Discussing the Oil-Control Effects of the North Latitudinal 38° Belt in Central Part of the Ordos Basin

<正>The Ordos Basin in the western part of the North China Craton is commonly believed to be a multi-controlled oilbearing basin.It is bounded by the Xing’an-Mongolian Orogen to the north,the Qingling Orogen to the south,the Lüliang mountain to the east and the Helanshan-Liupanshan mountain belt to the west.The interpretation of geophysical data reveals a latitudinal(38°)fault belt in the centre of the Ordos Basin,which controls the hydrocarbon generation,migration and accumulation in the basin.This study attempts to     

Influence of hydrothermal-metasomatic processes on the formation of present-day sulfide ores in carbonate bottom sediments of the mid-Atlantic Ridge (19°–20° N)

Based on materials obtained in Cruises 33 and 34 of the R/V Professor Logachev, the paper addresses formation conditions, morphology, structures, mineral composition of the present-day oceanic sulfide ores, and their relationships with the host (biogenic carbonate) bottom sediments in the 19°–20° N MAR (Zenith-Victoria and Petersburg hydrothermal fields) region. The grain size distribution, mineral composition of the carbonate (background) and ore-hosting sediments, as well as physicochemical parameters of their interstitial waters, are examined. The results suggest a significant role of hydrothermal-metasomatic processes in the formation of ores and ore-bearing sediments. A model is proposed for the formation of sulfide mineralization in oceanic sediments at the geochemical barrier in the zone of their interaction with the acid hydrothermal (diffuse-type) ore-bearing solutions delivered from rocks of the ocean floor.     

The aqueous corrosion of potash-lime-silica glass in the range 10–250°C

It is difficult to measure accurately the natural long-term corrosion rates of highly durable nuclear waste glasses. Care should be taken when using data from high temperature experiments to predict corrosion rates under ambient repository conditions as there are many factors (such as the precipitation of secondary compounds, the chemistry of the water in contact with the glass, or circulation of this water through the repository) that can influence the temperature dependence of aqueous reactions. In this study, some standard leach tests using pure water, in continuous flow and direct sampling autoclaves, were performed on a synthetic medieval glass. Archaeological glass samples of a similar composition and which had suffered several centuries of corrosion in damp soil had been the subject of previous studies. The corrosion of the archaeological samples in damp soil was well understood and the aim was to determine how well standard leach tests would predict the observed corrosion.The experimentally measured long-term corrosion rates were not simply dependent on temperature, therefore they could not be used to predict either the corrosion rates or products found on the archaeological samples. In continuous flow experiments this was largely because the release of some cations (e.g. Mg²⁺) was proportional to the flow rates used, and so the long-term corrosion was dependent on both flow rate and temperature. In the autoclave experiments, concentrations of dissolved ions climbed rapidly in the small water volume, leading to the precipitation of complex mineral phase assemblages. The experiments did not reach silica saturation, therefore the long-term rates measured were a function of both the temperature and the extent of reaction. The initial release rates of silica and of the network modifying cations showed an Arrhenius temperature dependence with an activation energy of about 78.5 kJmol⁻¹. These results would have predicted the soil corrosion of the archaeological samples to within about 30%, i.e. the initial corrosion rate in pure water was similar to the long-term rate in damp soil. As an explanation of the experimental observations it is suggested that clay minerals in the soil consumed silica as the glass dissolved, maintaining under-saturated conditions and allowing corrosion at a rate similar to the initial rate in pure water.     

Thermodynamic properties of compounds in the PdO-H2O system at 25°C

Literature thermodynamic data on species and particles existing in the heterogeneous PdO-H₂O system were checked for consistency, and the equilibrium constants for dissolution of palladium oxide and hydroxide in water and for Pd²⁺ (aq) hydrolysis were recommended. Δ _f G _298.15 ^° obtained in this work for Pd²⁺(aq) sharply differs (no less than by 6 kJ/mol) from values that are reported in fundamental thermodynamic reference books and based on experimentally measured palladium electrode potential at 25°C. Detailed examination of literature data on the thermodynamic properties of compounds in the Cl-Pd(aq) system is required to account for revealed inconsistency.     

