Horizontal and Vertical Co2 Advection In A Sloping Forest

A system measuring the horizontal and vertical advection was devised and installed in a sloping forest at the Vielsalm site, Belgium. The measurements showed that under stable conditions a flow regime established below the canopy: air flowed horizontally along the slope and entrained the air above the canopy vertically. This movement occurs during stable nights characterised by strongly negative net radiation. It creates negative air concentration gradients in both the vertical and horizontal directions. The advection fluxes associated with these movements are opposite and of a similar order of magnitude. This implies that the horizontal advection cannot be ignored in the carbon budget equation at night. Unfortunately, the large variability of, and considerable uncertainty about, advection fluxes does not enable one to produce estimates of the source term from these equations. Advection measurement systems should be improved in order to enable such estimates to be made. Particular attention should be paid to the estimation of the vertical velocity above the canopy and to the vertical profiles of the horizontal velocity and horizontal CO₂ gradient below the canopy.     

Comparing CO2 Storage and Advection Conditions at Night at Different Carboeuroflux Sites

Anemometer and CO₂ concentration data from temporary campaigns performed at six CARBOEUROFLUX forest sites were used to estimate the importance of non-turbulent fluxes in nighttime conditions. While storage was observed to be significant only during periods of both low turbulence and low advection, the advective fluxes strongly influence the nocturnal CO₂ balance, with the exception of almost flat and highly homogeneous sites. On the basis of the main factors determining the onset of advective fluxes, the ‘advection velocity’, which takes net radiation and local topography into account, was introduced as a criterion to characterise the conditions of storage enrichment/depletion. Comparative analyses of the six sites showed several common features of the advective fluxes but also some substantial differences. In particular, all sites where advection occurs show the onset of a boundary layer characterised by a downslope flow, negative vertical velocities and negative vertical CO₂ concentration gradients during nighttime. As a consequence, vertical advection was observed to be positive at all sites, which corresponds to a removal of CO₂ from the ecosystem. The main differences between sites are the distance from the ridge, which influences the boundary-layer depth, and the sign of the mean horizontal CO₂ concentration gradients, which is probably determined by the source/sink distribution. As a consequence, both positive and negative horizontal advective fluxes (corresponding respectively to CO₂ removal from the ecosystem and to CO₂ supply to the ecosystem) were observed. Conclusive results on the importance of non-turbulent components in the mass balance require, however, further experimental investigations at sites with different topographies, slopes, different land covers, which would allow a more comprehensive analysis of the processes underlying the occurrence of advective fluxes. The quantification of these processes would help to better quantify nocturnal CO₂ exchange rates.     

The Influence of Advection on the Short Term CO 2 -Budget in and Above a Forest Canopy

An experimental micrometeorological set-up was established at the CARBOEURO-FLUX site in Tharandt, Germany, to measure all relevant variables for the calculation of the vertical and horizontal advective fluxes of carbon dioxide. The set-up includes two auxiliary towers to measure horizontal and vertical CO₂ and H₂O gradients through the canopy, and to make ultrasonic wind measurements in the trunk space. In combination with the long-term flux tower an approximately even-sided prism with a typical side-length of 50 m was established. It is shown that under stable (nighttime) conditions the mean advective fluxes have magnitudes on the same order as the daily eddy covariance (EC) flux, which implies that they play a significant, but not yet fully understood, role in the carbon budget equation. The two advective fluxes are opposite and seem to cancel each other at night (at least for these measurements). During the day, vertical advection tends to zero, while horizontal advection is still present implying a flow of CO₂ out of the control volume. From our measurements, a mean daily gain of 2.2 gC m^–2 d^–1 for the horizontal advection and a mean daily loss of 2.5 gC m^–2d^–1 for the vertical advection is calculated for a period of 20 days. However the large scatter of the advective fluxes has to be further investigated. It is not clear yet whether the large variability is natural or due to measurement errors and conceptual deficiencies of the experiment. Similar results are found in the few comparable studies.     

