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1.
The Rb-Sr composition of eight melt rock and three basement samples from the East Clearwater impact structure, Quebec, and two basement samples from the West Clearwater structure has been determined. The whole rock 87Sr/86Sr ratios of the melt samples, 0.7167–0.7253, are within the range of the basement samples, 0.7054–0.7322, and provide further evidence that the melt rocks represent shock-melted basement. A mineral isochron obtained from a relatively coarse grained melt rock gives an age of 287±26 Ma for the crystallization age of the melt. This is equivalent to K-Ar whole-rock ages of 285±30 Ma and 300±30 Ma and a Rb-Sr age of 266±15 Ma obtained on melt rocks from West Clearwater and confirms the previously generally held assumption that the East and West Clearwater structures resulted from the simultaneous impact of two bodies at 285–300 Ma ago.Contribution from the Earth Physics Branch No. 909  相似文献   

2.
Physical properties and the crystallization behavior of natural diaplectic labradorite glass of the shocked anorthosite from the Manicouagan impact crater have been studied. Glasses prepared by laboratory fusion of this anorthosite and a synthetic An55 plagioclase composition were used for comparison. The close similarities in the mid-and far-infrared spectra of the diaplectic and fused glasses indicate a comparable degree of short-range order and lack of long-range order in their structures. They also show an identical viscosity-temperature relation, reflecting a similar and probably high degree of coherence of the (Si,Al)O4 tetrahedra in the network. However, striking differences exist in the crystallization characteristics. Diffusion-controlled crystallization takes place in the fused glass between about 900 and 1,400° C and proceeds generally by the advance of dendritic crystal layers from the surface into the interior of the samples. By contrast, diffusion plays a minor, if any, role in the crystallization of the diaplectic glass, which, on annealing between 800 and 1,000° C reverts to the original plagioclase structure and the primary mineral grains are restored. From the present experimental results it is suggested that high shock-induced temperatures cause onset of the melting process in the compressed crystalline labradorite. However, due to the extremely short duration of the transient high-temperature excursions, the crystal-melt transition does not come to completion. Instead, a disordered transitional state of the compressed material is frozen-in which is recovered after pressure release as diaplectic glass. Its structure thus represents a frozen-in disordered state intermediate between the structures of the crystalline labradorite and its melt. It appears that the diaplectic glass structure is rather inhomogeneous, thereby reflecting the heterogeneous deformational and thermal conditions associated with shock compression.  相似文献   

3.
The methamorphic history of the Patapedia thermal zone, Gaspé, Quebec, is re-evaluated in the light of results obtained from a study of fluid inclusions contained in quartz phenocrysts of felsic dyke rocks. The thermal zone is characterised by calc-silicate bodies that have outwardly telescoping prograde metamorphic isograds and display extensive retrograde metamorphism with associated copper mineralization. Three distinct fluid inclusion types are recognized: a low to moderate salinity, high density aqueous fluid (Type I); a low density CO2 fluid (Type II); and a high salinity, high density aqueous fluid (Type III). Fluid inclusion Types I and II predominate whereas Type III inclusions form <10% of the fluid inclusion population. All three fluid types are interpreted to have been present during prograde metamorphism. Temperatures and pressures of metamorphism estimated from fluid inclusion microthermometry and isochore calculations are 450°–500° C and 700–1000 bars, respectively. A model is proposed in which the metamorphism at Patapedia was caused by heat transferred from a low to moderate salinity fluid of partly orthomagmatic origin (Type I inclusions). During the early stages, and particularly in the deeper parts of the system, CO2 produced by metamorphism was completely miscible in the aqueous hydrothermal fluid and locally resulted in high XCO2 fluids. On cooling and/or migrating to higher levels these latter fluids exsolved high salinity aqueous fluids represented by the Type III inclusions. Most of the metamorphism, however, took place at temperature-pressure conditions consistent with the immiscibility of CO2 and the hydrothermal fluid and was consequently accompanied by the release of large volumes of CO2 vapour which is represented by Type II inclusions. The final stage of the history of the Patapedia aureole was marked by retrograde metamorphism and copper mineralization of a calcite-free calc-silicate hornfels in the presence of a low XCO2 fluid.  相似文献   

