Palaeomagnetic investigation of Cenozoic volcanic rocks bordering the North Anatolian Fault Zone,Reşadiye and Koyulhisar Districts,central-east Anatolia,Turkey

A palaeomagnetic study is reported from the lavas of Eocene, Miocene and Pliocene age cropping out immediately to the north of the North Anatolian Fault Zone (NAFZ) in the Re?adiye–Mesudiye region of central-eastern Anatolia. Rock magnetic investigations identify a high percentage of multi-domained magnetite as the dominant ferromagnet in these rocks and this probably accounts for a relatively poor response to alternating field and thermal demagnetisation. Thirty of 37 units yielded acceptable groupings of characteristic magnetisation directions. An earlier study indicated small anticlockwise crustal block rotation in this region since Upper Cretaceous times (D/I?=?347/50°), and our study indicates that this was overtaken by clockwise rotation in Eocene times (D/I?=?40/47°), although sample size control from the Palaeogene is poor. Results from later Miocene (D/I?=?2/62°) and Pliocene (D/I?=?0/53°) volcanic rocks indicate that no significant tectonic rotation has occurred in the north of the NAFZ in Neogene times. This contrasts with rotations in the weaker crust comprising the Anatolian collage south of the NAFZ, where differential and sometimes large anticlockwise rotations occurred during the latter part of the Neogene.     

Paleomagnetic versus GPS determined tectonic rotation around eastern Himalayan syntaxis in East Asia

Northward indentation of the Indian Plate has brought about significant tectonic deformation into East Asia. A record of long-term tectonic deformation in this area for the past 50 M yr, particularly the vertical axis rotation, is available through paleomagnetic data. In order to depict rotational deformation in this area with respect to Eurasia, we compiled reliable paleomagnetic data sets from 79 localities distributed around eastern Himalayan syntaxis in East Asia. This record delineates that a zone affected by clockwise rotational deformation extends from the southern tip of the Chuan Dian Fragment to as far as the northwestern part of the Indochina Peninsula. A limited zone that experienced a significant amount of clockwise rotation after an initial India–Asia collision is now located at 23.5°N, 101°E, far away from an area (27.5°N, 95.5°E) where an intense rotational motion has been viewed by a snapshot of GPS measurements. This discrepancy in clockwise rotated positions is attributed to southeastward extrusion of the tectonic blocks within East Asia as a result of ongoing indentation of the Indian Plate. A quantitative comparison between the GPS and paleomagnetically determined clockwise rotation further suggests that following an initial India–Asia collision the crust at 30°N, 94°E paleoposition was subjected to southeastward displacement together with clockwise rotation, which eventually reached to present-day position of 23.5°N, 101°E, implying a crustal displacement of about 1000 km during the past 50 M yr.     

Paleogeographic evidence on the Jurassic tectonic history of the Pontides: new paleomagnetic data from the Sakarya continent and Eastern Pontides

The Jurassic paleogeographic position of the Pontides is not well studied because of insufficient paleomagnetic data. For this reason, a paleomagnetic study was carried out in order to constrain the paleolatitudinal drift of the Turkish blocks during the Jurassic period. A total of 32 sites were sampled from volcanic and volcanoclastic rocks of the Lower/Middle Jurassic Kelkit formation (Eastern Pontides), Mudurnu formation (Sakarya continent) and Upper Jurassic–Lower Cretaceous Ferhatkaya formation exposed around Amasya region (Eastern Pontides). Rock magnetic experiments demonstrate that the main ferromagnetic mineral is pseudo-single-domain titanomagnetite in these rocks. Paleomagnetic analysis revealed two main components of the natural remanent magnetization during stepwise thermal and alternating field demagnetization. The first component is a low-coercivity (unblocking temperature) component with a direction sometimes similar to that of the earth’s present field or a viscous component. The second component, which is interpreted as the characteristic remanent magnetization (ChRM) direction, has low to high coercivity properties between 20 and 100 mT or unblocking temperatures between 300 and 580°C. A positive fold test at the 95% level of confidence proved that the ChRM of the sites is primary. Paleomagnetic directions calculated for the Kelkit formation in the Eastern Pontides have a mean direction of D = 334.8°, I = 49.7°, α ₉₅ = 7.1° after tilt-correction. A mean direction of D = 332.2°, I = 48.5°, α ₉₅ = 14.6° was obtained from the volcanoclastic rocks of the Mudurnu formation, and D = 324.3°, I = 43.3°, α ₉₅ = 9.5° was calculated for the Upper Jurassic–Lower Cretaceous limestones/Ferhatkaya formation of the Amasya region. The Jurassic rocks in the Eastern Pontides and Mudurnu region are considered to represent products of the rifted Neo-Tethys ocean, while the Upper Jurassic–Lower Cretaceous sediments in Amasya are related to basin-filling materials. The data suggest that the Kelkit formation was formed at 30.5°N paleolatitude and the equivalent Mudurnu formation at 29.5°N paleolatitude. The paleolatitude of the Eastern Pontides indicates that this rifting block was separated from Eurasia by a marginal basin instead of being a part of Eurasia. The lower paleolatitude of the Amasya region at 24.8°N in the Upper Jurassic to Lower Cretaceous clearly indicates southward drift of the Turkish blocks during the Jurassic to Lower Cretaceous period together with the motion of Eurasia.     

