南极大气臭氧和温度垂直结构及其季节变化的研究

利用南极中山站2008年2月至2009年2月臭氧和温度探空等资料,对中山站上空大气臭氧和温度的垂直结构及季节变化特征进行了研究.结果表明,在中山站上空热对流层顶和臭氧对流层顶的高度相近,年平均高度分别为7.9和7.4km.对流层顶的气压和温度都存在位相相反一波型季节变化.春季和冬季对流层顶的温度转折没有夏季和秋季明显,而依据臭氧变化恰能更好地确定对流层顶高度.在对流层臭氧垂直分布的季节变化不显著;而平流层却十分明显.春季下平流层臭氧严重耗损,14km处的臭氧最小分压仅为1.57MPa,最大分压出现在上平流层,其他季节下平流层臭氧随高度增加而升高.春季下平流层臭氧的严重损耗,与极夜过后低温条件和平流层冰晶云表面消耗臭氧的光化学过程有密切关系.大气臭氧和温度的垂直结构及季节变化特征,对春季南极臭氧洞的形成和发展具有重要意义.     

长江三角洲地区春季低空大气臭氧垂直分布特征

介绍分析了2001年3月3日~4月13日浙江临安臭氧探空观测5 km以下臭氧垂直分布特征. 结果表明, 臭氧浓度垂直分布与湿球位温、风场有密切的关系. 臭氧浓度在2 km以下变化幅度很大, 明显的东风分量伴随臭氧高值. 5 km以下臭氧垂直分布可以分为峰值型、均匀型、分层结构型、低空污染型和线性增长型5个基本类型. 此外, 还分析了3种情形下区域尺度输送对低空污染型臭氧分布的影响.     

春季Hadley环流异常对夏季西北太平洋热带气旋频数影响的数值模拟试验

观测事实揭示出春季Hadley环流与夏季西北太平洋热带气旋频数之间存在显著的负相关关系.由春季Hadley环流异常引起的西北太平洋地区夏季纬向风垂直切变、大气辐合辐散等的异常变化是这一关系存在的内在原因.本文通过数值试验对这一关系的真实性进行了验证,即利用中国科学院大气物理研究所发展的9层大气环流模式（IAP9L-AGCM）模拟了春季Hadley环流异常偏强情景,并分析了该情景下影响西北太平洋热带气旋生成的环境场的响应.结果表明,在春季Hadley环流偏强情景下,夏季西北太平洋地区纬向风垂直切变幅度加大,低空大气异常辐散,高空大气异常辐合,东亚夏季风减弱,这种环流背景不利于热带气旋生成和发展,因此,西北太平洋热带气旋频数异常偏少.数值模拟结果与已有的诊断结果相吻合,进而证实了春季Hadley环流与夏季西北太平洋热带气旋频数负相关关系的存在.因此,春季Hadley环流信号可以用于西北太平洋热带气旋活动的气候预测.     

北京地区一次持续重污染过程O3、NOx、CO的垂直分布分析

在2004年9月27日至10月12日期间,北京地区大气环境出现了严重污染事件,其间,使用紫外光度法O3分析仪、化学发光NO-NO2-NOx分析仪和气体相关过滤CO分析仪,在中国科学院大气物理研究所北京325 m气象与环境观测塔上进行了污染物浓度梯度观测,分别在8、120、280 m三层观测平台对大气中的O3、NOx、CO体积比浓度进行了垂直梯度的连续观测.通过分析该过程中大气污染物和相关气象因素的垂直分布数据得知,污染物浓度在280 m以内分布很不均一;较低气压控制下,24 h变温为正时,易形成由辐合、堆积造成的污染物浓度增高.通过敏感性分析计算,近地层臭氧光化学生成处于VOC敏感,是垂直梯度分布的主要因素;边界层顶存在高浓度氧化污染气团的振荡效应.     

