Entanglement of Pinnipeds in Synthetic Materials at South-east Farallon Island, California, 1976–1998

Entanglement records of hauled out pinnipeds are useful for monitoring trends in impacts of synthetic materials, a principal contaminant, upon pinniped populations. This report documents entanglement of five species (California Sea Lions, Northern Elephant Seals, Steller Sea Lions, Pacific Harbor Seals, and Northern Fur Seals) at South-east Farallon Island (SEFI), an island in Northern California, 1976–1998, when a total of 914 pinnipeds were observed entangled in or with body constrictions from synthetic material. There was a significant decrease in entangled Northern Elephant Seals over the study period. Of the 27 Steller Sea Lions observed entangled, 37% were adult Steller Sea Lions entangled in salmon fishing gear. This report highlights an ongoing problem of entanglement of pinnipeds in synthetic materials in Northern California.     

Contamination of Tris(4-Chlorophenyl) Methane and Tris(4-Chlorophenyl) Methanol in Marine Mammals from Russia and Japan: Body Distribution, Bioaccumulation and Contamination Status

Four seal species (Phoca caspica, Phoca sibirica, Phoca hispida and Phoca largha) and one whale (Orcinus orca) from Russia and Japan were examined to determine the body distribution, bioaccumulation and contamination status of tris(4-chlorophenyl) methane (TCPMe) and tris(4-chlorophenyl) methanol (TCPMOH). Lipid normalized concentrations of TCPMe and TCPMOH were comparable in various organs and tissues, implying that their body distribution is followed to the lipid-dependent accumulation, similar to that for other organochlorines. The highest body burden of these compounds was found in the blubber. Bioaccumulation potential of TCPMe and TCPMOH was high and comparable to PCBs and DDTs. Relatively higher concentrations of TCPMe and TCPMOH were observed in Caspian seal than in other seal species examined. TCPMOH concentration in killer whale was the highest of the marine mammals examined. Another peak detected had similar mass spectrum to TCPMOH, however, at a different retention time, suggesting the presence of an isomer of TCPMOH.     

Organochlorine Pesticide Residues in Soils and Sediments of the Herbert and Burdekin River Regions, North Queensland – Implications for Contamination of the Great Barrier Reef

Organochlorine pesticides were widely used in the Australian sugarcane industry from the early 1950s until the late 1980s. Erosion of sugarcane soils and subsequent transport of sediment bound contaminants in river run-off to the Great Barrier Reef lagoon is a growing concern as the cane industry continues to expand. Organochlorine pesticide residues can be used as tracers to examine the worst-case scenario of the spatial extent to which currently used, though less persistent, organic agricultural pesticides might extend. The coastal alluvial flood-plains of the Herbert and Burdekin Rivers in North Queensland have sugarcane growing as the major coastal land-use. Sediment cores and surface sediment samples were collected from near-shore coastal regions of the Herbert and Burdekin Rivers. In addition, soil samples from cane-fields in the two catchments were collected. Analyses of the marine surface sediment samples and three sediment cores revealed the absence of detectable concentrations of organochlorine pesticides (<5 pg/g). However, easily detectable concentrations were found in the sugarcane soil samples (0.01–45 ng/g).     

Chitosan – A Sizing Agent in Fabric Production – Development and Ecological Evaluation

Chitosan, a natural polymer, was investigated as a possible sizing agent in fabric production by appropriate modification in the textile industry. Based on recipe developments at a laboratory‐scale, the ecological and economical potential of mainly cotton yarns were demonstrated and developed. Subsequent tests within the scope of industrial production confirmed the findings of the basic developments. As an interesting alternative to the conventional sizing process involving the removal of the size after weaving, the use of appropriate processing technologies makes it possible to apply chitosan in the form of a sizing agent resistant to wash‐out processes. Therefore, the wash‐out process and the combined wastewater loading can be avoided and the properties of chitosan can be used beneficially in the later applications of the fabric. The traditional method of sizing and weaving developments as well as the analyses of material recycling showed the possibilities of using closed circuits in textile production involving sizing agent and water. It is possible that a chitosan‐specific enzyme suitable for production conditions, which facilitates the wash‐out process in combination with the biodegradation of the wastewater in a sewage plant, could be developed.     

