Temporal and spatial variations of <Emphasis Type="Italic">δ</Emphasis><Superscript>15</Superscript>N and <Emphasis Type="Italic">δ</Emphasis><Superscript>18</Superscript>O for atmospheric N<Subscript>2</Subscript>O above the oceanic surface from Shanghai to Antarctica

During the 22nd Chinese Antarctic Research Expedition (CHINARE-22), the atmospheric gas samples above the oceanic surface and near the surface were collected on the track for the scientific ship “Xuelong” and on Millor Peninsula of eastern Antarctica, respectively, using the Tedlar gas bags. Every day the sampling times were 10:00 and 22:00 (local time), respectively. In the laboratory, high-precision measurement of the isotopic compositions for N₂O in these gas samples was conducted using Thermo Finnigan MAT-253 Isotopic Mass Spectrometer with a fully automated interface for the pre-GC concentration (PreCon) of trace gases. The temporal and spatial variations of δ ¹⁵N and δ ¹⁸O in atmospheric N₂O were analyzed. The mean δ ¹⁵N and δ ¹⁸O-N₂O values above the oceanic surface were (7.21±0.50)‰ and (44.52±0.52)‰, respectively. From 30°N to Antarctica, the δ ¹⁵N (6.05‰–7.88‰) linearly increased with the rate of about 0.01‰ with the latitude while the δ ¹⁸O (43.05‰–48.78‰) showed a large fluctuation. The δ ¹⁵N negatively correlated with air temperature and N₂O concentration, and slightly positively correlated with δ ¹⁸O. The summertime variations of δ ¹⁵N and δ ¹⁸O-N₂O appeared the same trend on Millor Peninsula of eastern Antarctica. They significantly positively correlated with each other and negatively with N₂O concentration. The δ ¹⁵N and δ ¹⁸O-N₂O at different sites averaged (7.42±0.35)‰ and (44.69±0.49)‰, respectively, slightly higher than those above the oceanic surface, significantly higher than those of atmospheric N₂O in the low-latitude regions of Northern Hemisphere. The predominant factors affecting the spatial variations of δ ¹⁵N and δ ¹⁸O values were also discussed. The isotopic data given in this study can help to investigate the global and regional N₂O budgets. Supported by the National Natural Science Foundation of China (Grant Nos. 40676005 and 40406001)     

Characteristics and quantitative of negative ion in salt aqueous solution by Raman spectroscopy at ?170°C

The results from Raman spectroscopy analysis of salt aqueous solutions at −170°C demonstrate that for those clearly sharp iron peaks whose Raman wavenumber is close to each other such as NO ₃ ⁻ and CO ₃ ²⁻ , their original shape could be restorable by the stripping technique, and that ice’s sharp characteristic peak 3090–3109 cm⁻¹) is steady, while the spectrum band of the complex compound (nCl⁻-[H⁺-OH⁻]_n) chlorine ion combined chemically with water molecule is 3401–3413 cm⁻¹. On the other hand, the research shows that the higher the negative iron concentration, the stronger its Raman characteristic peak intensity and the smaller the ice’s. Based on the number of data and theoretical work, the strong correlation of the molar concentration of negative ion with the S _i/S _{H 2}O band area ratio is built up. Moreover, the developed Raman method is successfully used in the component analysis of the field fluid inclusions from Silurian sandstone in Tarim basin.     

Interrelation between fault zone structures and earthquake processes

In order to develop capabilities for predicting earthquake processes on the basis of known fault zone structures and stress conditions, we need to find relations between seismogenic structures and processes. In the present paper we search for the scale dependence in various earthquake phenomena with the hope to find some structures in the earth that may control the earthquake processes. Among these phenomena, we shall focus on (1) geologic structures which play some role in nucleation and stopping of earthquake fault rupture, (2) depth ranges of the brittle seismogenic zone, (3) asperities and barriers distributed over a fault plane, (4) source-controlledf _max effect, (5) nonfractal behavior of creep events, and (6) temporal correlation between codaQ ^–1 and seismicity of earthquakes with magnitude characteristic to a given area. Our review of various scale-dependent phenomena leads us to propose a working hypothesis that the temporal change in codaQ ^–1 may reflect the activity of creep fractures near the brittle-ductile transition zone.     

