of other sulfur compounds in the atmosphere of Venus—a lack that is otherwise puzzling.Sulfuric acid precipitation may explain some peculiarities in Venera and Mariner data. Because sulfuric acid solutions are in good agreement with the Venus data, and because no other material that has been proposed is even consistent with the polarimetric and spectroscopic data, H₂SO₄ must be considered the most probable constituent of the Venus clouds.     

Venus: A perspective at the beginning of planetary exploration

In situ measurements of the Venus atmosphere, made by the entry probes Venera 4, 5, 6, and 7, and data from the Mariner 5 flyby, have provided essentially new and reliable information and have powerfully contributed to our understanding of the nearest planet. The abundances of the principal atmospheric constituents and the temperature and pressure profiles down to the Venus surface were obtained for the first time. It was shown that the atmosphere is composed primarily of CO₂ and that N₂ (if any) and H₂O are relatively minor admixtures. In the region of the Venera 7 landing, the temperature and pressure at the Venus surface were established as equal to 747 ± 20°K and 90 ± 15 kgcm⁻². Space vehicles have also provided limited but quite important information on the physical properties of the Venus upper atmosphere and ionosphere, and on the interaction of the planet with the interplanetary environment. The main characteristics of the Venus atmosphere are discussed here with emphasis on the Venera results, including instrumentation, data processing, and altitude profiles.     

Response of Venus ions to solar wind dynamic pressure

Orbiter ion mass spectrometer measurements, as available in the UADS data files are used to study the response of dayside Venus ions at various altitudes to solar wind dynamic pressure, P _sw. Ion densities below about 200 km are not affected by changes in P _sw. At altitudes above 200 km the ions get abruptly depleted with increase in P _sw, and this abrupt depletion occurs at lower altitudes when P _sw is high. At lower P _sw, the depletion occurs at higher altitudes. The effect is similar for all ions. These results are also compared with the empirical relationship observed by Brace et al. (1980) between the ionopause altitude and P _sw from electron density measurements on orbiter electron temperature probe.     

Ultraviolet absorbers in the Venus clouds

Some absorption features in the ultraviolet spectrum of Venus observed by the OAO-2 cannot be interpreted in terms of H₂SO₄. Carbon suboxide polymer has a yellow colour and absorption at 2000 Å. Fine graphite grains have an absorption band at about 2175 Å as is well known in the case of the interstellar extinction curves. A mixture of these substances which is inevitably formed in the Venus atmosphere by photochemical reactions is the best candidate for explaining the Venus absorption features in the ultraviolet.     

Oxygen airglow emission on Venus and Mars as seen by VIRTIS/VEX and OMEGA/MEX imaging spectrometers

Imaging spectrometers are highly effective instruments for investigation of planetary atmospheres. They present the advantage of coupling the compositional information to the spatial distribution, allowing simultaneous study of chemistry and dynamics in the atmospheres of Venus and Mars. In this work, we summarize recent results about the O₂(a¹Δ_g) night and day glows, respectively obtained by VIRTIS/Venus Express and OMEGA/Mars Express, the imaging spectrometers currently in orbit around Venus and Mars. The case of the O₂(a¹Δ_g - X³Σ_g⁻) IR emission at 1.27 μm on the night side of Venus and the day side of Mars is analyzed, pointing out dynamical aspects of these planets, like the detection of gravity waves in their atmospheres. The monitoring of seasonal and daily airglow variations provides hints about the photochemistry on these planets.     

The clouds of Venus: Sulfuric acid by the lead chamber process

The Pioneer Venus atmospheric probe provided new data on the louds of Venus. A model consistent with this data involves SO₂ being oxidized to H₂SO₄ by NO_x in the presence of H₂O. NO_x also forms nitrosylsulfuric acid (NOHSO₄) dissolved in the H₂SO₄ droplets. This acid solution, along with SO₂ and perhaps NO₂, can explain the uv and visible reflection spectrum of Venus. In the middle and lower clouds NOHSO₄ forms solid particles.     

