Joints,faults and palaeostress evolution in the Campo de Dalias (Betic Cordilleras,southeastern Spain)

The Campo de Dal??as, located between the central and eastern Betic Cordilleras, shows an evolution determined by the overprinting of two main stress fields since Pliocene times. The first of these develops hybrid and tensional joint sets up to Pleistocene (100 000 yr) and is characterized by NNW–SSE horizontal trend of compression and an ENE–WSW horizontal extension. The second stress field has prolate to triaxial extensional ellipsoids, also with ENE–WSW horizontal extension, and continues to be active today. The most recent stresses produce the reactivation of previous joints as faults whose trends are comprised mainly from N120°E to N170°E and have a normal and transtensional regime, with dextral or sinistral components. The palaeostress evolution of this region is similar to that undergone by other basins of the Eastern Betic Cordilleras, although the Pliocene–Pleistocene transcurrent deformations in the Campo de Dal??as only develop joints and not strike-slip faults.     

Geochemistry of thermal springs,Alhama de Granada (southern Spain)

The waters of the thermal springs at Alhama de Granada vary in temperature between 27 and 45°C. Temporal changes in the composition of the principal spring (Baños Viejos) indicate that a small degree of mixing may occur between deep thermal waters and shallow groundwater. Slight compositional variations also occur between the various thermal springs in the study area. These spatial variations are due to the different local hydrodynamic conditions in the springs. Towards the north in less hydraulically transmissive rocks, cooling of the rising water is more noticeable, as are ion exchange and processes of SO₄ reduction. The chemical composition of the water is related to the dissolution of evaporites (SO₄ and Cl salts), carbonates and silicates, and to the possible existence of sources of S within the rock. Estimates of the mean residence times have been obtained based on ¹⁴C_DIC and T. The state of thermodynamic equilibrium at the spring discharge was calculated using the SOLMINEQ.88 program. The results indicate that all the samples are supersaturated with respect to quartz, chalcedony, cristobalite, calcite, aragonite and dolomite, and undersaturated with respect to gypsum, anhydrite and halite. The use of different geothermometers and modelling of saturation indices for quartz, albite and anhydrite indicate temperatures of about 110°C.     

Identification of arid phases during the last 50 cal. ka BP from the Fuentillejo maar‐lacustrine record (Campo de Calatrava Volcanic Field,Spain)

Geochemical (element analysis, molecular analysis of organic compounds), physical, palynological, mineralogical and sedimentary facies analysis were performed to characterise the sedimentary record in Fuentillejo maar‐lake in the Central Spanish Volcanic Field of Campo de Calatrava, in order to reconstruct the palaeoenvironmental and palaeoclimatic processes which controlled vegetation patterns and deposition of different sedimentary facies. The upper 20 m of core FUENT‐1 show variations in clastic input, water chemistry, vegetation and organic fraction sources in the lake throughout the Late Pleistocene and Holocene. The temporal framework provided by ¹⁴C accelerator mass spectrometry dating allows assigning the sequence to the last 50 cal. ka BP. Arid phases identified in the FUENT‐1 sequence are correlated to Heinrich events (HE) and to stadials of the Dansgaard/Oeschger (D/O) cycles. Siliciclastic facies with high magnetic susceptibility values, high Juniperus pollen content, a low Paq index (aquatic macrophysics proxy index), a decrease in the relative percentage of the n‐C₂₇ and an increase in the n‐C₃₁ alkanes are indicative of arid and colder climatic events related to HE 2, HE 1 and the Younger Dryas (YD). Similar short cold and arid phases during the Holocene were identified at 9.2–8.6, 7.5–7 and 5.5–5 cal. ka BP. In dolomite–mud facies, the pollen data show an increase in the herbs component, mainly – Chenopodiaceae, Artemisia and Ephedra – steppe taxa; a low Paq index, a decrease in the relative percentage of the n‐C₂₇ alkane and an increase in the n‐C₃₁ alkane are also observed. This facies was probably the result of lower lake levels and more saline–alkaline conditions, which can be interpreted as linked to arid–warm periods. These warm and arid phases were more frequent during Marine Isotope Stage (MIS) 3 and the interstadials of MIS 2. HE 4, HE 2, HE 1 and the YD in core FUENT‐1 were immediately followed by increases of warm steppe pollen assemblages that document rapid warming similar to the D/O cycles but do not imply increasing humidity in the area. Fuentillejo hydrology is controlled by changes in the atmospheric and oceanic systems that operated on the North Atlantic region at millennial scale during the last 50 cal. ka BP. Copyright © 2009 John Wiley & Sons, Ltd.     

