Suprathermal oxygen and hydrogen atoms in the upper Martian atmosphere

The processes of kinetics and transport of hot oxygen and hydrogen atoms in the transition (from the thermosphere to the exosphere) region of the upper Martian atmosphere are studied. The reaction of dissociative recombination of the principal ionospheric ion O ₂ ⁺ with thermal electrons in the ionosphere of Mars served as the source of hot oxygen atoms. The process of momentum and energy transfer in elastic collisions between hot oxygen atoms and atmospheric hydrogen atoms with thermal energies was regarded as the source of hot hydrogen atoms. The kinetic energy distribution functions are determined for suprathermal oxygen and hydrogen atoms. It is shown that the exosphere is populated with a significant number of suprathermal oxygen atoms with kinetic energies ranging up to the escape energy of 2 eV (i.e., the hot oxygen Martian corona is formed). The transfer of energy from hot oxygen atoms to thermal hydrogen atoms creates an additional nonthermal flux of atomic hydrogen escaping from the Martian atmosphere.     

Stochastic models of hot planetary and satellite coronas: A photochemical source of hot oxygen in the upper atmosphere of Mars

The processes of the kinetics and transport of hot oxygen atoms in the upper atmosphere of Mars are studied. A reaction of dissociative recombination of the main ionospheric ion O ₂ ⁺ with thermal electrons is considered as a photochemical source of suprathermal oxygen atoms. Oxygen atoms are formed in the dissociative recombination reaction with an excess of kinetic energy of about 0.4–4 eV and lose that energy in elastic and inelastic collisions with the ambient thermal atmospheric gas. The altitude distributions of the concentrations of neutral and ionized components, as well as their temperatures, were taken from Krasnopolsky (2002). Unlike the models published earlier, detailed calculations of the formation, collisional kinetics, and transport of suprathermal oxygen atoms in the thermosphere-exosphere transition region of the upper atmosphere of Mars have been made for the first time. For this, we used a stochastic model of the formation of a hot planetary corona (Shematovich, 2004). It has been shown that the considered photochemical source of suprathermal oxygen leads to the formation of the hot corona and to higher nonthermal losses of oxygen from the upper atmosphere of Mars due to escape fluxes. The detailed energy spectra of the fluxes of suprathermal atomic oxygen were calculated for the thermosphere-exosphere transition region of the Martian atmosphere.Translated from Astronomicheskii Vestnik, Vol. 39, No. 1, 2005, pp. 26–37.Original Russian Text Copyright © 2005 by Krestyanikova, Shematovich.     

Suprathermal oxygen atoms in the Martian upper atmosphere: Contribution of the proton and hydrogen atom precipitation

This is a study of the kinetics and transport of hot oxygen atoms in the transition region (from the thermosphere to the exosphere) of the Martian upper atmosphere. It is assumed that the source of the hot oxygen atoms is the transfer of momentum and energy in elastic collisions between thermal atmospheric oxygen atoms and the high-energy protons and hydrogen atoms precipitating onto the Martian upper atmosphere from the solar-wind plasma. The distribution functions of suprathermal oxygen atoms by the kinetic energy are calculated. It is shown that the exosphere is populated by a large number of suprathermal oxygen atoms with kinetic energies up to the escape energy 2 eV; i.e., a hot oxygen corona is formed around Mars. The transfer of energy from the precipitating solar-wind plasma protons and hydrogen atoms to the thermal oxygen atoms leads to the formation of an additional nonthermal escape flux of atomic oxygen from the Martian atmosphere. The precipitation-induced escape flux of hot oxygen atoms may become dominant under the conditions of extreme solar events, such as solar flares and coronal mass ejections, as shown by recent observations onboard NASA’s MAVEN spacecraft (Jakosky et al., 2015).     

