Metasomatic alteration of chromite from parts of the late Archaean Sittampundi Layered Magmatic Complex (SLC), Tamil Nadu,India

Chromite deposits associated with layered anorthosite complexes in the Archaean high-grade terranes are rare in the world. The late Archaean Sittampundi Layered Magmatic Complex, Tamil Nadu, India is one of the few such deposits in the world where layers of Fe-Al rich chromites are associated with extremely calcic (An>95) anorthosite. ‘Frozen in’ magmatic mineralogy of the chromitite and the enclosing anorthosite suggest successive crystallization of chromite + clinopyroxene and chromite + clinopyroxene + anorthite from a hydrous Al-rich basaltic melt that was emplaced in a suprasubduction zone setting. Intense deformation and upper amphibolite facies metamorphism at ∼2.45 Ga converted the magmatic assemblages to hitherto unreported hornblende + gedrite + Mg-Al rich spinel ± chlorite bearing assemblages. During metamorphic reconstitution, chromite was pseudomorphically replaced by green spinel in the domains rich in secondary amphiboles. Mass-balance calculation and algebraic analyses of the observed mineralogy suggest that a number of chemical species including chromium became mobile during the formation of spinel pseudomorph in response to infiltration driven metamorphism. Aluminium became mobile in the length scale of chromite grain but remained immobile in the length scale of a thin section.     

Origin of peraluminous minerals (corundum,spinel, and sapphirine) in a highly calcic anorthosite from the Sittampundi Layered Complex,Tamil Nadu,India

The highly calcic anorthosite (An_>95) from the Sittampundi Layered Complex (SLC) develops corundum, spinel and sapphirine that are hitherto not reported from any anorthositic rocks in the world. Petrological observations indicate the following sequence of mineral growth: plagioclase_matrix → corundum; clinopyroxene → amphibole; corundum + amphibole → plagioclase_corona + spinel; and spinel + corundum → coronitic sapphirine. Phase relations in the CaO–Na₂O–Al₂O₃–SiO₂–H₂O (CNASH) system suggest that corundum was presumably developed through vapour present incongruent melting of the highly calcic plagioclase during ultra-high temperature (UHT) metamorphism (T ≥ 1000 °C, P ≥ 9 kbar). Topological constraints in parts of the Na₂O–CaO–MgO–Al₂O₃–SiO₂–H₂O (NCMASH) system suggest that subsequent to the UHT metamorphism, aqueous fluid(s) permeated the rock and the assemblage corundum + amphibole + anorthite + clinozoisite was stabilized during high-pressure (HP) metamorphism (11 ± 2 kbar, 750 ± 50 °C). Constraints of the NCMASH topology and thermodynamic and textural modeling study suggest that coronitic plagioclase and spinel formed at the expense of corundum + amphibole during a steeply decompressive retrograde P–T path (7–8 kbar and 700–800 °C) in an open system. Textural modeling studies combined with chemical potential diagrams (μSiO₂–μMgO) in the MASH system support the view that sapphirine also formed from due to silica and Mg metasomatism of the precursor spinel ± corundum, on the steeply decompressive retrograde P–T path, prior to onset of significant cooling of the SLC. Extremely channelized fluid flow and large positive solid volume change of the stoichiometrically balanced sapphirine forming reaction explains the localized growth of sapphirine.     

Rb-Sr age of the Sivamalai alkaline complex,Tamil Nadu

The Sivamalai alkaline complex comprises ferro-, pyroxene-hornblende- and nepheline-syenites. Field relations show that the nepheline syenites followed the emplacement of non-feldspathoidal syenites. Mineralogical data on the syenite suite have been reviewed. The Sivamalai alkaline rocks are not strongly enriched in rare-earth elements like most miaskites. Rb-Sr isotopic analyses of a suite of six samples from the various members of the complex define an isochron corresponding to an age of 623 ±21 Ma (2σ) and initial Sr ratio of 0.70376 ±14 (2σ). This is consistent with a model of fractional crystallization of a parent magma derived from an upper mantle source with apparently no isotopic evidence for more than one magma source for the complex. The Sivamalai alkaline complex represents a Pan-African alkaline magmatic event in the southern granulite terrane of Peninsular India.     