Upper cretaceous biostratigraphy of the south-central Pyrenees (Lleida,Spain)

Abstract

Biostratigraphical data using larger foraminifera and planktonic foraminifera permitted us to establish the correlation between shallow platform sediments rich in larger foraminifera (Montsec and Serres Marginals thrust sheets) and deeper ones containing planktonic foraminifera (Boixols thrust sheet).

Consequently, the Santa Fe limestones containing Ovalveolina-Praealveolinaassemblage represent the Cenomanian. Early Turonian ( ‘IT~ archaeocretacea and P. helvetica zones) exist in both, Montsec and Boixols thrust sheets and it is constituted by Pithonella limestones. Late Turonian (M. schneegansi zone) is only present in Boixols thrust sheet (Reguard Fm.), the Montsec thrust sheet having an erosive hiatus.

Late Coniacian-Early Santonian (D. Concavata zone) is represented in the Montsec thrust sheet (Cova Limestones) and in the eastern part of the Boixols thrust sheet (St. Corneli Fm.) by two differents facies giving two different microfaunal assemblages; the firts one, characterized by Ophtalmidiidae s.l indicate a restricted lagoonal environment while the second one, characterized by diverses species of complex agglutinated, Fabulariidae, Meandropsinidae and Rotaliidae, represents an open shallow platform. In the Boixols thrust sheet (Anseroles Fm.) dominate the planktonic foraminifera and small benthic.

In the late Santonian (D. asyrnetrica zone) the sea reached as far as Serres Marginales thrust sheet where sediments (Tragó de Noguera unit) are terrigenous and deposited in a very shallow platform. In the Montsec thrust sheet (Montsec marls) the larger foraminifera indicate a platform deeper than that of the Serres Marginals thrust sheet. In the Boixols thrust sheet the sediments are deposited in an outer platform (Herbasavina Fm.) or turbiditic basin (Mascarell Mb.).

During Campanian times the transgresion reaches the maximum. In the Serres Marginals sediments are deposited in a restricted shallow environment rich in Meandropsinidae (Serres Limestones). In the Montsec thrust sheet they are deposited in a platform with patch reefs and shoals (Terradets limestones) and in the Boixols one in an outer platform, talus and/or basin.

During Early Maastrichtian times (C. falsostuarti zone) terrigenous materials arrived in the basin, the rate of sedimentation increased outstripping the subsidence rate and the retreat of the sea to the north. Late Maastrichtian (C. gansseri zone) is only present in the Boixols thrust sheet.     

Intensive agriculture, wetlands, quarries and water management. A case study (Campo de Dalias, SE Spain)

 The intensive agricultural activities that have developed over the last 50 years in the Campo de Dalias (Almeria region) have required large quantities of gravel and clay as the basic materials for the substrate over which crops are raised. With this motive, numerous gravel pits have been opened that have extracted several million cubic metres of material in recent years. Similar quantities of clay have been extracted from the distal sectors of the alluvial fans that descend from the Sierra de Gador, and from within a large endoreic basin. In the latter quarries, some wetlands have developed, probably because of the rise in the water-table level in the aquifer over which they lie. The gravel pits are situated in the apical sectors of the alluvial fans, overlying hydrogeological units that are widely overexploited. For this reason the gravel pits could be used for artificial recharge; in addition to increasing the availability of water in the aquifer, the risk of catastrophic flooding would also be reduced. Revision received: 19 November 1999 · Accepted: 28 December 1999     

Geochemistry and petrogenesis of two-Pyroxene andesites from Sierra de Gata (SE Spain)