Cape Grim isotope measurements — A preliminary assessment

Measurements of the stable carbon isotope ratio in atmospheric CO₂ permit a distinction between variations resulting from biospheric and oceanic exchange. In situ extraction of CO₂ from Cape Grim air (41°S) for isotopic analysis commenced in 1977; however difficulties with technique reliability were experienced until 1982. Since 1982, 2.6 years of relatively consistent values have accumulated.For a preliminary assessment of the latter data, estimates of the isotopic behaviour from the global transport and inter-reservoir exchange model of Pearman and Hyson (1985) have been employed. The assessment demonstrates the precision requirements of a carbon isotope monitoring program and the relevance of the isotope measurements as a constraint on parameterization of the model.Clear evidence of the changes due to fossil fuel combustion is seen in the year-to-year differences in ¹³C, with the mean and standard error of the overall trend being –0.025±0.005 yr^-1. A significant seasonal variation in ¹³C is apparent, despite considerable inter-annual variability possibly associated with the 1982/83 ENSO phenomena. The average peak-to-peak amplitude is 0.055±0.014 with a maximum on day 85±15 (approx. 26 March).There is some evidence for a complex seasonal inter-relationship between concentration and isotope ratio, both in the Cape Grim data and in Mook et al. (1983) South Pole data, but with marked differences between the stations, and with both different from the model estimates.In particular, the Cape Grim results suggest that exchange with Southern Hemisphere biosphere is the main contributor to the seasonal variation in isotope ratio at this latitude.     

Effects of an Urban Park and Residential Area on the Atmospheric CO2 Concentration and Flux in Seoul, Korea

The CO₂ concentrations and fluxes over an urban forest site (Namsan) and an urban residential region (Boramae) in Seoul, Korea, during the non-growing season (2–4 March 2011), the growing season (10–12 June 2011), and the late-growing season (22–24 September 2011) were analyzed. The CO₂ concentrations of two sites showed nearly the same diurnal variation, with a maximum value occurring during the night and a minimum value occurring during daytime, as well as the same seasonal variation, with a maximum value during the non-growing season (early spring) and a minimum value during the growing season (summer). The CO₂ flux over the urban forest did not show any typical diurnal variation during the non-growing season, but did show diurnal variation with a small positive value during the night and a large negative value during daytime in the growing and late-growing seasons due to photosynthesis in the urban forest. The CO₂ flux over the urban residential region showed a positive daily mean value for all periods, with large values during the non-growing season and small values during the growing season, and it also showed diurnal variation with two maxima at 0600–1000 LST and 1800–2400 LST, and two minima at 0300-0600 LST and 1100-1500 LST, and was strongly correlated with the use of liquefied natural gas for cooking and heating by surrounding houses.     

锡林浩特草原CO2通量特征及其影响因素分析

利用锡林浩特国家气候观象台开路涡度相关系统、辐射土壤观测系统,测得的长期连续通量观测数据,对锡林浩特草原2009—2011年期间的CO₂通量观测特征进行了分析。结果表明:CO₂通量存在明显的年际、季节和日变化特征。3 a中NEE年际变率达到200 g·m^-2,季节变率最大达到460 g·m^-2,日变化幅度生长季最大达到0.25 mg·m^-2·s^-1。通过不同时间尺度碳通量与温度、水分、辐射等环境因子的分析,认为CO₂通量日变化主要受温度和光合有效辐射影响,而季节变化和年变化主要受降水和土壤含水量的影响。降水强度及时间分布是制约牧草CO₂吸收的关键因素,大于15%的土壤含水量有利于促进牧草生长。     

On the Significance of the Webb Correction to Fluxes

For establishing correct mass or energy balances at the Earth's surface, detailed and correct measurements of air constituent fluxes are needed. Flux measurements obtained from the eddy covariance technique have to pass several corrections of different relevance in order to give correct flux data. One of these corrections, the Webb correction, is analysed herein from latent heat flux and CO₂ flux data recorded during two field experiments. The significance of this correction for the latent heat flux data varies with the air humidity and the Bowen ratio. The correction changes the latent heat flux values only a little, but significantly (by 2 to 3%). For other air constituents (like CO₂), the Webb correction is much more important (20 to 30% of the flux).     

