Petrology of the Treknattan intrusion in the Fongen-Hyllingen complex, Trondheim region, Norway: a late intrusion into an evolved layered complex

The basic-ultrabasic Treknattan intrusion is an important example of a late intrusion in a solidified, evolved, layered complex and sheds light on possible mechanisms by which such associations may develop. The Treknattan intrusion, emplaced into the basic Fongen-Hyllingen intrusion shortly after the latter had solidified, consists mainly of massive or weakly layered peridotite (olivine ± Cr-spinel cumulate) and troctolite (plagioclase + olivine ± Cr-spinel cumulate). The mineral compositional range partially overlaps the most primitive end of the much larger variation-interval in the Fongen-Hyllingen intrusion. The margin of the Treknattan intrusion is sometimes outlined by massive feldspathic websterite which appears to have formed by reaction between magma and melts of gabbroic country rock. The parental magma appears to have been a relatively water-rich picritic basalt with a possible genetic relationship to the magma parental to the enveloping Fongen-Hyllingen intrusion, both displaying tholeiitic relationship between olivine and Ca-poor pyroxene, and having crystallized from relatively water-rich magmas with an early crystallization order of olivine ± Cr-spinel-plagioclase-Ca-rich pyroxene. The recognition of the Treknattan intrusion as a separate body suggests that the bulk composition of the Fongen-Hyllingen intrusion is dioritic rather than gabbroic as previously thought.     

On the origin of microrhythmic layering in arfvedsonite lujavrite from the Ilímaussaq alkaline complex, South Greenland

Microrhythmic layering is locally developed in agpaitic arfvedsonite lujavrite from the Ilímaussaq alkaline complex, South Greenland. Three–15-cm-thick laminated dark layers alternate with 1–10-cm-thick, light-coloured granular urtitic layers. Dark layers are uniform (isomodal) but the urtitic layers are enriched in early nepheline and eudialyte in their lower parts and in late analcime and REE phosphate minerals in the upper parts. The layers are separated by sharp contacts; they are draped around rafts from the overlying roof zone and lack structures indicative of current processes or post-cumulus deformation. Compared with the background arfvedsonite lujavrite of the complex, the dark layers are richer in sodalite, microcline and arfvedsonite and poorer in analcime and eudialyte. They have higher K₂O, Cl, FeO and S but lower Na₂O, H₂O⁺, Zr and P contents, the opposite of the light-coloured layers. The complementary chemistry of the two types of layers oscillates about the composition of the background arfvedsonite lujavrite. Layers probably formed in a stagnant bottom layer of the lujavrite magma chamber. Each layer started as a liquid layer which exchanged components with the underlying crystallization front. On cooling, it crystallized primocrysts and exchanged components with the overlying magma which became a new, complementary liquid layer and, during further cooling and burial within the sequence of layers, it underwent largely closed-system interstitial crystallization. Exhaustion of Cl and a sharp decrease in a_NaCl relative to a_H2O terminated the crystallization of a sodalite-rich dark layer and initiated abundant crystallization of nepheline in the overlying liquid layer (urtitic layer). The layered sequence represents a local K₂O-, Cl-rich but Na₂O-, H₂O-poor facies of arfvedsonite lujavrite and may have formed by exchanging components with sodalite-bearing rafts from the roof zone.     

含铁地下水成因、危害及防治

含铁地下水形成于中偏酸性的还原性水文地球化学环境中,人为活动也可引发含铁水的出现。含铁水进入水井附近后,有沉淀析出铁矿物从而堵塞水井附近含水层和滤水管的危险,也因为其偏低的ＰＨ值和可能含有硫化物而对金属水井管材具有腐蚀作用。防治含铁水对水井破坏作用的根本方法是采取改善地下水水质的现场处理技术。     

Structure of the larvikite-lardalite complex,Oslo-region,Norway, and its evolution

Structures not previously described from the southern part of the Permian rift-system in the Oslo-district, Norway, are presented. These indicate that the larvikite massif is a ring complex consisting of numerous individual sections which are roughly circular and repeatedly cut each other in a manner that suggests sequential shifting of centres of igneous activity towards the west. The compositions of these sections vary from quartzbearing varieties in the earliest parts through intermediate types to larvikite and lardalite with excess nepheline in the youngest parts.As this complex covers almost the total width of the Oslo rift-system, it forms an important profile across the graben structure. It suggests unilateral westward migration of centres of igneous activity in this region, viewed either as magma injection or cauldron subsidence and therefore provides additional information regarding the origin and evolution of the Oslo paleo-rift system.

