Geochemistry,mineralogy and petrogenesis of the northeast Niğde volcanics,central Anatolia,Turkey

The volcanics exposed in the northeast Niğde area are characterized by pumiceous pyroclastic rocks present as ash flows and fall deposits and by compositions ranging from dacite to rhyolite. Xenoliths found in the volcanics are basaltic andesite, andesite and dacite in composition. These rocks exhibit linear chemical variations between end‐member compositions and a continuity of trace element behaviour exists through the basaltic andesite–andesite–dacite–rhyolite compositional range. This is consistent with the fractionation of ferromagnesian minerals and plagioclase from a basaltic andesite or andesite parent. These rocks are peraluminous and show typical high‐K calc‐alkaline differentiation trends with total iron content decreasing progressively with increasing silica content. Bulk rock and mineral compositional trends and petrographic data suggest that crustal material was added to the magmas by subducted oceanic crust and is a likely contaminant of the source zone of the Niğde magmas. The chemical variations in these volcanics indicate that crystal liquid fractionation has been a dominant process in controlling the chemistry of the northeast Niğde volcanics. It is also clear, from the petrographic and chemical features, that magma mixing with disequilibrium played a significant role in the evolution of the Niğde volcanic rocks. This is shown by normal and reverse zoning in plagioclase and resorption of most of the observed minerals. The xenoliths found in the Niğde volcanics represent the deeper part of the magma reservoir which equilibrated at the higher pressures. Copyright © 2002 John Wiley & Sons, Ltd.     

Late Cretaceous coeval acidic and basic magmatism,Karacaali Magmatic Complex,Central Anatolia,Turkey

The Central Anatolia Crystalline Complex (CACC) is characterized by Late Cretaceous high-temperature metamorphic rocks intruded by S-, I-, and A-type granitoids. Coeval basic plutonic and volcanic rocks also crop out in the complex. The NE–SW-trending Karacaali Magmatic Complex (KMC) represents a clear example of synchronous basic and acidic magmatic associations. We present new data on this coeval magmatism. The KMC plutonic rocks mainly consist of monzonite, granite, and gabbro, whereas the associated volcanic rocks are chiefly of basalt and rhyolite. All of the units have been cut by quartz, quartz-tourmaline, and calcite veins and by porphyritic leucogranite, aplitic, and basaltic dikes. The rhyolitic, basaltic, and gabbroic samples yield well-defined ⁴⁰Ar/³⁹Ar plateau ages of 69.1 ± 1.3, 58 ± 10, and 66.4 ± 1 million years, respectively; these data indicate that a younger multiphase basic magma was injected into a partially crystallized monzonitic magma chamber. The basic intrusions added heat to the system and gave rise to the re-fusion of the already crystallized parts of the monzonitic melt, forming the younger leucogranitic magma. The gradational contacts, cross-cutting relationships, trace element contents, trace element patterns, rare-earth element (REE) patterns, and ⁴⁰Ar/³⁹Ar geochronological data of the studied igneous suite clearly demonstrate that the acidic and basic rocks of the KMC were contemporaneous and are produced by partial melting of distinct sources rather than by fractional crystallization of a single source.     

Ar/Ar age and geochemistry of the post-collisional Miocene Yamadağ volcanics in the Arapkir area (Malatya Province), eastern Anatolia, Turkey

The Neogene Yamadağ volcanics occupy a vast area between Sivas and Malatya in eastern Anatolia, Turkey. These volcanic rocks are characterized by pyroclastics comprising agglomerates, tuffs and some small outcrops of basaltic–andesitic–dacitic rocks, overlain upward by basaltic and dacitic rocks, and finally by basaltic lava flows in the Arapkir area, northern Malatya Province. The basaltic lava flows in the Arapkir area yield a ⁴⁰Ar/³⁹Ar age of 15.8 ± 0.2 Ma, whereas the dacitic lava flows give ⁴⁰Ar/³⁹Ar ages ranging from 17.6 through 14.7 ± 0.1 to 12.2 ± 0.2 Ma, corresponding to the Middle Miocene. These volcanic rocks have subalkaline basaltic, basaltic andesitic; alkaline basaltic trachyandesitic and dacitic chemical compositions. Some special textures, such as spongy-cellular, sieve and embayed textures; oscillatory zoning and glass inclusions in plagioclase phenocrysts; ghost amphiboles and fresh biotite flakes are attributable to disequilibrium crystallization related to magma mixing between coeval magmas. The main solidification processes consist of fractional crystallization and magma mixing which were operative during the soldification of these volcanic rocks. The dacitic rocks are enriched in LILE, LREE and Th, U type HFSE relative to the basaltic rocks. The basaltic rocks also show some marked differences in terms of trace-element and REE geochemistry; namely, the alkaline basaltic trachyandesites have pronounced higher HFSE, MREE and HREE contents relative to the subalkaline basalts. Trace and REE geochemical data reveal the existence of three distinct magma sources – one subalkaline basaltic trachyandesitic, one alkaline basaltic and one dacitic – in the genesis of the Yamadağ volcanics in the Arapkir region. The subalkaline basaltic and alkaline basaltic trachyandesitic magmas were derived from an E-MORB type enriched mantle source with a relatively high- and low-degree partial melting, respectively. The magmatic melt of dacitic rocks seem to be derived from an OIB-type enriched lithospheric mantle with a low proportion of partial melting. The enriched lithospheric mantle source reflect the metasomatism induced by earlier subduction-derived fluids. All these coeval magmas were generated in a post-collisional extensional geodynamic setting in Eastern Anatolia, Turkey.     

