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1.
Electron paramagnetic resonance (EPR) spectra of CO
3
3–
molecule-ions stabilized by Sc3+ in natural calcite were identified and studied at X-band frequencies and room temperature. The principal values of the g-tensor (g
xx= 1.9997, g
yy = 2.0030, g
zz = 1.9972) and the direction cosines of the g and A tensors for CO
3
3–
-Sc3+ center were found to be close to that for the well-known CO
3
3–
-Y3+ center. A quantitative comparison of different impurity contents in calcite samples and analysis of the intensities of forbidden transitions were used to identify Sc3+. An estimation of the unpaired electron spin density on the nuclei of paramagnetic centers confirms that both centers, CO
3
3–
-Sc3+ and CO
3
3–
-Y3+, have the same nature. 相似文献
2.
Lin Li Takaya Nagai Tomoki Ishido Satoko Motai Kiyoshi Fujino Shoichi Itoh 《Physics and Chemistry of Minerals》2014,41(6):431-437
Experiments using laser-heated diamond anvil cells combined with synchrotron X-ray diffraction and SEM–EDS chemical analyses have confirmed the existence of a complete solid solution in the MgSiO3–MnSiO3 perovskite system at high pressure and high temperature. The (Mg, Mn)SiO3 perovskite produced is orthorhombic, and a linear relationship between the unit cell parameters of this perovskite and the proportion of MnSiO3 components incorporated seems to obey Vegard’s rule at about 50 GPa. The orthorhombic distortion, judged from the axial ratios of a/b and \( \sqrt{2}\,a/c, \) monotonically decreases from MgSiO3 to MnSiO3 perovskite at about 50 GPa. The orthorhombic distortion in (Mg0.5, Mn0.5)SiO3 perovskite is almost unchanged with increasing pressure from 30 to 50 GPa. On the other hand, that distortion in (Mg0.9, Mn0.1)SiO3 perovskite increases with pressure. (Mg, Mn)SiO3 perovskite incorporating less than 10 mol% of MnSiO3 component is quenchable. A value of the bulk modulus of 256(2) GPa with a fixed first pressure derivative of four is obtained for (Mg0.9, Mn0.1)SiO3. MnSiO3 is the first chemical component confirmed to form a complete solid solution with MgSiO3 perovskite at the P–T conditions present in the lower mantle. 相似文献
3.
SONG Zhongbao JIANG Changyi ZHANG Yulian LING Jinlan CHEN Xiangyang YANG Tao QI Shengsheng 《《地质学报》英文版》2014,88(Z2):312-313
Please refer to the attachment(s) for more details 相似文献
4.
V. A. Hagen-Thorn D. A. Morozova A. A. Arkharov E. I. Hagen-Thorn I. S. Troitsky Yu. V. Troitskaya Yu. V. Milanova E. V. Volkov L. O. Takalo A. Sillanpää 《Astronomy Reports》2017,61(6):503-512
The results of photometric (BV RIJHK) and polarimetric (R)monitoring of the blazar 3C 66A performed at the St. Petersburg State University and the Central AstronomicalObservatory of the Russian Academy of Sciences in 2007–2015, radio observations performed by the Boston University team with the Very Long Baseline Array at 43 GHz, and a gamma-ray light curve based on observations with the Fermi SpaceObservatory are presented. Color variations of the object are studied. Changes in the optical spectral energy distribution are observed at some times, indicating the appearance and disappearance of individual variable sources. A variable source with a degree of polarization of 36% is identified, which is responsible for the polarization variations observed during one episode. The correlations between the variations in the different spectral ranges indicate that the optical and gamma-ray radiation originates near the radio core detected at 43 GHz. The presence of five superluminal components emerging from the core is detected. 相似文献
5.
