Detrital zircon ages from southern Norway – implications for the Proterozoic evolution of the southwestern Baltic Shield

An ion-microprobe (SIMS) U-Pb zircon dating study on four samples of Precambrian metasediments from the high-grade Bamble Sector, southern Norway, gives the first information on the timing of discrete crust-forming events in the SW part of the Baltic Shield. Recent Nd and Pb studies have indicated that the sources of the clastic metasediments in this area have crustal histories extending back to 1.7 to 2.1 Ga, although there is no record of rocks older than 1.6 Ga in southern Norway. The analysed metasediments are from a sequence of intercalated, centimetre to 10-metre wide units of quartzites, semi-metapelites, metapelites and mafic granulites. The zircons can be grouped in two morphological populations: (1) long prismatic; (2) rounded, often flattened. The BSE images reveal that both populations consist of oscillatory zoned, rounded and corroded cores (detrital grains of magmatic origin), surrounded by homogeneous rims (metamorphic overgrowths). The detrital zircons have ²⁰⁷Pb/²⁰⁶Pb ages between 1367 and 1939 Ma, with frequency maxima in the range 1.85 to 1.70 Ga and 1.60 to 1.50 Ga. There is no correlation between crystal habit and age of the zircon. One resorbed, inner zircon core in a detrital grain is strongly discordant and gives a composite inner core-magmatic outer core ²⁰⁷Pb/²⁰⁶Pb age of 2383 Ma. Two discrete, unzoned zircons have ²⁰⁷Pb/²⁰⁶Pb ages of 1122 and 1133 Ma, representing zircon growth during the Sveconorwegian high-grade metamorphism. Also the μm wide overgrowths, embayments in the detrital cores and apparent “inner cores” which represent secondary metamorphic zircon growth in deep embayments in detrital grains, are of Sveconorwegian age. The composite-detrital-metamorphic zircon analyses give generally discordant ²⁰⁶Pb/²³⁸U versus ²⁰⁷Pb/²³⁵U ratios and maximum ²⁰⁷Pb/²⁰⁶Pb ages of 1438 Ma. These data demonstrate the existence of a protocrust of 1.7 to 2.0 Ga in the southwestern part of the Baltic Shield, implying a break in the overall westward younging trend of the Precambrian crust, inferred from the southeastern part of the Baltic Shield. Received: 8 April 1997 / Accepted: 14 July 1997     

扬子板块西南部古元古代岩浆及变质事件——兼论扬子板块对Nuna超大陆事件的响应

寻找扬子板块西南地区古老结晶基底一直是众多地质学者追寻的目标,其涉及扬子板块在Nuna超大陆重建中的位置和演化过程,也是前寒武纪研究的重要课题。继在扬子板块西南部中国云南石屏撮科村首次报道2.35Ga花岗片麻岩结晶基底后,又在撮科村—高家坡一带3个花岗岩样品中分别获得了2347.3±4.9Ma、2324.3±8.6Ma和2329.4±5.9Ma的SHRIMP锆石U-Pb年龄,进一步确认扬子板块西南部中国境内存在2.32～2.35Ga的岩浆事件,其应为Nuna超大陆汇聚期Arrowsmith造山事件在扬子板块的响应。另在1件糜棱岩化花岗闪长岩样品中获得了1909.8±5.7Ma和1843.1±7.6Ma两组年龄,在扬子板块西南部中国境内首次发现1.90Ga和1.84Ga的构造或变质事件。结合前人研究成果,确定扬子板块西南部存在2.91～2.84Ga,2.36～2.32Ga,2.28～2.19Ga的岩浆事件,以及1.97～1.95Ga,1.90Ga,1.84～1.83Ga的变质事件,为确定扬子板块在Nuna超大陆重建中的位置提供了更多证据。     

Zircon dating of North Bohemian granulites, Czech Republic: further evidence for the Lower Carboniferous high-pressure event in the Bohemian Massif

