Titan's surface: Search for spectral diversity and composition using the Cassini VIMS investigation

The surface composition of Titan is of great importance for understanding both the internal evolution of Titan and its atmosphere. The Visual and Infrared Mapping Spectrometer (VIMS) investigation on Cassini is observing Titan from 0.35 to 5.11 μm with spatial resolution down to a few kilometers during each flyby of the spacecraft as it orbits Saturn. Our search for spectral diversity using seven methane transmission windows in the near infrared suggests that spectrally distinct units exist on the surface of Titan and that most of the surface can be modeled using only a few distinct spectral units: water frost, CO₂ frost, atmospheric scattering, and an unknown material bright at 2 μm. A dark, spectrally neutral material is also implied. Use of an atmospheric scattering component with spectral mixing analysis may provide a method for partially removing atmospheric effects. In some locations, atmospheric scattering accounts for the majority of the signal. There are also small regions with unusual spectra that may be due to low signal and high noise and/or may be exotic materials of interest. Further, we searched within the methane windows for spectral features associated with Titan's surface. Only the 5-μm and, to a lesser extent, the 2-μm window provide a reasonable opportunity for this, as the shorter-wavelength windows are too narrow and the 2.8-μm window is cluttered with an unknown atmospheric constituent. We find evidence for only one spectral feature: near 4.92 μm for the 5-μm bright Tui Regio region. CO₂ frost with grains smaller than about 10 μm is the best candidate we have found so far to explain this absorption as well as the feature's spectral contrast between the 2.7- and the 2.8-μm atmosphere subwindows. This suggested CO₂ identification is supported by the presence of an endmember in the spectral mixture analysis that is consistent with CO₂ frost with large grain sizes. We find no other absorption features that are statistically significant, including those reported earlier by others. These results are consistent with but greatly extend our early analysis that treated only the Ta data set [McCord, T.B., et al., 2006a. Planet. Space Sci. 54, 1524-1539]. In the spectral feature search process, we explored in detail the noise characteristics of the VIMS data within the 5-μm window, which has generally very low signal (4-20 DN), due to the measurement conditions and low illumination levels. We find noise of nearly Gaussian statistics except for some erratic darks and noise spikes, and the data set seems generally well behaved. We present examples of our attempt to improve on the standard VIMS pipeline data calibration.     

Titan's atmospheric chemistry: Photolysis of gas mixtures containing hydrogen cyanide and carbon monoxide at 185 and 254 nm

The formation of organic compounds in the atmosphere of Titan is an ongoing process of the generation of complex organics from the simplest hydrocarbon, methane. Solar radiation and magnetosphere electrons are the main energy sources that drive the reactions in Titan's atmosphere. Since energy from solar radiation is 200 times greater than that from magnetosphere electrons, we have investigated the products formed by the action of UV radiation (185 and 254 nm) on a mixture of gases containing nitrogen, methane, hydrogen, acetylene, ethylene, and cyanoacetylene, the basic gas mixture (BGM) that simulates aspects of Titan's atmosphere using a flow reactor [Tran, B.N., Ferris, J.P., Chera, J.J., 2003a. Icarus 162, 114-124; Tran, B.N., Joseph, J.C., Force, M., Briggs, R.G., Vuitton, V., Ferris, J.P., 2005. Icarus 177, 106-115]. The present research extends these studies by the addition of carbon monoxide and hydrogen cyanide to the BGM. Quantum yields for the loss of reactants and the formation of volatile products were determined and compared with those measured in the absence of the hydrogen cyanide and carbon monoxide. The GCMS analyses of the volatile photolysis products from the BGM, with added hydrogen cyanide, had a composition similar to that of the BGM while the photolysis products of the BGM with added carbon monoxide contained many oxygenated compounds. The infrared spectrum of the corresponding solid product revealed the absorption band of a ketone group, which was probably formed from the reaction of carbon monoxide with the free radicals generated by photolysis of acetylene and ethylene. Of particular interest was the observation that the addition of HCN to the gas mixture only resulted in a very small change in the C/N ratio and in the intensity of the CN frequency at 2210 cm⁻¹ in the infrared spectrum suggesting that little HCN is incorporated into the haze analog. The C/N ratio of the haze analogs was found to be in the 10-12 range. The UV spectra of the solid products formed when HCN or CO added to the BGM is similar to the UV absorption formed from the BGM alone. This result is consistent with absence of additional UV chromophores to the solid product when these mixtures are photolyzed. The following photoproducts, which were not starting materials in our photochemical studies, have been observed on Titan: acetonitrile, benzene, diacetylene, ethane, propene, propane, and propyne.     

