Determination of the concentration of potassium chloride solution having the same electrical conductivity, at 15°C and infinite frequency, as standard seawater of salinity 35.0000 ‰ (Chlorinity 19.37394 ‰)

The absolute electrical conductivity at15degC of several lots of standard seawater has been measured with great precision as a function of chlorinity. Potassium chloride (KCI) solutions of known concentration and having almost the same conductivity were also measured and the concentration giving the same conductivity at15degC as35.0000permilstandard seawater (Chl =19.37394permil) was found to be 32.4352 g/kg.     

The effect of concentration and temperature on the conductivity ratio of potassium chloride solutions to standard seawater of salinity 35 ‰(Cl 19.3740 ‰)

The ratiosZ_{K,t}of electrical conductivities of potassium chloride (KCI) solutions of known concentration (K) to standard seawater at the same temperature have been measured at15degC and24degC for solutions withZ_{k,15}between 0.96 and 1.04. The "normal" concentration (N or K_{N}) givingZ_{N,15}= 1was found to beK_{N} = 32.4356gKCI/kg solution. The effect of temperature onZ_{N,t}was measured over the range15degC to30degC. Equations are given for KCI concentration as a function ofZ_{15}and the inverse function, forZ_{15}/Z_{24}as a function ofZ_{24}(to allow use of a laboratory salinometer for the KCI-seawater comparisons), andZ_{N,t}as a function of temperature.     

The electrical conductivity of weight diluted and concentrated standard seawater as a function of salinity and temperature

The ratiosR_{s,t,o}of electrical conductivity of seawater samples of precisely known salinity to standard seawater at the same temperature have been measured over a wide range of salinities from 0 to42permilS and over the full range of oceanic temperatures from -2 to35degC. The samples withS<35permilwere prepared by accurate weight dilution of standard seawater with distilled water. High salinity samples were prepared by fast evaporation of standard seawater and subsequent weight dilution into the already determined <35permilrange. An equation was derived which expresses the S versusR_{s,t,o}relationship very precisely from1-42permiland at all temperatures, i.e.,S = f_{1}(R_{s,t,o}) + f_{2}(R_{s, t,o},t) =Sigma_{n=0}^{5} a_{n}R^{n/2}+ frac{Delta t}{1+kDelta t} Sigma_{n=0}^{5} b_{n}R^{n/2}whereDelta t = t-15degC,R = R_{s, t.o}; only the first termf_{1}is required at15degC. The effeet of temperature on the electrical conductivity of standard seawater was also measured. The ratior_{t}of the conductivity at temperaturetto the conductivity at15degC (C_{35,t, o}/C_{35,15,o}) is very aeenrately expressed by a fourth degree equation int. i.e,r_{t}=Sigma_{n=0}^{4} c_{n}t^{n}These two equations are sufficient for all salinity determinations at normal atmospheric pressure.     

Conductivity/salinity/temperature relationship of diluted and concentrated standard seawater

The conductivity ratio of diluted and concentrated standard seawater has been measured very accurately in a salinity range from 0 to42permiland at temperature from -1 to30degC. All the data have been fitted into polynomials which are compared with previous data. The specific conductance of seawater is deduced and a polynomial for the full range of salinity and temperature is proposed. Data presented in this paper have been used, with those of Dauphinee presented in this issue, to elaborate the new "Practical Salinity Scale 1978."     

The practical salinity scale 1978 and its antecedents

The history of the definition of salinity and the methods of computing It are traced from the beginning of the twentieth century until the present. Difficulties that have arisen in existing practices are discussed, in particular, the situation regarding reduction of in-situ CTD observations. The Practical Salinity Scale 1978 is an attempt to remove the shortcomings; it has been recommended for international acceptance. The basis for this new scale is an equation relating the ratio of the electrical conductivity of the seawater sample to that of a standard potassium chloride solution (KCI) at15degC atmospheric pressure. The samples used were prepared from standard seawater diluted with distilled water or evaporated by weight. Finally, the set of new equations for CTD data reduction is given, based upon the work of authors whose papers are appearing elsewhere in this volume.     

