Carbonaceous aerosols of aviation and shipping emissions

This is a study of the physical and chemical properties of carbonaceous aerosols emitted by transport systems (namely, by aircraft gas turbine engines and large ship diesel engines) into the atmosphere. A comparative analysis of the morphology, size, elemental composition, and surface chemistry between aviation and diesel soot particles reveals the general and characteristic features of emissions from each source. The high pollution rate of diesel soot particles, considerable fraction of metal admixtures, and availability of char particles characterize the specific features of the formation of particles of this type. The main characteristics characterizing the interaction between aviation and shipping emission aerosols in the moist atmosphere (the composition of organic and water-soluble fractions at the surface) have been obtained. Due to high hygroscopicity, the microparticles can generate cloud condensation nuclei and initiate contrails and additional tropospheric cloudiness.     

Aircraft-generated soot aerosols: Physicochemical properties and effects of emission into the atmosphere

This review describes the new results of analysis of both the physicochemical properties of soot particles emitted by commercial aircraft and subsequent variations in these properties under aircraft-contrail conditions. The results of the study of model laboratory soot samples are given for comparison. The state-of-the-art level of experimental studies of hygroscopicity of soot particles and their efficiency as crystallization centers are presented. The ability of soot aerosols to form condensation nuclei in aircraft contrails and ice nuclei in the upper troposphere is estimated. The estimates of the effects of aircraft soot emissions into the atmosphere are given.     

Structure and optical properties of soot aerosol in a moist atmosphere: 2. Influence of hydrophilicity of particles on the extinction, scattering, and absorption coefficients

The optical coefficients of soot particles are measured in a flow-through optical cell at the wavelength 635 nm in a dry atmosphere and in an atmosphere saturated with water vapor. Two types of systems modeling atmospheric soot aerosols and differing in the degree of hygroscopicity of their particles are investigated and compared. One of the systems contains hydrophobic acetylene soot, and the other contains hydrophilic soot obtained through modification of the initial soot by vapors of glutaric acid. The results show that the optical properties of hydrophobic soot depend only slightly on the conditions of moistening, whereas the optical properties of hydrophilic soot change abruptly upon its moistening because of the formation of a hydrate shell. In the atmosphere saturated with water-vapor, the monomolecular layer of a hydrophilic organic substance leads to the watering of particles and an abrupt (more than twofold) increase in the cross section of light scattering. A further growth of the hydrophilic component of soot particles initiates the formation of micron drops on them, thus resulting not only in the natural effect of light scattering enhancement but also in a noticeable light absorption increase. In particular, a light absorption enhancement by a factor of 3.5 is characteristic of particles of enriched hydrophilic soot.     

Filter-based differential hygroscopicity analyzer of aerosol particles

We describe a new differential analyzer implementing a technique for studying the hygroscopic properties of filter-precipitated aerosol particles based on a katharometric measurement of the amount of water vapor absorbed by an aerosol sample. The instrument has been tested on particles of sodium chloride and ammonium sulphate. A comparison of our data with the results of analogous measurements described in literature shows that the suggested technique has several important advantages, i.e., (1) higher sensitivity, which allows the measurement of particles of no more than 0.1 mg in mass; (2) a wide range of relative humidity variations (up to 99% at an accuracy of 0.06% RH at the upper-range value); (3) the absence of intermediate measurement steps connected with the need to account for water absorption by elements of a measurement system; and (4) the absence of restrictions to the size and shape of particles studied. In addition, the measurement technique rules out the possibility of errors caused by the kinetic effects of mass transport in the aerosol-water vapor system.     

Influence of chemical composition and microstructure on the hygroscopic growth of pyrogenic aerosol

The hygroscopic properties of a model smoke aerosol series including ammonium sulfate, levoglucosan, and oxalic and humic acids were investigated. The condensation growth of particles and the relative humidity of direct and inverse particle-droplet phase transitions were measured with a tandem differential mobility analyzer. The data were obtained in the range of relative humidity from 4 to 95% at 298 K. Experimental growth factors were compared to the results of Koehler theory by using contemporary models of water activity in particles. It was shown that the hygroscopic properties of the aerosols were substantially different from the hygroscopic properties of the corresponding bulk phases. It was found that a complex microstructure of nanoparticles resulted in excess volume absorption of water, in some cases causing their full deliquescence at lower relative humidities than in macrosystems of identical composition. From the measurement data, a parametrization of hygroscopic particle growth was performed. The results of parametrization can be used to construct refined models of a smoke aerosol.     