Titan's atmosphere and surface: Parallels and differences with the primitive Earth

In spite of a marked resemblance with our planet, Titan should not be hastily considered as another Earth but rather as a useful tool in the study of chemical and physical processes in the primitive Earth.     

The reflectance spectrum of Titan's surface at the Huygens landing site determined by the descent imager/spectral radiometer

The descent imager/spectral radiometer aboard the Huygens probe successfully acquired images and spectra of the surface of Titan. To counter the effects of haze and atmospheric methane absorption it carried a surface science lamp to illuminate the surface just before landing. We reconstruct the reflectance spectrum of the landing site in the 500-1500 nm range from downward looking visual and infrared spectrometers data that show evidence of lamp light. Our reconstruction is a followup to the analysis by Tomasko et al. [2005. Rain, winds and haze during the Huygens probe's descent to Titan's surface. Nature 438, 765-778], who scaled their result to the ratio of the up- and down flux measured just before landing. Instead, we use the lamp flux from the calibration experiment, and find a significantly higher overall reflectance. We attribute this to a phase angle dependance, possibly representing the opposition surge commonly encountered on solar system bodies. The reconstruction in the visible wavelength range is greatly improved. Here, the reflectance spectrum features a red slope, consistent with the presence of organic material. We confirm the blue slope in the near-IR, featureless apart from a single shallow absorption feature at 1500 nm. We agree with Tomasko et al. that the evidence for water ice is inconclusive. By modeling of absorption bands we find a methane mixing ratio of 4.5±0.5% just above the surface. There is no evidence for the presence of liquid methane, but the data do not rule out a wet soil at a depth of several centimeters.     

Space weathering on Eros: Constraints from albedo and spectral measurements of Psyche crater

Abstract— We present combined multi‐spectral imager (MSI) (0.95 μm) and near‐infrared spectrometer (NIS) (0.8–2.4 μm) observations of Psyche crater on S‐type asteroid 433 Eros obtained by the Near‐Earth Asteroid Rendezvous (NEAR)—Shoemaker spacecraft. At 5.3 km in diameter, Psyche is one of the largest craters on Eros which exhibit distinctive brightness patterns consistent with downslope motion of dark regolith material overlying a substrate of brighter material. At spatial scales of 620 m/ spectrum, Psyche crater wall materials exhibit albedo contrasts of 32–40% at 0.946 μm. Associated spectral variations occur at a much lower level of 4–8% (±2–4%). We report results of scattering model and lunar analogy investigations into several possible causes for these albedo and spectral trends: grain size differences, olivine, pyroxene, and troilite variations, and optical surface maturation. We find that the albedo contrasts in Psyche crater are not consistent with a cause due solely to variations in grain size, olivine, pyroxene or lunar‐like optical maturation. A grain size change sufficient to explain the observed albedo contrasts would result in strong color variations that are not observed. Olivine and pyroxene variations would produce strong band‐correlated variations that are not observed. A simple lunar‐like optical maturation effect would produce strong reddening that is not observed. The contrasts and associated spectral variation trends are most consistent with a combination of enhanced troilite (a dark spectrally neutral component simulating optical effects of shock) and lunar‐like optical maturation. These results suggest that space weathering processes may affect the spectral properties of Eros materials, causing surface exposures to differ optically from subsurface bedrock. However, there are significant spectral differences between Eros' proposed analog meteorites (ordinary chondrites and/or primitive achondrites), and Eros' freshest exposures of subsurface bright materials. After accounting for all differences in the measurement units of our reflectance comparisons, we have found that the bright materials on Eros have reflectance values at 0.946 μm consistent with meteorites, but spectral continua that are much redder than meteorites from 1.5 to 2.4 μm. Most importantly, we calculate that average Eros surface materials are 30–40% darker than meteorites.     