U-Pb zircon and rutile multigrain ages and ²⁰⁷Pb/²⁰⁶Pb zircon evaporation ages are reported from high-pressure felsic and metapelitic granulites from northern Bohemia, Czech Republic. The granulites, in contrast to those from other occurrences in the Bohemian Massif, do not show evidence of successive HT/MPLP overprints. Multigrain size fractions of nearly spherical, multifaceted, metamorphic zircons from three samples are slightly discordant and yield a U-Pb Concordia intercept age of 348 ± 10 Ma, whereas single zircon evaporation of two samples resulted in ²⁰⁷Pb/²⁰⁶Pb ages of 339 ± 1.5 and 339 ± 1.4 Ma, respectively. A rutile fraction from one sample has a U-Pb Concordia intercept age of 346 ± 14 Ma. All ages are identical, within error, and a mean age of 342 ± 5 Ma was adopted to reflect the peak of HP metamorphism. Because rutile has a lower closing temperature for the U-Pb isotopic system than zircon, the results and the P-T data imply rapid uplift and cooling after peak metamorphism. The above age is identical to ages for high-grade metamorphism reported from the southern Bohemian Massif and the Granulite Massif in Saxony. It can be speculated that all these granulites were part of the same lower crustal unit in early Carboniferous, being separated later due to crustal stacking and subsequent late Variscan orogenic collapse.     

南辽河群盖县组的重新厘定:来自辽南地区黄花甸-苏子沟一带变质砂岩碎屑锆石U-Pb年代学证据

传统认为辽河群顶部的盖县组广泛分布于辽南地区。本文对岫岩县黄花甸-苏子沟一带的南辽河群盖县组变质长石石英砂岩和变质石英砂岩进行了LA-ICP-MS碎屑锆石U-Pb年代学研究。其中变质长石石英砂岩中碎屑锆石普遍发育核-边结构,核部具有清晰的振荡环带;变质石英砂岩中碎屑锆石基本无核-边结构,具有清晰或者略模糊的振荡环带。锆石微量元素分析结果显示,具有振荡环带锆石微区具有轻稀土元素(LREE)亏损、重稀土元素(HREE)相对富集的配分曲线特征,Ce正异常和Eu负异常明显,Th/U和Zr/Hf比值较高,表明其岩浆成因。变质长石石英砂岩岩浆成因锆石微区~(207)Pb/~(206)Pb谐和年龄集中于2506～1748Ma之间,且呈现～2178Ma和～1863Ma两个年龄主峰,表明主要物质来源为同时期花岗质岩石(条痕状花岗岩和斑状花岗岩);变质石英砂岩岩浆成因锆石微区~(207)Pb/~(206)Pb谐和年龄集中于3546～1950Ma之间,呈现～2149Ma年龄主峰值,表明主要物质来源为条痕状花岗岩,另有少量太古宙基底物质的加入。研究区变质长石石英砂岩～1.86Ga的年龄峰值与辽河群其它变沉积岩明显不同,表明沉积时代一定晚于～1.86Ga,即形成于辽河群古元古代变质作用之后。综合研究区盖县组变质长石石英砂岩与辽河群其它变沉积岩碎屑锆石U-Pb年龄的差异,我们建议将盖县组部分变沉积岩从辽河群中解体出来。     

U-Pb and Pb-Pb ages of zircons from basaltic eucrites: Implications for early basaltic volcanism on the eucrite parent body