Aerosol composition and microstructure in the smoky atmosphere of Moscow during the August 2010 extreme wildfires

This is a comprehensive study of the physicochemical characterization of multicomponent aerosols in the smoky atmosphere of Moscow during the extreme wildfires of August 2010 and against the background atmosphere of August 2011. Thermal–optical analysis, liquid and ion chromatography, IR spectroscopy, and electron microscopy were used to determine the organic content (OC) and elemental content (EC) of carbon, organic/inorganic and ionic compounds, and biomass burning markers (anhydrosaccharides and the potassium ion) and study the morphology and elemental composition of individual particles. It has been shown that the fires are characterized by an increased OC/EC ratio and high concentrations of ammonium, potassium, and sulfate ions in correlation with an increased content of levoglucosan as a marker of biomass burning. The organic compounds containing carbonyl groups point to the process of photochemical aging and the formation of secondary organic aerosols in the urban atmosphere when aerosols are emitted from forest fires. A cluster analysis of individual particles has indicated that when the smokiest atmosphere is characterized by prevailing soot/tar ball particles, which are smoke-emission micromarkers.     

Surfactant components of marine organic matter as agents for biogeochemical fractionation and pollutant transport via marine aerosols

The role of surfactant organic matter in marine aerosol production has been studied under conditions in which there is a large coverage of whitecaps on the sea surface. To improve the knowledge of matter exchange and pollutant recycling from the sea surface into the atmosphere, a spray drop adsorption model (SDAM) was developed and the validity of the proposed model verified by the following experimental results: (1) an increase of surfactant matter on the sea surface during rough sea conditions (‘surface wave concentration'); (2) an (hyperbolic-like) increase of the enrichment ratio (ER) of surfactant fluorescent organic matter (SFOM), made up predominantly by humic substances (HS), as the particle size decrease; (3) a similar behaviour for elements with pollutant properties, and which are known to interact with HS and other surfactant materials, considered pollution tracers. An additional laboratory experiment, based on the adsorption model conditions, gives enrichment ratio greater than unity for K and Ca. The first results on marine aerosols trapped in marine clouds (at 1000 m above sea level and at 100 km from the coast) seem to further support the proposed model and its ability to predict the transition from saline to almost entirely organic particles for the smaller fractions of marine aerosols. The possible contribution of these particles to the recycling and to the long range transport of pollutants via marine aerosols has been considered.     

The Increase of Biogenic Sulfate Aerosol and Particle Number in Marine Atmosphere over the Northwestern North Pacific

During a cruise aboard the R/V Hakuho-maru in the northwestern North Pacific in the summer of 1998 the particle number concentrations and the major ionic components of size fractionated aerosols were measured to investigate the aerosol produced by marine biological activity. Continuous low concentrations of nitrate (<1.8 nmol m⁻³), similar to the marine air background level, were found over the northwestern North Pacific (40–45°N) and the Sea of Okhotsk (44–45°N). Over the Sea of Okhotsk, a high concentration of chlorophyll-a (5.4 mg m⁻³) in seawater was observed, and atmospheric concentrations of non sea-salt (nss-) sulfate (44 nmol m⁻³), methane sulfonic acid (MSA) (1.8 nmol m⁻³) and particle number in the size range of 0.1 < D < 0.5 μm (199 cm⁻³) were found to be 9, 7, and 2 times, respectively, higher than those in the background marine air. The increase in particle number concentrations mainly in the size range of 0.2 < D < 0.3 μm was likely caused by the increase of biogenic sulfate over the high productive region of the Sea of Okhotsk. In humid air conditions (R.H. > 96%), the increased biogenic sulfate that condensed the large amount of water vapor would not have sufficient solute mass to activate as cloud condensation nuclei (CNN) and would remain as aerosol particles in the marine air with frequent sea-fogs over the high productive region. Biogenic sulfate originating from dimethyl sulfide (DMS) would gradually grow into the CCN size and continuously supply a great number of CCN to the marine air in the northwestern North Pacific. This revised version was published online in July 2006 with corrections to the Cover Date.     

