On the Bur Gheluai H5 chondrite and other meteorites with complex exposure histories

Abstract— We present the ¹⁴C, ²⁶Al, ¹⁰Be, ³He, ⁴He, ²⁰Ne, ²¹Ne, ²²Ne, ³⁶Ar, ³⁸Ar, and ⁴⁰Ar concentrations and the track densities measured in up to 13 samples of the Bur Gheluai (H5) meteorite fall. Only a multi-stage exposure history can explain the data in a self-consistent way. Parameters for a model two-stage history obtained by simultaneous, least-squares fitting of the concentrations of ¹⁴C, ²⁶Al, ¹⁰Be, and ²¹Ne were: first stage duration ～10 Ma and radius >2 m; second stage duration ～0.6 Ma and radius 40–100 cm. Nominal one-stage ²¹Ne production rates (P₂₁) inferred from ²⁶Al in Bur Gheluai samples exceed those inferred from ¹⁰Be as expected for a meteorite with a complex history. Nonetheless, data for other meteorites indicate that multi-stage irradiations alone do not account for all the high reported values of P₂₁ based on ²⁶A***l: The equations describing the production of cosmogenic nuclides show that uncorrected shielding effects may also play a role. A compilation of ordinary, solar-gas-poor chondrites for which two-stage histories have been proposed includes many with short second stages but none with unambiguously long first stages (>0.2 Ga).     

The production of cosmogenic nuclides in stony meteoroids by galactic cosmic‐ray particles

Abstract— We present a purely physical model for the calculation of depth‐ and size‐dependent production rates of cosmogenic nuclides by galactic cosmic‐ray (GCR) particles. besides the spectra of primary and secondary particles and the excitation functions of the underlying nuclear reactions, the model is based on only one free parameter—the integral number of gcr particles in the meteoroid orbits. We derived this value from analysis of radionuclide data in Knyahinya. We also show that the mean GCR proton spectrum in the meteoroid orbits has been constant over about the last 10 Ma. For the major target elements in stony meteoroids, we present depth‐ and size‐dependent production rates for ¹⁰Be, ¹⁴C, ²⁶Al, ³⁶Cl, and ⁵³Mn as well as for the rare gas isotopes ³He, ²⁰Ne, ²¹Ne, ²²Ne, ³⁶Ar, and ³⁸Ar. The new data differ from semi‐empirical estimates by up to a factor of 4 but agree within ～20% with results obtained by earlier parametric or physical approaches. The depth and size dependence of the shielding parameter ²²Ne/²¹Ne and the correlations ²⁶Al vs. ¹⁰Be, ²⁶Al vs. ⁵³Mn, ¹⁰Be/²¹Ne vs. ²²Ne/²¹Ne, and ³⁶Ar vs. ³⁶Cl for deciphering preatmospheric sizes, shielding depths, terrestrial residence times, and exposure histories are also discussed.     

The complex exposure history of the Jiddat al Harasis 073 L‐chondrite shower

Abstract— We measured the concentrations and isotopic compositions of He, Ne, and Ar in 29 bulk samples from 11 different strewn field fragments of the large Jiddat al Harasis (JaH) 073 L6 chondrite shower, including 7 samples from known locations within the main mass. In addition, we measured the concentrations of cosmogenic ¹⁰Be, ²⁶Al, ³⁶Cl, and ⁴¹Ca in 10 samples. All fragments of this shower are characterized by low ¹⁰Be concentrations (7.6–12.8 dpm/kg), high ²⁶Al/¹⁰Be ratios (3.5‐5), large contributions of neutron capture ⁴¹Ca (200–1800 dpm/kgCa), low ³He/²¹Ne ratios (1.5‐3.0), large variations in cosmogenic ²¹Ne (1.2–12) × 10^?8cm³STP/g, and significant contributions of neutron‐capture ³⁶Ar. Stepwise heating experiments show that neutron‐capture produced ³⁶Ar is predominantly released between 1000–1200 °C. All these results are consistent with a first‐stage exposure of ?65 Ma within ?20 cm of the surface of the L‐chondrite parent body, followed by ejection of a 1.5‐2 m large object, which was then delivered to Earth within about 0.5 and 0.7 Ma. The cosmogenic nuclide data in JaH 073 thus corroborate the trend that many of the large chondrites studied so far experienced a complex exposure history. The observed ³He/²¹Ne ratios of 2.5‐3.0 in the most shielded samples (including those of the main mass) are lower than predicted by model calculations, but similar to the lowest values found in the large Gold Basin L‐chondrite shower. The Bern plot, which gives a linear correlation for ³He/²¹Ne versus ²²Ne/²¹Ne, is evidently not valid for very high shielding. Some of our measured ²²Ne/²¹Ne ratios in JaH 073 are lower than 1.06, which is not well understood, but might be explained by loss of cosmogenic neon from shocked sodium‐rich plagioclase during terrestrial weathering. The amount of trapped atmospheric argon in the JaH 073 fragments varies by almost two orders of magnitude and shows only a weak correlation with the size of the fragments, which range from <100 g to >50 kg. Finally, low concentrations of radiogenic ⁴He and ⁴⁰Ar indicate incomplete degassing < 1 Ga ago, probably at the main collision event on the L‐chondrite parent body ?480 Ma ago.     

