“三江”义敦岛弧带玄武岩喷发序列与裂谷—岛弧转化

岩石-构造组合是恢复古板块构造历史的最有效手段之一,同时是表征古板块边界与板内环境的最重要的地质证据。本文拟从岩石-构造组合角度,通过对义敦岛弧带玄武岩,特别是前岛弧期玄武岩喷发序列、岩石组合、地球化学特征和其形成背景的研究,试图从较深层次上揭示岩浆-构造内在联系,探索义敦古岛弧的形成与发展。     

祁连山新元古代中—晚期至早古生代火山作用与构造演化

祁连山地区的新元古代中—晚期至早古生代火山作用显示系统地时、空变化,其乃是祁连山构造演化的火山响应。随着祁连山构造演化从Rodinia超大陆裂谷化—裂解,经早古生代大洋打开、扩张、洋壳俯冲和弧后伸展,直至洋盆闭合、弧-陆碰撞和陆-陆碰撞,火山作用也逐渐从裂谷和大陆溢流玄武质喷发,经大洋中脊型、岛弧和弧后盆地火山活动,转变为碰撞后裂谷式喷发。850~604 Ma的大陆裂谷和大陆溢流熔岩主要分布于祁连和柴达木陆块。从大约550 Ma至446 Ma,在北祁连和南祁连洋-沟-弧-盆系中广泛发育大洋中脊型、岛弧和弧后盆地型熔岩。与此同时,在祁连陆块中部,发育约522~442 Ma的陆内裂谷火山作用。早古生代洋盆于奥陶纪末(约446 Ma)闭合。随后,从约445 Ma至约428 Ma,于祁连陆块北缘发育碰撞后火山活动。此种时-空变异对形成祁连山的深部地球动力学过程提供了重要约束。该过程包括:(1)地幔柱或超级地幔柱上涌,导致Rodinia超大陆发生裂谷化、裂解、早古生代大洋打开、扩张、俯冲,并伴随岛弧形成;(2)俯冲的大洋板片回转,致使弧后伸展,进而形成弧后盆地;(3)洋盆闭合、板片断离,继而发生软流圈上涌,诱发碰撞后火山活动。晚志留世至早泥盆世(420~400 Ma),先期俯冲的地壳物质折返,发生强烈的造山活动。400 Ma后,山体垮塌、岩石圈伸展,相应发生碰撞后花岗质侵入活动。     

Mineralogy,geochemistry and petrogenesis of Kurile island-arc basalts

Whole-rock (major- and trace-element) and mineral chemical data are presented for basaltic rocks from the main evolutionary stages of the Kurile island arc, NW Pacific. An outer, inactive arc contains a Cretaceous-Lower Tertiary sequence of tholeiitic, calcalkaline and shoshonitic basalts. The main arc (Miocene-Quaternary) is dominated by weakly tholeiitic, with lesser, alkalic basalts. The mineralogy of Kuriles basalts is characterised by An-rich plagioclases, a continuous transition from chromites to titanomagnetites, pyroxenes with low Fe³⁺ contents and without strong Fe-enrichment, abundance of groundmass pigeonites and the absence of amphiboles. There is an increase in K₂O contents both along-arc (northwards) and towards the reararc side. The basalts show an exceptionally wide but continuous range of K₂O contents (0.1–4.7%) which correlate with other LIL element contents. Tholeiitic basalts with low LIL element contents, La/Yb and Th/U, but high K/ Rb, P₂O₅/La and Zr/Nb were derived from depleted, lherzolitic mantle which had suffered fluid metasomatism by K, Rb, Cs, Sr, Ba, Pb and H₂O only. Alkali basalts are also thought to be derived from depleted mantle but melt metasomatism involved addition of all LIL elements to a garnet lherzolite mantle. The Kuriles basalts and their mantle sources range continuously between these two end-member compositions. The metasomatic fluids/melts were probably released by early dehydration and later melting within subducted oceanic lithosphere though the process is not adequately constrained.     

Pacific superplume-related oceanic basalts hosted by accretionary complexes of Central Asia, Russian Far East and Japan