Summary The Miocene volcanic suite of Sierra de Gata (Betic Cordillera) is composed of dacites, rhyodacites and rhyolites, besides basaltic andesites and andesites. The latter are very fresh and are the least fractionated rock types; thus they have been investigated in order to put some constraints on the genetic interpretation of the volcanic sequence. These rocks are composed of plagioclase, orthopyroxene, clinopyroxene and magnetite both as phenocrysts and in the groundmass. Olivine and ilmenite occur occasionally. The andesites exhibit orogenic chemical features. They are characterized by very low Ni, Co and Cr contents and show negative Eu anomalies, which support fractionation of mafic phases and plagioclase at depth. The petrogenesis of the andesites, however, cannot be related simply to fractionation processes of a single mafic magma since the lack of good interelemental correlations, the scattering of Sr-isotope ratios and the isotope disequilibrium between the phases conflict with such a simple mechanism. A model which can better explain the petrogenesis of the analyzed andesites considers the intervention of different mafic melts, generated in a heterogeneous mantle and characterized by different chemical and isotopic compositions, which fractionated at depth and concomitantly interacted significantly with the continental crust.

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Geochemie und Petrogenese von Pyroxen-Andesiten der Sierra de Gata (SE Spanien)

Zusammenfassung Die miozäne Vulkanitabfolge der Sierra de Gata (Betische Kordillere) wird von Daciten, Rhyodaciten, Rhyoliten sowie basaltischen Andesiten and Andesiten aufgebaut, letztere sind in einem guten Erhaltungszustand and zeigen die geringste Fraktionierung. Sie wurden daher genauer untersucht, um Aussagen über die Genese dieser Vulkanite machen zu können.Phenokrysten und Grundmasse bestehen aus Plagioklas, Orthopyroxen, Klinopyroxen und Magnetit. Manchmal kommen Olivin und Ilmenit hinzu. Die Geochemie der Andesite folgt typisch orogenen Trends. Sie sind durch sehr niedrige Ni-, Co- und Cr-Gehalte und negative Eu-Anomalien charakterisiert; dies belegt eine Fraktionierung der mafischen Gemengteile und des Plagioklases in der Tiefe. Die petrogenetische Entwicklung der Andesite kann allerdings nicht einfach mit Fraktionierungsprozessen eines einzigen mafischen Magmas erklärt werden. Das Fehlen von Element-Korrelationen, das starke Streuen der Sr-Isotopenverhältnisse und das Isotopenungleichgewicht zwischen den einzelnen Mineralphasen stehen in Widerspruch zu einem derartigen einfachen Modell. Ein Modell, das die Petrogenese der untersuchten Andesite besser erklärt, zieht die Beteiligung verschiedener mafischen Schmelzen-sie bildeten sich in einem heterogenen Mantel und sind durch Unterschiede im Chemismus und ihrer Isotopenzusammensetzung charakterisiert—in Betracht. Dabei kam es zu Fraktionierung dieser Magmen in der Tiefe und zu beträchtlichen Reaktionen mit kontinentalem Krustenmaterial.

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With 5 Figures     

Carbonate platform depositional sequences, Upper Cretaceous, south-central Pyrenees (Spain)

The Upper Cretaceous (Cenomanian-Maastrichtian) of the south-central Pyrenees shows five carbonate platform sequences where the major parameters are tectonism, relative sea-level fluctuations and inherited depositional profile. Depositional geometries and basin analysis permit an understanding of the depositional history.Five depositional sequences have been recognized: (1) The Santa Fe sequence (Middle-Upper Cenomanian), a ramp to a skeletal rimmed shelf with an escarpment bypass margin. The lower boundary is an angular unconformity and the upper one records a sea-level drop. The platform location of the margin was determined by a listric normal fault. (2) An abrupt sea-level rise drowned the former platform. The Congost sequence (Turonian-Lower Coniacian), a distally steepened ramp with erosional distal deep slope. The depositional model was largely controlled by pre-existing basin morphology. Cessation of platform development was due to a relative sea-level drop. (3) The Sant Corneli sequence (Upper Coniacian-Lower Santonian), a mixed terrigenous-skeletal homoclinal ramp with upright margin, deep slope and dysaerobic basin. The slope results from the backstepping by 24 km of the previous margin and gentle basin tilting. The platform margin remained more or less at the same position, and relief between platform and slope increased indicating continuous relative sea-level rise. The upper boundary is an angular unconformity at the platform margin produced by an abrupt sea-level rise and platform drowning, and by listric normal faulting. (4) The Vallcarga sequence (Upper Santonian-Campanian), a distal-steepened skeletal homoclinal ramp, erosional escarpment and turbidite basin, which corresponds to the Mesozoic maximum marine expansion. A listric normal fault created two depositional areas: a more or less flat footwall block with a north-northwest prograding carbonate ramp.     

