Environmental quality evaluation of the Vacacaí River, Rio Grande do Sul, Brazil

The water quality of the Vacacaí River was assessed at different sites in the period between winter 2005 and autumn 2006. All samples were analyzed for 52 elements (Sc, Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Th, Li, Be, Mg, Al, Ca, V, Cr, Mn, Fe, Ni, Co, Cu, Zn, Ga, As, Se, Rb, Sr, Ag, Cd, In, Cs, Ba, Tl, Pb, Bi, U, Na, K, Hg, B, Mo, Sn, Te, Ti), temperature, pH, ammonia, and alkalinity levels. Water from the Vacacaí River ranged from slightly acidic to alkaline. No difference was observed in the chemical composition at different sites of the Vacacaí River. Levels of Ba, Ca, Sr and Mg increase in the dry seasons and reach their highest concentrations in autumn; Be and U decrease in the dry season and reach their highest concentration in spring. Al, Fe, Cr, Ni, Th, U Mn, Ca and Mg are highly positively related, indicating a common origin. Se and Cu are probably from anthropogenic source, from the rice crops of the margins of the river. Waterborne Al and Fe levels were above the desirable level for drinking water at all sites during all seasons. These results demonstrate the need for constant monitoring of water parameters, which is crucial to ensure water quality for the population of this region.     

Mercury in the Waters of the Jundiaí River, SP, Brazil: The Role of Dissolved Organic Matter

Many developing countries have regions of high demographic density, where untreated residuary waters from different sources are often discharged into rivers, streams and other water bodies. This paper discusses the reducing action of organic matter of anthropic origin on the mercury redox cycle in the Jundiaí River impacted by discharged wastes, and on the Piraí River, a non-impacted water body. The total mercury concentrations in these locations vary from 1.7 to 32?ng?L^?1 in the former and from 0.6 to 10.6?ng?L^?1 in the latter. Dissolved organic carbon concentrations of up to 68.3 and 6.5?mg?L^?1 were observed, confirming the higher impact on the Jundiaí River. It was found that an inverse correlation between the concentration of dissolved organic carbon and total mercury was stronger in the Jundiaí River, given that it receives higher organic loads, suggesting that organic matter exerts a reducing action on mercury, which is released as gas into the atmosphere. This correlation was not observed in the Piraí River, where the organic matter of natural origin is probably not sufficiently labile to act intensely upon the Hg redox cycle, favoring the metal transport.     

The Mesoproterozoic to early Neoproterozoic passive margin Lajeado Group and Apiaí Gabbro,Southeastern Brazil

The Lajeado Group in the Ribeira Belt,southeastern Brazil,corresponds to an open-sea carbonate platform,comprised of seven overlapping siliciclastic and carbonatic formations,intruded in its upper portion by the Apiai Gabbro.These rocks have a Neoproterozoic tectonometamorphic overprint related to arc magmatism and the Brasiliano collisional orogeny.Geochronological constraints are given by new UPb SHRIMP and LA-ICP-MS data for Lajeado Group detrital zircons and for magmatic zircons from the Apiai Gabbro.The youngest detrital zircons in the Lajeado Group are 1400-1200 Ma,and constrain its maximum age of deposition to be 1200 Ma,whereas the 877 ± 8 Ma age for magmatic zircons in the Apiai Gabbro give the minimum age.Detritus source areas are mainly Paleoproterozoic(2200-1800 Ma)with some Archean and Mesoproterozoic contribution(1500-1200 Ma),with distal or tectonic stable cratonic character.The Lajeado Group should be a Stenian-Tonian carbonate platform passive margin of a continent at this time,namely the Columbia/Nuna or the Rodinia.The Apiai Gabbro displays similar age to other intrusive basic rocks in the Lajeado and Itaiacoca groups and represents tholeiitic MORB-like magmatism that we relate to the initial break-up of a Mesoproterozoic continent and the formation of the Brasiliano oceans.     

