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1.
Accelerator mass spectrometry gives the following 10Be contents (dpm/kg) for the SNC meteorites: Shergotty, 13.0 ± 1.5 and 17.3 ± 2.7; Zagami, 18.6 ± 2.5 and 20.0 ± 3.2; ALHA 77005, 15 ± 3; EETA 79001A, 7.8 ± 1.1 and 6.3 ± 0.5; EETA 79001B, 8.5 ± 1.1; Nakhla, 19.7 ± 3.3; Lafayette, 18.1 ± 2.5; Governador Valadares, 25.6 ± 3.6; Chassigny, 20.5 ± 3.1. The 10Be contents of the NC meteorites indicate that significant accumulation of cosmogenic nuclides occurred in decimeter rather than planetary-size bodies. The agreement of the 3He, 21Ne, and 10Be exposure ages of the shergottites also supports small-body irradiation. A long terrestrial age for EETA 79001 appears unlikely.  相似文献   

2.
Cosmogenic 26A1 activities have been measured by γ-γ coincidence counting in the three ureilites which had not previously been studied. The values in dpm/kg are: Dingo Pup Donga, 38.4 ± 2.4; North Haig, 39.3 ± 4.8; Dyalpur, 55.8 ± 4.8. Five of the six known ureilites thus have lower 26A1 contents, 63 per cent to 77 per cent, than the calculated saturation values, in marked contrast to most other stony meteorites. This cannot be attributed to short cosmic ray exposure ages. Nor do size and depth effects account for the narrow range of 26A1 activities, because a nuclear particle track study indicates that preatmospheric radii were highly variable, from ≥ 40 cm for Goalpara to only a few cm for Dingo Pup Donga. By default, the most likely explanation is that the ureilites had much smaller or much larger orbits than all other stony meteorites.  相似文献   

3.
We have determined the production rate of in situ-produced 10Be in calcite through measurements of 10Be and 36Cl concentrations in the same calcite samples and of 10Be concentrations in depth profiles of flint from the same erosional surface. This yields a 10Be production rate in calcite of 37.9 ± 6.0 at/g/yr at sea level and high latitude, approximately sixfold higher than production in the coexisting flint. We propose that this higher rate of production may be due to high production cross sections for C spallation by cosmic rays with energies below 50 MeV. These results also open the possibility of dating burial events in carbonate-rich environments by differential radioactive decay of 10Be and 36Cl.  相似文献   

4.
We present the first comprehensive set of dissolved 10Be and 9Be concentrations in surface waters and vertical profiles of all major sub-basins of the Arctic Ocean, which are complemented by data from the major Arctic rivers Mackenzie, Lena, Yenisey and Ob. The results show that 10Be and 9Be concentrations in waters below 150 m depth are low and only vary within a factor of 2 throughout the Arctic Basin (350-750 atoms/g and 9-15 pmol/kg, respectively). In marked contrast, Be isotope compositions in the upper 150 m are highly variable and show systematic variations. Cosmogenic 10Be concentrations range from 150 to 1000 atoms/g and concentrations of terrigenous 9Be range from 7 to 65 pmol/kg, resulting in 10Be/9Be ratios (atom/atom) between 0.5 and 14 × 10−8. Inflowing Atlantic water masses in the Eurasian Basin are characterized by a 10Be/9Be signature of 7 × 10−8. The inflow of Pacific water masses across the Bering Strait is characterized by lower ratios of 2-3 × 10−8, which can be traced into the central Arctic Ocean, possibly as far as the Fram Strait. A comparison of the high dissolved surface 10Be and 9Be concentrations (corresponding to low 10Be/9Be signatures of ∼2 × 10−8) in the Eurasian Basin with hydrographic parameters and river data documents efficient and rapid transport of Be with Siberian river waters across the Siberian Arctic shelves into the central Arctic Basin, although significant loss and exchange of Be on the shelves occurs. In contrast, fresh surface waters from the Canada Basin also show high cosmogenic 10Be contents, but are not enriched in terrigenous 9Be (resulting in high 10Be/9Be signatures of up to 14 × 10−8). This is explained by a combination of efficient scavenging of Be in the Mackenzie River estuary and the shelves and additional supply of cosmogenic 10Be via atmospheric fallout and melting of old sea ice. The residence time of Be in the deep Arctic Ocean estimated from our data is 800 years and thus similar to the average Be residence time in the global ocean.  相似文献   