Grain growth kinetics in CaTiO3-perovskite + FeO-wüstite aggregates were studied at the conditions of T = 1223–1623 K, P = 0.1 MPa and P = 200 MPa. Starting samples were fabricated by hot-pressing mechanically mixed powders of CaTiO3 + FeO with FeO = 0%, 1%, 3%, 6%, 10%, 20% and 100% by weight in a gas-medium apparatus at 1323 K and 300 MPa for 5 h. The
increase of grain size (G) of CaTiO3 with time (t) follows a growth law: G
n
−G
n
0 = κ·t(κ=κ0exp(−(Q/RT)). Two grain growth regimes are observed at T < 1523 K and T ≥ 1523 K. For T < 1523 K, the best fits of the data to the growth law yield growth exponents of n = 2.2 ± 0.2, 3.0 ± 0.3 and 3.5 ± 0.3 for samples with FeO = 0%, 3% and 10% respectively. Under these conditions the rate
constants, κ, obey an Arrhenius relation with Q = 206 ± 35 kJ/mol and 385 ± 65 kJ/mol for samples with FeO = 3% and 10%. Grain growth of CaTiO3 becomes sluggish when FeO content exceeds 6%. For T ≥ 1523 K, the best fits of the data to the growth law yield n = 2.5 ± 0.2 for both samples with FeO = 3% and 10%. The activation energies (Q ) were determined as 71 ± 30 kJ/mol and 229 ± 45 kJ/mol for samples with FeO = 3% and 10%, respectively. The TEM observations
show a remarkable difference in the distribution and geometry of FeO below and above 1523 K: nanometer-sized particles of
FeO were observed along CaTiO3 grain boundaries in samples annealed at T < 1523 K. No FeO particles were detected along CaTiO3 grain boundaries in samples annealed at T ≥ 1523 K, but large clusters of FeO particles are observed locally indicating a fast separation of FeO from CaTiO3. Thus we conclude that the slow growth rate of CaTiO3 at T < 1523 K is due to the pinning by FeO particles at grain boundary, and that the change of grain growth kinetics in CaTiO3 at T ≥ 1523 K may relate to the separation of FeO from CaTiO3, which we interpret as due to the phase transformation of CaTiO3 at around 1523 K.
Received: 19 June 1998 / Revised, accepted: 24 March 1999 相似文献
6.
V. A. Hagen-Thorn N. V. Efimova V. M. Larionov C. M. Raiteri M. Villata A. A. Arkharov E. I. Hagen-Thorn C. A. Gomez S. G. Jorstad L. V. Larionova L. O. Takalo A. Sillanpää 《Astronomy Reports》2009,53(6):510-518
We present an analysis of multicolor (U BV RI JH K) observations of the blazar 3C 454.3 made in 2004–2006. We used the light curves compiled at the Turin Observatory from coordinated observations in the framework of the WEBT program. We consider color variations in two time intervals, when an unprecedented strong outburst occurred (2004–2005), and when the object was in a post-eruptive state and a low-amplitude brightness increase was observed (2006). The spectral energy distribution (SED) of the variable component remained the same within each of these intervals, but differed between them. In both cases, this SED followed a power law after correction for extinction, suggesting the variable component has a synchrotron nature. We conclude that the variations in the optical and IR were due to the same variable source. The object’s unusual color behavior (the brighter, the redder) was due to an increasing contribution from a variable component that was redder than the constant component (big blue bump). 相似文献
7.
Please refer to the attachment(s) for more details. 相似文献
8.
9.
Mateja Jemec Auflič Matjaž Mikoš Timotej Verbovšek Željko Arbanas Snježana Mihalić Arbanas 《Landslides》2018,15(2):381-384
The 3rd Regional Symposium on Landslides in the Adriatic-Balkan Region (3rd ReSyLAB) was held in Ljubljana, Slovenia, from June 11 to 13, 2017, with 70 participants from nine countries (Austria, Bosnia and Hercegovina, Croatia, Czech Republic, Italy, Republic of Macedonia, Serbia, Slovenia, Spain)—scientists, engineers, researchers, students, experts, politicians, and other decision-makers working in the area of landslide risk reduction in the region. The ReSyLAB is a biannual event organized by the Adriatic-Balkan Network of the International Consortium on Landslides (ICL ABN). Being an important form of activities of this ICL regional network comprising of six ICL members from four countries, it was also a contribution of the International Consortium on Landslides (ICL) to the implementation of the Sendai Framework for Disaster Risk Reduction 2015–2030. This article reports on the main outcomes of the 3rd ReSyLAB Symposium. Altogether, 41 abstracts were published in the symposium book of abstracts, and the symposium proceedings with over 20 reviewed full papers are under preparation to be printed early in 2018. During the 3rd ReSyLAB, a five invited keynote lectures have been presented, and 28 oral presentations are given to the audience. An important part of the symposium was a Round Table entitled “Enhancing cooperation between landslide research community and end users.” On the last day of the symposium, over 30 experts participated in two post-symposium study tours in Slovenia. 相似文献
10.