Application of Agro‐Based Biomasses for Zinc Removal from Wastewater – A Review

Zinc remediation of aqueous streams is of special concern due to its highly toxic and persistent nature. Conventional treatment technologies for the removal of zinc are not economical and further generate huge quantity of toxic chemical sludge. Biosorption is emerging as a potential alternative to the existing conventional technologies for the removal of metal ions from aqueous solutions. Mechanisms involved in the biosorption process include chemisorption, complexation, adsorption–complexation on surface and pores, ion exchange, microprecipitation, heavy metal hydroxide condensation onto the bio surface, and surface adsorption. Biosorption largely depends on parameters such as pH, the initial metal ion concentration, biomass concentration, presence of various competitive metal ions in solution, and to a limited extent on temperature. Biosorption using biomass such as agricultural wastes, industrial residues, municipal solid waste, biosolids, food processing waste, aquatic plants, animal wastes, etc., is regarded as a cost‐effective technique for the treatment of high volume and low concentration complex wastewaters containing zinc metal. Very few reviews are available where readers can get an overview of the sorption capacities of agro based biomasses used for zinc remediation together with the traditional remediation methods. The purpose of this review article is to provide the scattered available information on various aspects of utilization of the agro based biomasses for zinc metal ions removal. An extensive table summarizes the sorption capacities of various adsorbents. These biosorbents can be modified using various methods for better efficiency and multiple reuses to enhance their applicability at industrial scale. We have incorporated most of the valuable available literature on zinc removal from waste water using agro based biomasses in this review.     

Quantifying Inputs of Pesticides to the Great Barrier Reef Marine Park – A Case Study in the Herbert River Catchment of North-East Queensland

The Great Barrier Reef Marine Park (GBRMP) is an ecosystem whose ecological features are recognized internationally. There is a need to evaluate the impacts of historical and contemporary changes in land use on the GBRMP. This paper quantifies pesticide inputs in the Herbert River catchment of North Queensland in the context of changes in land use over the last 100 years. We show that three major phases of rural land use and land cover change have occurred, with large areas of native vegetation converted to agricultural production. The increase in agricultural land has seen a corresponding increase in the area receiving pesticides. We present data showing application histories for organochlorine, organophosphate, phenoxy, triazine, urea, mercurial and azole group pesticides. While the fate of these pesticides in aquatic and marine systems is largely unknown, these trends pose a significant challenge for agricultural industries in complying with the principles of ecologically sustainable development (ESD).     

Modelling exposure of oceanic higher trophic-level consumers to polychlorinated biphenyls: Pollution ‘hotspots’ in relation to mass mortality events of marine mammals

Marine mammals in the past mass mortality events may have been susceptible to infection because their immune systems were suppressed through the bioaccumulation of environmental pollutants such as polychlorinated biphenyls (PCBs). We compiled mortality event data sets of 33 marine mammal species, and employed a Finely-Advanced Transboundary Environmental model (FATE) to model the exposure of the global fish community to PCB congeners, in order to define critical exposure levels (CELs) of PCBs above which mass mortality events are likely to occur. Our modelling approach enabled us to describe the mass mortality events in the context of exposure of higher-trophic consumers to PCBs and to identify marine pollution ‘hotspots’ such as the Mediterranean Sea and north-western European coasts. We demonstrated that the CELs can be applied to quantify a chemical pollution Planetary Boundary, under which a safe operating space for marine mammals and humanity can exist.     

Geomagnetic field variations between chrons 33r and 19r (83–41 Ma) from sea-surface magnetic anomaly profiles

Sea-surface magnetic profiles exhibit coherent short wavelength “micro-anomalies” (or “tiny wiggles”) superimposed to the main anomalies due to reversals. In this study, we investigate the nature and distribution of these tiny wiggles on oceanic crust formed during the  42 Myr-long period following the Cretaceous Normal Superchron. To this end, we compute stacks of anomaly profiles from different areas in the Indian and the Pacific oceans. Using a simple method based on upward continuation, we demonstrate that, the tiny wiggles are consistent worldwide although their patterns exhibit different resolutions at different spreading rates. They are therefore confidently ascribed to past fluctuations of the geomagnetic dipole moment. A high resolution record of these fluctuations is obtained by selecting and stacking profiles from areas with the highest spreading rates. Modeling the micro-anomalies as short magnetic polarity intervals yields durations for these intervals generally shorter than 10 kyr, likely too short to be indeed “true” subchrons. Moreover, the number of detected tiny wiggles clearly depends on the spreading rate. These results support geomagnetic intensity fluctuations as being the cause of most tiny wiggles, as also suggested by recent magnetostratigraphic data. The tiny wiggles are uniformly distributed within chrons, indicating that paleointensity fluctuations are neither inhibited after, nor enhanced before, a reversal beyond a “blind” zone of about 10 km (corresponding to 80 to 250 kyr depending on the spreading rate) for which the anomalies due to reversals prevent the detection of tiny wiggles. Most tiny wiggles probably represent a filtered record of a uniform secular variation regime, as suggested by their uniform spatial distribution over the whole investigated period.     