5.
Controlled laboratory experiments have been used to study the diagenetic chemistry of 239,240Pu 137Cs, and 55Fe. Experiments using Buzzards Bay sediments in small tanks show that sulfate reduction is accompanied by the production of large pore water concentration gradients of alkalinity, phosphate, ammonia and dissolved organic carbon and the formation of subsurface maxima in Fe and Mn. These pore water profiles demonstrate that bacterially-mediated processes of organic matter degradation and redox reactions can be simulated in the laboratory.A vertical profile of 55Fe in pore waters is reported for the first time: it follows the profile of stable Fe and as such has a large (200 dpm/100 kg) subsurface maximum between 2–4 cm depth. Comparison of 55Fe/Fe ratios in sediments and pore waters shows that there is preferential solubilization of 55Fe over stable Fe.The pore water activities of 239,240Pu show no gradients within the large uncertainties of the counting statistics, but are two to four times higher than Buzzards Bay seawater (0.05 dpm/100 kg).The activity of 137Cs in the pore water profile is constant (40 dpm/100 kg) within the large counting uncertainties and is twice that of Buzzards Bay seawater. Cs-137 does not appear to be involved in diagenetic chemistry but may increase in pore waters as a result of ion exchange reactions.Flux estimates based on the pore water data show that remobilization and transport of 239,240 Pu in coastal sediments are not significant processes while the transport of l37Cs may be.  相似文献   

6.
The collection of large volumes of pore water (1–2 liters per 2 cm horizon of sediment) and low level radiochemical measurements of 239,240Pu and 137Cs have been combined to produce the first study of these fallout artificial radionuclides in marine pore waters. Profiles from box cores taken in June and September 1982 from Buzzards Bay, Mass., are reported along with profiles of many diagenetic constituents (i.e. SO42?, alkalinity, Fe, Mn, DOC, and nutrients).The 239,240Pu pore water profile is characterized by a subsurface maximum of about 0.28 dpm/100 kg lying between 3–11 cm. Overlying seawater, in contrast, has an activity of 0.01 ± 0.02 dpm/100 kg. Below about 11 cm, the pore water 239,240Pu distribution follows that of the solid phase which decreases rapidly with depth. The pore water profiles of 137Cs are characterized by a broad and deeply penetrating maximum where activities of about 35–40 dpm/100 kg extend from 3 to 20 cm. Overlying seawater, in contrast, has an activity of 17–24 dpm/100 kg. The 137Cs and 239,240Pu pore water data show that there is preferential downward transport of 137Cs and that 239,240Pu does not have an active diagenetic chemistry and is not significantly mobile in these coastal sediments.  相似文献   

7.
The 10Be contents of 28 stony meteorites with known 21Ne contents range from 0.97 to 23 dpm/kg and give an average 21Ne production rate (P21) of (0.28 ± 0.02) × 108 cm3 STP/g-Myr for shielding conditions corresponding to 22Ne21Ne = 1.114 in an H-chondrite. Our P21(10Be) agrees with others' P21 based on 22Na, 81Kr and 53Mn but not on 26A1. Temporal variations in the cosmic ray flux do not explain the disagreement satisfactorily; major errors in the radionuclide half-lives are not indicated. The discrepancy seems rooted in the data selection and the difficulties of making accurate corrections for shielding, chemical composition and other sources of variability.  相似文献   