Formation of Water-Bearing Defects in Olivine in the Presence of Water–Hydrocarbon Fluid at 6.3 GPa and 1200°C

The main trends of water dissolution in Fe-bearing olivine have been investigated in the olivine–H₂O–hydrocarbon fluid system in experiments at a pressure of 6.3 GPa, a temperature of 1200°C, and hydrogen fugacity ( fH₂) buffered by the Mo–MoO₂ equilibrium. The content and contribution of ОH defects of different types in Fe-bearing olivines depend on the composition of reduced fluids in the system. As the fraction of hydrocarbons in the fluid increases, the H₂O content in olivine crystals decreases from 900 to 160–180 ppm, while the ОН absorption peaks become lower at high frequencies and occupy a larger part of the infrared spectrum in the low-frequency region. According to the experimental results, even the deepest seated mantle olivines with OH defects were not equilibrated with a fluid rich in light alkanes or oxygenated hydrocarbons.     

Paleoseismicity and seismic hazard in southern Patagonia (Argentina-Chile; 50°–55°S) and the role of the Magallanes-Fagnano transform fault

Patagonia, including the island of Tierra del Fuego, lies in southernmost South America at the junction of the South American, Antarctic, and Scotia tectonic plates. Historical and instrumental records have documented several local earthquakes of damaging magnitude, posing a threat to the rapidly growing population of 300,000 and the expanding industrial and service infrastructure. Short and inaccurate instrumental records of local seismic events and a diffuse epicenter distribution not clearly related to the recognized seismogenic structures have hindered an adequate evaluation of the seismic hazard for this region. To improve this situation, a paleoseismological study was carried out on two gravelly strandplains on the Atlantic coast of Patagonia. Surveying combined ground-probing radar, vertical electric sounding, and seismic refraction. Coseismic normal faults buried beneath the strandplain bodies were revealed and related to the morphology of the strandplains. The faults have probable ages between 0.9 and 6.4 kyr BP and a recurrence rate of about 1 kyr. The more likely source for these structures is the Magallanes-Fagnano fault, a continental transform fault that crosses Tierra del Fuego. The distance of more than 300 km from the buried coseismic structures to the trace of the Magallanes-Fagnano fault argues for high-magnitude earthquake activity on this fault throughout the Holocene. Urban development on soft glacial and alluvial substrates increases the hazard.     

The Magmatic–Hydrothermal Transition and Origin of Brine in the Oceanic Core Complex of the Mid-Atlantic Ridge at 13° N

New data on local mineral associations and the microheterogeneity of minerals and fluid inclusions in gabbro were obtained for the gabbro–peridotite oceanic core complex with a long-lived detachment fault controlling the hydrothermal activity. It is assumed that the hydrothermal hydrogen-bearing fluid with a NaCl content of >30 wt % is formed in the seawater/harzburgite (~1/5) reaction of serpentinization. The brine residual after serpentinization interacted with gabbro at the final stages of crystallization of an intrusion and assimilated some components (K, REEs, and Ba) from the residual melt. The interaction was resulted in metamorphic transformations of gabbro at decreasing temperature below 500°C. The reaction of the decomposition of magmatic titanomagnetite with the transition of iron reduced to Fe²⁺ into newly formed chlorinebearing amphibole at 540–450°C and logf(O₂) from–20 to–24 is shown.

     

Geochemical and isotopic signatures of magmatic products in the MAR rift valley at 12°49′–17°23′ N and 29°59′–33°41′ N: Evidence of Two contrasting sources of the parental melts

Data presented in the paper suggest significant differences between the thermodynamic conditions under which magmatic complexes were formed in MAR at 29°–34° N and 12°–18° N. The melts occurring at 29°–34° N were derived by the melting of a mantle source with a homogeneous distribution of volatile components and arrived at the surface without significant fractionation, likely, due to their rapid ascent. The MAR segments between 12° and 18° N combine contrasting geodynamic environments of magmatism, which predetermined the development of a large plume region with the widespread mixing of the melting products of geochemically distinct mantle sources. At the same time, this region is characterized by conditions favorable for the origin of localized zones of anomalous plume magmatism. These sporadic magmatic sources were spatially restricted to MAR fragments with the Hess crust, whose compositional and mechanical properties were, perhaps, favorable for the focusing and localization of plume magmatism. The plume source between 12° and 18°N beneath MAR may be geochemically heterogeneous.     

