Determination of the concentration of potassium chloride solution having the same electrical conductivity, at 15°C and infinite frequency, as standard seawater of salinity 35.0000 ‰ (Chlorinity 19.37394 ‰)

The absolute electrical conductivity at15degC of several lots of standard seawater has been measured with great precision as a function of chlorinity. Potassium chloride (KCI) solutions of known concentration and having almost the same conductivity were also measured and the concentration giving the same conductivity at15degC as35.0000permilstandard seawater (Chl =19.37394permil) was found to be 32.4352 g/kg.     

The effect of concentration and temperature on the conductivity ratio of potassium chloride solutions to standard seawater of salinity 35 ‰(Cl 19.3740 ‰)

The ratiosZ_{K,t}of electrical conductivities of potassium chloride (KCI) solutions of known concentration (K) to standard seawater at the same temperature have been measured at15degC and24degC for solutions withZ_{k,15}between 0.96 and 1.04. The "normal" concentration (N or K_{N}) givingZ_{N,15}= 1was found to beK_{N} = 32.4356gKCI/kg solution. The effect of temperature onZ_{N,t}was measured over the range15degC to30degC. Equations are given for KCI concentration as a function ofZ_{15}and the inverse function, forZ_{15}/Z_{24}as a function ofZ_{24}(to allow use of a laboratory salinometer for the KCI-seawater comparisons), andZ_{N,t}as a function of temperature.     

西南印度洋49°～56°E洋脊段的热液羽状流:来自深水中的氦同位素异常证据

海水中的氦同位素能对海底热液活动进行有效示踪。本文对在西南印度洋49°~56°E洋脊段采集的5条CTD拖曳剖面共14件深水样品进行了氦氖同位素分析。通过分析水体中存在的氦同位素异常,探讨调查区热液异常的特征和热液羽状流的分布。分析表明,5条CTD剖面均存在δ3He异常,其中CTD7-2(位置:37.927°S、49.412°E,水深2 140m,离底高度100m)的δ3He值最大,达到49.2%。根据δ3He分布特征,认为调查区内存在至少6处热液羽状流,其中37.927°S、49.412°E以西数千米范围内可能存在海底热液喷口。     

The morphotectonics and its evolutionary dynamics of the central Southwest Indian Ridge (49° to 51°E)

The morphotectonic features and their evolution of the central Southwest Indian Ridge （SWIR） are dis- cussed on the base of the high-resolution flfll-coverage bathyraetric data on the ridge between 49°-51°E. A comparative analysis of the topographic features of the axial and flank area indicates that the axial topogra- phy is alternated by the ridge and trough with en echelon pattern and evolved under a spatial-temporal mi- gration especially in 49°-50.17°E. It is probably due to the undulation at the top of the mantle asthenosphere, which is propagating with the mantle flow. From 50.17° to 50.7°E, is a topographical high terrain with a crust much thicker than the global average of the oceanic crust thickness. Its origin should be independent of the spreading mechanism of ultra-slow spreading ridges. The large numbers of volcanoes in this area indicate robust magmatic activity and may be related to the Crozet hot spot according to RMBA （residual mantle Bouguer anomaly）. The different geomorphological feature between the north and south flanks of the ridge indicates an asymmetric spreading, and leading to the development of the OCC （oceanic core complex）. The tectonic activity of the south frank is stronger than the north and is favorable to develop the OCC. The first found active hydrothermal vent in the SWIR at 37°47＇S, 49°39＇E is thought to be associated with the detach- ment fault related to the OCC.     

The solubility of calcite in seawater at atmospheric pressure and 35%permil; salinity

The apparent (stoichiometric) solubility product of calcite in artificial seawater of salinity 35‰ was measured by a saturometer technique. The value of the apparent solubility product was found to be (4·59 ± 0·05) × 10⁻⁷ moles/(kilogram of seawater)² at 25°C with a temperature coefficient of −0·0108 × 10⁻⁷/°C between 2 and 25°C. These values are significantly smaller than those found by MacIntyre (1965) and other workers. The effect of these results on the saturation of the oceans with respect to calcite is examined.     