Temporal variations of <Emphasis Type="Italic">δ</Emphasis><Superscript>18</Superscript>O of atmospheric water vapor at Delingha

Oxygen stable isotope of atmospheric water vapor is widely used to study the modern process of climate. Atmospheric water vapor samples were collected at Dlingha, northeast of Tibetan Plateau during the period from July 2005 to February 2006. The variation of δ ¹⁸O and the relationships between δ ¹⁸O and both the temperature and specific humidity are analyzed in this paper. Results show that the seasonal variation of δ ¹⁸O of atmospheric water vapor at Delingha is remarkable with higher δ ¹⁸O in summer and lower δ ¹⁸O in winter. The temporal variation of vapor δ ¹⁸O shows obvious fluctuations, with magnitude of over 37‰ The daily variation of the δ ¹⁸O is highly correlated with air temperature. The relationship between δ ¹⁸O and atmospheric water vapor content is complex. Study shows that δ ¹⁸O of atmospheric water vapor is positively correlated with specific humidity in winter in seasonal scale and inversely correlated with specific humidity in summer rainy period. The δ ¹⁸O values of atmospheric water vapor are lower than those of precipitation at Delingha, and the average difference is 10.7‰ Variations of δ ¹⁸O of atmospheric water vapor is also found to be affected by precipitation events, The model results show that the precipitation effect could have caused the vapor δ ¹⁸O in the raining season to lower by 7% in average in July and August. Supported by the National Natural Science Foundation of China (Grant Nos. 40671043, 40571039 and 40771048) and National Basic Research Program of China (Grant No. 2005CB422002)     

Variations of <Emphasis Type="Italic">δ</Emphasis><Superscript>18</Superscript>O in precipitation from the Muztagata Glacier,East Pamirs

Expeditions to Muztagata (in the eastern Pamirs) during the summer seasons of 2002 and 2003 collected precipitation samples and measured their oxygen isotopes. The δ ¹⁸O in precipitation displays a wide range, varying from −17.40‰ to +1.33‰ in June-September 2002 and from −22.31‰ to +4.59‰ in May-August 2003. The δ ¹⁸O in precipitation correlates with the initial temperature of precipitation during the observing periods. The positive correlation between δ ¹⁸O and temperature suggests that δ ¹⁸O can be used as an indicator of temperature in this region. The δ ¹⁸O values in fresh-snow samples collected from two snow events at different elevations on the Muztagata Glacier show a strong “altitude effect”, with a ratio of nearly −0.40% per 100 m from 5500 m to 7450 m.     

Unified approach to amplitude attenuation and coda excitation in the randomly inhomogeneous lithosphere

A unified model is proposed for explaining the frequency dependent amplitude attenuation and the coda wave excitation on the basis of the single scattering process in the randomly inhomogeneous lithosphere. Adopting Birch's law and a direct proportion between density and wave velocity, we statistically describe the inhomogeneous medium by one random function characterized by the von Karman autocorrelation function. We calculate the amplitude attenuation from the solid angle integral of scattered wave energy on the basis of the Born approxiimation after subtracting the travel-time fluctuation effect caused by slowly varying velocity inhomogeneities. This subtraction is equivalent to neglect energy loss by scattering within a cone around the forward direction. The random inhomogeneity of the von Karman autocorrelation function of order 0.35 with the mean square fractional fluctuation of 7.2×10^–3 1.3×10^–2 and the correlation distance of 2.15.1 km well explains observed backward scattering coefficientg and the ratioQ _P ^–1 /Q _S ^–1 , and observed and partially conjecturedQ _S ^–1 for frequencies between 0.5 Hz and 30 Hz.     

Relationships between δ18O in summer precipitation and temperature and moisture trajectories at Muztagata, western China

Based on summer observations of stable isotope of precipitation at Muztagata, western China, during 2002-2003, this paper presents the relationship between δ ¹⁸O in precipitation and air temperature, and discusses the effect of moisture transport on δ ¹⁸O in precipitation. Results show that air temperature correlates positively with δ ¹⁸O in precipitation, and the temperature effect controls the δ ¹⁸O of precipitation in this area. The Muztagata region exhibits high δ ¹⁸O values in summer precipitation, similar to those shown at stations in adjacent regions. According to the results of our model set up to trace the moisture trajectories, the westerlies and local moisture circulation contribute to variations of oxygen isotopes in precipitation. In addition, the impacts of the moisture transport distance, the moisture transport level, and the incursion of the polar air mass also influence the variations of δ ¹⁸O in precipitation. The moisture origins and transport mechanisms also contribute to the variation of δ ¹⁸O in precipitation at Muztagata.     

