大别山榴辉岩岩石学及地球化学特征

本文分析了大别山地区榴辉岩的产出特点,矿物化学、岩石化学及元素地球化学特征。所获资料表明大别山榴辉岩与围岩一起经历了超高压变质作用,但其化学成分特征与围岩存在一定的差异,兼有大陆玄武岩和大洋玄武岩的特征。这些岩石大部分可能为板块俯冲过程中带入的大洋岩石残片。在深部变质形成榴辉岩后又随大别杂岩一起被抬升到地表,在抬升过程中经历了不同程度的退变质作用。     

大别山碧溪岭未经历超高压变质的片麻状花岗岩

关于大别山超高压变质带中与榴辉岩密切伴生的花岗片麻岩是否也经历了超高压变质作用一直是个争议的问题。笔者最近在碧溪岭片麻状花岗岩中首次发现了可靠的岩相学和矿物学证据 ,证明该岩石只遭受到绿片岩相变质作用的改造 ,而未曾记录超高压变质矿物组合。根据片麻状花岗岩与围岩接触部位强烈糜棱岩化的发育 ,认为超高压岩石在抬升到地壳范围时与以花岗质岩石为主构成的扬子陆壳发生了大规模的构造并置。     

桐柏—大别山构造混杂岩带对比研究

桐柏—大别山造山带地球化学、变质作用以及野外地质调查研究表明：七角山岩组和浒湾岩组是具有相似构造环境、形成于晋宁期的构造混杂岩。高压榴辉（闪）岩原岩是形成多种构造环境的变玄武岩，桐柏固庙、信阳柳林高压榴闪岩的发现说明区内高压变质带沿北坡向西延伸。定远岩组、随县岩群、耀岭河岩群反映了板块拼合后所形成的陆内裂谷、造山后火山弧环境     

苏鲁超高压变质带东北端多种成因类型变基性岩:来自岩石学、同位素年代学及地球化学属性的制约

苏鲁超高压变质带是扬子板块与华北板块在三叠纪俯冲-碰撞的产物。变基性岩是苏鲁超高压变质带内出露最广泛的岩石类型之一,研究其岩石学、年代学、地球化学属性及成因机制,对于揭示扬子板块与华北板块之间的俯冲-碰撞-折返的动力学过程具有重要的科学意义。以(退变)榴辉岩为代表的超高压变质岩石广泛出露在威海-荣成一带,少量出露在乳山地区。锆石LA-ICP-MS U-Pb定年结果显示,(退变)榴辉岩的原岩时代为792~760Ma,峰期榴辉岩相变质时代为243~226Ma,后期角闪岩相退变质时代为221~207Ma。非榴辉岩相变质的基性岩(麻粒岩和斜长角闪岩)主要出露在乳山地区,其原岩形成时代应不晚于古元古代(1939Ma),峰期麻粒岩相变质时代为1895~1870Ma,后期角闪岩相退变质时代为1848~1806Ma,与胶北地体变基性岩的原岩时代和变质时代十分相似。全岩地球化学研究结果表明,(退变)榴辉岩的原岩显示高Fe拉斑玄武岩的特点,根据其稀土和微量元素特征,可将(退变)榴辉岩进一步划分为A、B和C三组。在球粒陨石标准化稀土配分模式和原始地幔均一化蛛网图解上,A、B和C三组样品分别具有轻稀土弱亏损、轻稀土弱富集和轻稀土富集的特点。轻稀土富集或弱富集型(退变)榴辉岩的原岩地球化学性质与岛弧或大陆玄武岩相似,它们的源区可能与深部富集地幔或受流体交代的地幔楔存在密切的成因关系;而轻稀土亏损型(退变)榴辉岩的原岩可能来自于亏损地幔的部分熔融。由此可见,(退变)榴辉岩的原岩具有成因多样性的特点。乳山地区的基性麻粒岩和斜长角闪岩的原岩也具有高Fe拉斑玄武岩的地球化学属性,Al2O3与Mg O呈正相关变化,TiO_2、P_2O_5与MgO表现出一定程度的负相关性。绝大多数非榴辉岩相变质基性岩的球粒陨石标准化稀土配分模式和原始地幔均一化蛛网配分曲线具有微右倾或明显右倾的特点。上述特征表明,研究区绝大多数非榴辉岩相变质的基性岩原岩来自于富集地幔,少数来自于原始地幔或亏损地幔,并经历了斜长石和辉石的分离结晶以及不同程度的部分熔融过程。由此可见,乳山地区出露的非超高压变质基性岩的原岩具有与胶北地体(高压)基性麻粒岩相近的成因特点。岩石学、同位素年代学和地球化学特征的综合对比研究结果表明,在苏鲁超高压变质带东北端的威海-荣成-乳山地区,既存在与华北板块古老变质基底相关的变基性岩,也存在与华南板块北缘新元古代变质基底相关的超高压榴辉岩,表明三叠纪时期华北板块东南缘胶北地体的部分古老变质基底曾卷入到扬子板块与华北板块之间的俯冲-碰撞造山过程,随后与超高压岩石一起抬升折返,形成当今的构造混杂岩带。     