Suprathermal hydrogen produced by the dissociation of molecular hydrogen in the extended atmosphere of exoplanet HD 209458b

The ionization and dissociation of molecular hydrogen by the ultraviolet (UV) radiation of the parent star lead to the formation of hydrogen atoms with an excess of kinetic energy and, thus, are an important source of suprathermal hydrogen atoms in the upper atmosphere of exoplanet HD 209458b. Contemporary aeronomical models did not investigate these processes because they assumed the fast local thermalization of the hot atoms of hydrogen by elastic collisions. However, the kinetics and transfer of these atoms were not calculated in detail, because they require the solving of the Boltzmann equation for a nonthermal atom population. This work estimates the effect of the UV radiation of the parent star and the accompanying photocleacton flux on the production of the suprathermal fraction of atomic hydrogen in the H₂ → H transition region. We also consider the formation of the escaping flux of Hatoms created by this effect in the upper atmosphere of HD 209458b. We calculate the production rate and energy spectrum of the hydrogen atoms with excess kinetic energy during the dissociation of H₂. Using the numerical stochastic model created by Shematovich (2004) for a hot planetary corona, we investigate the molecular-scale kinetics and transfer of suprathermal hydrogen atoms in the upper atmosphere and the emergent flux of atoms evaporating from the atmosphere. The latter is estimated as 3.4 × 10¹² cm⁻² s⁻¹ for a moderate stellar activity level of UV radiation, which leads to a planetary atmosphere evaporation rate of 3.4 × 10⁹ g s⁻¹ due to the process of the dissociation of H₂. This estimate is close to the observational value of ∼10¹⁰ g s⁻¹ for the rate of atmospheric loss of HD 209458b.     

Stochastic models of hot planetary and satellite coronas: Atomic oxygen in Europa’s corona

This paper analyzes the formation, kinetics, and transport of hot oxygen atoms in the atmosphere of the Jovian satellite Europa. Atmospheric sources of suprathermal oxygen atoms are assumed to be represented by the processes of dissociation of molecular oxygen, which is the main component of the atmosphere, by solar UV radiation and electron fluxes from the inner magnetosphere of Jupiter, as well as by the reaction of dissociative recombination of the main ionospheric ion O ₂ ⁺ which thermal electrons. It is shown that dissociation in Europa’s near-surface atmosphere is balanced by the processes of the loss of atomic oxygen due to the effective escape of suprathermal oxygen atoms into the inner magnetosphere of Jupiter along the orbit of Europa and due to ionization by magnetospheric electrons and catalytic recombination of oxygen atoms on the icy surface of the satellite. It thus follows that atomic oxygen is only a small admixture to the main atmospheric component—molecular oxygen—in the near-surface part of the atmosphere. However, the outer exospheric layers of Europa’s atmosphere are populated mostly by suprathermal oxygen atoms. The near-surface molecular envelope of Europa is therefore surrounded by a tenuous extended corona of hot atomic oxygen.     

Upper limits for the Martian exospheric number density during the Planet B/Nozomi mission

Dissociative recombination (DR) of ionospheric O₂⁺ ions is an important source of suprathermal atomic oxygen in the exosphere as previous studies about the Martian upper atmosphere have shown. Because of the weaker gravitational attraction a hot oxygen corona on Mars should be denser than that observed on Venus. Since the most important mechanism for the production of the hot oxygen atoms in the Martian exosphere is DR, we investigated the variability of this production mechanism depending of solar activity. The Japanese Nozomi spacecraft will have the possibility to detect with the neutral mass spectrometer (NMS) for the first time in-situ the theoretically predicted hot oxygen corona on Mars, if the corona number density above the cold background atmosphere is of the order of 10,000 cm⁻³. Due to a problem in the propulsion system Nozomi failed its planned arrival rendevouzs with Mars in October 1999 and will, therefore, arrive at the red planet not before January 2004. Solar activity will reach its maximum in 2001, so the related production rate of hot oxygen atoms will be in the medium range during the new arrival date of Nozomi. We used the ionospheric profiles from the Viking mission for low solar activity conditions (F_10.7≈70) and the Mariner 9 mission with a solar activity of about 120 for medium solar wind activity. The latter is comparable to the level we expect for the Mars arrival of Nozomi. The resulting influence of the hot oxygen corona number density distribution was calculated with a Monte Carlo technique. This technique is used to compute a hot particle density distribution function. We studied the atomic diffusion process in the Martian atmosphere by simulating the collision probability, particle direction and energy loss after collisions by generating random numbers. Compared to previous studies we have improved the Monte Carlo model by using more and smaller altitude steps and more detailed treatment of particles with a temporary downward motion. This has resulted in an increased amount of collisions and a shift to lower energies in the energy spectrum. Our results show that the hot oxygen component should begin to dominate above the cold background atmosphere at an altitude of about 500 km above the Martian surface. The NMS instrument on board of Nozomi should detect the hot oxygen component after its arrival at Mars in January 2004, at an altitude of about 600 km above the Martian surface. Since the solar activity will decrease during the mission the measurements during the first orbits will be the most significant ones. The first in-situ measurements of the hot oxygen number density would be very important for adjusting atmospheric escape models by separating ballistic, satellite and escape trajectories of the hot oxygen atoms, which are significant for studies of the evolution and solar wind interaction of the Martian atmosphere.     

