月球岩浆洋演化的实验岩石学研究进展SCIEI北大核心CSCD

由于缺少直接来自月球深部的岩石样品,实验和计算模拟是认识早期月球演化过程的有效方法和手段。20世纪70年代以来,陆续开展了大量的实验岩石学和实验地球化学工作对月球岩浆洋(lunar magma ocean,LMO)演化模型进行验证和修正。但是,学界对LMO模型中的两个关键性参数,即初始物质组成和熔融深度,仍然存在不同的认识。根据月震和重力探测数据推测的平均月壳厚度的差异、月球样品含水量的研究以及新的遥感数据解译发现月表广泛分布富镁铝尖晶石(Cr#<5)等等,直接影响我们对月球初始物质组成和LMO深度以及月球深部高压矿物相的评估。本文通过整理高温高压实验岩石学和实验地球化学在研究LMO演化方面的一系列研究成果,主要聚焦以下几个科学问题:(1)月球初始物质组成中的难熔元素和挥发分含量,以及LMO深度对月壳厚度、结晶矿物的种类及含量有着决定性的影响;(2)高压矿物相石榴子石在月球深部稳定存在的可能性及其对残余岩浆中微量元素的分配行为的制约;(3)特殊类型的月球样品(包括火山玻璃、镁质岩套等)的成因机制对月球深部物质组成具有指示意义;(4)月核的不同物质组成对LMO模型的初始成分含量,特别是微量元素的限定作用。我们以最新的观测数据和月球样品的分析结果为依据,对已有的LMO演化模型进行重新评估,提出月球深部含有石榴子石的LMO演化模型的可能性,并对该方向亟需开展的工作进行探讨。     

月球形成演化与月球地质图编研

按照大碰撞假说,月球形成于一次大碰撞事件,抛射出的高能量物质留在绕地轨道上,最后吸积形成月球。月球核幔在早期迅速发生分离,并出现全球性的岩浆熔融,形成了岩浆圈层（岩浆洋）。岩浆洋的结晶分异和固化导致了月壳的形成。随着月壳与月幔发生持续分异,形成了固化的月壳。而在月球后期的演化历史中,撞击作用是最重要的地质作用,形成了多尺度、多期次的撞击盆地和撞击坑,而大型撞击盆地多形成于月球演化的早期。月球地质图是开展月球形成与演化研究的重要手段,从20世纪60年代起,到70年代末止,通过对阿波罗时代探月成果的系统总结,完成了第一轮月球地质图的研制。但尽管从20世纪90年代以来国际月球探测和月球科学的研究进入一个新的高潮,获得了大量有关月球形成和演化的新认识,但还没有正式的新的月球地质图发布,因此开展新一轮月球地质图的编研,系统总结后阿波罗时代的月球探测与研究成果,是非常必要和迫切的。在新一轮月球地质图的编制过程中,需重点关注图件比例尺的选择、月面历史的划分以及月球构造和岩石建造的表达。     

月球雨海盆地多环结构的厘定及其深部构造研究

雨海盆地是月球正面最大、月球上研究程度最高的多环结构撞击盆地,已有很多学者对其多环结构的边界进行恢复研究,但在多环结构最初始形状、多环位置/数量、盆地大小等方面,至今未能达成共识。本文利用GRAIL自由空气重力异常数据、LOLA激光测高数据进行了多源数据的融合,结果表明,雨海盆地是具有偏心圆的三环结构特点,其直径从外到内分别为1 500 km、1 100 km、665 km。基于欧拉反演结果研究表明,在雨海撞击盆地中部存在两种不同深度、构造运动性质及方向的断裂构造,即：(1)深度大于40 km,向下逐渐向内倾斜、延伸的深部断裂构造;(2)深度在40 km以内,由月表向下逐渐向外倾斜、延伸的浅部断裂构造。结合物质成分及地球物理特征的研究,雨海地区的地质构造演化过程可分为两个阶段：(1)在月球早期阶段(45~38.5亿年),主要以内动力地质作用即岩浆洋冷凝过程为主,形成了雨海盆地深度在40 km以下逐渐向内倾斜、延伸的构造断裂,其为本区在月球早期深部岩浆洋产生、分异及运移提供了通道,该构造断裂代表了雨海盆地撞击前的月球早期深部岩浆洋的构造地质演化阶段;(2)在月球晚期阶段(≤38.5亿年),主要以内、外动力地质作用并重,形成了雨海盆地深度在40 km以内逐渐向外倾斜、延伸的构造断裂,其应为本区不同期次的玄武质岩浆喷出或溢流到月表提供了运移通道,该构造断裂代表了雨海盆地撞击后的月球晚期不同期次玄武质岩浆喷发、充填溢流的月海岩浆活动作用的构造地质演化阶段。     

