Relationship between paleotemperatures of metamorphic dolomites and ESR determined Mn(II) partitioning ratios

An Electron Spin Resonance (ESR) study of the distribution of Mn(II) between Mg sites and Ca sites in 28 contact metamorphic dolomite samples suggests that the distribution is temperature sensitive. The data can be modelled by alternative interpretations. In the first a polynomial equation approximates the trend of the data suggesting an exponential relation with Mn(II) ratios decreasing to a stable value of 10 with increasing temperature (to near 900°C). The second suggests two groups of dolomites. One group, close to the intrusion (< 100 m), has a low partitioning ratio (10 to 30), possibly increasing linearly with increasing distance from the intrusive contact. The second group (100 to 400 m) increases in scatter and distribution ratio (20 to 215) with increasing distance. Whatever the detailed relationship, we conclude that Mn partitioning is related to the thermal halo of the intrusion and that lower ratios result from higher temperatures. Mn(II) partitioning ratios may yield absolute paleotemperature data when calibrated against other techniques.     

川东南龙王庙组埋藏及混合水白云岩化作用

通过野外调查和地球化学分析,认为四川盆地东南部土河场和南山坪剖面龙王庙组的白云岩不同于区内其他的白云岩。川东南地区龙王庙组白云岩多为回流渗透成因,土河场白云岩则为埋藏白云岩,而南山坪白云岩则为混合水成因。土河场白云岩分布在龙王庙组的下部,不具备形成回流渗透白云岩的地质条件,包体测温显示土河场白云岩的形成温度较高,均在105 ℃以上,其Mn元素和Fe元素含量较高,平均值分别为792.5×10-6和3 428.8×10-6,且具有很好的相关性,δ18O平均为-8.18‰,明显低于研究区其他剖面的白云岩,这些特征均反映了土河场剖面白云岩形成于埋藏环境的特征。南山坪剖面主体处于斜坡相中,也不具备形成回流渗透白云岩的地质条件。南山坪白云岩具有明显的低Na元素的特征,δ18O也明显偏负,显示其形成于温度相对较低的低盐度流体环境中,此外,南山坪白云岩具有明显的U元素富集的特征,指示南山坪白云岩形成与大气淡水有关,为混合水成因的白云岩。这两类白云岩具有相对较好的物性条件,对川东南地区储层发育具有重要意义。     

塔里木盆地下奥陶统白云岩化流体来源的地球化学分析

塔里木盆地是中国重要的含油气盆地,其中奥陶系白云岩是主要储层之一,然而有关白云岩成因的问题众说纷纭,其中的关键是对于白云岩化流体性质的认识不一。元素地球化学和同位素测试分析表明,白云岩的稀土元素来源大部分继承原始灰岩,具有与海水类似的配分特征,只不过稀土元素的含量明显增高了;Sr、Ti含量和Sr/Ba比值较高,且Sr和Mn都具典型的埋藏演化特征;碳、氧同位素分布于正常海相范围内,与典型的埋藏白云岩特征类似;在局部发育一些与断裂相关的铁(锰)白云岩和鞍状白云岩,显示明显的Eu正异常,具相对较高的Fe-Mn-Ba-Si(-Zn-Pb)元素含量及Sr/Ba比值。分析结果说明塔中和塔北下奥陶统的白云岩化流体主要为正常或浓缩了的海水,白云岩形成于准同生和/或埋藏环境,局部发育与断裂相关的热液白云岩,而前人强调的大气淡水或混合水作用对白云岩的形成并不重要。     

塔里木盆地北部丘里塔格群(寒武系至奥陶系)白云岩的成因

本文通过详细岩石学及地球化学研究,探讨了塔里木盆地丘里塔格群(寒武至奥陶系)白云岩的成因。研究表明藻纹层白云岩、微晶白云岩及颗粒白云岩中的颗粒为近地表准同生白云化的产物。结晶白云岩(细晶以上)及颗粒白云岩中的中粗晶白云岩胶结物是深埋藏成岩环境的产物。并对埋藏白云化的镁离子来源及搬运机理进行了探讨。     