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Zusammenfassung Die Arbeit behandelt bisher nicht beschriebene Strukturen im südlichen Teil des permischen Bruchsenkungsgebietes im Oslogebiet in Norwegen. Sie zeigen, daß das Larvikit-Massiv einen ringförmigen Komplex bildet aus zahlreichen, ungefähr zirkulären und untereinander diskordanten Teilbereichen. Die Lage der Diskordanzen erlaubt die Annahme, einer westlich gerichteten sukzessiven Verlagerung der Zentren magmatischer Aktivität. Mit abnehmendem Alter dieser Teilbereiche verändert sich deren Mineralbestand von quartzführend über intermediär hin zur larvikitischen und lardalitischen Zusammensetzung mit Nephelinüberschuß.Da dieser Komplex fast den gesamten Bereich des Osloer Bruchsenkungsgebietes deckt, stellt er ein wichtiges Profil durch die Grabenstruktur dar. Dieses läßt plausibel erscheinen, daß die Zentren der magmatischen Vorgänge der Gegend einem einheitlich westgerichteten Trend gefolgt sind gleichviel, ob man in ihnen großräumige Vorgänge ringförmiger Magmen-intrusion sieht oder zylindrische Kesselbrüche (Cauldrons). Die in der Arbeit dargelegten Ergebnisse sind somit geeignet, die Frage des Ursprungs und der Entwicklung des Osloer Bruchsenkungsgebietes weiter zu erhellen.

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Résumé Une nouvelle analyse structurale de massif de larvikite au sud du rift permien d'Oslo, Norvège, montre que ce massif forme un complexe annulaire comprenant de nombreuses composantes à peu pres circulaires et discordantes entre elles. Les segments se recoupent successivement indiquant un déplacement des centres d'activité magmatique vers l'ouest. Les larvikites passent de types à composition acide avec quartz dans les premiers segments, à des types intermédiaires puis a des compositions sousatourée avec néphéline en excess dans les segments les plus jeunes.Comme le massif occupe presque toute la largeur du rift d'Oslo il constitue une coupe importante de cette fosse paléozoique. Sa structure suggère une migration continue vers l'ouest des centres d'activité volcanique pour autant qu'on y voie des intrusions annulaires de magma, ou des effondrements successifs de la caldeira. Ce résultat apporte une information nouvelle sur l'origine et l'évolution du rift permien d'Oslo au sud de la Norvège.

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Raft-like Metabasaltic Inclusions in the Fongen-Hyllingen Layered Intrusive Complex, Norway, and their Implications for Magma Chamber Evolution

The Hyllingen Series comprises the southern part of the Caledoniansynorogenic Fongen- Hyllingen layered mafic intrusion, whichoccupies an area of 160 km², southeast of Trondheim, Norway.Large, raft-like inclusions form an important part of the HyllingenScries. Most of these are of fine-grained, equigranular rocksof basaltic composition with lithologies matching those of theadjacent country rocks. The rafts, which compose up to 22% ofthe lower part of the Hyllingen Series, are broadly concordantwith modal layering in the host gabbroic rocks. Individual bodiescan be up to 1500 m long and over 100 m thick. Some of the raftsare branching, and appear locally to form a threedimensionalnetwork. Impact structures are associated with small metabasicinclusions but not with the large rafts. The Hyllingen magma chamber is believed to have developed asa southerly expanding, thin wedge, forming the upper part ofthe Fongen chamber. The magma was compositionally zoned andcrystallized along the inclined floor of the wedge-shaped chamber.The wedge expanded as a result of the influx of dense, primitivemagma in the northern part of the chamber. The highly evolvedmagma at the top of the chamber penetrated along fractures inthe roof and spread laterally to form sill-like bodies. Theroof zone consisted of a network of veins and sills penetratingan interconnected framework of metabasic hornfels. Continuedcrystallization at the floor, while the magma chamber expanded,finally resulted in the interconnected rafts being engulfedby the crystallization front. Fragments detached from the roofsank to the floor to cause the observed impact structures. Thelarge, raft-like, fine-grained, granular, gabbroic bodies areconsidered to be in situ country rock inclusions. Reprints available from J. R. Wilson     

Hydrothermal origin of mafic layers in alpine-type peridotites: Evidence from the seiad ultramafic complex,California, USA