4.
A CdSe high-pressure polymorph of the NaCl structural type of a0 = 0.549 nm and Fm–3m space group was discovered in nature for the first time. Its composition is within range of CdSe–CdSe1–х where x = 0.2 apfu. The phase was discovered as abundant nanosize inclusions in irgizite-type condensate glass separated from the sample of impact rock of the Zhamanshin crater (Central Kazakhstan). The treated mineral was presumably formed within a gas–plasma cloud at the moment of impact.  相似文献   

5.
The Integrated Lake Watershed Acidification Study (ILWAS) model was used to simulate the recovery of the highly acidified Clearwater Lake, Ontario. Recovery started in the mid-1970s and continued through the 1980s in response to an estimated 30–50% decrease in S deposition from smelter emissions in nearby Sudbury, Ontario. Appreciable recovery of Clearwater Lake between the mid-1970s and 1987 is simulated by the ILWAS model, as indicated by a 50% decrease in SO4 concentration, an 80% decrease in total Al concentration, an increase in acid-neutralizing capacity (ANC) from −60 to −17 μeq/l, and an increase in pH from 4.2 to 4.8. These decreases in acidic constituents are in good agreement with monitoring data. Long-term simulations indicate that deacidification may continue until 2020, if S deposition rates remain at or less than the 1987 level. Simulations for years beyond 2020 yield yearly average ANC values of 18–40 μeq/l and pH values of 6.2–6.6, which are comparable to the estimated pre-smelter pH of 6.0–6.5 for Clearwater Lake. The agreement between simulated and monitoring data for the first 10 a of recovery and the simulated long-term recovery of the lake to its presmelter level of acidity lend confidence in the capability of numerical models to simulate the reversibility of watershed acidification and suggest that some highly acidic watersheds may eventually recover, given substantial decreases in acid deposition.  相似文献   

6.
Physical evidence for the drainage of glacial lakes remains relatively rare in depositional records, giving rise to much debate on the location of outlets and discharge pathways, as well as on the climate impact of the attendant meltwater forcing. Lake Ojibway developed following the withdrawal of the Laurentide Ice Sheet in northern Ontario and Quebec, Canada. The late‐stage evolution of this large ice‐dammed lake was influenced by the complex dynamics of the retreating ice margin, which highly complicates the identification of the termination of Lake Ojibway in glaciolacustrine sediment records. Here, we document the composition of sections of rhythmites that contain in their upper part an anomalously thick and whitish bed (10–15 cm) that is in turn overlain by ~1 m of faintly bedded rhythmites. Grain‐size analyses showed that the thick whitish bed consists primarily of fine to coarse silt (2–63 μm), contrasting with the lower and upper rhythmites that are largely dominated by clay (<2 μm). The detrital carbonate content of the thick silt bed is characterized by consistently high values (2.5 to 2.8%), whereas the bounding rhythmites show lower and highly variable values. Oxygen isotope measurements further show a marked change going from typical glacial meltwater values (~ ?29.6 to ?27.7‰; VSMOW) for the lower rhythmites and the silt bed to modern‐like meteoric values (?18.4 to ?14.6‰) for the uppermost rhythmites. These data suggest that this marker bed may be associated with a major drawdown event that possibly corresponds to the final drainage of Lake Ojibway. AMS radiocarbon dating of ostracods extracted from the drainage bed also documents an important hardwater effect within the Ojibway basin.  相似文献   

