PLASMA CHEMISTRY OF METEORITES—I. CLEANSING AND REDUCTION OF THE ODESSA IRON METEORITE

Three small samples of the Odessa, Texas iron meteorite, two surrounded by sandy soil, were introduced into a hydrogen plasma. The soil was effectively cleansed from the iron surfaces, being substantially destroyed with only a fine dust remaining. The appearance of the iron meteorite samples indicated that the terrestrial oxidation was reversed, probably to magnetite, Fe₃O₄, and metallic iron.     

ELECTROLYTIC CORROSION OF IRON METEORITES

Six iron meteorites were electrolyzed and the resulting corrosion was studied by a potentiostatic technique. It was found that both iron and nickel in the kamacite phase dissolve, and that neither iron nor nickel dissolve from taenite. The rate of corrosion was shown to be inversely proportional to the nickel content. However, structure, as well as nickel content, plays an important part in the electrolytic process. The Coya Norte, Chile meteorite dissolved more rapidly and more easily (at a lower potential) than did pure iron even though the Coya Norte meteorite contains 5.5% nickel.     

POTENTIOSTATIC STUDY OF IRON METEORITE CORROSION

A potentiostat was used to study the electrolytic corrosion of iron meteorites in a neutral solution. Low current densities were chosen so that the observed potentials would more closely approximate the theoretical Nernst values. Iron, nickel, and cobalt ions, the products of corrosion, were soluble in the electrolyte solution, and were determined after each electrolysis by atomic absorption spectrophotometry. Kamacite and taenite dissolved as individual phases, with kamacite dissolving preferentially. Cobalt dissolved along with iron and nickel from each phase. There is a direct relationship between nickel content and the potential at which a meteorite first starts to dissolve; the higher the nickel content, the more resistant the meteorite is to corrosion. None of the six meteorites observed started to dissolve at a lower potential than pure iron, nor at a higher potential than pure nickel     

FORMS OF NONTERRESTRIAL DUST ON THE EARTH

The author carried out a study of pulverised cosmic matter extracted from the soil at the fall locality of the Sikhote Alin iron meteorite shower. Three forms of dust were distinguishable: meteoritic, sharp-angled, irregular particles from the break-up of the meteorite; meteoric, spherical, magnetic particles from ablation; and micro meteorites. Meteoritic and meteoric dust was also discovered in the soil of the regions of fall of the Boguslavka and Yardymly iron meteorites. Experiments made by the author for the purpose of obtaining artificial meteoric dust from meteoritic matter of various types have shown that the meteoric dust obtained from stony meteorites is composed of spherules similar to those extracted from the soil in the areas of fall of the Sikhote Alin, Boguslavka and Yardymly iron meteorites. Cosmic dust, the particles of which are usually called micrometeorites, due to their small size, are not subjected to the influence of temperature as they pass through the Earth's atmosphere and they reach the Earth's surface unaltered. It is proposed that meteoric and cosmic dust comprises the largest part of the cosmic matter falling onto the Earth:     

THE MAGNETIC INVESTIGATION OF THE SIKHOTE-ALIN IRON METEORITE SHOWER AT THE SITE OF FALL

Individual and splinter specimens of the iron meteorite shower of Sikhote-Alin and rock samples from impact craters have been studied magnetically. The results indicate that: 1) Histograms for the distribution of natural remanent magnetization J_n of individual and splinter specimens are characterized by a high correlation coefficient (0.82 ± 0.06). For the splinter specimens, a trend to an increase in number of specimens with anomalously high J_n values is observed; 2) the Earth's magnetic field did not greatly affect the magnetic properties of this iron meteorite; and 3) for rock samples taken from different craters, there was found to be a relation between the natural remanent magnetization and the energy conditions of the crater formation.     

