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1.
Data on spatiotemporal variations in groundwater levels are crucial for understanding arsenic (As) behavior and dynamics in groundwater systems. Little is known about the influences of groundwater extraction on the transport and mobilization of As in the Hetao Basin, Inner Mongolia (China), so groundwater levels were recorded in five monitoring wells from 2011 to 2016 and in 57 irrigation wells and two multilevel wells in 2016. Results showed that groundwater level in the groundwater irrigation area had two troughs each year, induced by extensive groundwater extraction, while groundwater levels in the river-diverted (Yellow River) water irrigation area had two peaks each year, resulting from surface-water irrigation. From 2011 to 2016, groundwater levels in the groundwater irrigation area presented a decreasing trend due to the overextraction. Groundwater samples were taken for geochemical analysis each year in July from 2011 to 2016. Increasing trends were observed in groundwater total dissolved solids (TDS) and As. Owing to the reverse groundwater flow direction, the Shahai Lake acts as a new groundwater recharge source. Lake water had flushed the near-surface sediments, which contain abundant soluble components, and increased groundwater salinity. In addition, groundwater extraction induced strong downward hydraulic gradients, which led to leakage recharge from shallow high-TDS groundwater to the deep semiconfined aquifer. The most plausible explanation for similar variations among As, Fe(II) and total organic carbon (TOC) concentrations is the expected dissimilatory reduction of Fe(III) oxyhydroxides.  相似文献   

2.
内蒙古河套灌区浅层地下水化学特征和灌溉适宜性分析   总被引:1,自引:0,他引:1  
随着黄河流域水资源供需矛盾加剧,我国特大型灌区——内蒙古河套灌区开始采用黄河水与地下水相结合的方式进行农业灌溉。本研究采集河套灌区内499组地下水样品和1组黄河水样品,在分析地下水和黄河水样品的水化学特征基础上,运用钠吸附比(SAR)、渗透指数(PI)、钠含量(SC)和残余碳酸钠(RSC)以及《农田灌溉水质标准(GB 5084—2021)》对地下水和黄河水的灌溉适宜性进行对比分析。结果表明,地下水与黄河水均为弱碱性水,Ca2+和HC03-为优势离子,Gibbs图显示地下水受到岩石风化淋溶和蒸发浓缩的双重影响,对灌溉适宜性影响较大的钠盐主要来自岩盐溶解。灌溉适宜性分析结果表明,从SAR、PI和RSC指标来看,地下水的灌溉适宜性较好,从SC指标来看,不适宜灌溉的地下水主要分布在灌区北部总排干和灌区南部黄河沿岸;根据农田灌溉水质标准分析,除总砷和氯化物两项指标外,其余指标适宜灌溉样品占比均高于90%,综合评价全区共231组地下水样品适宜灌溉。地下水与黄河水灌溉适宜性对比表明,黄河水的SAR和SC指标灌溉适宜性分析结果较好,地下水的PI和RSC指标灌溉适宜性分析结果较好,根据灌溉水质标准显示黄河水所有指标均适宜灌溉。本研究为日后内蒙古河套灌区合理选用灌溉水源提供数据支撑,为该区域地下水的治理与防控提供科学依据。  相似文献   

3.
Groundwater is crucial for multiple uses over the world, especially in arid and semiarid regions. However, human activities significantly decreased groundwater quality. In this study, the spatiotemporal variation of groundwater quality was evaluated in an arid area where long-term paper wastewater irrigation has been implemented. For this study, seven wells were regularly monitored for physicochemical parameters over a period of 1 year. Statistical and graphical approaches were applied to interpret the spatiotemporal variation of groundwater quality parameters in the wastewater irrigation zone. Correlation analysis was also carried out to reveal the sources of some major ions. The results indicate that the groundwater type in the study area is dominated by the Cl–Na, followed by the HCO3–Na, the HCO3–Ca·Mg, and the SO4·Cl–Ca·Mg types. Groundwater in the area is significantly contaminated locally with fluoride, nitrite and ammonia, and the chemical oxygen demand levels were increased in some groundwater monitoring wells. Most contaminants showed an increasing trend from the Yellow River water irrigation zone toward the wastewater irrigation zone. Rock weathering, mineral dissolution, and cation exchange are important processes controlling groundwater quality, but human activities, such as wastewater irrigation, play an undeniable role in affecting groundwater quality in this area. The results of this study contribute to the understanding of the formation and circulation of groundwater under human activities and provide a scientific basis for regional water quality evaluation, water quality improvement, and protection.  相似文献   

