塔深1井寒武系白云岩储层同位素流体地球化学示踪

通过对塔里木盆地沙雅隆起阿克库勒凸起东部塔深1井寒武系白云岩岩石学特征及成岩成因分析,影响塔深1井寒武系地层流体改变主要成岩有准同生期、埋藏期和后期热液改造期等.塔深1井寒武系白云岩及充填孔、洞、缝内方解石的氧、碳、锶同位素地球化学特征表明:准生期白云岩δ~(13)C_(PDB)值(0.9‰～1.8‰)偏正、δ~(18)C_(PDB)值(-10.1‰～-4.2‰)偏负反映准同生期泥微晶白云石成因属于高盐度的海水使得碳酸盐泥发生白云石化;埋藏期白云岩碳、氧随重结晶作用加强,白云岩晶粒由细向粗变化值随埋深增加,由于同位素分馏作用而偏负,δ~(18)C_(PDB)值(-10.02‰～-5.7‰)呈明显的下降,但δ~(13)C_(PDB)值(-1.4‰～0‰)组成变化不大;后期热液白云岩在热液作用下δ~(18)C_(PDB)值普遍低于-10‰(δ~(18)C_(PDB)/‰-13.1～-9.4,δ~(13)C_(PDB)/‰-2～-0.647);基质方解石δ~(18)C_(PDB)值为-10.1‰～-10.13‰,δ~(13)C_(PDB)值为-1.48‰～-1.62‰;充填孔洞缝粗-巨晶方解石δ~(18)C_(PDB)值为-10.89‰～-14.28‰,δ~(13)C_(PDB)值为-2‰～-3.09‰,反映准同生期→埋藏期→后期热液晶粒大小由泥微晶→细晶→中晶→粗晶氧碳同位素值逐渐变小偏负,据~(87)Sr/~(86)Sr(0.707 284～0.746 888)值均远高于现今海洋中海水的锶同位素组成(0.708)及围岩的锶同位素(0.707 284),说明鞍形白云石以及方解石结晶时的孔隙流体不是残余在岩石孔隙中的同生期海水,而是外来的富含锶的流体,也就是深部热液流体.渗透回流白云石化、埋藏白云石化和高温热液白云石化等特征表明白云岩形成于超盐度、埋藏和高温热液等3种不同的环境,因此影响储层形成与分布,从而影响对白云岩的勘探.     

大贵州滩二叠系—三叠系界线附近锶同位素组成特征

位于贵州南部的“大贵州滩”上,二叠系—三叠系界线附近地层为一套连续的发育完整的碳酸盐岩。二叠系顶部主要为厚层生物屑泥粒灰岩,而三叠系底部则主要为钙质微生物骨架灰岩及厚层粒泥灰岩。穿过二叠系—三叠系界线的取样累计厚度81m,二叠系和三叠系大致各占一半的厚度,共取样品91件,n(87Sr)/n(86Sr)值变化在0.707269～0.707409之间,平均为0.707327,低于现代海水的锶同位素比值的平均值（0.7090737）。锶同位素比值变化曲线表明从晚二叠世末期到早三叠世初期,同位素比值虽小幅度的起伏波动频繁,但总体上没有明显变化,三叠系底部的平均值（0.707330）略高于二叠系顶部的平均值（0.707323）。大贵州滩晚二叠世末至早三叠世初锶同位素组成的总体演化趋势与扬子台地及世界其它地方同时期的锶同位素组成的演化趋势（呈急剧的上升）不同,造成这种状况的原因可能是在全球事件控制的大背景下,由于大贵州滩特殊的环境条件,陆源物质对其影响小,导致了壳源锶对锶同位素组成的制约作用减弱,因而锶同位素组成未发生明显变化。     

新生代浮游有孔虫整体变化趋势

新生代浮游有孔虫在确定地层时代和推断古沉积环境等方面有着极其重要的实用价值,本文利用新生代浮游有孔虫数据库,对其中的属种资料进行了大量的分析和总结,初步了解了新生代浮游有孔虫整体特征的变化趋势及其在各地史时期中的面貌,使我们有可能建立一种以浮游有孔虫分类特征为基础的“模式”。这样,我们不仅把握了新生代浮游有孔虫的宏观特征,而且有可能找到一种只要对某些特征组合面貌进行判断即可大致确定地层时代的快速方法。     