Active faults, seismicity and stresses in an internal boundary of a tectonic arc (Campo de Dalías and Níjar, southeastern Betic Cordilleras, Spain)

The Betic-Rif Cordilleras, formed by the interaction of NW–SE convergence between the Eurasian and African plates and the westward motion of their Internal Zones, provide a good example of an active tectonic arc. The Campo de Dalías and Campo de Níjar constitute outcropping sectors of Neogene and Quaternary rocks located in the southeastern border of the Betic Cordilleras and allow us to study the recent deformations developed in the internal border of this tectonic arc.The main active faults with related seismicity, representing a moderate seismic hazard, associated to the southeastern Betic Cordilleras boundary, include high-angle NW–SE-oriented normal faults that affect, at least, the upper part of the crust, a main detachment located at 10 km depth, and probably another detachment at 20 km as well. Seismite structures, recent fault scarps with associated colluvial wedges that deform the drainage network and the alignment of the coastline, indicate that the high-angle faults have been active at least since the Quaternary.Paleostresses determined from microfault analysis in Quaternary deposits generally show an ENE–WSW trend of extension. Present-day earthquake focal mechanisms include normal, strike-slip and reverse faulting. Normal and strike-slip focal mechanisms generally indicate ENE–WSW extension, and strike-slip and reverse focal mechanisms are related to NNW–SSE compression.The maximum horizontal compression has a consistently NNW–SSE trend. The deep activity of detachments and reverse faults determines the NNW–SSE crustal shortening related to the Eurasian–African plate convergence. At surface, however, the predominance of normal faults is probably produced by the increase in the relative weight of the vertical stress axis, which in turn may be related to relief uplift and subsequent horizontal spreading. The internal mountain front boundary of the Betic Cordilleras developed through the activity of a set of structures that is more complex than a typical external mountain front, probably as a consequence of a vertical variable stress field that acted on previously deformed rocks belonging to the Internal Zone of the cordilleras.     

A 220 ka palaeoenvironmental reconstruction of the Fuentillejo maar lake record (Central Spain) using biomarker analysis

The sedimentary record of the volcanic lake known as the Fuentillejo maar (central Spain) offers the opportunity to determine the palaeoenvironmental evolution of the central-southern part of the Iberian Peninsula during the Middle and Upper Pleistocene. A total of 439 samples from the upper 88 m of a ca. 142 m long core (spanning the last ca. 355 ka) were examined. The interval corresponds to the last 220 ka of the record. High n-alkane CPI values and the presence of sulfur revealed that little diagenetic signal attenuation or modification had occurred. A number of n-alkane-based indices (e.g. predominant n-alkane, ACL, Paq and TAR_HC ratios, and the proportion of C₂₇, C₂₉ and C₃₁ n-alkanes with respect to the summed C₂₇ + C₂₉ + C₃₁) alkanes, showed changing conditions in the organic matter input to the maar lake over time, with episodes involving a major input of terrestrial vegetation, alternating with others in which algae or a mixed input of terrestrial plants, aquatic macrophytes and algae occurred. The proportions of C₂₇, C₂₉ and C₃₁ were useful for reconstructing the palaeoenvironmental evolution of the basin as they allowed assignment of several dry intervals during which grasses developed, while during humid phases trees expanded at the expense of grasses.In general, we found good correspondence between these episodes and the climatic cycles observed in δ¹⁸O records from ices cores in Greenland and Antarctica, as well as from marine cores. Thus, we conclude that global palaeoclimatological changes were recorded in the maar record. Likewise, Heinrich Events appeared to be reflected in the n-alkane indices. This was confirmed by single spectral analysis and cross spectral analysis with the insolation curve on 21 July at a latitude of 65°N. The approach revealed that the cycles interpreted in the Fuentillejo record (103, 41, 23 and 19 ka) showed evidence of orbital influence related to the astronomical cycles of the eccentricity variation in the Earth’s orbit, the Earth’s obliquity oscillation, and the precession variation (Milankovitch theory).     