Influence of the hot oxygen corona on the satellite drag in the Earth’s upper atmosphere

Calculation results on the possible influence of the hot oxygen fraction on the satellite drag in the Earth’s upper atmosphere on the basis of the previously developed theoretical model of the hot oxygen geocorona are presented. Calculations have shown that for satellites with orbits above 500 km, the contribution from the corona is extremely important. Even for the energy flux Q ₀ = 1 erg cm⁻² s⁻¹, the contribution of the hot oxygen can reach tens of percent; and considering that real energy fluxes are usually higher, one can suggest that for extreme solar events, the contribution of hot oxygen to the atmospheric drag of the satellite will be dominant. For lower altitudes, the contribution of hot oxygen is, to a considerable degree, defined by the solar activity level. The calculations imply that for the daytime polar atmosphere, the change of the solar activity level from F _10.7 ∼ 200 to F _10.7 ∼ 70 leads to an increase in the ratio of the hot oxygen partial pressure to the thermal oxygen partial pressure by a factor of almost 30, from 0.85 to 25%. The transition from daytime conditions to nighttime conditions almost does not change the contribution from suprathermal particles. The decrease of the characteristic energy of precipitating particles, i.e., for the case of charged particles with a softer energy spectrum, leads to a noticeable increase of the contribution of the suprathermal fraction, by a factor of 1.5–2. It has been ascertained that electrons make the main contribution to the formation of the suprathermal fraction; and with the increase of the energy of precipitating electrons, the contribution of hot oxygen to the satellite drag also increases proportionally. Thus, for a typical burst, the contribution of the suprathermal fraction is 30% even at relatively high solar activity F _10.7 = 135.     

Stochastic Models of Hot Planetary and Satellite Coronas: Suprathermal Nitrogen in Titan's Upper Atmosphere

The processes of dissociation and dissociative ionization of molecular nitrogen by solar UV radiation and by the accompanying flux of photoelectrons, as well as sputtering of the atmosphere by fluxes of magnetospheric ions and pick-up ions, are the main sources of translationally excited (hot, or suprathermal) nitrogen atoms and molecules in Titan's upper atmosphere. Since Titan does not possess an intrinsic magnetic field, ions from Saturn's magnetosphere can penetrate into the outer layers of Titan's atmosphere and sputter atoms and molecules from the atmosphere in momentum-transfer and charge exchange collisions. Atmospheric sputtering by corotating nitrogen ions and carbon-containing pick-up ions, as well as photodissociation-related losses, was considered previously by Lammer and Bauer (1993) and Shematovich et al. (2001, 2003). In this paper we investigate the processes of the formation and evolution of the fraction of suprathermal nitrogen atoms and molecules in the transition region of Titan's upper atmosphere using the previously developed Monte Carlo model for hot satellite and planetary coronas (Shematovich, 1999, 2004). It is established that the suprathermal nitrogen fraction in the transition region of Titan's upper atmosphere includes nitrogen atoms and molecules but the suprathermal nitrogen concentration is relatively small owing to high rates of escape from the atmosphere and to the efficient thermalization of suprathermal nitrogen at the altitudes of the relatively dense lower thermosphere. However, the scale height for suprathermal nitrogen in the transition region is much higher than that for the ambient atmospheric gas. Therefore, suprathermal nitrogen becomes one of the dominant components in the outer exosphere.     