Geochemical and mantle-like isotopic (Nd, Sr) composition of the Baklan Granite from the Muratdağı Region (Banaz, Uşak), western Turkey: Implications for input of juvenile magmas in the source domains of western Anatolia Eocene–Miocene granites

The (late syn)- post-collisional magmatic activities of western and northwestern Anatolia are characterized by intrusion of a great number of granitoids. Amongst them, Baklan Granite, located in the southern part of the Muratdağı Region from the Menderes Massif (Banaz, Uşak), has peculiar chemical and isotopic characteristics. The Baklan rocks are made up by K-feldspar, plagioclase, quartz, biotite and hornblende, with accessory apatite, titanite and magnetite, and include mafic microgranular enclaves (MME). Chemically, the Baklan intrusion is of sub-alkaline character, belongs to the high-K, calc-alkaline series and displays features of I-type affinity. It is typically metaluminous to mildly peraluminous, and classified predominantly as granodiorite in composition. The spider and REE patterns show that the rocks are fractionated and have small negative Eu anomalies (Eu/Eu^* = 0.62–0.86), with the depletion of Nb, Ti, P and, to a lesser extent, Ba and Sr. The pluton was dated by the K–Ar method on the whole-rock, yielded ages between 17.8 ± 0.7 and 19.4 ± 0.9 Ma (Early Miocene). The intrusion possesses primitive low initial ⁸⁷Sr/⁸⁶Sr ratios (0.70331–0.70452) and negative ε_Nd(t) values (−5.0 to −5.6). The chemical contrast between evolved Baklan rocks (SiO₂, 62–71 wt.%; Cr, 7–27 ppm; Ni, 5–11 ppm; Mg#, 45–51) and more primitive clinopyroxene-bearing monzonitic enclaves (SiO₂, 54–59 wt.%; Cr, 20–310 ppm; Ni, 10–70 ppm; Mg#, 50–61) signifies that there is no co-genetic link between host granite and enclaves. The chemical and isotopic characteristics of the Baklan intrusion argue for an important role of a juvenile component, such as underplated mantle-derived basalt, in the generation of the granitoids. Crustal contamination has not contributed significantly to their origin. However, with respect to those of the Baklan intrusion, the generation of the (late syn)- post-collisional intrusions with higher Nd(t) values from the western Anatolia require a much higher amount of juvenil component in their source domains.     

Petrology and Geochemistry of Post-Collisional Early Miocene Volcanism in the Karacada? Area (Central Anatolia, Turkey)

Early Miocene (ca.?21–18 Ma) volcanism in the Karacada? area comprises three groups of volcanic rocks: (1) calcalkaline suite (andesitic to rhyolitic lavas and their pyroclastics), (2) mildly-alkaline suite (alkali basalt, hawaiite, mugearite, benmoreite and trachydacite), and (3) a single trachyandesitic flow unit. Field observations, 40Ar/39Ar ages and geochemical data show that there was a progressive temporal transition from group 1 to 3 in a post-collisional tectonic setting. The calcalkaline suite rocks with medium-K in composition resemble those of subduction-related lavas, whereas the mildly-alkaline suite rocks having a sodic tendency (Na2O/K2O=1.5–3.2) resemble those of within-plate lavas. Incompatible element and Sr-Nd isotopic characteristics of the suites suggest that the lithospheric mantle beneath the Karacada? area was heterogeneously enriched by two processes before collision: (1) enrichment by subduction-related processes, which is important in the genesis of the calcalkaline volcanism, (2) enrichment by small degree melts from the astenosphere, which dominates the mildly alkaline volcanism. Perturbation of the enriched lithosphere by either delamination following collision and uplift or removal of the subducted slab following subduction and collision (i.e., slab breakoff) is the likely mechanism for the initiation of the post-collision volcanism.     

