浙江嵊县—新昌新生代玄武岩及包体的研究

浙江新生代玄武岩主要岩石类型为橄榄拉斑玄武岩.矿物组合、岩石化学和REE特征表明为碱性玄武岩系列,是非原生岩浆的结晶产物(M=36-60,SI=15-37)。K-Ar同位素年龄4—10Ma.碱性橄榄玄武岩内赋存幔源包体和高压巨晶,其中尖晶石二辉橄榄岩包体熔融程度8％,形成温度975℃,压力15.7×10~8Pa。     

内蒙古赤峰柴胡栏子金矿基性麻粒岩包体特征及其成矿动力学意义

柴胡栏子金矿位于华北板块北缘,属中温热液蚀变岩型金矿。金成矿与矿区北部的早中生代辉石闪长岩体有密切关系。在辉石闪长岩体内发育大量包体,可以分为基性麻粒岩和角闪岩两类包体。包体的地球化学、形成温压条件表明基性岩包体为来源于大陆下地壳的基性麻粒岩包体,来源深度大约相当于下地壳中部-中上部位置,为早中生代时期底侵作用的产物。角闪岩包体来源于下地壳上部-中地壳下部位置,被上升岩浆带至地壳浅部。包体和寄主岩石具有相似的地球化学和氧、铅、锶、钕同位素特征,说明二者具有相同的岩浆来源。基性麻粒岩包体为底侵作用早期形成的堆晶岩受到后续岩浆的烘烤发生麻粒岩化形成。基性麻粒岩和寄主岩石辉石闪长岩与金矿床形成的密切时空关系显示底侵作用对柴胡栏子金矿含矿流体形成、运移和矿质富集有重要控制作用,其中 H2O和CO2等挥发性组分对控制流体形成和演化有至关重要作用。基性麻粒岩包体发育为成柴胡栏子金矿成矿物质来源于深部提供了有力的证据。     

大别山麻粒岩包体的氧同位素研究

对北大别变质杂岩中的麻粒岩包体进行详细的氧同位素地球化学研究,发现其全岩δ~(18)O值偏低,为3.3‰～4.4‰。在麻粒岩相变质条件下,大别山麻粒岩包体的共存矿物对之间达到并保存了氧同位素平衡,后期退变质作用未明显破坏这种平衡。由矿物氧同位素地质测温得到的顶峰变质温度800～875C,与一般麻粒岩相变质温度相吻合。在变质作用之前或顶峰变质作用过程中,大别山麻粒岩包体的原岩曾与一δ~(18)O值低于3‰的外来流体发生了高温水—岩交换作用,并且这种交换作用在一定范围内是相对均一的。     

下地壳基性麻粒岩流变强度实验研究

镁铁质基性麻粒岩被认为可能是大陆下地壳的主要组成岩石[1,2],涉及当前地球动力学研究中地壳变形和高原隆升,壳幔边界的力学耦合与拆离,底侵和拆沉作用等一系列地球动力学问题阳[3,4],具有重要的地球动力学意义.大陆下地壳的流变学性质是我们深入认识这些地球深部过程的关键点之一.     

浙江新昌地幔岩捕虏体中的硫化物包裹体初步研究

浙江新昌一带晚第三纪碱性玄武岩中地幔岩（二辉橄榄岩）捕虏体内存在大量硫化物熔体包裹体。电子探针分析表明,硫化物相成分主要为镍黄铁矿,次为磁共铁矿。硫化物包裹体的Ｎｉ／Ｆｅ值与寄主地幔岩的橄榄石含量呈正相关。同一包裹体的硫化物相成分不均一,自中心至边缘硫化物的Ｎｉ／Ｆｅ、（Ｆｅ＋Ｎｉ）／Ｓ值和Ｎｉ呈均呈增加趋势。通过与中国汉诺坝、德国ＷｅｓｔＥｉｆｅｌ东欧Ｎｏｇｒａｄ－Ｇｏｍｏｒ地区资料的综合分析,     