Characterization of the proteinaceous matter in marine aerosols

Marine aerosols play a dominant role in the transfer of oceanic material to the atmosphere. Most marine aerosol originates when air bubbles burst at the sea surface ejecting material from the sea surface microlayer and bubble surface layers into the air. Concentrations of chemical compounds in these surface layers often differ from their concentrations in bulk water. We examined the enrichment of aerosols with proteinaceous matter and attempted to characterize the physical nature and sources of this matter. We measured concentrations of dissolved free (DFAA), dissolved combined (DCAA), and particulate (PAA) amino acids, transparent stainable particles (TSP), and bacteria and virus-like particles as carriers of protein, in natural and simulated aerosols. We also evaluated D/L ratios certain amino acids in all amino acid fractions.DFAA and DCAA enriched the aerosols we sampled by 1.2–20 times compared to bulk seawater; PAA enrichment was usually higher (up to 50-fold). Aerosols contained particles typical of seawater, e.g., microorganisms, organic debris, inorganic particles with adsorbed organic matter, but also a large number of semitransparent gel-like particles, which all contained amino acids. Some of these particles were probably scavenged from bulk water, but new particles produced as bubbles burst at the surface comprised at least 10% of total proteinaceous matter in the aerosol. D/L ratios of certain amino acid suggested that the particles were most likely made from dissolved polymers secreted by phytoplankton that were concentrated on bubble surfaces and in the microlayer. Examination with Alcian Blue (a dye that targets carbohydrates) and Coomassie Blue (a dye that targets proteins) showed that most TSP in the aerosols contained both proteins and polysaccharides. Microorganisms enriched the aerosols by up to two orders of magnitude, but contributed less than 4% to the total protein pool.     

Organic components in size-separated aerosols from the western North Pacific

Marine aerosols in the western North Pacific were collected using a cascade impactor. Size-separated aerosols were analyzed for organic carbon, alkanes and polycyclic aromatic hydrocarbons (PAH). The results showed that the rate of decrease of the atmospheric concentrations of these organic components with increase in distance from Japan as well as from the coast of the Eurasian Continent was in the order PAHalkanes>organic carbon. The bulk of all these organic components occurred in the smallest size fraction of particles (<1m). Analysis of the alkanes and PAH indicated that the hydrocarbons in aerosols in Japanese coastal marine areas are primarily derived from terrestrial anthropogenic sources which also contribute to a lesser extent to aerosols in marine areas about 1,000 km off the coast of Japan. In remote marine areas the hydrocarbons on small particles (<1m) have principally a natural terrestrial origin while those on larger particles are marine in origin.     

Asymmetry parameter of the optical scattering phase function of a mixed-phase cloud

Basic characteristics of optical scattering in a mixed-phase cloud (asymmetry parameter of the scattering phase function and efficiency scattering factors and scattering coefficients) are considered. Theoretical consideration is based on the mixed-phase cloud model in the form of a uniform mixture of ice crystals and water droplets. Expressions allowing calculation of asymmetry parameter of the mixed-phase cloud scattering phase function are obtained as functions of the cloud temperature, average size of cloud particles, and ratios of the number densities of differently shaped ice crystals. Data calculated for the asymmetry parameter of infrared scattering in a mixed-phase cloud layer at its given temperature are presented.     

Some statistical characteristics of large deepwater waves around the Korean Peninsula

The relationship between significant wave height and period, the variability of significant wave period, the spectral peak enhancement factor, and the directional spreading parameter of large deepwater waves around the Korean Peninsula have been investigated using various sources of wave measurement and hindcasting data. For very large waves comparable to design waves, it is recommended to use the average value of the empirical formulas proposed by Shore Protection Manual in 1977 and by Goda in 2003 for the relationship between significant wave height and period. The standard deviation of significant wave periods non-dimensionalized with respect to the mean value for a certain significant wave height varies between 0.04 and 0.21 with a typical value of 0.1 depending upon different regions and different ranges of significant wave heights. The probability density function of the peak enhancement factor is expressed as a lognormal distribution, with its mean value of 2.14, which is somewhat smaller than the value in the North Sea. For relatively large waves, the probability density function of the directional spreading parameter at peak frequency is also expressed as a lognormal distribution.     