Cretaceous alkaline intrusive rocks present in the Bitterfontein area comprise a suite having compositions ranging from olivine melilitite to syenite. These rocks which include some of lamprophyric affinity form part of the widespread dominantly alkaline suite of intrusives occurring in a broad zone parallel to the south western African coastal regions. This paper presents the petrology of the Bitterfontein alkaline rocks together with mineral and rock analyses. The chemistry of the rocks shows the suite to define a SiO₂ enrichment trend linking the compositions of olivine melilitite to oversaturated basic rocks. This trend is compared with trends defined by essentially tholeiitic volcanics and kimberlite-olivine melilitite compositions and a genetic relationship with the latter is apparent. Polybaric crystallisation of a larnite normative liquid in a crustal environment coupled with fractionation especially of phlogopite is important in the generation of members of the Bitterfontein suite. Phlogopite fractionation represents a deviation by the Bitterfontein suite from the evolutionary trend predicted by experimental work for low pressure anhydrous compositions in the Fo-La-Ne-SiO₂ system.     

Lherzolite nodules from the Fen alkaline complex,Norway

The alkaline ultrabasic rooks (damkjernite) of the Fen alkaline complex contain abundant rounded inclusions of spinel lherzolite, closely similar in composition and mineralogy to the nodules found in many undersaturated basaltic rocks. Clinopyroxene compositions indicate crystallization at P=10–13 KB, T=1200–1250° C. A model involving partial melting in a rising diapir of mantle peridotite allows interpretation of the nodules either as mantle fragments or as cognate cumulates, and suggests that crustal thinning in the Oslo area possibly began as early as 500–600 m.y. ago. The presence of the nodules indicates that the damkjernite did not pause for intracrustal differentiation during its rapid ascent to the surface. The crustal contamination suggested by recent Sr-isotope studies may have occurred during differentiation at the base of the continental crust.Contribution No. 62 in The Norwegian Geotraverse Project.     

Amphibole-bearing Cumulate Inclusions, Grand Canyon, Arizona and their bearing on Silica-Undersaturated Hydrous Magmas in the Upper Mantle

Rare inclusions in Holocene basanite within the western GrandCanyon are comprised of poikilitic titaniferous amphibole togetherwith variable proportions of relatively Fe-rich clinopyroxene,orthopyroxene, olivine, Cr-poor spinel, and pyropic garnet,magnesian ilmenite, and titaniferous phlogopite. No feldsparhas been found in the 219 inclusions investigated. Availableexperimental data suggest crystallization at approximately 20kb (65 km depth) in a region where the crust is 30–40km thick. On the basis of their fabric, the inclusions appear to representcumulates, but other modes of origin cannot be completely ruledout. Anhydrous grains, including some considered to be postcumulusprecipitates, experienced extensive resorption into the interstitialhydrous melt before it ultimately crystallized, perhaps 100?C below liquidus temperatures, as the poikilitic amphibole.In spite of these crystal-melt reactions, and some probablesubsolidus recrystallization as well, systematic variationsin cumulus phase compositions exist and indicate one main precipitationsequence was ol+sp, ol+sp+cpx, cpx+cpx+sp, cpx+sp, cpx+sp+ilm.The local pyropic garnet appears postcumulus in the last threecumulus assemblages. The igneous bodies represented by the inclusions comprised arelatively small portion of the upper mantle sampled by theascending basanitic magma. But in contrast to the thin amphibole-bearingveins in the mantle-derived massif at Etang de Lherz, the igneousbodies beneath the Grand Canyon are considered to be substantiallylarger in dimension, on the order of at least meters ratherthan a few centimeters. Primary nephelinite-basanite melts produced by variable butsmall degrees of partial melting of hydrous upper mantle arenot represented by the poikilitic amphiboles because of complexprocesses at the site of emplacement, including reactions betweenmelt and chromian-spinel peridotite wall rocks.     

The origin of oceanic plagiogranites from the karmoy ophiolite,western Norway

Both field relationships and geochemical characteristics indicate two suites of plagiogranitic and related rocks coexisting in the higher parts of the Karmoy ophiolite of western Norway. The plutonic zone of this ophiolite can be subdivided into three complexes; the East-Karmoy Igneous Complex, the Visnes High Level Complex and the Veavagen Igneous Complex and plagiogranitic rocks are well developed in the first two of these.Within the East-Karmoy Igneous Complex, plagiogranites are associated with high temperature, pre-basic dyke, shear zones. Rare earth element modelling indicates that these plagiogranites were derived by anatexis of amphibolite (hydrated diabase) assuming a starting material consisting of 40% hornblende and 60% plagioclase and that batch melting occurred within the stability field of hornblende.In comparison, plagiogranite occurs in a number of bodies in the upper part of the Visnes High Level Complex and forms a sandwich horizon together with biotite diorites and epidosites between a roof assemblage of dykes, microgabbros and magnetite gabbros, and a floor assemblage of layered and non-layered gabbros. The R.E.E. modelling of the petrogenesis of this series of plagiogranites indicates that they were derived by filter pressing of a differentiated interstitial liquid to the vari-textured gabbros, although the distribution of highly hygromagmatophile elements such as K, Rb, Ba, etc. cannot be explained satisfactorily by this model alone. Depletion in these elements appears to be an autometasomatic effect.     