Coda wave attenuation in the Parecis Basin,Amazon Craton,Brazil: sensitivity to basement depth

Small local earthquakes from two aftershock sequences in Porto dos Gaúchos, Amazon craton—Brazil, were used to estimate the coda wave attenuation in the frequency band of 1 to 24 Hz. The time-domain coda-decay method of a single backscattering model is employed to estimate frequency dependence of the quality factor (Q _c) of coda waves modeled using Q_c = Q₀ f^hQ_{\rm c} =Q_{\rm 0} f^\eta , where Q ₀ is the coda quality factor at frequency of 1 Hz and η is the frequency parameter. We also used the independent frequency model approach (Morozov, Geophys J Int, 175:239–252, 2008), based in the temporal attenuation coefficient, χ(f) instead of Q(f), given by the equation c(f)=g+\fracpfQ_e \chi (f)\!=\!\gamma \!+\!\frac{\pi f}{Q_{\rm e} }, for the calculation of the geometrical attenuation (γ) and effective attenuation (Q_e^-1 )(Q_{\rm e}^{-1} ). Q _c values have been computed at central frequencies (and band) of 1.5 (1–2), 3.0 (2–4), 6.0 (4–8), 9.0 (6–12), 12 (8–16), and 18 (12–24) Hz for five different datasets selected according to the geotectonic environment as well as the ability to sample shallow or deeper structures, particularly the sediments of the Parecis basin and the crystalline basement of the Amazon craton. For the Parecis basin Q_c = (98±12)f^(1.14±0.08)Q_{\rm c} =(98\pm 12)f^{(1.14\pm 0.08)}, for the surrounding shield Q_c = (167±46)f^(1.03±0.04)Q_{\rm c} =(167\pm 46)f^{(1.03\pm 0.04)}, and for the whole region of Porto dos Gaúchos Q_c = (99±19)f^(1.17±0.02)Q_{\rm c} =(99\pm 19)f^{(1.17\pm 0.02)}. Using the independent frequency model, we found: for the cratonic zone, γ = 0.014 s^− 1, Q_e^-1 = 0.0001Q_{\rm e}^{-1} =0.0001, ν ≈ 1.12; for the basin zone with sediments of ~500 m, γ = 0.031 s^− 1, Q_e^-1 = 0.0003Q_{\rm e}^{-1} =0.0003, ν ≈ 1.27; and for the Parecis basin with sediments of ~1,000 m, γ = 0.047 s^− 1, Q_e^-1 = 0.0005Q_{\rm e}^{-1} =0.0005, ν ≈ 1.42. Analysis of the attenuation factor (Q _c) for different values of the geometrical spreading parameter (ν) indicated that an increase of ν generally causes an increase in Q _c, both in the basin as well as in the craton. But the differences in the attenuation between different geological environments are maintained for different models of geometrical spreading. It was shown that the energy of coda waves is attenuated more strongly in the sediments, Q_c = (78±23)f^(1.17±0.14)Q_{\rm c} =(78\pm 23)f^{(1.17\pm 0.14)} (in the deepest part of the basin), than in the basement, Q_c = (167±46)f^(1.03±0.04)Q_{\rm c} =(167\pm 46)f^{(1.03\pm 0.04)} (in the craton). Thus, the coda wave analysis can contribute to studies of geological structures in the upper crust, as the average coda quality factor is dependent on the thickness of sedimentary layer.     

New production in the South China Sea

Measurement of²²⁸Ra activities in the upper 300 m water column was conducted at two stations in the South China Sea using an MnO₂-fiber extraction/β-counting technique of²²⁸Ac. Results showed that²²⁸Ra activities ranged from 0.38 to 3.60 Bq · m^-3. The vertical profiles of²²⁸Ra at the time-series station favored a steady state assumption. Based on a one-dimensional steady state model,²²⁸Ra-nitrate coupled approach was applied to stations NS97-43, NS99-53 (T₁), NS99-53 (T₂). New production thus quantified were 4.4, 5.1 and 5.7 mmolC · m^-2 · d^-1, respectively,f ratios in the South China Sea were estimated from the derived new production and the documented primary productivity in the regime, to be 0.12–0.15.     