Energy distribution function of translationally hot O(3P) atoms in the atmosphere of Earth

Translationally hot O(³P) atoms are produced in the atmosphere of Earth by photolysis of O₂ and O₃ and quenching of O(¹D). A rigorous kinetic theory analysis of this problem is developed and compared with the approach previously employed by Logan and McElroy [Planet. Space Sci.25, 117 (1977)]. It is shown that the kinetic theory employed by the previous workers is somewhat deficient. With the line-of-centers cross-section, the rates of reactions of the translationally hot O(³P) atoms with other atmospheric gases are calculated and found to be in some instances many orders of magnitude larger than the equilibrium rates. Though the non-equilibrium reaction rates with O(³P) are substantially increased, they are still not competitive with the corresponding reaction rates with O(¹D).     

Helium on Mars and Venus: EUVE observations and modeling

Long-exposure spectroscopy of Mars and Venus with the Extreme Ultraviolet Explorer (EUVE) has revealed emissions of He 584 Å on both planets and He 537 Å/O⁺ 539 Å and He⁺ 304 Å on Venus. Our knowledge of the solar emission at 584 Å, eddy diffusion in Mars' upper atmosphere, electron energy distributions above Mars' ionopause, and hot oxygen densities in Mars' exosphere has been significantly improved since our analysis of the first EUVE observation of Mars [Krasnopolsky, Gladstone, 1996, Helium on Mars: EUVE and Phobos data and implications for Mars' evolution, J. Geophys. Res. 101, 15,765-15,772]. These new results and a more recent EUVE observation of Mars are the motivation for us to revisit the problem in this paper. We find that the abundance of helium in the upper atmosphere, where the main loss processes occur, is similar to that in the previous paper, though the mixing ratio in the lower and middle atmosphere is now better estimated at 10±6 ppm. Our estimate of the total loss of helium is almost unchanged at 8×¹⁰²³ s⁻¹, because a significant decrease in the loss by electron impact ionization above the ionopause is compensated by a higher loss in collisions with hot oxygen. We neglect the outgassing of helium produced by radioactive decay of U and Th because of the absence of current volcanism and a very low upper limit to the seepage of volcanic gases. The capture of solar wind α-particles is currently the only substantial source of helium on Mars, and its efficiency remains at 0.3. A similar analysis of EUV emissions from Venus results in a helium abundance in the upper atmosphere which is equal to the mean of the abundances measured previously with two optical and two mass spectrometers, and a derived helium mixing ratio in the middle and lower atmosphere of 9±6 ppm. Helium escape by ionization and sweeping out of helium ions by the solar wind above the ionopause is smaller than that calculated by Prather and McElroy [1983, Helium on Venus: implications for uranium and thorium, Science 220, 410-411] by a factor of 3. However, charge exchange of He⁺ ions with CO₂ and N₂ between the exobase and ionopause and collisions with hot oxygen ignored previously add to the total loss which appears to be at the level of 10⁶ cm⁻² s⁻¹ predicted by Prather and McElroy [1983, Science 220, 410-411]. The loss of helium is compensated by outgassing of helium produced by radioactive decay of U and Th and by the capture of the solar wind α-particles with an efficiency of 0.1. We also compare our derived α-particle capture efficiencies for Mars and Venus with observed X-ray emissions resulting from the charge exchange of solar wind heavy ions with the extended atmospheres on both planets [Dennerl et al., 2002, Discovery of X-rays from Venus with Chandra, Astron. Astrophys. 386, 319-330; Dennerl, 2002, Discovery of X-rays from Mars with Chandra, Astron. Astrophys. 394, 1119-1128]. The emissions from both disk and halo on Mars agree with our calculated values; however, we do not see a reasonable explanation for the X-ray halo emission on Venus. The ratio of the charge exchange efficiencies derived from the disk X-ray emissions of Mars and Venus is similar to the ratio of the capture efficiencies for these planets. The surprisingly bright emission of He⁺ at 304 Å observed by EUVE and Venera 11 and 12 suggests that charge exchange in the flow of the solar wind α-particles around the ionopause is much stronger than in the flow of α-particles into the ionosphere.     