MORPHOLOGIES OF IRON CRYSTALS FROM THE HAVERÖ METEORITE

Studies of unpolished chips of the Haverö meteorite using the scanning electron microscope (SEM) and the electron microprobe (EMP), show two types of metallic iron particles: A, discrete convex globules of 5 to 50 microns made up of lamellae and interlocked grains, evenly interspersed among the matrix; B, flattened contorted crystals, less than one micron, lining the iron globules and cavities in the silicates or forming rounded spiny bodies. This second type of iron is interpreted, according to the current theory, as resulting from the in situ reduction of iron-magnesium silicates     

COMPOSITION AND ORIGIN OF THE UNUSUAL OKTIBBEHA COUNTY IRON METEORITE

We have analyzed Oktibbeha County, the most Ni-rich iron meteorite, for Ni, Co, Cu, Ga, Ge, As, Sb, Ir, and Au. Cu and Sb are higher than in any other iron, but other trace elements are within the ranges typically found in iron meteorites. Extrapolation of trace element trends in group IAB indicates that Oktibbeha County is a member of this group. This sheds light on the origin of groups IAB and IIICD, which are thought to be derived from impact melts on parent bodies of chondritic composition. Lafayette (iron), another sample reported in the literature to have a similarly high Ni content, is probably a pseudometeorite.     

BRIANZA: AN EXAMPLE OF WRONGLY BELIEVED CHONDRITE

The results obtained from the specimen labelled BRIANZA revealed that it is an artificial iron and not a chondritic meteorite, as previously supposed.     

ON THE BRITTLENESS OF GIBEON METEORITIC IRON

The iron-nickel alloy of the Gibeon octahedrite exhibited a transition from the normal ductile behavior to brittle behavior in tensile tests conducted below 103 °K. This result contradicts data published previously and implies that a temperature-induced transition could explain the fragmentation of a large parent metallic mass into meteorite-sized objects, since the micro-structures of existing octahedrites are consistent with brittle rather than ductile fracture events. Examination of the fractures and microstructures of the tensile specimens affirmed that the observed transition is consistent with meteoritic structures. It is concluded that the mechanical properties of Gibeon meteoritic iron are compatible with both the solid iron core and the metallic “raisin” models for the structure of the parent planet with respect to fragmentation mechanisms.     

THE METEORITE CRATERS OF MORASKO IN POLAND

In 1914, in Morasko near Poznań, a 77.5 kg iron meteorite was found. Later there were additional findings. In 1955 seven crater-like structures, situated in the neighborhood of the meteorite finds, were identified. Until now it has been doubtful whether the iron meteorites and the craters belong together. New examinations by the author confirm beyond any doubt that the meteorites and the craters were caused by the same event.     

SATURATION MAGNETIZATION MEASUREMENTS OF CARBONACEOUS CHONDRITES

The saturation magnetization of some carbonaceous chondrites was studied using a Faraday balance. The Faraday balance was shown to be an accurate (± 3%), reliable technique for measuring saturation magnetization by comparison with vibrating-sample magnetometer measurements on the same samples. Hyman and Rowe (1983) previously used these saturation magnetization measurements to measure the magnetite content of the five CI chondrites. Here, we present measurements on the magnetite contents of some CM2, CV3 and a CV5 chondrites. The method was also used to measure the content of metallic nickel-iron in Ornans, 3.4 ± 0.3%. Of the CM2 chondrites examined, only Bells, Essebi and Haripura had magnetite contents over about 1% by weight. A number of CV chondrites have magnetite between 2.3 and 13%, with little or no metallic iron. Leoville and Vigarano contain both magnetite and metallic iron, complicating the saturation magnetization results. Arch and Allende have very little metallic iron or magnetite, probably < 1% of either. This technique measures only ferrimagnetic magnetite; superparamagnetic magnetite with particle size < 300Å is ignored.     