Neogene rotations of the Chenoua massif,northern Algeria,from remagnetizations

The tectonics of the Chenoua massif suggests block rotations of Neogene nappes associated with the African–European plate convergence. To estimate the extent of these rotations, a Paleomagnetic study on rhyolites and andesites of Langhian–Serravallian age and sandstones of Burdigalian age was carried out on 23 sites (200 specimens). The sites are distributed in the northwestern, southeastern and southern Chenoua massif. One or two components of magnetization, mainly carried by magnetite, pyrrhotite and/or hematite, were isolated in sandstones and volcanics. The sandstone sites reveal magnetizations in sandstones from the Cap Blanc syncline that are post-folding. However, both polarities are found, which is consistent with data from Africa during the Upper Miocene. Clockwise and counterclockwise rotations were recorded, dating back to the Neogene times in volcanics and sediments. From the faulted Cap Blanc syncline counterclockwise rotations of 1?±?4° to 18?±?28° around a vertical axis occurred in sediments since the Miocene with respect to Africa. In fact, remagnetizations occurred at several periods of time and in different sites, providing information on the evolution of post-tectonic rotations. Some volcanics record counterclockwise rotations of about 30° since the Miocene, whereas others do not show any significant rotation. This can be explained by the direction of the principal compressive stress axis σ ₁ and by lateral extrusions related to an indentation model, in which we expect both clockwise and counterclockwise rotations.     

Geology of the epithermal Ag–Au Huevos Verdes vein system and San José district, Deseado massif, Patagonia, Argentina

The San José district is located in the northwest part of the Deseado massif and hosts a number of epithermal Ag–Au quartz veins of intermediate sulfidation style, including the Huevos Verdes vein system. Veins are hosted by andesitic rocks of the Bajo Pobre Formation and locally by rhyodacitic pyroclastic rocks of the Chon Aike Formation. New ⁴⁰Ar/³⁹Ar constraints on the age of host rocks and mineralization define Late Jurassic ages of 151.3 ± 0.7 Ma to 144.7 ± 0.1 Ma for volcanic rocks of the Bajo Pobre Formation and of 147.6 ± 1.1 Ma for the Chon Aike Formation. Illite ages of the Huevos Verdes vein system of 140.8 ± 0.2 and 140.5 ± 0.3 Ma are 4 m.y. younger than the volcanic host rock unit. These age dates are among the youngest reported for Jurassic volcanism in the Deseado massif and correlate well with the regional context of magmatic and hydrothermal activity. The Huevos Verdes vein system has a strike length of 2,000 m, with several ore shoots along strike. The vein consists of a pre-ore stage and three main ore stages. Early barren quartz and chalcedony are followed by a mottled quartz stage of coarse saccharoidal quartz with irregular streaks and discontinuous bands of sulfide-rich material. The banded quartz–sulfide stage consists of sulfide-rich bands alternating with bands of quartz and bands of chlorite ± illite. Late-stage sulfide-rich veinlets are associated with kaolinite gangue. Ore minerals are argentite and electrum, together with pyrite, sphalerite, galena, chalcopyrite, minor bornite, covellite, and ruby silver. Wall rock alteration is characterized by narrow (< 3 m) halos of illite and illite/smectite next to veins, grading outward into propylitic alteration. Gangue minerals are dominantly massive quartz intergrown with minor to accessory adularia. Epidote, illite, illite/smectite, and, preferentially at deeper levels, Fe-chlorite gangue indicate near-neutral pH hydrothermal fluids at temperatures of >220°C. Kaolinite occurring with the late sulfide-rich veinlet stage indicates pH < 4 and a temperature of <200°C. The Huevos Verdes system has an overall strike of 325°, dipping on average 65° NE. The orientations of individual ore shoots are controlled by vein strike and intersecting north-northwest-striking faults. We propose a structural model for the time of mineralization of the San José district, consisting of a conjugate shear pair of sinistral north-northwest- and dextral west-northwest-striking faults that correspond to R and R′ in the Riedel shear model and that are related to master faults (M) of north-northeast-strike. Veins of 315° strike can be interpreted as nearly pure extensional fractures (T). Variations in vein strike predict an induced sinistral shear component for strike directions of >315°, whereas strike directions of <315° are predicted with an induced dextral strike–slip movement. The components of the structural model appear to be present on a regional scale and are not restricted to the San José district.     

