Interpretation of undisturbed hydrogeochemical conditions in Neogene sediments of the Horonobe area, Hokkaido, Japan

Empirical, geostatistical and geochemical modeling techniques were used to determine whether chemical, isotopic and mineralogical data collected in surface-based borehole investigations at the Horonobe Underground Research Laboratory (URL) site in Hokkaido, Japan were representative of the natural environment before it was disturbed by borehole drilling, hydraulic testing and sampling. Water samples collected either by pumping groundwaters to the surface from borehole sections that had been isolated by inflatable packers or by squeezing porewaters from drillcores sampled from the same borehole and sampling depth were found to be similar in certain respects (m_Na+, m_Cl−, δ¹⁸O and δD) but not others (m_SO42−, m_Ca2+, m_Mg2+ and m_K+). The inconsistencies suggest that a majority of the porewater samples were contaminated as a result of pyrite oxidation and dissolution of carbonate minerals during sampling, storage and/or squeezing of the drillcores. Multivariate geostatistical analyses support this hypothesis, and further suggest that uncontaminated porewaters and groundwaters can be divided into three representative groups: a low salinity, low δ¹⁸O and low δD group; a moderate salinity, low Ca-Mg group; and a high salinity, high K and moderate Ca-Mg group. The groundwaters also contain high concentrations of dissolved gases, including CH₄(g), CO₂(g), H₂S(g) and various hydrocarbons, which exsolve from the groundwaters as they are pumped to the surface for sampling. The effects of such degassing on the chemistry of groundwater samples was evaluated by using a reaction-path model to simulate the titration of gases collected at the surface back into the samples. Results suggest that undisturbed groundwaters are slightly more acidic than their sampled counterparts, and contain roughly equivalent activities of dissolved CH₄(aq) and carbonate species. Redox potentials calculated using the corrected groundwater compositions and assuming equilibrium for the CH₄(aq)/CO₂(aq) redox couple are significantly more negative than those determined in situ in one borehole using a downhole chemical probe, and those that can be inferred from the ubiquitous presence of small amounts of framboidal pyrite and siderite in siliceous biogenic sediments of the Horonobe area. The empirical, geostatistical and geochemical modeling techniques considered in this study can be adapted for use in characterizing the hydrogeochemical environment of a site that will eventually be selected to host a geologic repository for high-level nuclear waste in Japan.     

A late Pleistocene human presence at Huaca Prieta,Peru, and early Pacific Coastal adaptations

Archaeological excavations in deep pre-mound levels at Huaca Prieta in northern Peru have yielded new evidence of late Pleistocene cultural deposits that shed insights into the early human occupation of the Pacific coast of South America. Radiocarbon dates place this occupation between ~ 14,200 and 13,300 cal yr BP. The cultural evidence shares certain basic technological and subsistence traits, including maritime resources and simple flake tools, with previously discovered late Pleistocene sites along the Pacific coast of Peru and Chile. The results help to expand our knowledge of early maritime societies and human adaption to changing coastal environments.     

Plio–Pleistocene Hydrothermal Activity Related to Gold Mineralization in the Seta Area, Northeastern Hokkaido, Japan

Abstract: Plio–Pleistocene hydrothermal activity resulted in high grade low sulfidation epithermal gold mineralization in the Seta area, the southern end of the Monbetsu-Kamishihoro Graben of northeastern Hokkaido, Japan. Hydrothermal activity and accompanying hydrothermal eruptions began at approximately 2 Ma along NNW-SSE trending faults, the Tohbu-ko fault I and II. This activity resulted in two main zones of gold mineralization, the west quartz-adularia veins(QAV) and east stock-work zone(STZ), formed between 1. 8 and 1. 2 Ma. A smectite-chlorite alteration zone is observed at deeper levels, while kaolinite and kaolinite-smectite zones occur at shallower levels with an acid-leached zone present near the surface. The kaoli-nite and kaolinite-smectite zones are also distributed along faults and the STZ, to depths of several hundred meters. δ³⁴S values of pyrite and alunite from the kaolinite and silicified zones indicate alunite formed by the oxidation of sulfide, either H₂S(vapor) or mineral.
Formation of the STZ and the southern part of the QAV took place during lacustrine sedimentation, while formation of the northern part of the QAV took place after eruption of andesitic lava; the latter being associated with widespread alteration formed under neutral-pH conditions. δ¹⁸O values of quartz veins and silicified rocks indicate that the paleo-hydrothermal waters have a large meteoric component, increasing with decreasing depth in the STZ. Acid hydrothermal waters, resulting from near surface oxidation of H₂S were responsible for acid-leaching and kaolinization of surrounding rocks. Between 1. 4 and 0. 3 Ma, the acid hot waters drained back along the STZ to depths of at least 500m, as a result of a fall in the paleo-water table level.     