中国南部对流层中上层臭氧增加的气象场判识及臭氧变化的多尺度特征

副热带急流对中国南部地区对流层中上层臭氧浓度的影响程度及地理范围目前还研究较少,且缺乏综合使用常规气象资料及卫星资料来判识对流层中上层臭氧浓度增高的方法.本文利用NCEP再分析与最终分析资料、日本GMS-5地球静止卫星水汽云图资料,以2001年3月27~29日中国南部的临安、昆明、香港臭氧探测个例为基础,结合1996年3月29日香港与2001年4月13日临安对流层中上层高浓度臭氧分布个例对副热带急流对中国南部对流层中上层臭氧浓度的影响进行了详细分析,提出根据气象要素场判识春季中国南部对流层中上层臭氧浓度增高的充分条件为根据卫星水汽图像上的暗区、高空急流入口区的左侧辐合区、高空锋区、对流层中上层≥1 PVU的向下伸展的舌状高位涡区来综合判断.本文的分析结果表明,本文个例中对流层中上层高浓度臭氧来自平流层;香港对流层中上层低浓度臭氧来自热带海洋地区.不仅臭氧垂直廓线的多个极小与极大值表明臭氧垂直分布的多尺度变化特征,而且对流层中上层PV分布以及卫星水汽图像分析也表明大气中的多尺度运动对臭氧垂直分布特征有显著影响.本文的结果表明与副热带高空急流相联系的平流层空气侵入不仅发生在中国大陆的较高纬度地区,较低纬度的昆明与香港地区也有平流层空气侵入导致对流层中上层臭氧浓度升高.     

北京城区大气混合层内臭氧垂直结构特征的初步分析——基于臭氧探空

本文利用2013年6月至2015年10月北京南苑观象台两年多午后臭氧探空资料,初步分析了北京城区大气混合层内臭氧浓度的垂直分布规律以及典型天气条件下大气边界层臭氧的变化特征.主要结果有：（1）季节平均而言,地表至对流层中部（8 km）的臭氧浓度在夏季最高,冬季最低,相差50~130 μg·m^-3,最大差异在边界层.总体而言,对流层臭氧浓度随高度有比较缓慢的增加,但是边界层内臭氧浓度的垂直结构随季节有比较大的差异：夏季混合层中部存在一个臭氧浓度极大值,这与夏季比较强的光化学生成臭氧有关;而在冬季地面臭氧浓度很低,平均值小于40 μg·m^-3,说明冬季地面是臭氧很强的汇.（2）臭氧浓度季节内变率的季节差异也十分明显,夏季最大、冬季最小.季节内变率在从边界层向自由对流层过渡区域最小（夏季为24 μg·m^-3,冬季仅为10 μg·m^-3）,在边界层内变率较大,夏季可达64 μg·m^-3（冬季为30 μg·m^-3）,这也说明边界层化学过程明显影响臭氧浓度的变化.（3）我们从所有白天样本中严格筛选了部分混合层样本,并把臭氧浓度在由混合层向自由大气过渡时的垂直分布分成了三类,即臭氧浓度随高度增大（Ⅰ型）、减小（Ⅱ型）以及基本稳定不变（Ⅲ型）;臭氧垂直结构类型有明显的季节特征,夏季主要是Ⅱ型,而冬季则以Ⅰ型为主.（4）此外,我们还针对一些典型天气过程（强风、静稳雾天和PM_2.5污染）边界层内臭氧的变化特征进行了分析,结果表明：强风切变产生的机械对流引起的充分混合,有利于高层臭氧向低层输送,使得混合层内臭氧浓度的垂直梯度明显减小,同时混合层高度较高,达3 km以上;在高湿度静稳天气控制下,大气混合层较稳定,对北京上空污染物的垂直扩散十分不利：颗粒物浓度升高,削弱到达近地层的太阳辐射,从而降低臭氧的生成效率,混合层内臭氧浓度与混合层厚度都处于较低水平.     

測量大气臭氧垂直分布的逆轉方法<C>——对逆轉方法<A><B>的改进

本文给出了1个新的测量大气臭氧垂直分布的逆转方法,该方法将臭氧层分为6层,各层的臭氧含量,前后两次用图解法由联立方程定量的解出。使用这个方法,我们对在北京观测的10条逆转曲线作了计算,并将这些计算结果作了讨论及初步的误差估计。     