The relationship between collision-related calcalkaline, and within-plate alkaline volcanism in the Karacadağ Area (Konya-Türkiye, Central Anatolia)

The Karacadağ (Kulu-Konya) area is one of the main volcanic provinces in Central Anatolia. The Karacadağ volcanites are composed of large volumes of andesitic-dacitic lavas associated with pyroclastics and small volumes of alkali basalt, trachybasalt and trachyandesite lavas. Two groups of volcanic rocks can be distinguished: (1) calcalkaline rocks including andesites and dacites, and (2) alkaline rocks including basalts, trachybasalts and trachyandesites. ⁴⁰Ar/³⁹Ar ages show that the Karacadağ volcanites were erupted during Early Miocene (ca.18–19 Ma) and suggest that alkaline volcanites succeed shortly afterwards calcalkaline volcanites. Major oxides and trace elements plotted versus SiO₂ suggest fractionation of hornblende, Fe–Ti oxide and apatite for calcalkaline volcanic rocks and olivine, clinopyroxene and Fe–Ti oxide for alkaline volcanic rocks in the magmatic evolution. The incompatible trace element patterns of the calcalkaline volcanites show enrichment of LILEs (Sr, K, Rb, Ba and Th) and negative HFSEs (Nb, Ta) anomalies suggesting an enriched lithospheric source by a subduction-related process. On the other hand, alkaline volcanites show enrichment of both LILEs and HFSEs suggesting an enriched lithospheric source by small volume melts from the asthenosphere. The rocks also have moderately fractionated REE patterns with (La/Lu)_N ratios of 7–24 for calcalkaline and 6–17 for alkaline volcanites. Moreover, the volcanites have relatively low ⁸⁷Sr/⁸⁶Sr(t) ratios for between 0.703782 and 0.705129, and high ε_Nd(t) values between +2.25 and +4.49. Generally, the Sr–Nd isotopic compositions of the rocks range from the mantle array to bulk earth. All of these observations and findings suggest that the calcalkaline volcanites were formed in a subduction modified orogenic setting, and the alkaline volcanites in a within-plate setting.     

Hydrogeochemical and Isotopic Study of Groundwater in a Semi-arid Region: Yeniceoba Plain (Cihanbeyli-KONYA), Central Anatolia,Turkey

Groundwater is the most important source of water supply in the Yeniceoba Plain in Central Anatolia,Turkey.An understanding of the geochemical evolution of groundwater is important for the sustainable development of water resources in this region.A hydrogeochemical investigation was conducted in the Plio-Quaternary aquifer system using stable isotopes(δ~(18)O andδD),tritium(~3H),major and minor elements(Ca,Na,K,Mg,Cl,SO_4,NO_3,HCO_3 and Br)in order to identify groundwater chemistry patterns and the processes affecting groundwater mineralization in this system.The chemical data reveal that the chemical composition of groundwater in this aquifer system is mainly controlled by rock/water interactions including dissolution of evaporitic minerals,weathering of silicates,precipitation/dissolution of carbonates,ion exchange,and evaporation.Based on the values of Cl/Br ratio(300 mg/l)in the Plio-Quaternary groundwater,dissolution of evaporitic minerals in aquifer contributes significantly to the high mineralization.The stable isotope analyses indicate that the groundwater in the system was influenced by evaporation of rainfall during infiltration.Low tritium values(generally1 tritium units)of groundwater reflect a minor contribution of recent recharge and groundwater residence times of more than three or four decades.     