江苏晚古生代孢粉组合序列

结合新得的孢粉材料 ,总结了江苏泥盆纪—二叠纪孢粉组合序列 ,共计 7个组合 (带 ) :1)五通组下部观山段AL组合 (Fa2 b- c) ;　 2 )擂鼓台段中下部 L H组合 (Fa2 d) ;　 3)擂鼓台段中上部 L C组合 (Tn1 a— Tn1 b早期 ) ;　 4a)擂鼓台段顶部 MD组合 (Tn1 b晚期— Tn2 ) ;　 4b)“老坎组”MC组合 (Tn1 b晚期— Tn2 ) ;　 5 )高骊山组 DP组合(Tn3— V1 - 2 ) ;　 6 )龙潭组 GM组合 (P21 — P1 2 ) ;　 7)大隆组 CS组合 (暂名 ) (P22 )。简要介绍了每个组合的内容和特征并对某些地层的时代作了进一步讨论。     

华北地块南缘中段中生代花岗质岩石的40Ar-39Ar年代学研究

对华北地块南缘4个中生代花岗质岩体中的角闪石和黑云母进行了40Ar-39Ar定年研究。结果表明,陕西黑山村岩体黑云母花岗闪长岩中黑云母的40Ar-39Ar坪年龄为126. 6±0. 3Ma,河南马家湾岩体细粒黑云母花岗闪长岩中黑云母的40Ar-39Ar坪年龄为126. 6±0. 2Ma,河南洛宁南八百坡岩体黑云母二长花岗岩中角闪石的40Ar-39Ar坪年龄为128. 3±0. 3Ma,山西蚕坊岩体花岗闪长岩中角闪石的40Ar-39Ar坪年龄为129. 2±0. 2Ma。上述结果显示华北地块南缘中生代的岩浆活动主要发生在早白垩世。该期岩浆的产生应与中国东部早白垩世的伸展环境相联系。     

内蒙古拜仁达坝及维拉斯托银多金属矿床的硫和铅同位素研究

拜仁达坝和维拉斯托是近年来在内蒙古东部地区发现的2个大型银多金属矿床,文章对其开展了硫和铅同位素研究。结果表明,拜仁达坝矿床矿石中硫化物的δ34S值为-4.0‰～+1.6‰,维拉斯托矿床矿石中硫化物的δ34S值为-0.8‰～+2.0‰,与岩浆热液型矿床的硫同位素值接近,表明这2个矿床中的硫主要来自岩浆。拜仁达坝矿区43件金属硫化物的206Pb/204Pb值为18.333～18.515,207Pb/204Pb值为15.532～15.656,208Pb/204Pb值为38.057～38.610;维拉斯托矿区20件金属硫化物的206Pb/204Pb值为18.304～18.377,207Pb/204Pb值为15.520～15.610,208Pb/204Pb值为38.112～38.435。拜仁达坝东矿区矿石中的铅同位素组成与维拉斯托矿区相似,变化范围小,相对贫放射性铅同位素,并且均为混合铅。矿石中的铅可能来自围岩地层及深源岩浆。     

Seasonal transport pattern of chromium(III and VI) in a stream receiving wastewater from tanneries

Water, suspended matter and sediment samples from a system heavily impacted by wastewater from numerous small tanneries (the upper Dunajec River, southern Poland) were collected to establish the annual cycle of Cr. To study possible oxidation processes the speciation of Cr and Mn concentrations were also investigated. This study showed that Cr(III and VI) temporal and spatial distributions are regulated by coupled anthropogenic (source location and emissions) and hydrologic factors (water flow and particle transport). Chromium(III) concentrations in all compartments varied seasonally as a function of the hydrological regime, production cycle in tanneries and distance from the discharge location. Cr(III) was largely associated with the particulate phase and rapidly deposited in river bed sediments. Contaminated river sediments were however flushed during flood periods to the reservoir located downstream from tanneries. During the tanning season (November to March), Chromium(III) concentrations in the water column and total Cr concentration in sediments exceeded relevant ecotoxicological guidelines only upstream from the reservoir, which trapped about 70% of the annual Cr(III) load transported by the Dunajec river. A correlation between Cr(VI)/Cr(III) ratios and Mn concentration in sediments downstream from the reservoir suggests the possibility of Cr(III) oxidation in natural conditions.     