Temporal and spatial variation on codaQ −1 associated with the North Palm Springs earthquake of July 8, 1986

A temporal and spatial change of codaQ ^–1 associated with the occurrence of the North Palm Springs earthquake of July 8, 1986 was studied by using 242 small local earthquakes in the vicinity of the mainshock. We found that the codaQ ^–1 of earthquakes which occurred before the mainshock was significantly higher than that of the aftershocks in the mainshock area while the codaQ ^–1 for the surrounding area remained almost constant throughout 1986. CodaQ ^–1 was determined separately for the lapse time windows of 10 to 20 sec. and 15 to 40 sec. for the period from 1981 to 1987. The result for the time window 10 to 20 sec. showed a peak in codaQ ^–1 before the time of mainshock at all frequencies. The peak appeared earlier at lower frequencies. There was no significant change in codaQ ^–1 for the time window 15 to 40 sec., probably because the change was restricted to a small area.     

Coda Q in the Kachchh Basin, Western India Using Aftershocks of the Bhuj Earthquake of January 26, 2001

Q_C-estimates of Kachchh Basin in western India have been obtained in a high frequency range from 1.5 to 24.0 Hz using the aftershock data of Bhuj earthquake of January 26, 2001 recorded within an epicentral distance of 80 km. The decay of coda waves of 30 sec window from 186 seismograms has been analysed in four lapse time windows, adopting the single backscattering model. The study shows that Q_c is a function of frequency and increases as frequency increases. The frequency dependent Q_c relations obtained for four lapse-time windows are: Q_c=82 f^1.17 (20–50 sec), Q_c=106 f^1.11 (30–60 sec), Q_c=126f^1.03 (40–70 sec) and Q_c=122f^1.02 (50–80 sec). These empirical relations represent the average attenuation properties of a zone covering the surface area of about 11,000, 20,000, 28,000 and 38,000 square km and a depth extent of about 60, 80, 95, 110 km, respectively. With increasing window length, the degree of frequency dependence, n, decreases marginally from 1.17 to 1.02, whereas Q₀ increases significantly from 82 to 122. At lower frequencies up to 6 Hz, Q_c⁻¹ of Kachchh Basin is in agreement with other regions of the world, whereas at higher frequencies from 12 to 24 Hz it is found to be low.     

Statistical features of the seismic noise-field

We present a preliminary study of the dependence of the statistical features of the soil motion due to seismic noise on the near-surface geology in the frequency range from 1 Hz to ∼ 40 Hz. In detail, we have investigated the 3D average squared soil displacement 〈r²〉 and the distribution function of the displacement flctuations at different geological sites. The anomalous scaling of the average squared soil displacement 〈r²(τ)〉~τ_α, and the Gaussian shape of the probability distribution function of its fluctuations suggest that the soil motion under the influence of the seismic noise is consistent with a persistent fractional Brownian motion (fBm) characterized by a scaling exponent 1.5 < α < 2. Therefore, the seismic noise-field, thought as a stochastic process, shows a markovian character with a memory longer than a pure Brownian motion (α = 1/2). Moreover, a dependence of such persistent behavior of the noise-field dynamics on the near-surface local geology has been found and it is discussed.     

过量Zn2+对水花生(Alternanthera philoxeroides)愈伤组织氧化胁迫及多胺代谢的影响

以植物组织培养技术培养的水花生愈伤组织为实验材料,研究了过量Zn2+(0、0.2、0.4、0.8、1.6 mmol/L)对水花生愈伤组织的氧化损伤及多胺代谢的影响.结果表明,随着Zn2+浓度增加:(1)水花生愈伤组织的超氧阴离子产生速率和硫代巴比妥酸反应物水平显著提升,超氧化物歧化酶活性明显抑制,叶绿素a含量显著降低;(2)精氨酸脱羧酶和鸟氨酸脱羧酶活性均升高,多胺氧化酶和二胺氧化酶活性在低Zn2+浓度处升高、高Zn2+浓度处降低;(3)总腐胺和总精胺含量在低Zn2+浓度处降低、高Zn2+浓度处增加,总亚精胺含量仅在Zn2+浓度为1.6 mmol/L时有显著增加;(4)游离态腐胺含量变化与总腐胺含量相似,游离态亚精胺含量在高Zn2+浓度时下降,游离态精胺含量仅在Zn2+浓度为0.2 mmol/L时略有下降;(5)结合态腐胺和精胺在Zn2+浓度为0.2 mmol/L时下降而在其余处理组中上升,结合态亚精胺含量各处理组中均增加;(6)束缚态腐胺和亚精胺含量均下降.可见,过量Zn2+胁迫导致水花生愈伤组织氧化性损伤,并扰乱其多胺代谢平衡;束缚态多胺向结合态多胺的转化是过量Zn2+胁迫下水花生愈伤组织多胺代谢变化的一个显著特征;以结合态为代表的内源性多胺积累对水花生愈伤组织抵抗过量Zn2+胁迫具有重要意义.     