风垂直切变对中尺度地形对流降水影响的研究

针对长江中下游中尺度地形特点以及暴雨过程发生发展期间风垂直切变的主要观测特征,设计了一系列中尺度地形的三维理想数值试验,分析了干大气地形流和重力波特征,探讨了条件不稳定湿大气地形对流降水的模态分布,在此基础上研究了圆形、直线风垂直切变和切变厚度对中尺度地形对流降水强度和模态分布的影响.结果发现:在 F_r≈1的干大气条件下,气流遇到地形后分支、绕流和爬升现象同时存在,地形激发的重力波在水平和垂直方向上传播,其在迎风坡、背风坡、地形上游和下游的振幅不同,并组织出不同强度的垂直上升运动.在F_r > 1的条件不稳定湿大气下,地形对流降水主要存在三种模态,即迎风坡和背风坡准静止对流降水以及地形下游移动性对流降水,地形对流降水的形成与重力波在低层组织的上升运动密切相关.风垂直切变对地形对流降水的强度和模态分布有重要作用,其中圆形风垂直切变(风随高度旋转)不仅影响地形下游对流降水系统的移动方向,而且影响迎风坡和背风坡山脚处对流降水中心的分布和强度;直线风垂直切变(风随高度无旋转)主要影响地形对流降水的移动速度和强度.风随高度自下而上顺(逆)时针旋转,地形对流系统向下游传播时向右(左)偏移.风垂直切变主要通过影响地形重力波的结构和传播以及对流系统的形成、移动方向和速度,来影响地形对流降水的模态分布,其中对流层中低层的风垂直切变对地形对流降水强度和模态分布有重要影响.     

Gtz逆轉效应中I_(3112 )的有效散射高度上升过程的跳跃性及逆轉方法B解的不唯一性

本文探討了Gotz逆轉效应中,单色天頂散射光强I_3112（?）的有效散射高度h_E的上升过程。首先从理論上証明:h_E并非沿高度連續的上升,而是跳跃上升的。然后用实际观測数据的計算,証实了理論結果。由此并指出,由于h_E的跳跃,那么在应用逆轉效应,建立測定大气臭氧垂直分布方法时,如果将大气分层較多,那么可能在臭氧层中下部所得的結果,是不唯一的。基于上述結果,进一步研究了方法B,发現目前国际上通用的,由Ramanathan与Davo所給出的逆轉方法B的解是不唯的。这些解之間有着亘大的差异。因此以該方法計算出的各层臭氧含量,并不能肯定大气臭氧的垂直分布情况。     

火箭观测到的中层垂直速度扰动细微结构

使用一枚携带ｃｈａｆｆ的火箭观测到的垂直速度数据，研究中层大气垂直速度扰动细微结构。结果表明，垂直速度扰动有明显的层状结构，各层厚度约１５０－５００ｍ，层间垂直分离距离在几百米到１－３ｋｍ间。在垂直速度方差和低Ｒｉ数峰值间以及动力不稳定和ＭＳＴ雷达回波区域间有好的对应关系。水平速度垂直波数谱与饱和谱在谱斜率和谱振幅上存在好的一致．这些观测结果表明，火箭测量到的细微结构可以用波场饱和解释。     

FY-3气象卫星紫外臭氧总量探测仪辐亮度在轨定标与反演结果分析

FY-3气象卫星上搭载的紫外臭氧总量探测仪TOU是我国自主开发研制的首台用于全球臭氧总量定量测量的探测仪,自发射以来已成功在轨运行近两年.由于TOU发射前辐亮度定标存在偏差,为了得到高精度的产品,TOU必须进行在轨定标.本文介绍了基于辐射传输模式计算对TOU辐亮度进行在轨道定标的方法,定标过程中用于模拟辐亮度计算的臭氧总量由与TOU观测时刻相近的国外臭氧总量探测仪器MetOp/GOME-2提供.文章将在轨定标后TOU的反演结果与AURA/OMI以及地基的产品进行比较,结果表明,用辐射传输模式对TOU辐亮度进行在轨定标的方法是可行的,反演结果能够真实地反映臭氧的时空分布特性,在全球部分地基观测站所处的位置上对TOU, OMI以及地基的臭氧总量进行比较的结果表明,TOU与OMI的相对偏差均方根约为2.52%,TOU与地基以及OMI与地基观测结果之间的相对偏差均方根分别为4.45%和3.89%.     