Groundwater dolocretes from the Upper Triassic of the Paris Basin, France: a case study of an arid, continental diagenetic facies

Thick dolomite-cemented horizons (dolocretes) occur within a fluvial sandstone-mudstone sequence of Late Triassic age in the western part of the Paris Basin, France. Two types of dolomites can be distinguished: (a) nodular dolomitic beds less than a few metres thick, which formed within mottled overbank siltstones and mudstones; and (b) massive dolomite up to 16 m thick, which occurs in coarse grained channel sandstones and conglomerates. The majority of the dolomite consists of a finely crystalline groundmass of dolomicrospar and, less commonly, dolomicrite. Glaebules, irregular spar-filled cracks, spheroidal dolomite, silicification and vuggy porosity are locally abundant in the massive dolomite. In contrast, biologically induced micromorphological features such as rhizocretions and alveolar-septal fabrics were observed in the thin, nodular dolomite beds. The dolomite is near stoichiometric, well ordered and non-ferroan. 18O values range from ?7·7 to ?0·4%o PDB and 18O values range from ?5·1 to + 1·8%0 PDB and no obvious difference in the stable isotopic composition between both types of dolomites was observed. Sr isotope ratios range from 0·7101 to 0·7126 and are invariably higher than the contemporary Triassic sea water. A vadose—pedogenic origin for the thin dolocrete layers is indicated by the occurrence of rhizocretions and other biological structures. Several features, however, argue against a pedogenic origin for the massive carbonates, most notably the absence of biologically induced structures, the occurrence in coarse grained channel (and not overbank) deposits, and the great thickness. These units are thus interpreted as groundwater in origin. Phreatic calcretes of Quaternary age, widespread in inland Australia, are regarded as a modern analogue for the Triassic Paris Basin dolocretes. Petrographic observations argue in favour of primary (proto)dolomite precipitation, although early diagenetic replacement of calcite by (proto)dolomite cannot be ruled out. Strontium and carbon isotope data of early diagenetic dolocrete cements and oxygen isotope data of early diagenetic silica indicate an entirely non-marine, continental origin for the groundwaters. The poorly ordered and non-stoichiometric protodolomite probably underwent stabilization upon further burial resulting in a near-stoichiometric, well ordered dolomite that clearly lacks evidence for pervasive recrystallization.     

Dolomites in the Tazekka Pb–Zn district, eastern Morocco: polyphase origin from hydrothermal fluids

Many different types of water and processes have been proposed for the formation of dolomites. The three phases of hydrothermal dolomites in the Middle Atlas Causse were investigated to elucidate their formation processes. The first two of these are associated with sphalerite and galena in stratiform and open space-filling deposits. These formed early in the history of the deposition of the Pb–Zn mineralization and commonly reveal a paragenetic overlap. A later phase, post-dating Pb–Zn mineralization, is reflected in saddle dolomite.
All three phases show a decrease in δ¹⁸O and δ¹³C values passing from sterile (unmineralized) to mineralized rocks, and isotopic signatures are independent of the carrier facies. However, early-formed dolomites can be separated into two distinct groups on the basis of δ¹⁸O values. Type 1 dolomites host stratiform ore deposits, whereas type 2 dolomites host an open space-filling ore-body. Later saddle dolomites are more depleted in ¹⁸O than either of these.
The early hydrothermal and saddle dolomites precipitated from similar fluids during three distinct events, but formed by two mechanisms: replacement (hydrothermal dolomite) and cement precipitation (saddle dolomite). They show different isotopic signatures and apparently formed at different temperatures. Field data, petrographic and stable isotope results suggest a continuum of replacement, during the Carixian for the early hydrothermal dolomite 1, and during the Toarcian for early hydrothermal dolomite 2, followed by a cement precipitation phase for saddle dolomite.     