Distribution of ionospheric O<Superscript>+</Superscript> ion in synchronous altitude region

Based on satellite observation data, using dynamics equation, the ionospheric O⁺ ion’s distribution in the synchronous altitude region for different geomagnetic activity indexK _p is studied by theoretical modeling and numerical analyzing, and semi-empirical models for the O⁺ ion’s density and flux versus longitude in the synchronous altitude region for differentK _p are given. The main results show that in the synchronous altitude region: (i) The O⁺ ion’s density and flux in day-side are larger than those in nightside. (ii) With longitude changing, the higher the geomagnetic activity indexK _p is, the higher the O⁺ ion’s density and flux, and their variation amplitude will be. The O⁺ ion’s density and flux whenK _{p ≥} 6 will be about ten times as great as that whenK _p = 0. (iii) WhenK _p = 0 orK _{p ≥} 6, the O⁺ ion’s density reaches maximum at longitudes 120° and 240° respectively, and minimum in the magnetotail. WhenK _p = 3−5, the O⁺ ion’s density gets to maximum at longitude 0°, and minimum in the magnetotail. However, the O⁺ ion’s flux reaches maximum at longitude 120° and 240° respectively, and minimum in the magnetotail for anyK _p value.     

不同水体营养盐浓度下沉积物添加镧改性膨润土(Phoslock®)对轮叶黑藻(Hydrilla verticillata)生长的影响

轮叶黑藻(Hydrilla verticillata)是我国浅水湖泊常见的沉水植物,经常用于湖泊生态修复工程.然而在生态修复中后期,轮叶黑藻又往往会过度繁殖,影响其他湖泊功能的发挥.镧改性膨润土(锁磷剂)可以有效地降低沉积物中生物可利用磷含量,近年来被用于控制湖泊沉积物磷释放,其对轮叶黑藻生长和形态的影响还有待阐明.本研究在2种不同上覆水营养盐浓度条件下,设置添加和不添加锁磷剂2种处理,探究沉积物添加锁磷剂对轮叶黑藻生长及形态特征的影响.结果表明:1)沉积物添加锁磷剂之后,铁锰结合态磷、有机磷、铝结合态磷等生物可利用磷浓度显著降低,而生物不可用磷,如钙结合态磷浓度显著升高; 2)沉积物添加锁磷剂显著降低了轮叶黑藻的生物量和生长率.添加锁磷剂的处理组植物的株高、地上部分生物量均明显低于无锁磷剂组;相反,添加锁磷剂显著增加了植物的根长和地下部分生物量,进而提高了植物的根冠比; 3)锁磷剂对轮叶黑藻生长的影响程度与水体营养盐浓度有关,在低营养盐浓度水体中锁磷剂对植物生长和形态特征的影响更为显著.本研究表明,锁磷剂的添加能降低沉积物中生物可利用磷浓度,抑制轮叶黑藻的生长,同时这种影响程度与在水体营养盐浓度有关.     

Adsorption of Au(III) and Au(I) complexes on δ-MnO2

The sorption of AuCl₄ ⁻,AuCl₂ ⁻ and Au(S₂O₃)^3- on δ-MnO₂ was investigated at pH2–11.6, 0.01 mol/L and 0.1 mol/L NaNO₃ solutions. At pH 4 in two electrolyte strength solutions, Au sorption densities on δ-MnO₂ are 0.18–0.21 and 0.28μmoL/m² for AuCl₄ ⁻ and Au(S₂O₃)₂ ^3-, respectively, and the Au surface coverage is approximate to or lower than 1%. This adsorption of the two Au complexes decreases as the solution pH increases, which conforms to the sorption regularity of the anion on δ-MnO₂. The Au sorption decreases in the sequence of Au(S₂O₃)₂ ^3- >AuCl₄ ⁻ >AuC1₂ ⁻. The intrinsic equilibrium constants (logK ^int) of the three Au complexes are 1.17–2.7, much higher than those of Cu and Cd. The hydrolysis products of AuCl₄ ^- are preferentially adsorbed by δ-MnO₂ and the inner-sphere Au-surface complexes are formed on the surface. Project supported by the National Studying-abroad Foundation, the National Natural Science Foundation of China (Grant No. 49573200) and the Australian Mining Industry.     