4.
Assessment of surface water and groundwater quality is necessary as it controls their usability for drinking and irrigation purposes. This study was carried out to assess the suitability of groundwater for these purposes and to understand the impact of water stored in a check dam on groundwater quality near Chennai, Tamil Nadu, India. Water samples were collected from a check dam across Arani River and 13 nearby wells during October 2010, January 2011, and April 2011. These samples were analyzed for pH, electrical conductivity (EC), and calcium, magnesium, sodium, potassium, carbonate, bicarbonate, chloride, and sulfate concentrations. The World Health Organization and the Bureau of Indian Standards guidelines were used to assess the suitability of groundwater for the purpose of drinking. Suitability of water for irrigation was determined based on the EC, sodium adsorption ratio, US Salinity Laboratory diagram, percentage sodium, Wilcox’s diagram, Kelly’s index, and Doneen’s permeability index. About 38 % of the groundwater samples were suitable for drinking and 70 % were suitable for irrigational use. Water stored in the check dam and groundwater in the wells closer to the structure were suitable for both drinking and irrigation purposes. The study confirms that the check dam in this area improves the groundwater quality in its surroundings.  相似文献   

5.
Assessment of groundwater quality is an important aspect of water security, which is the key to ensure sustainable development. The objective of the study is to bring out an integrated approach for assessment of groundwater quality for drinking and irrigation purposes. Gogi region, Karnataka, India was chosen as the study area due to the effect of the presence of medium-grade uranium deposits. An integrated approach including the concentration of major ions, trace elements and uranium was employed to investigate the quality of groundwater. Totally, 367 groundwater samples were collected periodically from 52 wells distributes over the Gogi region and the parameters such as pH, electrical conductivity, total dissolved solids (TDS), Ca2+, Mg2+, Na+, K+, Cl?, SO4 2?, NO3 ?, Zn, Pb, Cu, and uranium of groundwater were analysed. Spatial distribution maps of various chemical constituents were prepared using geographic information system and its temporal variation was plotted in box and whisker plot. The analytical data were compared with Bureau of Indian Standards and World Health Organisation standards to determine drinking water quality and parameters such as salinity hazard, alkalinity hazard and percent sodium were estimated to assess the irrigation quality. Multivariate statistical analysis by cluster analysis was also performed which results in two groups consisting of wells with unsuitable water for drinking purposes. Groundwater in about 15% of the sampling wells were found to be unsuitable for domestic purpose based on TDS and about 17% were unsuitable based on uranium concentration. Finally, integration of spatial variation in TDS and uranium reveals that about 25% of the wells were unsuitable for domestic purposes. It is suggested that such an integrated approach needs to be formulated considering major ions, trace elements and radioactive elements for proper assessment of water quality. Implementation of managed aquifer recharge structures in the study area is suggested since it would potentially reduce the concentration of ions.  相似文献   

6.
An integrated approach was used to evaluate the impact of flash flood recharge on groundwater quality and its suitability for drinking, irrigation, livestock and poultry uses in the Wadi Baysh Basin, Western Saudi Arabia. Analyses of 182 groundwater samples, collected from the study area before and after a flash flood (FF) event, show that the average concentrations of TDS, Mg, Na, Cl, NO3 and EC decreased significantly after the event. The major water types (mixed CaMgCl, NaCl and CaCl) indicate that the infiltration of surface water from FF recharge has a great influence on groundwater chemistry. Drinking water suitability maps, created using WHO standards, indicate that wells located in the upstream region are suitable for drinking despite their high TDS and total hardness (TH) values. Groundwater in the coastal region is unsuitable due to its high salinity, high TH and high concentrations of major ions. The suitability of groundwater for irrigational use was assessed using salinity, sodium adsorption ratio, bicarbonate hazard, residual sodium carbonate, Kelly’s ratio, magnesium hazard, sodium percentage and permeability index values, which indicated that groundwater in the study region is suitable for most soils and crops. After FF, groundwater quality is improved by dilution, especially in the downstream region. USSL classification shows that the majority of the water samples are in the C3S1, C4S2, and C3S2 classes and are therefore suitable for the irrigation of salt-tolerant crops. Irrigational suitability maps suggest that wells in the upstream region are suitable for irrigation, whereas wells located near to the coast are unfit for irrigation. This study implies that construction of check dams in the dry valleys (wadies) may improve the groundwater quality in the area.  相似文献   