The physical structures of snow and sea ice in the Arctic section of 150°-180°W during the summer of 2010

The physical structures of snow and sea ice in the Arctic section of 150°-180°W were observed on the basis of snow-pit, ice-core, and drill-hole measurements from late July to late August 2010. Almost all the investigated floes were first-year ice, except for one located north of Alaska, which was probably multi-year ice transported from north of the Canadian Arctic Archipelago during early summer. The snow covers over all the investigated floes were in the melting phase, with temperatures approaching 0℃ and densities of 295-398 kg/m3 . The snow covers can be divided into two to five layers of different textures, with most cases having a top layer of fresh snow, a round-grain layer in the middle, and slush and/or thin icing layers at the bottom. The first-year sea ice contained about 7%-17% granular ice at the top. There was no granular ice in the lower layers. The interior melting and desalination of sea ice introduced strong stratifications of temperature, salinity, density, and gas and brine volume fractions. The sea ice temperature exhibited linear cooling with depth, while the salinity and the density increased linearly with normalized depth from 0.2 to 0.9 and from 0 to 0.65, respectively. The top layer, especially the freeboard layer, had the lowest salinity and density, and consequently the largest gas content and the smallest brine content. Both the salinity and density in the ice basal layer were highly scattered due to large differences in ice porosity among the samples. The bulk average sea ice temperature, salinity, density, and gas and brine volume fractions were-0.8℃, 1.8, 837 kg/m3 , 9.3% and 10.4%, respectively. The snow cover, sea ice bottom, and sea ice interior show evidences of melting during mid-August in the investigated floe located at about 87°N, 175°W.     

南海18°N断面中层水的年代际变化

利用中国科学院南海海洋研究所历史温盐剖面观测资料和WOD09(World Ocean Database2009)中的CTD、OSD、PFL温盐剖面资料,分析了1965-2012年间南海18°N跨海盆断面中层水的变化特征。研究结果表明:中层水平均盐度呈现显著的年代际变化,20世纪60年代中期至70年代末,中层水平均盐度约为34.432,80年代盐度增加至34.440,90年代之后至今盐度明显降低;在年代际尺度变异调制下,不同年代中层水盐度变化有不同的变化趋势,1967-1977年呈现显著的下降趋势,1990-1997年中层水盐度从34.450迅速降为34.414,而在1997年之后表现出明显上升趋势,与此同时,中层水温度有着相似的变化特征,与90年代之前相比,21世纪以来温度与盐度同步下降,并且变化幅度变小。与大洋的中层水团年代际变异相比,南海18°N断面中层水呈现出与大洋不同的特征。另外,中层水盐度有着十分显著的年际变化,其振幅远大于年代际尺度变异,并且与ENSO密切相关,在厄尔尼诺年达到极小值。     

Latitudinal changes (6°S-20°N) of summer ciliate abundance and species compositions in surface waters from the Java Sea to the South China Sea

Ciliates play a curial role in energy transfer from pico-and nano-phytoplankton to mesozooplankton in marine ecosystems. In order to visualize their geographical distributions from the Java Sea to the South China Sea (6°S to 20°N), the authors investigated the ciliate abundance and species composition in surface waters during May 18 to 27 of 2010. The ciliate abundance decreased latitudinally from 3 080 ind./L (～6°S) to 40 ind./L (～3°N), and then increased to 1 180 ind./L (～16°N) at the end of the survey. A total of 22 ciliates belonging to 15 genera were identified with the tintinnids accounted for 50% (11 species); and the species number showed a same spatial change as the ciliate abundance. Moreover, the Strombidium occupied over 50% of total ciliate abundance in most stations and Mesodinium and Tintinnopsis contributed to about 18.7% and 11.4%, respectively. In particular, our results indicate that the geographical changes in ciliate abundance were positively regulated by larger nano-and micro-phytoplankton biomass, rather than smaller pico-phytoplankton in the investigated waters.     