月球的化学演化

月球是一个发生了化学分异的星球,它由月壳、月幔±一个小的金属月核组成。大量观察事实显示月球曾经有过岩浆洋,岩浆洋的结晶分异主导了月球的化学演化。目前主流观点认为,月球是在太阳系演化的早期,至少45亿年前,一个火星大小的星球,与即将完成原始吸积的地球胚胎发生偏心撞击,造成地球的熔融,形成岩浆洋,飞溅出来的物质迅速吸积形成绕地球运动的月球,并且在月球上形成了全球规模的岩浆洋,进而发生了结晶分异。,由于月球上没有海洋和板块俯冲,岩浆洋分异是其化学演化的主要途径。月球岩浆洋的80％～85％在大撞击后的100Ma内已经固化,这可能是由于月球体积小、表面没有大气包裹所致。月球极贫水,因此在岩浆结晶过程中斜长石首先结晶。斜长石由于密度小于玄武质岩浆而漂浮在岩浆洋的表层,橄榄石等密度大的矿物则堆积在岩浆洋的底部。随着结晶分异的进行,残余岩浆不断富集不相容元素,包括K、U等放射性元素;与此同时,密度较大的钛铁矿开始结晶,造成高钛堆晶岩密度大于其下的橄榄石堆晶岩的不稳定结构,进而发生月幔翻转,引发一系列岩浆活动,进而形成月球上特有的镁质系列、碱质系列等岩石。由于月球氧逸度较低,Eu主要以＋2价形式存在,因此斜长石高度富集Eu,相应地除高地斜长岩外,其他岩石均表现为Eu高度亏损的特点。与此同时,Re在低氧逸度下表现为强亲铁元素的特点,Re／Os在月球岩浆过程中不发生分异。月球的体积远小于地球,因而其演化时间远远短于地球,很多原始的分异被完整地保留下来。因此月球的化学演化是类地行星早期演化过程的“化石”,尽管与现代的地球存在较大差异,但是对于认识地球早期演化具有借鉴意义。     

存在初始“传导盖层”的月球岩浆洋演化与月壳成因

月球早期经历了岩浆洋阶段,岩浆洋的研究对认识月球内部构造有着重要意义。月球岩浆洋演化主导模型认为:岩浆洋结晶到80%左右,斜长石开始结晶,并上浮形成斜长岩月壳。该模型与观察事实存在两点矛盾:1)基于该模型计算结晶的斜长石An牌号比高地样品斜长石An牌号测试结果低;2)该模型散热速率计算指示岩浆洋在几个百万年时间内固化,而同位素体系对月球岩石样品定年结果表明月壳的结晶年龄十分古老,并且结晶区间跨越了270Myr,这与主导模型之间存在矛盾。以解决以上两点矛盾为目的,本文论证岩浆洋在演化之初硕部存在冷却"盖层",并将硅酸盐熔体在温度梯度下的热扩散效应引入岩浆洋演化模型。热扩散效应指均一的物质在温度梯度下发生分异的过程。本文工作模型是:由于月球的重力常数小,不能有效的保持大气,因此月球的岩浆洋表面温度很低。此时岩浆洋自上而下存在一个过渡的瞬态固化"盖层"(淬火层),岩浆洋自上而下存在温度梯度,岩浆洋在该梯度下发生热扩散效应(Soret效应),Soret效应导致上部结晶斜长石的熔体富Ca和贫Na,因此结晶的斜长石An牌号高。     