Magma Mingling/mixing vs. Magmatic Fractionation: Geneses of the Shirakawa Mo-mineralized Granitoids, Central Japan

Abstract. Leucocratic biotite granites are main components in the Hatogaya pluton and the Hirase stock in the Shirakawa region of central Japan. Molybdenite‐quartz vein mineralizations are widespread in and around the Hatogaya pluton and the Hirase stock, in which the largest is vein swarm of the Hirase mine. Mafic enclaves occur abundantly with granitic to granodi‐oritic matrix in the northern part of the Hatogaya pluton, while they are rare in the Hirase granitic stock. The enclaves with generally round shape have mostly diabasic to fine plutonic textures under the microscope, and show interfingering and lobate contacts with the felsic matrix. The enclaves are quartz monzodiorite in composition containing SiO>₂ mostly around 60 %. They have felsic blebs, thus are considered a mingled magma of basaltic compositions originated in depth and a felsic magma generated from the Hida metamorphic‐plutonic complexes or their basement. The mingled magma further mixed with and reacted with the felsic magma with SiO₂ 70 %, and then formed granodiorite‐granite of the high Na group (Na₂O higher than 4.25 %). Thus, compositional variation of the northern part of the Hatogaya pluton was caused by the magma mingling. The mingling happened to be deeper level produced homogeneous granodiorite of the Mihoro pluton. Biotite granite of the low Na group (less than 4.25 %) could have originated in a granitic magma generated also from the Hida metamorphic‐plutonic complexes or their basement. Most of the granites, occurring in the southern part of the Hatogaya pluton and Hirase stock, show high Rb/Sr ratio, strong Eu negative anomalies and flat REE patterns, and are thus considered as fractionated products of the SiO₂ 70 % original magma. The strong concentration of molybdenum in the Hirase stock can be explained by high degree of magmatic fractionation which produced MoS₂‐rich residual melts, suitable fractures developed at the latest Cretaceous time, and preservation of the mineralized fractures at the present level of erosion.     

Mio-Pliocene basin development in the eastern part of the Cappadocian Volcanic Province (Central Anatolia,Turkey) and its implications for regional tectonics

The Cappadocian Volcanic Province (CVP) comprises predominantly of a thick succession of volcanogenic rocks and interbedded siliciclastic sediments of Middle Miocene to Recent age in Central Anatolia, Turkey. The conditions of basin development in the eastern part of the CVP have been elucidated by using sedimentological and geomorphological approaches. The prevailing tectonic regime, its extent and causes are also discussed. Sedimentological analysis supported by geomorphological observations revealed a major NE-trending probably normal, border fault and its several synthetics. This tectonic element constitutes the SE margin of the basin and divided the CVP from the Tauride range during Middle Miocene to Pliocene. The basin fill in the study area comprises gravelly alluvial fans near the border fault, while fluvial clastics and lacustrine carbonates dominate towards the centre. Some pyroclastic rocks and lava flows are also made part of the fill. The southeastern basin margin is characterized morphologically by a number of uplifted basement blocks, probably associated with synthetic faults, and some deeply incised canyons in the footwall. These canyons were subsequently filled with a Mid-Pliocene ignimbrite sheet, and represent the sediment supply conduits to the basin. The cessation of filling in the basin was determined by strike-slip faults that uplifted and detached the basin about 2.6 Ma. This date also marks the onset of the neotectonic period in the region. The overall extensional tectonic regime inferred for the eastern CVP appears coeval with events recognised in the southern basins, i.e. Adana and Mut Basins and the eastern Mediterranean. Some physical connections between these basins also have been demonstrated. It is suggested that the CVP and the southern basins were all created during a phase of extension resulting from continued northward subduction of the African plate beneath the Eurasia during the Late Cenozoic.     

U/Th dating of fissure ridge travertines from the Kirsehir region (Central Anatolia Turkey): structural relations and implications for the Neotectonic development of the Anatolian block

Travertines exposed in several locations in Central Anatolia are the important lithological product for the interpretation of local neotectonics. The fissure-type travertines provide significant information about stress orientation during deposition. Two travertine masses cropping out in the Kirsehir region have been studied and dated by the U-series method to obtain new chronological constraints, determine dilation rates and contribute to studies on the recent tectonic evolution of the area. The Kusdili and Kayabasi travertine masses are located on the hanging wall of the Kirsehir Fault, similar to numerous fissure ridge banded travertine deposits which are inactive today in the region. While individual fissures of the Kusdili travertine mass (Late Pleistocene-Holocene) have been dilated at rates of between 0.303 and 0.386 mm yr–1 during deposition, the Kayabasi travertine mass (Late Pleistocene) produced measured dilation rates of between 0.136 and 0.187 mm yr–1. The central fissures, filled by banded travertine, roughly follow the ridge crests. While the ridge crest has a NNE-SSW trend in the Kayabasi travertine mass, the ridge crest of the Kusdili travertine mass shows a NE-SW trend. This difference may be related to the clockwise rotation of the stress tensors from Late Pleistocene to Late Pleistocene-Holocene in the region.     