E–W extension and block rotation of the southeastern Tibet: Unravelling late deformation stages in the eastern Himalayas (NW Bhutan) by means of pyrrhotite remanences

In the Himalayan chain the collision of India into Eurasia has produced some of the most complex crustal interactions along the Himalayan–Alpine Orogen. In NW Bhutan, middle to late Miocene deformation has been partitioned between conjugate strike-slip faulting, E–W extension along the Yadong-Gulu graben and kilometre-scale folding. To better understand the late deformation stages and their implications for the evolution of the eastern Himalayas, the palaeomagnetism in the erosional remnant of the Tethyan Himalayan rocks outcropping in NW Bhutan has been studied. Their position to the south of the trace of the inner South Tibetan Detachment, to the south of the Tibetan Plateau offers a unique possibility to study the Tertiary rotation of the Himalayas. Pyrrhotite is the carrier of the characteristic magnetisation based on 270–325 °C unblocking temperatures. The age of the remanence is ca. 13 Ma indicated by illite ⁴⁰K/⁴⁰Ar cooling ages and a negative fold test. Small circle intersection method applied to the pyrrhotite components shows a ca. 32° clockwise rotation with respect to stable India since 13 Ma. We suggest that this clockwise rotation is related to strain partitioning between NE-directed shortening, sinistral-slip along the Lingshi fault, and east–west extension. This represents a field-based explanation and a minimum onset age for present-day eastward motion of the upper-crust of SE-Tibet and NE-Himalayas.     

A paleomagnetic study of the Basque Arc (Basque-Cantabrian Basin,Western Pyrenees)

The Basque Arc constitutes the northern segment of the Basque-Cantabrian basin, in the western part of the Pyrenees. The main goal of the present study was to find out by means of paleomagnetic analysis if the arched shape of the Basque Arc has a primary origin, due to the development of sedimentary basins related to the opening of the Bay of Biscay or a secondary origin due to rotations about vertical axes. Nine volcanic flows of late Albian to Santonian age (100–83.5 My) were sampled together with 10 sedimentary sites (marls, limestones, calcarenites and sandstones) of lower Jurassic to early Eocene age in order to carry out paleomagnetic and rock-magnetic experiments, 15 paleodirections being obtained. In order to analyse these results together with data from previous studies, the studied area was subdivided into a western, a central and an eastern sector. While inclinations of all three sectors show a similar value, declinations differ. The western sector displays a 37 ± 16° clockwise rotation of its mean paleodeclination, the central sector is not rotated (4 ± 9°) and both sedimentary sites which make up the eastern sector show counter-clockwise rotations (−25 ± 11° and −68 ± 9°). These results suggest that the shape of the Basque Arc does not have a primary origin, but a secondary origin due to rotations about vertical axes as a result of differential shortening related to post-Lutetian compressive tectonics which resulted in the formation of the Pyrenees.     