Comment on the papers “Production of hot nitrogen atoms in the martian thermosphere” by F. Bakalian and “Monte Carlo computations of the escape of atomic nitrogen from Mars” by F. Bakalian and R.E. Hartle

In recent articles published in Icarus, Bakalian [2006. Icarus 183, 69-78] discusses and computes the production rates of hot nitrogen atoms in the martian thermosphere due to N₂ photodissociation and N⁺₂ dissociative recombination, and Bakalian and Hartle [2006. Icarus 183, 55-68] use a Monte Carlo code to compute the escape rates of nitrogen atoms from Mars due to photodissociation of N₂, dissociative recombination of N⁺₂, and pickup ion escape due to photoionization of N atoms above the ionopause. Bakalian concludes that “photodissociation of N₂ is the dominant escape mechanism in the martian atmosphere.” We will show that this conclusion is not supportable. In addition, both papers contain scientific errors, misrepresentations, inaccurate referencing, lack of proper attribution, and they fail to place these investigations into the existing extensive body of work on this subject.     

On the properties of O and O2 ions in a hybrid model and in Mars Express IMA/ASPERA-3 data: A case study

We have performed a numerical simulation to analyze the energy spectra of escaping planetary O⁺ and O₂⁺ ions at Mars. The simulated time-energy spectrograms were generated along orbit no. 555 (June 27, 2004) of Mars Express when its Ion Mass Analyzer (IMA)/ASPERA-3 ion instrument detected escaping planetary ions. The simulated time-energy spectrograms are in general agreement with the hypothesis that planetary O⁺ and O₂⁺ ions far from Mars are accelerated by the convective electric field. The HYB-Mars hybrid model simulation also shows that O⁺ ions originating from the ionized hot oxygen corona result in a high-energy (E>1 keV) O⁺ ion population that exists very close to Mars. In addition, the simulation also results in a low-energy (E<0.1 keV) planetary ion population near the pericenter. In the analyzed orbit, IMA did not observe a clear high-energy planetary ion or a clear low-energy planetary ion population near Mars. One possible source for this discrepancy may be the Martian magnetic crustal anomalies because MEX passed over a strong crustal field region near the pericenter, but the hybrid model does not include the magnetic crustal anomalies.     

Titan's corona: The contribution of exothermic chemistry

The contribution of exothermic ion and neutral chemistry to Titan's corona is studied. The production rates for fast neutrals N₂, CH₄, H, H₂, ³CH₂, CH₃, C₂H₄, C₂H₅, C₂H₆, N(⁴S), NH, and HCN are determined using a coupled ion and neutral model of Titan's upper atmosphere. After production, the formation of the suprathermal particles is modeled using a two-stream simulation, as they travel simultaneously through a thermal mixture of N₂, CH₄, and H₂. The resulting suprathermal fluxes, hot density profiles, and energy distributions are compared to the N₂ and CH₄ INMS exospheric data presented in [De La Haye, V., Waite Jr., J.H., Johnson, R.E., Yelle, R.V., Cravens, T.E., Luhmann, J.G., Kasprzak, W.T., Gell, D.A., Magee, B., Leblanc, F., Michael, M., Jurac, S., Robertson, I.P., 2007. J. Geophys. Res., doi:10.1029/2006JA012222, in press], and are found insufficient for producing the suprathermal populations measured. Global losses of nitrogen atoms and carbon atoms in all forms due to exothermic chemistry are estimated to be and .     