8.
In order to assess current understanding of meteoric 10Be dynamics and distribution in terrestrial soils, we assembled a database of all published meteoric 10Be soil depth profiles, including 104 profiles from 27 studies in globally diverse locations, collectively containing 679 individual measurements. This allows for the systematic comparison of meteoric 10Be concentration to other soil characteristics and the comparison of profile depth distributions between geologic settings. Percent clay, 9Be, and dithionite-citrate extracted Al positively correlate to meteoric 10Be in more than half of the soils where they were measured, but the lack of significant correlation in other soils suggests that no one soil factor controls meteoric 10Be distribution with depth. Dithionite-citrate extracted Fe and cation exchange capacity are only weakly correlated to meteoric 10Be. Percent organic carbon and pH are not significantly related to meteoric 10Be concentration when all data are complied.The compilation shows that meteoric 10Be concentration is seldom uniform with depth in a soil profile. In young or rapidly eroding soils, maximum meteoric 10Be concentrations are typically found in the uppermost 20 cm. In older, more slowly eroding soils, the highest meteoric 10Be concentrations are found at depth, usually between 50 and 200 cm. We find that the highest measured meteoric 10Be concentration in a soil profile is an important metric, as both the value and the depth of the maximum meteoric 10Be concentration correlate with the total measured meteoric 10Be inventory of the soil profile.In order to refine the use of meteoric 10Be as an estimator of soil erosion rate, we compare near-surface meteoric 10Be concentrations to total meteoric 10Be soil inventories. These trends are used to calibrate models of meteoric 10Be loss by soil erosion. Erosion rates calculated using this method vary based on the assumed depth and timing of erosional events and on the reference data selected.  相似文献   

9.
晚更新世黄土堆积物中的10Be记录   总被引:5,自引:1,他引:5       下载免费PDF全文
给出西峰黄土剖面0.15Ma以来10Be浓度、CaCO3含量、粒度分布和有机质含量曲线。通过与深海沉积物δ18O曲线拟合,建立了西峰黄土剖面10Be时标,并与洛川黄土剖面10Be记录进行了对比研究。进一步计算了黄土堆积速率及10Be沉降量。  相似文献   

10.
The radioisotope 10Be has been used as a tracer to evaluate subduction and recycling of sediments in island arcs. As a cosmogenic isotope strongly enriched in oceanic sediments, it is especially suitable for monitoring sediment subduction.We report here 10Be results for 106 arc volcanic rocks and 33 basalts from mid-ocean ridges, oceanic islands, continental rifts, and continental flood basalt provinces. The 33 basalts from non-arc environments all contain < 1 × 106 atom/gram (g−1) and form a reference or “control group” against which the arc data may be compared. Lavas from the Sunda, Mariana and Halmahera arcs, each with 12 samples, are indistinguishable from the control group. Nine samples from Japan range from 0.1 × 106 to 13.5 × 106 g−1 of 10Be. Lavas from the Aleutians and Central America (excluding Costa Rica) consistently have 10Be contents greater than those of the control group, extending to 15.3 × 106 g−1 for the Aleutians and 24 × 106 g−1 for Central America. Both the Japan and Central American arcs show a geographic variation in 10Be abundances; the Aleutian arc does not.Conceptually, four models may be used to explain the incorporation of 10Be in island arcs. Model 1 is the limiting case calculation presented in Brownet al. (1982). Physically, it corresponds to an assumption that all 10Be in the uppermost sediment layers is carried to depth, the 10Be is mechanically decoupled from the sediment pile and is added to the arc magma source region. This model results in the highest calculated 10Be contents in arc lavas. In the more physically reasonable Model 2, the 10Be-rich upper sediments are assumed to mix with the deeper, 10Be-poor, sediments and the sediments are subsequently incorporated into the source region. Model 3 assumes 10Be to be incorporated from sedimentary layers encountered during magma ascent. In Model 4 only sediments contained within grabens in the downgoing slab may be subducted. As yet insufficient data exist to permit conclusive evaluation of these models, but correlations between 10Be contents in arc volcanic rocks and recent sedimentation rates and sediment thickness, measured outboard of the trench, suggest that Model 2 may be the most important mechanism for 10Be incorporation in many island arcs.  相似文献   