Plume-related oceanic magmatism form oceanic islands, seamounts and plateaus (hereafter “seamounts” or “paleoseamounts”), which are important features in geological history. The accretion of oceanic seamounts to active continental margins significantly contributed to the formation of the continental crust. This paper reviews occurrences of Late Neoproterozoic–Mesozoic seamounts of the Paleo-Asian and Paleo-Pacific oceans, which are hosted by accretionary complexes (ACs) of Russian Altai, East Kazakhstan, Mongolia, Russian Far East and Japan. The paleoseamounts commonly consist of Ti–LREE–Nb-enriched plume-related basalts (OIB-type or intraplate basalts) capped with massive limestone and associated with other units of oceanic plate stratigraphy (OPS): oceanic floor basalts (MORB), pelagic chert, epiclastic slope facies, etc. The paper presents available geochemical data on the plume-related basalts including the first geochemical data on the Middle Paleozoic OIB-type basalts of the Paleo-Asian Ocean hosted by the Ulaanbaatar AC of Mongolia. An emphasis is made for the structural setting of OPS units, specific geochemical features of intraplate basalts, problems of their identification, and distinguishing from magmatic units of a different origin such as MORB, island-arc and back-arc basalts. Finally, we propose a continuous, though periodical, evolution of the Pacific superplume-related magmatism, which can be more reliably proved by studying Middle Paleozoic OPS units hosted by ACs of Mongolia and Tien Shan, and discuss prospects of future studies.     

Depleted arc volcanism in the Alboran Sea and shoshonitic volcanism in Morocco: geochemical and isotopic constraints on Neogene tectonic processes

Samples of volcanic rocks from Alborán Island, the Alboran Sea floor and from the Gourougou volcanic centre in northern Morocco have been analyzed for major and trace elements and Sr–Nd isotopes to test current theories on the tectonic geodynamic evolution of the Alboran Sea. The Alborán Island samples are low-K tholeiitic basaltic andesites whose depleted contents of HFS elements (0.5×N-MORB), especially Nb (0.2×N-MORB), show marked geochemical parallels with volcanics from immature intra-oceanic arcs and back-arc basins. Several of the submarine samples have similar compositions, one showing low-Ca boninite affinity. ¹⁴³Nd/¹⁴⁴Nd ratios fall in the same range as many island-arc and back-arc basin samples, whereas ⁸⁷Sr/⁸⁶Sr ratios (on leached samples) are somewhat more radiogenic. Our data point to active subduction taking place beneath the Alboran region in Miocene times, and imply the presence of an associated back-arc spreading centre. Our sea floor suite includes a few more evolved dacite and rhyolite samples with (⁸⁷Sr/⁸⁶Sr)₀ up to 0.717 that probably represent varying degrees of crustal melting. The shoshonite and high-K basaltic andesite lavas from Gourougou have comparable normalized incompatible-element enrichment diagrams and Ce/Y ratios to shoshonitic volcanics from oceanic island arcs, though they have less pronounced Nb deficits. They are much less LIL- and LREE-enriched than continental arc analogues and post-collisional shoshonites from Tibet. The magmas probably originated by melting in subcontinental lithospheric mantle that had experienced negligible subduction input. Sr–Nd isotope compositions point to significant crustal contamination which appears to account for the small Nb anomalies.

The unmistakable supra-subduction zone (SSZ) signature shown by our Alboran basalts and basaltic andesite samples refutes geodynamic models that attribute all Neogene volcanism in the Alboran domain to decompression melting of upwelling asthenosphere arising from convective thinning of over-thickened lithosphere. Our data support recent models in which subsidence is caused by westward rollback of an eastward-dipping subduction zone beneath the westernmost Mediterranean. Moreover, severance of the lithosphere at the edges of the rolling-back slab provides opportunities for locally melting lithospheric mantle, providing a possible explanation for the shoshonitic volcanism seen in northern Morocco and more sporadically in SE Spain.     