大别山超高压变质带中牛凸岭地区低温-高压榴辉岩的发现及其意义

依据时南大别超高压带腹地的榴辉岩野外地质调查、岩相学和热力学的研究表明,南大别腹地--牛凸岭地区榴辉岩属于低温高压榴辉岩,并未经历超高压变质作用.该地区榴辉岩的共生围岩主要为片岩、片麻岩和斜长角闪岩,石榴石多为自形-半自形,内含大量的早期矿物包体,峰期变质温压条件分别为:T=360～520℃;P=1.3～2.4GPa.对比南大别超高压榴辉岩形成的变质条件,两者压力差可达0.7GPa,约20km厚的地壳深度缺失.结合构造分析牛凸岭单元更类似于桐城-源潭铺高压块体,推测其属于构造上层部位岩片.     

北大别超高压榴辉岩的快速折返与缓慢冷却过程

岩石学研究表明,北大别超高压榴辉岩经过了超高压和高压榴辉岩相变质作用以及麻粒岩相叠加和角闪岩相退变质作用.其中,高压麻粒岩相和角闪岩相变质阶段形成的后成合晶以及石榴子石和单斜辉石等矿物中成分分带的存在,证明该区榴辉岩经历了一个快速折返过程;而不同变质阶段的温度、压力和形成时代,却反映该区榴辉岩在峰期超高压变质作用之后又经历了一个缓慢冷却过程.超高压岩石折返期间的缓慢冷却过程也许正是北大别长期难以发现柯石英和有关超高压证据的重要原因.因此,本文为大别山不同超高压岩片的差异折返模型的建立提供了新的证据.     

安徽省大别山东段江岭地区榴辉岩及其围岩的变质作用研究

安徽省大别山东段江岭地区的南大别碰撞杂岩主要由榴辉岩、云母片岩－变粒岩及片麻岩系组成,这三套岩石具有不同的变质演化阶段和Ｐ－Ｔ轨迹：榴辉岩有５个变质阶段,早期出现超高压型、高压型、晚期为中压型;云母片岩－变粒岩有４个变质阶段,早期出现高压型,晚期为中压型;片麻岩系仅有一期中压绿帘角闪岩相变质。三套岩石变质历史的差异,反映其所经历的构造过程不同,三者在构造作用下混杂到一起,构成碰撞混杂岩。     

大别山北缘凤凰台组砾石地球化学特征及源区构造环境

根据大别山北缘合肥盆地凤凰台组暨毛坦厂组中的榴辉岩、角闪岩、斜长片麻岩等砾石地球化学研究,SiO2含量为43.31%～57.35%,原岩主要为古橄玄武岩-玄武岩-玄武安山岩-玄武粗安岩组成的火山岩,其次为斜长岩和辉绿玢岩等侵入岩.与原始地幔相比,岩石具有LILE富集、Nb-Ta负异常槽明显、Ti强烈亏损等特征.它们可能属于一个由苦橄玄武岩、拉斑玄武岩、英安岩和流纹岩等组成的火山弧,是一个SSZ型岛弧.砾石原岩与北大别杂岩("古岛弧根带")中的镁铁-超镁铁岩带、片麻岩等有成因上的联系.砾石主要不是直接来源于现在遭受剥露的"古岛弧根带",而可能是来自上部的火山弧.     