On the production of cosmogenic nuclides in meteoroids by galactic protons

Abstract— A purely physical model is presented describing the depth- and size-dependence of the production of cosmogenic nuclides in meteoroids with radii up to 85 cm and in planetary surfaces by galactic cosmic ray protons. The model is based on Monte Carlo calculations of the intra- and internuclear cascades, by which depth- and size-dependent spectra of primary and secondary protons and of secondary neutrons are derived, and on experimental and theoretical thin-target cross sections of the underlying nuclear reactions. Model calculations are presented for production rates of ⁵³Mn, ²⁶Al, ²²Ne, and ²¹Ne in H- and L-chondrites and of ⁵³Mn and ²⁶Al in lunar surface material and compared with experimental data. From the analysis of ⁵³Mn and ²⁶Al in the Apollo 15 lunar drill core and in the L-chondrite Knyahinya GCR p-spectra and integral particle fluxes at 1 A.U. and in the meteoroid orbits averaged over the last 10 Ma are derived. An analysis of experimental depth profiles in four H- and L-chondrites demonstrates, that the new model is well capable of describing depth- and size-dependences of production rates of cosmogenic nuclides. Moreover, it is possible to determine exposure ages for these meteorites on the basis of the theoretical ²¹Ne production rates. The model calculations further explain the depth- and size-dependence of ²²Ne/²¹Ne-ratios and the dependences on these ratios of ²¹Ne, ²⁶Al and ⁵³Mn production rates. The future requirements for model calculations of cosmogenic nuclide production rates in extraterrestrial matter are outlined.     

Exposure history of the Mocs (L6) chondrite: A study of strewn field samples

Abstract— We measured cosmogenic radionuclides (¹⁰Be, ²⁶Al, and ³⁶Cl) and noble gases (He, Ne, and Ar) in 10 specimens of the Mocs L6 chondrite to determine the exposure history and preatmospheric relationship among fragments from known locations in the strewn field. Cosmogenic noble gas contents alone are consistent with a simple irradiation exposure of 15.2 Ma. However, Mocs has very low ²²Ne/²¹Ne ratios indicative of deep burial in a large meteoroid, but radionuclide levels at saturation values typical for much smaller meteoroids: this paradox suggests a possible complex exposure. For the latter case, we propose a two‐stage exposure history in which Mocs initially was deeply buried in a large object for 110 Ma, followed by exposure in a 65 cm object for 10.5 Ma. Relative shielding was inferred from the measured ²²Ne/²¹Ne ratios assuming constant ²²Ne/²¹Ne production for all samples during the first stage. These shielding levels, which are supported by estimates based on ³⁶Cl production by neutron capture, indicate a possible relationship between depth of samples in the Mocs meteoroid and fall location in the strewn field.     

