Chemical effects of irregular interstellar oxide grains

The importance of chemically-active geometrical surface sites on the surfaces of interstellar oxide grains is discussed in terms of their catalytic behaviour in molecular formation. Surface features — such as steps and corners — are considered in detail, and the binding energies of the hydrogen atom and the proton at these sites are estimated. It appears likely that chemical effects of interstellar oxide grains are located not only at point defects discussed elsewhere, but also at these geometrical surface features. Adsorbed surface species, surface reaction schemes, and the possible effects of grain impurities are briefly considered.     

CO adsorption and the optical properties of interstellar grains

Laboratory data on the spectra of CO adsorbed on small MgO particles show that CO absorption leads to a weakening of the 220 nm band together with a shift of this band to shorter wavelengths. CO adsorption also results in the formation of a cyclic CO carbon ion that absorbs at 2.15 m^–1. It is shown that this band provides a close match to a major component of the very broad structure seen in interstellar extinction at the same energy. Effects of CO adsorption on the 220 nm band and VUV extinction are discussed in light of recent observational data on stars with peculiar extinction curves.     

A note on the composition and structure of interstellar grains

Gürtleret al. (1981) argue that SiO could not be the material responsible for the interstellar 10 micron feature as had been proposed by Duleyet al. (1979). While Millar (1982) has quite successfully refuted the arguments of Gürtleret al. (1981), we present here some additional considerations which indicate that the model of Duleyet al. (1979) requires appreciable modification to be consistent with recent experimental results.     

The temperature of interstellar porous grains

Free-space equilibrium temperatures for porous interstellar grains are computed for different dust sizes and are compared to those expected for homogeneous normal grains for two material candidates: graphite and a lunar silicate. Relevant differences are found with the former, but are essentially negligible with the latter. The results are discussed in terms of the different optical properties produced by the porosity of the grains. The possible astrophysical implications of these findings are also mentioned.     

The maximum temperatures of interstellar grains

The maximum temperature a typical interstellar grain will attain upon absorption of a photon or chemical band formation of molecules on its surface is calculated by considering the exact Debye theory of dielectrics. Other contributions to the specific heats of solids are discussed. It is shown that the use of the approximate Debye theory whereC _v is proportional toT will lead to serious errors in the calculation of velocities of desorption of molecules from grain surfaces.     

The temperature of interstellar iron grains

In order for catalytic reactions to occur in interstellar dust clouds, it is necessary for the temperature of the grains to be about an order of magnitude hotter than usually calculated for grains of dielectric materials. However, transition metal (e.g., iron) grains should be fairly abundant, and because they absorb strongly in the visible and ultraviolet regions of the interstellar radiation field, they have equilibrium temperatures 133 K. This was determined by a new method which utilizes Semi-Empirical free electron theory parameters in the infrared, coupled with a reiteration scheme which takes into consideration the change of conductivity of the iron with temperature.     

The temperature of interstellar oxide grains

Grain temperatures have been derived for small oxide grains in a typical interstellar radiation field. Detailed Mie calculations have been used to determineQ _abs from 1000 Å to 30 m. Longward of 30 m, there is no optical data available but the fact that such grains are likely highly defected implies that a ^–1 dependence in the far-infrared may be appropriate.     

The spectroscopic identification of interstellar grains

It is shown that the condition of matching the 3.3–3.9 m spectrum of the galactic infrared source GC-IRS 7 leads to a remarkably tight convergence on the transmittance curve measured in the laboratory for the dessicated bacteriumE. coli. Other materials, including certain biochemicals and postulated prebiologic compounds, are shown to be deficient with regard to meeting this condition.     

The formation of plum-pudding interstellar grains

A calculation is given of the growth of multicored (plum-pudding) interstellar grains as the result of simultaneous condensation of an icy matrix on small cores combined with coagulation of the resulting grains induced by radiation pressure. It is shown that starting with cores of radius 10^–6 cm in normal gas clouds generally gives rise to plum-pudding grains of radius 10^–5 cm after 10⁸–10⁹ yr.     

Ultraviolet scattering properties and the size distribution of interstellar grains

Recent work related to the determination of the size distribution of interstellar grains is reviewed briefly. It is shown that the scattering properties of interstellar grains determined from ultraviolet observations of reflection nebulae point toward the existence of a bimodal size distribution of grains, consisting of classical wavelength sized grains and a class of much more numerous smaller particles, which scatter far ultraviolet light isotropically with near unit albedo. The implications of this result are discussed briefly.Invited contribution to the Proceedings of a Workshop onThermodynamics and Kinetics of Dust Formation in the Space Medium held at the Lunar and Planetary Institute, Houston, 6–8 September, 1978.     

The velocity of pulsars and interstellar irregularities in the scintillation pattern

The scintillation theory is developed for application to the interstellar medium taking into account both the movement of the pulsars and the movement of the interstellar irregularities.It is shown that the velocity of the drifting pattern differs essentially from that for the pulsars. This difference is due to the medium extent effect and to the motion of the irregularities. The pulsar velocityv ₀ and the parameters of the motion of the irregularities ( , ) can be derived from the obtained formulae, using the known parameters of the cross-correlation function of scintillations (V _ef, ₁,S).In contrast with the interplanetary scintillation, the asymmetry of the form of the cross-correlation function of the interstellar scintillations is caused not only by the motion of the interstellar irregularities, but also by the movement of the source itself.     