7.
This study describes the groundwater quantity and quality conditions in the Damghan aquifer in Iran. The quantitative analysis of data obtained from observation wells indicates overexploitation of groundwater during recent years, which has resulted in deterioration of water quality. The mean water level has declined about 7.4 m between years of 1966 and 2010. The hydrochemical facies of water collected from sampling wells were investigated though Piper and Chadha diagrams, and the general dominant type of water in the study area was determined as Na-Cl. The quality assessment examined the suitability of groundwater for drinking and irrigation purposes. Compared to the World Health Organization (WHO) guidelines for drinking water, all regions were found to have unpotable groundwater. Furthermore, unsuitability of groundwater for agricultural applications due to high salinity was observed through analysis of major quality indicators. The saltwater intrusion was investigated by ionic ratio analyses and was determined to be the main factor contributing to high salinity and deterioration of the groundwater quality in the Damghan basin.  相似文献   

8.
张和军  孟庆伟 《地下水》2006,28(1):29-32
黄河下游冲积平原区地下水的开发利用,以开采浅层地下水为主,其质量问题日益成为人们关心的焦点。本文在对大量水样资料分析的基础上,从污染评价、饮用水评价、农业灌溉用水评价、工业锅炉用水评价及综合评价等五个方面对黄河下游(河南段)地下水质量进行了评价。  相似文献   

9.
A combination of major and trace elements have been used to characterize surface- and groundwater in El Minia district, Egypt. Surface water versus groundwater chemistry data enabled geographical zonation and chemical types to be differentiated. The main target of this research is to investigate the groundwater quality and hydrochemical evaluation. The situation is further complicated by contamination with lithogenic and anthropogenic (agricultural and sewage wastewaters) sources and low plan exploitation techniques. The investigated Pleistocene aquifer is composed of sand and gravel of different sizes, with some clay intercalation. The semi-confined condition was around the River Nile shifted to unconfine outside the floodplain. The groundwater flow generally from south to north and locally diverts towards the western part from the River Nile. Fifty-six, 11, five, and two water samples were collected from the Pleistocene aquifer, River Nile, Ibrahimia canal, and Al Moheet drain, respectively. The collected water samples were analyzed for major and trace elements. The toxic metal concentrations of Al Moheet drain are higher than those in the River Nile and the Ibrahimia canal. Cr, Hg, As, and Cd concentrations in the River Nile and Ibrahimia canal are fluctuated above and below the WHO drinking standards. Se concentration in River Nile and Ibrahimia canal is below WHO drinking and irrigation guidelines. Total dissolved solid content in groundwater is generally low, but it is increased due to the western part of the study area. The geographic position of the River Nile, Ibrahimia canal, and Al Moheet drain impact on the groundwater quality. The PHREEQC confirm the high mixing proportions from the River Nile into the groundwater and decline away from it. In addition to the thicknesses of the Pleistocene, aquifer and aquitard layer enhance the River Nile and agricultural wastewaters intrusion into the aquifer system. The toxic metal concentrations (Pb, Cd, Cr, PO4, Se, Mn, As, Hg, Ni, Al, Fe, and SIO2) in groundwater were increased mainly in the northwestern and southeastern part (far from the River Nile). It is attributed to anthropogenic, high vulnerability rate (unconfined), and partially to lithogenic. In most localities, the groundwater are unsuitable for drinking and irrigation purposes with respect to Se concentration, while they are unsuitable for dinking according Mn, As, and Hg contents. There are some Cd and Pb anomalies concentrations, which cause severe restriction if used in irrigation. The results suggested that significant changes are urgently needed in water use strategy to achieve sustainable development.  相似文献   

10.
《Applied Geochemistry》1994,9(3):271-278
The North and South Platte Rivers contribute sigficant concentrations of dissolved uranium to the Platte River system from the weathering of uraniferous rocks at their headwaters in Colorado and Wyoming. Uranium isotopes measured in three groups of samples collected from the Platte River and its major tributaries exhibted a wide range of concentrations (0.27–31.7 μg/l) and activity ratios (1.03–1.72) reflecting variations in the contributions of different sources under differing flow conditions. Locally elevated uranium concentrations and higher activity ratios were associated with groundwater sources during low flow periods. Uranium concentrations in surface runoff were lower than in baseflow and correlated significantly with dissolved solids. Uranium activity ratios in runoff were closer to equilibrium values than those in baseflow suggesting that dissolved uranium in runoff is less affected by disequilibrium processes. Mixing calculations using uranium concentrations and activity ratios indicate considerable variations in longitudinal and transverse mixing of tributary water with Plate River water, and temporal variations of groundwater contributions (baseflow and irrigation return flow) in the Plate River system.  相似文献   