Geoarchaeological context of late Pleistocene and early Holocene occupation at the Cooper's Ferry site,western Idaho,USA

Archaeological excavations at the Cooper's Ferry site (10IH73), located in the lower Salmon River canyon of western Idaho, revealed a stratified sequence of cultural occupations that included a pit feature containing stemmed points. However, radiocarbon ages determined on charcoal and bone in the pit feature range between ca. 12,000 yr B.P. and 7300 yr B.P. By considering the effects of postdepositional processes on dated samples, and by comparing the lithostratigraphy, pedostratigraphy, and stable isotope geochemistry of pedogenic carbonates from Cooper's Ferry with other well‐dated stratigraphic sections in the canyon, site geochronology is clarified. Based on the presence of key radiocarbon ages and distinctive stratigraphic criteria, we argue that the initial occupation and interment of lithic artifacts in a pit feature at Cooper's Ferry occurred during the late Pleistocene, between ca. 11,410 and 11,370 yr B.P., and not during the early Holocene. Records of geomorphic change and paleoenvironmental proxy data from the site reveal that early occupation in the lower Salmon River canyon corresponds with evolving riparian ecosystems, which must be considered as a contextual aspect of local prehistoric cultural ecology. © 2004 Wiley Periodicals, Inc.     

Piemontite from the manganiferous hematite ore deposits in the Tokoro Belt,Hokkaido, Japan

Summary Piemontites occur in manganiferous hematite ore deposits and radiolarian chest in the Nikoro Group, Tokoro Belt, eastern Hokkaido, Japan. The piemontite-bearing chest and ore bodies have suffered low-grade metamorphism of high pressure intermediate type. In ore bodies, piemontite forms veinlets with quartz and/or pumpellyite-(Mn²⁺) containing Mn³⁺ in Y site. In chest, piemontite occurs not only in veinlets but also in radiolarian tests with pumpellyite-(Mn²⁺). The mineral assemblages characterized by piemontite, pumpellyite-(Mn²⁺), okhotskite, hematite and bixbyite indicate that chest and ore deposits were metamorphosed under extremely highfO₂ condition. Some piemontites in ores contain as much as 1.12 Mn³⁺, and the sum of Mn³⁺ and Fe³⁺ attains 1.46 per formula unit, whereas piemontites in chest contain less (Mn³⁺ + Fe³⁺). This difference in compositions may essentially be ascribed to the difference in the host rock compositions. On the other hand, Mn³⁺ and Fe³⁺ contents of piemontites in ores vary considerably by Al (Mn³⁺, Fe³⁺) and Mn³⁺ Fe³⁺ substitutions. This phenomenon may be interpreted in terms of the local availability of Mn³⁺ and Fe³⁺ in the host rocks.The low-temperature stability limit of piemontite is evaluated from the relations between piemontite and pumpellyite and from the estimated P-T conditions of piemontite crystallization in chert and ore deposits.

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Piemontit aus den manganreichen Hematit-Lagerstätten des Tokoro-Gürtels, Hokkaido, Japan

Zusammenfassung Piemontite treten in manganführenden Hämatitlagerstätten und Radiolariten in der Nikoro-Gruppe des Tokoro-Gürtels, Ost-Hokkaido, Japan; auf. Die Piemontit-füh-renden Radiolarite und Erzkörper zeigen eine niedrig temperierte (Low-grade Bereich), Hochdruck (intermediate-type)-Metamorphose. In den Erzkörpern bildet Piemontit Gänge zusammen mit Quarz und/oder Mn³⁺ (in der Y-Position)-führendem Pumpellyit-(Mn²⁺). In den Radiolariten tritt Piemontit nicht nur in Gängen, sondern auch zusammen mit Pumpellyit-(Mn²⁺) in Radiolarien auf. Die Mineralparagenese Piemontit, Pumpellyit-(Mn²⁺), Okhotskit, Hämatit und Bixbyit deutet darauf hin, daß die Radiolarite und Erzlagerstätten unter hohenfO₂-Bedingungen metamorphisiert worden sind.In den Erzkörpern enthalten einige Piemontite bis zu 1.12 Mn³⁺ und die Summe von Mn³⁺ und Fe³⁺ erreicht 1.46 pro Formeleinheit. Die Piemontite in den Radiolariten zeigen geringere Mn³⁺ + Fe³⁺ Gehalte. Diese Unterschiede in der Zusammensetzung sind auf die unterschiedlichen Trägergesteine zurückzuführen. Außerdem variieren die Mn³⁺ und Fe³⁺-Gehalte der Piemontite in den Erzkörpern deutlich auf Grund der Substitution von Al (Mn³⁺, Fe³⁺) und Mn³⁺ Fe³⁺. Dieses Phänomen kann durch die lokale Verfügbarkeit von Mn³⁺ und Fe³⁺ im Trägergestein interpretiert werden.Die niedrige Temperatur-Stabilität von Piemontit kann durch die Assoziation Piemontit-Pumpellyit und durch die bestimmten P-T-Bedingungen der Piemontit-Kristallisation in den Radiolariten und Erzlagerstätten abgeschätzt werden.