Mineralogy and trace element chemistry of the siliceous earth of barmer basin, Rajasthan: Evidence for a volcanic origin

We report the presence of a 3–5 cm thick loose fragmental layer in the Siliceous Earth at Matti ka Gol in the Barmer basin of Rajasthan. Petrographic, chemical and mineralogical study reveals the presence of abundant volcanic debris such as glass shards, agglutinates, hollow spheroids, kinked biotites, feldspars showing oscillatory zoning, olivines, ilmenite and native iron. The presence of similar particles in the whole section suggests that the Siliceous Earth is a volcanic ash. Stratigraphic correlation, palynological and microvertebrate data suggest that the Siliceous Earth may have deposited over a short span of time during the Upper Cretaceous to Lower Palaeocene. In view of the possibility that this section may contain K/T impact debris, we looked for grains having impact signatures. Some patches of the Siliceous Earth of Bariyara show the presence of Ni-rich (> 0.5%) vesicular glasses, sanidine spherules, magnesioferrite crystals, soot, etc., but because of their low abundance, it is not possible to establish if they are volcanic, micrometeorite ablation products or a part of the K/T impact ejecta.     

Late Triassic Intraoceanic Arc Aystem within Neotethys: Evidence from Cumulate Hornblende Gabbro in Gangdese Belt, South Tibet

The Neotethys plays an important role in shaping the Gangdese magmatic belt,southern Tibet.However,the initial time of spreading and subduction of the Neotethys remains contentious.In this study,a suite of late Triassic cumulate hornblende gabbro was identified in the southern margin of the Gangdese magmatic belt.The gabbro exhibits cumulate structure,with hornblende and plagioclase as the primary mineral phases.Isotopic data indicate a hydrous magma source derived from a depleted mantle wedge that has been modified by slab dehydration.Geochemical discriminations suggest that the gabbro was formed in an intraoceanic arc setting,with crystallization ages of ca.220-213 Ma.Hornblende,hornblendelagioclase and ilmenite thermometers reveal that the crystallization temperature of 900-750°C for the gabbro.Hornblende and hornblende-plagioclase geobarometers yield an emplacement depth at ca.14.5-19.5 km.This gabbro constitutes a line of evidence for an intraoceanic arc magmatism that is coeval with the counterparts in the southern Turkey,revealing an intraoceanic subduction system within the Neotethys from west to east in the Late Triassic and that the oceanization of the Neotethys was much earlier than previous expectation.     

Sedimentology and origin of deposits from a small ice-dammed lake, Leirbreen, Norway

This paper describes recent proglacial lacustrine sediments exposed by the drainage of a small (probably never more than 0·03 km²) ice-dammed lake basin at Leirbreen, central Jotunheimen, Norway. The dominant facies include ripple-laminated, massive and horizontally-stratified sands, massive and horizontally-laminated silts, and irregularly-laminated fine sands and silts. The major control on lake circulation and the nature and distribution of these facies was an underflow driven by a subglacial meltwater stream which formed the major lake input. Although much of the sedimentary sequence indicates a pulsatory input, the proximal character of this small lake prevented the development of classic varved silts. Compressional deformation of shoreline sediments was due to winter lake ice push. Other deformational processes included the grounding of icebergs, water escape and syn-sedimentary downslope collapse. Observations from an adjacent small ice-marginal lake at Leirbreen provide support for several of the inferences drawn from the sediments of the former ice-dammed lake.     