MINERALOGY AND CHEMISTRY OF THE ASHMORE CHONDRITE

The Ashmore olivine-bronzite chondrite is a group H, type 5 stone which differs from other H5 chondrites mainly in its higher proportion of chromite (0.9 wt %) and in the relatively lower iron and higher magnesium content of the chromite. The modal proportions of opaque phases were obtained by point-counting in reflected light, and the modal proportions of nonopaque silicate phases in the matrix were estimated from traverses of a selected small area by electron microprobe. The consistency between the bulk chemical analysis and the chemical composition calculated from the modal mineral proportions implies that the bulk silicate composition of the chondrules is very similar to that of the silicate matrix and suggests a common source for both chondrules and matrix.     

MINERALOGY OF THE BOCAIUVA IRON METEORITE: A PRELIMINARY STUDY

The Bocaiuva iron contains 10 to 15% by volume of silicate inclusions which are surrounded by kamacite (6.5 wt % Ni). The metal shows a Widmanstätten pattern in metal areas devoid of silicates; taenite evolved in plessite fields. The silicate inclusions occur as nodules, and as irregular or chain-like aggregates in which olivine may be rounded or faceted. The magnesian silicates (forsterite, enstatite, diopside) are similar in composition to those of the group IAB irons, whereas the interstitial plagioclase is much more calcic (An 50) than that usually found. Iron sulfide occurs as pyrrhotite and contains 1–2 wt% Cu. Chromite and euhedral magnetite are accessory phases always associated with pyrrhotite. Some patches of pyrrhotite enclose rounded chromite and small plagioclase crystals displaying compositions different from those of the ground mass of the inclusions. Schreibersite shows a compositional variability. This preliminary study underlines the unusual nature of Ms iron and raises several questions concerning the genetic relations between silicates, sulfide and metal, and the thermal history of the whole material.     

THE GOSNELLS IRON — A FRAGMENT OF THE MOUNT DOOLING OCTAHEDRITE

A 1.5 kg iron found in 1960 at Gosnells, near Perth, Western Australia, belongs to Wasson's chemical group I-An3 and is structurally unusual, being best described as a heat-altered granular coarse octahedrite. It is chemically and structurally very similar to the Mount Dooling iron, found in 1909 about 400 km away, and has a fracture surface which fits the Mount Dooling mass very closely. The Gosnells fragment was probably transported by human agency, though it is not known when or by whom.     

COMPOSITIONAL STUDY OF THE LONE TREE,IOWA, CHONDRITE

A meteorite, named for the location of its discovery near Lone Tree, Iowa, was found by Loren Westfall in May 1971. Electron microprobe and petrographic studies reveal its mineral composition to be olivine, low-calcium clinopyroxene, high-calcium clinopyroxene, troilite, kamacite, taenite and iron oxides. On the basis of texture, olivine composition (19% Fa), low-calcium clinopyroxene composition (17% Fs, 2% Wo) and metal (determined by modal analysis), this meteorite is classified as an H group bronzite chondrite. While it has characteristics of classes 3 and 4 (Van Schmus and Wood, 1967, Table 2) it fits class 4 better since low-calcium pyroxene has a MD of 5.6%, olivine has a MD of 3.2%, turbid glass is present in chondrules, feldspar is absent, and the matrix is opaque. The opacity of the matrix may be due to iron oxides in microfractures in a microcrystalline matrix.     

MINERALOGY,PETROLOGY AND CHEMISTRY OF THE MESSINA (ITALY) CHONDRITE

The meteorite which fell near Messina, Italy, on 16 July 1955 is a typical olivine-hypersthene (L-group) chondrite. Its mineralogical composition is: olivine (Fa24), orthopyroxene (Fs20) with some polysynthetically twinned clynopyroxene, plagioclase (An10) and merrillite. Opaque phases present are: copper, kamacite, taenite, plessite, chalcopyrrhotite, mackinawite, troilite and chromite. The stone contains abundant chondrules. The matrix consists chiefly of broken chondrules with tiny fragments of crystals and rare amorphous material. Chondrules form more than 42% of the meteorite by volume. Some unusual features of the fabric of this meteorite include silicate grains showing deformation; silicates with fusion spots of dark glass containing blebs of metallic iron; iron and troilite with marginal fusion yielding globules and droplets sometimes showing flow structures. The classification of this chondrite is confirmed by bulk chemical analysis.     