The variation of turbulent diapycnal mixing at 18°N in the South China Sea stirred by wind stress

The spatial and temporal variations of turbulent diapycnal mixing along 18°N in the South China Sea(SCS) are estimated by a fine-scale parameterization method based on strain, which is obtained from CTD measurements in yearly September from 2004 to 2010. The section mean diffusivity can reach ~10~(–4)m~2/s, which is an order of magnitude larger than the value in the open ocean. Both internal tides and wind-generated near-inertial internal waves play an important role in furnishing the diapycnal mixing here. The former dominates the diapycnal mixing in the deep ocean and makes nonnegligible contribution in the upper ocean, leading to enhanced diapycnal mixing throughout the water column over rough topography. In contrast, the influence of the wind-induced nearinertial internal wave is mainly confined to the upper ocean. Over both flat and rough bathymetries, the diapycnal diffusivity has a growth trend from 2005 to 2010 in the upper 700 m, which results from the increase of wind work on the near-inertial motions.     

Mineralogical characteristics of polymetallic sulfides from the Deyin-1 hydrothermal field near 15°S,southern Mid-Atlantic Ridge

A seafloor hydrothermal field, named Deyin-1 later, near 15°S southern Mid-Atlantic Ridge(SMAR) was newly found during the 22 nd cruise carried out by the China Ocean Mineral Resources Research Development Association(COMRA). Sulfide samples were collected at three stations from the hydrothermal field during the26 th cruise in 2012. In this paper, mineralogical characteristics of the sulfides were analyzed with optical microscope, X-ray diffractometer, scanning electron microscope and electron microprobe to study the crystallization sequence of minerals and the process of hydrothermal mineralization. According to the difference of the ore-forming metal elements, the sulfide samples can be divided into three types:(1) the Ferich sulfide, which contains mainly pyrite and chalcopyrite;(2) the Fe-Cu-rich sulfide consisting predominantly of pyrite, chalcopyrite and isocubanite, with lesser amount of sphalerite, marmatite and pyrrhotine; and(3) the Fe-Zn-rich sulfide dominated by pyrite, sphalerite and marmatite, with variable amounts of chalcopyrite, isocubanite, pyrrhotine, marcasite, galena and gratonite. Mineral precipitations in these sulfides are in the sequence of chalcopyrite(isocubanite and possible coarse pyrite), fine pyrite,sphalerite(marmatite), galena, gratonite and then the minerals out of the dissolution. Two morphologically distinct generations(Py-I and Py-II) of pyrite are identified in each of the samples; inclusions of marmatite tend to exist in the coarse pyrite crystals(Py-I). Sphalerite in the Fe-Zn-rich sulfide is characterized by a"chalcopyrite disease" phenomenon. Mineral paragenetic relationships and a wide range of chemical compositions suggest that the environment of hydrothermal mineralization was largely changing. By comparison, the Fe-rich sulfide was formed in a relatively stable environment with a high temperature, but the conditions for the formation of the Fe-Cu-rich sulfide were variable. The Fe-Zn-rich sulfide was precipitated during the hydrothermal venting at relatively low temperature.     

热带中东太平洋海域10°N断面水团分析

本文基于实测温盐数据等资料,利用水团的浓度混合分析等方法,揭示了热带中东太平洋海域10°N断面的水团构成自上而下分别为东部赤道–热带水团、北太平洋中央水团、加利福尼亚流系水团、南太平洋中央水团、太平洋亚北极水团和太平洋深层水团。分析发现,受热带辐合带影响,9°～10°N海域常年持续的正风应力旋度诱发上升流出现,北太平洋中央水团、加利福尼亚流系水团、南太平洋中央水团和太平洋亚北极水团4个通风潜沉水团经向运动至该纬度带时被抽吸至次表层和中层,并散布在不同深度。以往研究仅指出上述4个水团在海表通风形成后将潜沉并向赤道方向运动,本研究进一步阐明了4个水团潜沉后向热带海域运动的动力机制及其在热带中东太平洋10°N断面的散布深度。研究成果揭示了热带中东太平洋水团与北太平洋副热带、亚极地和南太平洋副热带海区中上层水团间的循环过程,对认识北太平洋高–中–低纬度间物质和能量的交换和再分配具有重要科学价值。     