We have undertaken petrologic and SHRIMP U-Th-Pb isotopic studies on zircons from basaltic eucrites (Yamato [Y]-75011, Y-792510, Asuka [A]-881388, A-881467 and Padvarninkai) with different thermal and shock histories. Eucritic zircons are associated with ilmenite in most cases and have subhedral shapes in unmetamorphosed and metamorphosed eucrites. Some zircons in highly metamorphosed eucrites with granulitic texture occur alone in pyroxene, and typically have rounded to subrounded shapes due to recrystallization. Superchondritic Zr/Hf ratios of eucritic zircons indicate that they crystallized from incompatible element-rich melts after crystallization of ilmenite. Concentrations of uranium and thorium in zircons in the unmetamorphosed eucrite Y-75011 are higher than those in metamorphosed eucrites.The U-Pb systems of eucritic zircons are almost concordant but some zircon grains show reverse discordance. Radiogenic lead-loss up to 48% from zircons is observed in the shock-melted eucrite Padvarninkai. The ²⁰⁷Pb-²⁰⁶Pb ages of zircon in Y-75011 (4550 ± 9 Ma, n = 5) are nearly identical, within analytical uncertainty, to the ages of zircons from the metamorphosed eucrite Y-792510 (4545 ± 15 Ma, n = 13), the highly metamorphosed eucrites A-881388 (4555 ± 54 Ma, n = 5) and A-881467 (4558 ± 13 Ma, n = 8), and the shock-melted eucrite Padvarninkai (4555 ± 13 Ma, n = 18). The averaged ²⁰⁷Pb-²⁰⁶Pb age of zircon from five eucrites analyzed in this study is 4554 ± 7 Ma (95% confidence limits, n = 49), indistinguishable from the averaged U-Pb age (4552 ± 9 Ma) of the same samples. Because of the high closure temperature of lead in zircon (T_closure = ∼1050°C with a cooling rate of 0.2°C/yr), the ²⁰⁷Pb-²⁰⁶Pb ages of eucritic zircon do not represent metamorphic ages but crystallization ages of extrusive lavas.This fact strongly suggests that volcanism of the eucrite parent body occurred at a very early stage of the Solar System history, 7-20 Ma after CAI formation (4567.2 ± 0.6 Ma), thus basaltic eucrites crystallized from parental magmas within a short interval following the differentiation of their parent body. The U-Pb ages of eucritic zircons are older than the U-Pb, Sm-Nd and Rb-Sr ages of some basaltic eucrites, which is consistent with differences in closure temperatures of each isotopic system, and suggests that thermal and shock metamorphism affected the isotopic systems of pyroxene, plagioclase and phosphates.     

Paleoproterozoic metamorphism in the northern Fennoscandian Shield: age constraints revealed by monazite

ABSTRACT

We have identified two contrasting styles of Paleoproterozoic metamorphism in the northern part of the Fennoscandian Shield. The Karelia and Lapland-Kola Provinces, comprising Archean and overlying Paleoproterozoic supracrustal rocks, show a typical medium pressure Barrovian-style metamorphism with commonly found kyanite-bearing mineral assemblages and ITD (isothermal decompression) PT paths. In the juxtaposed Svecofennia Province metamorphism represents low pressure-high temperature Buchan style with garnet-cordierite migmatites and intercalated andalusite-cordierite and andalusite-staurolite schists and sillimanite-muscovite gneisses. The retrograde PT paths show only a moderate uplift during cooling.

U-Pb age determinations on monazite were made using the LA-ICP-MS from more than 80 samples from metasedimentary rocks. The sampling covered most parts of the Paleoproterozoic bedrock in Finland. The analyses reveal three peaks at c. 1.91 Ga, 1.86–1.88 Ga and at 1.79–1.81 Ga. The oldest, c. 1.91 Ga monazites are mostly found in the Lapland-Kola Province which is located in the northernmost Finland. In the Karelia Province where the Paleoproterozoic is underlain by Archean bedrock monazite yielded ages of 1.76?1.81 Ga with only a few older exceptions in samples showing a spread of ²⁰⁷Pb/²⁰⁶Pb ages from c. 1.92–1.81 Ga. The Karelia Province underwent tectonic thickening, where monazite ages of around 1.80 Ga mostly represent exhumation near the temperature maximum.

In the Svecofennia Province monazite ages vary from c. 1.89 to 1.78 Ga. In the Western Finland Subprovince the monazite ages in high-grade migmatites are mostly 1.86?1.88 Ga but within the older migmatite areas there are lower grade zones where monazite yields ages of c. 1.80 Ga. Some samples also show a spread of ²⁰⁷Pb/²⁰⁶Pb ages from 1.89?1.86 Ga to c. 1.78 Ga. In the Southern Finland Subprovince most ages are either 1.80?1.78 Ga, especially in the andalusite grade schists, or the sample shows a spread of ²⁰⁷Pb/²⁰⁶Pb ages from c. 1.88 to 1.78 Ga. Only in the eastern part of the Southern Finland Subprovince there are rocks which yield merely 1.86?1.89 Ga ages. Low pressure-high temperature metamorphism and lack of high or medium P/T rocks in the Svecofennia Province refers rather to accretionary than collisional processes.     