Titan's surface and rotation: new results from Voyager 1 images

We present an analysis of images of Saturn's moon Titan, obtained by the Voyager 1 spacecraft on November 8-12, 1980. Orange filter (590-640 nm) images were photometrically corrected and a longitudinal average removed from them, leaving residual images with up to 5% contrast, and dominated by surface reflectivity. The resultant map shows the same regions observed at 673 nm by the Hubble Space Telescope (HST). Many of the same albedo features are present in both datasets, despite the short wavelength (600 nm) of the Voyager 1 images. A very small apparent longitudinal offset over the 14 year observation interval places tight constraints on Titan's rotation, which appears essentially synchronous at 15.9458±0.0016 days (orbital period =15.945421±0.000005 days). The detectability of the surface at such short wavelengths puts constraints on the optical depth, which may be overestimated by some fractal models.     

Venus: Cloud optical depth and surface albedo from Venera 8

We have used the measurements of the solar flux obtained by the Venera 8 spacecraft inside the atmosphere of Venus and the values of the Venus spherical albedo to deduce the characteristics of the clouds and of the ground. The method used is the exponential kernel approximation and the results have been tested by exact computations with the spherical harmonics method.A cloud layer with an optical thickness $\text{τ}{}_1\text{? 144}$, an albedo for single scattering $\text{ω}{}_0\text{= 0.9998}$ in the rear infrared, above a Rayleigh layer between 0 and 32 km and a ground of reflectivity ? = 0.4, gives a good agreement with the experimental results. A model with two cloud layers is also discussed.     

Observing the martian surface albedo pattern: Comparing the AEOS and TES data sets

High spatial resolution images of Mars were acquired with the Advanced Electro-Optical System (AEOS) 3.63-meter telescope at the Maui Space Surveillance System (MSSS) during both the 2001 and 2003 Mars apparitions. Comparisons are made of the surface albedo patterns obtained from these AEOS images to the surface albedo maps constructed from the Mars Global Surveyor (MGS) Thermal Emission Spectrometer (TES) data taken during the same time periods. These comparisons demonstrate that the images provide albedo information in a limited area surrounding the sub-Earth point that is consistent with the TES-derived albedo field. Additionally, it is shown that by employing adaptive optics (AO), the typical ground-based observing season of Mars can be extended. This is the only known published AO data set of Mars with temporal coverage over an entire apparition. Changes in the surface albedo affect the local ground temperature, which impacts the depth of the planetary boundary layer (PBL) above the surface. Since it is the state of the PBL that controls surface/atmospheric interaction, albedo variations have the power to alter the amount of dust that is lifted. A one-dimensional radiative/convective version of the NASA Ames Mars General Circulation Model is used to demonstrate that the measured albedo variations can alter the daytime ground temperatures by as much as 5 K, which in turn alters the structure of the planetary boundary layer (PBL). Therefore, albedo changes are thermodynamically important, and the ability to characterize them, should orbital observations become unavailable, is a valuable capability.     