Strike-slip motions in the Gulf of Siğaçik (western Turkey): Properties of the 17 October 2005 earthquake seismic sequence

The October 2005 series of earthquakes that occurred in the Gulf of Siğaçik (western Turkey) reveal the operation of pure strike-slip faults, as evidenced from the 49 focal mechanisms we determined, in a region dominated by N–S extension and bounded by well-documented graben structures. The sequence is characterized by the occurrence of three moderate size events (17 October 2005, 05:45 UTC, Mw 5.4; 17 October 2005, 09:46 UTC, Mw 5.8; and 20 October 2005, 21:40 UTC, Mw 5.8) with an eastward propagation and close spatial separation (< 6 km). We relocated over 200 aftershocks, combining phases from the Greek and Turkish seismological networks, which align roughly in a NE–SW cloud, but considerably spread after the first day of the sequence, indicating the simultaneous activation of multiple structures nearly orthogonal to the main rupture. It is hard to relate the occurrence of the events to any of the previously mapped faults in the region. The region of occurrence is a well-known geothermal area which implies that it is in a very unstable state, with the fault systems close to rupture and very sensitive to stress perturbations. Here we showed that the sequence is adequately explained by static stress triggering. It is worth noting that this sequence, though moderate in magnitudes, provides stronger evidence for the operation of sub-parallel strike-slip faults in the central Aegean Sea–western Turkey, north of the volcanic arc, which seem to be optimally oriented in the regional stress field and facilitate the Anatolia motion into the Aegean Sea.     

K‐Ar age determination,whole‐rock and oxygen isotope geochemistry of the post‐collisional Bizmişen and Çaltı plutons,SW Erzincan,eastern Central Anatolia,Turkey

Post‐collisional granitoid plutons intrude obducted Neo‐Tethyan ophiolitic rocks in central and eastern Central Anatolia. The Bizmişen and Çaltı plutons and the ophiolitic rocks that they intrude are overlain by fossiliferous and flyschoidal sedimentary rocks of the early Miocene Kemah Formation. These sedimentary rocks were deposited in basins that developed at the same time as tectonic unroofing of the plutons along E–W and NW–SE trending faults in Oligo‐Miocene time. Mineral separates from the Bizmişen and Çaltı plutons yield K‐Ar ages ranging from 42 to 46 Ma, and from 40 to 49 Ma, respectively. Major, trace, and rare‐earth element geochemistry as well as mineralogical and textural evidence reveals that the Bizmişen pluton crystallized first, followed at shallower depth by the Çaltı pluton from a medium‐K calcalkaline, I‐type hybrid magma which was generated by magma mixing of coeval mafic and felsic magmas. Delta ¹⁸O values of both plutons fall in the field of I‐type granitoids, although those of the Çaltı pluton are consistently higher than those of the Bizmişen pluton. This is in agreement with field observations, petrographic and whole‐rock geochemical data, which indicate that the Bizmişen pluton represents relatively uncontaminated mantle material, whereas the Çaltı pluton has a significant crustal component. Structural data indicating the middle Eocene emplacement age and intrusion into already obducted ophiolitic rocks, suggest a post‐collisional extensional origin. However, the pure geochemical discrimination diagrams indicate an arc origin which can be inherited either from the source material or from an upper mantle material modified by an early subduction process during the evolution of the Neo‐Tethyan ocean. Copyright © 2005 John Wiley & Sons, Ltd.     

Stratigraphy and tectono-sedimentary evolution of the Upper Cretaceous–Tertiary sequence in the southern part of the Malatya Basin, East Anatolia, Turkey