Thermobarometric constraints on pressure variations across the Plattengneiss shear zone of the Eastern Alps: implications for exhumation models during Eoalpine subduction

Forward and inverse mineral equilibria modelling of metapelitic rocks in the hangingwall and footwall of the Plattengneiss, a major shear zone in the Eastern Alps, is used to constrain their tectonometamorphic evolution and assess models for their exhumation. Forward (pseudosection) modelling of two metapelitic rocks suggests a steep clockwise P–T path with a near‐isothermal decompression segment from a pressure peak at ~18–19 kbar and 670 °C to the metamorphic peak at 680–720 °C and 11–13 kbar. A subsequent decrease to 600–645 °C and 8–9 kbar is inferred from the late growth of staurolite in some samples. Conventional thermobarometric calculations (inverse modelling) on 18 samples with the inferred peak assemblage garnet + plagioclase + muscovite + biotite + quartz + rutile ± ilmenite ± kyanite are associated with large 2σ uncertainties, and absolute pressures calculated for all samples are statistically indistinguishable. However, calculations constraining relative pressure differences (ΔP) between samples sharing a common mineral assemblage are associated with much smaller uncertainties and yield pressure differences that are statistically meaningful. Although the overall pattern is complicated, the results suggest a pressure gradient of up to 3 kbar across the shear zone that is consistent with volume loss and a model of exhumation related to slab extraction for the Plattengneiss shear zone.     

Low‐pressure–high‐temperature metamorphism during extension in a Jurassic magmatic arc,Central Pontides,Turkey

Magmatic arcs are zones of high heat flow; however, examples of metamorphic belts formed under magmatic arcs are rare. In the Pontides in northern Turkey, along the southern active margin of Eurasia, high temperature–low pressure metamorphic rocks and associated magmatic rocks are interpreted to have formed under a Jurassic continental magmatic arc, which extends for 2800 km through the Crimea and Caucasus to Iran. The metamorphism and magmatism occurred in an extensional tectonic environment as shown by the absence of a regional Jurassic contractional deformation, and the presence of Jurassic extensional volcaniclastic marine basin in the Pontides, over 2 km in thickness, where deposition was coeval with the high‐T metamorphism at depth. The heat flow was focused during the metamorphism, and unmetamorphosed Triassic sequences crop out within a few kilometres of the Jurassic metamorphic rocks. The heat for the high‐T metamorphism was brought up to crustal levels by mantle melts, relicts of which are found as ultramafic, gabbroic and dioritic enclaves in the Jurassic granitoids. The metamorphic rocks are predominantly gneiss and migmatite with the characteristic mineral assemblage quartz + K‐feldspar + plagioclase + biotite + cordierite ± sillimanite ± garnet. Mineral equilibria give peak metamorphic conditions of 4 ± 1 kbar and 720 ± 40 °C. Zircon U–Pb and biotite Ar–Ar ages show that the peak metamorphism took place during the Middle Jurassic at c. 172 Ma, and the rocks cooled to 300 °C at c. 162 Ma, when they were intruded by shallow‐level dacitic and andesitic porphyries and granitoids. The geochemistry of the Jurassic porphyries and volcanic rocks has a distinct arc signature with a crustal melt component. A crustal melt component is also suggested by cordierite and garnet in the magmatic assemblage and the abundance of inherited zircons in the porphyries.     

Palaeomagnetic assessment of plutons from the southern Peninsular Ranges batholith and the Jurassic Vizcaíno igneous suites,Baja California,México

ABSTRACT

We report geological and palaeomagnetic data from five discrete plutons in the southern part of the Peninsular Ranges batholith (PRB) and one pluton that is part of the Jurassic plutonic suite in the Vizcaíno peninsula. The PRB plutons are Cretaceous and belong to the Alisitos island arc. The Jurassic pluton intrudes a Triassic-Jurassic ophiolite.