Evolution of the Neogene Andean foreland basins of the Southern Pampas and Northern Patagonia (34°–41°S), Argentina

The Pampas plain (30°–41°S) has historically been considered as a sector that evolved independently from the adjacent Andean ranges. Nevertheless, the study of the Pampas showed that it is reasonable to expect an important influence from the Andes into the extraandean area. The Pampas plain can be divided into two sectors: the northern portion, adjacent to the Pampean Ranges, has been studied by Davila (2005, 2007, 2010). The southern sector (34°–41°S) is the objective of the present work. The study of this area allowed to characterize two separate foreland basins: the Southern Pampa basin and the Northern Patagonian basin. The infill is composed of Late Miocene and Pliocene units, interpreted as distal synorogenic sequences associated with the late Cenozoic Andean uplift at this latitudinal range. These foreland basins have been defined based on facies changes, distinct depositional styles, along with the analysis of sedimentary and isopach maps. The basins geometries are proposed following De Celles and Gilles (1996) taking into account the infill geometry, distribution and grain size. In both cases, these depocenters are located remarkably far away from the Andean tectonics loads. Therefore they cannot be explained with short-wave subsidence patterns. Elastic models explain the tectonic subsidence in the proximal depocenters but fail to replicate the complete distal basins. These characteristics show that dynamic subsidence is controlling the subsidence in the Southern Pampas and Northern Patagonian basins.     

Complexation of metal ions in brines: application of electronic spectroscopy in the study of the Cu(II)-LiCl-H2O system between 25 and 90°C

The concentration and transport of metals in hydrothermal solutions depend on how metals ions combine with ligands to form complexes, and experimental methods are necessary to identify the important complexes. UV-Vis-NIR spectrophotometry was used to study the formation of Cu(II)-chloride complexes in LiCl brines up to very high chlorinities (18 m LiCl), at temperatures between 25°C and 90°C. The number of Cu(II)-chloride complexes necessary to account for the variation in spectra with varying chloride molality at each temperature was estimated using principal component analysis. The molar absorptivity coefficients and concentrations of each complex were then determined using a “model-free” analysis, which does not require any assumption about the chemistry of the system, other than the number of absorbing species present. Subsequently, the results from the “model-free” analysis were integrated with independent experimental evidence to develop a thermodynamic speciation model, where the logarithms of the equilibrium constants for Cu(II)-chloride formation reactions were fitted to the data using a non-linear least-squares approach. Maps of the residual function were used to estimate uncertainties in the fitted equilibrium constants.The results of this study are similar to published properties of distorted octahedral [CuCl(OH₂)₅]⁺ and [CuCl₂(OH₂)₄]⁰ at all temperatures, but diverge for [CuCl₃(OH₂)₃]⁻ and distorted tetrahedral [CuCl₄]²⁻. Moreover, the data suggest the presence of [CuCl₅]³⁻, probably with D_3h point group, at very high salt concentration. This study demonstrates that it is possible to determine apparent thermodynamic equilibrium constants for the formation of complexes of trace amount of metals in highly concentrated brines, such as those associated with many ore deposits. The results are dependent on the choice of activity coefficients for charged and neutral aqueous complexes, but this influence is relatively small compared with the experimental uncertainty. This study shows that Cu²⁺ chloro-complexes, predominantly [CuCl₂(OH₂)₄]⁰ and [CuCl₄]²⁻, will play a dominant role in nature where free oxygen is available (near-surface), and where chloride activities are very high (evaporitic basins; hypersaline soils).     

The structure of the Precambrian and Lower Paleozoic basement of the Central Andes between 22° and 32°S. Lat.

Three major diastrophic cycles, defined by their structural style and their spatial distribution are recognized in the Andean Basement of this region. The oldest structures are related to the Panamerican Orogeny (500 to 700 m. a.) which produced in the Central Craton multiply deformed complexes of schists, gneisses and granites, that are covered discordantly by unmetamorphosed Cambrian and Ordovician beds. West of the Central Craton Ordovician sedimentary beds are folded with a simple structural style and intruded by granites. Both the sedimentry beds and the granites are covered discordantly by undeformed Devonian sequences. The folding of the Ordovician is attributed to the ocloyic phase of the Caledonian movements. West of the ocloyic belt is another foldbelt consisting of strongly folded Devonian beds attributed to the chanic phase (hercynian). The chanic belt is intruded by carboniferous and permian granites and covered discordantly by Carboniferous and Permian sequences.The features observed in the eastern slope of the Andes suggest that the Paleozoic foldbelts are intracratonic. Whether there are accreted terrains in the Pacific Coastal Cordillera is matter of controversy.