Titan's surface from the Cassini RADAR radiometry data during SAR mode

We present initial results on the calibration and interpretation of the high-resolution radiometry data acquired during the Synthetic Aperture Radar (SAR) mode (SAR-radiometry) of the Cassini Radar Mapper during its first five flybys of Saturn's moon Titan.We construct maps of the brightness temperature at the 2-cm wavelength coincident with SAR swath imaging. A preliminary radiometry calibration shows that brightness temperature in these maps varies from 64 to 89 K. Surface features and physical properties derived from the SAR-radiometry maps and SAR imaging are strongly correlated; in general, we find that surface features with high radar reflectivity are associated with radiometrically cold regions, while surface features with low radar reflectivity correlate with radiometrically warm regions. We examined scatterplots of the normalized radar cross-section σ⁰ versus brightness temperature, outlining signatures that characterize various terrains and surface features. The results indicate that volume scattering is important in many areas of Titan's surface, particularly Xanadu, while other areas exhibit complex brightness temperature variations consistent with variable slopes or surface material and compositional properties.     

Mapping Titan's surface features within the visible spectrum via Cassini VIMS

Titan shows its surface through many methane windows in the 1–5 $\mathrm{\mu }\mathrm{m}$ region. Windows at shorter wavelengths also exist, polluted by scattering off of atmospheric haze that reduces the surface contrast. At visible wavelengths, the surface of Titan has been observed by Voyager I, the Hubble Space Telescope, and ground-based telescopes. We present here global surface mapping of Titan using the visible wavelength channels from Cassini's Visual and Infrared Mapping Spectrometer (VIMS). We show global maps in each of the VIMS-V channels extending from 0.35 to 1.05 $\mathrm{\mu }\mathrm{m}$. We find methane windows at 0.637, 0.681, 0.754, 0.827, 0.937, and $1.046\mathrm{\mu }\mathrm{m}$ and apply an RGB color scheme to the 0.754, 0.827 and $0.937\mathrm{\mu }\mathrm{m}$ windows to search for surface albedo variations. Our results show that Titan appears gray at visible wavelengths; hence scattering albedo is a good approximation of the Bond albedo. Maps of this genre have already been made and published using the infrared channels of VIMS. Ours are the first global maps of Titan shortward of $0.938\mathrm{\mu }\mathrm{m}$. We compare the older IR maps to the new VIMS-V maps to constrain surface composition. For instance Tui Regio and Hotei Regio, referred to as $5\text{‐}\mathrm{\mu }\mathrm{m}$ bright spots in previous papers, do not distinguish themselves at all visible wavelengths. The distinction between the dune areas and the bright albedo spots, however, such as the difference between Xanadu and Senkyo, is easily discernible. We employ an empirically derived algorithm to remove haze layers from Titan, revealing a better look at the surface contrast.     

Electrical properties of Titan's surface from Cassini RADAR scatterometer measurements

We report regional-scale low-resolution backscatter images of Titan's surface acquired by the Cassini RADAR scatterometer at a wavelength of 2.18-cm. We find that the average angular dependence of the backscatter from large regions and from specific surface features is consistent with a model composed of a quasi-specular Hagfors term plus a diffuse cosine component. A Gaussian quasi-specular term also fits the data, but less well than the Hagfors term. We derive values for the mean dielectric constant and root-mean-square (rms) slope of the surface from the quasi-specular term, which we ascribe to scattering from the surface interface only. The diffuse term accommodates contributions from volume scattering, multiple scattering, or wavelength-scale near-surface structure. The Hagfors model results imply a surface with regional mean dielectric constants between 1.9 and 3.6 and regional surface roughness that varies between 5.3° and 13.4° in rms-slope. Dielectric constants between 2 and 3 are expected for a surface composed of solid simple hydrocarbons, water ice, or a mixture of both. Smaller dielectric constants, between 1.6 and 1.9, are consistent with liquid hydrocarbons, while larger dielectric constants, near 4.5, may indicate the presence of water-ammonia ice [Lorenz, R.D., 1998. Icarus 136, 344-348] or organic heteropolymers [Thompson, W.R., Squyres, S.W., 1990. Icarus 86, 336-354]. We present backscatter images corrected for angular effects using the model residuals, which show strong features that correspond roughly to those in 0.94-μm ISS images. We model the localized backscatter from specific features to estimate dielectric constant and rms slope when the angular coverage is within the quasi-specular part of the backscatter curve. Only two apparent surface features are scanned with angular coverage sufficient for accurate modeling. Data from the bright albedo feature Quivira suggests a dielectric constant near 2.8 and rms slope near 10.1°. The dark albedo feature Shangri-La is best fit by a Hagfors model with a dielectric constant close to 2.4 and an rms slope near 9.5°. From the modeled backscatter curves, we find the average radar albedo in the same linear (SL) polarization to be near 0.34. We constrain the total-power albedo in order to compare the measurements with available groundbased radar results, which are typically obtained in both senses of circular polarization. We estimate an upper limit of 0.4 on the total-power albedo, a value that is significantly higher than the 0.21 total albedo value measured at 13 cm [Campbell, D., Black, G., Carter, L., Ostro, S., 2003. Science 302, 431-434]. This is consistent with a surface that has more small-scale structure and is thus more reflective at 2-cm than 13-cm. We compare results across overlapping observations and observe that the reduction and analysis are repeatable and consistent. We also confirm the strong correlations between radar and near-infrared images.     