The Araucaria Plateau is a geomorphological unit that occupies approximately three-quarters of the terrain in the southern region of Brazil. The plateau displays different altitudinal levels (600 to <1400 m a.s.l.) that are locally recognized as remnants of planed surfaces (S8–S1). These surfaces are maintained by basic (S3–S8) and acidic (S1 and S2) volcanic flows from the Neocretaceous period of the Paraná Basin. The largest extent of this plateau is located in a humid subtropical climate zone. Colluvial, colluvial–alluvial, alluvial sediments and paleosols (Ab diagnostic horizons) occur predominantly in S2. The paleosols are located in low-hierarchical-order fossil valleys (first- to fourth-order in Strahler's stream classification) and valley heads, which are referred to as paleovalleys in this paper. We employed these paleosols as stratigraphic level markers of the pedogenesis of the regional Upper Quaternary and propose their importance as records of the paleoenvironmental conditions of the Araucaria Plateau in areas above 1200 m a.s.l. These paleosols were dated by 14C and show ages between 23.8 ± 0.05 kyr BP (28.06–29.08 kyr cal. BP) and 41.16 ± 0.48 kyr BP (44.13–45.58 kyr cal. BP). The calibrated ages are related to Marine Isotope Stage 3 (MIS 3), in which the last period of global warming occurred (approximately 60–25 kyr cal. BP). We integrated the morphological, pedogeochemical, clay fraction mineralogy, micromorphological and δC-13 analyses of five paleosols from S2 to verify the paleoenvironmental conditions of the Araucaria Plateau and its correspondence with the paleoclimatic phenomena that were identified on a global scale during MIS 3 in the Southern Hemisphere. We obtained the following conclusions: a) the properties of paleosols reflect pedological processes that are adjusted to the paleoenvironmental conditions at the end of MIS 3 and the transition to MIS 2 (Last Glacial Maximum); b) aplasmogenic partial acidolysis was the predominant pedogeochemical process during MIS 3; c) during this period, the water regime was sufficiently humid to develop hydromorphic horizons in the valley bottoms of the entire drainage network to the valley heads; d) regional change toward a drier hydric regime occurred in MIS 2, when erosion of the paleosols predominated; and e) in MIS 1 (current Holocene interglacial), burial of the paleosols and relief inversion occurred, which resulted in fossilization of the valleys. 相似文献
11.
A.J. van Loon 《Proceedings of the Geologists' Association. Geologists' Association》2012,123(3):394-396
Even for earth scientists it appears difficult to keep in mind that a sedimentary succession does not form due to accumulation at a constant rate, but that long periods of slow accumulation may alternate with short phases of event sedimentation and/or shorter or longer time-spans of non-deposition or even erosion. An example of this incorrect way of thinking is a recently published article in which it is postulated that the find of a ceratopsian brow horn only 13 cm below the K/T boundary in the Hell Creek Formation (Montana, USA) proves that dinosaurs did not become extinct before the K/T impact. It is argued why the postulated consequence (closure of the so-called 3-m gap: a zone of some metres thick underneath the K/T boundary in which, thus far, no dinosaur remnants had been found in the USA) is based on incorrect presumptions, particularly the relationship between time and space. 相似文献
12.
Christopher J. Norton Youichi Kondo Akira Ono Yingqi Zhang Mark C. Diab 《Quaternary International》2010,211(1-2):113-122
The nature of late Quaternary megafaunal extinctions has been the subject of intense debate since the 1960s. Traditionally, scientists cite either climatic changes or human predation as the primary reason for worldwide megafaunal extinctions. In many island cases (e.g., Madagascar, New Zealand), scientists have had a tendency to lean toward humans as being the direct or indirect dominant cause for the relatively quick extirpation of indigenous megafaunas. This study evaluates the record for megafaunal (e.g., Palaeoloxodon, Mammuthus, Sinomegaceros) extinctions in the Japanese islands and draw the tentative conclusion that: (1) humans directly and/or indirectly influenced the extinction of some large herbivores; and (2) the megafaunal extinctions likely began earlier than originally proposed; during the marine isotope stage (“MIS”) 3–2 transition (~30–20 ka) rather than during the MIS 2–1 (~15–10 ka) shift that roughly coincides with the advent of the Jomon period in Japan. However, we temper our findings due to the current paucity of sites in Japan that have associated archaeology and vertebrate paleontological materials that date to the MIS 3–2 transition. 相似文献
13.