Chromite-bearing spessartites from Kasuga-mura,Japan, and their bearing on possible mantle origin andesite

An unusual association of chromite and hornblende was found in the spessartites of andesite composition, occurring as a dike swarm associated with a Cretaceous granite batholith. The spessartites are largely porphyritic with phenocrysts of either hornblende or augite. One dike, comprising a finegrained spessartite, exhibits distinct chilled selvages of aphanitic facies. The chromites in the fine-grained and augite-spessartites are significantly higher in Cr/ (Cr+Al) than those occurring rarely as inclusions in the phenocrystic hornblendes in the hornblende spessartite, although both are similar in Mg/ (Mg+Fe), Fe₂O₃, and TiO₂. The phenocrystic hornblendes are titaniferous pargasite with high Mg/ (Mg+Fe), and differ in their higher octahedral Al from the groundmass hornblendes including those in the fine-grained spessartite. The crystallization sequence in the phenocrystic hornblende-bearing spessartites is Al-rich chromite, phenocrystic hornblende, and plagioclase without pyroxene, suggesting a high water content in the magma and the start of the crystallization at relatively high pressures. The finegrained spessartite from which the porphyritic spessartites have been derived by fractionation of dominant mafic minerals, has the high Mg-value and Cr content equivalent to those in primitive, undifferentiated basalts, although still andesitic in SiO₂ content. Chemically similar magnesian andesites, although uncommon, found in some orogenic calc-alkalic suites may represent a magma composition in equilibrium with mantle peridotite under the condition of high water pressures.     

The chemistry of bottled mineral and spring waters from Norway,Sweden, Finland and Iceland

Twenty-two bottled mineral and spring waters from Norway, Sweden, Finland and Iceland have been analysed for 71 inorganic chemical parameters with low detection limits as a subset of a large European survey of bottled groundwater chemistry (N = 884). The Nordic bottled groundwaters comprise mainly Ca–Na–HCO₃–Cl water types, but more distinct Ca–HCO₃, Na HCO₃ and Na–Cl water types are also offered. The distributions for most elements fall between groundwater from Fennoscandian Quaternary unconsolidated aquifers and groundwater from Norwegian crystalline bedrock boreholes. Treated tap waters have slightly lower median values for many parameters, but elements associated with plumbing have significantly higher concentrations in tap waters than in bottled waters. The small dataset is able to show that excessive fluoride and uranium contents are potential drinking water problems in Fennoscandia. Nitrate and arsenic displayed low to moderate concentrations, but the number of samples from Finland and Northern Sweden was too low to detect that elevated concentrations of arsenic occur in bedrock boreholes in some regions. The data shows clearly that water sold in plastic bottles is contaminated with antimony. Antimony is toxic and suspected to be carcinogenic, but the levels are well below the EU drinking water limit. The study does not provide any health-based arguments for buying bottled mineral and spring waters for those who are served with drinking water from public waterworks. Drinking water from crystalline bedrock aquifers should be analysed. In case of elevated concentrations of fluoride, uranium or arsenic, most bottled waters, but not all, will be better alternatives when treatment of the well water is not practicable.     

Mg isotope constraints on soil pore-fluid chemistry: Evidence from Santa Cruz, California

Mg isotope ratios (²⁶Mg/²⁴Mg) are reported in soil pore-fluids, rain and seawater, grass and smectite from a 90 kyr old soil, developed on an uplifted marine terrace from Santa Cruz, California. Rain water has an invariant ²⁶Mg/²⁴Mg ratio (expressed as δ²⁶Mg) at −0.79 ± 0.05‰, identical to seawater δ²⁶Mg. Detrital smectite (from the base of the soil profile, and therefore unweathered) has a δ²⁶Mg value of 0.11‰, potentially enriched in ²⁶Mg by up to 0.3‰ compared to the bulk silicate Earth Mg isotope composition (although within the range of all terrestrial silicates). The soil pore-waters show a continuous profile with depth for δ²⁶Mg, ranging from −0.99‰ near the surface to −0.43‰ at the base of the profile. Shallow pore-waters (<1 m) have δ²⁶Mg values that are similar to, or slightly lower than the rain waters. This implies that the degree of biological cycling of Mg in the pore-waters is relatively small and is quantified as <32%, calculated using the average Mg isotope enrichment factor between grass and rain (δ²⁶Mg_grass-δ²⁶Mg_rain) of 0.21‰. The deep pore-waters (1-15 m deep) have δ²⁶Mg values that are intermediate between the smectite and rain, ranging from −0.76‰ to −0.43‰, and show a similar trend with depth compared to Sr isotope ratios. The similarity between Sr and Mg isotope ratios confirms that the Mg in the pore-waters can be explained by a mixture between rain and smectite derived Mg, despite the fact that Mg and Sr concentrations may be buffered by the exchangeable reservoir. However, whilst Sr isotope ratios in the pore-waters span almost the complete range between mineral and rain inputs, Mg isotopes compositions are much closer to the rain inputs. If Mg and Sr isotope ratios are controlled uniquely by a mixture, the data can be used to estimate the mineral weathering inputs to the pore-waters, by correcting for the rain inputs. This isotopic correction is compared to the commonly used chloride correction for precipitation inputs. A consistent interpretation is only possible if Mg isotope ratios are fractionated either by the precipitation of a secondary Mg bearing phase, not detected by conventional methods, or selective leaching of ²⁴Mg from smectite. There is therefore dual control on the Mg isotopic composition of the pore-waters, mixing of two inputs with distinct isotopic compositions, modified by fractionation. The data provide (1) further evidence for Mg isotope fractionation at the surface of the Earth and (2) the first field evidence of Mg isotope fractionation during uptake by natural plants. The coherent behaviour of Mg isotope ratios in soil environments is encouraging for the development of Mg isotope ratios as a quantitative tracer of both weathering inputs of Mg to waters, and the physicochemical processes that cycle Mg, a major cation linked to the carbon cycle, during continental weathering.     