Maps of Titan's surface from 1 to 2.5 μm

We have acquired resolved images of Titan with the adaptive optics systems PUEO/KIR at the CFHT (Hawaii) and NAOS/CONICA at the VLT (Chile). We report here on images and maps (when data at several orbital phases are available) of Titan's surface from observations taken during the last 4 years (2001-2004) in all the methane windows between 1 and 2.5 μm (namely, at 1.08, 1.28, 1.6, and 2 μm). We present the only complete maps of Titan currently available at 1.3 μm, a spectral window where Titan appears particularly bright in spectroscopy, with a resolution of about 200 km at best on the ground. Our surface maps show the bright and dark regions sharing Titan's landscape with as much detail as possible from the ground and with high contrast in most cases. From the information gathered by comparing the maps at different wavelengths we derive constraints on the ground's composition. Our results could complete/optimize the return of the Cassini-Huygens mission.     

Mars: The spectral albedo (0.3–2.5μ) of small bright and dark regions

A review of the available spectral geometric albedo measurements for Mars was presented earlier for the spectral region 0.3 to 1.1μ. A new observational study has greatly increased the store of data, especially for small Martian regions and for the infrared spectral region 1.0 to 2.5μ. Here we combine the new data with data both from the earlier review and, for the infrared spectral region, from the literature. We present a more complete picture of Martian spectral reflectivity properties than was available. This study should provide a more firm basis upon which models of Martian surface composition can be built. At visible wavelengths the Mars dark area Syrtis Major is red rather than green or grey in color; the bright area Arabia is even redder than Syrtis Major. Absorption bands, which differ between bright and dark areas, appear in the reflection curves. The 1μ absorption feature for dark areas is confirmed and more completely described. A previously unreported absorption band near 0.95μ for bright areas appears along with several absorption features in the infrared. The geometric albedo for Arabia reaches a maximum of about 0.43 at 1μ. The Bond albedo for this same area reaches a maximum of 60%. The bright area Arabia is occasionally three times brighter than the dark area Syrtis Major at red wavelengths. Published infrared reflection data available for Mars are not in complete agreement. Changes in brightness and color of Arabia are discussed which are not in agreement with traditional darkening wave theory.     