The sodium and hydrogen gas clouds of Io

Models are developed to describe the spatial distribution of gases emitted by Io and are applied to recent observations which indicate extensive gas clouds of hydrogen and sodium in orbit around Jupiter. Hydrogen and sodium atoms are emitted from Io with velocities in the range 2 to 3 km sec^?1, with fluxes of about 10¹⁰ and 10⁸cm^?2sec^?1 for hydrogen and sodium respectively. Hydrogen atoms may be formed by photodecomposition of gases such as NH₃ or H₂S released from the satellite surface and may escape thermally from an exosphere whose temperature is about 500 K. Sodium may be ejected from the surface by energetic particles or by ultraviolet radiation and it appears that a non-thermal mechanism drawing energy from Jupiter's magnetic field is required in order to account for its release to space.     

Oxygen ion escape at Mars in a hybrid model: High energy and low energy ions

We have studied the escape and energization of several O⁺ populations and an population at Mars by using a hybrid model. The quasi-neutral hybrid model, HYB-Mars model, included five oxygen ion populations making it possible to distinguish photoions from oxygen ions originating from charge exchange processes and from the ionosphere.We have identified two high-energy ion components and one low-energy ion component of oxygen. They have different spatial and energy distributions near Mars. The two high-energy oxygen ion components, consisting of a high-energy “beam” and a high-energy “halo”, have different origins. (1) The high-energy (>∼100 eV) “beam” of O⁺ and ions are originating from the ionosphere. These ions form a highly asymmetric spatial distribution of escaping oxygen ions with respect to the direction of the convective electric field in the solar wind. (2) The high-energy (>∼100 eV) “halo” component contains O⁺ ions which are formed from the oxygen neutral exosphere by extreme ultraviolet radiation (EUV) and by charge exchange processes. These energetic halo ions can be found all around Mars. (3) The low energy O⁺ and ions (<∼100 eV) form a relatively symmetric spatial distribution around the Mars-Sun line. They originate from the ionosphere and from charge exchange processes between protons and exospheric oxygen atoms.The existence of the low- and the high-energy oxygen components is in agreement with recent in situ plasma measurements made by the ASPERA-3 instrument on the Mars Express mission. The analysis of the escaping oxygen ions suggests that the global energization of escaping planetary ions in the martian tail is controlled by the convective electric field.     

First ENA observations at Mars: Subsolar ENA jet

The Neutral Particle Detector (NPD), an Energetic Neutral Atom (ENA) sensor of the Analyzer of Space Plasmas and Energetic Atoms (ASPERA-3) on board Mars Express, detected intense fluxes of ENAs emitted from the subsolar region of Mars. The typical ENA fluxes are (4-7) × 10⁵ cm⁻² sr⁻¹ s⁻¹ in the energy range 0.3-3 keV. These ENAs are likely to be generated in the subsolar region of the martian exosphere. As the satellite moved away from Mars, the ENA flux decreased while the field of view of the NPD pointed toward the subsolar region. These decreases occurred very quickly with a time scale of a few tens of seconds in two thirds of the orbits. Such a behavior can be explained by the spacecraft crossing a spatially constrained ENA jet, i.e., a highly directional ENA emission from a compact region of the subsolar exosphere. This ENA jet is highly possible to be emitted conically from the subsolar region. Such directional ENAs can result from the anisotropic solar wind flow around the subsolar region, but this can not be explained in the frame of MHD models.     