西太平洋典型边缘海盆的岩浆活动

在发育有全球最大、最复杂的弧—沟—盆体系的西太平洋地区,集中了全球75％左右的边缘海盆(弧后盆地).根据磁异常条带年龄,这些边缘海盆可粗略分为3个扩张幕.主要根据DS-DP,ODP和IODP计划实施以来所获得的成果,结合其他海洋调查航次研究成果,系统阐述了分属3个扩张幕的西菲律宾海盆(第一扩张幕)、南海—四国海盆(第二扩张幕)和冲绳海槽(第三扩张幕)—马里亚纳海槽内的岩浆活动特点.西菲律宾海盆(扩张时代为65～35 Ma BP)从原先的赤道位置迁移至现今的位置,其内存在如似正常洋中脊玄武岩(NMORB)、洋岛玄武岩(OIB)及弧火山岩等多种岩石类型,其地球动力学背景分别与弧后扩张、地幔柱及火山弧等背景有关,其复杂的构造演化样式需要进一步研究;四国海盆(扩张时代为27 ～ 15 Ma BP)是由古伊豆—小笠原—马里亚纳弧(IBM)裂解形成的,其内除发育正常(N)—富集(E)的洋中脊玄武岩(NMORB-EMORB)外,还在扩张停止的同时出现了板内火山作用,形成了中K-超K碱性玄武岩.四国海盆的扩张模式并没有从岩石学和地质年代学角度进行明确制约,板内火山作用的地球动力学背景也不甚清楚.南海(扩张时代为32～15.5 MaBP)是由来自华南地块的一些微陆块向东南裂离后的海底扩张所形成,并在海底扩张后2 ～8 Ma出现板内火山作用,截止目前,并没有获取到洋壳基底样品,主要获取到了南海海山似OIB的玄武岩,未来需要从岩石学和地质年代学角度对南海海底扩张动力学和时代以及扩张期后的板内火山作用动力学背景进行进一步制约.马里亚纳海槽(扩张时代为5 Ma BP至今)为一年青的洋内弧后盆地,其北段处于裂解增进阶段,其内出露有似MORB(中南段)及介于似MORB与似岛弧岩石之间过渡类型的玄武岩(增进端);虽然在扩张时代上与马里亚纳海槽相当,但冲绳海槽(扩张时代为4 Ma BP至今)为一陆缘、初生弧后盆地,从西南往东北方向,不同区段处于不同的伸展发育阶段,西南段出露有似MORB岩石,中段岩石主要为玄武质岩石和流纹质岩石组成双峰组合,而东北段为中酸性火山岩.正在活动的马里亚纳海槽与冲绳海槽的岩浆作用研究应和其伴随的火山岛弧及其相邻的海沟处正在俯冲的洋壳板块结合起来,完整理解板块俯冲输入(subduction input)与弧及弧后输出(volcanic output)之间的关系,这将为揭示西太平洋地区构造演化提供重要证据.即将在西太平洋地区实施的IODP 349 ～ 352航次,为我国科学家提供了研究西太平洋地区构造演化的契机.     

Kalikorva structure and its position in the system of the northern Karelian greenstone belts: Geochemical and geochronological data

New geochemical data on volcanic rocks and the first U-Pb zircon ages for the Kalikorva structure made it possible to determine the time and conditions of their formation and constrain geodynamic models. The lower sequences of the Kalikorva structure is dominated by metatholeiites with high MgO, Cr, and Ni contents, high Mg#, and REE distribution patterns close to the mantle level. They contain rare komatiite interlayers and lenses of pyroxenites and peridotites and can be considered as products of the deep melting of mantle material. At the same time, the tholeiitic metabasalts bear island-arc signatures and are intercalated with metagraywackes and metadacites (adakites). This rock association could be formed under spreading conditions at the beginning of an island-arc regime. The upper sequence is dominated by metagraywackes and contains diverse rocks with both MORB (tholeiitic and komatiitic basalts) and island-arc (calc-alkaline andesite and dacites, subalkaline basalts, and picritic basalts) affinity, which is typical of back-arc basins. The U-Pb dating of zircons from the metadacites and detrital zircons from the metagraywackes of the Kalikorva structure yielded similar ages of 2785 ± 13 and 2766 ± 21 Ma, respectively. They coincide with the age of the late volcanic complex of the Hisovaara Group of the Hisovaara structure (2780 Ma). Both complexes include island-arc associations with subduction signatures and contain adakites, Nb-Ti basalts, and basaltic andesites. The metagraywackes and metadacites of the Chupa sequence of the Belomorian mobile belt are older than the similar rocks of the Kalikorva complex and have an age of 2870 ± 30 Ma. Ages of 2735 ± 20 Ma and 2720 ± 4 Ma were previously obtained for the metaandesites of the Kichany volcanogenic complex, which could be an even younger volcanic arc.     

Movement of lithospheric plates relative to subduction zones: Formation of marginal seas and active continental margins

Subduction zones with deep seismicity are believed to be associated with the descending branches of convective flows in the mantle and are subordinated to them. Therefore, the position of subduction zones can be considered as relatively fixed with respect to the steady-state system of convective flows. The lithospheric plate overhanging a subduction zone (as a rule of continental type) may:

1. (1) either move away from the subduction zone; or

2. (2) move onto it. In the first case extensional conditions originate behind the subduction zone and the new oceanic crust of back-arc basins forms. In the second case active Andean-type continental margins with thickening of the crust and lithosphere are observed.

Behind the majority of volcanic island-arcs, along the boundary with marginal-sea basins, independent shallow seismicity belts can be traced. They are parallel to the main seismicity belts coinciding with the Benioff zones. The seismicity belts frame island-arc microplates. Island-arc microplates are assumed to be a frame of reference to calculate relative movements of the consuming and overhanging plates. Using slip vector azimuths for shallow seismicity belts in the frontal parts of the Kurile, Japan, Izu-Bonin, Mariana and Tonga—Kermadec arcs, the position of the pole of rotation of the Pacific plate with respect to the western Pacific island-arc microplates was computed. Its coordinates are 66.1°N, 119.2°W. From the global closure of plate movements it has been determined that for the past 10 m.y. the Eurasian and Indian plates have been moving away from the Western Pacific island-arc system, both rotating clockwise, around poles at 31.1°N, 164.2°W and 1.3°S, 157.5°W, respectively. This provides for the opening of the back-arc basins. At the same time South America is moving onto the subduction zone at the rate of 4 cm/yr. Some “hot spots”, such as Hawaiian, Tibesti, and those of the South Atlantic, are moving relative to the island-arc system at a very low rate, viz. 0.5–0.7 cm/yr. Presumably, the western Pacific subduction zone and “hot spots” form a single frame of reference which can generally be used for the analysis of absolute motions.     