Metamorphic evolution of the Sesia-Lanzo Zone,Western Alps: time constraints from multi-system geochronology

 The Sesia-Lanzo Zone is a polymetamorphic unit containing Hercynian granulite relics overprinted by eclogite and greenschist facies metamorphism and deformation during the Alpine orogeny. Different parts of the unit record different stages on the P-T-deformation evolution, allowing multi-system isotopic studies to unravel the precise timing of the metamorphic history. New Rb–Sr white mica and U–Pb sphene data constrain the age of eclogite facies metamorphism and deformation to 60–70 Ma. This substantially alters the common view of early- to mid-Cretaceous eclogite facies metamorphism in this unit. The new results are more consistent with the established geotectonic framework for the Alpine orogeny, since they do not require a prolonged period of depressed geothermal gradient at a time when the region was in extension. It is also more concordant with recent studies of other units that demonstrate post-Cretaceous high-pressure metamorphism. Step-heated ⁴⁰Ar–³⁹Ar analysis of phengites yields good plateaux giving ages older than the corresponding Rb–Sr age. Such anomalously high ages indicate the presence of radiogenic argon-rich fluids in the grain boundary network under the fluid/pressure conditions acting during this high-pressure metamorphic event. The U–Pb sphene ages are variable in polymetamorphic rocks, and show inheritance of older Pb or sphene crystals into the high-pressure event. Two monometamorphic assemblages yield concordant ages at 66±1 Ma, reflecting crystallisation of the eclogite facies assemblage. The Gneiss Minuti Complex (GMC) lies structurally below the Eclogitic Micaschists, and its pervasive greenschist facies fabric yields tightly clustered Rb–Sr white mica ages at 38–39 Ma. This greenschist event did not affect the majority of the EMC. The ⁴⁰Ar–³⁹Ar ages of micas formed at this time were very disturbed, whereas micas surviving from an earlier higher pressure assemblage had their ⁴⁰Ar–³⁹Ar system reset. The greenschist event did not strongly affect U–Pb systematics in Hercynian age sphenes, suggesting that the GMC did not uniformly suffer an eclogite facies metamorphism during the Alpine cycle, but was juxtaposed against the EMC later in the orogeny. This model still requires that the locus of deformation and metamorphism (and possibly fluid flux) moved outboard with time, leaving the Sesia-Lanzo basement as a shear-bounded unreactive block within the orogenic wedge. Received: 12 October 1995/Accepted:25 June 1996     

U-Pb systematics of garnet: dating the growth of garnet in the late Archean Pikwitonei granulite domain at Cauchon and Natawahunan Lakes,Manitoba, Canada

This study considers the potential of using the U-Pb dating of garnet for determining quantitative P-T-t paths for the late Archean metamorphism in the Pikwitonei granulite domain. Garnets for U-Pb dating were selected mainly from samples that also provide information on pressure and temperature. The garnets used for dating were clear and free of any visible inclusions. Pb concentrations range from 63 ppb to 966 ppb and U from 136 ppb to 1143 ppb. The measured ²⁰⁶Pb/²⁰⁴Pb ratios range from 52.8 to 529.4. The ages are generally discordant with U/Pb ages that may lie above or below concordia. The discordance is caused by a recent disturbance of the U/Pb ratio in the garnets as indicated by replicate analyses on the same garnet separates that reproduce ²⁰⁷Pb/²⁰⁶Pb ages well within analytical uncertainty and in most cases within ±1.5 Ma at 2600–2750 Ma. High grade metamorphism continued over a period of at least one hundred million years, but the garnet-K-feldspar Pb-Pb ages suggest that, during this time, garnet growth has been favored during three distinct periods in the Cauchon Lake area: 2700–2687 Ma 2660–2637 Ma 2605–2591 Ma The ca. 2695 Ma garnet ages from Cauchon Lake date the time of melting and staurolite breakdown during prograde metamorphism, the ca. 2640 Ma ages date the time of extensive migmatization and the last period of metamorphic garnet growth, the ca. 2600 Ma ages date the time of crystallization of igneous garnet in late granitic intrusions. Peak metamorphism occurred around 2640 Ma followed by the intrusions of pegmatites starting at 2629 Ma. The Pb-Pb ages for garnet are similar to the U-Pb ages for zircon that date a leucocratic mobilizate (2695 Ma), a plagioclaseamphibole mobilizate (2637 Ma) and pegmatite (2598 Ma) (Heaman et al. 1986 a; Krogh et al. 1986; this study). Xenocrysts of garnet from 2600 Ma old graphic granites give minimum ages of 2984 Ma and 2741 Ma which are minima for the times of garnet growth in the source of the granites. The agreement of the zircon and garnet ages suggests that the metamorphism may have been punctuated by events that led to the development of melts or encouraged mineral growth at specific times. If so, the prograde and retrograde paths of metamorphism in the area may have contained minor excursions in pressure, temperature or fluid fugacities. In the Natawahunan Lake area some 50 km northwest of Cauchon Lake, garnet growth associated with the prograde breakdown of staurolite occurred at ca. 2744–2734 Ma. This suggests that a similar style of metamorphism may have occurred earlier in the Natawahunan Lake area than at Cauchon Lake area, or higher grades of metamorphism were reached earlier and were of longer duration associated with the somewhat greater depths in the Natawahunan Lake area. These results indicate the these garnets, which are 0.1–1 cm in diameter, have maintained closed system behavior for U and Pb at peak metamorphic conditions, i.e. temperatures up to 800° C and pressures of 7.5 kb.     