11.
Hydrogeochemical characteristics of central Jianghan Plain, China   总被引:2,自引:0,他引:2  
The central Jianghan Plain is the semi-closed basin in the middle reaches of Yangtze River. A total of 78 water samples targeting groundwater were collected from 75 sites in this study site, the area between Yangtze River and Han River, including rivers and lakes for temperature, pH, electrical conductivity (EC), total dissolved solids (TDS) and ion composition measurements. Correlation matrix was used to assess the geochemical and anthropogenic processes. The most confined groundwater was grouped into HCO3–Ca–Mg, while phreatic groundwater and surface water had a more diversified hydrochemistry. The spatial variation in overall water quality as well as comparison with WHO (World Health Organization) standards for drinking water is illustrated. Mn, As and NO3 ? concentrations were found to exceed the allowable limits for drinking water of WHO guidelines, and they also show remarkable spatial variations. Abnormally high nitrate concentration, up to 150–190 mg/l, was found only in phreatic groundwater, which suggested that the nitrate pollution might be caused by agricultural activities. The present study may be helpful in further studies concerning water quality issues in this area where groundwater is a vital source for drinking and other activities.  相似文献   

12.
The assessment of groundwater quality and its environmental implications in the region of the abandoned Cunha Baixa uranium mine (Central Portugal) was carried out from 1995 to 2004. Shallow groundwater is the major water supply source for irrigation in the neighbourhood of Cunha Baixa village. Water samples from the mine site as well as from private wells were collected in order to identify the mining impact on water composition, the extent of contamination and the seasonal and temporal groundwater quality variations. Some of the sampled private wells contain waters having low pH (<4.5–5) and high values of EC, TDS, SO4, F, Ca, Mg, Al, Mn, Ni, U, Zn and 226Ra. The wells located through the ESE–WSE groundwater flow path (1 km down gradient of the mining site) display the most contaminated water. In the summer season, the levels of SO4, Al, Mn, and U were 50–120 times higher than those registered for uncontaminated waters and exceeded the quality limits for irrigation purposes, presenting soil degradation risks. Nevertheless, this study indicates that groundwater contamination suffered a small decrease from 1999 to 2004. The bioaccumulation of toxic metals such as Al, Mn, and U within the food chain may cause a serious health hazard to the Cunha Baixa village inhabitants.  相似文献   

13.
 Drilling of 15 boreholes at a disused liquid waste disposal site near Perth, Western Australia, has indicated that a contamination plume extends about 1000 m in a southerly direction from the site in the direction of groundwater flow. The plume is up to 600 m wide and 5–40 m thick. Chemical and microbiological analyses have indicated that contaminated groundwater contains high concentrations of ammonia, iron, and bacteria at levels that commonly exceed national drinking water guidelines. It is likely that a proposed water supply production well in the path of the contamination plume will have to be abandoned, and additional wells may have to be abandoned if the plume continues to extend in the direction of groundwater flow. There is currently insufficient information to indicate whether the plume is continuing to expand, but studies on similar plumes in the Perth metropolitan area have indicated that contaminated groundwater can move at rates up to 100 m yr–1. Several other liquid waste disposal sites are now located in residential areas of Perth where wells are used for garden irrigation. Further work is required to ensure that there is no potential impact of groundwater contamination on public health in these areas. Received: 31 July 1995 · Accepted: 18 September 1995  相似文献   

14.
The Yakima River, a major tributary of the Columbia River, is currently overallocated in its surface water usage in part because of large agricultural water use. As a result, groundwater availability and surface water/groundwater interactions have become an important issue in this area. In several sub-basins, the Yakima River water is diverted and applied liberally to fields in the summer creating artificial recharge of shallow groundwater. Major ion, trace element, and stable isotope geochemistry of samples from 26 groundwater wells from a transect across the Yakima River and 24 surface waters in the Kittitas sub-basin were used to delineate waters with similar geochemical signatures and to identify surface water influence on groundwater. Major ion chemistry and stable isotope signatures combined with principal component analysis revealed four major hydrochemical groups. One of these groups, collected from shallow wells within the sedimentary basin fill, displays temporal variations in NO3 and SO4 along with high δ18O and δD values, indicating significant contribution from Yakima River and/or irrigation water. Two other major hydrochemical groups reflect interaction with the main aquifer lithologies in the basin: the Columbia River basalts (high-Na groundwaters), and the volcaniclastic rocks of the Ellensburg Formation (Ca–Mg–HCO3 type waters). The fourth major group has interacted with the volcaniclastic rocks and is influenced to a lesser degree by surface waters. The geochemical groupings constrain a conceptual model for groundwater flow that includes movement of water between underlying Columbia River basalt and deeper sedimentary basin fill and seasonal input of irrigation water.  相似文献   