7.
The Boltysh meteorite impact crater, Ukraine, formed at the Cretaceous–Palaeogene boundary at ca 65·2 Ma. A borehole drilled in the central part of the crater cored a >400 m thick high‐resolution lacustrine succession that covers the Dan‐C2 hyperthermal event associated with a negative carbon isotope excursion. Continuous terrestrial records of past hyperthermals are of limited availability, which makes this record a unique case study of the continental impact of rapid climate warming. This study uses high‐resolution sedimentological core log data together with thin‐section, X‐ray diffraction, microprobe and palynological analyses to: (i) reconstruct lake sedimentological and ecological development across the carbon isotope excursion; and (ii) assess the environmental effect of hyperthermals on terrestrial ecosystems. Based on detailed facies analysis, five gradual stages of lake formation are identified, which show a strong relationship to carbon isotope shifts and associated climatic trends. Initially, sediment supply into the Boltysh lake was controlled by crater morphology. During later lake stages, sediment supply was increasingly controlled by changes in inflow–evaporation ratios which affected seasonal stratification patterns and longer term lake levels. An inferred increase in atmospheric pCO2 related to the carbon isotope excursion, together with increasing mean annual temperatures, was probably responsible for periodic increases in biological activity of photosynthesising organisms and biomass production. These fluctuations in facies and lake settings largely correspond to orbital‐paced moisture availability oscillations. The gradual reduction in sediment supply commencing during early lake formation prior to carbon isotope excursion inception suggest that the Dan‐C2 event did not initiate sedimentary changes, but intensified sedimentary response to orbital controlled climate change.  相似文献   

8.
The composition of the sampled melt rocks at the 22 km diameter E. Clearwater impact structure indicates the presence of ~8% C-1 material. The meteoritic component is fractionated with refractory siderophiles, up to 30 times C-1 abundances, concentrated in ten to hundred micron-sized, magnetic particles. These particles consist of the Ni-sulphide, millerite, and what is assumed to be a mixture of refractory silicates and magnetite with grain sizes of <1 μm. The larger particles have a core-rim structure with millerite and occasionally very minor galena and possibly pentlandite in the core. An origin as a combination of altered meteoritic metal and condensed meteoritic silicate is favored for the origin of the siderophile-rich particles. If 8% meteoritic material is taken as the average meteoritic contamination in the melt, then the E. Clearwater projectile may have impacted with a velocity of 17 km s?1. Peak shock pressures would have been of the order of 300 GPa, sufficient to vaporize the silicate component but only melt the metal component of the projectile. As the meteoritic material was being driven down into vaporized/ melted target rocks during the initial stages of impact, the melted Fe, Ni metal underwent oxidation, Fe was removed, and meteoritic silicate material recondensed on the cooler, essentially Ni metal. As cavity excavation proceeded, these Ni metal, silicate-oxide particles were incorporated in the melt, their refractory nature prevented thermal digestion and sulphur in the melt reacted with the metal to produce millerite on final equilibration. If this hypothesis is correct, it suggests that the E. Clearwater projectile was a C-2 or C-3 chondrite, both of which are compatible with the trace element composition of the melt rocks. Clearwater Lake is a twin impact structure formed by an asteroid pair. It is still not clear, however, what type of projectile formed the 32 km diameter western structure, where the surface melt rocks contain no identifiable meteoritic signature.  相似文献   

9.
Cheko, a small lake located in Siberia close to the epicentre of the 1908 Tunguska explosion, might fill a crater left by the impact of a fragment of a Cosmic Body. Sediment cores from the lake’s bottom were studied to support or reject this hypothesis. A 175‐cm long core, collected near the center of the lake, consists of an upper ~1 m thick sequence of lacustrine deposits overlaying coarser chaotic material. 210Pb and 137Cs indicate that the transition from lower to upper sequence occurred close to the time of the Tunguska Event. Pollen analysis reveals that remains of aquatic plants are abundant in the top post‐1908 sequence, but are absent in the lower pre‐1908 portion of the core. These results, including organic C, N and δ13C data, suggest that Lake Cheko formed at the time of the Tunguska Event.  相似文献   

10.
The structural state of diaplectic labradorite glass (≈An58) from the Manicouagan impact crater and of its fusion-formed glass analog have been investigated by X-ray diffraction studies. The experimental X-ray intensity distribution patterns indicate that the diaplectic and fusion-formed glasses are structurally rather similar, the former being apparently slightly less disordered. Theoretical X-ray distribution curves have been calculated using the structure of high albite as a quasi-crystalline model of the glass structure. The experimental and theoretical curves show fair similarity when the calculations are based on the complete unit cell. It is inferred therefore, that the structures of both kinds of glasses possess an average short range order comparable to that in high albite and extending to about the dimensions of the unit cell. In addition, the experimental X-ray scattering pattern and X-ray Debye-Scherrer transmission photographs of the diaplectic glass reveal the presence of relics up to about 8 nm in size of the previous crystalline lattice of the primary labradorite. The present results support Grady's shear band model according to which diaplectic glass may represent the quench product of a shock-generated high-density melt frozen in prior to total pressure release.  相似文献   