Comparative Measurements Of Co2flux Over A Forest Using Closed-Path And Open-Path Co2analysers

An eddy covariance system using a closed-path CO₂analyser was constructed for long-term CO₂flux measurements above a forest, and its total frequency response was valuated experimentally. The amplitude and phase responses of the system wereexamined through a preliminary test, in which a prescribed pattern of CO₂fluctuation was input to the system. The result showed that the amplitude of the output from the system was attenuated as frequency increased, with a half-power frequency of 0.3 Hz. The phase was delayed by the air sampling through a long tube, but the delay in phase decreased asfrequency increased. We then presented a new technique for the correction of flux loss due to the inadequate system response for the eddy covariance measurements of CO₂ flux. Using the present system and the correction technique, diurnal variations in CO₂ flux were measured over a temperate deciduous forest on three days in 1997. The results were compared with the CO₂fluxes measured with a fast response open-path gas analyser. The CO₂fluxes from the closed-path system agreed with those from the open-path system after the Webb, Pearman and Leuning correction was made for the latter. In the present test over a forest, the contribution of the frequency-response correction to the CO₂fluxes was small and its averaged percentage was only 3%in the daytime. However, the percentage would likely increase, if the system were applied to a shorter vegetation site where high frequency components are more important. The comparison confirmed that we can obtain correct measurements of CO₂flux using the present closed-path system and the correction technique.     

Practical applicability of high frequency correction theories to CO<Subscript>2</Subscript> flux measured by a closed-path system

The theoretical correction of CO₂ fluxes for high frequency attenuation in closed-path systems was re-summarized and its applicability examined using both measurements obtained at an Asiaflux forest site and empirical transfer functions used in previous studies. For our measurement system, the theoretical transfer function was applicable to high frequency correction, even when condensation occurred in the sampling line. Further, in respect to some measurement systems described in previous studies, it was found that the theoretical function was potentially applicable along with the empirical functions used. Meanwhile, in some systems significant errors could not be resolved by re-estimation of the theories. In these systems, because of undefined buffering effects, the actual response lag time decided by the maximum covariance method or by measurement of the system response time using tracer gas was significantly different from the lag time calculated from the tube dimensions and the measured flow rate. If the average flow rate calculated by the actual lag time was used to determine the theoretical function, the theoretical function became closer to, and sometimes agreed with, the empirical function. Any remaining deviation from each function might be associated with pressure fluctuations, but this problem was unable to be examined here. The results suggested that an empirical formulation for each site is considered applicable rather than a theoretical approach, although the theories are being developed to practical application.     

Measurement of the photodissociation coefficient of NO2 in the atmosphere: II,stratospheric measurements

The photodissociation coefficient of NO₂, J _{NO 2}, has been measured from a balloon platform in the stratosphere. Results from two balloon flights are reported. High Sun values of J _{NO 2} measured were 10.5±0.3 and 10.3±0.3×10^-3 s^-1 at 24 and 32 km respectively. The decrease in J _{NO 2} at sunset was monitored in both flights. The measurements are found to be in good agreement with calculations of J _{NO 2} using a simplified isotropic multiple scattering computer routine.     

Stratospheric and total NO2 column measurements with a modified Canterbury filter photometer

A programme of ground-based stratospheric and total NO₂ column measurements was instituted at the Laboratory of Atmospheric Physics (40.5° N, 22.9° E) in August 1985. We present here the results of the first two years of measurements with a modified Canterbury filter photometer, details of which are given in the text. The stratospheric NO₂ column, obtained at twilight during low local NO₂ levels, shows the seasonal variation with monthly mean values of about 6×10^-15 molec. cm^-2 in the summertime to about 2.2×10^-15 molec. cm^-2 in the wintertime. These measurements compare well with measurements obtained with different instruments by other groups at similar latitudes (about 40° N) but in different places. Also, the asymmetry of the evening-to-morning stratospheric NO₂ over Thessaloniki was found to be on the average equal to 1.58. Total NO₂ column over Thessaloniki has a pronounced seasonal variation with amplitude of 0.68 matm. cm which can be explained partly from measured local NO₂ sources which discharge in the mixing layer and partly from photolysis of the NO₂ reservoir species.     