GEOLOGY AND TERRESTRIAL AGE OF THE DERRICK PEAK METEORITE OCCURRENCE,ANTARCTICA

Sixteen iron meteorites together weighing 320 kg were recovered from the north-eastern flank of Derrick Peak, northern Britannia Range, Antarctica (156°30′E, 80°05′S), in December 1978. The well preserved meteorites rested cleanly upon an elevated, lag covered, glacially carved post-Middle Miocene to Pliocene bench cut into Devonian orthoquartzites intruded by Jurassic dolerite, and at a lower elevation upon Middle Pleistocene glacial drifts. In considering that the irons are in situ, and based on drift correlations along the Transantarctic Mountains, a maximum terrestrial age of 200,000–300,000 years B.P. is favoured.     

Laboratory experiments on the weathering of iron meteorites and carbonaceous chondrites by iron‐oxidizing bacteria

Abstract— Batch culture experiments were performed to investigate the weathering of meteoritic material by iron‐oxidizing bacteria. The aerobic, acidophilic iron oxidizer (A. ferrooxidans) was capable of oxidizing iron from both carbonaceous chondrites (Murchison and Cold Bokkeveld) and iron meteorites (York and Casas Grandes). Preliminary iron isotope results clearly show contrasted iron pathways during oxidation with and without bacteria suggesting that a biological role in meteorite weathering could be distinguished isotopically. Anaerobic iron‐oxidizers growing under pH‐neutral conditions oxidized iron from iron meteorites. These results show that rapid biologically‐mediated alteration of extraterrestrial materials can occur in both aerobic and anaerobic environments. These results also demonstrate that iron can act as a source of energy for microorganisms from both iron and carbonaceous chondrites in aerobic and anaerobic conditions with implications for life on the early Earth and the possible use of microorganisms to extract minerals from asteroidal material.     

The meteoritic origin of Tutankhamun's iron dagger blade

Scholars have long discussed the introduction and spread of iron metallurgy in different civilizations. The sporadic use of iron has been reported in the Eastern Mediterranean area from the late Neolithic period to the Bronze Age. Despite the rare existence of smelted iron, it is generally assumed that early iron objects were produced from meteoritic iron. Nevertheless, the methods of working the metal, its use, and diffusion are contentious issues compromised by lack of detailed analysis. Since its discovery in 1925, the meteoritic origin of the iron dagger blade from the sarcophagus of the ancient Egyptian King Tutankhamun (14th C. BCE) has been the subject of debate and previous analyses yielded controversial results. We show that the composition of the blade (Fe plus 10.8 wt% Ni and 0.58 wt% Co), accurately determined through portable x‐ray fluorescence spectrometry, strongly supports its meteoritic origin. In agreement with recent results of metallographic analysis of ancient iron artifacts from Gerzeh, our study confirms that ancient Egyptians attributed great value to meteoritic iron for the production of precious objects. Moreover, the high manufacturing quality of Tutankhamun's dagger blade, in comparison with other simple‐shaped meteoritic iron artifacts, suggests a significant mastery of ironworking in Tutankhamun's time.     

INFRARED (JHK) PHOTOMETRY OF METEORITES AND ASTEROIDS

We present JHK colors observed for ten asteroids and synthesized JHK colors for seven meteorite groups, samples of iron and nickel metal, pyroxene, olivine, feldspar, a lunar anorthite and some terrestrial mineral samples. Pronounced differences are apparent between the chondritic and achondritic meteorite classes; the chondritic classes show less subdued trends in J-H color which reflect their metamorphic grade We find small but significant differences between the JHK colors of the predominant C and S classes of asteroids. All JHK colors of asteroids observed here fall within the limited domain defined by the various chondritic and iron-rich meteorites but are strikingly different from those of most achondritic meteorites