The Practical Salinity Scale 1978: Fitting the data

Three equations have been fitted to new data relating the electrical conductivity of seawater to the Practical Salinity Scale 1978. These equations have been designed for the reduction of in-situ measurements of temperature, pressure, and conductivity from anywhere in the world oceans. The standard deviation of the fit is roughly equivalent topm0.0015permilin salinity depending on the pressure at which the data is taken and, as such is commensurate with the best accuracy attainable with modern instruments.     

A versatile sonar system for ocean research and fisheries applications

An echo sounder has been developed with features ideally suited to oceanographic and fisheries research. Instruments commonly used for such research are inaccurate, limited in dynamic range, unstable, and generally inflexible. An effort has been made to overcome these deficiencies with the sonar system discussed here. The echo sounder to be described has a time-varied-gain receiver (20 log_{10} Ror40 log_{10} R + 2alphaR) accurate to withinpm0.5dB over a 100-dB range. The equivalent dynamic range is 140 dB (the ratio of the maximum signal at minimum gain to the equivalent input noise at maximum gain in a 4-kHz bandwidth). The temperature stability ispm0.5dB from10degto35degC at any range. Operating parameters, including frequency, can be easily altered to accommodate a variety of needs.     

Deep ocean temperature profile measurements

Temperature is one of the most frequently measured parameters of the ocean because of its importance to the understanding and prediction of oceanic and meteorological events, and also because the measurement is required for the determination of salinity and density. The ocean temperature range is narrow,-2degto35degC, but measurement is complicated by the harsh ocean environment, the necessity of remote hands off readings, power limitations due to the cable, and the fast response required to obtain a profile in a reasonable length of time. Platinum and copper thermometers are used for most precision measurements with thermistors or thermocouples used in some cases to improve speed of response and for lesser accuracy. A number of very different circuits have been used successfully in salinity, temperature, and depth profiling systems and achieve millidegree accuracies in laboratory measurements. However, very careful precautions and many checks are required to achieve that accuracy in the field, and to achieve the correlation of conductivity, pressure, and temperature readings required for equivalent accuracy in the salinity and density measurements.     

A thermometer for oceanographic research with a time constant of about 1 ms and a resolution of less than 0.001 K: Its properties and results of its application on cruises

The author has developed a new thermometer with a time constant of about 0.5 ms as a part of his two-phase alternating current bridge. The thermometer permits the application of a Pt-wire with a low resistance of about 10-50 mOmega. A resolution of less than 0.001 K in the range of40degC can be reached. Properties, experiments, and results from measurements with this fast thermometer are described.     

In situ vane system for seafloor strength investigations

The In Situ Vane (ISV) system has been developed to determine the strength profile within the upper 1.5 m of deep sea clays. The system is designed to operate in 6000-m water depth after one-year dormancy on the bottom and consists of four integrated packages; controller and data acquisition system, mechanical system, volume compensator, and power supply. This paper describes development of a prototype which was used under a pressure of 550 bars after a 30-day dormancy and of the full system which was successfully used in a deep water (5800 m) test. In the first full application of the system the ISV will be used to measure changes in sediment strength caused by high temperature (300degC) as part of the U.S. Subseabed Disposal Program.     

Aircraft measurement of sea surface temperature during the West Coast Experiment

During the West Coast Experiment in March 1977, a test was conducted to ascertain the effectiveness of using remote sensing techniques to estimate sea surface temperature (SST) from infrared (IR) emissions of the sea surface. Aircraft flights were made over three buoys moored in southern California coastal waters, and data was collected of sea surface emissions at thermal IR wavelengths (7.95-13.5 mum). SST obtained from the remote sensing measurements were compared with in situ SST measured with thermistors mounted on the buoys. The remotely determined SST were from1.4-2.9degC lower than the in situ measurements. Several factors are discussed that could account for the differences.     