Metamorphic history of glaucophane‐paragonite‐zoisite eclogites from the Shanderman area,northern Iran

The Shanderman eclogites and related metamorphosed oceanic rocks mark the site of closure of the Palaeotethys ocean in northern Iran. The protolith of the eclogites was an oceanic tholeiitic basalt with MORB composition. Eclogite occurs within a serpentinite matrix, accompanied by mafic rocks resembling a dismembered ophiolite. The eclogitic mafic rocks record different stages of metamorphism during subduction and exhumation. Minerals formed during the prograde stages are preserved as inclusions in peak metamorphic garnet and omphacite. The rocks experienced blueschist facies metamorphism on their prograde path and were metamorphosed in eclogite facies at the peak of metamorphism. The peak metamorphic mineral paragenesis of the rocks is omphacite, garnet (pyrope‐rich), glaucophane, paragonite, zoisite and rutile. Based on textural relations, post‐peak stages can be divided into amphibolite and greenschist facies. Pressure and temperature estimates for eclogite facies minerals (peak of metamorphism) indicate 15–20 kbar at ~600 °C. The pre‐peak blueschist facies assemblage yields <11 kbar and 400–460 °C. The average pressure and temperature of the post‐peak amphibolite stage was 5–6 kbar, ~470 °C. The Shanderman eclogites were formed by subduction of Palaeotethys oceanic crust to a depth of no more than 75 km. Subduction was followed by collision between the Central Iran and Turan blocks, and then exhumation of the high pressure rocks in northern Iran.     

变质地质学新领域——超高压变质作用与地球动力学

简要总结了近年在欧亚大陆发现的超高压变质岩地质产状，岩石类型，结晶条件和构造位置等基本特片，对超高压变质作用及其地球动力学机制的研究现状及存在的问题进行了评述，基于对大别－苏鲁超高压变质带的研究成果，认为超高压变质作用可能是新型的区域变质作用，而目前所建立的任何一种地球动力学模型都不完善，建议今后在岩石学和矿物学研究基础上，加强对超高压变质杂岩的地球化学，构造地质学，实验岩石学及地球物理学等方面的     

Constraints on the early cooling rates of Mt. Dabie from diffusion modeling of chemical zoning of garnet

Diffusion modeling of zoning profiles in eclogite garnets from three different tectonic units of Mt. Dabie, UHPM unit, HPM unit and northern Dabie, was used to estimate the relative time span and cooling rates of these rocks. Modeling result for the Huangzhen eclogite garnet shows that the maximal time span for the diffusion-adjustment process is about 22 Ma since the peak-temperature metamorphism, which is the maximum time span from amphibolite facies metamorphism to greenschist facies metamorphism. The Bixiling eclogites had subjected to a cooling process at a rate of - 10℃/Ma from 750℃ to 560℃ during 20 Ma. The second cooling stage of the Raobazhai eclogite following granulite-facies metamorphism is an initial fast cooling process at a rate of about 25℃/Ma and then slowed down gradually. All these belong to a coherent Dabie collision orogen with differences in subduction depth and exhumation/uplifting path.     