11.
An attempt is made to correlate and separate in terms of style and time two contrasting sets of structural elements in the northwestern part of the Appalachian Uplands in the Province of Quebec, Canada. There is sufficient evidence to indicate that a fold system with north-south trending axes is superimposed on a fold system with east-west axes. It is suggested that the two sets of structures represent pulses of one long-continued deformation accompanied by corresponding early and late phases of metamorphism.
Zusammenfassung Es wurde versucht, in den Appalachen des südöstlichen Teiles der Provinz Quebec, Kanada, zwei ungleichzeitige tektonische Systeme verschiedenen Baustils zu trennen. Die komplexen Kleinstrukturen zeigen, da\ Ost-West streichende Faltenachsen von einer jüngeren Nord-Süd-Faltung überprägt worden sind. Der Autor ist der Meinung, da\ die zwei tektonischen Systeme, die von einer frühen und späten Phase der Metamorphose begleitet werden, den zeitlich getrennten Verformungsstadien einer Orogenese entsprechen.
  相似文献   

12.
The composition of the sampled melt rocks at the 22 km diameter E. Clearwater impact structure indicates the presence of 8% C-1 material. The meteoritic component is fractionated with refractory siderophiles, up to 30 times C-1 abundances, concentrated in ten to hundred micron-sized, magnetic particles. These particles consist of the Ni-sulphide, millerite, and what is assumed to be a mixture of refractory silicates and magnetite with grain sizes of <1 m. The larger particles have a core-rim structure with millerite and occasionally very minor galena and possibly pentlandite in the core. An origin as a combination of altered meteoritic metal and condensed meteoritic silicate is favored for the origin of the siderophile-rich particles. If 8% meteoritic material is taken as the average meteoritic contamination in the melt, then the E. Clearwater projectile may have impacted with a velocity of 17 km s–1. Peak shock pressures would have been of the order of 300 GPa, sufficient to vaporize the silicate component but only melt the metal component of the projectile. As the meteoritic material was being driven down into vaporized/ melted target rocks during the initial stages of impact, the melted Fe, Ni metal underwent oxidation, Fe was removed, and meteoritic silicate material recondensed on the cooler, essentially Ni metal. As cavity excavation proceeded, these Ni metal, silicate-oxide particles were incorporated in the melt, their refractory nature prevented thermal digestion and sulphur in the melt reacted with the metal to produce millerite on final equilibration. If this hypothesis is correct, it suggests that the E. Clearwater projectile was a C-2 or C-3 chondrite, both of which are compatible with the trace element composition of the melt rocks. Clearwater Lake is a twin impact structure formed by an asteroid pair. It is still not clear, however, what type of projectile formed the 32 km diameter western structure, where the surface melt rocks contain no identifiable meteoritic signature.  相似文献   

13.
Mt. St. Hilaire occurs as a small funnel-shaped intrusion in the Monteregian petrographic province of Quebec and consists of alkali gabbros and later nepheline syenites. Based on field relations, petrography, and geochemistry, five types of gabbro are recognized. In order of intrusion these are: leucogabbro, foliated gabbro, kaersutite-biotite gabbro, kaersutite gabbro, and a gabbro-melagabbro series. Based on analyses of the early-forming ilmenite-titanomagnetite, the gabbros crystallized under high fO2 conditions which lead to subsequent crystallization of olivines with high MnO contents. Fractionation of ilmenite and titanomagnetite was a major control on the Ti and A[TV]concentrations in the clinopyroxenes. Plagioclase compositions in the gabbros became richer in Ab contents in the sequence gabbro-melagabbro to leucogabbro. Whole-rock analyses suggest that the parental magma of alkali basaltic composition was fairly evolved prior to emplacement. Lack of olivine in the cumulate gabbro-melagabbros and low Ni and Cr in all gabbros may reflect either extreme olivine fractionation and/or a very low olivine content in the source material for these basalts. Differentiation of the gabbros occurred both pre- and post-emplacement, probably by a process of crystal-liquid fractionation at depths between 3-5 and 8 km. This is in accordance with geophysical measurements for other Monteregian intrusions. A model is presented for the mechanism of emplacement.  相似文献   