Neogene evolution of the Campo de Dalias and the surrounding offshore areas - (Northeastern Alboran Sea)

Abstract

The Campo de Dalias is an emerged portion of the Alboran Sea, located on its northeastern margin. The study of this basin and its surrounding offshore areas reveals the structure on the region, whose outstanding feature is the N70-80E anticline extending from Guardias Viejas to Roquetas and continuing eastward under the sea. The other parts of the structure are characterized by several fault sets, the most important of which are those of N 70-9OE, N 120E and N45E direction. Some of these fault sets of originally different ages later replayed throughout the late Miocene up to the Quaternary. These replays seem to have occurred in approximately N-S compressive situations.

The main compressive events took place in the latest Torto-nian and early Pleistocene. Between these two events a stage of considerable subsidence in the Pliocene basin can be detected, which caused the accumulation of sediments over a thousand metres thick in some places. Equally, we can detect an important uplift of the surrounding reliefs coeval with subsidence. Two transgressive situations are recorded and two important eustatic falls and partial emersion of the basin margin, mainly during the Messinian.     

Geoarchaeology and Construction of the La Chabola de la Hechicera Megalithic Tomb,Elvillar, Northern Spain

La Chabola de la Hechicera, a Neolithic collective tomb which was first used at ca. 3850 B.C., has been re‐excavated for interpretation and stabilization. Information about the sources, handling, and placement of building materials allowed determination of the methods used to construct the dolmen monument. All of the rocks used in the structure are local Miocene sandstones, and the slabs were probably taken directly from the base of natural slopes near the monument. The chamber slabs were not carved, but some passage slabs were retouched to level the cover slabs. Fragments for the tumulus were obtained by mechanical fracturing. All of the slabs are imbricated, making it possible to determine the order in which they were placed. Thus, the identification of building materials and their mode of placement allows for the reconstruction of each stage of the building of the monument, providing unusually rich data for understanding the geoarchaeology and building archaeology of a dolmenic structure.     

Geochemistry of the polymetamorphic mafic-ultramafic complex at Cabo Ortegal (NW Spain)

The Paleozoic Cabo Ortegal complex (Galicia, NW Spain) contains (1) a mafic rock series, now high-grade metamorphic rocks, that is equivalent to modern continental plateau basalts; this can be deduced from its trace element ‘fingerprint’, the [La/Sm]_a ratio of 3.25 and the quartz normative composition, (2) a younger mafic rock series equivalent to modern (Icelandic) ‘plume’ tholeiites, as can be inferred again from the trace element ‘fingerprint’, the [La/Sm]_a ratio of around unity and the olivine normative composition, (3) an ultramafic rock series that was the melt phase and then the residual phase in two subsequent melting events as can be inferred from the low La, Sm, K, and Rb contents compared with the high [La/Sm]_a and K/Rb ratios. The data are fitted into an evolution model of continental rifting, mantle-plume diapirism and rejuvenation of the lowe, crust.     

A complementary section for the proposed Toarcian (Lower Jurassic) global stratotype: The Almonacid de la Cuba section (Spain)

We present the biostratigraphy (ammonites, brachiopods, foraminifers, and ostracodes), lithostratigraphy, sedimentology, sequence stratigraphy, magnetostratigraphy, and isotope stratigraphy of the Almonacid de la Cuba section located in the Iberian Range, central-eastern Spain. This section, which contains a continuous and expanded record of the Pliensbachian-Toarcian boundary (Early Jurassic), has been proposed as a complementary section for the Toarcian GSSP. An excellent ammonite-based biozonation has been obtained. Four ammonite assemblages characterized by the presence of Pleuroceras, Canavaria, Dactylioceras (Eodactylites), and Dactylioceras (Orthodactylites) have been distinguished. The base of the Toarcian is located at level CU35.2, based on the first occurrence of Dactylioceras. The occurrence of taxa from the NW European and the Mediterranean provinces is useful to improve the correlation between both provinces. Foraminiferal and ostracode assemblages are rich and diversified and no significant biostratigraphic events take place at the Pliensbachian-Toarcian boundary. The magnetostratigraphic data presented here are the most complete record of reversals of the earth magnetic field for the Pliensbachian-Toarcian boundary. A good record of the onset of the positive δ¹³C excursion reported in the Lower Toarcian of many European sections has been obtained. Average paleotemperatures measured at the latest Pliensbachian Spinatum Biochron of about 12.5°C, recorded a marked increase of the seawater temperature which started during the Toarcian, reaching average temperatures of 16.7°C at the Tenuicostatum Biochron. The obtained ⁸⁷Sr/⁸⁶Sr values fully agree with the LOWESS calibration curve.     