不同成因锆石阴极发光及微量元素特征:以新疆阿尔泰地区花岗岩和伟晶岩为例

新疆阿勒泰可可托海地区出露大量花岗岩和伟晶岩脉,利用阴极发光显微照相(CL)、电子探针背散射(BSE)和激光剥蚀电感耦合等离子质谱技术(LA-ICP-MS),观察和分析岩石中锆石的内部结构、稀土元素及Th,U含量后结果表明:该区花岗岩锆石具振荡环带和强烈的阴极发光特征,Th/U比值较高(Th/U=0.16～0.99),轻稀土亏损、重稀土富集,具较大的Ce正异常,为典型岩浆成因锆石。伟晶岩(KP-08-11)锆石为热液锆石,不具振荡环带和阴极发光,具低的Th/U比值(0.01～0.13),强烈富集稀土元素,尤其是轻稀土元素较花岗岩锆石高一个数量级,Ce的正异常相对较低。伟晶岩(KP3-08-1)锆石为变质重结晶锆石,Th/U比值分布范围较广(0.01～0.78),强烈亏损稀土元素,稀土元素配分模式存在显著的"REE四分组效应"。微量元素特征表明,伟晶岩(KP-08-11)锆石可能结晶自富U贫Th的残余岩浆流体,而伟晶岩(KP3-08-1)的锆石经历了蜕晶质化和变质重结晶作用,但依然保持了共存伟晶岩熔体的微量元素特征。     

热液成矿多元论

过去一提起热液矿床,很自然地想到是指岩浆期后的产物。成矿物质来自深部岩浆源,出露、不出露的岩体或假想隐伏存在的岩体就是成矿母岩。即岩浆冷凝过程中分馏出气体和含水溶液,成矿物质从热液中沉淀出来而成矿。     

有明黏土各向异性固结特性的试验研究

由于大多数黏土矿物是片状的,在沉积和随后的固结过程中黏土颗粒和组构单元趋向水平定向排列,使天然沉积黏土呈现各向异性的固结特性。通过垂直切和水平切试样的恒应变速率固结试验研究了日本有明黏土的各向异性固结特性。试验结果表明,水平切试样的先期固结压力pch与垂直切试样的先期固结压力pcv的比值在0.5～1.0之间,主要是因为天然沉积黏土各向异性的屈服轨迹以及垂直切和水平切试样所经历的应力路径不同;在正常固结阶段,水平切试样的固结系数ch与垂直切试样的固结系数cv之比约为1.43,水平切试样的渗透系数kh与垂直切试样的渗透系数kv之比约为1.40,水平切试样的体积压缩系数mh与垂直切试样的体积压缩系数mv基本相等。因此,有明黏土固结系数的各向异性主要是因为渗透系数的各向异性,而渗透系数的各向异性本质上是因为其微观结构的各向异性。     

定量评估我国西北干旱区土地利用变化对植被指数的影响

在全球变化的背景下,定量区分人类活动和气候波动对干旱区植被的影响具有重要意义。采用多种统计学方法,分析了我国西北干旱区1990-2010年土地利用/覆被变化（LUCC）和1982-2010年归一化植被指数（NDVI）的时空变化特征,并定量评估了LUCC对NDVI变化的影响。结果表明：1990-2010年,西北干旱区耕地增加量最多,高达13 476 km²,其次是林地和水域,各地类增加的面积主要来自草地（12 590 km²）和未利用地（6 025 km²）。各土地类型变化速度快慢依次为：耕地 > 建设用地 > 水域 > 林地 > 草地 > 未利用地。2000-2010年,研究区土地利用程度综合指数（0.79）明显高于1990-2000年（0.23）,表明近年来人类活动对土地利用变化的影响程度显著增强。1982-2010年,西北干旱区NDVI呈增加态势,但近年来（2002-2010年）NDVI略有下降。其中,1990-2000年,LUCC对西北干旱区NDVI总变化的贡献率较低,仅为2.9%;而1990-2010,LUCC的贡献率为26.7%,表明气候变化对植被指数变化的贡献率高达73.3%。     

Pb isotopic ratios and elemental abundances for selective leachates from near-surface till: implications for mineral exploration