The oldest record of Ediacaran macrofossils in Gondwana (~563 Ma,Itajaí Basin,Brazil)

The Avalon biota (Ediacaran Period, 570–559 Ma) marks the first appearance of macroscopic and complex benthic communities in the fossil record. This assemblage is known from a few localities worldwide, mainly in Canada and England. Here, we report for the first time the presence of Ediacaran macrofossils in deposits of similar age from Gondwana (Itajaí Basin, southern Brazil). Our new radiometric date (~563 Ma) indicates that the Itajaí Basin can be chronocorrelated with the classic Avalonian deposits and thus represents one of the oldest records of the Ediacaran biota in Gondwana. We describe the presence of the Ediacaran genus Palaeopascichnus, as well as discs (Aspidella and Nimbia), and other problematic forms. Contrary to the deep-marine macroorganisms of the Avalon Assemblage, the Itajaí fossils are associated with abundant and exceptionally preserved three-dimensional microbial mats and microbially induced sedimentary structures (MISS) in relatively shallow settings (upper slope and distal delta front deposits). In this sense, the Itajaí biota could represent early adaptations of benthic macrobiota to the shallower and more photic environments that characterize the later White Sea Assemblage.     

Fluid evolution of the Hub Stock, Horní Slavkov–Krásno Sn–W ore district, Bohemian Massif, Czech Republic

The Horní Slavkov–Krásno Sn–W ore district is hosted by strongly altered Variscan topaz–albite granite (Krudum granite body) on the northwestern margin of the Bohemian Massif. We studied the fluid inclusions on greisens, ore pockets, and ore veins from the Hub Stock, an apical expression of the Krudum granite. Fluid inclusions record almost continuously the post-magmatic cooling history of the granite body from ～500 to <50°C. Rarely observed highest-temperature (～500°C) highest-salinity (～30?wt.% NaCl eq.) fluid inclusions are probably the result of secondary boiling of fluids exsolved from the crystallizing magma during pressure release which followed hydraulic brecciation of the gneissic mantle above the granite cupola. The greisenization was related to near-critical low-salinity (0–7?wt.% NaCl eq.) aqueous fluids with low amount of CO₂, CH₄, and N₂ (≤10?mol% in total) at temperatures of ～350–400°C and pressures of 300–530 bar. Crush-leach data display highly variable and negatively correlated I/Cl and Br/Cl values which are incompatible with both orthomagmatic and/or metamorphic origin of the fluid phase, but can be explained by infiltration of surficial and/or sedimentary fluids. Low fluid salinity indicates a substantial portion of meteoric waters in the fluid mixture that is in accordance with previous stable isotope data. The post-greisenization fluid activity associated with vein formation and argillitization is characterized by decreasing temperature (<350 to <50°C), decreasing pressure (down to ～50–100 bar), and mostly also decreasing salinity.     

Microfossils associated with silicified Stratifera undata Komar 1966 from the late Proterozoic Bambuí Group,south-central Brazil

Small, partly silicified, laterally linked stromatolites exhibiting a high degree of inheritance in the shape of successively stacked laminae from the lower Bambuí Group (late Proterozoic), near Unaí, Minas Gerais, south-central Brazil, are here described and classified as Stratifera undata Komar 1966. Rare, moderately preserved microfossils and stratiform concentrations of poorly preserved probable microfossils consist essentially of coccoidal forms, there being no convincing evidence of filamentous forms. If, in fact, coccoidal micro-organisms were the overwhelmingly dominant mat-formers, this represents an unusual situation among silicified microflorules from morphologically distinct Precambrian stromatolites yet is quite similar to that observed in another form of Stratifera (S. biwabikensis from the Gunflint Iron-Formation), which, like the Unaí stromatolites, also formed under permanently submerged conditions. S. undata is now known in Brazil from similar upper Proterozoic settings in two very widely separated localities, which suggests its potential use in regional stratigraphic correlation. As a result of this study, we recommend that greater attention be paid to the ‘simpler’ stromatolite morphologies, especially when micro fossiliferous, since such forms commonly comprise the basal portions of biostratigraphically significant stromatolites and may share a common microstructure with these same, more complex forms. Inasmuch as microstructure is generally acknowledged as the stromatolite property most closely controlled by biological factors, study of silicified microflorules within simpler forms may permit inferences regarding not only the microbial communities responsible for more complex stromatolites having the same microstructure but also possible biological reasons for the succession of distinct stromatolite assemblages observed in upper Precambrian rocks.     