月球“质量瘤”盆地的深部结构与撞击演化

月球"质量瘤"是指具有等轴状、高幅值重力异常的撞击盆地区域,重力异常是高密度月幔物质隆起与月海玄武岩充填共同作用的结果。研究这种高密度物质异常成因、来源、空间展布特征以及"质量瘤"盆地的深部结构,可以推测其形成与演化历史。利用嫦娥一号激光测高数据与LP165P月球重力场模型计算获得月球布格重力异常,采用新的垂直圆柱体重力异常计算公式,模拟月海充填玄武岩与月幔隆起,使其模拟计算的重力异常与测量的相对布格重力异常相吻合。计算结果表明,月球正面月海区域"质量瘤"盆地充填的玄武岩较高地区域的厚,在典型"质量瘤"盆地的布格重力异常中,月幔隆起是主要因素。计算还发现雨海与澄海下部月壳厚度比正面其他盆地的厚,而且澄海区域的地形表现为中心突起,下部月幔呈一定凹形,推测由于风暴洋区克里普岩的存在使得该区域月壳内部温度高,物质流动性增强,演化后期月壳物质横向压力均衡调整导致月壳物质向盆地中心回流,使得盆地下部月壳增厚,月幔凹陷,盆地地表出现一定程度的抬升。     

月球重力场研究及其应用进展

月球重力场研究及相关应用是月球科学探测中的重要内容之一。本文回顾了月球重力测量及月球重力场模型、月球地形模型等主要研究进展,总结了月球重力场（包括地形）在月球内部结构研究,特别是在月壳结构以及月球质量瘤等方面取得的研究成果。此外,月球重力场还应用于月幔／月核研究、月球均衡状态、月球物质成分及月球演化历史的研究中。随着我国嫦娥探月计划的实施,利用其探测数据建立自主重力场模型及地形模型成为我国探月研究的基础工作之一。在此基础上可开展月壳结构、月球均衡状态、月球质量瘤及月壳成分等研究,同时借鉴地球科学中相关学术思想和方法技术,从而促进对月球及类地行星等结构的研究。     

月震与月球内部结构

阿波罗（Apollo）登月计划在月球表面上布设的月震仪为探索月球内部结构提供了极佳资料来源,本文综述了近年来对月震资料的分析及利用月震资料研究月球内部结构的相关研究结果。月震仪记录到的振动信号主要分为天体撞击、月震和局域震动三类。天体撞击又分为流星体撞击和人造天体撞击,其震源位于月球表面。月震按震源深度分布分为浅源月震与深源月震,前者的震源深度大约为50～220km,释放的能量较大但发生次数较少,记录信号以高频成分为主;后者的震源深度大约为700～1150km,并具丛集性,与潮汐应力有关。局域震动在月球日出与日落时出现,被认为是由近月表的热破裂和变形过程所产生。月球内部结构的多数研究集中于月震仪下方月壳厚度计算及上月幔一维速度模型的建立。结果表明月壳平均厚度大约为40km,而不是早期研究得到的60km左右;通过现有的月震资料还不能得到月球下月幔、月核、月球深部间断面的相关信息。文章最后对月球内部的进一步研究做了总结和展望。     

月球质量瘤成因及研究方法综述

月球重力探测一直是国际深空探测的重要目标之一。计算月球重力发现,月球表面存在重力异常区域——质量瘤。通过对质量瘤的特征、成因以及研究方法进行概述总结,认为质量瘤是月幔隆升、高密度物质聚集所致,后期的玄武岩充填可能会增加重力异常,但作用微弱。尽管可以利用月震波分析和月球内部三维密度分布反演新技术,但是基于重力数据和地形资料的研究方法更能高效地对月球的重力场及其特征进行详细研究,高精度的重力场模型可以揭示月球深部构造及层圈形态,进而探索早期月球起源、内部物质演化与运动过程等。该研究方法可为月球和其他类地行星的重力研究提供参考。     