Polarization properties of spherical interstellar grains on light scattering

On the basis of the Mie theory, the differential cross-section for polarization and the polarization efficiency are calculated for some spherical interstellar grains consisting of ice, silicate, or graphite in the ultraviolet, optical, and near infrared wavelengths. As far as the polarization due to scattering is concerned, these particles scatter light as Rayleigh scattering for 0<x1, wherex is the dimensionless size parameter. The polarization efficienties depend strongly on the value of the imaginary part (m) of the refractive index of grain material whenx1: the efficiency takes a maximum value atx1 and decreases to zero asx approaches zero for the absorbing sphere such as the dielectric particle withm0.1 or the graphite grain in the infrared wavelengths.     

The retention of spallation products in interstellar grains

Stimulated by recent studies indicating the possible survival of presolar grains in certain meteorites, the importance of recoil loss for the retention of spallation products in submicrometer-sized interstellar dust during irradiation by high-energy cosmic ray protons has been calculated. The model presented incorporates range straggling effects, a realistic distribution of interstellar grain sizes, and utilizes an accurate theoretical formalism for the fragmentation recoil momenta. Apart from an only vague understanding of possible grain composition, the greatest uncertainty concerns the intrinsic material density of interstellar dust which determines the recoil range for any given momentum. It is found that even allowing for a fivefold variation of density values, the retention against recoil is substantial: for example, some 20 to 50% of all ³⁸Ar nuclei resulting from high-energy interaction remain trapped, depending on the target element considered. Retentivities for the various spallation reactions contributing to ³⁸Ar have been calculated and are used to deduce an interstellar spallogenic production rate. The results are then considered in the light of recent discoveries of ⁴⁰Ar³⁹Ar apparent ages in excess of 4.53×10⁹ years for some inclusions from the meteorite Allende. Limitations of both the theoretical and experimental efforts presently preclude conclusive statements regarding the question of interstellar grain survival. However, a procedure is outlined whereby this issue might be clarified in future investigations.     

The formation of interstellar grains in supernovae explosions

It is shown that the subsequent Brownian coagulation of small molecular clusters produced in the shell following a supernovae explosion leads to grain sizes in reasonable agreement with observations.     

The rosseland mean opacity of interstellar grains

We have calculated the opacity of interstellar grains in the temperature range 10–1500 K. Two composite grain models have been considered. One of them consists of silicate coated with an ice mantle and the second has a graphite core coated also with an ice mantle. These models are compared with isolated grain models. An exact analytical and computational development of Güttler's formulae for composite grain models has been used to calculate the extinction coefficient.It has been found that the thickness of the mantle affects the opacity of the interstellar grains. The opacity of composite models differs from that of the isolated models. The effect of the different species (ice, silicate, and graphite) is also clear.     

The heterogeneous condensation of interstellar ice grains

Processes of heterogeneous condensation are investigated. We consider the situation that vapor and solid grains of which material is other than that of the vapor coexist and the saturation of the vapor increases with time. If the contact angle of the condensate to the solid is small (?90°), the condensate will be formed as mantles coating the solid grains but only a fraction of the solid grains will be coated by mantles. The ratio of core-mantle grains to bare solid grains in number will be smaller as the density of the vapor and the time scale of saturation increase are large. Actual calculations are made by adopting H₂O ice as the mantle material and magnesium silicate as the core material.     

On the acceleration of interstellar grains

Dust grains of radiir _g 3×10^–6 cm, injected into the intercloud medium at speeds in the range 10⁷–10⁸ cm s^–1, may be stochastically accelerated to speeds 0.1c due to scattering by irregularities in the galactic magnetic field.     

On the nature of interstellar grains

Data on interstellar extinction are interpreted to imply an identification of interstellar grains with naturally freeze-dried bacteria and algae. The total mass of such bacterial and algal cells in the galaxy is enormous, 10⁴⁰ g. The identification is based on Mie scattering calculations for an experimentally determined size distribution of bacteria. Agreement between our model calculations and astronomical data is remarkably precise over the wavelength intervals µ^–1 < ;^–2 < 1.94µ^–1 and 2.5µ^–1 < ;^–1 < 3.0 ;^–1. Over the more restricted waveband 4000–5000 Å an excess interstellar absorption is found which is in uncannily close agreement with the absorption properties of phytoplankton pigments. The strongest of the diffuse interstellar bands are provisionally assingned to carotenoid-chlorophyll pigment complexes such as exist in algae and pigmented bacteria. The 2200 Å interstellar absorption feature could be due to degraded cellulose strands which form spherical graphitic particles, but could equally well be due to protein-lipid-nucleic acid complexes in bacteria and viruses. Interstellar extinction at wavelengths <1800 Å could be due to scattering by virus particles.     

The electric charge distribution on interstellar grains

The results of the preceding paper are applied to a consideration of the motion of grains in a magnetic field, the calculation of particle collision cross-sections and charge effects in molecular synthesis.     

Organic models of interstellar grains

A number of experimental studies have been carried out to verify the claim that interstellar grains largely consist of organic material, including biological cells. Our spectroscopic studies on biological cells and organic extracts from carbonaceous compounds have failed to identify the well-known 2200 Å interstellar extinction peak with the organic material.