Nature and evolution of the lower crust under central Spain: Inferences from granulite xenoliths (Calatrava Volcanic Field-Spanish central system)

So far, the nature and evolution of the lower crust under central Spain have been constrained mainly on the basis of a heterogeneous suite of granulite xenoliths from the Spanish Central System (SCS). In recent years, ultramafic volcanics from the Calatrava Volcanic Field (CVF) have also provided deep-seated crustal xenoliths which have not been studied in detail. Our data, combining mineral, whole-rock and isotopic geochemistry with U–Pb–Hf isotope ratios in zircons from the CVF and SCS xenoliths, highlight the felsic composition of the lower crust under central Iberia. A number of the Calatrava xenoliths represents Variscan igneous protoliths, which are a minor population in the SCS, and were likely formed by crystallisation of intermediate and felsic melts in the lower crust during the Variscan orogeny (leucodiorite protolith age of 314 ± 3 Ma and leucogranite protolith age of 308 ± 2.5 Ma). U–Pb data of metamorphic zircons show that granulite-facies metamorphism mainly occurred from 299 to 285 Ma in both areas. These ages are slightly younger than those of granitic intrusions that could be genetically related to the granulitic residue, which points to a main role of U–Pb isotope resetting in lower crustal zircons during HT or UHT conditions. The zircon U–Pb–Hf isotopic ratios support the idea that the lower crust in central Iberia consists mainly of Ordovician–Neoproterozoic metaigneous and metasedimentary rocks associated with the Cadomian continental arc of northern Gondwana. These rocks provide evidence of mixing between juvenile magmas and an enriched crustal component, ultimately extracted from an Eburnean crust. Other more evolved components present in detrital zircons are likely related to recycling of Archean crust derived from North Africa cratonic terranes.     

Geochemistry, mineralogy, and technological properties of the main Stephanian (Carboniferous) coal seams from the Puertollano Basin, Spain

This study is focused on the occurrence and distribution of mineral matter and major and trace elements in the high volatile bituminous coal from Puertollano (south-central Spain). The relationship between ash behaviour and inorganic composition, as well as the possible formation of fouling and slagging deposits in boilers during the conversion process, were investigated. The Puertollano coals do not exhibit plastic properties, despite their rank, probably because of their high ash and inertinite contents.The Puertollano coal has medium to low total S content (0.48% to 1.63% db, with a mean of 1.0% db) and is characterised by relatively high contents of Si, Pb, Sb, and Cs. Some elements such as As, Cd, Co, Cr, Cu, Ge, Li, Mn, Ni, W, and Zn are also present in relatively high contents. The enrichment in a number of heavy metals could be attributed to the common sulphide ores occurring near the Puertollano coal deposit.The following trace elements affinities are deduced: (a) sulphide affinity: As, Co, Cd, Cu, Ni, Sb, Tl, and Zn; (b) aluminum–silicate affinity: K, Ti, B, Co, Cr, Cs, Cu Ga, Hf, Li, Nb, Rb, Sn, Ta, Th, V, Zr, and LREE; (c) Carbonate affinity: Ca, Mg, Mn, and B; (d) organic affinity: B.The very high Si levels and the anomalous enrichment in Cs, Ge, Pb, Sb, and Zn shown by the Puertollano coals account for the high contents of these elements in the Puertollano fly ash when compared with the other Spanish coal fly ashes.The chemical composition of the high temperature ash (HTA) is consistent with the trend shown by the ash fusion temperatures (AFT) and also with the predictive indices related to slagging and fouling propensities. Thus, the ash fusion temperatures increase with high values of Al₂O₃ as well as with the decrease in Fe₂O₃, CaO, and MgO.     