The Carrancas Formation,Bambuí Group: A record of pre-Marinoan sedimentation on the southern São Francisco craton,Brazil

The Carrancas Formation outcrops in east-central Brazil on the southern margin of the São Francisco craton where it comprises the base of the late Neoproterozoic Bambuí Group. It is overlain by the basal Ediacaran cap carbonate Sete Lagoas Formation and was for a long time considered to be glacially influenced and correlative with the glaciogenic Jequitaí Formation. New stratigraphic, isotopic and geochronologic data imply that the Carrancas Formation was instead formed by the shedding of debris from basement highs uplifted during an episode of minor continental rifting. Reddish dolostones in the upper Carrancas Formation have δ¹³C values ranging from +7.1 to +9.6‰, which is a unique C isotopic composition for the lowermost Bambuí Group but similar to values found in the Tijucuçu sequence, a pre-glacial unit in the Araçuaí fold belt on the eastern margin of the São Francisco craton. The stratigraphic position below basal Ediacaran cap carbonates and the highly positive δ¹³C values together indicate a Cryogenian interglacial age for the Carrancas Formation, with the high δ¹³C values representing the so-called Keele peak, which precedes the pre-Marinoan Trezona negative δ¹³C excursion in other well characterized Cryogenian sequences. Hence, The Carrancas Formation pre-dates de Marinoan Jequitaí Formation and represents an interval of Cryogenian stratigraphy not previously known to occur on the southern margin of São Francicso craton. Documentation of Cryogenian interglacial strata on the São Francisco craton reinforces recent revisions to the age of Bambuí Group strata and has implications for the development of the Bambuí basin.     

Earth's surface movements in the hazardous area of Jezeří Castle,Krušné hory Mountains

Abstact The results are summarized of the correlation between the detailed geomorphological analysis and the geodynamic interpretation of the twelve high-precision levelling measurements of the Earth's recent surface movements (1983–1989) in the hazardous area of Jezeí Castle in the Kruné hory Mts. Indicated are the types and régime of these movements (Tab 1, Fig 3) which are climatic, tectonic and anthropogenous in origin. Both slightly and strongly deformed zones in the near-surface part of crystalline rocks massif were formed (Fig 1). The landform patterns (Fig 2), as well as the present-day activity of geological processes are described.     

New U–Pb ages and lithochemical attributes of the Ediacaran Rio Doce magmatic arc,Araçuaí confined orogen,southeastern Brazil

The Araçuaí orogen of southeastern Brazil, together with its counterpart located in Africa, the West Congo belt, formed through closure of a gulf connected to the Adamastor Ocean by the end of the Ediacaran and beginning of the Cambrian. Convergence of the margins of the gulf led to the development of the Rio Doce magmatic arc between 630 Ma and 580 Ma on a continental basement mostly composed of Rhyacian orthogneisses. The Rio Doce arc mainly consists of tonalite-granodiorite batholiths, generally crowded with mafic to dioritic enclaves, and minor gabbronorite-enderbite-charnockite plutons, suggesting mixing processes involving crustal and mantle sources. We investigate the basement, magma sources and emplacement ages of the Rio Doce arc. Our data suggest the arc comprises three main granitic rock groups: i) Opx-bearing rocks mostly of enderbite to charnockite composition; ii) enclave-rich tonalite-granodiorite (ETG); and iii) enclave-poor granite-granodiorite with minor tonalite (GT). The Opx-bearing rocks are magnesian, calc-alkalic to alkali-calcic and metaluminous. Together, the ETG and GT rock groups range in composition from tonalite to granite, are metaluminous to slightly peraluminous, show a predominantly medium- to high-K, expanded calc-alkaline signature, and other geochemical and isotopic attributes typical of a pre-collisional volcanic arc formed on a continental margin setting. Mineralogical, chemical, and geochronological data suggest the involvement of HT-melting of granulitic (H₂O-depleted) sources of Rhyacian age for the generation of Opx-bearing granitic rocks, additionally to magma mixing and fractional crystallization processes. In conclusion, the studied rock groups of the Rio Doce arc were likely formed by interactions of mantle and crustal processes, in an active continental margin setting. These processes involved ascent of mantle magmas that induced partial melting on the continental basement represented by the Rhyacian gneisses.     