11.
宇宙成因核素10 Be(半衰期1.5Ma)不但是古环境变化的示踪剂,而且具有确定地质年龄的能力。80个全岩样品的10 Be和化学分析数据表明,黄土高原约6Ma以来的红粘土和黄土序列中年龄校正的10 Be浓度与沉积物粒度和风化程度的化学指标具有显著的关系。根据这种关系建立的10 Be浓度与化学指标的经验回归线性模型,可以估计红粘土和黄土形成时的10 Be浓度,确定红粘土和黄土形成的10 Be放射性年龄。  相似文献   

12.
东北四海龙湾玛珥湖沉积物纹层计年与137Cs、210Pb测年   总被引:15,自引:6,他引:15       下载免费PDF全文
对东北四海龙湾玛珥湖SHLF6孔纹层沉积物的137Cs放射性测量表明:137Cs比活度的最大值出现在55cm处,对应于1963年世界原子弹试爆高峰期。纹层计年表明0~6cm共有35个纹层层偶。从75cm到65cm,137Cs比活度从256±009dpm/g急剧增加到1868±017dpm/g,可能65cm对应于1954年。通过测量226Ra子核214Pb和214Bi(能量为295keV,352keV和609keV)放射的光子数获得226Ra比活度数据,然后求得过剩210Pb比活度(210Pbuns)。210Pbuns比活度随深度增加而呈指数衰减,其异常波动可能与人类活动以及沉积速率变化有关,例如55cm处210Pb比活度较高,与137Cs的峰值对应,这可能与1963年前后人工核实验的高峰有关,因为核试验不仅产生137Cs,而且可以产生208Pb和210Pb;45cm处210Pb比活度较低,而226Ra较高,可能与人类活动加剧,导致沉积速率增加有关。根据210PbunsCRS模式,SHLF6孔0~19cm的平均沉积速率为20mg/cm2·a,或约为011cm/a。210Pb测年数据与137Cs时标及纹层计年均有很好的一致性。四海龙湾玛珥湖发育的纹层为年纹层,可以建立高分辨率时间序列。  相似文献   

13.
An integrated study of the cosmic ray exposure history of the San Juan Capistrano meteorite was carried out using measurements of rare gas isotopic abundances, particle track densities and radioisotope concentrations. Spallation systematics determined for Kr isotopes in lunar samples are shown to be valid also for the San Juan Capistrano and St. Severin meteorites, thus allowing us to determine a reliable 81Kr/83Kr production ratio as needed for applying the 81Kr-Kr dating method. The 81Kr-Kr age of SJC is 28.7 ± 2.0 Myr, about 35% longer than ages determined by spallation He or Ne. The minimum observed track production rate (2.6 × 105 tracks/cm2 · Myr) sets a minimum of 8 cm for the preatmospheric radius of an assumed spherical body. Track density gradients and the low 60Co activity (<2.9 dpm/g Co) both set an upper limit of 10 cm to the radius. Track results show that ablation losses have averaged 6cm. The relative spallation yields of 78Kr and 83Kr, and the ratios 3He/21Ne and 22Ne/21Ne are all compatible with a hard irradiation as would be experienced by a sample depth of about 6 cm in a body of 8–10 cm. The low activities of 54Mn, 22Na and 26Al are also consistent with these irradiation conditions.  相似文献   

14.
We report in this study the distribution of10Be in the top 40 m of the Renland ice core (East Greenland) and in a 30 m long core from DML (Dronning Maud Land, Antarctica) for the period 1931–1988. The two sites show differences in10Be content, the Antarctica site showing smaller variance and a lower average10Be annual flux. Similarly, the average accumulation rate (cm water equivalent year−1) is higher in the Renland relative to DML. The variability in accumulation (precipitation) rates seems to explain part of the difference in10Be flux between the two polar sites. Cyclic fluctuations of10Be flux correlate with the 11-year sunspot number and cosmic ray intensity than with the aa index (perturbation of the geomagnetic activity by the solar wind). Our data corroborate10Be cyclic fluctuation pattern from the Dye 3 ice core and confirm a promising potential for correlation of global and local events.  相似文献   