岩浆底侵的热-流变学效应及对峨眉山大火成岩省的启示

岩浆底侵在大陆地壳的形成和演化过程中起着非常重要的作用。本文基于二维热传导方程模拟不同规模的地壳底侵产生的热-流变学效应,以及幔源岩浆温度和含水量对底侵厚度的影响;并以现有的岩石地球化学分析、深部地球物理探测结果为约束,模拟了峨眉山大火成岩省内带幔源岩浆底侵对应的地表热流随时间演化,探讨了形成幔源岩浆底侵的潜温和初始熔融的深度制约。结果显示:1)幔源岩浆底侵引起的热扰动的耗散时间取决于岩浆底侵的初始厚度。以幔源岩浆侵入温度为1300℃,20km厚的地壳底侵为例,热扰动完全耗散需经历约150Myr;而5km厚的地壳底侵,只需经历50Myr热扰动已基本耗散殆尽。2)在初始阶段,岩浆底侵会造成岩石圈强度的显著降低;随着热耗散的进行,岩石圈强度会逐渐恢复;在热扰动耗散殆尽之后,岩石圈强度反倒比底侵前的岩石圈强度更大。这表明岩浆底侵不但可以导致地壳增厚,还会最终导致岩石圈的强化。3)温度对地壳底侵厚度的影响比含水量的影响要大得多。将我们的模型应用于峨眉山大火成岩省,结果表明内带地壳底侵的热耗散需持续上百个百万年,岩浆潜温超过1500℃,初始熔融深度超过200km。     

Lunar Magma Ocean crystallization revisited: Bulk composition, early cumulate mineralogy, and the source regions of the highlands Mg-suite

Crystallization of the Lunar Magma Ocean (LMO) has been numerically modeled and its products inferred from sample observations, but it has never been fully tested experimentally. This study is a reexamination of the LMO hypothesis by means of the first experimental simulation of lunar differentiation. Two end-member bulk Moon compositions are considered: one enriched in refractory lithophile elements relative to Earth and one with no such enrichment. A “two-stage” model of magma ocean crystallization based on geophysical constraints is simulated and features early crystal suspension and equilibrium crystallization followed by fractional crystallization of the residual magma ocean. An initially entirely molten Moon is assumed. Part 1 of this study, presented here, focuses on stage 1 of this model and considers the early cumulates formed by equilibrium crystallization, differences in mantle mineralogy resulting from different bulk Moon compositions, and implications for the source regions of the highlands Mg-suite.Refractory element enriched bulk Moon compositions produce a deep mantle that contains garnet and trace Cr-spinel in addition to low-Ca pyroxene and olivine. In contrast, compositions without refractory element enrichment produce a deep dunitic mantle with low-Ca pyroxene but without an aluminous phase. The differences in bulk composition are magnified in the residual melt; the residual LMO from the refractory element enriched composition will likely produce plagioclase and ilmenite earlier and in greater quantities. Both compositions produce Mg-rich early cumulate piles that extend from the core-mantle boundary to ∼355 km depth, if 50% equilibrium crystallization and whole Moon melting are assumed. These early LMO cumulates provide good fits for the source regions for a component of the high-Mg^∗, Ni- and Co-poor parental magmas of the Mg-suite cumulates, if certain conditions are called upon. The olivine in early LMO cumulates produced by either bulk Moon composition is far too rich in Cr to be reasonable for the source regions of the Mg-suite, meaning either core formation in the presence of S and/or C must be invoked to deplete the LMO and the crystallizing olivine in Cr, or that current estimates of the bulk lunar Cr content are too high. We infer that melts meeting the criteria of the Mg-suite parents could be produced from early LMO cumulates by solid state KREEP and plagioclase hybridization near the base of the crust and subsequent partial melting. Additionally, we propose a revised model for Mg-suite petrogenesis.     