Inconsistency in the conductivity of standard potassium chloride solutions made from different high-quality reagents

The salinity of seawater has been defined in terms of the ratio of its electrical conductivity to that of a standard potassium chloride solution. The potassium chloride solution is obtained by dissolution of high-purity potassium chloride in ultrapure water. However, even high-purity potassium chloride is not 100% pure, and suppliers do not certify it, as the standard for electrical conductivity. We prepared defined solutions using several kinds of high-purity potassium chloride and examined the difference between the measured electrical conductivity ratio and the value calculated from the experimental equation given in the UNESCO background papers. The differences between the electrical conductivity ratios of the solutions made from the various potassium chloride reagents were equivalent to about 0.0012 in salinity. The solution may not actually become a standard for salinity measurements even if it is prepared exactly according to the present definition. The lot dependency of the electrical conductivity ratio of the potassium chloride solutions may result in a systematic error in the measurement of salinity.     

Effect of a snow cover on microwave backscatter from sea ice

The effect of a snow cover on sea ice upon radar backscatter at microwave frequencies (X- andKu-baud) can be important. The effect of scattering from the snow cover on thesigmadegof first-year ice is shown to be severe (5 cm of dry snow can raisesigmadegby 8 dB at 9 GHz), while that onsigmadegof multiyear ice is shown to be smaller. The low thermal conductivity of snow compared to that of sea ice effectively raises the temperature of the upper surface of the ice, resulting in higher dielectric constants for the ice, thereby modifying the backscatter both from the ice surface and from the scattering volume. The temperature effect of a 10-cm snow cover on 3-m-thick multiyear ice is to lower thesigmadegby only about 0.3 dB for air temperature of-20degC. The effect on 1-m-thick first-year ice is even less. Hence, the volume-scattering effect of snow is more important than the temperature effect. The presence of a wet snow cover can block the volume-scattering contribution of the multiyear ice. The effect of wet snow cover on first-year ice should be smaller than that Of dry, snow, becausesigmadegof wet snow is lower than that of dry snow.     

Density of standard seawater solutions at atmospheric pressure

Abstract

This paper gives the results of the density of diluted and concentrated standard seawater which has been measured in a salinity range from 0 to 42 and a temperature from 0 to 30°C. Equations for density of standard seawater (S = 35) vs the temperature and for density of standard seawater solutions vs the temperature and salinity have been fitted.     

A low-power hypsometer-type barometer for remote weather stations

The paper describes a low-power barometer intended for remote weather stations, but also meeting the requirements for manned stations and airports, in which the condensation temperature of carbon disulphide (CS2) is used to determine the barometric pressure(p). A heated cylindrical bulb with a re-entrant well for a thermistor through the bottom and an internal radiation shield is 1/3 filled with CS2. Helical springs assist CS2migration on wetted surfaces and allow liquid and vapor to pass one another in the small diameter exit-condenser tube. A miniature Dewar flask gives thermal insulation and a 0.01-mm beryllium-copper diaphragm transmits the external pressure. The condensation temperature is read with a simple Wheatstone bridge and dc amplifier giving an outputV_{0} = 0.5(p- 100 Pa)V. Pulsed power with the pulse length controlled by a second thermistor on the outlet tube is used for efficiency. Long term tests of a number of barometers have given power levels around 40 mW at20degC and indicated maximum drifts ofpm50Pa/year,pml0Pa/day, andpm2Pa short term.     

海水中钾的测定——交流示波极谱滴定在海水分析中的应用(Ⅰ)

研究用交流示波极谱测定海水中钾的方法。海水试样用NaOH调节pH约12,加入过量四苯硼化钠标准溶液,用微孔滤膜(或滤纸)过滤沉淀。收集游液,用TI(Ⅰ)标准溶液滴定过量的四苯基硼离子。方法回收率为99.5％。测定结果与四苯硼化钾重量法结果一致。海水中共存离子不干扰测定,并可用于海水及多种盐溶液中钾的测定。本法因其简便、快速、准确而易于推广。     