15.
任静  李超  刘宇平  武振坤  任磊 《岩矿测试》2018,37(3):275-282
经历反复埋藏暴露演化过程的河流阶地样品,难以用常规方法将原生宇宙核素10Be、26Al有效分离。本文在前人实验方法基础上,使用人工挑选、磁选仪分选及酸洗方法,分离样品中碳酸盐、含铁矿物及大气生成的10Be,进一步优化了石英提纯实验流程。结果表明:长度为9 cm、内径为1 cm的阴离子交换树脂装置匹配4 mol/L氢氟酸淋滤液,可将B、Mg、Ca、Cr、Fe、Mn、Ni、Ti和Be、Al有效分离,Be、Al回收率分别可达95.7%、85.7%。阳离子交换树脂能有效分离Be、Al,两元素回收率均达到85%。获得10Be/9Be和26Al/27Al流程空白分别为2.19×10-15和1.63×10-15。优化后的实验方法显著提高了河流阶地样品中原生宇宙核素10Be、26Al的纯化效率,且10Be/9Be和26Al/27Al流程空白数值与国内外实验室具有可比性。采用本方法获得了成都平原冲积物10Be、26Al暴露年龄分别是76.36±9.51 ka和69.44±14.13 ka,为评价龙门山前缘隐伏断裂构造特征和活动性提供了年代学依据。  相似文献   

16.
Surface sediments of the Washington coast have 210Pb activites which average 104 ± 48dpm/g for submarine canyon and slope regimes and 18 ± 12dpm/g for the continental shelf regime. 210Pb sedimentary fluxes are also higher in canyons, averaging 18 ± 13dpm/cm2 per yr, compared to 5.2 ± 3.1 dpm/cm2 per yr for slope and 4.8 ± 1.8dpm/cm2 per year for shelf regions. These 210Pb activities and fluxes are 2–7 times greater than those reported for other coastal regions. Inputs from the atmosphere and the Columbia River are not sufficient to supply the 210Pb, but advection of seawater containing dissolved 210Pb produced in situ from 226Ra provides an input several times larger than the sedimentary fluxes. The sedimentary 210Pb flux is limited by scavenging reactions rather than by supply of dissolved 210Pb.Calculations of maximum biological uptake and fluxes of 210Pb and ‘selective’ chemical leaching experiments all show that the primary scavenging processes are due to hydrous Mn and Fe oxides rather than biological phases. The pattern of higher 210Pb depositional fluxes in canyons than in nearby open slope areas of comparable water depth is most reasonably explained by enhanced scavenging of dissolved 210Pb near the sea floor, rather than by processes operating throughout the water column. Relatively rapid removal of dissolved 210Pb from the near bottom nepheloid layer to slope and canyon sediments is shown by its mean residence time of less than two years in this layer.  相似文献   

17.
In Amazon-shelf waters, as salinity increases to 36.5 × 10−3, dissolved uranium activities increase to a maximum of 4.60 dpm 1−1. This value is much higher than the open-ocean value (2.50 dpm 1−1), indicating a source of dissolved uranium to shelf waters in addition to that supplied from open-ocean and riverine waters. Uranium activities are much lower for surface sediments in the Amazon-shelf seabed (mean: 0.69 ±.09 dpm g−1) than for suspended sediments in the Amazon River (1.82 dpm g−1). Data suggest that the loss of particulate uranium from riverine sediments (and the consequent input of dissolved uranium to shelf waters) is probably the result of uranium desorption from the ferric-oxyhydroxide coatings on sediment particles, and/or uranium release by mobilization of the ferric oxyhydroxides. The total flux (i.e., riverine flux plus desorbed-remobilized particulate flux) of dissolved 238U from the Amazon shelf (about 1.2 × 1015 dpm yr−1) constitutes about 15% of uranium input to the world ocean, commensurate to the Amazon River's contribution to world river-water discharge (approximately 18%). Measurement of only the riverine flux of dissolved 238U underestimates, by a factor of about 5, the flux of dissolved238U from the Amazon shelf to the open ocean.  相似文献   