The effect of pressure on the solubility of amorphous silica in seawater at 0°C

The solubility of amorphous silica in seawater at 0°C and from 1 to 1,220 atm. was found to be a linear function of pressure above 270 atm., but to deviate from linearity below that pressure. Using a quadratic derivation of Planck's equation, ΔV for the dissolution was found to be −16.5 cm³mole⁻¹, and Δk was found to be −4.4 · 10⁻² cm³ mole⁻¹ atm⁻¹∂Δk/∂P was found to be 27.2 · 10⁻⁵ cm³ mole⁻¹ atm⁻² which is too significant a factor to allow the commonly made assumption that ∂Δk/∂P =0. North's (1973) model of hydration suggests that this non-zero ∂Δk/∂P may indicate that the silicic acid molecule is more extensively hydrated at lower pressures.If the pressure in an experiment is suddenly lowered to atmospheric pressure after equilibrium solubility had been attained at the higher pressure, the precipitation that occurs to reduce the resulting supersaturation is complete within one hour in the experimental system used in this study.     

Chemical composition and petrogenesis of plagioclases in plagioclase-phyric basalts from the Southwest Indian Ridge(51°E)

Electron microprobe analysis was conducted on plagioclase from the plagioclase ultraphyric basalts(PUBs)erupted on the Southwest Indian Ridge(SWIR)(51°E) to investigate the geochemical changes in order to better understand the magmatic processes occurring under ultraslow spreading ridges and to provide insights into the thermal and dynamic regimes of the magmatic reservoirs and conduit systems. The phenocryst cores are generally calcic(An_(74–82)) and are depleted in FeO and MgO. Whereas the phenocryst rims(An_(67–71)) and the plagioclase in the groundmass(An_(58–63)) are more sodic and have higher FeO and MgO contents than the phenocryst cores. The crystallization temperatures of the phenocryst cores and the calculation of the equilibrium between the phenocrysts and the matrix suggest that the plagioclase cores are unlikely to have crystallized from the host basaltic melt, but are likely to have crystallized from a more calcic melt. The enrichment in incompatible elements(FeO and MgO), as well as the higher FeO/MgO ratios of the outermost phenocryst rims and the groundmass, are the result of plagioclase-melt disequilibrium diffusion during the short residence time in which the plagioclase crystallized. Our results indicate that an evolved melt replenishing under the SWIR(51°E) drives the eruption over a short period of time.     

The dissociation constants of carbonic acid in seawater at salinities 5 to 45 and temperatures 0 to 45°C

The pK₁^* and pK₂^* for the dissociation of carbonic acid in seawater have been determined from 0 to 45°C and S = 5 to 45. The values of pK₁^* have been determined from emf measurements for the cell:

Pt](1 − X)H2 + XCO2|NaHCO3, CO2 in synthetic seawater|AgC1; Ag

where X is the mole fraction of CO₂ in the gas. The values of pK₂^* have been determined from emf measurements on the cell:

Pt, H2(g, 1 atm)|Na2CO3, NaHCO3 in synthethic seawater|AgC1; Ag

The results have been fitted to the equations:

lnK^*₁ = 2.83655 − 2307.1266/T − 1.5529413 lnT + (−0.20760841 − 4.0484/T)S^0.5 + 0.08468345S − 0.00654208S¹

InK^*₂ = −9.226508 − 3351.6106/T− 0.2005743 lnT + (−0.106901773 − 23.9722/T)S^0.5 + 0.1130822S − 0.00846934S^1.5

where T is the temperature in K, S is the salinity, and the standard deviations of the fits are σ = 0.0048 in lnK₁^* and σ = 0.0070 in lnK₂^*.Our new results are in good agreement at S = 35 (±0.002 in pK₁^*and ±0.005 in pK₂^*) from 0 to 45°C with the earlier results of Goyet and Poisson (1989). Since our measurements are more precise than the earlier measurements due to the use of the Pt, H₂|AgCl, Ag electrode system, we feel that our equations should be used to calculate the components of the carbonate system in seawater.     