Our study was designed to evaluate the palaeomagnetic homogeneity of the batholith from the Sierra San Pedro Mártir, at ~31°N, to about ~28.3°N. The Punta Prieta, Nuevo Rosarito, San Jerónimo, and La Rinconada plutons in the western zone of the PRB are characterized by magnetizations residing in magnetite. The Compostela pluton is emplaced in a transition zone and has a magnetization that resides in haematite. The five Cretaceous plutons yield a combined palaeopole at 80.3°N, 162.1°E, A₉₅ = 9.8°, N = 5 that after correcting for the opening of the Gulf of California rotates to 77.6°N, 173.6°E, the rotated pole being in angular distance of only 4.4° from the North America reference pole. The Jurassic San Roque pluton yields a mean 0.6°N, 306.1°E, A₉₅ = 9.2°, N = 10, which is discordant, showing a clockwise rotation of about 131° ± 16° and flattening of 9.5° ± 12.9° with respect to the 150 Ma cratonic reference palaeopole. The results suggest that the intrusion of the undeformed Cretaceous Punta Prieta to Compostela plutons (128.1 ± 1.4 and 100.5 ± 2.7 Ma, respectively) restricts tectonic accretion of the Jurassic-Early Cretaceous sequences to the North America margin to the time before mid-Cretaceous magmatism (~100 Ma) in the PRB near present latitude 28°N. Mesozoic and Cenozoic strike-slip faulting along the Vizcaíno margin can account for the 131° clockwise rotation of the San Roque pluton. Our results do not support significant latitudinal movement between Vizcaíno, the PRB, and mainland Mexico with the exception of the Neogene San Andreas Fault-related right lateral movement.     

Paleomagnetism of the Middle–Late Jurassic to Cretaceous red beds from the Peninsular Thailand: Implications for collision tectonics

Jurassic to Cretaceous red sandstones were sampled at 33 sites from the Khlong Min and Lam Thap formations of the Trang Syncline (7.6°N, 99.6°E), the Peninsular Thailand. Rock magnetic experiments generally revealed hematite as a carrier of natural remanent magnetization. Stepwise thermal demagnetization isolates remanent components with unblocking temperatures of 620–690 °C. An easterly deflected declination (D = 31.1°, I = 12.2°, α₉₅ = 13.9°, N = 9, in stratigraphic coordinates) is observed as pre-folding remanent magnetization from North Trang Syncline, whereas westerly deflected declination (D = 342.8°, I = 22.3°, α₉₅ = 12.7°, N = 13 in geographic coordinates) appears in the post-folding remanent magnetization from West Trang Syncline. These observations suggest an occurrence of two opposite tectonic rotations in the Trang area, which as a part of Thai–Malay Peninsula received clockwise rotation after Jurassic together with Shan-Thai and Indochina blocks. Between the Late Cretaceous and Middle Miocene, this area as a part of southern Sundaland Block experienced up to 24.5° ± 11.5° counter-clockwise rotation with respect to South China Block. This post-Cretaceous tectonic rotation in Trang area is considered as a part of large scale counter-clockwise rotation experienced by the southern Sundaland Block (including the Peninsular Malaysia, Borneo and south Sulawesi areas) as a result of Australian Plate collision with southeast Asia. Within the framework of Sundaland Block, the northern boundary of counter-clockwise rotated zone lies between the Trang area and the Khorat Basin.     

P-T evolution of metapelites from the Bajgan complex in the Makran accretionary prism,south eastern Iran

The Bajgan Complex, one of the basement constituents of the arc massif in Iranian Makran forms a rugged, deeply incised terrain. The complex consists of pelitic schists with minor psammitic and basic schists, calc silicate rocks, amphibolites, marbles, metavolcanosediments, mafic and felsic intrusives as well as ultramafic rocks. Metapelitic rocks show an amphibolite facies regional metamorphism and contain garnet, biotite, white mica, quartz, albite ± rutile ± apatite. Thermobarometry of garnet schist yields pressure of more than 9 kbar and temperatures between 560 and 675 °C. The geothermal gradient obtained for the peak of regional metamorphism is 19 °C/km, corresponding to a depth of ca. 31 km. Replacement of garnet by chlorite and epidote suggest greenschist facies metamorphism due to a decrease in temperature and pressure through exhumation and retrograde metamorphism (370–450 °C and 3–6 kbar). The metapelitic rocks followed a ‘clockwise’ P–T path during metamorphism, consistent with thermal decline following tectonic thickening. The formation of medium-pressure metamorphic rocks is related to presence of active subduction of the Neotethys Oceanic lithosphere beneath Eurasia in the Makran.     