Basaltic magmatism on the Moon: A perspective from volcanic picritic glass beads

It is widely accepted that basaltic magmas are products of partial fusion of periodotite within planetary mantles. As such, they provide valuable insights into the composition, structure, and processes of planetary interiors. Those compositions which approach primary melt compositions provide the most direct information about planetary interiors and serve as a starting point to understand basaltic evolution. Within the collection of lunar samples returned by the Apollo and Luna missions are homogeneous, picritic glass beads of volcanic origin. These picritic glasses are our closest approximations to primary magmas. As such, these glass beads provide a unique perspective concerning the origin of mare basalts, the characteristics of the lunar interior, and processes in the early differentiation of the Moon. We have obtained trace element data for these picritic glasses using SIMS techniques. These data and literature isotopic and experimental data on the picritic glasses are placed within the framework of mare basaltic magmatism.The volcanic glasses are very diverse in their trace element characteristics, for example, they have a wide range of REE pattern shapes and concentrations. Like the crystalline mare basalts, all picritic glasses have a negative Eu anomaly. Unlike the crystalline mare basalts, there is little correlation between the size of the Eu anomaly and overall REE concentrations. Trace element differences among the various glasses suggests that a KREEP component was incorporated into their mantle source. This implies large scale mixing of the “Lunar Magma Ocean”-derived cumulate pile. Subtle differences among glasses suggest that local mixing of sources may also have been an important process. Preservation of subtle chemical differences in the picritic glasses and crystalline basalts may be interpreted as indicating that they were produced by small to moderate degrees of partial melting and that the lunar mantle did not experience extensive melting during episodes of mare volcanism.Several lines of evidence are consistent with the view that the picritic glasses were derived from mantle sources that were compositionally distinct from the sources for crystalline mare basalts. These are parallel, but no common, liquid lines of descent; chemical differences between picritic glasses and the more primitive crystalline mare basalts; experimental studies indicating that the picritic glasses are multiply saturated at depths greater than that of the mare basalts; differences in lead isotopic data; and the mode of eruption (i.e., fire fountaining for glass beads). These data also provide circumstantial evidence that suggests that the picritic glasses were derived from a source somewhat more volatile-rich than that of the mare basalts.Several petrogenetic models are suggested by the trace element characteristics of the picritic glasses:

• 1.(1) Partial melting of heterogeneous lunar mantle at depths greater than 300 km to produce the parental magmas (picritic) for both the mare basalts and picritic glasses. Picritic magmas represented by glass beads were erupted to the surface with small degrees of fractional crystallization while mare basalts were produced by larger degrees of fractional crystallization (15–30%) of similar (but not identical) picritic magmas.
• 2.(2) Picritic magmas represented by the glass beads were generated at depths greater than 400 km in a volatile-enriched (relative to the mare basalt source) heterogeneous mantle while mare basalts are fractional crystallization products of picritic magmas generated at depths of less than 400 km.
• 3.(3) The picritic magmas represented by the glass beads represent polybaric melting that initiated at depths of at least 1000 km. A primitive mantle component or less processed cumulate mantle components may have been involved in the generation of the picritic glasses in any of these models.

     

Equilibrium between Clinopyroxene and Host Rocks: Implication for the Magmatic Source and Evolution of Alkali Basalts of the Taohekou Formation in the Northern Daba Mountains, China