Aircraft measurements of the microwave scattering signature of the ocean

Microwave scattering signatures of the ocean have been measured over a range of surface wind speeds from 3 m/s to 23.6 m/s using the AAFE RADSCAT scatterometer in an aircraft. Normalized scattering coefficients are presented for vertical and horizontal polarizations as a function of incidence angle (nadir to55deg) and radar azimuth angle (0degto360deg) relative to surface wind direction. For a given radar polarization, incidence angle, and azimuth angle relative to the wind direction, these scattering data exhibit a power law dependence on surface wind speed. The relation of the scattering coefficient to azimuth angle obtained during aircraft circles (antenna conical scans) is anisotropic and suggests that microwave scatterometers can be used to infer both wind speed and direction. These results have been used for the design of the Seasat-A Satellite Scatterometer (SASS) to be flown in 1978 on this first NASA oceanographic satellite.     

中国系列标准海水制备与质量评价

中国系列标准海水是国家二级标准物质 [GBW (E) 130 0 11],在盐度或电导率传感器的现场检定 ,实验室盐度计的检定和校准中应用广泛。主要介绍中国系列标准海水的制备和不确定度分析。     

Four years of low-altitude sea ice broad-band backscatter measurements

The ability to use radar to discriminate Arctic Sea ice types has been investigated using surface-based and helicopter-borne scatterometer systems. The surface-based FM/CW radar operated at 1.5 GHz and at multiple frequencies in the 8-18-GHz region. Measurements were made at angles of10degto70degfrom nadir. The helicopter-based radar operated at the 8-18-GHz frequencies with incidence angles of0degto60deg. Extensive surface-truth measurements were made at or near the time of backscattar measurement to describe the physical and electrical properties of the polar scene. Measurements in the 8-18-GHz region verify the ability to discriminate multiyear, thick first-year, thin first-year, and pressure-ridged sea ice and lake ice. The lowest frequency, 9 GHz, was found to provide the greatest contrast between these ice categories, with significant levels of separation existing between angles from15degto70deg. The radar cross sections for like antenna polarizations, VV and HH, were very similar in absolute level and angular response. Cross-polarization, VH and HV, provided the greatest contrast between ice types, The 1.5-GHz measurements showed that thick first-year, thin first-year, and multiyear sea ice cannot be distinguished at10degto60degincidence angles with like polarization, VV, by backscatter alone; but that undeformed sea ice can be discriminated from pressure-ridged ice and lake ice. The effect of snow cover on the backscatter from thick first-year ice was also investigated. It contributes on the order of 0 to 4 dB, depending on frequency and incidence angle; the contribution of the snow layer increased with increasing frequency. Snow cover on smooth lake ice was found to be a major backscatter mechanism. Summer measurements demonstrate the inability to extend the knowledge of the backscatter from sea ice under spring conditions to all seasons.     

我国氨氮海水质量基准的探讨

我国现行的氨氮海水质量标准参照国外基准与标准制定,未考虑是否能够有效保护中国海洋物种,科学性欠缺。对我国海水氨氮质量基准进行研究,采用美国EPA推荐的物种敏感度排序(SSR)技术,结合美国海水氨氮水质基准数学模型,搜集利用我国15种海水水生生物的非离子氨毒性数据,根据非离子氨氮和总氨氮转换公式,得出水体在不同pH值、温度和盐度条件下的总氨氮水质基准在pH为7.0~9.0、温度为0~30℃的范围内,盐度为10时,基准最大浓度(CMC)和基准连续浓度(CCC)的范围分别为0.089~57.141 mg/L与0.007~4.365 mg/L;盐度为20时,CMC和CCC的范围分别为0.092~61.152 mg/L与0.007~4.671 mg/L;盐度为30时,CMC和CCC的范围分别为0.095~65.446 mg/L与0.007~4.999 mg/L;3个环境因子,对CCC和CMC的影响程度由大到小依次为:pH、温度、盐度。相对于美国,我国急性基准的取值区间收缩了5倍,慢性基准的取值区间收缩了10倍。研究结果认为,现行的非离子氨数值应修正为0.007 mg/L才能有效保护我国海洋生物,同时建议使用总氨氮的基准来管理海水中氨氮变化。为修订我国氨氮海水质量标准提供了科学依据。