Exposure history of the St‐Robert (H5) fall

Abstract— The compositionally typical H5 chondrite St‐Robert has an exposure age, 7.8 Ma, indistinguishable from that of the main cluster of H chondrites. Small values of the cosmogenic ²²Ne/²¹Ne ratio in interior samples imply a pre‐atmospheric radius on the order of 40 cm. Sample depths based on tracks and the production rates of Bhattacharya et al. (1973) range from 6 to ～40 cm and are generally larger than depths estimated from published ⁶⁰Co activities, perhaps because the track production rates adopted are too high. Depth profiles of the production rates of ¹⁴C, ³⁶Cl, ²⁶Al, ¹⁰Be, and ²¹Ne in stony material show increases with depth and reach levels 5% to 15% higher than expected from modeling calculations. The maximum concentrations in St‐Robert are, however, generally comparable to those measured for the L5 chondrite, Knyahinya, whose pre‐atmospheric radius of ～45 cm is thought to lead to the maximum possible production rates in chondrites. We infer that the pre‐atmospheric radius of St‐Robert was within 5 cm of the value that supports maximum production rates (i.e., 45 ± 5 cm). This radius corresponds to a pre‐atmospheric mass of (1.3 ± 0.4) × 10³ kg. The agreement of exposure ages for St‐Robert obtained in several different ways and the similarity of the depth profiles for ¹⁴C, ²⁶Al, ¹⁰Be, and ²¹Ne argue against a lengthy pre‐exposure of St‐Robert on the parent body and against a two‐stage exposure after launch from the parent body. Following Morbidelli and Gladman (1998), we suggest that St‐Robert was chipped from deep in its parent body, spent the next 7–8 Ma without undergoing a major collision, was nudged gradually into an orbital resonance with Jupiter, and then traveled quickly to Earth.     

Allan Hills 88019: An Antarctic H-chondrite with a very long terrestrial age

Abstract— We have measured the concentrations of the cosmogenic radionuclides ¹⁰Be, ²⁶Al and ³⁶Cl (half-lives 1.51 Ma, 716 ka, and 300 ka, respectively) in two different laboratories by accelerator mass spectrometry (AMS) techniques, as well as concentrations and isotopic compositions of stable He, Ne and Ar in the Antarctic H-chondrite Allan Hills (ALH) 88019. In addition, nuclear track densities were measured. From these results, it is concluded that the meteoroid ALH 88019 had a preatmospheric radius of (20 ± 5) cm and a shielding depth for the analyzed samples of between 4 and 8 cm. Using calculated and experimentally determined production rates of cosmogenic nuclides, an exposure age of ～40 Ma is obtained from cosmogenic ²¹Ne and ³⁸Ar. The extremely low concentrations of radionuclides are explained by a very long terrestrial age for this meteorite of 2 ± 0.4 Ma. A similarly long terrestrial age was found so far only for the Antarctic L-chondrite Lewis Cliff (LEW) 86360. Such long ages establish one boundary condition for the history of meteorites in Antarctica.     

Calibration of cosmogenic noble gas production in ordinary chondrites based on 36Cl‐36Ar ages. Part 1: Refined produced rates for cosmogenic 21Ne and 38Ar

We measured the concentrations and isotopic compositions of He, Ne, and Ar in bulk samples and metal separates of 14 ordinary chondrite falls with long exposure ages and high metamorphic grades. In addition, we measured concentrations of the cosmogenic radionuclides ¹⁰Be, ²⁶Al, and ³⁶Cl in metal separates and in the nonmagnetic fractions of the selected meteorites. Using cosmogenic ³⁶Cl and ³⁶Ar measured in the metal separates, we determined ³⁶Cl‐³⁶Ar cosmic‐ray exposure (CRE) ages, which are shielding‐independent and therefore particularly reliable. Using the cosmogenic noble gases and radionuclides, we are able to decipher the CRE history for the studied objects. Based on the correlation ³He/²¹Ne versus ²²Ne/²¹Ne, we demonstrate that, among the meteorites studied, only one suffered significant diffusive losses (about 35%). The data confirm that the linear correlation ³He/²¹Ne versus ²²Ne/²¹Ne breaks down at high shielding. Using ³⁶Cl‐³⁶Ar exposure ages and measured noble gas concentrations, we determine ²¹Ne and ³⁸Ar production rates as a function of ²²Ne/²¹Ne. The new data agree with recent model calculations for the relationship between ²¹Ne and ³⁸Ar production rates and the ²²Ne/²¹Ne ratio, which does not always provide unique shielding information. Based on the model calculations, we determine a new correlation line for ²¹Ne and ³⁸Ar production rates as a function of the shielding indicator ²²Ne/²¹Ne for H, L, and LL chondrites with preatmospheric radii less than about 65 cm. We also calculated the ¹⁰Be/²¹Ne and ²⁶Al/²¹Ne production rate ratios for the investigated samples, which show good agreement with recent model calculations.     