Titan's surface at 2.2-cm wavelength imaged by the Cassini RADAR radiometer: Calibration and first results

The first comprehensive calibration and mapping of the thermal microwave emission from Titan's surface is reported based on radiometric data obtained at 2.2-cm wavelength by the passive radiometer included in the Cassini Radar instrument. The data reported were accumulated from 69 separate observational segments in Titan passes from Ta (October 2004) through T30 (May 2007) and include emission from 94% of Titan's surface. They are diverse in the key observing parameters of emission angle, polarization, and spatial resolution, and their reduction into calibrated global mosaic maps involved several steps. Analysis of the polarimetry obtained at low to moderate resolution (50+ km) enabled integration of the radiometry into a single mosaic of the equivalent brightness temperature at normal incidence with a relative precision of about 1 K. The Huygens probe measurement of Titan's surface temperature and radiometry obtained on Titan's dune fields allowed us to infer an absolute calibration estimated to be accurate to a level approaching 1 K. The results provide evidence for a surface that is complex and varied on large scales. The radiometry primarily constrains physical properties of the surface, where we see strong evidence for subsurface (volume) scattering as a dominant mechanism that determines the emissivity, with the possibility of a fluffy or graded-density surface layer in many regions. The results are consistent with, but not necessarily definitive of a surface composition resulting from the slow deposition and processing of organic compounds from the atmosphere.     

Photometric properties of Titan''s surface from Cassini VIMS: Relevance to titan''s hemispherical albedo dichotomy and surface stability

The Visual and Infrared Mapping Spectrometer (VIMS) instrument on the Cassini Saturn Orbiter returned spectral imaging data as the spacecraft undertook six close encounters with Titan beginning 7 July, 2004. Three of these flybys each produced overlapping coverage of two distinct regions of Titan's surface. Twenty-four points were selected on approximately opposite hemispheres to serve as photometric controls. Six points were selected in each of four reflectance classes. On one hemisphere each control point was observed at three distinct phase angles. From the derived phase coefficients, preliminary normal reflectances were derived for each reflectance class. The normal reflectance of Titan's surface units at 2.0178 μm ranged from 0.079 to 0.185 for the most absorbing to the most reflective units assuming no contribution from absorbing haze. When a modest haze contribution of τ=0.1 is considered these numbers increase to 0.089–0.215. We find that the lowest three reflectance classes have comparable normal reflectance on either hemisphere. However, for the highest brightness class the normal reflectance is higher on the hemisphere encompassing longitude 14–65° compared to the same high brightness class for the hemisphere encompassing 122–156° longitude. We conclude that an albedo dichotomy observed in continental sized units on Titan is due not only to one unit having more areal coverage of reflective material than the other but the material on the brighter unit is intrinsically more reflective than the most reflective material on the other unit. This suggests that surface renewal processes are more widespread on Titan's more reflective units than on its less reflective units.

We note that one of our photometric control points has increased in reflectance by 12% relative to the surrounding terrain from July of 2004 to April and May of 2005. Possible causes of this effect include atmospheric processes such as ground fog or orographic clouds; the suggestion of active volcanism cannot be ruled out.

Several interesting circular features which resembled impact craters were identified on Titan's surface at the time of the initial Titan flyby in July of 2004. We traced photometric profiles through two of these candidate craters and attempted to fit these profiles to the photometric properties expected from model depressions. We find that the best-fit attempt to model these features as craters requires that they be unrealistically deep, approximately 70 km deep. We conclude that despite their appearance, these circular features are not craters, however, the possibility that they are palimpsests cannot be ruled out.

We used two methods to test for the presence of vast expanses of liquids on Titan's surface that had been suggested to resemble oceans. Specular reflection of sunlight would be indicative of widespread liquids on the surface; we found no evidence of this. A large liquid body should also show uniformity in photometric profile; we found the profiles to be highly variable. The lack of specular reflection and the high photometric variability in the profiles across candidate oceans is inconsistent with the presence of vast expanses of flat-lying liquids on Titan's surface. While liquid accumulation may be present as small, sub-pixel-sized bodies, or in areas of the surface which still remain to be observed by VIMS, the presence of large ocean-sized accumulations of liquids can be ruled out.

The Cassini orbital tour offers the opportunity for VIMS to image the same parts of Titan's surface repeatedly at many different illumination and observation geometries. This creates the possibility of understanding the properties of Titan's atmosphere and haze by iteratively adapting models to create a best fit to the surface reflectance properties.