14.
The textural relationships and structural states of optically isotropic labradorite from the Manicouagan, Quebec, impact structure have been examined by light (optical) and transmission electron (TEM) microscopy. Two distinct diaplectic glasses have been recognized based on their contrasting morphology, timing and the inferred modes of formation. The earliest isotropic bands and grain-scale isotropism (maskelynite) optically exhibit a gradational,in situ transformation from crystalline plagioclase with preservation of relict textures (twins, grain boundaries). The same transformation from crystalline to amorphous structure is observed in TEM to occur heterogeneously at scales on the order of the unit cell. The progressive transformation of optical properties reflects an increase in the volume fraction and eventual coalescence of these amorphous units. This maskelynite-type diaplectic glass is interpreted to form in the solid-state directly from crystalline material during the compressional phase of the shock wave. The other isotropic material occurs in spatially discrete tensiongashes and planar deformation features (PDFs) that overprint the maskelynite-type glass. This second type of diaplectic glass (PDF-type) is developed homogeneously within a given glass band and exhibits sharp crystal-glass boundaries, in contrast to the gradational boundaries of the maskelynite-type glass. PDF-type glass is interpreted to form by melting in tensional release zones during passage of the rarefaction wave. These observations emphasize the ability of naturally shocked rocks to preserve subtle evidence of variations in the shock process from highly transient events.  相似文献   

15.
A well-developed regolith is preserved beneath early Proterozoic (Aphebian) rocks of the Otish and Mistassini Groups in Central Quebec, Canada. The regolith is covered by fluviatile clastic rocks (Otish Group) in the north, and by a thick sequence of stromatolitic and sandy dolomite (Mistassini Group) in the south.Where preserved beneath clastic rocks, the regolith exhibits the structures and textures of its crystalline parent rocks (tonalite, gneiss and amphibolite), despite the alteration of feldspars to clay minerals and the partial oxidation of biotite. A later event recrystallized the clay minerals to muscovite, while conserving the original outline of the feldspars. Beneath the dolomite, the regolith was largely replaced by dolomite, but retains many original textures. Dolomite replaced first the clay minerals, then quartz and unaltered feldspars and finally biotite. Repeated crustifications of dolomite with intervals of chert and minor anthraxolite surround unaltered blocks of crystalline rock within the regolith profile and similar complex veins fill many master joints. These veins are identical in composition to vug fillings throughout the overlying carbonate formations. Clasts of partly dolomitized regolith included in non-dolomitic sands filling channels and scours dug deep into the profile, suggest that dolomitization commenced very early, possibly related to a sabkha environment developed during the transgression.  相似文献   

16.
A progressive change in the level of shock deformation is documented in autochthonous rocks from the central uplift of the Slate Islands impact structure, Lake Superior. Correlation of these observations, which are based mainly on the relative frequency of planar features of specific crystallographic orientation in quartz, with experimental data is used to estimate the average shock pressures recorded in the samples studied. Recorded pressures range from 5.8 to 15.3 GPa and generally increase towards the proposed shock centre. Variations in the shock response of quartz of different grain size and texture are observed within and between samples. It is apparent that large interlocking quartz grains in eyes record approximately 15–20% higher levels of shock deformation than small grains in mosaics or large isolated phenocrysts. These variations in shock deformation are attributed to the effect of shock wave reverberations between grains and length of shock pulse duration within grains.Comparison of the Slate Islands data with similar observations at the larger Charlevoix impact structure indicates that the rate of change of recorded shock pressure with distance is greater at the Slate Islands structure. This is interpreted as due to variations in the strain rates and/or the rate of shock wave attenuation with radial distance between impact structures of different size.Contribution from Earth Physics Branch No. 626  相似文献   