Trace-element abundances of iron-rich eclogites,with implications on the geodynamical evolution of the Voltri Group (Pennidic Belt)

Fe (136,900 ppm)- and Ti (28,540 ppm)-rich eclogites contained in the Voltri serpentinites show contents of metallic trace elements different from those of other eclogites described so far, both those of ophiolitic type and those included in ultramafic rocks. The Voltri eclogites are enriched in Mn (1,894 ppm), V (610 ppm), and Co (75 ppm) and depleted in Cr (110 ppm), Ni (56 ppm), and Zr (46 ppm) in comparison with other occurrences. The analyzed samples are: twelve flaser-eclogites, four fine-grained bimineralic eclogites and three eclogites showing an advanced degree of retrometamorphism toward greenschist facies. The given average values (in ppm) are based on nineteen analyzed samples. This trace-element content is believed to reflect the highly fractionated tholeiitic character of the eclogites and suggests that the Voltri rocks originated from the isochemical metamorphism of ferrogabbros which were probably intruded into the serpentinized lherzolites of a mid-oceanic ridge at the time of the opening of the Pennidic trough.     

PTtD Path and Fluid Evolution of HighPressure Eclogites from the Dabie Mountains,Central East China

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大别山超高压变质带中“脉状”榴辉岩的锆石U-Pb年龄

榴辉岩广泛分布于大别山超高压变质带中,出露规模大小不等,成因类型复杂,围岩类型多样,不仅产于基性、超基性岩中,还产于片麻岩、大理岩、石英硬玉岩、变质花岗岩中。对大别山超高压变质带出露的两处"脉状"榴辉岩进行锆石U Pb年龄测定,分别获得上交点年龄(858±25)Ma和(845±150)Ma,下交点年龄(249±20)Ma和(237±13)Ma,表明其原岩形成时代为新元古代,印支期发生过高压—超高压变质作用,与大别山超高压变质带中其他类型的榴辉岩年龄基本一致。     

大别造山带北部石竹河片麻岩的锆石U—Pb年龄及其地质意义

大别造山带北部石竹河二长片麻岩的锆石U-Pb年龄测定结果表明,其原岩形成时代为707±42Ma,在229±18Ma曾受到高温变质作用。这一结果表明印支期变质作用不仅反映在大别造山带南部的变质岩中,而且造山带北部的部分变质岩也保存了这一重要记录。大别造山带北部存在印支期变质年龄的片麻岩、榴辉岩或残留相表明,该地块与造山带南部一样是印支期板块俯冲碰撞中俯冲板块的一部分。华北和扬子板块的碰撞缝合线可能位于大别造山带的北侧。     

北大别的高温超高压变质作用与多阶段折返

近期的变质岩石学、地球化学及同位素年代学研究表明,北大别整体经历了高温超高压变质作用和多阶段折返历史,因而表现为广泛发育的多期减压结构和极少保留早期的超高压变质记录。北大别榴辉岩以高温变质作用以及折返期间因麻粒岩相和角闪岩相退变质变质作用而形成的多期后成合晶为显著特征。石榴子石中伴有放射状胀裂纹的单晶和多晶石英包体指示早期柯石英的转变结果,这已被锆石中发现的柯石英残晶所证实。结合北大别北部榴辉岩和片麻岩中发现的金刚石等超高压证据以及三叠纪变质记录,由此证明北大别整体经历过深俯冲和印支期超高压变质作用。北大别榴辉岩的多阶段高温条件主要来自石榴子石-绿辉石矿物对温度计、单斜辉石中紫苏辉石+石英针状矿物出熔体以及金红石中较高的Zr含量和变质锆石中较高的Ti含量等得出的温度证据。此外,多期后成合晶以及石榴子石和单斜辉石等矿物中成分分带的存在,证明该区榴辉岩经历了一个多阶段、快速折返过程;而不同变质阶段的温度、压力和形成时代,却反映该区榴辉岩经历了长时间的高温变质演化与缓慢冷却过程。长时间的高温变质作用与缓慢冷却过程也许正是北大别长期难以发现柯石英和有关超高压记录的重要原因。因此,这些成果为大别山三个不同超高压岩片的差异折返模型的建立提供了新的证据。     

Tectonic Affinity, T-t Path and Uplift Trajectory of Eclogites from Northern Dabie Mountains, Central-Eastern China