The impact of the Tokyo Metropolitan Emissions Trading Scheme on reducing greenhouse gas emissions: findings from a facility-based study

This paper provides a detailed analysis of the Tokyo Metropolitan Emissions Trading Scheme (Tokyo ETS), Japan’s first emissions trading scheme with mandatory cap initiated by the government of Tokyo. Unlike trading schemes in other countries, the Tokyo ETS covers indirect emissions from the commercial sector. It is well known that a variety of market barriers impede full realization of energy efficiency opportunities, especially in the commercial sector. Experiences with the Tokyo ETS should therefore provide important lessons for the design of climate change mitigation policies, especially when targeting the commercial sector. The emissions from covered entities have been drastically reduced from those at the scheme’s outset, with an average 14% reduction as of the end of the first commitment period of five years (2010–2014) compared with 2009 levels. This paper shows that the Tokyo ETS alone did not cause these reductions; there were other drivers. Among them, the energy savings triggered by the Great East Japan Earthquake in 2011 were crucial. The contribution of credit trading, in contrast, was limited since most of the covered entities reduced emissions by themselves. Through an investigation of official reports, an assessment of the emissions data from the covered entities compared to those of uncovered entities and in-depth interviews with firms covered by the scheme, this paper confirms that the main drivers of emissions reductions by covered entities were separate from the ETS. In fact, the advisory aspect of the scheme seems to be much more important in encouraging energy-saving actions.

Key policy insights

• Most of the observed emission reductions were not caused by the Tokyo ETS alone.

• An advisory instrument was crucial to the effectiveness of the Tokyo ETS.

• The experience of the Tokyo ETS suggests that making full use of the advantages of emissions trading is difficult in the case of the commercial sector.

• Price signals have not provided a stimulus to climate change mitigation actions, which implies that establishing a cap to yield effective carbon prices poses a challenge.

     

Investigating a Hierarchy of Eulerian Closure Models for Scalar Transfer Inside Forested Canopies

Modelling the transfer of heat, water vapour, and CO₂ between the biosphere and the atmosphere is made difficult by the complex two-way interaction between leaves and their immediate microclimate. When simulating scalar sources and sinks inside canopies on seasonal, inter-annual, or forest development time scales, the so-called well-mixed assumption (WMA) of mean concentration (i.e. vertically constant inside the canopy but dynamically evolving in time) is often employed. The WMA eliminates the need to model how vegetation alters its immediate microclimate, which necessitates formulations that utilize turbulent transport theories. Here, two inter-related questions pertinent to the WMA for modelling scalar sources, sinks, and fluxes at seasonal to inter-annual time scales are explored: (1) if the WMA is to be replaced so as to resolve this two-way interaction, how detailed must the turbulent transport model be? And (2) what are the added predictive skills gained by resolving the two-way interaction vis-à-vis other uncertainties such as seasonal variations in physiological parameters. These two questions are addressed by simulating multi-year mean scalar concentration and eddy-covariance scalar flux measurements collected in a Loblolly pine (P. taeda L.) plantation near Durham, North Carolina, U.S.A. using turbulent transport models ranging from K-theory (or first-order closure) to third-order closure schemes. The multi-layer model calculations with these closure schemes were contrasted with model calculations employing the WMA. These comparisons suggested that (i) among the three scalars, sensible heat flux predictions are most biased with respect to eddy-covariance measurements when using the WMA, (ii) first-order closure schemes are sufficient to reproduce the seasonal to inter-annual variations in scalar fluxes provided the canonical length scale of turbulence is properly specified, (iii) second-order closure models best agree with measured mean scalar concentration (and temperature) profiles inside the canopy as well as scalar fluxes above the canopy, (iv) there are no clear gains in predictive skills when using third-order closure schemes over their second-order closure counterparts. At inter-annual time scales, biases in modelled scalar fluxes incurred by using the WMA exceed those incurred when correcting for the seasonal amplitude in the maximum carboxylation capacity (V _{cmax, 25}) provided its mean value is unbiased. The role of local thermal stratification inside the canopy and possible computational simplifications in decoupling scalar transfer from the generation of the flow statistics are also discussed.

“The tree, tilting its leaves to capture bullets of light; inhaling, exhaling; its many thousand stomata breathing, creating the air”. Ruth Stone, 2002, In the Next Galaxy

     

Uptake and Storage of Anthropogenic CO2 in the Pacific Ocean Estimated Using Two Modeling Approaches