Distinguishing Developing Versus Non-Developing African Easterly Waves Using Adaptive Observational Strategies

The impacts of dust loaded, Saharan Air Layer (SAL) during the life cycle of African Easterly Waves (AEWs) is a many-faceted scientific problem. It entails possible radiative effects of dust aerosols, impacts of dust on cloud physics, and the cloud nuclei of condensation, advective effects, that is, intrusions of dry dusty air versus humid air into the interior of storms. This paper addresses several such AEWs of the eastern Atlantic Ocean, where we have made use of special aircraft reconnaissance data sets that include wind and humidity profiles in the vertical. Using what are called adaptive observational strategies within a mesoscale model, we show the impacts of adding such observations in the analysis and in short-range forecasts of several AEWs. We do not have the direct and indirect effects of aerosols, but we do include the advective component. Our results show that the inclusion of humidity profiling distinguishes between developing versus nondeveloping AEWs from the use of these additional data sets via the adaptive observational strategies.     

Properties of coarse particles in suspended particulate matter of the North Yellow Sea during summer

Fine particles in seawater commonly form large porous aggregates. Aggregate density and settling velocity determine the behavior of this suspended particulate matter(SPM) within the water column.However, few studies of aggregate particles over a continental shelf have been undertaken. In our case study, properties of aggregate particles, including size and composition, over the continental shelf of the North Yellow Sea were investigated. During a scienti?c cruise in July 2016, in situ ef fective particle size distributions of SPM at 10 stations were measured, while temperature and turbidity measurements and samples of water were obtained from surface, middle, and bottom layers. Dispersed and inorganic particle size distributions were determined in the laboratory. The in situ SPM was divided into(1) small particles(<32 μm),(2) medium particles(32–256 μm) and(3) large particles(>256 μm). Large particles and medium particles dominated the total volume concentrations(VCs) of in situ SPM. After dispersion, the VCs of medium particles decreased to low values(<0.1 μL/L). The VCs of large particles in the surface and middle layers also decreased markedly, although they had higher peak values(0.1–1 μL/L). This suggests that almost all in situ medium particles and some large particles were aggregated, while other large particles were single particles. Correlation analysis showed that primary particles <32 μm in?uenced the formation of these aggregates. Microscopic examination revealed that these aggregates consisted of both organic and inorganic ?ne particles, while large particles were mucus-bound organic aggregates or individual plankton.The vertical distribution of coarser particles was clearly related to water strati?cation. Generally, medium aggregate particles were dominant in SPM of the bottom layer. A thermocline blocked resuspension of?ne material into upper layers, yielding low VCs of medium-sized aggregate particles in the surface layer.Abundant large biogenic particles were present in both surface and middle layers.     

Numerical simulation of the action on a warm convective cloud by hygroscopic particles

A one-dimensional numerical model of a warm convective cloud is presented. This model is used to study the effectiveness of the action on the cloud by hygroscopic particles with the aim of intensifying precipitation. The numerical simulation takes into account the processes of condensation, coagulation, and sedimentation of cloud droplets and makes it possible to obtain spatiotemporal characteristics of cloud development. A system of differential equations describing time variations in the temperature, pressure, and watervapor supersaturation during the adiabatic rise of a continuous air flow is solved. The evolution of the size distribution of cloud droplets is described by a kinetic equation. A continuous acting source of droplets with the size distribution calculated with consideration for condensation properties and dispersion characteristics of condensation nuclei (natural and additionally introduced during the action) is specified at the cloud-base level. The cloud top is formed owing to the evaporation of droplets in the barrier atmospheric layer over the cloud. The influence of changes in the barrier-layer height on the structure of cloud parameters and precipitation-formation processes is analyzed. The introduction of additional hygroscopic particles into a cloud is shown to act as a trigger mechanism initiating the processes of coagulation and sedimentation in the cloud medium. In this case, a positive effect of action by fine particles can be achieved if a certain reserve of sufficiently large droplets is present in the cloud. The results of calculating the dependence of the action effect on the height of the barrier layer, restricting cloud development, are presented.     

Formation of cloud microstructure during hygroscopic seeding

The evolution of cloud microstructure initiated by hygroscopic seeding is studied on the basis of numerical simulation of cloud formation in the initial stage of condensation. The influence of both physicochemical properties of atmospheric aerosol and atmospheric conditions controlling the cloud type on the microstructure of a developing cloud (without hygroscopic seeding) is analyzed. It is shown that cloud seeding with additional particles whose sizes exceed the characteristic size of atmospheric condensation nuclei leads to a decrease in the concentration of cloud droplets and an increase in their sizes. This result of cloud seeding represents a positive effect for stimulation of precipitation from convective clouds. It is shown that this positive effect is achieved if there are some relationships between the parameters characterizing the hygroscopic particles and the atmospheric conditions. In particular, the maximum effect of action can be achieved at some optimal concentration of seeded particles. The decrease in the concentration of cloud droplets because of hygroscopic seeding is compared to the results of numerical simulations performed by other authors with allowance for coagulation processes in clouds. It is shown that this decrease can serve as an estimate for the effectiveness of hygroscopic seeding as a means for artificial intensification of precipitation from convective clouds.     