新疆甜水海地块种羊场石炭纪火山岩年代学和地球化学:岩石成因和地质意义

甜水海地块西段的种羊场地区发育一套互层状产出的玄武岩-玄武安山岩-流纹岩,本文对其进行了岩石学、同位素年代学和地球化学研究。结果表明,流纹岩LA-ICP-MS锆石U-Pb定年获得三组年龄:343.5±4.1Ma表明火山岩的形成时代为早石炭纪,2439±26Ma和1988±36Ma说明甜水海地块存在前寒武纪结晶基底。其中玄武质岩石岩性从拉斑系列、钙碱性系列向碱性系列过渡,呈现出E-MORB(OIB)、大陆板内拉张和岛弧的混合特征,与典型弧后盆地Okinawa玄武岩有一定的差异,表明其可能是异常陆缘弧后盆地拉张裂解的产物。玄武质岩石和流纹岩的主量元素、稀土元素和微量元素比值对的差异表明它们不是同源岩浆演化的产物,玄武质岩石的源区为类似E-MORB(OIB)的岩石圈地幔,且发生了部分熔融,原始岩浆上升过程中经历了矿物分离结晶和地壳混染作用。流纹岩属于高硅高碱的钙碱性火山岩,是上地壳部分熔融的产物。种羊场早石炭纪火山岩可能代表了古特提洋西端早期扩张的记录,为西昆仑-喀喇昆仑地区晚古生代多岛洋格局提供了新的证据。     

Potassic specifics of basalts from the Sinii Utes Depression: Geochemical correlations and problems of K-Ar dating (Southern Primorye region)

New data are reported on the structure of the sections, the geochemical composition, and the age of the volcano-sedimentary and volcanic rocks from the Sinii Utes Depression in the southern Primorye region. The Sinii Utes Depression is filled with two sequences: the lower sequence composed of sedimentary-volcanogenic coaliferous rocks (the stratotype of the Sinii Utes Formation) and the upper sequence consisting of tephroid with overlying basalts. This work addresses the geochemical composition and the problems of K-Ar dating of the basalts. The uppermost basaltic flow yielded a K-Ar age of 22.0 ± 1.0 Ma. The dates obtained for the middle and upper parts of the lava flows are underestimated, which is explained by their heating due to the combustion of brown coals of the Sinii Utes Formation underlying the lava flow. Calculations show that argon could only partly have been removed from the basalts owing to the conductive heat transfer and was lost largely due to the infiltration of hot gases in the heterogeneous fissured medium. The basaltic volcanism on the continental margins of the southern Primorye region and the adjacent Korean and Chinese areas at the Oligocene-Miocene boundary preceded the Early-Middle Miocene spreading and formation of the Sea of Japan basin. The undifferentiated moderately alkaline basalts of within-plate affinity developed in the Amba Depression and some other structures of the southern Primorye region and the within-plate alkali basalts of the Phohang Graben in the Korean Peninsula serve as an indicator of the incipient spreading regime in the Sea of Japan. Potassic basalt-trachybasalt eruptions occurred locally in riftogenic depressions and shield volcanoes; in some structures, this volcanism was terminated by eruptions of intermediate and acid lavas. Such an evolution of the volcanism is explained by the selective contamination of basaltic melts during their interaction with crustal acid material and the generation of acid anatectic melts.     

Caribbean island-arc rifting and back-arc basin development in the Late Cretaceous: Geochemical, isotopic and geochronological evidence from Central Hispaniola