A basin-wide ocean general circulation model(OGCM) of the Pacific Ocean is employed to estimate the uptake and storage of anthropogenic CO 2 using two different simulation approaches.The simulation(named BIO) makes use of a carbon model with biological processes and full thermodynamic equations to calculate surface water partial pressure of CO 2,whereas the other simulation(named PTB) makes use of a perturbation approach to calculate surface water partial pressure of anthropogenic CO 2.The results from the two simulations agree well with the estimates based on observation data in most important aspects of the vertical distribution as well as the total inventory of anthropogenic carbon.The storage of anthropogenic carbon from BIO is closer to the observation-based estimate than that from PTB.The Revelle factor in 1994 obtained in BIO is generally larger than that obtained in PTB in the whole Pacific,except for the subtropical South Pacific.This,to large extent,leads to the difference in the surface anthropogenic CO 2 concentration between the two runs.The relative difference in the annual uptake between the two runs is almost constant during the integration processes after 1850.This is probably not caused by dissolved inorganic carbon(DIC),but rather by a factor independent of time.In both runs,the rate of change in anthropogenic CO 2 fluxes with time is consistent with the rate of change in the growth rate of atmospheric partial pressure of CO 2.     

Influence of leaf water potential on diurnal changes in CO2 and water vapour fluxes

Mass and energy fluxes between the atmosphere and vegetation are driven by meteorological variables, and controlled by plant water status, which may change more markedly diurnally than soil water. We tested the hypothesis that integration of dynamic changes in leaf water potential may improve the simulation of CO₂ and water fluxes over a wheat canopy. Simulation of leaf water potential was integrated into a comprehensive model (the ChinaAgrosys) of heat, water and CO₂ fluxes and crop growth. Photosynthesis from individual leaves was integrated to the canopy by taking into consideration the attenuation of radiation when penetrating the canopy. Transpiration was calculated with the Shuttleworth-Wallace model in which canopy resistance was taken as a link between energy balance and physiological regulation. A revised version of the Ball-Woodrow-Berry stomatal model was applied to produce a new canopy resistance model, which was validated against measured CO₂ and water vapour fluxes over winter wheat fields in Yucheng (36°57′ N, 116°36′ E, 28 m above sea level) in the North China Plain during 1997, 2001 and 2004. Leaf water potential played an important role in causing stomatal conductance to fall at midday, which caused diurnal changes in photosynthesis and transpiration. Changes in soil water potential were less important. Inclusion of the dynamics of leaf water potential can improve the precision of the simulation of CO₂ and water vapour fluxes, especially in the afternoon under water stress conditions.     

A Simple Method of Estimating Scalar Fluxes Over Forests

A simple aerodynamic-variance method is proposed to fill gaps in continuous CO₂ flux measurements in rainy conditions, when open-path analysers do not function. The method requires turbulent conditions (friction velocity greater than 0.1 ms^–1), and uses measurements of mean wind speed, and standard deviations of temperature and CO₂ concentration fluctuations to complement, and at times replace, eddy-covariance measurements of friction velocity, sensible heat flux and CO₂ flux. Friction velocity is estimated from the mean wind speed with a flux-gradient relationship modified for the roughness sublayer. Since normalised standard deviations do not follow Monin-Obukhov similarity theory in the roughness sublayer, a simple classification scheme according to the scalar turbulence scale was used. This scheme is shown to produce sensible heat and CO₂ flux estimates that are well correlated with the measured values.     

Balloon-borne measurements of NO2: can a comparison of remote techniques be made from the historic data?

When all balloon-borne measurements of NO₂ in the stratosphere are reviewed, the profiles show a wide spread. Measurements of the total amount in a vertical column suggest that variability should be low when only profiles measured at mid-latitudes close to equinox are selected. With this selection, the standard deviation of the profiles measured by each technique is often less than ±20%, but the mean profiles measured by each technique differ by up to a factor 2. Despite the profiles not being measured simultaneously, these differences are identical to those revealed by the simultaneous measurements of the Balloon Intercomparison Campaigns of 1982 and 1983-a comparison can be made from the historic data alone. This suggests that measurements of other gases should be similarly reviewed and appropriate selection criteria be found that reduces the standard deviations of the measurements by any one technique. The techniques can then be intercompared without new simultaneous flights.     

[Bmin][BF4]+AMP复合溶液捕集温室气体CO2

采用基于离子液体[Bmin][BF₄]+AMP作为捕集CO₂的复合溶液,在膜吸收-热再生循环装置上,研究了该复合溶液捕集CO₂的过程和传质性能;通过阻力层传质模型,比较了预测值与实验值.结果表明：在相同条件和较高负载下,复合溶液具有较高的传递推动力和更高的传质系数;模型预测值和实验值符合较好,平均误差为12.8%.实验证明复合溶液的传质性能优于单一溶液.