基于水质荧光指纹法的湖泊污染溯源研究——以太湖流域滆湖为例

随着社会经济和城市化进程的快速发展,湖泊水环境污染问题日益突出,加剧了湖泊原有功能的退化和丧失,因此污染治理成为了湖泊功能恢复和可持续发挥的必要条件,但如何实现污染精准溯源又是污染治理的重要前提。为此,本文以太湖流域滆湖为例,采用一种新兴技术——水质荧光指纹法开展湖泊污染溯源。于2021年累计采集滆湖周边70个农业、13个生活、3个企业排口的瞬时出水构建污染源荧光指纹库,连续12个月采集滆湖湖体8个样点水样分析水体荧光组分。通过平行因子分析共解析出4种污染源指纹和滆湖5种水体组分,经荧光相似度(塔克同余系数)分析进一步明确滆湖主要受到种植业面源、生活源和工业源的影响。此外,荧光强度与叶绿素a浓度和藻密度的强相关性表明藻类繁殖活动也会影响滆湖。从不同污染源对滆湖的时空影响特征来看,种植业面源主要在春、夏季影响西部、中部水域,生活源主要在夏、冬季影响西部、北部水域,工业源主要在特定月份(3 4月、10 12月)影响西部水域,藻类繁殖活动主要在夏季影响湖体。通过荧光组分与水质参数的时空相关性分析得到农业源和总磷、总氮,生活源和氨氮、有机物参数(BOD₅、COD_...     

滇池化学需氧量及营养盐负荷量的预测

本文采用多元线性回归及合田健模型分别对滇池有机污染及富营养化的主要因子COD、TN、TP进行预测,并将污染负荷量分至各点源。定量说明污水处理厂对治理城市污水的积极作用,为流域进行污染治理提供了科学依据。     

鄱阳湖西侧周边农村水塘夏季表层沉积物氮、磷、有机质分布特征及评价

水塘作为农村重要的水生态系统,其环境状况与人们生产生活和健康密切相关。为了解鄱阳湖西侧周边农村水塘沉积物的有机质和营养盐赋存状况,于2018—2019年对鄱阳湖流域西侧附近4个县的23个水塘进行沉积物营养盐的分析,同时通过相关分析和差异性分析对其来源进行解析,并采用综合污染指数评价法和主成分分析法对水塘沉积物的污染程度进行评价。结果表明：水塘沉积物污染物含量较高,其有机质、有机碳（TOC）、总氮（TN）和总磷（TP）含量分别为5.81%±2.16%、2.46%±1.02%、（6.48±2.35） mg/g和（1.89±0.80） mg/g。3种形态的无机氮中铵态氮含量最高,其次为硝态氮和亚硝态氮。沉积物TP受到洗涤废水的影响较大,清淤和活化显著减轻了沉积物TN和TOC污染。综合污染指数评价结果表明重度污染和中度污染的水塘占比分别为95.65%和4.35%,其平均评价结果为重度污染,表明水塘沉积物污染严重。而主成分分析结果表明P18水塘污染最重,而P6水塘污染最轻。综合污染指数与主成分分析总得分的相关系数为0.92,表明两者的评价结果较为一致。本研究通过分析鄱阳湖西侧农村水塘的沉积物营养...     

Assessment of groundwater pollution risk as a characteristic of the stability of its quality

Definitions of hazard and risk of groundwater pollution are given. A deterministic method for the assessment of groundwater pollution risk using estimates of groundwater protection against and vulnerability to pollution and stability indicators of groundwater quality is considered. Also presented are the principal methodological approaches to the assessment of groundwater protection against pollution and the formation of the structure of indicators and indices characterizing the stability of groundwater quality. The structure of hazard, risks, and damages associated with groundwater pollution is shown. Expert appraisal method is used for the assessment of groundwater pollution risks.     

太湖地区农业源污染核算研究进展

太湖地区水体污染严重,控制太湖污染、改善太湖水质,对发挥太湖的综合服务功能,促进全流域经济可持续发展和社会稳定具有重要的战略意义.充分把握和核算太湖地区农业源污染排放量、入河量及其时空分布是落实太湖地区污染物科学减排从而进一步改善太湖水质的基础.本研究总结和概述了太湖地区农业源污染现有的核算方法、产排污参数、控制途径等,结合太湖地区农业源污染构成、排放与布局的复杂情况,提出综合运用各种核算研究方法,充分考虑各污染来源,确定农业源污染的产污量、排污量和入河量,并通过建立分期、分区、细分类型的农业源污染排放、入河参数,为科学确定农业源污染减排指标以及制定减排措施提供依据.     