The Malatya Basin is situated on the southern Taurus-Anatolian Platform. The southern part of the basin contains a sedimentary sequence which can be divided into four main units, each separated by an unconformity. From base to top, these are: (1) Permo-Carboniferous; (2) Upper Cretaceous–Lower Paleocene, (3) Middle-Upper Eocene and (4) Upper Miocene. The Upper Cretaceous–Tertiary sedimentary sequence resting on basement rocks is up to 700 m thick.The Permo-Carboniferous basement consist of dolomites and recrystallized limestones. The Upper Cretaceous–Lower Paleocene transgressive–regressive sequence shows a transition from terrestrial environments, via lagoonal to shallow-marine limestones to deep marine turbiditic sediments, followed upwards by shallow marine cherty limestones. The marine sediments contain planktic and benthic foraminifers indicating an upper Campanian, Maastrichtian and Danian age. The Middle-Upper Eocene is a transgressive–regressive sequence represented by terrestrial and lagoonal clastics, shallow-marine limestones and deep marine turbidites. The planktic and benthic foraminifers in the marine sediments indicate a Middle-Upper Eocene age. The upper Miocene sequence consists of a reddish-brown conglomerate–sandstone–mudstone alternation of alluvial and fluvial facies.During Late Cretaceous–Early Paleocene times, the Gündüzbey Group was deposited in the southern part of a fore-arc basin, simultaneously with volcanics belonging to the Yüksekova Group. During Middle-Late Eocene times, the Yeşilyurt Group was deposited in the northern part of the Maden Basin and the Helete volcanic arc. The Middle-Upper Eocene Malatya Basin was formed due to block faulting at the beginning of the Middle Eocene time. During the Late Paleocene–Early Eocene, and at the end of the Eocene, the study areas became continental due to the southward advance of nappe structures.The rock sequences in the southern part of the Malatya Basin may be divided into four tectonic units, from base to top: the lower allochthon, the upper allochthon, the parautochthon and autochthonous rock units.     

西藏甲玛铜多金属矿床暗色包体岩石成因:对岩浆混合和成矿的启示

岩浆混合作用的研究对揭示壳幔相互作用,探讨成岩成矿过程具有重要意义。甲玛矿区位于冈底斯成矿带东段,为超大型斑岩-矽卡岩型铜多金属矿床,矿区内的中酸性岩浆岩中普遍发育暗色包体,对其中的暗色包体中的闪长质包体开展详细的岩相学、岩石地球化学、Hf同位素地球化学及U-Pb同位素地质年代学等方面研究以期查明岩石成因,为岩浆混合作用和成矿作出启示,完善甲玛成岩成矿模型。岩相学观察表明,闪长质包体及寄主岩浆岩中存在多种反映岩浆混合作用的典型组构,如长石-石英熔蚀结构、石英镶边结构、长石交代筛状结构、长石反环带结构、磷灰石针柱状结构等,锆石LA-ICP-MS UPb同位素定年结果显示,包体形成时代(15. 3±0. 3Ma)与中酸性寄主岩石在误差范围内一致,也符合了岩浆混合作用的存在。闪长质包体化学成分上类似高Mg埃达克岩(MgO=3. 53%～6. 62%,Sr/Y=20～57,(La/Yb)N=51～64),具有低SiO_2(52. 44%～59. 45%),高K_2O(3. 19%～5. 62%),高相容元素(Ni=86×10~(-6)～146×10~(-6); Cr=102×10~(-6)～228×10~(-6))的特征,∑REE高于中酸性寄主岩浆岩,且轻重稀土分异明显((LREE/HREE)N=21～23),富集LILE(Rb=189×10~(-6)～284×10~(-6),Sr=498×10~(-6)～658×10~(-6),Ba=1247×10~(-6)～1378×10~(-6)),相对亏损HFSE(Nb、Ta、Ti),在稀土元素配分图及微量元素蛛网图中闪长质包体介于冈底斯带碰撞后时期的超钾镁铁质岩(来源于富集的岩石圈地幔)与甲玛中酸性寄主岩浆岩(主要来源于加厚新生下地壳)之间,Hf同位素(ε_(Hf)(t)=-0. 9～4. 6)同样也介于超钾镁铁质岩与花岗闪长斑岩(代表中酸性寄主岩浆)之间。这些特征说明闪长质包体是富集的岩石圈地幔部分熔融形成的镁铁质岩浆与加厚新生下地壳部分熔融形成的中酸性岩浆发生混合的产物,同时指示了东冈底斯带中新世时期也存在岩石圈地幔伸展对流减薄事件,以及证实了南拉萨地体广泛分布的高钾埃达克质岩在形成过程中,伴随着与富集岩石圈地幔来源的超钾镁铁质岩浆发生不同程度混合。此外,富集的岩石圈地幔部分熔融形成的镁铁质岩浆的混入,将会为中酸性岩浆系统加入大量的水和金属物质,这也是控制甲玛超大型斑岩-矽卡岩型矿床形成的关键因素。     