白云石成因研究新方法--白云石晶体结构分析

传统的白云石研究方法对于白云石成因分析具有多解性,对于已有白云石成因模式的套用或重新建立新的白云石成因模式将白云石的形成机理过于简单化、模式化。白云石的晶体结构保存了晶体的形成环境、结晶速度、晶体生长与变化特征、流体特征的证据,白云石晶体结构分析是进行白云石成因分析的有效手段,之前很少有研究者从晶体结构角度进行白云石成因分析。在岩石学和地球化学研究的基础上,本文对四川盆地灯影组-寒武系鞍状白云石、纤状白云石、残余颗粒细晶白云石、孔洞充填粗晶白云石和泥晶白云石五种白云石进行了微组构取样,并利用X衍射仪、透射电镜等晶体结构研究手段,从晶体结构角度对五种白云石组构的有序度、晶胞参数、晶格条纹、晶面间距、晶格缺陷等晶体结构参数进行了差异性研究,分析了它们不同的形成环境和成岩演化特征,初步建立了不同类型白云石晶体结构判识标志。     

川中磨溪—高石梯地区栖霞组白云岩特征及成因机制

川中磨溪—高石梯地区栖霞组发育滩相白云岩,目前对滩相中差异白云石化机理不明确,导致难以预测优质白云岩储层的分布。在岩石学和地层特征研究基础上,通过分析不同类型白云岩的微量元素及碳、氧、锶同位素特征,结合颗粒滩类型和构造背景,系统研究了该区不同类型白云岩的成因机理及模式。结果显示:研究区栖霞组白云岩中白云石以细晶为主,中晶和粗晶次之,晶形多为半自形—自形。白云岩具有明显的残余颗粒结构,表明原始岩性为颗粒灰岩。细晶、细—中晶白云岩的阴极发光整体较暗,呈暗红色至红色,稀土元素配分模式与同期灰岩相似,白云岩的87Sr/86Sr比值大部分落于二叠纪海水的87Sr/86Sr比值范围之内,表明白云岩的成岩流体与海水沉积的灰岩具有同源性。白云岩的δ13C值（3.73‰~4.19‰）与同期灰岩δ13C值（3.61‰~4.93‰）相近,表明白云岩与灰岩具有一致的碳源。从灰岩到白云岩,Sr含量明显减少且Mn含量有所增加,说明灰岩经过一定的成岩作用被交代形成白云岩,该类白云岩为埋藏条件下地层中富Mg2+的流体交代孔隙型颗粒灰岩而成;中—粗晶白云岩的阴极发光呈红色,具明显环带特征,且具有高的Mn含量、低Sr/Ba比值及铕的正异常,87Sr/86Sr比值高于同期海水值,δ18O值在-8.06‰~-8.52‰,为颗粒灰岩在埋藏期受持续、充足的云化流体供给而成,较高的包裹体均一温度和δ18O值明显偏负均指示埋藏白云化作用过程还受到局部高温的影响。总体而言,埋藏白云岩化是该区白云岩的主要成因,地层中富镁的流体在压力和热对流的双重影响下进行迁移,促进白云岩化流体的运移,但局部地区鞍形白云石的形成遭受了后期不同程度的热液改造作用。     

川东北上二叠统长兴组白云岩地球化学特征及形成机制

四川盆地东北部长兴组储集层主要由细—中晶白云岩组成,其次为微晶白云岩。根据薄片观察、阴极发光、电子探针分析发现,细—中晶白云岩与微晶白云岩在阴极发光特征方面很相似,都不发光,且在Mg、Ca、Fe、Mn、Sr和Ba含量方面也没有区别。根据上述分析结果认为,研究区的细—中晶白云岩是微晶白云岩在准同生期重结晶形成的,控制重结晶的主要因素是引起准同生白云石化的蒸发卤水下渗。这一认识为确定研究区白云岩储集层的空间分布提供了新的思路。     