On the influence of atmospheric chemical reactions on the ion composition of aerosol particles in the Baikal region

Monitoring data on the ion composition of aerosols and gas admixtures in the background and polluted atmosphere of the Lake Baikal region are presented. The ion composition and morphology of aerosols are affected by heterogeneous chemical reactions and variations in relative humidity. Two types of aerosol particles are revealed over this region. The fraction of solid particles recorded in most episodes includes primarily carbonates of alkaline and alkaline-earth metals. With increased atmospheric humidity, these particles are engaged in heterogeneous chemical reactions with gas-phase NH₃ and H₂SO₄, proceeding through the phase of watering. As a result, the composition of these aerosols is changed, and a fraction of aqueous H₂O/H₂SO₄/(NH₄)₂SO₄ aerosol particles of a different composition is formed. On the basis of a physical and chemical analysis of monitoring data on the aerosol composition and concentrations of gas admixtures, the average aerosol-size distribution of different types is estimated. For the first time, the mean acidity of aqueous aerosol particles is estimated.     

A comparison of summer precipitation structures over the South China Sea and the East China Sea based on tropical rainfall measurementmission

The three-dimensional structures of summer precipitation over the South China Sea （SCS） and the East China Sea （ECS） are investigated based on tropical rainfall measurement mission （TRMM）. The primary results are as follows. First, both the convective and stratiform precipitation rates in the SCS are much higher than those of the ECS. The contribution of the convective cloud precipitation to the surface precipitation is primarily over the SCS and the ECS with a proportion of about 70%, but the contribution of convective cloud precipitation is slightly larger in the SCS than the ECS. The contribution of stratus precipitation is slightly larger in the ECS than that in the SCS. Second, the content of cloud particles and precipitation particles in the ECS in June was greater than that in the SCS, while in July and August, the content of cloud and precipitation particles in the ECS was less than that in the SCS. Third, the latent heat profile of the ECS is quite different from that of the SCS. In June, the peak values of evaporation and condensation latent heating rates in the ECS are greater than those in the SCS. In July and August, however, the peak values of evaporation and condensation latent heating rates in the ECS are about 0.05°/h less than those in the SCS.     

基于LiDAR回波强度数据的潮间带植被滤波方法

地面三维激光扫描技术以其高精度、高密度等优点,在潮间带地形测量中得到了非常广泛的应用。为了对潮间带地形地貌进行精确反演,必须对点云数据中的非地面点(主要是植被点)予以滤波。对地面三维激光扫描回波强度数据的距离效应进行改正,利用改正后强度数据实现了一种快速精确的植被滤波方法。实验结果表明:与商业软件利用点云几何信息进行植被滤波相比,根据回波强度数据进行植被滤波的精度约为75%,且大大减少了计算量,对潮间带高精度三维地形重构有重要研究意义和应用价值。     

Dynamics of trace gases and aerosols in the atmosphere with consideration for heterogeneous processes

A combined mathematical model has been developed to reproduce space and time variations in the concentrations of multicomponent gas constituents and aerosols in the atmosphere on both regional and urban scales. This model contains blocks of transport of gas constituents and aerosols in the atmosphere with consideration for homogeneous binary nucleation, the kinetic processes of condensation/evaporation and coagulation, chemical processes occurring in both gas and liquid phases, and the processes of mass exchange during the gas-droplet (particle) interaction. A nonhydrostatic model of atmospheric mesoscale processes is used to calculate the fields of meteorological elements and turbulent characteristics. The generation of new-phase particles from precursor gases by the mechanism of homogeneous binary nucleation and their interaction with background aerosol are considered. The results of numerical experiments are compared with the data obtained from field observations of both space and time variations in the concentrations of gas constituents and aerosols and in the ionic content of aerosol particles over the Baikal region under the influence of emissions from powerful industrial sources.