Heavy metal frost on Venus

Chemical equilibrium calculations of volatile metal geochemistry on Venus show that high dielectric constant compounds of lead and bismuth such as PbS (galena), Bi₂S₃ (bismuthite) or Pb-Bi sulfosalts condense in the venusian highlands and may be responsible for the low radar emissivities observed by Magellan and Pioneer Venus. Our calculations also show that elemental tellurium is unstable on Venus' surface and will not condense below 46.6 km. This is over 30 km higher than Maxwell Montes, the highest point on Venus' surface. Elemental analyses of Venus' highlands surface by laser induced breakdown spectroscopy (LIBS) and/or X-ray fluorescence (XRF) can verify the identity of the heavy metal frost on Venus. The Pb-Pb age of Venus could be determined by mass spectrometric measurements of the Pb²⁰⁷/Pb²⁰⁴ and Pb²⁰⁶/Pb²⁰⁴ isotopic ratios in Pb-bearing frosts. All of these measurements are technologically feasible now.     

Limits on Venus' SO2 abundance profile from interferometric observations at 3.4 mm wavelength

The role of SO₂ in the chemistry of the clouds of Venus has been investigated by deducing its mixing ratio profile in the atmosphere through millimeter wavelength interferometric measurements of the planet's limb darkening. The first zero crossing of the Venus visibility function was measured to be β₀ = 0.6221 ± 0.0007 at a wavelength of 3.4 mm using a reference radius for Venus of 6100 km. This measurement constrains the amount of limb darkening and shows that the high concentrations of SO₂ found in the lower atmosphere do not persist above an altitude of 42 km. Thus, a sink for SO₂ exists below the level of the lowest cloud deck.     

Spectroscopy of molecular oxygen in the Atmospheres of Venus and Mars

The abundances of molecular oxygen in the atmospheres of Venus and Mars are sensitive to fundamental photochemical processes. A new upper limit is reported for the molecular oxygen mixing ratio (O₂/CO₂ < × 10^?7) in the integrated column above the visible cloud tops of Venus, based on spectroscopic observations carried out in early spring, 1982. During the same observing period, an O₂ column abundance of 8.5 cm-am for the atmosphere of Mars was measured, slightly below the O₂ abundances measured a decade earlier.     

Laboratory studies on the reactions between Chlorine,Sulfur Dioxide,and Oxygen: Implications for the Venus Stratosphere

The title reaction was studied by photolyzing mixtures of Cl₂ and SO₂ with and without O₂ present in an atmosphere of N₂, using Fourier transform infrared spectrophotometry to monitor reactants and products. In the absence of oxygen, sulfur dioxide is quantitatively converted to sulfuryl chloride. With 10 to 150 Torr O₂ present H₂SO₄ is produced as well as SO₂Cl₂. When a number of speculative reactions inferred from these experiments are added to a published model for Venus stratospheric chemistry, it emerges that SO₂Cl₂ is a key reservoir species for chlorine and that the reaction between Cl and So₂ provides an important cycle for destroying O₂ and converting SO₂ to H₂So₄. The modified model could provide a possible solution to the photochemistry of the Venus stratosphere if the mixing ratio of chlorine on Venus were as high as 8 ppm.     

The 1.10- and 1.18-μm nightside windows of Venus observed by SPICAV-IR aboard Venus Express

Observations of the 1.10- and 1.18-μm nightside windows by the SPICAV-IR instrument aboard Venus Express were analyzed to characterize the various sources of gaseous opacity and determine the H₂O mole fraction in the lower atmosphere of Venus. We showed that the line profile model of Afanasenko and Rodin (Afanasenko, T.S., Rodin, A.V. [2007]. Astron. Lett. 33, 203–210) underestimates the CO₂ absorption in the high-wavelength wing of the 1.18-μm window and we derived an empirical lineshape that matches this wing well. An additional continuum opacity is required to reproduce the variation of the 1.10- and 1.18-μm radiances with surface elevation as observed by the VIRTIS-M instrument aboard Venus Express. A constant absorption coefficient of 0.7 ± 0.2 × 10⁻⁹ cm⁻¹ am⁻² best reproduces the observed variation. We compared spectra calculated with different CO₂ and H₂O line lists. We found that the CDSD line list lacks the 5ν₁ + ν₃ series of CO₂ bands, which provide significant opacity in Venus’ deep atmosphere, and we have constructed a composite line list that best reproduces the observations. We also showed for the first time that HDO brings significant absorption at 1140–1190 nm. Using the best representation of the atmospheric opacity we could reach, we retrieved a water vapor mole fraction of ppmv, pertaining to the altitude range 5–25 km. Combined with previous measurements in the 1.74- and 2.3-μm windows, this result provides strong evidence for a uniform H₂O profile below 40 km, in agreement with chemical models.