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Zusammenfassung Im Andenbasement dieser Region lassen sich drei diastrophische Hauptzyklen, die durch ihren strukturellen Baustil und ihre geographische Verbreitung definiert sind, unterscheiden. Die ältesten Strukturen sind verknüpft mit den Bewegungen der Panamerikanischen Orogenese (500–700 m. a.), welche im Zentralkraton einen polydeformierten Komplex von Schiefern, Gneissen und Graniten erzeugte. Diesem lagern diskordant kambrische und ordovizische Sequenzen ohne Metamorphose und präandiner Deformation auf. Nach Westen zu gibt es einen Gürtel stark deformierter ordovizischer Sedimente, die einen einfacheren Baustil als das präkambrische Basement aufweisen, und diskordant von undeformierten devonischen Abfolgen bedeckt sind. Die Faltung des Ordoviziums wird der Ocloyischen Phase der Kaledonischen Bewegung zugerechnet.Weiter westwärts tritt ein jüngerer Faltengürtel aus devonischen Sedimenten auf, die während der Chanischen Phase der Herzynischen Bewegung intensiv deformiert wurden, und von karbonischen und permischen Sequenzen diskordant überlagert sind.Der Ocloyische Gürtel ist von postordovizischen Graniten die von devonischen Schichten überlagert sind, und der Chanische Gürtel von karbonischen und permischen Graniten intrudiert. Im präkambrischen Basement des Zentralkratons treten einerseits präkambrische Granite auf, denen diskordant kambrische Schichten auflagern. Andererseits findet man Granite mit paläozoischen Isotopenaltern, letztere aber in Gebieten, wo wegen des Fehlens von Deckschichten eine stratigraphische Kontrolle unmöglich ist.Die gemachten Beobachtungen scheinen darauf hinzudeuten, daß die paläozoischen Faltengürtel intrakratonisch sind. Ob es allochtone »terrains« in der pazifischen Küstenkordillere gibt, ist Gegenstand der Kontroverse.

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Resumen En el basamento de los Andes de esta región se distinguen tres ciclos diastróficos mayores definidos por sus estilos estructurales y su distributión espacial. Las estructuras mas antiguas responden a movimientos que culminaron con la Orogénesis Panamericana (500–700 m. a.) que produjo en el Cratógeno Central un complejo de esquistos, gneises y granitos polideformados, al que se le superponen discordantemente secuencias cámbricas y ordovicicas sin metamorfismo ni déformatión preandina. Hacia el oeste hay un cinturón de sedimentos ordovícicos intensamente deformados con un estilo de plegamiento mas simple que el del basamento precámbrico y cubierto discordantemente por secuencias marinas devónicas sin deformatión. Los movimientos responsables de este plegamiento se atribuyen a la fase oclóyica de los movimientos caledónicos. Más hacia el oeste se manifiesta una franja de deformatión mas jóven atribuída a la Fase chánica de los movimientos hercínicos, en ella se encuentran sedimentitas devónicas intensamente plegadas cubiertas discordantemente por secuencias carbónicas y pérmicas.El cinturón oclóyico esta acompanãdo por granitos postordovícicos cubiertos por Devónico. Asimismo, el cinturón chánico (hercínico) esta intruido por granitos probablemente carbónicos. Con respecta a los granitos intruidos en el zócalo antiguo, hay algunos indudablemente precámbricos por estar cubiertos discordantemente por secuencias cámbricas sin metamorfismo, además hay granitos de edad dudosa que han dado valores isotópicos paleozoicos pero en lugares donde el control estratigráfico no es posible por ausencia de la cobertura paleozoica. De acuerdo a los hechos observados en la ladera oriental de los Andes surge la idea de que los cinturones de plegamiento paleozoicos son intracratónicos, aun es materia de controversia si en la Cordillera de la Costa junto al Pacifico hay terrenos alóctonos acrecionados.