Some problems related to the origin of methane on Mars

The following problems related to the origin of methane on Mars have been considered. (1) Laboratory simulations of the impact phenomena confirm effective heterogeneous chemistry between the products of the fireball. This chemistry lowers the fireball freezing temperature from 2000 to 750 K for methane and to 1100 K for CO/CO₂. Production of methane on Mars by cometary impacts is 0.8% of the total production. A probability that the observed methane on Mars came from impact of a single comet is 0.0011. (2) The PFS observations of variations of methane on Mars require a very effective heterogeneous loss of methane. Heterogeneous effect of dust is half that of the surface rocks. Thermochemical equilibrium requires production, not loss, of methane. Existing kinetic data show a very low efficiency of heterogeneous reactions of methane. Highly reactive superoxide ions generated by the solar UV photons on the martian rocks cannot remove methane. The required efficiency of heterogeneous loss of methane on Mars is higher than that on Earth by a factor of ?1000, although the expected efficiency on Earth is stronger than that on Mars because of the liquid ocean and the abundant oxygen. All these inconsistencies may be removed if variations of the rock reflectivity contribute to the PFS observations of methane on Mars. The PFS data on H₂CO, HCl, HF, and HBr also raise doubts. (3) Although geologic sources of methane are possible, the lack of current volcanism, hydrothermal activity, hot spots, and very low seepage of gases from the interior are not favorable for geologic methane. Any proposed geological source of methane on Mars should address these problems. Some weak points in the suggested geologic sources are discussed. (4) Measurements of ¹³C/¹²C and D/H in methane would be difficult because of the low methane abundance. These ratios are mostly sensitive to a temperature of methane formation and cannot distinguish between biogenic and low-temperature geologic sources. Their analysis requires the carbon isotope ratio in CO₂ on Mars, which is known with the insufficient accuracy, and D/H in water, which is different in the atmosphere, polar caps, regolith and interior. Therefore, the stable isotope ratios may not give a unique answer on the origin of methane. (5) Ethane and propane react with OH much faster than methane. If their production relative to methane is similar to that on Earth, then their expected abundances on Mars are of a few parts per trillion. (6) Loss of SO₂ in the reaction with peroxide on ice is smaller than its gas-phase loss by an order of magnitude. The overall results strengthen the biogenic origin of martian methane and its low variability.     

Lyman-alpha observations of venera-9 and 10 I. The non-thermal hydrogen population in the exosphere of venus

The dayside hydrogen exosphere was observed in October–November 1975 with a Lymanalpha photometer carried on board Venera-9 and 10. In addition to intensity measurements, the use of a hydrogen cell allowed for the first time linewidth measurements. Both intensity and linewidth measurements below 1500 km of altitude are well fitted by a single exospheric component (T_c = 500 ± 100 K, n_c = 1.5 × 10⁴ atom cm^?3at 250 km). Above 3000 km, the measured linewidth increased sharply, to decrease again above 4500 km. This feature is interpreted as the signature of an additional population of “hot” atoms circulating on satellite orbits, created just behind the bow-shock by charge-exchange collisions (with an efficiency of 4%) between the neutral atoms and the solar wind protons, which became turbulent after bow-shock crossing. The density ratio of “hot” to standard population is of the order of 10% around 3500 km of altitude.     

The lunar exosphere: The sputtering contribution

We have extended our Monte Carlo model of exospheres [Wurz, P., Lammer, H., 2003. Icarus 164 (1), 1-13] by treating the ion-induced sputtering process from a known surface in a self-consistent way. The comparison of the calculated exospheric densities with experimental data, which are mostly upper limits, shows that all of our calculated densities are within the measurement limits. The total calculated exospheric density at the lunar surface of about 1×¹⁰⁷ m⁻³ as result of solar wind sputtering we find is much less than the experimental total exospheric density of about ¹⁰¹² m⁻³. We conclude that sputtering contributes only a small fraction of the total exosphere, at least close to the surface. Because of the considerably larger scale height of atoms released via sputtering into the exosphere, sputtered atoms start to dominate the exosphere at altitudes exceeding a few 1000 km, with the exception of some light and abundant species released thermally, e.g. H₂, He, CH₄, and OH. Furthermore, for more refractory species such as calcium, our model indicates that sputtering may well be the dominant mechanism responsible for the lunar atmospheric inventory, but observational data does not yet allow firm conclusions to be drawn.