Geochronology and geochemistry of multiple generations of monazite from the Wepawaug Schist,Connecticut, USA: implications for monazite stability in metamorphic rocks

 U-Pb isotope analyses, rare earth and trace element analyses, and petrographic observations are presented for monazites from the Wepawaug Schist in southern Connecticut, USA. Two samples of kyanite zone schist were collected less than a meter apart. Each sample contains a different variety of monazite with distinct morphology, chemistry, and Pb isotopic composition. One sample preserves a largely amphibolite facies mineralogy, including kyanite, staurolite, garnet, biotite, and chlorite, with little textural evidence of later shearing. Monazites from this sample are xenoblastic with about 1 wt% ThO₂, 0.3 wt% CaO, and a more LREE enriched pattern than monazites from the second sample. These xenoblastic monazites preserve textural evidence of a retrograde reaction to apatite which involves chlorite, indicating that these monazites became unstable during retrograde chloritization of biotite. These monazites give strongly discordant U-Pb ages which fit a chord with an upper intercept age of 411±18 Ma, interpreted as the minimum growth age of these xenoblastic monazites, perhaps during amphibolite facies metamorphism. The second sample contains S-C banding, evidence of dynamic recrystallization, and abundant retrograde chlorite. This sample contains idioblastic monazites with about 3 wt% ThO₂, 0.8 wt% CaO, and with less fractionated REE patterns. These monazites give close to concordant U-Pb ages with a mean ²⁰⁷Pb*/²⁰⁶Pb* age of 388 ± 2 Ma. This age is interpreted as probably representing the time of monazite growth during retrogression of the sample from an amphibolite to greenschist facies mineralogy. Received: 26 June 1995/Accepted: 25 May 1996     

华北克拉通古元古代晚期地壳演化和荆山群形成时代制约——胶东地区变质中-基性侵入岩锆石SHRIMP U-Pb定年

胶东地区的荆山群呈近东西向环绕太古宙TTG花岗质片麻岩展布,主要由成熟度高的含石墨变泥砂质岩石、钙硅酸岩和大理岩组成,变质程度达高角闪岩相-麻粒岩相,具孔兹岩系性质。变质中-基性岩侵入到荆山群。它们的侵位时代对于探讨华北克拉通东部元古宙构造演化以及对荆山群沉积时代的制约,都有重要意义。锆石SHRIMP U-Pb定年结果表明,遭受低级变质的闪长岩(S0835)岩浆锆石年龄为1852±9Ma (MSWD=2.1),遭受中高级变质的辉长岩(S0816)变质锆石年龄为1865±11Ma (MSWD=0.76)。结合区域资料,可得出如下结论:(1)荆山群孔兹岩系形成于古元古代晚期(2.2~1.9Ga);(2)古元古代期间,胶东地区从挤压体制转入伸展体制的时间在1.87Ga之前。在华北克拉通中西部的恒山、大青山地区,存在1.97~1.92Ga辉长岩,在1.92~1.83Ga期间发生变质,与本文研究结果类似。这表明华北克拉通中-西部和东部具有类似的古元古代演化历史。     