T. Serafimovski A. V. Volkov D. Serafimovski G. Tasev I. Ivanovski K. Yu. Murashov 《Geology of Ore Deposits》2017,59(4):296-304
The Plavica Au–Ag–Cu deposit is related to the large Neogene volcanic center, which complicates the paleocaldera in the central Kratovo–Zletovo ore district of eastern Macedonia. Based on the geology, ore mineralogy, wall-rock alteration, and fluid inclusions, the Plavica deposit has been referred to the epithermal high-sulfidation type. The general 3D model of orebody at this deposit is based on its general geological structure and complex distribution of metal contents. The framework of the 3D model, which has been constructed in the ArcGIS System, comprises 195 exploration boreholes 47295.8 m in total length. The 3D model allows to a better understanding of distribution of mineralization and supplements the geological data on the deposit. 相似文献
14.
R. Das B. Venkataraman R. M. Mineeva L. V. Bershov 《Physics and Chemistry of Minerals》1990,17(1):24-26
The electron spin-lattice relaxation time (T1e) of the paramagnetic radical-ion center SO 3 ? in a naturally occurring single crystal of barite was studied in the temperature range 10–300 K by the pulse saturation recovery technique. The changes in T1e from 30 K to 300 K are much smaller than those expected from usual Raman processes in solids. The results suggest a very weak connection between SO 3 ? center and lattice. 相似文献
15.
A. G. Gorshkov A. V. Ipatov I. A. Ipatova V. K. Konnikova V. V. Mardyshkin M. G. Mingaliev M. A. Kharinov 《Astronomy Reports》2018,62(3):183-199
The article presents the results of observations of the blazar 3C 454.3 (J2253+1608), obtained in 2010–2017 on the RATAN-600 radio telescope of the Special Astrophysical Observatory at 4.6, 8.2, 11.2, and 21.7 GHz and on the 32-m Zelenchuk and Badary radio telescopes of the Quasar VLBI Network of the Institute of Applied Astronomy at 4.84 and 8.57 GHz. Long-term variability of the radio emission is studied, as well as variability on time scales of several days and intraday variability (IDV). Two flares were observed in the long-term light curve, in 2010 and in 2015–2017. The flux density at 21.7 GHz increased by a factor of ten during these flares. The delay in the maximum of the first flare at 4.85 GHz relative to the maximum at 21.7 GHz was six months. The time scale for variability on the descending branch of the first flare at 21.7 GHz was τvar = 1.2 yrs, yielding an upper limit on the linear size of the emitting region of 0.4 pc, corresponding to an angular size of 0.06 mas. The brightness temperature during the flare exceeded the Compton limit, implying a Doppler factor δ = 3.5, consistent with the known presence of a relativistic jet oriented close to the line of sight. No significant variability on time scales from several days to several weeks was found in five sets of daily observations carried out over 120 days. IDV was detected at 8.57 GHz on the 32-m telescopes in 30 of 61 successful observing sessions, with the presence of IDV correlated with the maxima of flares. The characteristic time scale for the IDV was from two to ten hours. A number of IDV light curves show the presence of a time delay in the maxima in the light curves for simultaneous observations carried out on the Badary and Zelenchuk antennas, which are widely separated in longitude. This demonstrates that the IDV most like arises in the interstellar medium. 相似文献
16.
Future earthquake potential in the Bohai–Zhangjiakou Seismotectonic Zone (BZSZ) in North China deserves close attention. Tectonic stress accumulation state is an important indicator for earthquakes; therefore, this study aims to analyse the stress accumulation state in the BZSZ via three-dimensional visco-elastic numerical modelling. The results reveal that the maximum shear stress in the BZSZ increases gradually as the depth increases, and the stress range is wider in the lower layer. In the upper layer, the maximum shear stress is high in the Zhangjiakou area, whereas in the lower layer, relatively high values occur in the Penglai–Yantai area, which may be affected by the depth of the Moho surface. Besides, weak fault zones will be easily fractured when the maximum shear stress is not sufficiently high due to their low strengths, resulting in earthquakes. Therefore, based on the modelling results, the upper layer of the Zhangjiakou area and the lower layer of the Penglai–Yantai area in the BZSZ in North China are more likely to experience earthquakes. 相似文献
17.