The Taohekou Formation is a volcanic-sedimentary terrane formed in the early Silurian in the northern Daba Mountains, China. The volcanic rocks, with dominant alkali basalts and minor mantle xenoliths, are enriched in clinopyroxene phenocrysts. Geochemical analysis shows that the composition of clinopyroxenes from different lithofacies has a close affinity. There is a liner correlation present in composition of clinopyroxenes (including phenocryst, microcrystal and xenocryst) from coarse porphyritic basalts, pillow or fine porphyritic basalts to amygdaloidal basalts. All the clinopyroxenes, except the clinopyroxenes in mantle xenoliths, show a similar pattern of trace elements and REE, which indicates that they are likely products of successive fractional crystallization from cognate magma. Clinopyroxenes in mantle xenoliths, however, are mantle xenocrysts. The crystallization pressure of clinopyroxenes gradually decreases from mantle xenolith, deep-seated xenocryst, coarse porphritic basalts, pillow or fine porphritic basalts, to amygdaloidal basalts, which are 1.92-4.41 GPa, 1.18-2.36 GPa, 1.13-2.05 GPa, 0.44-0.62 GPa and 0.14-0.28 GPa respectively. Calculation results suggest that the primary magma originated from a mantle region deeper than 68 km and stagnates in intervals of 37-68 km, 15-20 km and 5-9 km during its ascent. The alkali basalts are characterized by increasing concentrations of Si and alkaline with the magmatic evolution. Meanwhile, they are markedly enriched in LREE, and the patterns of trace elements and REE are similar to those of oceanic island basalts.     

Petrogenesis of the Apollo 14 high-alumina basalts: Implications from ion microprobe analyses

In this study, ion microprobe analyses of individual minerals are used to investigate the petrogenesis of the Apollo 14 high-Al basalts. We use trace element concentrations from individual minerals in the Apollo 14 high-Al basalts to evaluate both endogenic and exogenic models. The data show that if the Apollo 14 high-Al basalts were produced by melting within the lunar mantle, these basalts cannot be related to one another by closed-system fractional crystallization of a single basaltic melt. Rather, the trace element data show that variable amounts of a KREEP component were added to the basalts by either assimilation, mixing into mantle sources, or impact melting. Single-stage assimilation-fractional crystallization models can only explain the data from this study if an excessively large mass of urKREEP is assimilated into the parent magma before olivine crystallization. Alternatively, the trace element data can be explained if the Apollo 14 high-Al basalts were produced by melting multiple Al-rich mantle sources that contain different amounts of urKREEP. Finally, for impact melting to be a relevant process, the data require that multiple large impact melts be formed from mixed KREEP-rich target lithologies. The resulting impact melts must then crystallize to produce basalts with igneous textures, high Al₂O₃ concentrations, uniform major element compositions, and a wide range of incompatible trace element concentrations.     

月球形成和演化的关键科学问题

我国正开展月球探测和科学研究,其成果将加深认识月球的组成、结构以及形成和演化,同时揭示地球的早期历史。通过对月球研究成果的总结,就月球形成和演化关键科学问题的现状作了较为详细的说明,从而为我国月球探测和科学研究提供有益的启示。主要的关键科学问题包括：地球一月球体系的大撞击成因、月球岩浆洋与月壳形成、39亿年大撞击事件、玄武岩浆喷发与月球内部结构和月球南极艾特肯（Aitken）撞击盆地的形成等。     

月球引力场和磁场探测新进展

简要地回顾了前苏联、美国探测月球引力场和磁场的历史,介绍了各国的探月计划;较详细地介绍和分析了美国克莱门汀(Clementine,Cl）和月球探测者(Lunar Prospector,LP)两艘飞船探测月球引力场和磁场的最新成果：Konopliv A S等根据月球探测者数据绘制的最新月球重力图(LP100j,月球正面n=90,背面n=60),Halekas J S等根据月球探测者电子反射测量数据绘制的第一张全月球磁场图,Zuber M T等根据克莱门汀数据制作的月球(自由空间和布格)重力异常图和月壳厚度图;提出了开展有关研究工作的几点建议。     

论月球不对称的演化

月球形成初期有一个固体内核,表层是岩浆“海洋”重力分异,冷却固结形成月壳,由于同步自转,其一侧总是向着地球,在地球引力场作用下,使固体内核向地球一侧移动,月壳表层轻的物质向背地球一侧漂浮,所以月亮背地球一侧１５０公里,向地球一侧仅有６０公里,这种演化机制使大部分月海分布在向地球一侧。