Light noble gases and cosmogenic radionuclides in Estherville,Budulan, and other mesosiderites: Implications for exposure histories and production rates

Abstract— We report measurements of ²⁶AI, ¹⁰Be, ⁴¹Ca, and ³⁶Cl in the silicate and metal phases of 11 mesosiderites, including several specimens each of Budulan and Estherville, of the brecciated meteorite Bencubbin, and of the iron meteorite Udei Station. Average production rate ratios (atom/atom) for metal phase samples from Estherville and Budulan are ²⁶Al/¹⁰Be = 0.77 ± 0.02; ³⁶Cl/¹⁰Be = 5.3 ± 0.2. For a larger set of meteorites that includes iron meteorites and other mesosiderites, we find ²⁶Al/¹⁰Be = 0.72 ± 0.01 and ³⁶Cl/¹⁰Be = 4.5 ± 0.2. The average ⁴¹Ca/³⁶Cl production rate ratio is 1.10 ± 0.04 for metal separates from Estherville and four small iron falls. The ⁴¹Ca activities in dpm/(kg Ca) of various silicate separates from Budulan and Estherville span nearly a factor of 4, from <400 to >1600, indicating preatmospheric radii of >30 cm. After allowance for composition, the activities of ²⁶Al and ¹⁰Be (dpm/kg silicate) are similar to values measured in most ordinary chondrites and appear to depend only weakly on bulk Fe content. Unless shielding effects are larger than suggested by the ³⁶Cl and ⁴¹Ca activities of the metal phases, matrix effects are unimportant for ¹⁰Be and minor for ²⁶Al. Noble gas concentrations and isotopic abundances are reported for samples of Barea, Emery, Mincy, Morristown, and Marjalahti. New estimates of ³⁶Cl/³⁶Ar exposure ages for the metal phases agree well with published values. Neon‐21 production rates for mesosiderite silicates calculated from these ages and from measured ²¹Ne contents are consistently higher than predicted for L chondrites despite the fact that the mesosiderite silicates have lower Mg contents than L chondrites. We suggest that the elevation of the ²¹Ne production rate in mesosiderite silicates reflects a “matrix effect,” that is, the influence of the higher Fe content of mesosiderites, which acts to enhance the flux of low‐energy secondary particles and hence the ²¹Ne production from Mg. As ¹⁰Be production is relatively insensitive to this matrix effect, ¹⁰Be/²¹Ne ages give erroneously low production rates and high exposure ages. By coincidence, standard ²²Ne/²¹Ne based “shielding” corrections give fairly reliable ²¹Ne production rates in the mesosiderite silicates.     

Exposure history of the Peekskill (H6) meteorite

Abstract— The Peekskill H6 meteorite fell on 1992 October 9. We report extensive measurements of cosmic-ray produced stable nuclides of He, Ne, and Ar, of the radionuclides ²²Na, ⁶⁰Co, ¹⁴C, ³⁶Cl, ²⁶Al, and ¹⁰Be, and of cosmic-ray track densities. After correction for shielding via the ²²Ne/²¹Ne ratio, the concentrations of cosmic-ray produced ³He, ²¹Ne and ³⁸Ar give an average exposure age of 25 Ma, which is considered to be a lower limit on the true value. The ¹⁰Be/²¹Ne age is 32 Ma and falls onto a peak in the H-chondrite exposure age distribution. The activities of ²⁶Al, ¹⁴C, ³⁶Cl, and ¹⁰Be are all close to the maximum values expected for H-chondrites. Together with cosmic-ray track densities and the ²²Ne/²¹Ne ratio, these radionuclide data place the samples at a depth >20 cm in a meteoroid with a radius >40 cm. In contrast, the ⁶⁰Co activity requires a near-surface location and/or a much smaller body. Calculations show that a flattened geometry for the Peekskill meteoroid does not explain the observations in the context of a one-stage irradiation. A two-stage model can account for the data. We estimate an upper bound of 70 cm on the radius of the earlier stage of irradiation and conclude that Peekskill's radius was <70 cm when it entered the Earth's atmosphere. This size limit is somewhat smaller than the dynamic determinations (Brown et al., 1994).     

Cosmogenic nuclides in the solar gas‐rich H3–6 chondrite breccia Frontier Mountain 90174