The Early Cretaceous Jacuí Group,a newly discovered volcaniclastic–epiclastic accumulation at the top of the Paraná Basin,southern Brazil

The presence of volcaniclastic rocks related to the silicic magmatism within the Serra Geral Formation has been a matter of long-standing debate. In this paper, we present extensive documentation that supports the presence and abundance of these rocks in the Jacuí Group, a newly discovered volcaniclastic and epiclastic accumulation in southern Brazil. The Jacuí Group is composed of two interfingered stratigraphic units, the Volta Alegre and Tupanciretã formations, and it represents the uppermost stratigraphic unit of the Paraná Basin. The Volta Alegre Formation is primarily composed of resedimented volcaniclastic tuffites, the pyroclasts which were sourced from the Santa Maria subgroup of the Palmas-type of the Serra Geral Formation. The Tupanciretã Formation is composed of fluvial and aeolian deposits transported towards the north–northwest. Deposition of the Jacuí Group began in the Early Cretaceous (∼132 Ma) and was coeval with the acidic volcanism of the Santa Maria subgroup. This group was deposited in a probable interior sag basin that represents either the beginning of the extension in the inner part of the continent that subsequently migrated to the east or the far-field impact of extensional processes that preceded the break-up of Gondwana and the opening of the South Atlantic Ocean.     

Multi-method assessment of connectivity between surface water and shallow groundwater: the case of Limarí River basin,north-central Chile

A study that tests the applicability and consistency of independent but complementary approaches in the assessment of interactions between surface water and shallow groundwater within a water-stressed basin is described. The mostly agricultural Limarí basin in arid north-central Chile was chosen as a suitable case study. The analyses involved: (1) a connectivity index method, (2) hydrochemistry, and (3) water isotopic geochemistry. Chemical and isotopic data were obtained from two sampling campaigns conducted in April (fall) and December (summer) of 2011 in 22 sampling locations, which included surface water and groundwater. The results obtained by each of the methodologies were mutually consistent and indicate high connectivity conditions. Additionally, the relative contribution by different sources was assessed through end-member mixing analysis, and for reaches of the river that showed gaining conditions, the contribution of groundwater inflow to stream discharge was estimated. It is suggested that this multi-method approach is useful for the characterization of surface-water–groundwater interactions, since it at least represents a suitable starting point for obtaining basic information on these relationships. Thus, it may become the base for further studies in arid and semi-arid basins facing water management challenges.     

Tertiary alkaline Roztoky Intrusive Complex, České středohoří Mts., Czech Republic: petrogenetic characteristics

The ?eské st?edoho?í Mts. is the dominant volcanic center of the Oh?e (Eger) rift zone. It hosts the Roztoky Intrusive Complex (RIC), which is made up of a caldera vent and intrusions of 33–28-Ma-old hypabyssal bodies of essexite–monzodiorite–sodalite syenite series accompanied by a radially oriented 30–25-Ma-old dike swarm comprising about 1,000 dikes. The hypabyssal rocks are mildly alkaline mostly foid-bearing types of mafic to intermediate compositions. The dike swarm consists of chemically mildly alkaline and rare strongly alkaline rocks (tinguaites). The geochemical signatures of the mildly alkaline hypabyssal and associated dike rocks of the RIC are consistent with HIMU mantle sources and contributions from lithospheric mantle. The compositional variations of essexite and monzodiorite can be best explained by fractional crystallization of parent magma without significant contributions of crustal material. On the other hand, the composition of monzosyenite, leuco-monzodiorite and sodalite syenite reflects fractional crystallization coupled with variable degrees of crustal assimilation. It is suggested that the parent magmas in the Oh?e rift were produced by an adiabatic decompression melting of ambient upper mantle in response to lithospheric extension associated with the Alpine Orogeny.     