The solubility of CaCO3 in seawater at 2°C based upon in-situ sampled pore water composition

Analyses of the concentration product (Ca²⁺) × (CO₃²⁻) in the pore waters of marine sediments have been used to estimate the apparent solubility products of sedimentary calcite (K′_SPc) and aragonite (K′_SPa) in seawater. Regression of the data gives the relation In K′^P_SPc = 1.94 × 10⁻³ δP − 14.59 The 2°C, 1 atm value of K′_SPc is, then, 4.61 × 10⁻⁷ mol² l⁻². The pressure coefficient yields a at 2°C of −43.8 cm³ atm⁻¹. A single station where aragonite is present in the sediments gives a value of K′_SPa = 9.2 × 10⁻⁷ (4°C, 81 atm). The calcite data are very similar to those determined experimentally by Ingle et al. (1973) for K′_SPc at 2°C and 1 atm. The calculated is also indistinguishable from the experimental results of Ingle (1975) if is assumed to be independent of pressure.     

Equilibrium and structural studies of silicon(IV) and aluminium(III) in aqueous solution. II. Formation constants for the monosilicate ions SiO(OH)3− and SiO2(OH)22−. A precision study at 25°C in a simplified seawater medium

The hydrolysis of silicic acid, Si(OH)₄, was studied in a simplified seawater medium (0.6 M Na(Cl)) at 25°C. The measurements were performed as potentiometric titrations (hydrogen electrode) in which OH^? was generated coulometrically. The total concentration of Si(OH)₄, B, and log[H⁺] were varied within the limits 0.00075 ? B ? 0.008 M and 2.5 ? -log[H⁺] ? 11.7, respectively. Within these ranges the formation of SiO(OH)₃^? and SiO₂(OH)₂^2? with formation constants log β_?11(Si(OH)₄ ? SiO(OH)₃^? + H⁺) = ?9.472 ±0.002 and log β_?21(Si(OH)₄ ? SiO₂(OH)₂^2? + 2H⁺) = ?22.07 ± 0.01 was established. With B > 0.003 M polysilicate complexes are formed, however, with $\text{-}\text{log[H}{}^{\mathrm{+}}\text{] ? 10.7}$ their formation does not significantly affect the evaluated formation constants. Data were analyzed with the least squares computer program LETAGROPVRID.     

Equilibrium and structural studies of silicon(IV) and aluminium(III) in aqueous solution. II. Formation constants for the monosilicate ions SiO(OH)3 and SiO2(OH)2. A precision study at 25°C in a simplified seawater medium

The hydrolysis of silicic acid, Si(OH)₄, was studied in a simplified seawater medium (0.6 M Na(Cl)) at 25°C. The measurements were performed as potentiometric titrations (hydrogen electrode) in which OH⁻ was generated coulometrically. The total concentration of Si(OH)₄, B, and log[H⁺] were varied within the limits 0.00075 B 0.008 M and 2.5 -log[H⁺] 11.7, respectively. Within these ranges the formation of SiO(OH)₃⁻ and SiO₂(OH)₂²⁻ with formation constants log β₋₁₁(Si(OH)₄ SiO(OH)₃⁻ + H⁺) = −9.472 ±0.002 and log β₋₂₁(Si(OH)₄ SiO₂(OH)₂²⁻ + 2H⁺) = −22.07 ± 0.01 was established. With B > 0.003 M polysilicate complexes are formed, however, with -log[H⁺] 10.7 their formation does not significantly affect the evaluated formation constants. Data were analyzed with the least squares computer program LETAGROPVRID.     