We present new regional petrologic, geochemical, Sr–Nd isotopic, and U–Pb geochronological data on the Turonian–Campanian mafic igneous rocks of Central Hispaniola that provide important clues on the development of the Caribbean island-arc. Central Hispaniola is made up of three main tectonic blocks—Jicomé, Jarabacoa and Bonao—that include four broad geochemical groups of Late Cretaceous mafic igneous rocks: group I, tholeiitic to calc-alkaline basalts and andesites; group II, low-Ti high-Mg andesites and basalts; group III, tholeiitic basalts and gabbros/dolerites; and group IV, tholeiitic to transitional and alkalic basalts. These igneous rocks show significant differences in time and space, from arc-like to non-arc-like characteristics, suggesting that they were derived from different mantle sources. We interpret these groups as the record of Caribbean arc-rifting and back-arc basin development in the Late Cretaceous. The> 90 Ma group I volcanic rocks and associated cumulate complexes preserved in the Jicomé and Jarabacoa blocks represent the Albian to Cenomanian Caribbean island-arc material. The arc rift stage magmatism in these blocks took place during the deposition of the Restauración Formation from the Turonian–Coniacian transition (~ 90 Ma) to Santonian/Lower Campanian, particularly in its lower part with extrusion at 90–88 Ma of group II low-Ti, high-Mg andesites/basalts. During this time or slightly afterwards adakitic rhyolites erupted in the Jarabacoa block. Group III tholeiitic lavas represent the initiation of Coniacian–Lower Campanian back-arc spreading. In the Bonao block, this stage is represented by back-arc basin-like basalts, gabbros and dolerite/diorite dykes intruded into the Loma Caribe peridotite, as well as the Peralvillo Sur Formation basalts, capped by tuffs, shales and Campanian cherts. This dismembered ophiolitic stratigraphy indicates that the Bonao block is a fragment of an ensimatic back-arc basin. In the Jicomé and Jarabacoa blocks, the mainly Campanian group IV basalts of the Peña Blanca, Siete Cabezas and Pelona–Pico Duarte Formation, represent the subsequent stage of back-arc spreading and off-axis non-arc-like magmatism, caused by migration of the arc toward the northeast. These basalts have geochemical affinities with the mantle domain influenced by the Caribbean plume, suggesting that mantle was flowing toward the NE, beneath the extended Caribbean island-arc, in response to rollback of the subducting proto-Caribbean slab.     

Origin and crystallization history of Permian tholeiites from the Saar-Nahe trough,SW Germany

The Hirschberg and Rödern diatremes, within the Permian Saar-Nahe trough, SW Germany, are composed chiefly of basaltic tuffs, with associated small intrusions of K-rich tholeiites. Several tholeiite bodies carry 2–20 mm crystals of magnesian clinopyroxene and orthopyroxene, the latter containing up to 5.5% Al₂O₃ and often extensively resorbed and rimmed by fine-grained olivine and clinopyroxene. Experimental duplication of these pyroxenes has been achieved under conditions of Pload=6–10 kb, T=1280–1080° C and 2–4 wt.-% H₂O, confirming that they represent a rare occurence of high pressure phenocrysts in tholeiitic basalts.These conditions of pyroxene crystallization also place constraints on processes of magma generation, indicating that the tholeiites originated by partial melting of unusually hydrous peridotite mantle (0.4–0.8% H₂O) beneath a relatively thin continental crust (maximum thickness approximately 30 km). Water present in the mantle at the site of magma generation may have been derived from the dehydration of oceanic lithosphere prior to the formation of the Saar-Nahe trough. This lithosphere probably underwent subduction at the margin of the Palaeozoic European continent during the Hercynian cycle of sedimentation, andesitic volcanism and folding. The termination of this cycle was followed by a period of basin-range type tensional faulting, leading to the formation of the Permian basins of present-day Central Europe, and widespread bimodal basalt/rhyolite volcanism.     

Geological evolution of the Afro-Arabian dome

The Afro-Arabian dome includes the elevated continental regions enclosing the Red Sea, Gulf of Aden, and the Ethiopian rift system, and extends northwards as far as Jordan. It is more than an order of magnitude larger than other African uplifts. Both the structures and the igneous rocks of the dome appear to be products of the superimposition of two, perhaps three, semi-independent generating systems, initiated at different times but all still active. A strain pattern dominated by NW-trending basins and rifts first became established early in the Cretaceous. By the end of the Oligocene, much of the extensional strain had been taken up along the Red Sea and Gulf of Aden axes, which subsequently developed into an ocean. Palaeogene “trap” volcanism of mildly alkaline to transitional character was related to this horizontal extension rather than to doming. Further west, the East Sahara swell has a history of intermittent alkaline volcanicity which began in the Mesozoic and was independent of magmatism in the Afro-Arabian dome. Volcanicity specifically related to doming began in the Miocene along a N-S zone of uplift extending from Ethiopia to Syria. This elongated swell forms the northern termination of the East African system of domes and rifts, characterized by episodic vertical uplift but very little extension. Superimposition of epeirogenic uplift upon structures formed by horizontal extension took place in the Neogene. Volcanicity related to vertical tectonics is mildly alkaline in character, whereas transitional and tholeiitic magmas are found along the spreading axes.     