Abstract— We re‐evaluated the cosmic‐ray exposure history of the H3‐6 chondrite shower Frontier Mountain (FRO) 90174, which previously was reported to have a simple exposure history, an irradiation time of about 7 Ma, and a pre‐atmospheric radius of 80–100 cm (Welten et al. 2001). Here we measured the concentrations and isotopic compositions of He, Ne, and Ar in 8 aliquots of 6 additional fragments of this shower, and ¹⁰Be and ²⁶Al in the stone fractions of seven fragments. The radionuclide concentrations in the stone fractions, combined with those in the metal fractions, confirm that all samples are fragments of the FRO 90174 shower. Four of the fragments contain solarwind‐implanted noble gases with a solar ²⁰Ne/²²Ne ratio of ?12.0, indicating that FRO 90174 is a regolith breccia. The concentrations of solar gases and cosmogenic ²¹Ne in the samples analyzed by us and by Welten et al. (2001) overlap with those of the FRO H‐chondrites from the 1984 season, suggesting that many of these samples are also part of the large FRO 90174 chondrite shower. The cosmogenic ²¹Ne concentrations in FRO 90174 show no simple correlation with ¹⁰Be and ²⁶Al activities. We found ²¹Ne excesses between 0.3‐1.1 × 10^?8cm³STP/g in 6 of the 17 samples. Since excess ²¹Ne and trapped solar gases are not homogeneously distributed, i.e., we found in one fragment aliquots with and without excess ²¹Ne and solar ²⁰Ne, we conclude that excess ²¹Ne is due to GCR irradiation of the regolith before compaction of the FRO 90174 object. Therefore, the chondrite shower FRO 90174 did not simply experience an exposure history, but some material was already irradiated at the surface of an asteroid leading to excess ²¹Ne. This excess ²¹Ne is correlated to implanted solar gases, clearly indicating that both processes occurred on the regolith.     

Cosmic‐ray exposure history of two Frontier Mountain H‐chondrite showers from spallation and neutron‐capture products

Abstract— We measured the concentrations of ¹⁰Be, ²⁶Al, ³⁶Cl, ⁴¹Ca and ¹⁴C in the metal and/or stone fractions of 27 Antarctic chondrites from Frontier Mountain (FRO), including two large H‐chondrite showers. To estimate the pre‐atmospheric size of the two showers, we determined the contribution of neutron‐capture produced ³⁶Cl (half‐life = 3.01 times 10⁵ years) and ⁴¹Ca (1.04 times 10⁵ years) in the stone fraction. The measured activities of neutron‐capture ³⁶Cl and ⁴¹Ca, as well as spallation produced ¹⁰Be and ²⁶Al, were compared with Monte Carlo‐based model calculations. The largest shower, FRO 90174, includes eight fragments with an average terrestrial age of (100 ± 30) × 10³ years; the neutron‐capture saturation activities extend to 27 dpm/kg stone for ³⁶Cl and 19 dpm/kg stone for ⁴¹Ca. The concentrations of spallation produced ¹⁰Be, ²⁶Al and ³⁶Cl constrain the radius (R) to 80–100 cm, while the neutron‐capture ⁴¹Ca activities indicate that the samples originated from the outer 25 cm. With a pre‐atmospheric radius of 80–100 cm, FRO 90174 is among the largest of the Antarctic stony meteorites. The large pre‐atmospheric size supports our hypothesis that at least 50 of the ～150 classified H5/H6‐chondrites from the Frontier Mountain stranding area belong to this single fall; this hypothesis does not entirely account for the high H/L ratio at Frontier Mountain. The smaller shower, FRO 90001, includes four fragments with an average terrestrial age of (40 ± 10) × 10³ years; they contain small contributions of neutron‐capture ³⁶Cl, but no excess of ⁴¹Ca. FRO 90001 experienced a complex exposure history with high shielding conditions in the first stage (150 < R < 300 cm) and much lower shielding in the second stage (R < 30 cm), the latter starting ～1.0 million years (Ma) ago. Based on the measured ¹⁰Be/²¹Ne and ²⁶Al/²¹Ne ratios, the cosmic‐ray exposure ages of the two showers are 7.2 ± 0.5 Ma for FRO 90174 and 8 ± 1 Ma for FRO 90001. These ages coincide with the well‐established H‐chondrite peak and corroborate the observation that the exposure age distribution of FRO H‐chondrites is similar to that of non‐Antarctic falls. In addition, we found that corrections for neutron‐capture ³⁶Ar (from decay of ³⁶Cl) result in concordant ²¹Ne and ³⁸Ar exposure ages.     