太湖宜溧河水系沉积物的重金属污染特征

用ICP方法分析了太湖宜溧河水系沉积物中主要重金属含量,以太湖宜溧河口下层沉积物作背景样品,用均根法对沉积物中重金属进行了污染综合指数计算,并根据划分的污染等级对宜溧河水系沉积物污染状况进行了分析和评价。结果表明：宜溧河及其入湖口沉积物平均呈轻污染状态,北部支流未受污染,南部支流和太湖沿岸呈轻污染,干流河段污染最为严重,呈偏中度污染水平,在个别测点综合评价已达到重度污染状态。全水系Cu,Zn,Cd和Pb的污染指数略高。其中仅有Cd含量高出我国土壤一级自然背景值,表现为Cd污染型,其原因能与该地区水泥制造业和有色金属冶炼的污染排放有关。     

Hydrological and associated pollution load simulation and estimation for the Three Gorges Reservoir of China

This study demonstrates an integrated study by coupling a NPS pollution load estimation sub-model with a distributed hydrological model to simulate the hydrological processes and associated pollution load processes in the Three Gorges (TG) Reservoir which is the largest water conservancy project in China, and further estimates the pollution loads and their responses to rainfall changes. The distributed hydrological model Easy Distributed Hydrological Model (EasyDHM) is featured as containing easy rain-runoff generation processes, comprehensive pre-process and post-process modules. Based on EasyDHM, this study develops a NPS pollution load estimation sub-model Easy Distributed Non-Point source evaluation sub-model taking both point source (PS) and NPS pollution into consideration. Through the application of the models in the TG area, this study clarifies the mechanism and characteristics of NPS pollution and estimates the pollution loads in the region. This study could provide technical support for the establishment of Best Management Practices for NPS pollution in the region, and references for the government during the processes of formulating and implementing decision-makings on pollution control and comprehensive management in the TG area.     

Chemometrics data analysis of marine water quality and source identification in Southern Hong Kong

Various chemometric methods were used to analyze data sets of marine water quality for 19 parameters measured at 16 different sites of southern Hong Kong from 2000 to 2004 (18,240 observations), to determine temporal and spatial variations in marine water quality and identify pollution sources. Hierarchical cluster analysis (CA) grouped the 12 months into three periods (January-April, May-August and September-December) and the 16 sampling sites into two groups (A and B) based on similarities in marine water-quality characteristics. Discriminant analysis (DA) was important in data reduction because it used only eight parameters (TEMP, TURB, Si, NO(3)(-)-N, NH(4)(+)-N, NO(2)(-)-N, DO, and Chl-a) to correctly assign about 86% of the cases, and five parameters (SD, NH(4)(+)-N, TP, NO(2)(-)-N, and BOD(5)) to correctly assign >81.15% of the cases. In addition, principal component analysis (PCA) identified four latent pollution sources for groups A and B: organic/eutrophication pollution, natural pollution, mineral pollution, and nutrient/fecal pollution. Furthermore, during the second and third periods, all sites received more organic/eutrophication pollution and natural pollution than in the first period. SM5, SM6, SM17, SM10, SM11, SM12, and SM13 (second period) were affected by organic and eutrophication pollution, whereas SM3 (third period) and SM9 (second period) were influenced by natural pollution. However, differences between mineral pollution and nutrient/fecal pollution were not significant among the three periods. SM17 and SM10 were affected by mineral pollution, whereas SM4 and SM9 were highly polluted by nitrogenous nutrient/fecal pollution.     