骑田岭花岗岩体的岩浆混合成因:寄主岩及其暗色闪长质微细粒包体的锆石U-Pb年龄和Hf同位素证据

南岭骑田岭复式岩体仰天湖单元燕山期二长花岗岩中广泛分布有暗色闪长质微细粒包体,这些包体主要呈被打散的片云状或次圆状,大小不等,颜色较寄主岩深,粒度较细。本文在锆石内部结构的CL图像特征研究基础上,用LA-ICP-MS和MC-ICP-MS测定了锆石U-Pb年龄及Hf同位素组成,探讨了寄主二长花岗岩、闪长质微细粒包体的锆石U-Pb年代学及Hf同位素组成特征。获得寄主二长花岗岩、闪长质微细粒包体的结晶年龄为(166.0±2.0)Ma和(169.8±4.1)Ma,对应的εHf(t)值为-13.2～-1.9与-8.3～+6.7。研究表明,骑田岭复式岩体中的仰天湖岩体是以古老地壳物质熔融为主体的壳源岩浆与幔源岩浆高度混合的产物。     

Biostratigraphic interpretation and systematics of Alveolina assemblages from the Ilerdian–Cuisian limestones of Southern Eskişehir, Central Turkey

The Ilerdian–Middle Cuisian sedimentary succession of the Seyitgazi region, southern Eskişehir (Central Anatolia, Turkey) is composed of claystones, limestones and clayey limestones. It contains abundant benthic foraminifera, particularly species of Alveolina. From this succession, 28 species of Alveolina d’Orbigny are described and their comparative stratigraphic distribution with the Alveolina species in the Tethyan Eocene is documented. Generally, Ilerdian–Cuisian Alveolina assemblages of the Seyitgazi region have close affinities with coeval Alveolina assemblages described in different studies from the Tethyan Province. The Ilerdian unit of the study area is characterized by Alveolina species such as Glomalveolina lepidula, Glomalveolina minutula, G. karsica, Alveolina vredenburgi, A. ellipsoidalis, A. avellana, A. aff. minervensis, A. dedolia, A. moussoulensis, A. subpyrenaica, A. laxa, A. aragonensis, A. varians, A. ilerdensis, A. trempina, A. citrea, A. pisella and A. decipiens. Likewise, the Early Middle Cuisian unit is represented by G. minutula, A. oblonga, A. schwageri, A. haymanensis, A. canavarii, A. aff. coudurensis, A. ruetimeyeri, A. muscatensis, A. cremae, A. bayburtensis and A. lehneri.     

Mineralogy, whole-rock and Sr-Nd isotope geochemistry of mafic microgranular enclaves in Cretaceous Dagbasi granitoids, Eastern Pontides, NE Turkey: Evidence of magma mixing, mingling and chemical equilibration

Rocks of the Late Cretaceous Dagbasi Pluton (88-83 Ma), located in the eastern Pontides, include mafic microgranular enclaves (MMEs) ranging from a few centimetres to metres in size, and from ellipsoidal to ovoid in shape. The MMEs are composed of gabbroic diorite, diorite and tonalite, whereas the felsic host rocks comprise mainly tonalite, granodiorite and monzogranite based on both mineralogical and chemical compositions. MMEs are characterized by a fine-grained, equigranular and hypidiomorphic texture. The common texture of felsic host rocks is equigranular and also reveals some special types of microscopic textures, e.g., oscillatory-zoned plagioclase, poikilitic K-feldspar, small lath-shaped plagioclase in large plagioclase, blade-shaped biotite, acicular apatite, spike zones in plagioclase and spongy-cellular plagioclase textures and rounded plagioclase megacrysts in MMEs. Compositions of plagioclases (An₃₃-An₆₀), hornblendes (Mg#=0.77-1.0) and biotites (Mg#=0.61-0.63) of MMEs are slightly distinct or similar to those of host rocks (An_12-57; hbl Mg#=0.63-1.0; Bi Mg#=0.50-0.69), which suggest partial to complete equilibration during mafic-felsic magma interactions.The felsic host rocks have SiO₂ between 60 and 76 wt% and display low to slightly medium-K tholeiitic to calc-alkaline and peraluminous to slightly metaluminous characteristics. Chondrite-normalized rare-earth element (REE) patterns are fractionated (La_cn/Lu_cn=1.5-7.3) with pronounced negative Eu anomalies (Eu/Eu*=0.46-1.1). Initial ε_Nd(i) values vary between −3.1 and 1.6, initial ⁸⁷Sr/⁸⁶Sr values between 0.7056 and 0.7067.Compared with the host rocks, the MMEs are characterized by relatively high Mg-number of 22-52, low contents of SiO₂ (53-63 wt%), low ASI (0.7-1.1) and low to medium-K tholeiitic to calc-alkaline, metaluminous to peraluminous composition. Chondrite-normalized REE patterns are relatively flat [(La/Yb)_cn=1.4-3.9; (Tb/Yb)_cn=0.9-1.5] and show small negative Eu anomalies (Eu/Eu*=0.63-1.01). Isotope signatures of these rocks (⁸⁷Sr/⁸⁶Sr_(i)=0.7054-0.7055; ε_Nd(i)=-1.0 to 1.9) are largely similar to the host rocks. Gabbroic diorite enclaves have relatively low contents of SiO₂, ASI; high Mg#, CaO, Al₂O₃, TiO₂, P₂O₅, Sr and Nb concentrations compared to dioritic and tonalitic enclaves.The geochemical and isotopic similarities between the MMEs and their host rocks indicate that the enclaves are of mixed origin and are most probably formed by the interaction between the lower crust- and mantle-derived magmas. All the geochemical data suggest that a basic magma derived from an enriched subcontinental lithospheric mantle, interacted with a crustal melt that originated from dehydration melting of the mafic lower crust at deep crustal levels. The existence of compositional and textural disequilibrium and the nature of chemical and isotopic variation in these rock types indicate that magma mixing/mingling between an evolved mafic and a granitic magma was involved in their genesis. Microgranular enclaves are thus interpreted to be globules of a more mafic magma probably from an enriched lithospheric mantle source. Al-in-amphibole estimates the pluton emplacement at ca. 0.3-3.8 kbar, and therefore, magma mixing and mingling must have occurred at 3.8 kbar or below this level.     