Arne Walther 《GeoJournal》1990,22(2):210-210
Reports
3rd International Energy Forum in Hamburg, Germany, 22–23 November 1990Meeting of leading experts to discuss the role of the Energy Industries in the Europe of the Future 相似文献18.
Yuanming Pan Mao Mao Zucheng Li Sanda M. Botis Rudolf I. Mashkovtsev Anton Shatskiy 《Physics and Chemistry of Minerals》2012,39(8):627-637
Single-crystal electron paramagnetic resonance spectra of electron-irradiated stishovite, measured at temperatures from 3.5 to 294?K, reveal three S?=?1/2 radiation-induced defects: an aluminum-associated oxygen hole center and two nd 1 centers (Ti3+ and W5+). The aluminum-associated oxygen hole center, characterized by an orthorhombic site symmetry, coaxial matrices of the electronic Zeeman g, nuclear hyperfine A(27Al) and nuclear quadrupole P(27Al), and the orientation of the g-minimum axis along an O–O direction and those of the unique A(27Al) and P(27Al) axes perpendicular to the O–O direction, is an Al–O2 3? center, with the unpaired electron equally distributed on two equatorial oxygen atoms of a substitutional Al3+ ion at the octahedral Si site. Fully optimized Al-doped structure, theoretical 27Al nuclear hyperfine and quadrupole coupling constants and directions, and 3D spin densities from periodic hybrid density functional theory calculations provide further support for this structural model. Spin Hamiltonian parameters of the Ti3+ and W5+ centers, which are confirmed by their diagnostic 47Ti, 49Ti and 183W hyperfine structures, arise from electron trapping on substitutional Ti4+ and W6+ ions at the octahedral Si site. 相似文献
19.
M. I. Agafonov E. A. Karitskaya O. I. Sharova N. G. Bochkarev S. V. Zharikov G. Z. Butenko A. V. Bondar’ M. Yu. Sidorov 《Astronomy Reports》2018,62(2):89-102
The results of a 3D Doppler tomography analysis for the X-ray binary system Cyg X-1 in the HeII λ 4686 Å line are presented. Information about the motions of gaseous flows outside the orbital plane has been obtained for the first time. Line profiles obtained in June 2007 on the 2-m telescope of the Terskol Branch of the Institute of Astronomy (Russia) and on the 2.1-m telescope of the National Astronomical Observatory of Mexico were used. A detailed analysis of these spectral data is presented: the distribution of the data in time, distribution of orbital phases for the projections, comparison of the line profile shapes for the data from two observatories. The geometry of the total transfer function obtained in the reconstruction is considered. The possibility of applying the profiles obtained to realize 3D tomography is justified. The resolution of the constructed 3D tomogram in velocity space is 60 × 60 × 40 km/s for V x , V y , V z . Fifteen cross sections for 15 different V z values perpendicular to the orbital plane are presented. The intensity distributions corresponding to the velocities of gaseous structures in the binary system are obtained. The reconstruction was realized using the radio-astronomical approach, developed for solving problems in tomography with a limited number of projections. 相似文献
20.
A. Sarkar R. Ramesh S. K. Bhattacharya N. B. Price 《Journal of Earth System Science》2000,109(1):157-169
δ18 O and δ13C of G.sacculifer have been measured in five cores from the northern Indian Ocean. In addition, high resolution analysis (1 to 2 cm) was performed
on one core (SK-20-185) for both δ18O and gd13C in five species of planktonic foraminifera. CaCO3 variation was measured in two cores. The results, presented here, show that
相似文献
– | • the summer monsoon was weaker during 18 ka and was stronger during 9 ka, relative to modern conditions; |
– | • δ13C variations are consistent with independent evidence that shows that during the last glacial maximum (LGM; 18 ka) the upwelling was reduced while during 9 ka it was vigorous; |
– | • calculation of CaCO3 flux shows that the LGM was characterized by low biogenic productivity in the Arabian Sea while during the Holocene productivity increased by ∼65%, as a direct consequence of the changes in upwelling. Similar changes (of lesser magnitude) are also seen in the equatorial Indian Ocean. The amount of terrigenous input into the Arabian Sea doubled during LGM possibly due to the higher erosion rate along the west coast. |
– | • δ18O values indicate that the Arabian Sea was saltier by 1 to 2%o during LGM. The northern part was dominated by evaporation while in the equatorial part there was an increased precipitation. |