U-rich pyrochlore from sevathur carbonatites,Tamil Nadu

In Sevathur pyrochlore occurs mainly in rauhaugite. All analysed pyrochlore grains are rich in UO₂. Majority of pyrochlores show alteration to various degrees and maximum alteration is noticed in ones collected from the weathered soil around carbonatite outcrops. There is significant leaching of Ca and Na leading to A-site vacancy and gain in Ba (5 to 7%) and Sr. UO₂ content, though show variation is present in all analysed grains. Elements like U and Th can be incorporated in mineral structures showing alpha and beta radiation. This may initiate a process of metamictization. It is reasonable to assume that these pyrochlore grains are metamict.     

Ti-poor hoegbomite in kornerupine-cordierite-sillimanite rocks from Ellammankovilpatti,Tamil Nadu,India

Hoegbomite occurs sparingly in minute (mostly 0.1 mm) grains with fine-grained hercynite, magnetite, and rutile in two coarse-grained kornerupine-cordierite-sillimanite rocks from Ellammankovilpatti, Tamil Nadu, India. The hoegbomite is Ti-poor (2.5 wt% TiO₂), Fe-rich (25–26% Fe as FeO), and contains 6.2–6.8% MgO, 59.8–60.1% Al₂O₃, 1.0–1.3% ZnO, 0.3–0.7% Cr₂O₃ and 0.02% Li₂O. Minor amounts (estimated not to exceed 0.2 wt% oxide) of V, Co, Ni, Ga, and Sn were detected on the electron microprobe, but Be, Nb, and Zr were not detected with the ion microprobe mass analyser. Assuming the crystal structure refined by Gatehouse and Grey (1982) to be applicable to the Ellammankovilpatti hoegbomite, the analyses were recalculated on a basis of 22 cations, 30 oxygens, and two hydroxyls, resulting in 49 to 53% of the iron being ferric. Identification of hoegbomite was confirmed by X-ray powder diffraction. Associated cordierite (Fe/(Fe+Mg)=0.14) and kornerupine (Fe/(Fe+Mg)= 0.27) contain 0.02 weight % Li₂O and 0.05–0.07% BeO, while only the kornerupine contains B₂O₃ — 1.57% (ion microprobe analyses). Hoegbomite and the other oxides may have crystallized at temperatures between 680 and 720° C (P6.5 kbar) following attainment of peak conditions by the reaction: kornerupine+sillimanite±rutile+ZnO+H₂O+O₂ =cordierite+chlorite+hercynite+hoegbomite +magnetite+B₂O₃.The conditions for hoegbomite formation at Ellammankovilpatti appear to be characteristic of many hoegbomite parageneses. Critical for hoegbomite are silica undersaturation and relatively high oxygen and water activities at fairly high temperatures, conditions which are most commonly attained in later phases of a metamorphic cycle in upper amphibolite- and granulite-facies terrains.     

Groundwater sustainability indicators in parts of Tiruppur and Coimbatore districts,Tamil Nadu

The present study emphasizes the use of groundwater sustainability indicators, developed to assess the sustainability of the aquifer in Uppar Odai sub-basin located in part of Tiruppur and Coimbatore districts, Tamil Nadu. There are seven indicators discussed based on their relevance in groundwater sustainability. In most parts of the subbasin, groundwater development already exceeds 80% of the groundwater recharge. The results have shown that the sub-basin area has been contaminated with low hazard pollutant such as nitrate and fluoride. In addition, about 28% and 32% of the sub-basin area respectively is not suitable for irrigation. The analysis of water level data for the last 42 years has shown decline in water table. However, the water level condition has improved in the recent years due to water conservation measures. The basin requires necessary groundwater planning and management to maintain sustainable aquifer condition.     

Magnetic,chemical and x-ray studies of magnetites from Tamil Nadu,India

Natural intensity, susceptibility, and Koenigsberger ratio were determined and studies of Rayleigh loops, and high field hysteresis, and variation of susceptibility with temperature from ?196° C to Curie temperature were made on a number of magnetite-quartzite and pyroxene, granulite samples from Tamil Nadu. FeO, Fe₂O₃, and TiO₂ proportions were estimated and cell dimensions were determined. From the magnetic studies it is inferred that in general the samples contain predominantly multidomain grains. In a few cases single-domain particles are detected, while in a few other samples a mixture of superparamagnetic particles and single domain states could be inferred. The relative remanence ratio is found to increase with coercive force. The ferromagnetic mineral in magnetite-quartzites is pure magnetite with a little alteration to hematite while in pyroxene granulites it is a titaniferous magnetite with a small percentage of TiO₂. It is probable that the cell dimensions are dependent on oxidation in magnetites, and on the content of TiO₂ in titaniferous magnetites.     