Rainfall–runoff trends in the south‐eastern USA: 1938–2005

An extensive dataset (230 precipitation gauges and 79 stream gauges) was used to analyse rainfall–runoff relationships in 10 subregions of a 482000 km² area in the south‐eastern USA (Maryland, Virginia, North Carolina, South Carolina and Georgia). The average annual rainfall and runoff for this study area between 1938 and 2005 were 1201 and 439 mm, respectively. Average runoff/rainfall ratios during this period varied between 0·24 in the southernmost Coastal Plain subregion to 0·64 in the Blue Ridge Province. Watershed elevation and relief are the principal determinants governing the conversion of rainfall to runoff. Temporal rainfall variation throughout the south‐eastern USA ranges from ～40% above and below normal while the variation for runoff is higher, from ? 75% to + 100%. In any given year there can exist a ± 25–50% error in predicted runoff deviation using the annual rainfall–runoff regression. Fast Fourier Transform and autoregressive spectral analysis revealed dominant cyclicities for rainfall and runoff between 14 and 17 years. Secondary periodicities were typically between 6–7 and 10–12 years. The inferred cyclicity may be related to ENSO and/or Central North Pacific atmospheric phenomena. Mann–Kendall analyses indicate that there were no consistent statistically significant temporal trends with respect to south‐eastern US rainfall and runoff during the study period. The results of U‐tests similarly indicated that rainfall between 1996 and 2005 was not statistically higher or lower than during earlier in the study period. Copyright © 2008 John Wiley & Sons, Ltd.     

The droughts of 1996–1997 and 2004–2005 in Amazonia: hydrological response in the river main‐stem

Severe hydrological droughts in the Amazon have generally been associated with strong El Niño events. More than 100 years of stage record at Manaus harbour confirms that minimum water levels generally coincide with intense warming in the tropical Pacific sea waters. During 2005, however, the Amazon experienced a severe drought which was not associated with an El Niño event. Unless what usually occurs during strong El Niño events, when negative rainfall anomalies usually affect central and eastern Amazon drainage basin; rainfall deficiencies in the drought of 2005 were spatially constrained to the west and southwest of the basin. In spite of this, discharge stations at the main‐stem recorded minimum water levels as low as those observed during the basin‐wide 1996–1997 El Niño‐related drought. The analysis of river discharges along the main‐stem and major tributaries during the drought of 2004–2005 revealed that the recession on major tributaries began almost simultaneously. This was not the case in the 1996–1997 drought, when above‐normal contribution of some tributaries for a short period during high water was crucial to partially counterbalance high discharge deficits of the other tributaries. Since time‐lagged contributions of major tributaries are fundamental to damp the extremes in the main‐stem, an almost coincident recession in almost all tributaries caused a rapid decrease in water discharges during the 2005 event. Copyright © 2010 John Wiley & Sons, Ltd.     

Machine Learning Approach to Predict Sediment Load – A Case Study

In this study, a novel machine learning technique called the support vector machine (SVM) method is proposed as a new predictive model to predict sediment loads in three Malaysian rivers. The SVM is employed without any restriction to an extensive database compiled from measurements in the Muda, Langat, and Kurau rivers. The SVM technique demonstrated a superior performance compared to other traditional sediment‐load methods. The coefficient of determination, 0.958, and the mean square error, 0.0698, of the SVM method are higher than those of the traditional method. The performance of the SVM method demonstrates its predictive capability and the possibility of the generalization of the model to nonlinear problems for river engineering applications.     

Seasonal flooding in Bangladesh – variability and predictability

At present, Bangladesh has a flood forecasting lead time of only 3 days or so. There is demand for a forecasting lead time of a month to a season. The primary objectives of this paper are to study the variability and predictability of seasonal flooding in Bangladesh, as revealed by large‐scale predictors of the climate across the watersheds. To explore the source of predictability, accessible Bangladesh hydrological indicators are related to large‐scale oceanic variability and to large‐scale atmospheric circulation patterns predicted by general circulation models (GCMs). Correlation analyses between the flood‐affected area (FAA) for July–September and tropical sea‐surface temperature (SST) indicate connections to tropical Pacific and Indian Ocean SSTs, at a short lead time of a month or so. These are related to El Niño–southern oscillation (ENSO). Correlations between the SSTs of the preceding October–December and the July–September FAA are weaker but notable. Forecasts of the FAA using the leading principal components (PCs) of SST were made, which provided good skill with a lead time of a month or so. The streamflows and rainfall observed in Bangladesh have been added to these prediction models. Finally, the SST PCs were replaced with PCs of GCM prediction fields (precipitation). The prediction models at short lead time that were constructed for FAA were of generally similar levels of skill to that for SST. This is encouraging, as it suggests that linkages with SST can be successfully recovered in a physical model of the climate system in Bangladesh. This study concludes that seasonal flood prediction in Bangladesh is possible from the unusually warm or cold SST in parts of the tropics. This predictability can be enhanced with the information achievable from monitoring the downstream streamflows (which are generated mainly from upstream rainfall conditions) in advance of the flooding season. Finally, this study recommends formalizing a regional cooperation among the countries in the principal co‐basin areas of the Ganges–Brahmaputra–Meghna to achieve this goal. Copyright © 2006 John Wiley & Sons, Ltd.     