The genesis of the amethyst geodes at Artigas (Uruguay) and the paleohydrology of the Guaraní aquifer: structural, geochemical, oxygen, carbon, strontium isotope and fluid inclusion study

The amethyst-bearing geodes found in the flood basalts of the Arapey formation at Artigas (Uruguay) were formed as protogeodes by bubbles of CO₂-rich basalt-derived fluids. The formation of the celadonite rim and the lining of the geodes by agate followed by quartz and amethyst were driven by the artesian water of the Guaraní aquifer percolating the basalts from below. The temperature of the amethyst formation is estimated from fluid inclusion data to be between 50° and 120°C. Oxygen stable isotope data suggest a crystallization temperature of calcite of about only 24°C. The actual wellhead temperature of the water produced from the Guaraní aquifer in the study area is around 29°C.     

Beiträge zur Geologie von Chiriquí (Republik Panamá)

Ohne Zusammenfassung     

On zeophyllite from Radejčín, České středohoří Mts.: X-ray and IR-investigations

Summary A redetermination of the crystal structure of zeophyllite, idealized Ca₁₃Si₁₀O₂₈F₁₀.6H₂O [a=9.377(2), c=36.57(2) Å; Z=3], space group R3 (No. 148) yielded R = 0.033 for 2238 observed single crystal X-ray data (Fo > 3_Fo). The atomic coordinates in combination with the anisotropic thermal displacement parameters as well as the internal R-value from merging equivalent intensities gave no evidence for a violation of trigonal symmetry. The structure is characterized by SiO₄ tetrahedra combined to open branched vierer single layers in an arrangement normal to the threefold axes. These layers are connected via the Ca(O,F)_x polyhedra and hydrogen bridges to a framework with a pronounced cleavage parallel to (00.1). The statistic . occurrence of Si-OH groups in parts of the structure was confirmed by IR-investigations.

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Über Zeophyllit aus Radzein, Böhmisches Mittelgebirge: Röntgen- und IR-Untersuchungen

Zusammenfassung Eine Neubestimmung der Kristallstruktur an Zeophyllit, idealisiert Ca₁₃Si{ion10}O₂₈F₁₀· .6H20 [a=9.377(2), c=36.57(2) Å; Z=3], Raumgruppe R3 (No. 148), ergab R = 0.033 für 2238 beobachtete Röntgeneinkristalldaten (Fo > 3_Fo). Die Koordinaten der Atome in Verbindung mit den Parametern der anisotropen thermischen Schwingung sowie der interne R-Wert nach Mittelung äquivalenter Intensitäten ergaben keinen Anhaltspunkt für eine Verletzung der trigonalen Symmetrie. Die Struktur ist charakterisiert durch SiO₄-Tetraeder, verknüpft zu open branched vierer single layers, die normal zur dreizähligen Achse angeordnet sind. Diese Schichten werden über die Ca(O,F)_x Polyeder und Wasserstoffbrücken zu einem Gerüst mit ausgeprägter Spaltbarkeit parallel (00.1) verbunden. In der Struktur statistisch auftretende Si-OH-Gruppen konnten durch IR-Untersuchungen belegt werden.

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With 4 Figures     

Neoproterozoic glacial deposits from the Araçuaí orogen,Brazil: Age,provenance and correlations with the São Francisco craton and West Congo belt

Glacigenic diamictite successions of the Macaúbas Group are widespread in the western domain of the Araçuaí orogen, east of the São Francisco craton (Brazil). Diamictites also occur on this craton and in the African counterpart of the Araçuaí orogen, the West Congo belt. Detrital zircon grains from the matrix of diamictites and sandstones from the Macaúbas Group were dated by the U–Pb SHRIMP technique. The geochronological study sets the maximum depositional age of the glacial diamictites at 900 Ma, and indicates multiple sources for the Macaúbas basin with ages ranging from 900 to 2800 Ma. Sm–Nd T_DM model ages, determined on whole rock samples, range from 1.8 Ga to 2.5 Ga and get older up-section. Comparison of our data with those from the cratonic area suggest that these glacial deposits can be correlated to the Jequitaí and Carrancas diamictites in the São Francisco craton, and to the Lower Mixtite Formation of the West Congolian Group, exposed in Africa. The 900–1000 Ma source is most probably represented by the Zadinian–Mayumbian volcanic rocks and related granites from the West Congo belt. However, one of the most voluminous sources, with ages in the 1.1–1.3 Ga interval, has not been detected in the São Francisco-Congo craton. Possible sources for these grains could occur elsewhere in Africa, or possibly from within the Brasília Belt in western central Brazil.     