     

The Pleistocene/Holocene boundary in marine deposits from the Oslofjord area

Feyling-Hanssen, R. W.: The Pleistocene/Holocene boundary in marine deposits from the Oslofjord area. Boreas, Vol. 1, pp. 241–246. Oslo 1st September, 1972.
In marine deposits from the southern Oslofjord area in Norway the boundary between Holocene and Pleistocene is found within a formation characterized by Arctic species, the so-called Yoldia Clay or zone A in the foraminiferal stratigraphy. The fossil assemblage on the Holocene side of the boundary is even poorer than that on the Pleistocene side, which is explained by the rapid Preboreal ice recession. The boundary is not conspicuously reflected in the faunas but still discernible and applicable.     

Late Pleistocene terrace deposits at Beckford,Worcestershire, England

The Pleistocene deposits in the area of the village of Beckford, in the Carrant Valley, Worcestershire are described. A radio-carbon date of 27,650±250 years B.P. has been obtained from plant material in the terrace deposits in the valley. Detailed studies have been made of the terrace sediments and of the remains of Mollusca and Coleoptera in fossiliferous layers. Frost structures are described and their stratigraphy considered. The nature of the local environment and regional climate in the final stages of the Upton Warren Interstadial period is reconstructed in detail. The terrace appears to have aggraded in a periglacial environment, dominated initially by solifluction processes. Extensive solifluction may have led to local diversions of drainage. In time, the climate deteriorated, becoming cooler and somewhat less continental with the onset of the main Devensian glaciation. This latter stage was characterised by extensive ice-wedge growth, aeolian activity and, subsequently, by river incision.     

Sedimentology and soil micromorphology of the late Pleistocene and early Holocene deposits of Grotta dell'Edera (Trieste Karst,NE Italy)

The deposits of Grotta dell'Edera have been studied by both standard sedimentological and soil micromorphological techniques, and have been divided into four main stages. The two older ones have not been dated, as they did not yield any human artefacts; nevertheless, according to their stratigraphic position and sedimentological-micromorphological characteristics, they may be considered as Tardiglacial. They testify to a thermoclastic event followed by loess deposition, both accompanied by strong inputs from outside the cave. The two following stages were ascribed to the Mesolithic (stage 3) and to the Neolithic-Copper Age (stage 4). In these two intervals sedimentation was strongly affected by human activity, while external inputs decreased. Mesolithic occupation produced sediments rich in ash and decayed organic matter. During the final stage, the cave was a shelter for domestic animals, and the deposits are mainly composed of their droppings. © 1997 John Wiley & Sons, Inc.     

Late Pleistocene deposits at Block Fen,Cambridgeshire, England

Organic sediments in a gravel quarry at Block Fen, Cambridgeshire, form a sheet dividing lower from upper gravels. Analyses of pollen, macroscopic plant remains and molluscs from these organic sediments are presented. They indicate the presence of temperate freshwater and slightly brackish fine floodplain sediments, which, on the basis of the palaeobotany, are correlated with the temperate Ipswichian Stage. The freshwater sediments, ascribed to Ipswichian substage IIb, occur at ca. ?3 m OD. Marine-influenced tidal sediments, ascribed to Ipswichian substage III, occur at ca. ?6 m OD. No evidence was found for the presence of more than one temperate stage in the sequence. The lower gravels are then correlated with the cold Wolstonian Stage and the upper gravels with the cold Devensian Stage. In contrast to the woodland environments indicated by the palaeobotany of the Ipswichian organic sediments, post-Ipswichian pollen diagrams and macroscopic plant remains in the upper suite of sands and gravels indicate open tree-less vegetation typical of the cold Devensian Stage. They also contain a typical cold-stage mollusc fauna. The sediments containing these floras and faunas are associated with thermal contraction cracks, indicating the presence of permafrost. The final sand and gravel aggradation in the Devensian forms the Block Fen Terrace, near 0 m OD. The evidence indicates that it is younger than the lacustrine sediments resulting from the blocking of the Fenland at the Wash by Late Devensian ice at ca. 18.5 ka BP. The sequence at Block Fen is related to nearby Ipswichian and Devensian sediments at Chatteris, March, Wimblington and Mepal, and to deposits at Wretton on the east margin of Fenland. The correlation permits an outline reconstruction of the history of the valley carrying the River Great Ouse between the Isle of Ely and the Chatteris and March ‘islands’ from the time of a gravel aggradation before the Ipswichian to the Flandrian. The reconstruction shows the time and level of the Ipswichian marine incursion into the Middle Level of Fenland and the extent of aggradation and erosion in the Devensian.     