A Neoarchean dismembered ophiolite complex from southern India: Geochemical and geochronological constraints on its suprasubduction origin

Ophiolites, the remnants of ancient oceanic lithosphere, have been described from collisional sutures of various ages with only few examples from Archean terranes. Here we report the discovery of a Neoarchean ophiolite suite from the southern margin of the Dharwar Craton in India, tectonically intercalated within a Neoproterozoic suture zone. The metamorphosed and variably dismembered ophiolite suite, exposed around Devanur, comprises altered ultramafic units, websterite, gabbros, mafic dykes, amphibolites, trondhjemites and pegmatites associated with ferruginous metachert. Structural and petrographic studies indicate that the rocks represent a highly sheared and metamorphosed suite emplaced as a thrust sheet. The major and trace element geochemistry of the mafic dykes indicate derivation from basaltic-andesitic magmas with tholeiitic to calc-alkaline characteristics. The rocks display negative Nb anomalies with enrichment of LILE (K, Rb, Ba, Th) and depletion in HFSE (Ti, Nb, Hf, Tb). The tectonic discrimination of these rocks based on various geochemical plots suggests that they were generated in a suprasubduction zone setting. We present new SHRIMP zircon U-Pb data for two trondhjemite samples from this complex, which yield ²³⁸U-²⁰⁶Pb ages of 2528 ± 61 and 2545 ± 56 Ma. The Neoarchean age from the trondhjemites obtained in our study is closely comparable to similar ages obtained in recent studies from magmatic zircons in charnockites and orthogneisses in the area. The suprasubduction zone assemblages and arc magmas suggest a Neoarchean ocean closure along the southern margin of the Dharwar Craton.     

Possibility of identification of back-arc paleobasins from high-grade orthometamorphite rocks: Evidence from basic crystalline schists of the Slyudyanka crystalline complex,South Baikal region

The Slyudyanka crystalline complex is located within the composite Khamar-Daban metamorphic terrane, the part of the Central Asian fold belt. Geochemical composition of the basic crystalline schists of the Slyudyanka Group (subterrane) metamorphosed under the high-temperature subfacies of the granulite facies suggests that their protoliths were tholeiitic basalts. Their geochemical signatures are intermediate between mid-ocean ridges and island arc basalts, best approximating back-arc basin basalts. The types of the metamorphic rocks of the Slyudyanka Group and their combination in sequences also most correspond to accumulation in back-arc basins. It was concluded that the high-grade metavolcanic rocks retain main geochemical signatures of protoliths, which allows the reconstruction of their paleogeodynamic settings, including back-arc basins.     

Composition,morphology, and origin of phosphate pellets: Evidence from phosphorites of the Lesser Karatau

The global Vendian-Cambrian epoch of phosphate accumulation is marked by the virtually synchronous appearance of giant sedimentary basins, where the largest phosphate-bearing provinces were formed in a relatively short time span. The paper is devoted to one of the main problems in phosphate geology, namely the origin of phosphate pellets. They are observed as microscopic particles in the stratified microgranular phosphorites formed during the Vendian-Cambrian epoch. Different forms of pellets from the productive formation of the Lesser Karatau were studied with the scanning electron microscope. The morphogenetic comparison of phosphate particles and microbiota found in the Vendian-Cambrian or older rocks was carried out. The distribution of major chemical elements in different pellets was studied for the first time. Based on the results obtained, regularities of the vertical and lateral distribution of phosphate pellets in the Lesser Karatau and the issue of their origin is discussed.