The Haraa Gol terrane in the western Hentiyn Mountains (northern Mongolia): geochemistry,geochronology, and geodynamics

According to geological, petrological, geochemical, and geochronological studies, the Haraa Gol terrane in the western Hentiyn Mts. is dominated by two rock assemblages of different ages, associated with the initiation and development of the island arcs and marginal spreading seas of the Mongol–Okhotsk Ocean. The Late Cambrian, Early Ordovician, and Middle Ordovician were marked by the effusion of basalt and basaltic andesite and the formation of gabbro and gabbro-dolerite in back-arc spreading basins. In the Late Silurian–Devonian, after a short pause, tectonomagmatic processes were activated, with the formation of differentiated island-arc volcanics, gabbro, and granitoids. Their absolute ⁴⁰Ar–³⁹Ar age is given in the paper. The model age of the T_Nd(DM) protolith of the Haraa Gol igneous rocks corresponds to the composition of the Mesoproterozoic juvenile crust.     

Potassic and low- and high-Ti mildly alkaline volcanism in the Neoproterozoic Ramada Plateau, southernmost Brazil

Ramada Plateau Neoproterozoic volcanism represents a portion of the shoshonitic and mildly alkaline magmatism related to postcollisional events of the Brasiliano/Pan African cycle of southernmost Brazil. It is constituted by shoshonitic basic-intermediate lavas, followed by a bimodal sequence characterized by pyroclastic deposits, lava flows, and hypabyssal rocks with ages of 549±5 Ma. The shoshonitic magmatism presents greater K₂O than Na₂O₂, K₂O/Na₂O ratios close to 1, and moderate large ion lithophile and high-field strength element contents. The bimodal basic-acid volcanism presents a transitional chemical affinity with features of sodic, silica-saturated alkaline to continental tholeiitic series. Observed basic and acid rocks with contrasting Ti contents are referred to as high- and low-Ti basalt-rhyolites. Another group of acid rocks with higher Nb, Ta, and Rb values was identified as high-Nb rhyolites. The Ramada Plateau magmatism is comparable to associations related to the final stages of orogenic cycles, in which shoshonitic and high- and low-Ti alkaline magmatism reflects the melting of subduction-modified sources, whereas the high-Nb magmas show less influence of subduction-related metasomatism and are closer to magmas produced from anorogenic sources. A model of magma generation in collisional settings involving slab break-off and asthenospheric upwelling is applied to the evolution of magmatism from subduction-related to anorogenic in the Ramada Plateau.     

Basalt geochemistry as a diagnostic indicator of tectonic setting

Basalt geochemistry can be used as a diagnostic indicator for determining the tectonic setting of origin, because specific plate tectonic settings often impart distinctive geochemical characteristics. For example: (1) mid-ocean ridge basalts (MORB) and oceanic island basalts (OIB) have clearly distinguishable trace element and Sr-Nd isotope geochemical characteristics; (2) arc related basalts, including IOAB (intra-oceanic arc basalts), IAB (island arc basalts) and CAB (continental arc basalts), exhibit following distinguishing features: all are characterized by low Nb/La ratios (<0.85) and negative Nb, Ta and Ti anomalies; most exhibit low Nb concentrations (<8 ppm), high positive ɛ_Nd values and low enrichment of incompatible elements except the continental arc shoshonitic basalts that possess high concentrations of incompatible trace elements and lower to negative ɛ_Nd values; (3) although contamination by continental crust or lithosphere can impart subduction-like signature (e.g., low Nb, low Ta and low Ti) and lead to misidentification of contaminated continental intraplate basalts as arc related, there are still some essential differences between continental intraplate basalts and arc related ones; such as: uncontaminated continental intraplate basalts have high Nb concentrations, Nb/La > 1, “hump-shaped” OIB-like trace element patterns and moderate positive ɛ_Nd values that distinguish them from the arc related ones; whereas, the contaminated continental intraplate basalts are characterized by pronounced negative Nb, Ta and Ti anomalies, but their concentrations of incompatible trace elements are conspicuously higher than those of subduction-zone basalts that also distinguishes them from the arc related ones; (4) an important difference between back-arc basin basalts (BABB) and the MORB is that the former exhibit both MORB-like and arc-like geochemical characteristics; (5) most oceanic plateau basalts (OPB) show diagnostic geochemical characteristics of enriched MORB (E-MORB) to transitional MORB (T-MORB); only the Kerguelen Plateau is an exception; the early (pre 90 Ma) volcanism of the Kerguelen Plateau is associated with the Early Cretaceous break-up of Gondwana and displays features of continental flood basaltic volcanism; with time, the tectonic setting of the Kerguelen plume-derived volcanism changed from a rifted continental margin setting (133–118 Ma) through a young, widening ocean (118–40 Ma), finally to an oceanic intraplate setting (~40 Ma to the present).Tectonic discrimination diagrams should not be used in isolation, but can still be useful as part of holistic geochemical characterization. For example: (1) MORB and OIB are distinguishable from each other in the 3Tb-Th-2Ta diagram; (2) the arc related basalts, including IOAB, IAB and CAB, constantly plot in the arc-related basalts fields in the Th/Yb-Ta/Yb diagram; (3) the 3Tb-Th-2Ta diagram can be utilized to fully illustrate both MORB-like and arc-like characteristics of BABB; (4) some discriminant diagrams (such as Zr/Y-Zr, Th/Yb-Ta/Yb, 3Tb-Th-2Ta and Hf/3-Th-Nb/16 diagrams) can be used to distinguish continental intra plate basalts from arc related ones; (5) although there are not any discrimination diagrams published that delineate an OPB field, some trace element diagrams can still reveal diagnostic characteristics of the OPB.     