17.
尹锋  陈鸣 《岩石学报》2022,38(3):901-912
撞击角砾岩是陨石撞击过程形成的特有岩石种类,是研究撞击成坑过程、陨石坑定年、矿物岩石冲击变质的理想对象。岫岩陨石坑是一个直径1800m的简单陨石坑,坑内有大量松散堆积的撞击角砾岩。本研究通过光学显微镜、费氏台、电子探针、X射线荧光光谱仪、电感耦合等离子质谱仪等分析测试手段,主要研究了岫岩陨石坑撞击角砾岩的岩相学和冲击变质特征,并在此基础上讨论了撞击角砾岩的形成过程和陨石坑的形貌特征。岫岩陨石坑内产出有三种撞击角砾岩,分别是来自上部的玄武质角砾岩和复成分岩屑角砾岩,以及底部的含熔体角砾岩。组成玄武质角砾岩和复成分岩屑角砾岩的碎屑受到的冲击程度较低,仅有少量石英发育面状变形页理,指示不超过20GPa的冲击压力。而组成含熔体角砾岩的碎屑受到了很强的冲击,发育了熔融硅酸盐玻璃、石英面状变形页理、柯石英、二氧化硅玻璃、击变长石玻璃、莱氏石等冲击变质特征,指示的峰值压力超过50GPa。本研究证实了含熔体角砾岩通常产出在简单陨石坑底部,由瞬间坑的坑缘和坑壁垮塌的岩石碎屑与坑底的冲击熔体混合形成。岫岩坑的真实深度是495m,真实深度与直径的比值为0.275,符合简单陨石坑的尺寸特征。陨石坑内的撞击角砾岩中心厚度为188m,与直径之比为0.104,略低于其它简单坑,可能是受丘陵地貌影响导致改造阶段垮塌到坑内的岩石角砾偏少。  相似文献   

18.
贵州太平洞金矿床流体包裹体特征及流体不混溶机制   总被引:5,自引:2,他引:5  
太平洞金矿床是兴仁-安龙金矿带灰家堡金矿区的重要卡林型金矿之一。流体包裹体研究证明,石英-黄铁矿阶段(Ⅰ)、石英-黄铁矿-毒砂阶段(Ⅱ)、石英-方解石-雄黄阶段(Ⅲ)的包裹体类型丰富,以气液水两相包裹体、CO2-H2O包裹体和纯液相水包裹体为主,CO2两相包裹体、纯气相有机质包裹体和有机质-H2O包裹体次之,偶见气液有机质包裹体。由Ⅰ→Ⅱ→Ⅲ阶段,气液水包裹体均一温度(200~260℃→180~240℃→100~160℃)呈现逐渐降低的趋势。在Ⅰ阶段的石英中,只在局部偶见到CO2-H2O包裹体和气液两相水包裹体共生;在Ⅱ阶段的石英中,纯液相水包裹体、气液两相盐水包裹体、CO2-H2O包裹体、CO2包裹体及纯气相有机质包裹体共存,它们共生在同一平面中且气液两相盐水包裹体和CO2-H2O包裹体测温数据相差不大,说明当时捕获的是不均匀成矿流体,它是由含有机质的成矿流体经历了CO2-低盐度水的不混溶作用形成的。因而认为,太平洞金矿床中成矿早期流体不混溶作用不明显,主成矿阶段流体的不混溶作用是导致金矿质沉淀的重要原因。  相似文献   

19.
20.
Mineral exploration drilling 60 km west of Leonora in 2008 intersected >95 m of poorly consolidated granitoid-dominated breccia at the base of a Cenozoic paleochannel beneath Lake Raeside. The breccia, initially interpreted as a kimberlite, is composed of poorly consolidated fragments of granitic gneiss, felsite and metamorphosed mafic rock within a matrix of fine to medium-grained breccia. Microscopic examination revealed quartz grains displaying well-developed planar deformation features (PDFs) dominated by the ω? {1013} planar set, diaplectic silica glass and diaplectic plagioclase glass. These features constitute the diagnostic hallmarks of shock metamorphism owing to high-velocity impact of a large meteorite or asteroid. The PDFs in quartz grains of the breccia are distinctly different from metamorphic deformation lamellae produced tectonically or in diatremes. Airborne total magnetic intensity data suggest an outline of an 11 km-diameter crater, consistent with the significant thickness of the shock-metamorphosed breccia at >95 m, suggestive of the existence of a large impact structure.  相似文献   

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