15.
The lower Varuna River basin in Varanasi district situated in the central Ganga plain is a highly productive agricultural area, and is also one of the fast growing urban areas in India. The agricultural and urbanization activities have a lot of impact on the groundwater quality of the study area. The river basin is underlain by Quaternary alluvial sediments consisting of clay, silt, sand and gravel of various grades. The hydrogeochemical study was undertaken by randomly collecting 75 groundwater samples from dug wells and hand pumps covering the entire basin in order to understand the sources of dissolved ions, and to assess the chemical quality of the groundwater through analysis of major ions. Based on the total dissolved solids, two groundwater samples are considered unsuitable for drinking purpose, but all samples are useful for irrigation. Graphical treatment of major ion chemistry by Piper diagram helps in identifying hydro-geochemical facies of groundwaters and the dominant hydrochemical facies is Ca-Mg-HCO3 with appreciable percentage of the water having mixed facies. As per Wilcox’s diagram and US Salinity laboratory classification, most of the groundwater samples are suitable for irrigation except two samples (No’s 30 and 68) which are unsuitable due to the presence of high salinity and medium sodium hazard. Irrigation waters classified based on residual sodium carbonate, have revealed that all groundwaters are in general safe for irrigation except one sample (No. 27), which needs treatment before use. Permeability index indicates that the groundwater samples are suitable for irrigation purpose. Although the general quality of groundwater of the lower Varuna River basin is suitable for irrigation purpose, fifty seven percent of the samples are found having nitrate content more than permissible limit (>45 mg/l) which is not good for human consumption. Application of N-Fertilizers on agricultural land as crop nutrients along the Varuna River course may be responsible for nitrate pollution in the groundwater due to leaching by applied irrigation water. The other potential sources of high nitrate concentration in extreme northern, southern and southwestern parts of study area are poor sewerage and drainage facilities, leakage of human excreta from very old septic tanks, and sanitary landfills. The high fluoride contamination (>1.5 mg/l) in some of the samples may be due to the dissolution of micaceous content in the alluvium. Nitrate and fluoride contamination of groundwater is a serious problem for its domestic use. Hence an immediate protective measure must be put into action in the study area.  相似文献   

16.
The Cihanbeyli basin is located in the northern part of Konya in the Central Anatolian region, Turkey and is characterized by semi-arid climatic conditions and scarcity in water resources. The suitability of groundwater quality for drinking and agricultural purposes in the Cihanbeyli basin was assessed by measuring physicochemical parameters, including major cation and anion compositions, pH, total dissolved solid, electrical conductivity, and total hardness. For this purpose, 54 samples were collected from different sources viz. deep wells, shallow wells, and springs. Results from hydrochemical analyses reveal that groundwater is mostly affected by salty and gypsiferous lithologies. Evaporite minerals such as gypsum, anhydrite, and chloride salts make high contributions from the recharge areas (west, northwest, and southwest parts) toward the discharge area (central and eastern parts). High values of total dissolved solids in groundwater are associated with high concentrations of all major ions. A comparison of groundwater quality in relation to drinking water standards showed that most of the water samples are not suitable for drinking. Based on sodium absorption ratio values and percent sodium, salinity appears to be responsible for the poor groundwater quality, rendering most of the samples unsuitable for irrigation usage. It is concluded that evaporation and mineral dissolution are the main processes that determine major ion compositions.  相似文献   

17.
史中兴  费良军  薛才  赵新宇 《地下水》2019,(3):63-64,75
对于水资源短缺的西北地区,研究大型引黄灌区退水规律及退水量预测对灌区水资源高效利用和灌区水资源管理具有十分重要的意义。本文利用宁夏青铜峡灌区的实测资料,通过灰色关联分析法研究了宁夏引黄灌区年退水量的影响因素和预测模型,得出影响灌区退水量的主要因素依次为灌溉引水量、地下水位、降水量和蒸发量;建立了灌区退水量的多元逐步回归预测模型,并对青铜峡灌区退水量进行了预测研究,结果表明,该模型具有较高的预测精度,研究成果为灌区水资源高效利用奠定了科学基础。  相似文献   