The L3–6 chondritic regolith breccia Northwest Africa (NWA) 869: (II) Noble gases and cosmogenic radionuclides

Abstract– We measured cosmogenic radionuclides and noble gases in the L3–6 chondrite breccia Northwest Africa (NWA) 869, one of the largest meteorite finds from the Sahara. Concentrations of ¹⁰Be, ²⁶Al, and ³⁶Cl in stone and metal fractions of six fragments of NWA 869 indicate a preatmospheric radius of 2.0–2.5 m. The ¹⁴C and ¹⁰Be concentrations in three fragments yield a terrestrial age of 4.4 ± 0.7 kyr, whereas two fragments show evidence for a recent change in shielding, most likely due to a recent impact on the NWA meteoroid, approximately 10⁵ yr ago, that excavated material up to approximately 80 cm deep and exposed previously shielded material to higher cosmic‐ray fluxes. This scenario is supported by the low cosmogenic ³He/²¹Ne ratios in these two samples, indicating recent loss of cosmogenic ³He. Most NWA samples, except for clasts of petrologic type 4–6, contain significant amounts of solar Ne and Ar, but are virtually free of solar helium, judging from the trapped ⁴He/²⁰Ne ratio of approximately 7. Trapped planetary‐type Kr and Xe are most clearly present in the bulk and matrix samples, where abundances of ¹²⁹Xe from decay of now extinct ¹²⁹I are highest. Cosmogenic ²¹Ne varies between 0.55 and 1.92 × 10^?8 cm³ STP g^?1, with no apparent relationship between cosmogenic and solar Ne contents. Low cosmogenic (²²Ne/²¹Ne)_c ratios in solar gas free specimens are consistent with irradiation in a large body. Combined ¹⁰Be and ²¹Ne concentrations indicate that NWA 869 had a 4π cosmic‐ray exposure (CRE) age of 5 ± 1 Myr, whereas elevated ²¹Ne concentrations in several clasts and bulk samples indicate a previous CRE of 10–30 Myr on the parent body, most probably as individual components in a regolith. Unlike many other large chondrites, NWA 869 does not show clear evidence of CRE as a large boulder near the surface of its parent body. Radiogenic ⁴He concentrations in most NWA 869 samples indicate a major outgassing event approximately 2.8 Gyr ago that may have also resulted in loss of solar helium.     

Complex exposure histories for meteorites with “short” exposure ages

Abstract— We report measurements of ²⁶Al and ¹⁰Be activities in nine ordinary chondrites and of the light noble gas concentrations and ³⁶Cl and ⁴¹Ca activities in subsets of those meteorites. All but Murray have low ²¹Ne concentrations (<1.0 × 10^?8cm³STP/g) and have previously been used to estimate ²¹Ne production rates. Ladder Creek, Murchison, Sena, and Timochin have inventories of cosmogenic radionuclides that are compatible with a single stage of irradiation and give ²¹Ne production rates that are consistent with the standard L-chondrite value of 0.33 × 10^?8cm³STP/g/Ma. In contrast, Cullison, Guenie, Shaw, and Tsarev experienced complex irradiation histories. They and several other meteorites with low nominal exposure ages also have lower ³He/²¹Ne ratios than expected based on their ²²Ne/²¹Ne ratios. A general association between low ²¹Ne contents and ³He losses suggests that meteorites with short lifetimes often occupy orbits with small perihelia. However, meteorites with low ²¹Ne contents, one-stage exposure histories, and losses of cosmogenic ³He are rare. Possible explanations for the scarcity are (1) statistical, (2) that it is harder for more deeply buried protometeoroids to lose gas in a liberating collision, and (3) that it is harder to insert more deeply buried protometeoroids directly into orbits with small perihelia.     

Exposure history of separated phases from the Kapoeta meteorite

Abstract— The cosmogenic radionuclides, ¹⁰Be, ²⁶Al, ³⁶Cl, and ⁵³Mn were measured in selected clasts and matrix samples from the howardite Kapoeta. Previous measurements of cosmogenic ²¹Ne indicate higher cosmic‐ray exposure ages for bulk samples than for some separated clasts or mineral separates. A possible interpretation for this difference in apparent exposure ages is a complex recent exposure history for Kapoeta. In this scenario some constituents are exposed to cosmic rays in a 2π geometry as part of a larger body immediately preceding its 4π exposure in a smaller body. To test this scenario we measured cosmogenic radionuclides in several clasts from Kapoeta. These measurements are consistent with a simple single‐stage 4π exposure history during which the entire inventory of cosmogenic radionuclides was produced. Taken together, these data are most consistent with a single‐stage 4π exposure lasting ～3 Ma. This scenario is nevertheless consistent with models in which the exposure of some constituents of Kapoeta to energetic particles occurred at an earlier time, as is indicated by ²¹Ne measurements. However, from our data we conclude that insubstantial quantities of cosmogenic radionuclides were inherited from this earlier irradiation; this earlier exposure to energetic particles must have predated the recent exposure by at least ～10 Ma to allow for the decay of the long half‐life cosmogenic radionuclides.     