Trends in rainfall and temperature in the Peruvian Amazon–Andes basin over the last 40 years (1965–2007)

The hydroclimatology of the Peruvian Amazon–Andes basin (PAB) which surface corresponding to 7% of the Amazon basin is still poorly documented. We propose here an extended and original analysis of the temporal evolution of monthly rainfall, mean temperature (T_mean), maximum temperature (T_max) and minimum temperature (T_min) time series over two PABs (Huallaga and Ucayali) over the last 40 years. This analysis is based on a new and more complete database that includes 77 weather stations over the 1965–2007 period, and we focus our attention on both annual and seasonal meteorological time series. A positive significant trend in mean temperature of 0.09 °C per decade is detected over the region with similar values in the Andes and rainforest when considering average data. However, a high percentage of stations with significant T_mean positive trends are located over the Andes region. Finally, changes in the mean values occurred earlier in T_max (during the 1970s) than in T_min (during the 1980s). In the PAB, there is neither trend nor mean change in rainfall during the 1965–2007 period. However, annual, summer and autumn rainfall in the southern Andes presents an important interannual variability that is associated with the sea surface temperature in the tropical Atlantic Ocean while there are limited relationships between rainfall and El Niño‐Southern Oscillation (ENSO) events. On the contrary, the interannual temperature variability is mainly related to ENSO events. Copyright © 2012 John Wiley & Sons, Ltd.     

Mass Diving Tourism – A New Dimension Calls for New Management Approaches

Diving has become a booming branch of the tourism business. The economies of many countries with reef-lined coasts depend on high numbers of tourist divers; the resultant degradation of reefs by mechanical damage is accepted due to the short-term gain from the tourism business. Many activities of recreational diving do not particularly require coral reefs – any varied three-dimensional structure (e.g. a wreck) may be sufficiently attractive. The conflict between the needs of nature conservation and the economic interests of diving tourism can be mitigated by the formation of artificial underwater attractions as reef substitutes. Based on experiments in the northern Red Sea, we propose to deposit calcium minerals from the seawater in situ by electrolysis on a template of any desired shape. After transplantation of living coral fragments, a diverse community will develop. With this method different modules can be designed and formed on the seabed which can serve different needs such as diver training, environmental education and recreation as well as reef rehabilitation. By a combination of such modules, a recreational underwater park can be formed well suited to function as a DAD (diver aggregation device) and therefore, divert diver pressure from the natural reef.     

Modelling the effect of Pliocene–Quaternary changes in sea level on stable and tectonically active land masses

A mathematical model was used to examine the effect of Pliocene and Quaternary changes in sea level on the development of tectonically active and inactive rock coasts. The model calculated rates of mechanical wave erosion according to such factors as the deep water wave regime, bottom topography and surface roughness, and the resistance of the rocks. Subaerial terraces were truncated or eliminated by subsequent terrace formation at lower elevations, especially on steeply sloping landmasses experiencing slow rates of uplift. Submarine terraces formed during glacial stillstands were best preserved when rapid subsidence quickly carried them below the level of wave action. On slowly subsiding landmasses, submarine terraces formed during interglacials and glacial periods experienced repeated erosional modification during subsequent periods of rising and falling sea level and were generally less distinctive. On rapidly rising or subsiding (>5 mm yr^‐1) landmasses, terraces that formed during interglacial stages alternated, above and below present sea level, with terraces formed during glacial stages. Despite some differences in terrace occurrence and elevational distribution, it may be difficult to distinguish profiles cut during accelerating or decelerating uplift. The amount of erosion during sea level oscillations increases with oscillation amplitude and the larger oscillations in the middle to late Quaternary were therefore more conducive to erosion than the smaller oscillations of the Pliocene and early Quaternary. The effect of oscillation amplitude may have been countered during the earlier stages of profile development, however, by steeper submarine gradients and reduced rates of wave attenuation. Copyright © 2014 John Wiley & Sons, Ltd.