Trace element degassing and enrichment in the eruptive plume of the 2000 eruption of Hekla volcano, Iceland

During its last eruption in February 2000, Hekla volcano (Iceland) emitted a sub-Plinian plume that was condensed and scavenged down to the ground by heavy snowstorms, offering the unique opportunity to study the chemistry of the gaseous plume released during highly explosive eruptions. In this paper, we present results on trace element and minor volatile species (sulfates, chlorides, and fluorides) concentrations in snow samples collected shortly after the beginning of the eruption. The goal of this study is to better constrain the degassing and mobility of trace elements in gaseous emissions. Trace element volatility at Hekla is quantified by means of enrichment factors (EF) relative to Be. Well-known volatile trace elements (e.g., transition metals, heavy metals, and metalloids) are considerably enriched in the volcanic plume of Hekla. Their abundances are governed by the primary magmatic degassing of sulfate and/or halide compounds, which are gaseous at magmatic temperature. Their volatility is, however, slightly lower than in basaltic systems, most likely because of the lower magma temperature and higher magma viscosity at Hekla. More surprisingly, refractory elements (e.g., REE, Th, Ba, and Y) are also significantly enriched in the eruptive plume of Hekla where their apparent volatility is two orders of magnitude higher than in mafic systems. In addition, REE patterns normalized to the Hekla 2000 lava composition show a significant enrichment of HREE over LREE, suggesting the presence of REE fluorides in the volcanic plume. Such enrichments in the most refractory elements and REE fractionation are difficult to reconcile with primary degassing processes, since REE fluorides are not gaseous at magma temperature. REE enrichments at Hekla could be attributed to incongruent dissolution of tephra grains at low temperature by F-rich volcanic gases and aerosols within the eruptive plume. This view is supported by both leaching experiments performed on Hekla tephra and thermodynamic considerations on REE mobility in hydrothermal fluids and modeling of glass dissolution in F-rich aqueous solutions. Tephra dissolution may also explain the observed enrichments in other refractory elements (e.g., Th, Y, and Ba) and could contribute to the degassing mass balance of some volatile trace elements, provided they are mobile in F-rich fluids. It thus appears that both primary magmatic degassing and secondary tephra dissolution processes govern the chemistry of eruptive plumes released during explosive eruptions.     

Mineralisation from Vall de Ribes area (Eastern Pyrenees,Spain)

Vein mineralisation with no preferred orientation, cutting lower Palaeozoic rocks, and local replacement deposits in dolomite show a zoning in tungsten-bismuth, arsenic and antimony minerals away from the adjacent late-Hercynian Costabona granite. A local reversed zoning is related to higher temperatures indicated by fluid inclusion study. Many of the minerals have not previously been reported from this area.     

Impact area determination of pyroclastic deposits in Lascar volcano, eruptive process in the year 1993

By means of multi-temporal analysis of satellite images and statistical algorithms, the amount of pyroclastic material deposited on Lascar volcano walls after the gravitational collapse of the eruptive column caused by the eruption that occurred on April the 19th and the 20th in 1993 was determined and quantified. For this analysis, scenes corresponding to Landsat 4 TM in 1989 and Landsat 7 ETM+ in 2001 were used. By careful selection methods such as combination of bands, unsupervised classification, and the Karhunen–Loève transform, detailed analysis of zones of change that correspond to pyroclastic deposits were made. This analysis was complemented with in situ data in order to correct and calibrate the satellite images to identify zones of 1993s eruption pyroclastic deposits. Using Kittler’s and other thresholding algorithms, a search was performed for a proper threshold to binarize the images to determine the surface area covered by the eruptive process. Matlab™ software was used both for general programming and for digital image processing.     

Variations in stratigraphic and reservoir properties adjacent to the Mid-Paleocene sequence boundary, Campo section, Pyrenees, Spain

The Paleocene of the Campo section, Spain has different sedimentological characteristics above and below the Mid-Paleocene Unconformity. Beneath the unconformity sediments are dominated by evaporitic carbonates and collapse breccias. Above it they are characterized by continental detrital beds alternating with paleosols. Different subaerial features are observed and correspond to different porosity values, pore–throat sizes and micrite morphologies. Unexposed or intertidal facies have low porosity, low throat–pore size (mesoporosity) and well preserved rhombic crystals. Intermediate exposed facies (paleosols) possess medium porosity, medium pore–throat size (microporosity) and mainly micro-rhombic crystals. Finally, the facies corresponding to high exposure intensity and to evaporitic original facies presents high porosity, permeability, large pore–throat size and rounded micritic crystals. These observations show that the emersion phase caused important dissolution, especially when associated with an easily dissolved original lithofacies.