不同污染程度湖泊底栖动物群落结构及多样性比较

首次对湖北梁子湖水系污染程度不同(中营养型、中富营养型、富营养型)的4个湖泊的底栖动物群落结构和物种多样性进行了周年研究,结果表明,底栖动物种类数、物种多样性与湖泊受污染程度呈负相关系,密度与污染程度大体上呈正相关．还讨论了底栖动物环境指示种生态特性,研究表明中国长足摇蚊的密度与水体营养水平呈正相关,软体动物种类数与湖泊污染程度呈负相关．通过对软体动物、寡毛类及摇蚊类密度和生物量在不同湖泊之间的差异的分析,表明湖泊水体污染导致了底栖动物多样性明显降低．     

太湖诱变剂污染调查分析

应用蚕豆根尖细胞微核试验监测太湖水污染,结果表明太湖诱变剂污染轻,分布面积小,限于西北湖区,污染分布及程度受水位状况影响较大。微核指标和其他理化性质指标互为补充,被用于评价太湖水质,并就太湖水湖保护及污染控制提出了若干建议     

Principles of zoning a territory by the hazard and risks of groundwater pollution

Principles of zoning a territory by the pollution hazard to groundwater depending on the pollution sources and their position in the environment are considered. Pollution hazard classifications are proposed for groundwater, pollutants (by their chemical and hydrochemical properties), and groundwater pollution risks, depending on the degree of hazard and the type of pollutant. A procedure is proposed for mapping the hazard and risks of groundwater pollution by various pollutants on the basis of the performed zoning.     

Influencing domain of peripheral sources in the urban heavy pollution process of Beijing

Multiple cities in a diveloped economic area may consist of a city cluster,and the difusion and mixing of its pollutants result in the effect of pollutants plume between cities and the large-scale regional pollution diffusion phenomenon.The distant transfer and diffusion of pollutants occurs when massive aerosols are affected by the dynamic porcess of large-scale circulations.Research suggesten that the life span of aerosol particles whose diameters are about 1 um is the longest.The longevity …     

城市场次降雨径流污染负荷快速估算方法

城市降雨径流污染是城市水质恶化的重要原因之一,定量计算城市降雨径流污染负荷,是实施城市水环境污染总量控制管理的基础和关键,可为城市水环境治理和污染控制提供科学依据.本文以污染物累积冲刷理论为基础,提出了“特征面积”的概念和计算公式,建立了场次降雨径流污染负荷数学模型,并结合案例,对数学模型在有效性、预测精度、适用性和局限性等方面进行评价.结果表明,特征面积较好地反映了污染物在各类土地上的污染负荷特性,场次降雨径流污染负荷与特征面积和降雨量的乘积呈正比.利用3场及以上降雨径流污染负荷结果,可较好地率定模型,从而可快速且较准确地估算单场次降雨径流污染负荷.该方法简单实用,获取数据工作量小,适用地区广.对于小降雨事件,建议采用降雨量相近的观测结果对模型进行率定,以提高模型的预测精度.     

The non-point source pollution in livestock-breeding areas of the Heihe River basin in Yellow River

A GIS-based distributed soil and water assessment tools (SWAT) model was used to simulate the runoff, sediment yield and the load of the non-point source pollution in the Heihe River basin, which is a tributary and main water supply source of the Yellow River. It is a typical stockbreeding area, and its industry and agriculture are not well developed. The main pollution source of the Heihe River was livestock related non-point source pollution. With GIS and remote sensing techniques, a database of non-point source pollution in the Heihe River basin was established. The SWAT model was parameterized for this area. The pollution load and transportation rules such as nitrogen were illustrated. After several years of hard work, the situations of point source pollution were more and more accurate. This paper provided an effective way to assess and calculate the pollution load in the wide agriculture area in China. With the help of historical data formulated parameters, the non-point source load and the theory of pollution load distribution were illustrated about the Heihe River basin. In 2000, the soluble N load in this area was 1.06 × 106 kg. By the simulation, the main pollution sources were in the south east of the basin, where the pasturing areas located in the south-east of Ruoergai County and in north of the Hongyuan County.     