18.
文章讨论了南黄海泥质区、东海陆架及冲绳海槽北部表层沉积物和柱状岩芯中10 Be及9 Be含量的水平和垂直分布,并与重金属Pb的分布进行了比较。表层沉积物中的10 Be,9 Be和Pb三者表现出完全不同的分布特征。10 Be的分布主要受黑潮及其支流黄海暖流所支配; 9 Be的分布受黄河陆源物质输入的影响,主要集中在南黄海泥质区; Pb则主要分布在长江口和琉球群岛附近,反映了人类活动的影响。冲绳海槽北部末次冰期和全新世时10 Be的沉积通量变化在整体上反映了10 Be大气生产率的变化,即地球磁场屏蔽效应的影响。03孔全新世时10 Be的沉积通量 (1.12×109atoms/cm2ka)基本上等于10 Be的现代大气平均生产率,而在末次冰期时平均为4.06×109atoms/cm2ka, 高于10 Be 的现代大气平均生产率3倍以上。在冲绳海槽由于黑潮的缘故,10 Be对气候的变化响应要比极地冰芯的10 Be变化响应灵敏的多,对气候变化信号起了放大的作用。冰期时冲绳海槽北部10 Be的沉积通量远远高于太平洋大洋海区,充分反映了黑潮的传送带作用和边缘海的聚焦沉积作用,并表明末次冰期时在千年尺度上黑潮仍流经冲绳海槽,且强度并未减弱。 10 Be的通量在新仙女木时降到整个岩芯所跨时期的最低点,甚至低于10 Be的现代大气平均生产率,因此推测在新仙女木事件时,黑潮的变动特别大,有可能改向或断流。  相似文献   

19.
We present results of measurements of cosmogenic 10Be, 26Al and 36Cl, and the indigenous (intrinsic) concentrations of the stable elements Be, Al and Cl in 120-200 kyr old corals from Barbados and Puerto Rico. The concentration levels of these radionuclides in the corals lie in the range 104 to 108 atoms/g. A comparison of the measured nuclide concentrations with those expected to be produced in the corals by nuclear interactions of energetic cosmic radiation shows that (i) the radionuclides 26Al and 36Cl are derived from in situ cosmic ray interactions in the corals after their formation, but that (ii) the radionuclide 10Be owes its provenance in the coralline lattice primarily due to incorporation of dissolved beryllium in seawater in the lattice structure of the corals.  相似文献   

20.
We report the development of a NaOH-leaching technique to extract the authigenic Al and Be in marine sediments, which should allow the sedimentary signals of cosmogenic 26Al and 10Be to be more effectively studied as geochemical/geophysical tracers. The technique has been applied to the study of 26Al and 10Be in opal-rich sediments from the North Pacific. The 26Al/27Al and 10Be/9Be ratios of ~3 × 10−14 and 1 × 10−7 leached from the sediments are higher than those in the total sediments by factors of 3–10 and 2–3, respectively. The authigenic 10Be/9Be ratios are similar to those in deep waters at the study site, pointing to the potential usefulness of the ratios in paleoceanographic studies. The fractions of total Be and Al in the sediment studied that are of authigenic origin average about 40 and 17%, respectively. Estimated 26AL/27A1 ratios in detrital sediments are ≤ 10−15, low enough to indicate that the source of 26Al in the ocean mainly comes from atmospheric production. In the study area, the deposition flux of 26Al is comparable to its atmospheric supply. However, the deposition flux of 10Be is about threefold higher than the atmospheric input, signifying lateral transport of 10Be from the open ocean to this area of relatively high particle flux. The 26Al/10Be ratio, being insensitive to the oceanic influx of lithogenic particles, may serve as a valuable proxy for paleoproductivity. Both the authigenic and total-sediment 26Al/27Al and 10Be/ 9Be ratios decreased significantly at ~6 ka, which could reflect an enhanced input of windblown lithogenic particles to the North Pacific. While the enhanced dust input did not significantly alter the deep-water 9Be concentration, it contributed to the observed increase of authigenic 9Be flux to the sediment.  相似文献   

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