下地壳麻粒岩包体研究进展及其意义

产于火山岩中的下地壳麻粒岩包体是人们窥视深部地壳的一个窗口，现已成为人们探索大陆下地壳物质组成和演化最直接的研究对象。下地壳岩石包体一般具有麻粒岩相矿物组合，主体由镁铁质麻粒岩组成，以出现紫苏辉石矿物为标志下地壳包体的平衡温度为700－1040℃，平衡压力在0．8－1．4GPa之间。在绝大多数地区，基性下地壳包体占优势，其共同特征是低SiO2、高CaO和Mg^ ，过渡族元素和不相容元素含量变化很大，不机构造背景和不同岩石类型的包体同位素成分也有差异，全球各大陆下地壳包体Nd、Pb同位素组成分布具有“块体效应”特征。利用出露于地表的下地壳麻粒岩包体可以探讨下地壳物质组成和成分，建立下地壳物性剖面和岩石圈模型，并可作为幔源岩浆底侵作用的重要判据之一。世界范围内下地壳麻粒岩包体研究表明，在探讨下地壳的组成特点上，由火山岩中麻粒岩包体和出露的麻粒岩地体两类岩石样品所获得的下地壳组成特点存在比较大的差异，前者较后者反映的下地壳组成更偏基性。下地壳包体的类型与成因对揭示大陆地壳的增生、演化方式以及壳－幔交换作用具有重要的指示意义。     

浙江新昌石榴石二辉橄榄岩包体的流变特征及其地质意义

浙江新昌的石榴石二辉橄榄岩包体以残斑结构为主,并有向粒状变晶结构过渡的趋势。橄榄石组构以［０１０］呈点极密型式,而［１００］和［００１］呈大圆环带为特征。橄榄石的位错亚构造以反映高温位错蠕变的位错壁、亚晶粒构造和滑动位错环为主要特征。利用新的地质温压计计算的平衡温度和压力分别为１１５０℃～１２１０℃和２．１～２．４ＧＰａ。利用显微构造应力计计算流动应力为２２～３０ＭＰａ,利用橄榄岩高温流变律计算的应变速率和等效粘滞度分别为１０－１４～１０－１３ｓ－１和１０１９～１０２０Ｐａ·ｓ,上述数据均已达到软流圈的数值。结合其流变特征认为该区的石榴石二辉橄榄岩代表软流圈的物质,其来源深度为６８～７８ｋｍ。它反映在新生代时期本区存在有软流圈的底辟,它可能控制了该区新生代大地构造的特征及地质演化。     

下地壳麻粒岩包体研究进展及其意义

产于火山岩中的下地壳麻粒岩包体是人们窥视深部地壳的一个窗口,现已成为人们探索大陆下地壳物质组成和演化最直接的研究对象.下地壳岩石包体一般具有麻粒岩相矿物组合,主体由镁铁质麻粒岩组成,以出现紫苏辉石矿物为标志下地壳包体的平衡温度为700~1 040℃,平衡压力在0.8~1.4 GPa之间.在绝大多数地区,基性下地壳包体占优势,其共同特征是低SiO2、高CaO和Mg#,过渡族元素和不相容元素含量变化很大,不同构造背景和不同岩石类型的包体同位素成分也有差异,全球各大陆下地壳包体Nd、Pb同位素组成分布具有"块体效应"特征.利用出露于地表的下地壳麻粒岩包体可以探讨下地壳物质组成和成分,建立下地壳物性剖面和岩石圈模型,并可作为幔源岩浆底侵作用的重要判据之一.世界范围内下地壳麻粒岩包体研究表明,在探讨下地壳的组成特点上,由火山岩中麻粒岩包体和出露的麻粒岩地体两类岩石样品所获得的下地壳组成特点存在比较大的差异,前者较后者反映的下地壳组成更偏基性.下地壳包体的类型与成因对揭示大陆地壳的增生、演化方式以及壳-幔交换作用具有重要的指示意义.     

大同附近桑乾片麻岩之基性包体

一九四九年秋季,作者赴山西大同怀仁县附近调查煤田,曾由该县所属之鹅毛口至楼子口间经过,於该煤田东缘部之片麻岩中,见有许多基性包体,甚感有趣,兹记述之,诸希指正。     

Nickeliferous sulfides in xenoliths,olivine megacrysts and basaltic glass

The composition of olivine and nickeliferous sulfide inclusions from a selection of mafic and ultramafre rocks, xenoliths and megacrysts, including picritic basalts from Kilauea Volcano, Hawaii, kimberlite from Fayette County, Pennsylvania, and megacrysts from Mount Shasta, California are compared with the mean experimental value of the distribution coefficient for Ni/Fe exchange (K_D3=32). Only nine of the forty five olivipe/bulk-sulfide pairs investigated have compositions consistent with equilibration at high temperature, yielding calculated K_D3 values in the range 22 to 41. The remaining pairs have calculated K_D3 values which range from 0 to 19. Bulk-sulfides in disequilibrated assem-blages are consistently depleted in nickel and within both indivudual associations and individual petrographic sections they exhibit a wide variation in NiS content. The bulk copper contents of olivine-and groundmass-hosted sulfides from Kilauea Volcano range from 0.5 to 43 at%, and samples from the Kilauea Iki lava lake are more Fe-and Cu-rich and generally have lower K_D3 values than those from the eruption itself. As with magmatic Ni–Cu sulfide deposits, most nickeliferous sulfide inclusions in mantle-related rocks and xenoliths and in volcanic rocks do not have pristine early-magmatic bulk compositions, and it would seem to be premature to attribute these sulfides solely to either a mantle or an early-magnatic origin.     