内蒙古北山地区盘陀山一带长城纪古硐井群碎屑锆石LA-ICP-MS U-Pb年龄及其地质意义

长城纪古硐井群作为内蒙古北山地区古老褶皱基底之上的第一个沉积盖层,尚未获得可靠的年龄资料,前人只是根据其产出的层位和岩石组合特征与燕山地区的长城系对比后,将其置于中元古代长城纪。对古硐井群变质长石石英砂岩中碎屑锆石进行了LA-ICP-MS U-Pb测年,结果显示,锆石~(207)Pb/~(206)Pb年龄数据90%介于1.3~2.2Ga之间,其余年龄介于2.4~3.2Ga之间,峰期在1.6~2.0Ga之间,最年轻的碎屑锆石~(207)Pb/~(206)Pb年龄为1393±50Ma。通过对比碎屑锆石的年龄频谱和周围古地块的形成时代,碎屑锆石的U-Pb年龄限制了古硐井群的沉积时代,应为中元古代蓟县纪,古硐井群的沉积物可能来自北山-阿拉善和塔里木-敦煌地块。     

Metallogeny and lead isotopic composition of base metal sulfide deposits in the Rappen area,northern Sweden

Early Proterozoic volcanic and sedimentary rocks of the Rappen district in northern Sweden were deposited at a destructive plate margin to the south of the Archaean craton of the western Baltic Shield. The volcano-sedimentary suite was intruded by two generations of early Proterozoic granites at ca. 1.89–1.85 Ga and ca.1.82–1.78 Ga, respectively, and metamorphosed at upper amphibolite facies conditions. Small stratabound iron, copper, and zinc deposits occur in felsic to mafic tuffs and arkosic sediments. Small deposits of molybdenum, tungsten, and uranium formed during the emplacement of the younger granites. The lead isotopic compositions of sulfide trace lead from the various deposits are highly heterogeneous. In the ²⁰⁶Pb/²⁰⁴Pb–²⁰⁷Pb/²⁰⁴Pb diagram they fall on mixing arrays between little evolved early Proterozoic lead and highly radiogenic Caledonian lead. The least radiogenic lead isotopic compositions from the various deposits have a wide range of ²⁰⁷Pb/²⁰⁴Pb ratios and thus indicate variable involvement of Archaean crustal lead in the Proterozoic deposits. Deposits hosted by siliciclastic rocks have higher ²⁰⁷Pb/²⁰⁴Pb ratios than deposits hosted in mafic to felsic tuffites. The lead isotopic heterogeneity suggests that the lead in the various deposits was locally derived and, furthermore, that the sedimentary rocks in part originated from the Archaean craton to the north. Lead mixing arrays in the ²⁰⁶Pb/²⁰⁴Pb–²⁰⁷Pb/²⁰⁴Pb diagram demonstrate that in Paleozoic time radiogenic lead was mobilized and transported in the basement. Source ages calculated from the mixing arrays (ca.1.9 Ga and ca.1.8 Ga) correspond to the age of the Early Proterozoic volcanism and metamorphism respectively. One group of deposits includes lead from at least three sources and illustrates that radiogenic lead was multiply mobilized and transported in the Proterozoic basement. It occurs in deposits that occur in zones that became permeable during the reactivations of the basement.     

The origin of geochemical diversity of lunar mantle sources inferred from the combined U-Pb, Rb-Sr, and Sm-Nd isotope systematics of mare basalt 10017