Aquifer characteristics and its modeling around an industrial complex,Tuticorin, Tamil Nadu,India: A case study

Anthropogenic pollution of shallow groundwater resources due to industrial activities is becoming a cause of concern in the east coastal belt of the state of Tamil Nadu, India. Integrated hydrogeological, geophysical and tracer studies were carried out in the coastal region encompassing an industrial complex. The objective has been to gain knowledge of aquifer characteristics, ascertaining groundwater movement and its flow direction, which would in turn reveal the possibility of contamination of groundwater regime and its better management. The results of multi-parameters and model study indicate that the velocity of groundwater flow ranges from 0.013 m/d to 0.22m/d in and around the industrial complex in upstream western part of the catchment and 0.026 m/d to 0.054m/d in the downstream eastern part, near the coast. These parameters are vital for the development of groundwater management scheme.     

The Ghingee Granite, Tamil Nadu, South India: Geochemistry and Petrogenesis

The Palaeo-Proterozoic Ghingee granite is an anatectic granite formed in high grade granulite terrain by ultrametamorphism. The compositional variations both in major and trace elements observed in this granite (SiO₂ : 64.16-73.81; Fe₂O₃ : 0.12-2.19; FeO : 0.12-2.80; MgO : 0.10-2.19; CaO : 1.66-4.71; K₂O : 1.09-5.09; Ba: 223-1883 ppm; Cr : 4-60 ppm) are attributed to a) source rock heterogeneity and b) the tectonic disturbances that might have abruptly ended the anatectic melting process. The granite is compositionally similar to Perur, Closepet and Hyderabad granites and is formed during Archaean-Proterozoic transition by anatectic and crustal remelting processes.     

Impact of urbanization in groundwater of south Chennai City, Tamil Nadu, India

Chennai is one of the four major metropolitan cities in India, and is located in the southeastern part of the country. The average rate of population growth of the city is 25 % per decade and this is recurrently reducing the green-covered area in the city. Exceptionally, during the post-economic liberalization period (i.e., between the years 1997 and 2007), the city lost up to 99 % of its green-covered areas at some parts. Subsequently, the Chennai City started to experience wide range of environmental issues, including groundwater pollution and the effects of groundwater depletion. As a consequence of these factors, a study was undertaken to determine the impact of urbanization on the groundwater quality. In the present study, groundwater samples were collected from 54 stations from the study area during the premonsoon and postmonsoon seasons for the year 2011–2012 and were analyzed for physico-chemical parameters and trace elements. The type of water that predominated in the study area was assessed based on hydrochemical facies. The study of the hydrochemical characteristics of the major ions in these waters shows that in premonsoon, the alkalis and the alkaline earth metals are found to be balanced by chlorides and bicarbonates and sulphates, respectively. Reverse ion exchange study illustrates that Ca, Mg and Na concentrations are interrelated through reverse ion exchange. Box and whisker plots illustrate the seasonal effect on the chemical parameters of the groundwater. Gibbs’ diagram reveals that the chemical composition of the groundwater in the study area is predominated by rock–water interaction. Besides, suitability of groundwater for irrigation was evaluated based on sodium adsorption ratio, Kelley’s ratio, magnesium ratio, Wilcox and USSL diagrams.     

Origin of chromite compositional variation in the Panton Sill,Western Australia

The compositional variation of chromite and associated olivine in chromite-rich and chromitepoor cumulus layers of the Panton Sill is described and a diffusion-controlled crystallization mechanism is proposed to explain this variation. By this mechanism, chromite initially precipitates with a fairly uniform composition, irrespective of the relative proportions of coprecipitating olivine and chromite, and is modified by continued growth during the postcumulus stage. The effect of postcumulus overgrowth of chromite, K _d =(Mg/Fe²⁺)liquid/(Mg/Fe²⁺) chromite6, is to deplete the surrounding magma in chromium and decrease Fe²⁺ relative to Mg such that a chemical gradient exists between the overlying magma, through which the cumulus grains settled, and the magma in contact with settled chromite grains near the magma/crystal pile interface. Postcumulus equilibration of olivine and chromite with the surrounding magma results in higher Mg/(Mg + Fe²⁺) ratios of both olivine and chromite and higher Al content of chromite. The extent of this postcumulus modification is directly related to the proportion of chromite to olivine in a particular layer. This model can be extended to stratiform intrusions elsewhere in which chromite coprecipitates with olivine, orthopyroxene or plagioclase and displays similar compositional trends.     