The alteration of olivine in basaltic and associated lavas

Olivines which cool under oxidizing conditions exsolve iron oxides at high temperature, and at low temperatures break down to essentially chloritic materials. Olivines which cool under non-oxidizing conditions alter at intermediate temperatures to complex assemblages of chlorite and interstratified phyllosilicates containing a smectite. Alteration under oxidizing conditions at low temperature, probably below 140° C, produces iddingsite, an orientated assemblage of goethite and interstratified phyllosilicates also containing a smectite.Post-deuteric alteration extends or initiates the breakdown of olivine to phyllosilicate mixtures often resulting in widespread movement of materials through the flow. Post-deuteric alteration of iddingsite produces strongly pleochroic, highly ordered varieties which eventually break down to green phyllosilicate assemblages.Weathering of olivine may produce orientated assemblages similar to deuteric forms of iddingsite. Weathering of green alteration products results in oxidation and the liberation of discrete iron hydroxides.Alteration in all cases requires exchange of material between interstitial components and olivine. During deuteric alteration, plagioclase and pyroxene are usually unaffected.     

Evolution of basaltic and differentiated lavas from Anjouan,Comores Archipelago

Anjouan is one of four volcanic islands comprising the Comores Archipelago. Three (arbitrarily defined) categories of basic magma are recognised on Anjouan: ‘hypersthenenormative’, ‘alkalic’ and ‘basanitic’, which appear in that order with an eruptive sequence involving 1) shield construction, 2) peripheral fissure-controlled activity, and 3) rejuvenescent (posterosional) eruptions. Differentiated magmas have evolved within the three chemical groupings, and trend mainly towards undersaturated trachyte and phonolite. These trends are considered to have developed by initial removal of olivine and clinopyroxene, followed by Fe-Ti oxides, apatite and amphibole from arrested liquid pools within and beneath the volcano. The appearance of feldspar on the liquidus was clearly inhibited by the high contents of normative diopside in most Anjouan magmas, although late stage plagioclase fractionation is probably responsible for development of peralkaline phonolites at shallow depths, assisted eventually by alkali feldspar. Lherzolite-xenolith-bearing lavas are likely to be directly mantle-derived liquids. Three analysed representatives with 100 · Mg/Mg + Fe²⁺ (atomic) ratios approaching 70 are characteristically rich in normative diopside and may confirm the suggestion of primitive ankaramitic melts in mantle regions. High pressure fractional crystallisation may involve fractionation of ‘eclogite’, orthopyroxene or clinopyroxene, with or without olivine. It is believed however that such processes do not adequately explain the compositional change from hypersthene-normative basalt towards basanite, as they imply unacceptable degrees of Fe-enrichment. Problems of large ion element enrichment and fractionation would also remain, while the high contents of Cr and Ni place limits on the extent of crystal fractionation. A partial melting model of magma genesis is able to explain the main features of basalt geochemistry, especially if the upper mantle low velocity zone is regarded as having been severely fractionated due to upward migration of large ion elements. An ‘open’ system of magma production in the context of regional plate movement, and the implied decoupling between lithosphere and asthenosphere, accomodates realistic degrees of partial melting and allows a greater potential volume of mantle available for melting than possible ‘closed’ systems. The model also accounts for the migratory pattern of Comores volcanism.     

Fluid inclusions as petrogenetic indicators in granulite xenoliths,Pali-Aike volcanic field,Chile