Geochemistry and petrogenesis of volcanic rocks of the Neoarchaean Sukumaland Greenstone Belt, northwestern Tanzania

The late Archaean volcanic rocks of the Rwamagaza area in the Sukumaland Greenstone Belt consists of basalts and basaltic andesites associated with volumetrically minor rhyodacites and rhyolites. Most basalts and basaltic andesites yield nearly flat patterns (La/Sm_CN = 0.89–1.34) indicating derivation by partial melting of the mantle at relatively low pressure outside the garnet stability field. On primitive mantle normalized trace element diagrams, the basalts and basaltic andesites can be subdivided into two groups. The first group is characterised by moderately negative Nb anomalies (Nb/La_pm = 0.51–0.73, mean = 0.61 ± 0.08) with slight enrichment of LREE relative to both Th and HREE. The second group is characterised by nearly flat patterns with no Nb anomalies (Nb/La_pm = 0.77 ± 0.39). The observed Nb and Th anomalies in the Rwamagaza basalts and basaltic andesites, cannot be explained by alteration, crustal contamination or melt–solid equilibria. Rather, the anomalies are interpreted, on the basis of Nb–Th–La–Ce systematics, as having formed by partial melting of a heterogeneous mantle consisting of variable mixtures of components derived from two distinct sources. These sources are depleted mantle similar to that generating modern MORB and an LREE-enriched and HFSE-depleted source similar to that feeding volcanism along modern convergent margins.The rhyolites are characterised by high Na₂O/K₂O ratios (>1) and Al₂O₃ (>15 wt.%), low HREE contents (Yb = 0.24–0.68 ppm) leading to highly fractionated REE patterns (La/Yb_CN = 18.4–54.7) and large negative Nb anomalies (Nb/La_pm = 0.11–0.20), characteristics that are typical of Cenozoic adakites and Archaean TTG which form by partial melting of the hydrated basaltic crust at pressures high enough to stabilize garnet ± amphibole. The Rwamagaza basalts and basaltic andesites are geochemically analogous to the Phanerozoic Mariana Trough Back Arc Basin Basalts and the overall geochemical diversity of Rwamagaza volcanic rocks is interpreted in terms of a geodynamic model involving the interaction of a depleted mantle, a melting subducting oceanic slab in a back arc setting.     

Erratum to: Review of post-collisional volcanism in the Central Anatolian Volcanic Province (Turkey), with special reference to the Tepekoy Volcanic Complex