Origin of Cretaceous phosphorites from the onshore of Tamil Nadu,India

Cretaceous phosphorites from the onshore of Tamil Nadu have been investigated for their origin and compared with those in the offshore. Cretaceous phosphorites occur as light brown to yellowish brown or white nodules in Karai Shale of the Uttatur Group in the onshore Cauvery basin. Nodules exhibit phosphatic nucleus encrusted by a chalky shell of carbonate. The nucleus of the nodules consists of light and dark coloured laminae, phosphate peloids/coated grains and detrital particles interspersed between the laminae. Scanning electron microscope (SEM) studies reveal trapping and binding activity of microbial filaments. A mat structure with linearly arranged microbial filaments and hollow, cell-based coccoid cyanobacterial mat are present. Nodules contain abundant carbonate fluorapatite, followed by minor calcite, quartz and feldspar. The P₂O₅ content of the phosphorites ranges from 18 to 26%. The CaO/P₂O₅, Sr and F contents are higher than that of pure carbonate fluorapatite. Concentrations of Si, Al, K, Fe, and Ti are low. We suggest that the nuclei of the nodules represent phosphate clasts related to phosphate stromatolites formed at intertidal conditions. At high energy levels the microbial mats were disintegrated into phosphate clasts, coated with carbonate and then reworked into Karai Shale. On the other hand, Quaternary phosphorites occur as irregular to rounded, grey coloured phosphate clasts at water depths between 180 and 320m on the continental shelf of Tamil Nadu. They exhibit grain-supported texture. Despite Quaternary in age, they also resemble phosphate stromatolites of intertidal origin and reworked as phosphate clasts onto the shelf margin depressions. Benthic microbial mats probably supplied high phosphorus to the sediments. Availability of excess phosphorus seems to be a pre-requisite for the formation of phosphate stromatolites.     

Radiocarbon ages of pedogenic carbonate nodules from Coimbatore region,Tamil Nadu

In this paper we discuss the limitation of radiocarbon dates on the pedogenic calcic nodules formed in situ within the vertisols in the upland region of Coimbatore, Tamil Nadu. The radiocarbon ages were obtained using low-level scintillation counters and the dates range from ∼24 to 31 ¹⁴C kyrs BP. The ages correlate with the marine isotope stage of Late MIS3. However, since the calcic nodules are pedogenised and formed in an open system, the ¹⁴C ages should only be considered as estimates and not absolute ages because of the possibility of open-system behaviour with respect to carbon. Thus, we express caution in the interpretation of these and other radiocarbon ages obtained on pedogenic carbonate nodules. Multiple sub-mm size subsamples could provide more reliable age estimates.     

Hydrochemistry of groundwater of Thiruporur block, Tamil Nadu (India)

An attempt has been made in this work to evaluate the environmental chemistry of groundwater in Thiruporur block, Kancheepuram District, Tamil Nadu, India. Eleven villages of Thiruporur block were selected; where the people use groundwater for drinking purpose, and the water samples were subjected to systematic analysis with a view to understand the potability of drinking water sources. The depth of the bore wells varied from 100 to 200?feet. The values obtained for different parameters were compared with the standard values given by ISI/ICMR/WHO and the variations were notable for the parameters like nitrate and total hardness for few samples. Therefore, a medical survey was carried out to study the harmful effects on the society due to these two parameters at the villages??Kayar and Melkottaiyar.     

Features of mineral and chemical composition of the Khamambettu Carbonatites, Tamil Nadu

The paper presents mineralogical features and EPMA results of the Khamambettu carbonatites. The mineralogical data suggest that these rocks have been generated in magmatic and hydrothermal stages. Mineral geothermometer for carbonatite give temperatures of 790°–980°C. Fluid inclusion measurements in monazite (hydrothermal stage) give temperatures of 220°–290°C. One of the features of the carbonatites is high content of magnesia that is defined by the presence of dolomite, olivine, spinel, phlogopite, Mg-rich ilmenite. Chloritization, serpentinization, amphibolization, silicification processes and occurrence of barite, monazite-(Ce), strontianite, celestine are related to hydrothermal stage. Hydrothermal minerals at the Khamambettu were formed by recrystallization of primary carbonatite minerals in the presence of Ba, (SO₄)^2?, REE and Si carried in solution by the hydrothermal fluid.