INTRODUCTIONTheDabieMountainsaretheeasternsectionoftheE WtrendingQinling DabieorogenicbeltbetweentheNorthChinablockandYangtzeblock ,andistransectedatitseasternendbyTan Lufault.Ultrahigh pressuremetamorphic (UHPM)rocksincludingcoesites (Okayetal.,1989;Wangetal.,1989)andmicrodiamonds (Xuetal.,1992b)bearingeclogitesareexposedintheDabieMountainsandSu Luorogen ,whichisthelargestUHPMbeltontheearthsurface .TheUHPMrocksarecomposedofdifferentkindsofmetamorphicrockssuchascoesite anddiamo…     

大别超高压变质过程中流体作用的微量元素效应及其地球化学意义

对大别地区角闪岩相－麻粒岩相和榴辉岩相岩石进行较系统的地球化学研究,探讨了超高压俯冲变质及折返过程中元素的再分配行为,并就其对变质过程中的部分熔融作用和流体交代作用的指示进行了分析。研究表明,大别榴辉岩原岩在其俯冲过程中发生了部分熔融作用,并在其早期脱水和后期退变质作用过程中与变质流体相之间产生了交换。脱水作用使榴辉岩Ｎｂ／Ｔａ比值升高,但后期的退变质作用使榴辉岩与其寄主围岩间的Ｎｂ／Ｔａ比值相对     

Petrology and Mineralogy of Eclogite and Garnet Amphibolite from Puerto Cabello, Venezuela

Occurrences of eclogite, eclogite-amphibolite, and garnet amphibolitefrom Puerto Cabello, Venezuela are described. Chemical analysesof thirteen rocks, eight garnets, six clinopyroxenes, and nineamphiboles are presented. Field evidence shows that the eclogitesand associated mafic rocks occur as sheets or lenses conformablewith pelitic and calcareous rocks and have been metamorphosedin situ. The associated country rocks have attained a metamorphicmineral assemblage typical of the epidote-amphibolite facies.The chemical composition of the eclogite and associated rocksis variable but is essentially that of tholeiitic basalt. Clino-pyroxenesfrom the eclogites are omphacites containing 34–51 moleper cent jadeite and the remainder largely diopside; coexistinggarnets contain approximately 50 mole per cent almandine, 24mole per cent pyrope, 25 mole per cent grossular+andradite,and 1 mole per cent spessartine. Determinations for the temperatureof metamorphism of these rocks give approximately 525±50°C. Determinations of total pressure of metamorphism, basedon the jadeite content of omphacite, on glaucophane II, kyanite,and calcite stability fields, and on stratigraphic reconstructionsgive a range of values between 5 and 10 kb with a most probablevalue near 7 kb. These data suggest a moderate geothermal gradientduring metamorphism of approximately 20 °C/km. An evaluationof the role of volatiles during metamorphism indicates thatthe original basalts were converted to eclogites in an environmentclosed to water and carbon dioxide. The field relationshipsat Puerto Cabello demonstrate the general instability of eclogite;the great majority of mafic rocks are amphibolites, garnet amphibolites,and eclogite-amphibolites. Eclogites, sensu stricto, are preservedonly in random ‘dry’ pockets within the stratigraphicsection containing the metabasalts. The transformation of basaltto eclogite to amphibolite is considered to have been a continuousparagenetic sequence during a single pseriod of metamorphism.     

大别造山带中镁铁质——超镁铁质岩石和榴辉岩有关问题的讨论

根据近年来积累的文献资料及研究讨论指出：（１）大别山造带镁铁质－－超镁铁质岩石可分成两大类;一类以任家湾、童家冲、祝家铺道士冲、青山、沙河等辉石辉长岩类为代表,它们具有相同的牲和成岩年龄,可能与华北、华南地块聚敛碰产生的岛弧或大陆岩浆岩有关;另一类以铙拔寨,大化坪、碧溪岭和毛屋岩体为代表,虽然它们的成岩年龄均在前寒武纪,但却有着不同的成岩时代和成岩环境。（２）大别造山带榴辉岩等多属异地来源,具有不