Pb isotope ratios obtained from fine-grained fractions ( < 63 and < 2 gmm from near-surface ( < 1 m depth) till surrounding ore deposits show isotopic overprinting from the underlying sulfide mineralization, and provide a new approach to mineral exploration for massive sulfide deposits (VMS) in glaciated terrains.In this study, Pb isotopic measurements, and selective leaching of 6 near-surface till samples down-ice from the Chisel Lake (Manitoba) and Manitouwadge (Ontario) VMS deposits were carried out in order to determine the location and nature of the Pb within till. Elemental abundances from selective leachates for all 6 samples display similar patterns and show that chalcophile elements (Cu, Ni, Pb and Zn), derived predominantly from the underlying VMS deposits, occur as (i) adsorbed/exchangeable metals; (ii) associated with oxyhydrous Fe and Mn; (iii) crystalline Fe oxides, and/or (iv) silicate. Despite the relative proximity of some of the till samples to the VMS deposits, only a very small component of the chalcophile elements is present as sulfide. This result is consistent with those from studies of weathered (oxidized) tills, which show that labile minerals such as sulfides have been completely destroyed and their chemical constituents reprecipitated or scavenged locally by clay-sized phyllosilicates and secondary oxides/hydroxides.Pb isotopic ratios for selective leachates from till samples with VMS-like (anomalous) signatures are similar to those from ore (galena) within the proximal VMS deposits. This indicates that the Pb is of a secondary nature and was probably scavenged and deposited after destruction of original sulfide minerals during till formation. The lack of a predominant sulfide-held Pb component within the selective leachates supports this interpretation. In contrast, Pb isotopic ratios for the same selective leachates from “background” samples are significantly higher and show that the Pb is not derived from proximal VMS deposits but from a more radiogenic source.Till samples were also leached using 2.5 M HCl (ldconventional” leaching). The Pb isotope ratios from the conventional leachates are similar to those obtained from the selective leachates, and show a large difference in Pb isotopic ratios between anomalous and background samples. We propose, therefore, that the conventional leaching rather than selective leaching or complete dissolution of a particular grain-size fraction be adopted for mineral exploration purposes using glacial sediments.The results from this study support the effective use of Pb isotope ratios from near-surface till as an exploration tool despite the weathered nature of the latter. We feel that this represents a more cost-effective technique over traditional geochemical prospecting methods, if used in conjunction with Pb abundance data.     

江山铅锌金矿选矿试验研究

针对江山铅锌金矿品位低,矿物组成复杂的特点,采用"铅-锌-硫优先浮选,硫(金)精矿氧化焙烧预处理-焙砂氰化浸金"的工艺,金在铅(金)精矿、锌精矿、硫(金)精矿中的总回收率为81.25%。可使硫(金)精矿中96.89%的硫以二氧化硫的形式得到回收,对原矿的回收率为73.25%;金的作业浸出率达84.76%,对原矿的回收率为31.91%;浸渣中的铁品位达57.99%,对原矿的回收率为26.71%。通过试验研究与分析,确定适宜的选矿工艺及药剂制度,为今后合理开发该区矿石提供技术依据。     

Crystal chemistry of diagenetic zeolites in volcanoclastic deposits of Italy

Zeolites from the most important volcanoclastic deposits of Italy include: (1) phillipsite and heulandite from the cinerite of the central northern Apennines; (2) chabazite and phillipsite from the phonolitic tephritic ignimbrite with black pumices; (3) phillipsite from the “tufo lionato” of Vulcano Laziale; (4) chabazite and phillipsite from the Campanian ignimbrite; (5) phillipsite from the Neapolitan yellow tuff; and (6) chabazite and phillipsite from the pyroclastics of Monte Vulture. Compared with sedimentary phillipsites and chabazites described in the literature, the chabazites and phillipsites studied here have lower Si/Al ratios and higher K contents. These chemical peculiarities are correlated with both the K-rich vesuvitic-leucititic, latitic-phonolitic, and potassic alkali-trachytic chemistry of the ash from which they were derived and, very likely, with the character of the hydrologically open system environment in which they formed. The zeolite of the heulandite-clinoptilolite group from the cinerite of the central northern Apennines is classified as a true heulandite on the basis of its chemical composition and thermal behavior.     

Chemical evolution of thermal waters from limestone aquifers of the Southern Upper Rhine Valley

Thermal spas in the Upper Rhine Graben recover their waters mainly from two different limestone aquifers, Hauptrogenstein (Middle Jurassic) and Muschelkalk (Middle Triassic). The thermal waters are heated along anomalous high thermal gradients in the Tertiary rift valley. The highest well head temperature is about 40°C in Hauptrogenstein wells and 60°C in Muschelkalk wells. Mineralization (TDS) is up to 5 g/kg in Hauptrogenstein and as high as 17 g/kg in the Muschelkalk aquifer. About 300 chemical analyses from 13 wells were used in this study.Compositional relationships between major chemical components (Na/Cl, K/Cl, Mg/Cl, SO₄/Cl, Cl/Br and Na/Br) suggest that thermal water from the Hauptrogenstein originates from mixing of 3 components: (a) meteoric water, (b) fossil seawater (residual formation water) and (c) a third component that resulted from water–rock reaction.The total amount of dissolved solids and the water type from the deeper Muschelkalk aquifer depends on the depth of the aquifer at the well location. The chemical characteristics of the thermal water indicate that water composition is derived mainly from water–rock interaction.     