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Morphology and impurity elements of zircon in the oceanic lithosphere at the Mid-Atlantic ridge axial zone (6°–13° N): Evidence of specifics of magmatic crystallization and postmagmatic transformations

The paper presents newly obtained original data on the morphology, internal structure (as seen in cathodoluminescence images, CL), and composition of more than 400 zircon grains separated from gabbroids and plagiogranites (OPG) sampled at the axial zone of the Mid-Atlantic Ridge (MAR). The zircons were analyzed for REE by LA-ICP-MS and for Hf, U, Th, Y, and P by EPMA. Magmatic zircon in the gabbroids crystallized from differentiating magmatic melt in a number of episodes, as follows from systematic rimward increase in the Hf concentration, and also often from the simultaneous increase in the (U + Th) and (Y + P) concentrations. These tendencies are also discernible (although much less clearly) in zircons from the OPG. Zircon in the OPG is depleted in REE compared to the least modified zircons in the gabbro, which suggests that the OPG were derived via partial melting of gabbro in the presence of seawater-derived concentrated aqueous salt fluid. Another reason for the REE depletion might be simultaneous crystallization of zircon and apatite. The CL-dark sectors, which are found in practically all of the magmatic zircon grains, have Y/P (a.p.f.u.) ? 1 which most likely resulted from OH accommodation in the zircon structure, a fact suggesting that the OPG parental melt contained water. High-temperature hydrothermal processes induced partial to complete recrystallization of zircon (via dissolution-reprecepitation), a process that was associated with ductile and brittle deformations of the zircon-hosting rocks. The morphology of the hydrothermal zircons varies depending on pH and silica activity in the fluid from weakly corroded subhedral crystals with typical vermicular microtopography of the crystal faces to completely modified grains of colloform structure. Geochemically, the earlier hydrothermal transformations of the zircons resulted in their enrichment in La and other LREE, except only Ce, whose concentration, conversely, decreases compared to that of the unmodified magmatic zircons. The hydrothermal zircon displays a reduced Ce anomaly and its most altered domains typically host minute inclusions of xenotime, U and Th oxides and silicates, and occasionally also baddeleyite, which suggests that the hydrothermal fluid was reduced and highly alkaline. These features were acquired by the seawater-derived fluid when it circulated within the axial MAR zone area due to phase separation in the H₂O–NaCl system and particularly as a result of fluid interaction with the abyssal peridotites of oceanic core complexes. Our data demonstrate that zircon is a sensitive indicator of tectonic and physicochemical processes in the oceanic crust.     

Miocene to recent history of the western Altiplano in northern Chile revealed by lacustrine sediments of the Lauca basin (18°15′–18°40′ S/69°30′–69°05′W)

The intramontane Lauca Basin at the western margin of the northern Chilean Altiplano lies to the west of and is topographically isolated from the well-known Plio-Pleistocene lake system of fluvio-lacustrine origin that covers the Bolivian Altiplano from Lake Titicaca to the north for more than 800 km to the Salar de Uyuni in the south. The Lauca Basin is filled by a sequence of some 120 m of mainly upper Miocene to Pliocene elastic and volcaniclastic sediments of lacustrine and alluvial origin. Volcanic rocks, partly pyroelastic, provide useful marker horizons. In the first period (6–4 Ma) of its evolution, the Lago Lauca was a shallow ephemeral lake. Evaporites indicate temporarily closed conditions. After 4 Ma the lake changed to a perennial water body surrounded by alluvial plains. In the late Pleistocene and Holocene (2-0 Ma) there was only marginal deposition of alluvial and glacial sediments. The basin formed as a half-graben or by pull-apart between 10 and 15 Ma (tectonic displacement of the basal ignimbrite sequence during the Quechua Phase) and 6.2 Ma (maximum K/Ar ages of biotites of tuff horizons in the deepest part of the basin). Apart from this early basin formation, there has been surprisingly little displacement during the past 6 Ma close to the Western Cordillera of the Altiplano. Also, climate indicators (pollen, evaporites, sedimentary facies) suggest that an arid climate has existed for the past 6 Ma on the Altiplano. Together, these pieces of evidence indicate the absence of large scale block-faulting, tilt and major uplift during the past 5–6 Ma in this area.     

Bursting the limits of time： the reconstruction of geohistory in the age of revolution

Bursting the Limits of Time by the distin- guished historian of geology Martin Rudwick is a massive, two-part book. The first part contains what he calls a synchronous history of what eventually became historical geology in western Europe between the time of de Sans- sure＇s epoch-making ascent of Mont Blanc in 1787 and the discovery of the Kirkdale hyaena cave by Buckland in the winter of 1821-1822,     

Evidence for Granitoid Magmatism and the Composition of the Silicic Melt in the Gabbroid Assemblage of the Mid-Atlantic Ridge at 13° N: New Data on Melt Inclusions

Doklady Earth Sciences - Despite the local occurrence of silicic magmatism during the formation of the oceanic crust, the nature of felsic granitoid veins (“oceanic plagiogranite”)...     