Exposure history and terrestrial ages of ordinary chondrites from the Dar al Gani region,Libya

Abstract— We measured the concentrations of noble gases in 32 ordinary chondrites from the Dar al Gani (DaG) region, Libya, as well as concentrations of the cosmogenic radionuclides ¹⁴C, ¹⁰Be, ²⁶Al, ³⁶Cl, and ⁴¹Ca in 18 of these samples. Although the trapped noble gases in five DaG samples show ratios typical of solar or planetary gases, in all other DaG samples, they are dominated by atmospheric contamination, which increases with the degree of weathering. Cosmic ray exposure (CRE) ages of DaG chondrites range from ?1 Myr to 53 Myr. The CRE age distribution of 10 DaG L chondrites shows a cluster around 40 Myr due to four members of a large L6 chondrite shower. The CRE age distribution of 19 DaG H chondrites shows only three ages coinciding with the main H chondrite peak at ?7 Myr, while seven ages are <5 Myr. Two of these H chondrites with short CRE ages (DaG 904 and 908) show evidence of a complex exposure history. Five of the H chondrites show evidence of high shielding conditions, including low ²²Ne/²¹Ne ratios and large contributions of neutron‐capture ³⁶Cl and ⁴¹Ca. These samples represent fragments of two or more large pre‐atmospheric objects, which supports the hypothesis that the high H/L chondrite ratio at DaG is due to one or more large unrecognized showers. The ¹⁴C concentrations correspond to terrestrial ages <35 kyr, similar to terrestrial ages of chondrites from other regions in the Sahara but younger than two DaG achondrites. Despite the loss of cosmogenic ³⁶Cl and ⁴¹Ca during oxidation of metal and troilite, concentrations of ³⁶Cl and ⁴¹Ca in the silicates are also consistent with ¹⁴C ages <35 kyr. The only exception is DaG 343 (H4), which has a ⁴¹Ca terrestrial age of 150 ± 40 kyr. This old age shows that not only iron meteorites and achondrites but also chondrites can survive the hot desert environment for more than 50 kyr. A possible explanation is that older meteorites were covered by soils during wetter periods and were recently exhumed by removal of these soils due to deflation during more arid periods, such as the current one, which started ?3000 years ago. Finally, based on the ²⁶Al/²¹Ne and ¹⁰Be/²¹Ne systematics in 16 DaG meteorites, we derived more reliable estimates of the ¹⁰Be/²¹Ne production rate ratio, which seems more sensitive to shielding than was predicted by the semi‐empirical model of Graf et al. (1990) but less sensitive than was predicted by the purely physical model of Leya et al. (2000).     

Energetic proton irradiation history of the howardite parent body regolith and implications for ancient solar activity

Abstract— Previous studies have shown that the Kapoeta howardite, as well as several other meteorites, contains excess concentrations of cosmogenic Ne in the darkened, solar-irradiated phase compared to the light, non-irradiated phase. The two explanations offered for the nuclear production of these Ne excesses in the parent body regolith are either from galactic cosmic-ray proton (GCR) irradiation or from a greatly enhanced flux of energetic solar “cosmic-ray” protons (SCR), as compared to the recent solar flux. Combining new isotopic data we obtained on acid-etched, separated feldspar from Kapoeta light and dark phases with literature data, we show that the cosmogenic ²¹Ne/²²Ne ratio of light phase feldspar (0.80) is consistent with only GCR irradiation in space for ～3 Ma. However, the ²¹Ne/²²Ne ratio (0.68) derived for irradiation of dark phase feldspar in the Kapoeta regolith indicates that cosmogenic Ne was produced in roughly equal proportions from galactic and solar protons. Considering a simple model of an immature Kapoeta parent body regolith, the duration of this early galactic exposure was only ～3–6 Ma, which would be an upper limit to the solar exposure time of individual grains. Concentrations of cosmogenic ²¹Ne in pyroxene separates and of cosmogenic ¹²⁶Xe in both feldspar and pyroxene are consistent with this interpretation. The near-surface irradiation time of individual grains in the Kapoeta regolith probably varied considerably due to regolith mixing to an average GCR irradiation depth of ～10 cm. Because of the very different depth scales for production of solar ～Fe tracks, SCR Ne, and GCR Ne, the actual regolith exposure times for average grains probably differed correspondingly. However, both the SCR ²¹Ne and solar track ages appear to be longer because of enhanced production by early solar activity. The SCR/GCR production ratio of ²¹Ne inferred from the Kapoeta data is larger by a at least a factor of 10 and possibly as much as a factor of ～50 compared to recent solar particle fluxes. Thus, this study indicates that our early Sun was much more active and emitted a substantially higher flux of energetic (>10 MeV/nucleon) protons.     