Granulite xenoliths within alkali olivine basalts of the Pali-Aike volcanic field, southern Chile, contain the mineral assemblage orthopyroxene + clinopyroxene + plagioclase + olivine + green spinel. These granulites are thought to be accidental inclusions of the lower crust incorporated in the mantle-derived basalt during its rise to the surface. Symplectic intergrowths of pyroxene and spinel developed between olivine and plagioclase imply that the reaction olivine+plagioclase = Al-orthopyroxene + Al-clinopyroxene + spinel (1) occurred during subsolidus cooling and recrystallization of a gabbroic protolith of the granulites.Examination of fluid inclusions in the granulites indicates the ubiquitous presence of an essentially pure CO₂ fluid phase. Inclusions of three different parageneses have been recognized: Type I inclusions occur along exsolution lamellae in clinopyroxene and are thought to represent precipitation of structurally-bound C or CO₂ during cooling of the gabbro. These are considered the most primary inclusions present. Type II inclusions occur as evenly distributed clusters not associated with any fractures. These inclusions probably represent entrapment of a free fluid phase during recrystallization of the host grains. IIa inclusions are found in granoblastic grains and have densities of 0.68–0.88 g/cm³. Higher density (=0.90–1.02 g/cm³) IIb inclusions occur only in symplectite phases. Secondary Type III CO₂+glass inclusions with =0.47–0.78 g/cm³ occur along healed fractures where basalt has penetrated the xenoliths. Type III inclusions appear related to exsolution of CO₂ from the host basalt during its ascent to the surface. These data suggest that CO₂ is an important constituent of the lower crust under conditions of granulite facies metamorphism, indicated by Type I and II fluid inclusions, and of the mantle, as indicated by Type III inclusions.Correlation of fluid inclusion densities with P-T conditions calculated from both two-pyroxene geothermometry and reation (1) indicate emplacement of a gabbroic pluton at 1,200–1,300° C, 4–6 kb; cooling was accompanied by a slight increase in pressure due to crustal thickening, and symplectite formation occurred at 850±35° C, 5–7 kb. Capture of the xenoliths by the basalt resulted in heating of the granulites, and CO₂ from the basalt was continuously entrapped by the xenoliths over the range 1,000–1,200° C, 4–6 kb. Examination of fluid inclusions of different generations can thus be used in conjunction with other petrologic data to place tight constraints on the specific P-T path followed by the granulite suite, in addition to indicating the nature of the fluid phase present at depth.     

冀北张家口地区汉诺坝玄武岩中麻粒岩捕虏体的硫化物相

捕虏体麻粒岩是了解下地壳形成和演化的重要样品.汉诺坝新生代玄武岩中的二辉麻粒岩捕虏体样品中富含各种硫化物相,主要类型有①孤立产出的球状出溶硫化物;②矿物颗粒之间或颗粒内的粗晶硫化物;③次生硫化物包裹体群;④裂隙充填硫化物.电子探针分析表明,硫化物的矿物成分均为贫镍磁黄铁矿,(Ni+Co+Cu)/Fe(原子比)远小于0.2;(Fe+Cu+Co+Ni)/S(原子比)比地幔岩的磁黄铁矿小,多小于0.875,反映了一种S过饱和环境.各种产状的磁黄铁矿中Au、Ag都有一定的含量,其平均值分别为0.19%～0.22%(Au)、0.01%～0.02%(Ag),反映下地壳的麻粒岩化与金矿化的成因联系.磁黄铁矿的Ni、Co、Cu含量与S正相关,说明微量重金属元素与S具有同源的关系,由于地幔去气伴随S而进入下地壳.     

冀北张家口地区汉诺坝玄武岩中麻粒岩捕虏体的硫化物相

捕虏体麻粒岩是了解下地壳形成和演化的重要样品。汉诺坝新生代玄武岩中的二辉麻粒岩捕虏体样品中富含各种硫化物相,主要类型有:①孤立产出的球状出溶硫化物;②矿物颗粒之间或颗粒内的粗晶硫化物;③次生硫化物包裹体群;④裂隙充填硫化物。电子探针分析表明,硫化物的矿物成分均为贫镍磁黄铁矿,(Ni+Co+Cu)/Fe(原子比)远小于0.2;(Fe+Cu+Co+Ni)/S(原子比)比地幔岩的磁黄铁矿小,多小于0.875,反映了一种S过饱和环境。各种产状的磁黄铁矿中Au、Ag都有一定的含量,其平均值分别为0.19%～0.22%(Au)、0.01%～0.02%(Ag),反映下地壳的麻粒岩化与金矿化的成因联系。磁黄铁矿的Ni、Co、Cu含量与S正相关,说明微量重金属元素与S具有同源的关系,由于地幔去气伴随S而进入下地壳。     

Geochemistry and origin of basaltic lavas from Marquesas Archipelago,French Polynesia

The Marquesas Archipelago, a volcanic chain in French Polynesia (south-central Pacific Ocean), is predominantly composed of alkalic, transitional and tholeiitic basalts. The variation trends in these intraplate basaltic rocks imply that the magmas were derived from different upper mantle sources. Model calculations using the total inverse method show that the peridotite source of most Marquesas basalts was enriched in incompatible elements compared to a primordial mantle and had higher than chondritic ratios of several elements such as La/Yb, Ti/V and P/Ce. A metasomatic enrichment event is suggested by the sequence of element enrichment in the source relative to the primordial mantle (Ba>Nb>La>Ce>Sr>Sm>Eu> Zr>Hf>Ti>Y>Yb). On the other hand, some lavas including tholeiites of Ua Pou and alkalic basalts of Hiva Oa, were probably derived from relatively depleted upper mantle. In some islands such as Hatutu, the different types of basalts were generated from sources with rather similar compositions. The residual phases of the Marquesas magmas included garnet. The sources of these magmas were similar in trace element chemistry to the oceanic mantle below Hawaii.     