Implications of subduction and subduction zone migration of the Paleo-Pacific Plate beneath eastern North China,based on distribution,geochronology, and geochemistry of Late Mesozoic volcanic rocks

Several major volcanic zones are distributed across the eastern North China Craton, from northwest to southeast: the Greater Xing’an Range, Jibei-Liaoxi, Xishan, and Songliao Basins, and the Yanji, Huanghua, and Ludong volcanic zones. The Huanghua depression within the Bohai Bay Basin was filled by middle Late Mesozoic volcanic rocks and abundant Cenozoic alkaline basalts. Zircon LA-ICP-MS and SHRIMP U–Pb dating show that basic–intermediate volcanic rocks were extruded in the Early Cretaceous of 118.8 ± 1.0 Ma (weighted mean ²⁰⁶Pb/²³⁸U age), before Late Cretaceous acid lavas at 71.5 ± 2.6 Ma. An inherited zircon from andesite has a Paleoprotoerozoic core crystallization age of 2,424 ± 22 Ma (²⁰⁶Pb/²⁰⁷Pb age) indicating that the basement of the Bohai Bay Basin is part of the North China Craton. Early Cretaceous basic and intermediate lavas are characterized by strong enrichments in LREE and LILE and depletions in HREE and HFSE, indicating a volcanic arc origin related to oceanic subduction. Depletion in Zr only occurs in basic and intermediate volcanic rocks, while depletions in Sr and Ti exist only in acid samples, indicating that the acid series is not genetically related to the basic–intermediate series. Formation ages and geochemical features indicate that the Late Cretaceous acid lavas are products of crustal remelting in an extensional regime. Combined information from all these volcanic zones shows that subduction-related volcanic rocks were generated in the Jibei-Liaoxi and Xishan volcanic zones during the Early Jurassic, about 60 Ma earlier than their analogues extruded in the Huanghua and Ludong volcanic zones during the Early Cretaceous. This younging trend also exists in the youngest extension-related volcanism in each of these zones: Early Cretaceous asthenosphere-derived alkaline basalts in the northwest and Late Cretaceous in the southeast. A tectonic model of northwestward subduction and continuous oceanward retreat of the Paleo-Pacific Plate is proposed to explain the migration pattern of both arc-related and post-subduction extension-related volcanic rocks. As the subduction zone continuously migrated, active continental margin and backarc regimes successively played their roles in different parts of North China during the Late Mesozoic (J₁–K₂).     

Paleomagnetism of Peninsular Malaysia

Paleomagnetic results from Upper Jurassic to Paleocene rocks in Peninsular Malaysia show counter clockwise (CCW) rotations, while clockwise rotations (CW) are predominantly found in older rocks. Continental redbeds of the Upper Jurassic to Lower Cretaceous Tembeling Group have a post folding remagnetization, giving a VGP at N54°E29°, corresponding to approximately 40° of CCW rotation relative to Eurasia and 60° CCW relative to the Indochina block (Khorat Plateau). Samples from Cretaceous to Paleocene mafic volcanics of the Kuantan dike swarm and the Segamat basalts give VGPs at N59°E47° and N34°E36°, respectively. These Malayasian data are indistinguishable from the Late Eocene and Oligocene VGPs reported for Borneo and the Celebes Sea and are similar to the Eocene VGPs reported for southwest Sulawesi and southwest Palawan. The occurrence of CCW deflected data over this large region suggests that much of Malaysia, Borneo, Sulawesi, and the Celebes Sea rotated approximately 30° to 40° CCW relative to the Geocentric Axial Dipole (GAD) between the Late Eocene and the Late Miocene, although not necessarily synchronously, nor as a single rigid plate. These regional CCW rotations are not consistent with simple extrusion based tectonic models. CW declinations have been measured in Late Triassic granites, Permian to Triassic volcanics, and remagnetized Paleozoic carbonates. The age of this magnetization is poorly understood and may be as old as Late Triassic, or as young as Middle or Late Cretaceous. The plate, or block rotations, giving rise to these directions are correspondingly weakly constrained.     