Study of ozone “weekend effect” in Shanghai

Analysis of observed ozone data in 2006 from five monitoring sites (Xujiahui, Chongming, Baoshan, Pudong, Jinshan) in Shanghai reveals that ozone (O_3) concentrations in Xujiahui are higher at week-ends than those on weekdays, despite the fact that emissions of ozone precursor substances, such as oxides of nitrogen (NOx), carbon monoxide (CO) and volatile organic compounds (VOCs) are lower at weekends than those on weekdays. The possible chemical cause of ozone "weekend effect" is that NO_2/NO ratio increases at weekends by 25.61% compared with those on weekdays. In addition, because of an average 12.13% reduction in NOx (NO NO_2) in the early morning (05:00-09:00) at weekends compared with that on weekdays, the ozone inhibition period ends 0.5 h earlier at weekends resulting in the longer duration of ozone accumulation and the higher ozone production rate. The rate of ozone production is a function of VOCs and NOx in the atmosphere. VOCs/NOx ratio in Xujiahui is 4.55 at weekends, and 4.37 on weekdays, belonging to the "NOx-limited". The increasing VOCs/NOx ratio at weekends leads to ozone enhancement from 73 ppbv to 80 ppbv, which are consistent with ozone "weekend effect" in Xujiahui. Furthermore, combining with MICAPS cloud amount data, the fact that ozone "weekend effect" in Xujiahui weakens gradually along with the increasing of cloud amount indicates that ozone photochemical production leads to ozone "weekend effect" in Xujiahui of Shanghai.     

Satellite data analysis of ozone differences in the Northern and Southern Hemispheres

Four years of SBUV ozone data and NOAA/NMC temperature data are analyzed for the relations between the annual total ozone behaviour in the Northern and Southern Hemispheres and the transport of ozone by planetary waves. It is found that the interhemispheric differences in the annual variation of total ozone are well explained by the interhemispheric differences in the planetary waves and the resulting ozone transports. The annual variation of the ozone transports by the stationary waves is found to control the ozone behavior in both hemispheres. Both the day-to-day and the interannual variation in total ozone are found to be strongly related to the corresponding variability of the planetary waves.Contribution Number 46 of the Stratospheric General Circulation with Chemistry Project at NASA/GSFC.     

Estimating the atmospheric ozone transmission for solar radiation models

Accurate calculation of the solar radiation at the earth’s surface requires evaluation of the atmospheric ozone transmission. To use the existing methods one needs to know the atmospheric ozone amount. The serious lack of ozone data makes almost impossible the application of these methods in most of the world. In this paper a new method of estimating the overall ozone attenuation in the Northern Hemisphere is presented. Multiyear monthly latitudinal average ozone data are used. A daily ozone transmission function is proposed, and values of it are calculated for each latitudinal circle from 0° to 70°N at 10 longitude-degree intervals. By regression techniques parameterized expressions of the daily ozone transmission in the Northern Hemisphere are obtained as a function of the latitude. The model is applied to Athens, and the results are in excellent agreement with those obtained by extremely detailed calculations of the ozone transmission. The reliability of the model, under special regional ozone conditions, is investigated. Calculations for 67 locations in the Northern Hemisphere prove that the deviations do not exceed 1 percent. The influence of the year-by-year ozone variability is also examined, and the maximum deviation is found to be near 1.6 percent. The proposed model can be easily incoporated into solar radiation models in order to provide the ozone depletion at any place in the Northern Hemisphere where atmospheric ozone data are not available.     

Statistical characteristics of the vertical ozone distribution in mid-latitudes

Summary The correlation matrix for the vertical ozone distribution and the temperature-ozone cross-correlation matrix, which was calculated from ozone soundings made over Berlin between 1967 and 1970, the statistical structure of the vertical ozone profile (correlation coefficients, average profiles, average standard deviation, relative variability) was derived for the three ozone seasons. The partial ozone pressure does not at all heights follow a normal distribution (e. g. at tropopause level). Generally, the correlation between tropospheric and stratospheric ozone is rather poor. In some layers the highest correlation coefficients, i.e. –0.3 and +0.4, occur in autumn (October to December) and in winter and spring (January to April). The correlation between the ozone amounts of various stratospheric layers is distinct in autumn, less distinct in summer (May to September) and entirely missing from January to April. Conspicuous cross-correlations between temperature and ozone have been found for all three seasons. a) With a negative correlation between tropospheric temperature and middle tropospheric to middle stratospheric ozone (maximum up to –0.8); b) with a rather strong positive correlation between the ozone amount and the temperature in the lower stratosphere (maximum up to +0.84); c) with a positive correlation between the ozone amount of the middle stratosphere and the temperature of the middle stratosphere (maximum up to +0.8). The highest correlation coefficients occur in autumn.     