Reactive transport modelling of reflux dolomitization in the Arab‐D reservoir,Ghawar field,Saudi Arabia

It has long been recognized that the Arab‐D reservoir in Ghawar field has been significantly dolomitized and that the distribution of dolomites is highly heterogeneous across this reservoir. Previous studies indicated that dolomite occurs with either a stratigraphic or non‐stratigraphic distribution; when mapped, dolomite tends to form several parallel linear trends across the field. Although stratigraphic dolomite was suggested to be formed early from highly evaporated pore fluids sourced from overlying evaporite deposits, non‐stratigraphic dolomite was thought to be generated primarily from hydrothermal fluids sourced from below. This study focuses primarily on these non‐stratigraphic dolomites, and proposes that: (i) these dolomites initially formed via seepage reflux, but were reinforced by late stage hydrothermal dolomitization; and (ii) reflux is also responsible for the formation of parallel, linear trends of dolomite. The reflux model hypothesizes that an evaporative lagoon (which is the source of dolomitizing fluids) formed during the falling stage systems tract of a depositional sequence, and that with continuing sea‐level fall this lagoon migrated progressively towards deeper parts of an intrashelf basin adjacent to the Ghawar field, leaving behind lines of dolomite bodies along a series of temporary coastlines. Two‐dimensional reactive transport models have been built to test this hypothesis, and have resulted in a predicted pattern of dolomite bodies that agrees with both the observed vertical distribution of non‐stratigraphic dolomite, as well as the mapped lateral distribution of the dolomite trends. In addition, the major ion compositions of Late Jurassic seawater are calculated based on fluid inclusion data in the literature. Using Jurassic seawater in current models leads to the absence of anhydrite cements and less potential of over‐dolomitization than using modern seawater.     

川东三叠系飞仙关组白云岩锶含量、锶同位素组成与白云石化流体

川东飞仙关组白云岩包括微晶白云岩、具原始结构的粒屑白云岩和结晶白云岩等3种主要的结构类型,其中结晶白云岩是重要的天然气储集岩。根据白云岩的锶舍量和锶同位素组成,结合相关岩石学和地球化学资料,本文研究了白云石化过程中锶的迁移和相应的同位素变化。三种类型白云岩具有类似的锶含量,但其(87)~Sr/(86)~Sr 比值均不同程度地高于同期海水值,锶在白云石和方解石(或文石)中分配系数的差别是影响白云石化过程中白云石锶含量最为重要的因素。不同流体中锶的混合方程计算表明:如果白云石化流体是大气淡水和海水的混合流体,则结晶白云岩的白云石化流体相当于94%的大气淡水和6%的海水混合,具原始结构的粒屑白云岩的白云石化流体相当于81%的大气淡水和19%的海水混合,微晶白云岩的白云石化流体相当于92%的大气淡水和8%的海水混合。但极低的锰含量、相对较高的锶含量和包裹体均一化温度等资料均不支持有94%的大气淡水参与了结晶白云岩的白云石化作用,其白云石化流体应是埋藏成岩过程中囚禁的近同期、但是非同期的海源流体,其来源可能与埋藏成岩过程中该时间段蒸发盐的溶解有关。锰含量、锶含量、(87)~Sr/(86)~Sr 比值都表明具原始结构的粒屑白云岩和微晶白云岩的白云石化过程都存在大气淡水的介入,微晶白云岩的白云石化可能与潮坪环境的蒸发泵机理有关;具原始结构的粒屑白云岩的白云石化可能与混合水白云石化作用有关,这类白云岩分布于向上浅滩化旋回滩体的顶部,这是埋藏前或浅埋藏阶段大气淡水与海水混合白云石化作用最容易发生地带。     