Palaeodiet of Miocene Producers and Depositional Environments: Inferences from the First Evidence of Microcoprolites from India

This paper reviews research on coprolites from India, providing the first evidence of microcoprolites from the early Miocene (Aquitanian) Khari Nadi Formation sedimentary succession, exposed about 1.5 km northeast of the village of Kotada, Kachchh (Kutch) District, Gujarat State, western India. Morphometric and size comparisons (in a statistical framework) with known coprolites from the Mesozoic-Cenozoic successions of India (including those recorded herein) and globally suggest that fishes were the likely producers of the Kotada coprolites. Scanning electron microscopy confirms the presence of fish dental remains within the coprolites, while both Scanning Electron Microscopy (SEM) and Energy Dispersive X-ray Spectroscopy (EDS) reveal the phosphatic nature of the microscopic coprolite specimens (recorded herein) hinting that the producer(s) were predominantly carnivorous (ichthyophagous) in their diet. Furthermore, X-Ray Fluorescence (XRF) analysis of the host and associated lithologies allows us to deduce that the Kotada coprolites were deposited in a shallow marine environment, with possible aerial exposure of the host lithology occurring at some point after deposition. To the best of our knowledge, the present report is the first record of microscopic fish coprolites from India, as well as being the first from the Aquitanian of India and the oldest Neogene record from India.     

粤北302铀矿床同位素地球化学研究

位于粤北诸广山岩体东南部的302铀矿床是我国规模较大、埋藏较深的花岗岩型铀矿床之一。该矿床产于印支期油洞岩体和燕山早期长江岩体的断裂蚀变带内,矿区内NWW向基性岩脉十分发育,矿体呈似脉状、扁豆状或透镜状。同位素研究表明,矿石的沥青铀矿Sm-Nd和U-Pb等时线年龄（70 Ma）与油洞岩体（232 Ma）、长江岩体（160 Ma）的年龄相差巨大;主成矿期成矿流体的δDH2O值为-65‰～-82‰（平均为-75‰）,δ18OH2O值为6.8‰～0.6‰（平均为3.9‰）,反映出成矿流体主要由地幔流体组成;方解石的δ13C值为-8.4‰～-5.3‰,表明矿化剂ΣCO2也来自地幔;矿区内辉绿岩的（87Sr/86Sr）i值为0.70861～0.70882,花岗岩的（87Sr/86Sr）i值为0.73519～0.77152,萤石的（87Sr/86Sr）i值为0.71474～0.71697,表明成矿组分Sr可能来源于基性脉岩（幔源）与赋矿花岗岩体（壳源）,并呈不同程度的混合,而主成矿组分铀主要来源于赋矿花岗岩体。     

山东金伯利岩中榄橄石的研究

本文百次研究了山东金伯利岩中橄榄石的产状、含量、大小、世代、形态、颜色、环带、矿物包体、折光率、2V、化学成分、端员组分特征及红外光谱和穆斯堡尔谱特征,并分析研究了橄榄石的成因。指出了无色—浅绿色的、含MgO、Cr2O3、NiO高的橄榄石是找金刚石矿的指示性矿物。     

三峡水库对长江河口北支咸潮倒灌影响探讨

为了解三峡水库的运行对长江河口北支咸潮倒灌的影响,对三峡水库初步运行前后北支咸潮倒灌的变化进行了分析.结果表明:三峡水库运行后,受水库下泄水量变化影响,北支咸潮倒灌时间提前,10~11月咸潮倒灌强度增加,12月至次年4月倒灌强度减弱,咸潮倒灌强度的降幅小于增幅;在咸潮倒灌最为严重和长江口淡水利用最为重要的1~4月,水库的实际运行所引起的北支咸潮倒灌减弱的幅度并不大;三峡水库的实际运行使得北支咸潮倒灌的强度在各月重新分配,但对一年中整个咸潮期咸潮倒灌的总强度影响不大;水库运行后,北支极端咸潮倒灌的强度降低,这对提高长江口水源地的供水安全及保证率有利.     

基于线粒体COI基因序列探讨鸭嘴舌形贝地理分布

从河北秦皇岛采集的用无水乙醇保存的鸭嘴舌形贝(Lingula anatina)样品中提取了DNA,经PCR扩增后进行克隆,得到了2条长度为682 bp的线粒体细胞色素C氧化酶第I亚基(COI)基因片段。调用GenBank中日本有明海和中国香港的鸭嘴舌形贝同源序列,用邻接法和贝叶斯法构建了系统发育树,结果表明:秦皇岛地区的鸭嘴舌形贝与日本有明海的鸭嘴舌形贝形成姊妹群,具有较近的亲缘关系,与香港的鸭嘴舌形贝亲缘关系较远。初步分析认为西太平洋地区鸭嘴舌形贝现有的地理分布并不是由浮游幼虫的扩散引起的,不同地区鸭嘴舌形贝的差异可能跟地理隔离有关。