Equatorial electrojet in the south Atlantic anomaly region

Features of the equatorial electrojet are studied at Sao Luiz (2.6°S, 44.2°W, inclination −0.25°) in eastern Brazil and Sikasso (11.3°N, 5.7°W, inclination 0.1°) in the western African sector. The stations are situated on either side of the lowest magnetic field intensity in the region of rapid changes in the declination. The daily variations of ΔX at the two stations are almost similar with the peak around noon with maximum values during equinoxes and minimum values during J-solstices. Daily variations of ΔY differ with the maximum deviation of about −35 nT around noon at Sao Luiz and much smaller value of about −10 nT around 14 h LT for Sikasso. The direction of the H vector varies from 15°W of north at 08 h to more than 30°W of north at 17 h for Sao Luiz and from 14°E of north to 25°W of north at 18 h for Sikasso. The plot of the deviations in ΔX and ΔY at different hours for the two stations shows the points along narrow ellipses with major axis aligned along 22°W of north for Sao Luiz and along 3°W of north for Sikasso as compared to declination of 20°W for Sao Luiz and 6°W for Sikasso. The deviations in ΔX at the two stations are fairly well correlated.     

Thermodynamics of the kaolinite-group minerals

The enthalpies of formation of kaolinite and dickite were determined by high-temperature melt solution calorimetry to be ΔfH°(298.15 K) = −4118 ± 10 and −4127 ±10 kJ/mol, respectively. These data represent the first calorimetric confirmation of the metastability of kaolinite with respect to dickite.     

Tectonic evaluation of the Indochina Block during Jurassic-Cretaceous from palaeomagnetic results of Mesozoic redbeds in central and southern Lao PDR

Rock magnetic and palaeomagnetic studies were performed on Mesozoic redbeds collected from the central and southern Laos, the northeastern and the eastern parts of the Khorat Plateau on the Indochina Block. Totally 606 samples from 56 sites were sampled and standard palaeomagnetic experiments were made on them. Positive fold tests are demonstrated for redbeds of Lower and Upper Cretaceous, while insignificant fold test is resulted for Lower Jurassic redbeds. The remanence carrying minerals defined from thermomagnetic measurement, AF and Thermal demagnetizations and back-field IRM measurements are both magnetite and hematite. The positive fold test argues that the remanent magnetization of magnetite or titanomagnetite and hematite in the redbeds is the primary and occurred before folding. The mean palaeomagnetic poles for Lower Jurassic, Lower Cretaceous, and Upper Cretaceous are defined at Plat./Plon. = 56.0°N/178.5°E (A₉₅ = 2.6°), 63. 3°N/170.2°E (A₉₅ = 6.9°), and 67.0°N/180.8°E (A₉₅ = 4.9°), respectively. Our palaeomagnetic results indicate a latitudinal translations (clockwise rotations) of the Indochina Block with respect to the South China Block of −10.8 ± 8.8° (16.4 ± 9.0°); −11.1 ± 6.2° (17.8 ± 6.8°); and −5.3 ± 4.7° (13.3 ± 5.0°), for Lower Jurassic, Lower Cretaceous, and Upper Cretaceous, respectively. These results indicate a latitudinal movement of the Indochina Block of about 5–11° (translation of about 750–1700 km in the southeastward direction along the Red River Fault) and clockwise rotation of 13–18° with respect to the South China Block. The estimated palaeoposition of the Khorat Plateau at ca. 21–26°N during Jurassic to Cretaceous argues for a close relation to the Sichuan Basin in the southwest of South China Block. These results confirm that the central part of the Indochina Block has acted like a rigid plate since Jurassic time and the results also support an earlier extrusion model for Indochina.     

Petrogenesis of the Neogene volcanic units in the NE–SW-trending basins in western Anatolia,Turkey