A large epeiric methanogenic Bambuí sea in the core of Gondwana supercontinent?

Carbon isotope compositions of both sedimentary carbonate and organic matter can be used as key proxies of the global carbon cycle and of its evolution through time,as long as they are acquired from waters where the dissolved inorganic carbon(DIC)is in isotope equilibrium with the atmospheric CO2.However,in shallow water platforms and epeiric settings,the influence of local to regional parameters on carbon cycling may lead to DIG isotope variations unrelated to the global carbon cycle.This may be especially true for the terminal Neoproterozoic,when Gondwana assembly isolated waters masses from the global ocean,and extreme positive and negative carbon isotope excursions are recorded,potentially decoupled from global signals.To improve our understanding on the type of information recorded by these excursions,we investigate the pairedδ^13Ccarb andδ^13Corg evolution for an increasingly restricted late Ediacaran-Cambrian foreland system in the West Gondwana interior:the basal Bambui Group.This succession represents a 1~(st)-order sedimentary sequence and records two majorδ^13Ccarb excursions in its two lowermost lower-rank sequences.The basal cap carbonate interval at the base of the first sequence,deposited when the basin was connected to the ocean,hosts antithetical negative and positive excursions forδ^13Ccarb andδ^13Corg,respectively,resulting inΔ^13C values lower than 25‰.From the top of the basal sequence upwards,an extremely positiveδ^13Ccarb excursion is coupled toδ^13Corg,reaching values of+14‰and-14‰,respectively.This positive excursion represents a remarkable basin-wide carbon isotope feature of the Bambui Group that occurs with only minor changes inΔ^13C values,suggesting change in the DIC isotope composition.We argue that this regional isotopic excursion is related to a disconnection between the intrabasinal and the global carbon cycles.This extreme carbon isotope excursion may have been a product of a disequilibria between the basin DIC and atmospheric CO2 induced by an active methanogenesis,favored by the basin restriction.The drawdown of sulfate reservoir by microbial sulfate reduction in a poorly ventilated and dominantly anoxic basin would have triggered methanogenesis and ultimately methane escape to the atmosphere,resulting in a^13C-enriched DIC influenced by methanogenic CO2.Isolated basins in the interior of the Gondwana supercontinent may have represented a significant source of methane inputs to the atmosphere,potentially affecting both the global carbon cycle and the climate.     

Granites of the intracontinental termination of a magmatic arc: an example from the Ediacaran Araçuaí orogen,southeastern Brazil

The Araçuaí orogen of southeastern Brazil together with the West Congo belt of central West Africa form the Araçuaí–West Congo orogen generated during closure of a terminal segment of the Neoproterozoic Adamastor Ocean. Corresponding to an embayment in the São Francisco–Congo Craton, this portion of the Adamastor was only partially floored by oceanic crust. The convergence of its margins led to the development of the Rio Doce magmatic arc between 630 Ma and 580 Ma. The Rio Doce magmatic arc terminates in the northern portion of the Araçuaí orogen. Granitic plutons exposed in the northern extremity of the arc provide a rare opportunity to study magmatism at arc terminations, and to understand the interplay between calc-alkaline magma production and crustal recycling. The plutons forming the terminus of the arc consist of granodiorites, tonalites and monzogranites similar to a magnesian, slightly peraluminous, calcic- (68%) to calc-alkaline (24%), with minor alkali-calcic (8%) facies, medium- to high-K magmatic series. Although marked by negative Nb–Ta, Sr and Ti anomalies, typically associated with subduction-related magmas, the combined Sr, Nd and Hf isotopic data characterize a crustal signature related to anatexis of metamorphosed igneous and sedimentary rocks, rather than fractional crystallization of mantle-derived magmas. Zircon U–Pb ages characterizes two groups of granitoids. The older group, crystallized between 630 and 590 Ma, experienced a migmatization event at ca. 585 Ma. The younger granitoids, emplaced between 570 and 590 Ma, do not show any evidence for migmatization. Most of the investigated samples show good correlation with the experimental compositional field of amphibolite dehydration-melting, with some samples plotting into the field of greywacke dehydration-melting. The studied rocks are not typical I-type or S-type granites, being particularly similar to transitional I/S-type granitoids described in the Ordovician Famatinian arc (NW Argentina). We suggest a hybrid model involving dehydration-melting of meta-igneous (amphibolites) and metasedimentary (greywackes) rocks for magma production in the northern termination of the Rio Doce arc. The real contribution of each end-member is, however, a challenging work still to be done.     