Experimental investigation of aqueous corrosion of R7T7 nuclear glass at 90°C in the presence of organic species

The initial dissolution kinetics of the French “R7T7” inactive LWR reference glass was investigated in organic media at 90°C by static experiments at imposed pH values. Tests were conducted with various organic acids or acid salts (formic acid, citric acid, humic acids, sodium citrate and sodium formate) at different concentrations and at pH values ranging from 3 to 9. The leachates were submitted to ICP-AES analysis, and the alteration films on the glass specimens were examined by SEM (equipped with an energy-dispersive chemical analysis systm) and XRD. Results are discussed for the following areas.Effect of pH: different mechanisms are involved at pH 2.5 and pH 9, but in both cases, the R7T7 glass dissolution kinetics are always controlled by a surface reaction mechanism. The most significant effects of the organic acids on the glass dissolution kinetics were observed at pH 3, which was not unexpected.Nature of the acid (or acid salt): this is an essential parameter. Formic acid (monoacid) and sodium formate had no effect on the initial glass dissolution rate nor on the nature of the alteration film; conversely, citric acid (triacid) and sodium citrate significantly affected glass dissolution. The role of citric acid in the surface reaction mechanism has been demonstrated experimentally at pH 2.5; it is also known to favor that extraction of Si (directly or indirectly) and Zr and probably of Fe. The humic acids are strong catalysts of the R7T7 glass dissolution reaction. The conclusions drawn from these observations corroborate other published findings, suggesting that the catalytic effect is appreciable only for species with at least two carboxylic acid functions.Effect of concentration: the effect of the concentration was observed at basic pH values in the presence of sodium citrate and humic acids. This parameter may thus be quantified and incorporated in the glass dissolution kinetic law.     

Formation of N–С–О–Н molecules and complexes in the basalt–basaltic andesite melts at 1.5 Gpa and 1400°C in the presence of liquid iron alloys

The contents and speciation of nitrogen, carbon, and hydrogen were determined in basalt–basaltic andesite melts in equilibrium with liquid Fe alloys at 1.5 Gpa, 1400°C, and oxygen fugacity (fO₂) 1.4–1.9 log units below that of the Fe–FeO buffer (ΔlogfO₂(IW) =–1.4 …–1.9). Experiments were carried out on a piston- cylinder type apparatus using welded Pt capsules in the presence of excess С (graphite). Starting mixture consisted of natural ferrobasaltic glass and silicon nitride (Si₃N₄) as nitrogen source in the system. Experimental quench products representing glasses with spherical inclusions of iron alloy were analyzed using electron microprobe, Raman, and IR spectroscopy. With increase of Si₃N₄ in the starting mixture and, respectively, decrease of fO₂, silicate melt forming during experiments became depleted in FeO and enriched in SiO₂. It was established that the nitrogen content in the glasses increases from 0.13 to 0.44 wt % with decrease of ΔlogfO₂(IW) from–1.4 to–1.9, whereas C content in the first approximation remains constant within 1.18–1.13 wt %, while the total water content (ОН^– + Н₂О) determined by IR spectroscopy decreases from 4.91 to 1.20 wt %. The N (0.13–0.48 wt %) and C (0.75–2.26 wt %) contents determined in the Fe alloy show no clear correlation with fO₂. The IR and Raman spectroscopic study of the glasses indicates the formation of molecules and complexes with bonds N–H (NH₃, NH₂ ^?, NH₂ ⁺, NH₄ ⁺), Н–О (Н₂О, OH^–), С–Н (СН₄) as well as N₂ and Н₂ molecules in silicate melts. IR spectra also reveal the presence of complexes with С=О, С–N bonds and СО₂ molecules. Obtained data are compared with results of previous studies on the solubility and speciation of N, С, and Н in the model FeO–Na₂O–SiO₂–Al₂O₃ melts in equilibrium with liquid iron alloys at 1.5 GPa (1400°C) and 4 GPa (1550°C) (Kadik et al., 2011, 2015).