Stratigraphical framework of basaltic lavas in Torres Syncline main valley,southern Parana-Etendeka Volcanic Province

The Paraná-Etendeka Volcanic Province records the volcanism of the Early Cretaceous that precedes the fragmentation of the South-Gondwana supercontinent. Traditionally, investigations of these rocks prioritized the acquisition of geochemical and isotopic data, considering the volcanic stack as a monotonous succession of tabular flows. Torres Syncline is a tectonic structure located in southern Brazil and where the Parana-Etendeka basalts are well preserved. This work provides a detailed analysis of lithofacies and facies architecture, integrated to petrographic and geochemical data. We identified seven distinct lithofacies grouped into four facies associations related to different flow morphologies. The basaltic lava flows in the area can be divided into two contrasting units: Unit I - pahoehoe flow fields; and Unit II - simple rubbly flows. The first unit is build up by innumerous pahoehoe lava flows that cover the sandstones of Botucatu Formation. These flows occur as sheet pahoehoe, compound pahoehoe, and ponded lavas morphologies. Compound lavas are olivine-phyric basalts with intergranular pyroxenes. In ponded lavas and cores of sheet flows coarse plagioclase-phyric basalts are common. The first pahoehoe lavas are more primitive with higher contents of MgO. The emplacement of compound pahoehoe flows is related to low volume eruptions, while sheet lavas were emplaced during sustained eruptions. In contrast, Unit II is formed by thick simple rubbly lavas, characterized by a massive core and a brecciated/rubbly top. Petrographically these flows are characterized by plagioclase-phyric to aphyric basalts with high density of plagioclase crystals in the matrix. Chemically they are more differentiated lavas, and the emplacement is related to sustained high effusion rate eruptions. Both units are low TiO₂ and have geochemical characteristics of Gramado magma type. The Torres Syncline main valley has a similar evolution when compared to other Large Igneous Provinces, with compound flows at the base and simple flows in the upper portions. The detailed field work allied with petrography and geochemical data are extremely important to identify heterogeneities inside the volcanic pile and allows the construction of a detailed lithostratigraphical framework.     

长白山区二道白河流域早更新世玄武质熔岩的成因

采用岩石化学和同位素分析方法,研究了二道白河流域早更新世玄武质熔岩的成因。玄武质熔岩由钠质拉斑玄武岩和钾质粗面玄武岩、玄武质粗面安山岩组成。它们的REE分配形式比较相近,表明它们来自共同的源区。Sr、Nd、Pb同位素示踪表明,二道白河流域早更新世玄武质熔岩岩浆源区接近于似原始地幔。它们的Mg#=100Mg O/(Mg O+Fe O)低于中国东部新生代玄武岩原始岩浆的Mg#(60~68),Ni(27.76×10-6~200.6×10-6)低于原始地幔,Rb/Sr(0.05~0.09)、Ba/Rb(15.64~264)高于原始地幔,说明这些岩石不是源自原始地幔。玄武质熔岩的DI变化于42~67,具有高Ca、高Sr、Eu正异常,微量元素图解显示玄武岩保留部分熔融趋势,粗面玄武岩、玄武质粗安岩具有结晶分异趋势,岩浆上升过程中发生了不同程度的地壳混染作用。玄武质熔岩的Nb/Ta之比为14.8~15.8,与勘察加半岛深俯冲带火山类似。Nb/Ta-(Na2O-K2O)关系图解显示研究区玄武质岩浆的形成与俯冲板片的部分熔融有关。     

塔里木西克尔基性麻粒岩捕虏体的发现及其地质意义

在塔里木西部新生代碧玄岩中新发现了基性麻粒岩捕虏体。其原生矿物组合为Cpx+Opx+Pl (An=30~50)+Sp+Ilm+Tim,次生矿物组合为Ol+Pl (An>50)+alkaline feldspar+glass。原生矿物组合的温度和压力分别为1005~1059℃ 和 0.6~1.1GPa; 次生矿物组合形成于近等温减压过程和固相线上熔融以及之后的近地表快速冷却。这些麻粒岩捕虏体代表了早期底侵到塔里木板块下地壳的幔源岩浆。