Short-term ground ozone fluctuations at Poona

Short-term fluctuations superimposed on the diurnal variations of surface ozone recorded at Poona during 1969–1970 are discussed.While there is a net production of ozone during electrical discharges in a thunder cloud, the surface ozone recorder often registered a decrease in surface ozone concentration. This decrease coincided with updraughts generated during the formation of a thunderstorm. Similar sharp increases in ozone were observed with downdraughts. In cases of lightning without the development of a thunderstorm over the station, an increase in ozone density was observed just after the first lightning discharge.Apart from the fluctuations associated with thunderstorms in summer, sharp fluctuations in density were also noticed during winter, in the mornings. Abrupt falls in ozone occur with the formation of a stable layer near the ground at night and a sudden surge after the breaking up of the layers in the morning. The changes in ozone are, however, much more pronounced than those in temperature and wind and this striking correlation between surface ozone, surface air temperature and wind provides a unique tool for the study of low-level temperature inversions, their establishment and destruction.     

On the relationship between vertical ozone distribution and the synoptic situation

Summary The purpose of the paper is to provide a statistical view of the role of circulation patterns and the origin of low stratospheric air in connection with vertical ozone distribution below the ozone maximum, and also with the total ozone amount. Ozonesonde data from the aerological observatory of the Czech Hydrometeorological Institute (CHMI) Prague-Libu (50·0N, 14·7E) for January to April during the period 1979–1990 have been analyzed using an objective method to find the distribution of laminae in the vertical profile of the ozone partial pressure related to the different types of circulation patterns. The synoptic classification following Grosswetterlagen (GWL) was used, the parameters of the ozone profile such as number, magnitude, thickness and height of laminae, or the appearance of the large laminae were obtained for the individual types of GWL and used in other procedures. The total ozone data from the ozone observatory of CHMI in Hradec Králové (50·2N, 15·8E) was also included together with the height of the tropopause and parameters of ozone profiles in the cluster analysis to investigate connections between the ozone distribution and circulation patterns (types of synoptic situation). The ozone low-level index (LLI), defined as the ratio of the integral amount of ozone in D.U. from the surface up to 50 hPa and total ozone were introduced to provide better information about ozone profile response to circulation patterns and thus provide a better grouping of similar types of GWL. The presented results imply the strong confirmation of the huge ozone laminae below the ozone maximum as the source of total ozone positive extremes under appropriate synoptic situations with the near location of the polar vortex edge, which could be used in common forecasts of atmospheric ozone as well as in remote sensing applications.     

平流层O3、O动力系统的平衡性质及南极平流层O3季节变化规律的研究

本文首次利用常微分方程定性理论对平流层O₃、O动力系统的平衡性质进行了讨论.结果表明,如果在平流层O₃的主要分布高度内,大气扩散作用小于光化学作用,那么平流层的O₃层处于稳定状态;反之,平流层的O₃层将遭到破坏.利用这一机制,我们可以解释南极平流层O₃的季度变化规律和每年9-10月份出现的南极O₃洞.     

Use of coupled ozone fields in a 3-D circulation model of the middle atmosphere

With a detailed chemistry scheme for the middle atmosphere up to 70 km which has been added to the 3-D Karlsruhe simulation model of the middle atmosphere (KASIMA), the effects of coupling chemistry and dynamics through ozone are studied for the middle atmosphere. An uncoupled version using an ozone climatology for determining heating rates and a coupled version using on-line ozone are compared in a 10-month integration with meteorological analyses for the winter 1992/93 as the lower boundary condition. Both versions simulate the meteorological situation satisfactorily, but exhibit a too cold lower stratosphere. The on-line ozone differs from the climatological data between 20 and 40 km by exhibiting too high ozone values, whereas in the lower mesosphere the ozone values are too low. The coupled model version is stable and differs only above 40 km significantly from the uncoupled version. Direct heating effects are identified to cause most of the differences. The well-known negative correlation between temperature and ozone is reproduced in the model. As a result, the coupled version slightly approaches the climatological ozone field. Further feedback effects are studied by using the on-line ozone field as a basis for an artificial climatology. For non-disturbed ozone conditions realistic monthly and zonally averaged ozone data are sufficient to determine the heating rates for modelling the middle atmosphere.