Multiarchive paleoseismic record of late Pleistocene and Holocene strong earthquakes in Switzerland

A multiarchive approach has been applied to the investigation of the late Pleistocene and Holocene record of strong earthquakes in Switzerland. The geological archives used for this study include active faults, lake deposits, slope instabilities, and caves. In the Basle area, eight trenches were opened across the Basle–Reinach fault, nearby rockfall deposits were systematically investigated, sediment cores were taken from two lakes, and nine caves were studied. In Central Switzerland, five lakes were investigated by means of high-resolution seismic lines and sediment cores. Furthermore, three caves were studied in Central Switzerland. Altogether, the investigations are based on more than 350 km of high-resolution reflection seismic lines, 450 m of core samples, 260 m of trenches, and 245 radiocarbon age determinations. The measured co-seismic displacements along the Basle–Reinach fault supply independent information for the magnitude of the AD 1356 Basle earthquake exclusively based on geological evidence. Deformation features related to three well-documented strong historic earthquake shocks were identified. Deformation features of the AD 1774 Altdorf and AD 1601 Unterwalden earthquakes can be used to calibrate paleoseismic evidence in Central Switzerland. Altogether, traces of 13 earthquakes could be found in the two study areas, all of them with magnitudes M_w  6 or greater. For the first time, the earthquake catalogue for Switzerland can be extended back beyond historic records, into the late Pleistocene, spanning 15,000 years.     

Some late Pleistocene involutions at Dalton-in-Furness,northern England

Involutions are reported for the first time from northwest England. They occur in ‘head’ deposits of reworked mudstone, shale, sandstone and breccia soliflucted over glacio-fluvial sands and gravels in the Poaka Beck valley. The involutions were developed in the late Devensian period and most present a strongly festooned cross-section. Excavation of these features showed that the regular form was a result of chance sectioning and that the cryoturbate structures were a cellular or pocket type of feature. Frost heave, ice segregation and a reversed density stratification all probably contributed to the development of the involutions, but an important factor was the ground water hydrology which gave especially favourable conditions for strong cryergic activity at this site.     

The Upper Pleistocene deposits at Cassington,near Oxford,England

For much of the Middle and all of the Upper Pleistocene the Upper Thames valley has remained outside the limit of ice advance. The main agents of landform evolution have been the River Thames and its tributaries, which have cut down episodically and in so doing have abandoned a series of river terraces. This study reports the findings of an investigation into exposures in the deposits underlying the Floodplain Terrace at Cassington, near Oxford, England. The sequence exposed reveals a stratigraphy of basal, predominantly fine-grained, lithofacies overlain by coarser gravel lithofacies. The fluvial architecture of these deposits indicates a major change in fluvial style from a low-energy (meandering) to a high energy (braided) channel system. The flora and fauna from the lower fine-grained lithofacies display a marked change from temperate at the base, to colder conditions towards the top, indicating a close association between deteriorating climate and changing fluvial depositional style. Amino acid and luminescence geochronology from the basal fine-grained lithofacies suggest correlation with Oxygen Isotope Stage 5 and hence it is argued that the major environmental change recorded at the site relates to the Oxygen Isotope Stage 5–4 transition. Deposition of much of the overlying gravel sequence probably occurred during Oxygen Isotope Stage 4, suggesting that the latter half of the Devensian may be less significant, in terms of fluvial landscape evolution in the Upper Thames valley, than was believed previously. © 1998 John Wiley & Sons, Ltd.     