Properties of electric turbulence in the polar cap ionosphere

Small-scale (scales of ∼0.5–256 km) electric fields in the polar cap ionosphere are studied on the basis of measurements of the Dynamics Explorer 2 (DE-2) low-altitude satellite with a polar orbit. Nineteen DE-2 passes through the high-latitude ionosphere from the morning side to the evening side are considered when the IMF z component was southward. A rather extensive polar cap, which could be identified using the ɛ-t spectrograms of precipitating particles with auroral energies, was formed during the analyzed events. It is shown that the logarithmic diagrams (LDs), constructed using the discrete wavelet transform of electric fields in the polar cap, are power law (μ ∼ s ^α). Here, μ is the variance of the detail coefficients of the signal discrete wavelet transform, s is the wavelet scale, and index α characterizes the LD slope. The probability density functions P(δE, s) of the electric field fluctuations δE observed on different scales s are non-Gaussian and have intensified wings. When the probability density functions are renormalized, that is constructed of δE/s ^γ, where γ is the scaling exponent, they lie near a single curve, which indicates that the studied fields are statistically self-similar. In spite of the fact that the amplitude of electric fluctuations in the polar cap is much smaller than in the auroral zone, the quantitative characteristics of field scaling in the two regions are similar. Two possible causes of the observed turbulent structure of the electric field in the polar cap are considered: (1) the structure is transferred from the solar wind, which is known to have turbulent properties, and (2) the structure is generated by convection velocity shears in the region of open magnetic field lines. The detected dependence of the characteristic distribution of turbulent electric fields over the polar cap region on IMF B _y and the correlation of the rms amplitudes of δE fluctuations with IMF B _z and the solar wind transfer function (B _y ² + B _z ²)^1/2sin(θ/2), where θ is the angle between the geomagnetic field and IMF reconnecting on the dayside magnetopause when IMF B _z < 0, together with the absence of dependence on the IMF variability are arguments for the second mechanism.     

Secular variations ing 1 0 component of geomagnetic field and its origin

The secular variations (SV) ing ₁ ⁰ of geomagnetic field, caused by the interaction between the geomagnetic field and the radial fluid-flow of the outer-core, are discussed with both statistical and analytic methods. When the value ofg ₁ ⁰ s ₂ ⁰ is relatively high compared with other terms, SV ing ₁ ⁰ is characterized by exponential change. When the effect of non-dipole field is notable, SV ing ₁ ⁰ shows complex features. Especially when the value of g ₁ ⁰ is close to zero, SV ing ₁ ⁰ is completely determined by the random process of non-dipole fields. Project supported by the National Natural Science Foundation of China (Grant No. 49429405) and by the Chinese Academy of Sciences.     

Cooling rates in the shock veins of chondrites: constraints on the (Mg, Fe)2SiO4 polymorph transformations

The occurrence of γ-phase, a high-pressure polymorph of olivine (α-phase), in the shock veins of Sixiangkou chondrite was due to a greater cooling rate (> 10 000°C·s^-1) in the veins. Because γ-phase partially reverted to β-phase and no back-transformation from β-phase to α-phase took place, the shock veins of Peace River chondrite with a cooling rate of 1 000–2 000δC·s^-1 contain a great amount of β-phase. In the shock veins of Mbale chondrite with a cooling rate of <500°C·s^-1, the majority of γ-phase reverted to α-phase. The heat dissipation in shock veins took place after a stage of shock compression of chondrite parent body, and the parent body was broken into fragmental pieces. Cooling rate in the shock veins constrained the back-transformations of (Mg, Fe)₂SiO₄ high-pressure polymorphs. Project of Chen and Xie supported by the National Natural Science Foundation of China (Grant No. 496720981, Natural Science Foundation of Guangdong Province (Grant No. 960500), and the Science Foundation of Academia Sinica for the returned scholars.     

Mercury contamination history of an estuarine floodplain reconstructed from a Pb-dated sediment core (Berg River, South Africa)

Mercury deposition histories have been scarcely documented in the southern hemisphere. A sediment core was collected from the ecologically important estuarine floodplain of the Berg River (South Africa). We establish the concentration of Hg in this ²¹⁰Pb-dated sediment core at <50 ng g⁻¹ Hg_T throughout the core, but with 1.3 ng g⁻¹ methylmercury in surface sediments. The ²¹⁰Pb dating of the core provides a first record of mercury deposition to the site and reveals the onset of enhanced mercury deposition in 1970. The ratio of methylmercury to total mercury is relatively high in these sediments when compared to other wetlands.