塔里木盆地顺南501井鹰山组白云岩储层特征与成因

塔里木盆地顺南地区多口钻井揭示在白云岩储层中天然气富集成藏,但白云岩储层的成因存在争议。顺南501井鹰山组取芯段发育白云岩储层,为研究该地区白云岩储层成因提供了条件。通过岩芯观察与描述、显微岩石学、成岩作用与序列研究、基于铸体薄片的孔隙图像分析、计算机断层扫描、电子探针背散射成像与微量元素Fe、Mn定量、流体包裹体等技术手段,研究了白云岩储层特征与成因。结果表明,白云岩储层类型为裂缝-孔隙型,主要储集空间为裂缝-扩溶缝、晶间孔-晶间溶孔,孔隙发育与裂缝具有明显相关关系。热液矿物萤石与方解石呈共生关系充填于裂缝与孔隙空间。裂缝与孔隙附近的白云石、白云石环边以及与萤石共生的方解石均具有较高的FeO、MnO含量。萤石发育成群无色透明盐水包裹体,均一温度为165℃~175℃、盐度为15.5~17.5 wt.% NaCl equiv.。热液流体活动对围岩的改造导致局部方解石、白云石富Fe2+、Mn2+,同时提供了萤石结晶所需要的F-。一方面热液流体改造白云岩形成储集空间,另一方面以萤石与方解石为代表的热液矿物则充填裂缝与孔隙。因此,构造-热液流体活动在一定程度上影响了白云岩储集空间的形成。     

鄂尔多斯盆地伊陕斜坡东北部马家沟组马五5亚段白云岩地球化学特征及其成因

鄂尔多斯盆地伊陕斜坡东北部奥陶系马家沟组马五₅亚段优质白云岩储层发育,多口井在该层系钻获高产工业气流,展现出巨大的天然气勘探潜力,而关于该层系白云岩储层的成因机理至今未达成共识.为此,在岩石学特征分析基础上,通过对白云岩碳、氧、锶同位素及微量元素等测试资料的系统分析,深入探讨了鄂尔多斯盆地伊陕斜坡东北部马五₅亚段白云岩的成因机理.结果表明:研究区马五₅亚段主要发育泥、粉细晶白云岩和豹斑灰云岩3种类型,前者主要发育于马五₅亚段底部,后两者主要发育于马五微晶白云岩₅亚段中上部,是主要的天然气储集体;粉细晶白云岩和豹斑灰云岩白云石有序度均较低,平均值分别为0.86、0.68,δ13C值多数与同期海水一致,δ18O值均显著偏负;多数粉细晶白云岩87Sr/86Sr值较同期海水显著偏正,豹斑灰云岩与同期海水一致;总体具有高Fe、Mn、Na、K和低Sr含量特征,豹斑灰云岩Fe、Mn、Na含量介于泥晶灰岩与粉细晶白云岩之间;稀土元素含量总体较低,且稀土元素配分模式相似,轻稀土元素富集,重稀土元素亏损,具明显Eu负异常和弱Ce正异常.综上认为研究区白云石化流体主要为海源性流体,早期可能有大气淡水的混入,两类优质白云岩均应形成于局限台地潮间-潮下带环境中的浅埋藏期回流渗透作用阶段.基于上述岩石学和地球化学特征,建立了研究区马五₅亚段纵向的沉积与成岩序列模式,为研究区优质白云岩储层的预测提供了理论依据.      