Neogene-Quaternary post-collisional volcanism in Central Anatolian Volcanic Province (CAVP) is mainly characterized by calc-alkaline andesites-dacites, with subordinate tholeiitic-transitional-mildly alkaline basaltic volcanism of the monogenetic cones. Tepekoy Volcanic Complex (TVC) in Nigde area consists of base surge deposits, and medium to high-K andesitic-dacitic lava flows and basaltic andesitic flows associated with monogenetic cones. Tepekoy lava flows petrographically exhibit disequilibrium textures indicative of magma mixing/mingling and a geochemisty characterized by high LILE and low HFSE abundances, negative Nb–Ta, Ba, P and Ti anomalies in mantle-normalized patterns. In this respect, they are similar to the other calc-alkaline volcanics of the CAVP. However, TVC lava flows have higher and variable Ba/Ta, Ba/Nb, Nb/Zr, Ba/TiO₂ ratios, indicating a heterogeneous, variably fluid-rich source. All the geochemical features of the TVC are comparable to orogenic andesites elsewhere and point to a sub-continental lithospheric mantle source enriched in incompatible elements due to previous subduction processes. Basaltic monogenetic volcanoes of CAVP display similar patterns, and HFS anomalies on mantle-normalized diagrams, and have incompatible element ratios intermediate between orogenic andesites and within-plate basalts (e.g. OIB). Accordingly, the calc-alkaline and transitional-mildly alkaline basaltic magmas may have a common source region. Variable degrees of partial melting of a heterogeneous source, enriched in incompatible elements due to previous subduction processes followed by fractionation, crustal contamination, and magma mixing in shallow magma chambers produced the calc-alkaline volcanism in the CAVP. Magma generation in the TVC, and CAVP in general is via decompression melting facilitated by a transtensional tectonic regime. Acceleration of the extensional regime, and transcurrent fault systems extending deep into the lithosphere favoured asthenospheric upwelling at the base of the lithosphere, and as a consequence, an increase in temperature. This created fluid-present melting of a fluid-enriched upper lithospheric mantle or lower crustal source, but also mixing with asthenosphere-derived melts. These magmas with hybrid source characteristics produced the tholeiitic-transitional-mildly alkaline basalts depending on the residence times within the crust. Hybrid magmas transported to the surface rapidly, favored by extensional post-collision regime, and produced mildly alkaline monogenetic volcanoes. Hybrid magmas interacted with the calc-alkaline magma chambers during the ascent to the surface suffered slight fractionation and crustal contamination due to relatively longer residence time compared to rapidly rising magmas. In this way they produced the mildly alkaline, transitional, and tholeiitic basaltic magmas. This model can explain the coexistence of a complete spectrum of q-normative, ol-hy-normative, and ne-normative monogenetic basalts with both subduction and within-plate signatures in the CAVP.     

Petrology of the Ninety East Ridge (Indian Ocean) compared to other aseismic ridges

The volcanics from the Ninety East Ridge in the Indian Ocean consist of basalts and oceanic andesites. The basalts from the Ninety East Ridge differ from the Mid-Indian Oceanic Ridge basalts in their higher pyroxene content, their higher Fe₂O₃ + FeO content (>11%), higher TiO₂ content (2–3%), and variable K₂O content (0.2–1.5%). Volcanics from other aseismic ridges, i.e. the Cocos, the Iceland-Faeroe and the Walvis ridges, show a trend of differentiation which has progressed further than is commonly encountered on mid-oceanic ridge rocks. The Ninety East and the Iceland-Faeroe ridges contain mildly tholeiitic basalts and oceanic andesites while the Walvis and the Cocos Ridges consist of plagioclase-alkali basalts, trachybasalts and trachytes. The majority of basalts found on aseismic ridges have a higher total iron oxide content (>11%) and a more variable K₂O (2–3%) and TiO₂ (1.5–4%) content than mid-oceanic ridge basalts. The type of volcanism encountered on aseismic ridges is similar to that of the islands which are near or associated with the ridges.     

http://www.sciencedirect.com/science/article/pii/S1674987112001533

The collision of a divergent ocean ridge may evolve into two end cases:in the continuity of ocean-floor subduction.or in the detachment of the subducted plate.The northern Patagonia active plate margin has the unique situation that in Cenozoic time it has been subjected to two divergent ridge collisions,each one representing one of the end members.The Neogene Antarctica-Nazca divergent ridge collision evolved as a continuous ocean-floor subduction system,promoting a magmatic hiatus at the arc axis,the obduction of part of the ridge ocean-floor in the fore-arc.and basaltic volcanism in the back-arc.In contrast,the Paleogene Farallon-Aluk divergent ridge collision evolved into a transform margin,with the detachment and sinking of the Aluk plate and the development of a large slab window.As in the previous case,this collision promoted a magmatic hiatus at the arc axis,but the tectono-magmatic scenario changed to postorogenic synextensional volcanism that spread to the former fore-arc（basalt,andesite,rhyolite） and former back-arc（bimodal ignimbrite flare-up,basalt）.Geochemistry of this slab window synextensional volcanism shows more MORB-like basalts towards the former fore-arc,and MORB-OIB-like basalts towards the former back-arc.Instead,an isolated undeformable crustal block in the former back-arc,with an "epeirogenic" response to the slab window and extensional regime,was covered by OIB-type basalts after uplift.Major elements show that slab window basalts reach TiCh values up to 3 wt%,as compared with the top value of 1.5 wt%of arc magmas.Besides,the MgO with respect to（FeO^t + Al₂O₃） ratio helps to distinguish slab window magma changes from the former fore-arc to the former back-arc and also with respect to the "epeirogenic" block.Higher contents of HFS elements such as Nb and Ta also help to distinguish this slab window from arc magmas and also,to distinguish slab window magma changes from the former fore-arc to the former back-arc and "epeirogenic" block settings.The isotope compositions of slab window magmatism show a disparate coeval array from MORB to crustal sources,interpreted as a consequence of the lack of protracted storage and homogenization due to the extensional setting.