The western Anatolian volcanic province formed during Eocene to Recent times is one of the major volcanic belts in the Aegean–western Anatolian region. We present new chemical (whole-rock major and trace elements, and Sr, Nd, Pb and O isotopes) and new Ar/Ar age data from the Miocene volcanic rocks in the NE–SW-trending Neogene basins that formed on the northern part of the Menderes Massif during its exhumation as a core complex. The early-middle Miocene volcanic rocks are classified as high-K calc-alkaline (HKVR), shoshonitic (SHVR) and ultrapotassic (UKVR), with the Late Miocene basalts being transitional between the early-middle Miocene volcanics and the Na-alkaline Quaternary Kula volcanics (QKV). The early-middle Miocene volcanic rocks are strongly enriched in large ion lithophile elements (LILE), have high ⁸⁷Sr/⁸⁶Sr_(i) (0.70631–0.71001), low ¹⁴³Nd/¹⁴⁴Nd_(i) (0.512145–0.512488) and high Pb isotope ratios (²⁰⁶Pb/²⁰⁴Pb = 18.838–19.148; ²⁰⁷Pb/²⁰⁴Pb = 15.672–15.725; ²⁰⁸Pb/²⁰⁴Pb = 38.904–39.172). The high field strength element (HFSE) ratios of the most primitive early-middle Miocene volcanic rocks indicate that they were derived from a mantle source with a primitive mantle (PM)-like composition. The HFSE ratios of the late Miocene basalts and QKV, on the other hand, indicate an OIB-like mantle origin—a hypothesis that is supported by their trace element patterns and isotopic compositions. The HFSE ratios of the early-middle Miocene volcanic rocks also indicate that their mantle source was distinct from those of the Eocene volcanic rocks located further north, and of the other volcanic provinces in the region. The mantle source of the SHVR and UKVR was influenced by (1) trace element and isotopic enrichment by subduction-related metasomatic events and (2) trace element enrichment by “multi-stage melting and melt percolation” processes in the lithospheric mantle. The contemporaneous SHVR and UKVR show little effect of upper crustal contamination. Trace element ratios of the HKVR indicate that they were derived mainly from lower continental crustal melts which then mixed with mantle-derived lavas (~20–40%). The HKVR then underwent differentiation from andesites to rhyolites via nearly pure fractional crystallization processes in the upper crust, such that have undergone a two-stage petrogenetic evolution.     

Combined paleomagnetic and geochronological study on Cretaceous strata of the Qiangtang terrane,central Tibet

A combined paleomagnetic and geochronological investigation has been performed on Cretaceous rocks in southern Qiangtang terrane (32.5°N, 84.3°E), near Gerze, central Tibetan Plateau. A total of 14 sites of volcanic rocks and 22 sites of red beds have been sampled. Our new U–Pb geochronologic study of zircons dates the volcanic rocks at 103.8 ± 0.46 Ma (Early Cretaceous) while the red beds belong to the Late Cretaceous. Rock magnetic experiments suggest that magnetite and hematite are the main magnetic carriers. After removing a low temperature component of viscous magnetic remanence, stable characteristic remanent magnetization (ChRM) was isolated successfully from all the sites by stepwise thermal demagnetization. The tilt-corrected mean direction from the 14 lava sites is D = 348.0°, I = 47.3°, k = 51.0, α₉₅ = 5.6°, corresponding to a paleopole at 79.3°N, 339.8°E, A₉₅ = 5.7° and yielding a paleolatitude of 29.3° ± 5.7°N for the study area. The ChRM directions isolated from the volcanic rocks pass a fold test at 95% confidence, suggesting a primary origin. The volcanic data appear to have effectively averaged out secular variation as indicated by both geological evidence and results from analyzing the virtual geomagnetic pole (VGP) scatter. The mean inclination from the Late Cretaceous red beds, however, is 13.1° shallower than that of the ~ 100 Ma volcanic rocks. After performing an elongation/inclination analysis on 174 samples of the red beds, a mean inclination of 47.9° with 95% confidence limits between 41.9° and 54.3° is obtained, which is consistent with the mean inclination of the volcanic rocks. The site-mean direction of the Late Cretaceous red beds after tilt-correction and inclination shallowing correction is D = 312.6°, I = 47.7°, k = 109.7, α₉₅ = 3.0°, N = 22 sites, corresponding to a paleopole at 49.2°N, 1.9°E, A₉₅ = 3.2° (yielding a paleolatitude of 28.7° ± 3.2°N for the study area). The ChRM of the red beds also passes a fold test at 99% confidence, indicating a primary origin. Comparing the paleolatitude of the Qiangtang terrane with the stable Asia, there is no significant difference between our sampling location in the southern Qiangtang terrane and the stable Asia during ~ 100 Ma and Late Cretaceous. Our results together with the high quality data previously published suggest that an ~ 550 km N–S convergence between the Qiangtang and Lhasa terranes happened after ~ 100 Ma. Comparison of the mean directions with expected directions from the stable Asia indicates that the Gerze area had experienced a significant counterclockwise rotation after ~ 100 Ma, which is most likely caused by the India–Asia collision.