Early and pervasive dolomitization by near-normal marine fluids: New lessons from an Eocene evaporative setting in Qatar

The upper Palaeocene–lower Eocene Umm er Radhuma Formation in the subsurface of Qatar is dominated by subtidal carbonate depositional packages overlain by bedded evaporites. In Saudi Arabia and Kuwait, peritidal carbonate depositional sequences with intercalated evaporites and carbonates in Umm er Radhuma have been previously interpreted to have been dolomitized via downward reflux of hypersaline brines. Here, textural, mineralogical and geochemical data from three research cores in Qatar are presented which, in contrast, are more consistent with dolomitization by near-normal marine fluids. Petrographic relationships support a paragenetic sequence whereby dolomitization occurred prior to the formation of all other diagenetic mineral phases, including chert, pyrite, palygorskite, gypsum, calcite and chalcedony, which suggests that dolomitization occurred very early. The dolomites occur as finely crystalline mimetic dolomites, relatively coarse planar-e dolomites, and coarser nonplanar dolomites, all of which are near-stoichiometric (50.3 mol% MgCO₃) and well-ordered (0.73). The dolomite stable isotope values (range −2.5‰ to +1‰; mean δ¹⁸O = −0.52‰) and trace element concentrations (Sr = 40 to 150 ppm and Na = 100 to 600 ppm) are compatible with dolomitization by near-normal seawater or mesohaline fluids. Comparisons between δ¹⁸O values from Umm er Radhuma dolomite and the overlying Rus Formation gypsum further suggest that dolomitization did not occur in fluids related to Rus evaporites. This study provides an example of early dolomitization of evaporite-related carbonates by near-normal seawater rather than by refluxing hypersaline brines from overlying bedded evaporites. Further, it adds to recent work suggesting that dolomitization by near-normal marine fluids in evaporite-associated settings may be more widespread than previously recognized.     

Chemical controls of cathodoluminescence of natural dolomites and calcites: new data and review

ABSTRACT Calcites and dolomites from the late Precambrian Bonahaven Formation of Scotland exhibit luminescence when MnCO₃>0.03 wt % (dolomite) or >0.06 wt % (calcite) and FeCO₃<2-2-5 wt % (dolomite). Comparison with other published data shows close similarity in the position of Fe-quenching in dolomite, but more variability in the position of Mn-activation in calcites and dolomites and the onset of Fe-quenching in calcites. These anomalies are thought to relate to chemical controls subsidiary to the dominant factors of Fe and Mn concentration. It is not practical to make a useful comparison between operating conditions of different luminescence instruments because of differences in design and an inability to measure routinely the current actually on the specimen surface.     

Some aspects of the Krol formation of the Himalaya,India

The Lower Krol sediments consist of intercalations of dolomite with shales in the marginal areas (Solan and Nainital), while limestones are interbedded with marls in the central part of the basin (Massoorie). The Upper Krols are largely composed of dolomites with subordinate limestones and shales.The non-carbonate detrital fraction is dominated by quartz with minor amounts of orthoclase, microcline and plagioclase feldspars. Illite and chlorite constitute the dominant clay minerals, lesser amounts of corrensite and kaolinite are sometimes present. An eastward increase in illite and decrease in chlorite has been ascribed to the supply and distribution of the terrigenum.Zirconium, rubidium, strontium, zinc, nickel and manganese were determined by X-ray fluorescence. Early diagenetic dolomites contain Sr, Zn, Ni and Mn in trace amounts, while the late diagenetic dolomites are characterized by an absence of these elements. The posttectonic dolomites are unusually rich in iron, manganese and sometimes in zinc.Authigenic formation of alkali feldspars, chlorite, illite, quartz and pyrite is not uncommon. The feldspars appear to have formed at early and late diagenetic stages. Potash feldspars dominate over albite in association with dolomite, whereas albite tends to be more common in the limestones.The Krol sedimentation seems to have started in a shallow coastal lagoon behind a barrier beach, upwards changing into tidal-flat deposits.     