Late Pleistocene and Holocene History at Mubwindi Swamp, Southwest Uganda

Deposits beneath Mubwindi Swamp provide a partial record of vegetation history since at least 43,000 yr ago. We studied pollen from two cores and obtained nine radiocarbon ages from one of these cores and three radiocarbon ages from the other. Pollen deposited before and soon after the last glacial maximum represents vegetation very different from the modern vegetation of the Mubwindi Swamp catchment. Although species now associated with higher altitudes were dominant some elements of moist lower montane forest persisted, possibly because of favorable soils or topography. The pollen data provides evidence for a late glacial montane forest refuge near Mubwindi Swamp. Moist lower montane forest became much more widespread soon after the glacial maximum. The only irrefutably Holocene sediments from Mubwindi Swamp date to the past 2500 yr. During this time a combination of climatic and human-induced changes in vegetation can be seen in the pollen records.     

Geochronology,sediment provenance,and fossil emplacement at Sumidouro Cave,a classic late Pleistocene/early Holocene Paleoanthropological site in eastern Brazil

Peter Wilhelm Lund's (1845a) heavily debated suggestion of a contemporaneity between Paleo‐Indians and extinct Pleistocene fauna at Sumidouro Cave was re‐examined through detailed sedimentological and geochronological analyses of sediment and both human and faunal remains. Sources of the cave's sediment include both entrances as well as ceiling fissures. Non‐human fossils, on the other hand, were probably carried by floodwater through the once more‐spacious swallet entrance. Seasonal flooding reworked and mixed these two highly asynchronous assemblages. U‐series and radiocarbon ages indicate that there are at least two distinct episodes of sediment input in the cave, at ˜240,000 yr B.P. and ˜8000 yr B.P. Human remains represent a later emplacement event, probably at ˜8400 cal yr B.P. Although the human remains are of considerable age, the cave's complex stratigraphy, flooding dynamics, and extensive removal of the cave's filling during earlier excavations do not allow the determination of an unequivocal co‐existence between Paleo‐Indians and extinct megafauna at the site. © 2005 Wiley Periodicals, Inc.     

Glacial deposits at the Boyne Bay Limestone Quarry,Portsoy, and their place in the late Pleistocene history of northeast Scotland

The glacial deposits at the Boyne Bay Limestone Quarry near Portsoy, a key Quaternary Site of Special Scientific Interest, comprise (i) a sandy, partly weathered diamicton (Craig of Boyne Till Formation, CBTF) resting on decomposed bedrock, (ii) a central, variably glaciotectonised assemblage of dark clay, diamicton and sand, with rafts of sand and weathered diamicton (Whitehills Glacigenic Formation, WGF), and (iii) an upper dark sandy diamicton (Old Hythe Till Formation, OHTF). The CBTF was probably derived from the west or southwest, and the WGF from seawards. Structures within the OHTF conform to deposition by east‐ or southeast‐moving ice from the Moray Firth, but some erratics indicate derivation from the south. The CBTF is believed to pre‐date the last (lpswichian) interglacial, but the WGF and OHTF both post‐date the early Middle Devensian, and are probably of Late Devensian age. It is proposed that the OHTF was deposited by ice from inland which was directed eastwards near the coast by a vigorous glacier in the Moray Firth, and that the complex, Late Devensian glacial history of the south coast of the Moray Firth as a whole is the result of the interplay of these two contemporary ice‐masses. British Geological Survey. © NERC 2000.     

Polymetallic Mineralization at the Nakakoshi Copper Deposits, Central Hokkaido, Japan

Abstract: Polymetallic mineralization at the Nakakoshi deposits, Kamikawa town, central Hokkaido, occur as fracture-filling veins in Cretaceous slate of the Hidaka Supergroup. Ten veins have been recognized in NE-SW and E-W directions. Sericite in altered slate which is the host of the deposits, was dated at 31. 1 Ma, Oligocene in age.
No. 9 vein consists of massive chalcopyrite ore with various kinds of minerals such as pyrite, pyrrhotite, arsenopyrite, sphalerite, tetrahedrite, Ag-minerals and Cu–Zn–Fe–In–Sn–S minerals, quartz and sericite. Chalcopyrite and pyrite contain sphalerite star and sphalerite with chalcopyrite emulsions. Maximum indium contents of sphalerite and the Cu–Zn–Fe–In–Sn–S minerals are 1. 8 and 16. 3 wt%, respectively. The sulfur isotopic ratios, δ³⁴S of ore minerals, range from –12. 9 to –9. 6%. Formation temperatures of the sulfide minerals are estimated as 300–500°C, based on the paragenesis and chemical compositions of the minerals.