18.
India’s surface water and groundwater distribution is temporally variable due to the monsoon. Agriculture is one of the dominant economic sectors in India. Groundwater quality is regularly assessed to determine usability for drinking and irrigation. In this study, World Health Organization and Bureau of Indian Standards guidelines were used to determine suitability of groundwater near artificial recharge structures (ARS) with a focus on the structures´ impact on groundwater quality. Groundwater resources were evaluated for irrigation suitability using electrical conductivity (EC), sodium adsorption ratio, the US Salinity Laboratory diagram, sodium concentration, Wilcox’s diagram, Kelly’s index, and Doneen’s permeability index. EC and major ions were tested in recharge areas at different distances from the ARS. The construction of ARS at optimal distances along major streams has improved groundwater quantity and quality in the sub-basin. Before construction of ARS, fluoride concentrations were higher; after construction, fluoride was reduced in most locations. Water stored in the check dam and groundwater in the wells closer to the structure were suitable for both drinking and irrigation purposes. Impact of ARS on nearby groundwater quality was observed at Pallipatti, Mulayanur, Venkadasamuthram, Pudupatti, Poyyappatti, Harur1, and Sekkampatti. More distant sites included Pappiredipatti, Nambiyappati, Menasi, Harur, Todampatti, and Adikarapatti. Data demonstrated improved groundwater quality in the area of the ARS. Through recharge, the non-potable fluoride in the region is reduced to the permissible limit for human consumption.  相似文献   

19.
基于野外调查、取样分析以及遥感影像等,介绍了银川平原水文地质条件及水资源利用概况,探讨了土壤盐渍化、湖泊湿地萎缩、地下水盐化、地下水超采以及土地荒漠化等水环境问题及其演化成因。结果表明:银川平原地下水主要接受渠系渗漏及灌溉入渗、大气降水入渗、平原周边地下侧向径流、洪水散失、黄河水等补给,地下水排泄方式主要是排水沟排泄、蒸发和人工开采等,大部分地区潜水埋深在3 m以内;地表水主要来源于黄河引水,水资源利用效率不高;土壤盐渍化总面积8.17×104hm2,呈逐年缩减的趋势,主要分布于银川平原北部,平原南部仅分布在邵岗东部、灵武东部秦渠和东干渠等;湖泊湿地总体呈逐渐减少趋势,主要分布在银川平原北部,永宁以北、平罗以南区域比较集中,滩涂沿黄河两岸分布;潜水总含盐量自西向东、自南向北不断增大;银川和石嘴山深层地下水超采严重,地下水降落漏斗面积已超过500 km2;沙漠化土地分布在银川平原的东西两侧;土壤盐渍化及地下水盐化主要由潜水位埋深过浅,蒸发强烈造成的。最后,提出了防治上述水环境问题的对策:进一步加强水资源管理以及地表水与地下水联合调配;提高农业水资源利用效率;完善田间工程配套,实现渠道防渗管道化;改进田间灌溉技术;严格污水排放,积极开展污水净化处理,实行污水资源化;加强对水土环境质量的系统监测。  相似文献   

20.
《Applied Geochemistry》2006,21(1):83-97
Groundwater in the Gwelup groundwater management area in Perth, Western Australia has been enriched in As due to the exposure of pyritic sediments caused by reduced rainfall, increased groundwater abstraction for irrigation and water supply, and prolonged dewatering carried out during urban construction activities. Groundwater near the watertable in a 25–60 m thick unconfined sandy aquifer has become acidic and has affected shallow wells used for garden irrigation. Arsenic concentrations up to 7000 μg/L were measured in shallow groundwater, triggering concerns about possible health effects if residents were to use water from household wells as a drinking water source. Deep production wells used for public water supply are not affected by acidity, but trends of progressively increasing concentrations of Fe, SO4 and Ca over a 30-a period indicate that pyrite oxidation products extend to the base of the unconfined aquifer. Falling Eh values are triggering the release of As from the reduction of Fe(III) oxyhydroxide minerals near the base of the unconfined aquifer, increasing the risk that groundwater used as a drinking water source will also become contaminated with high concentrations of As.  相似文献   

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