The Effect of Temporal Changes and Environmental Trophic Condition on the Isotopic Composition (ω13C and ω15N) of Atherina boyeri (Risso, 1810) and Gobius niger (L., 1758) in a Mediterranean Coastal Lagoon (Lake of Sabaudia): Implications for Food Web Structure

Abstract. ω¹³C and ω¹⁵N of organic matter sources and consumers were employed to analyse trophic differentiation between a benthic consumer, Gobius niger (L., 1758) (Pisces, Osteichthyes), and a pelagic consumer, Atherina boyeri (Risso, 1810) (Pisces, Osteichthyes) in a Mediterranean coastal lagoon (Lake of Sabaudia) in winter and summer 1999. Trophic differences between the two species throughout the two sampling periods were related to the environmental trophic condition (i. e. nutrient and phytopigment concentrations). Although these two fish have different habitats, they both exploited benthic organisms, above all in summer. When the nutrient and phytopigment concentrations were higher (summer), the most abundant benthic organisms were the main food sources for both species. In winter A. boyeri apparently shifted its feeding preferences to include zooplankton, confirming its opportunistic feeding strategy. Par-ticulate organic matter and algae seemed to play the main trophic role in the food web structure. Benthic invertebrates used both sources, while zooplankton seemed to rely exclusively on the particulate fraction. The overlapping and very depleted signatures of sedimentary and particulate organic matter highlights a strong link between sediments and water column, rarely observed in other aquatic ecosystems using stable isotopes. Such a finding further substantiates the importance of particulate organic matter as a food source in the study area.     

Equilibrium and structural studies of silicon(iv) and aluminium(iii) in aqueous solution. V. Acidity constants of silicic acid and the ionic product of water in the medium range 0.05–2.0 M Na(CI) at 25°C

The apparent ionization constants for silicic acid, k₁ and k₂, and the ionic product of water, k_w, have been determined in 0.05, 0.1, 0.2, 0.4 and 2.0 M Na(CI) media at 25°C. The medium dependence of these constants was found to fit equations of the form

$\text{log}\text{k}{}_{\mathrm{i}}\text{=}\text{log}\text{K}{}_{\mathrm{i}}\text{+a}{}_{\mathrm{i}}\text{I}{}^{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{(1+I}{}^{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{)+b}{}_{\mathrm{i}}\text{I}$

where K₁ is the ionization constant in pure water, α_i and b_i are parameters of which b_i has been adjusted to present data. The following results were obtained (α_i, b_i): pK₁ = 9.84, (1.022, ?0.11); pK₂ = 13.43, (2.044, ?0.20); and pK_w = 14.01 (1.022, ?0.22). k_i values are collected in Tables I and II. Attempts have been made to explain the medium dependence of k₁ and k₂ with weak sodium silicate complexing according to the equilibria

$\text{Na}{}^{\mathrm{+}}\text{+}\text{SiO(OH)}{}^{\mathrm{?}}{}_3\text{?}\text{NaSiO(OH)}{}_3\text{;k}{}_{11}$

$\text{Na}{}^{\mathrm{+}}\text{+}\text{SiO}{}_2\text{(OH)}{}^2{}_2\text{?}\text{NaSiO}{}_2\text{(HO)}{}^{\mathrm{?}}{}_2\text{; k}{}_{21}$

giving k₁₁ = 0.37M^?1 and k₂₁= 3.0M^?1. However, these weak interactions cannot be interpreted unambiguously from potentiometric data at different 1-levels. Probably the medium dependence could equally well be expressed by variations in the activity coefficients.The measurements were performed as potentiometric titrations using a hydrogen electrode. The average number of OH^- reacted per Si(OH)₄, Z, has been varied within the limits 0 ? Z ? 1.1 and B₁, the total concentration of Si(OH)₄, between 0.001 M and 0.008 M. k₁ was evaluated from experimental data with B ? 0.003 M, and k₂ with B ? 0.008 M and Z ? 0.95.