Textural and geochemical characteristics of off shore sediment of North Bay of Bengal:A statistical approach for marine metal pollution

Metal pollution study on sediments of North Bay of Bengal sediments presented in this paper is based on existing Lithostratigraphy of upstream,mineralogy and geochemical analysis of 42 sediment samples.The statistical analysis identifies the metal pollution as well as its apparent source in the off shore regions.Samples were analyzed for grain size,organic content and heavy metals(Fe,Mn,Cr,Cu,Ni,Pb,Cd,Zn and Co) using the sequential extraction method to evaluate geochemical processes and pollution load.In an effort to surmise anthropogenic input,several approaches including classification by quantitative indexes such as enrichment factor,contamination factor,degree of pollution,pollution load index and geo accumulation index,were attempted.Metal speciation results indicate high%of Cd in exchangeable fraction of Mahanadi transect sediments where as a considerable amount of oxidizable fraction of Cr was detected at Dhamra.Quantitative indexes place North Bay of Bengal under moderately polluted zone due to high level of Cd.Normalization of metals to Fe indicated relatively high enrichment factors for Cd and Cr.Factor analysis identified seven possible types of geochemical associations where sediment pH plays a major role for the heavy metal mobility.The higher Cd concentration in exchangeable fraction as well as the higher EF for Cd and Cr present in sediment may pose a risk of secondary water pollution under slightest disturbance in the geo-chemistry of sediments.Comparison study with available data of near costal zones and upstream stratigraphy revealed that open cast mining,overburden dumping,mineral based industrial effluents were the major source of pollution for catchment area contamination.Bay of Bengal is likely to face a serious threat of metal pollution with the present deposition rates unless rigorous pollution control norms are applied.     

Pollution of bottom sediments in Petrozavodsk Bay of Lake Onega with oil products

The results of hydrochemical studies of Petrozavodsk Bay of Lake Onega carried out during 2001–2004 were analyzed. Due consideration was given to the pollution of bottom sediments with oil products and to the trend in pollution variations. The present condition of bottom sediments of the bay and the consequences of their pollution were assessed.     

Salt pollution of surface water in oil fields of Khanty-Mansi Autonomous Area-Yugra

The article gives the results of analysis of salt pollution at deposits of Khanty-Mansi Autonomous Area-Yugra (KhMAO-Yugra) based on data of regional hydrochemical monitoring. Data of a twenty-year observation series were used to identify the most polluted water bodies and to determine deposits with the largest salt load. Correlation and regression analyses are used to assess the interrelation between technogenesis characteristics and pollution level. It was found that the current salt pollution in the area is lower than that in the 1990s, though the pollution level has increased at some deposits of the Ob–Irtysh interfluve.     

The impact of organic pollution on the macrobenthic fauna of Dubai Creek (UAE)

Dubai Creek is a tidal marine intrusion bisecting Dubai within the United Arab Emirates (UAE). The creek extends 14km inland from its opening into the Arabian Gulf, with a narrow lower creek channel leading to a lagoon section in the upper creek. The creek contains numerous sources of organic pollution including sewage outlet flows and boat waste. A survey of the creek was performed, assessing organic pollution, water properties, and the benthic macrofaunal community. The upper creek was heavily polluted with macrofauna communities commonly associated with organic pollution and eutrophication, while the lower creek contained low pollution and relatively healthy macrofauna communities. There is little net tidal flow of water within the creek and residence time in the lagoon is high, which may account for the high organic pollution levels. However, some evidence of the pollution effect moving into the lower creek was found. The results are considered in light of current and historic organic loading within the creek and future developments in the area.     

垃圾填埋场地下环境污染检测方法技术研究

本文应用电阻率成像观测方法对北京通州某垃圾填埋场开展了面积性测量,应用模糊数学隶属函数的理论给出了分辨地下污染状况的量化指标,并对填埋场地下环境污染状况进行了分区.钻孔资料表明,分区结果真实地反映了填埋场地下环境污染的分布状况.     

动态聚类分析与太湖水质分区

以总硬度、pH、溶氧、化学耗氧、总氮、总磷、浮游植物、透明度8项指标为依据,参照现行湖泊营养类型划分标准,应用fuzzy聚类分析方法对我国42个主要湖泊聚类并划分其营养类型,同时对各类型的指标特征进行了分析。结果表明:在相似水平λ=0.69下,42个湖泊共聚为13类。其中,中、富营养型有较强的相似性,其差异显著的指标为总氮、总磷和化学耗氧量;贫营养型湖泊相似性差,其共同特征是指标中一项或数项显著异于一般营养范围。聚类结果与传统分类基本吻合。