西沙群岛西科1井中新统-上新统白云岩微观特征及成因

西科1井白云岩主要分布于上中新统黄流组, 在上新统莺歌海组二段和中中新统梅山组有零星分布; 主要的白云岩层段一般发育在褐色铁质矿物浸染的古暴露面之下.根据岩石铸体薄片观察、阴极发光及扫描电镜测试分析, 西科1井白云岩中白云石总体上呈微晶及细粉晶双峰态结构, 微晶白云石为灰岩基质经选择性白云石化的结果, 呈平直晶面半自形晶, 主要为泥微晶基质白云石化的结果; 粉晶-细晶白云石呈平直晶面自形晶, 为胶结物白云石或过度白云化结果, 过度白云化雾心亮边白云石的"亮边"与胶结物白云石成分一致, 阴极发光下二者显示同样的光性特征.微量元素测试及碳氧同位素测试表明: 白云岩一般具有低铁、低锰含量, δ18O_PDB均为正值, 变化于2.293‰~5.072‰之间, δ13C_PDB变化于1.214‰~3.051‰之间; 西科1井白云岩与西琛1井白云岩具有相似的层位分布特征和碳、氧同位素特征, 可能反映着相同或相似的成因.回流渗透模式可能适用于西沙地区白云岩, 频繁的海平面升降、环礁内蒸发环境及与中新世末期构造运动有关的热流体上涌促进了西沙地区白云岩的形成, 高渗透性礁相碳酸盐岩沉积为高Mg/Ca比值的蒸发水回流渗透提供了运移通道.      

塔里木盆地东部地区寒武纪海盆局限期深水准同生白云岩化作用研究

塔东地区寒武纪盆地相以及斜坡相发育泥晶白云岩及泥质泥晶白云岩,具有深水环境标志。通过样品岩石学特征研究、碳、氧同位素分析、有序度分析、锶同位素比值分析以及阴极发光特征分析,提出了塔东地区海盆局限期海水咸化深水准同生白云化机理。海盆局限阶段水体盐度变高,使得斜坡以及海底松软碳酸盐沉积物发生白云石化形成深水环境的泥粉晶白云...     

渤海沙西北构造带下古生界碳酸盐岩潜山白云岩形成机制研究

通过岩心薄片、扫描电镜、碳氧锶稳定同位素、X衍射有序度及微量元素特征分析,系统研究了渤海湾盆地沙西北 构造带碳酸盐岩潜山白云岩的地球化学特征及成因机制。结果表明,沙西北构造带下古生界白云岩可划分为泥晶白云岩、 颗粒白云岩、泥质/灰质白云岩和鞍状白云岩四类,各类白云石特征差异明显。泥晶和颗粒白云岩δ18O大于-7‰,87Sr/86Sr值 与海水值接近,为0.7090~0.7120,Na2O含量较高,大于0.06%,有序度偏低,薄片中可见石膏,为准同生成因。泥质/灰质 白云岩为细晶结构,δ18O偏负,为-8‰~-10‰,87Sr/86Sr为0.7120~0.7140,Na2O含量降低,有序度变大,镜下见次生加大亮 边,为埋藏成因。鞍状白云岩为中粗晶结构,贫δ18O,87Sr/86Sr较高,薄片中见辉绿岩,为热液成因。本区白云岩以准同生 和埋藏成因为主,局部沿断裂可能存在热液成因。奥陶系沉积时期主要发生埋藏白云石化和溶蚀作用,是增加白云岩有效 孔隙的重要阶段,为优质储层形成起到了建设性作用。     

四川盆地西南中二叠统白云岩的地球化学特征及其成因

白云岩储层是碳酸盐岩油气领域的研究热点.在分析白云岩优质储层孔-洞-缝演化过程中,白云岩成因是重要的研究内容.以四川盆地西南间断出露的中二叠统栖霞组地层为研究对象,采用岩相学、X粉晶衍射及地球化学方法,讨论白云岩成因.白云岩野外发育于断裂破碎带周围,透镜状产出,多呈斑马纹状构造.显微镜下白云石鉴定为鞍状白云石.此外,白云岩具有较高的白云石有序度,地球化学特征则表现为明显偏负的氧同位素值和高锶同位素值.综合地质资料分析,白云岩为构造热液白云岩化成因.