Magmatic evolution of the Mantos Blancos copper deposit, Coastal Range of northern Chile: insight from Sr–Nd isotope, geochemical data and silicate melt inclusions

The Mantos Blancos copper deposit (500 Mt at 1.0% Cu) was affected by two superimposed hydrothermal events: (i) phyllic alteration related to a rhyolitic dome emplacement and brecciation at ca 155 Ma; and (ii) potassic, sodic and propylitic alteration at ca 142 Ma, coeval with stocks and sills emplacement of dioritic and granodioritic porphyries, that locally grade upwards into polymictic magmatic hydrothermal breccias. Major hypogene copper sulfide mineralization is related to the second event. A late‐ore mafic dike swarm cross‐cuts all rocks in the deposit. Two types of granodioritic porphyries can be distinguished from petrographic observations and geochemical data: granodiorite porphyry I (GP I) and granodiorite porphyry II (GP II), which resulted from two different trends of magmatic evolution. The concave shape of the rare earth element (REE) distribution pattern together with the weak or absence of negative Eu anomalies in mafic dikes, dioritic and GP I porphyries, suggest hornblende‐dominated fractionation for this magmatic suite. In contrast, distinct negative Eu anomalies and the flat REE patterns suggest plagioclase‐dominated fractionation, at low oxygen fugacity, for the GP II porphyry suite. But shallow mixing and mingling between silicic and dioritic melts are also likely for the formation of the GP II and polymictic breccias, respectively. Sr‐Nd isotopic compositions suggest that the rhyolitic dome rocks were generated from a dominantly crustal source, while the GP I has mantle affinity. The composition of melt inclusions (MI) in quartz crystals from the rhyolitic dome is similar to the bulk composition of their host rock. The MI analyzed in quartz from GP II and in the polymictic magmatic hydrothermal breccia of the deposit are compositionally more evolved than their host rocks. Field, geochemical and petrographic data provided here point to dioritic and siliceous melt interaction as an inducing mechanism for the release of hydrothermal fluids to form the Cu mineralization.     

Isotopic composition and origin of mineral and geothermal waters from Tuşnad Băi Spa, Harghita Mountains, Romania

Different types of free water have been analysed for their deuterium and chemical composition in order to evaluate their source, mixing phenomena, and the underground dynamics. All types of ground water (mineral, geothermal and wellhead water) display δD values (− 82.6‰ to − 72.6‰) similar to surface waters from the studied area (− 77.1‰ to − 73.6‰). The global salt content varies from 1102 to 8707 mg/l for the groundwater, and from 46 to 392 mg/l for the surface water. From the co-variation between the δD values and the chemical composition of the waters, as well as from the seasonal variation of these two parameters, it is evident that the free water from Tuşnad Băi are meteoric in origin. The mineralization of the mineral water took place by means of an intense underground circulation, probably in the fault system developed within the Neogene magmatites.