Noble gases in enstatite chondrites I: Exposure ages,pairing, and weathering effects

Abstract— Cosmic‐ray exposure ages calculated from cosmogenic noble gas nuclides are reported for 57 enstatite (E) chondrites, 43 of them were measured for the first time. With a total of 62 individual E chondrites (literature and this data, corrected for pairing) the observed spectrum of ages ranges between 0.07 and 66 Ma. Three clusters seem to develop at about 3.5, 8, and 25 Ma, respectively. Since the uncertainty of ages is estimated to be ～20% (in contrast to 10 to 15% for ordinary chondrites) and the number of examined samples is still comparatively small, these peaks have to be confirmed by more measurements. Regarding the two subgroups, EH and EL chondrites, no systematic trend is apparent in the distribution of cosmic‐ray exposure ages. Several E chondrites yield significantly lower ³⁸Ar ages compared to those calculated from cosmogenic ³He and ²¹Ne. For these E chondrites, we suggest a reduction of cosmogenic ³⁸Ar as a result of weathering. In order to prove the possible influence of terrestrial alteration on the cosmogenic noble gas record of E‐chondritic material, we simulated terrestrial weathering in an experiment of 12 weeks duration. The treatment showed that a significant amount of cosmogenic ³⁸Ar is lost on Earth by the influence of water.     

Cosmic‐ray exposure history of the Norton County enstatite achondrite

Abstract– We report measurements of cosmogenic nuclides in up to 11 bulk samples from various depths in Norton County. The activities of ³⁶Cl, ⁴¹Ca, ²⁶Al, and ¹⁰Be were measured by accelerator mass spectrometry; the concentrations of the stable isotopes of He, Ne, Ar, and Sm were measured by electron and thermal ionization mass spectrometry, respectively. Production rates for the nuclides were modeled using the LAHET and the Monte Carlo N‐Particle codes. Assuming a one‐stage irradiation of a meteoroid with a pre‐atmospheric radius of approximately 50 cm, the model satisfactorily reproduces the depth profiles of ¹⁰Be, ²⁶Al, and ⁵³Mn (<6%) but overestimates the ⁴¹Ca concentrations by about 20%. ³He, ²¹Ne, and ²⁶Al data give a one‐stage cosmic‐ray exposure (CRE) age of 115 Ma. Argon‐36 released at intermediate temperatures, ³⁶Ar_n, is attributed to production by thermal neutrons. From the values of ³⁶Ar_n, an assumed average Cl concentration of 4 ppm, and a CRE age of 115 Ma, we estimate thermal neutron fluences of 1–4 × 10¹⁶ neutrons cm^?2. We infer comparable values from ε¹⁴⁹Sm and ε¹⁵⁰Sm. Values calculated from ⁴¹Ca and a CRE age of 115 Ma, 0.2–1.4 × 10¹⁶ neutrons cm^?2, are lower by a factor of approximately 2.5, indicating that nearly half of the ¹⁴⁹Sm captures occurred earlier. One possible irradiation history places the center of proto‐Norton County at a depth of 88 cm in a large body for 140 Ma prior to its liberation as a meteoroid with a radius of 50 cm and further CRE for 100 Ma.     

Noble gases in ten Nullarbor chondrites: Exposure ages,terrestrial ages,and weathering effects

Abstract— We present concentration and isotopic composition of He, Ne, and Ar in ten chondrites from the Nullarbor region in Western Australia as well as the concentrations of ⁸⁴Ke, ¹²⁹Xe, and ¹³²Xe. From the measured cosmogenic ¹⁴C concentrations (Jull et al. 1995), shielding‐corrected production rates of ¹⁴C are deduced using cosmogenic ²²Ne/²¹Ne ratios. For shielding conditions characterized by ²²Ne/²¹Ne >1.10, this correction becomes significant and results in shorter terrestrial ages. The exposure ages of the ten Nullarbor chondrites are in the range of values usually observed in ordinary chondrites. Some of the meteorites have lost radiogenic gases as well as cosmogenic ³He. Most of the analyzed specimens show additional trapped Ar, Kr, and Xe of terrestrial origin. The incorporation of these gases into weathering products is common in chondrites from hot deserts.