Net Ecosystem Metabolism and Nonconservative Fluxes of Organic Matter in a Tropical Mangrove Estuary, Piauí River (NE of Brazil)

Net ecosystem metabolism (NEM) was measured in the Piauí River estuary, NE Brazil. A mass balance of C, N, and P was used to infer its sources and sinks. Dissolved inorganic carbon (DIC) concentrations and fluxes were measured over a year along this mangrove dominated estuary. DIC concentrations were high in all estuarine sections, particularly at the fluvial end member at the beginning of the rainy season. Carbon dioxide concentrations in the entire estuary were supersaturated throughout the year and highest in the upper estuarine compartment and freshwater, particularly at the rainy season, due to washout effects of carbonaceous soils and different organic anthropogenic effluents. The estuary served as a source of DIC to the atmosphere with an estimated flux of 13 mol CO₂ m^?2 year^?1. Input from the river was 46 mol CO₂ m^?2 year^?1. The metabolism of the system was heterotrophic, but short periods of autotrophy occurred in the lower more marine portions of the estuary. The pelagic system was more or less balanced between auto- and heterotrophy, whereas the benthic and intertidal mangrove region was heterotrophic. Estimated annual NEM yielded a total DIC production in the order of 18 mol CO₂ m^?2 year^?1. The anthropogenic inputs of particulate C, N, and P, dissolved inorganic P (DIP), and DIC were significant. The fluvial loading of particulate organic carbon and dissolved inorganic nitrogen (DIN) was largely retained in two flow regulation and hydroelectric reservoirs, promoting a reduction of C:N and C:P particulate ratios in the estuary. The net nonconservative fluxes obtained by a mass balance approach revealed that the estuary acts as a source of DIP, DIN, and DIC, the latter one being almost equivalent to the losses to the atmosphere. Mangrove forests and tidal mudflats were responsible for most of NEM rates and are the main sites of organic decomposition to sustain net heterotrophy. The main sources for this organic matter are the fluvial and anthropogenic inputs. The mangrove areas are the highest estuarine sources of DIP, DIC, and DIN.     

Using AMS combined with mineral shape preferred orientation analysis to understand the emplacement fabrics of the Apiaí gabbro-norite (Ribeira Belt,SE Brazil)

The Apiaí gabbro-norite is a massive fine-grained Neoproterozoic intrusion emplaced in a core of synformal structure that deforms low-grade marine metasedimentary rocks of the Ribeira Belt of south-eastern Brazil. The lack of visible magmatic layering or any internal fabric has been a major limitation in deciding whether the emplacement occurred before or after the regional folding. To assist in the tectonic interpretations, we combine low-field anisotropy of magnetic susceptibility (AMS) and silicate shape preferred orientation (SPO) to reveal the internal structure of the mafic intrusion. Magnetic data indicate a mean susceptibility of about 10⁻² SI and a mean anisotropy degree (P) of about 1.08, essentially yielded by titanomagnetite. The magnetic and silicate foliations for P ≥ 1.10 are parallel to each other, while the lineations tend to scatter on the foliation plane, in agreement with the dominant oblate symmetry of the AMS and SPO ellipsoids. For lower P values, the magnetic and silicate fabrics vary from coaxial to oblique, and for P ≤ 1.05, their shapes and orientations can be quite distinct. The crystal size distribution (CSD) of plagioclase for P > 1.05 is log linear, in agreement with a bulk simple crystallisation history. These results combined show that for a strong SPO, corresponding to a magnetic anisotropy above 1.10, AMS is a reliable indicator of the magmatic fabric. They indicate that the Apiaí gabbro-norite consists of sill-like body that was inclined gently to the north by the regional folding.