The results of our combined U-Pb, Rb-Sr, and Sm-Nd isotope study of mare basalt 10017 contribute to the understanding of the petrogenetic processes involved in the origin of geochemical diversity in lunar mare basalt sources, as well as the U-Pb isotope systematics of the Moon. The Rb-Sr, Sm-Nd, and ²³⁸U-²⁰⁶Pb isotope systems yield concordant crystallization ages of 3.633 ± 0.057 Ga, 3.678 ± 0.069 Ga, and 3.616 ± 0.098 Ga, respectively. The ²³⁵U-²⁰⁷Pb isochron yields an older, though still concordant, age of 3.80 ± 0.12 Ga. Neither the ²⁰⁶Pb-²⁰⁷Pb system nor U-Pb concordia system yields an age for 10017 that is concordant with the age determined from the Sm-Nd, Rb-Sr, and ²³⁸U-²⁰⁶Pb systems. The initial ⁸⁷Sr/⁸⁶Sr of 10017 is 0.69941 ± 7 and the initial ε_Nd is +3.2 ± 0.4. Initial Pb isotopic compositions, determined from the U-Pb isochrons, are ²⁰⁶Pb/²⁰⁴Pb_i = 31 ± 11 and ²⁰⁷Pb/²⁰⁴Pb_i = 34 ± 15. Together, these initial Pb compositions constrain the μ value of the 10017 source to be 70 ± 30, assuming a single-stage Pb growth model. This is considerably lower than μ values typically estimated for mare basalt sources (∼100-600). Regardless, the μ values calculated for the sources of mare basalts, as well as other lunar samples, show a range that is larger than can be explained by fractionation of U from Pb solely by crystallization of silicate phases and ilmenite during magma ocean solidification and formation of lunar mantle sources. The U-Pb isotope systematics may reflect late-stage formation of a sulfide phase, which strongly fractionates Pb from U but has minimal effect on Rb/Sr or Sm/Nd compositions, during crystallization of the lunar magma ocean.     

Geochemistry and genesis of the Lengenbach Pb-Zn-As-Tl-Ba-mineralisation,Binn Valley,Switzerland

 The Lengenbach Pb-Zn-As-Tl-Ba mineralisation is located in Triassic dolostones of the Penninic zone in the Swiss Alps where Alpine metamorphism reached upper greenschist to lower amphibolite grade. Geochemical data are used to constrain the origin of this unique occurrence. Two metamorphic redox environments are present: the As(III)-rich zone is controlled by barite-pyrite while the reduced zone contains graphite or pyrrhotite-pyrite and formally zerovalent As. The As(III)-rich zone is characterised by a mineral assemblage consistent with fO₂ in the stability field of barite+pyrite. An As-(Pb, Tl)-rich sulphide melt coexisted with a hydrothermal fluid at >kk300 °C in this zone. Mineralised dolostones are anomalous in As, Pb, Ag, Tl, Hg, Zn, Ba, Cd, Fe, Cu, Mo, U, V, B, Ga, Cr and possibly Sn and Au (in order of decreasing enrichment). As, Pb and Zn are present in the 0.1 to 1% range, Tl and Ag reach several hundred ppm. Uraninite is concentrated in silicate-rich bands and yields a late Alpine U-Pb age of 18.5±0.5 Ma. Pb- and S isotopic variations are interpreted by metamorphic overprinting and re-equilibration within an isochemically metamorphosed mineralisation. Hydrothermal sulphides are more strongly affected by uranogenic Pb than massive Pb-As-sulphides representing a former sulphide melt. The least overprinted mineralisation is characterised by ²⁰⁶Pb/²⁰⁴Pb U003U=18.44−18.56, ²⁰⁷Pb/²⁰⁴Pb=15.60−15.75, ²⁰⁸Pb/²⁰⁴Pb =38.44−38.84 and δ³⁴S (sulphide)=−25±2‰. S isotopic variations are largely a result of sulphide-sulphate re-equilibration yielding temperatures of 450± 30 °C. ⁸⁷Sr/⁸⁶Sr ratios of mineralised samples are lower than or equal to host dolostones, precluding major infiltration of basement-derived fluids during Alpine metamorphism. The Sr source (⁸⁷Sr/⁸⁶Sr close to 0.708) probably was seawater with a radiogenic, detrital mineral component. The genesis of the unique Lengenbach mineralisation is interpreted as the result of isochemical metamorphic overprinting of a carbonate hosted stratiform sulphide mineralisation. Well-crystallised sulphide minerals in fissures and druses formed during retrograde cooling of a sulphide melt in equilibrium with a hydrothermal fluid. The primary mineralisation was probably formed at or close below the sea floor and fed by sulphide-poor hydrothermal fluids. Sulphide was largely derived from seawater by open system bacterial sulphate reduction. U, V and Mo may be seawater-derived. Received: 1 February 1995/Accepted: 10 January 1996     

胶北太古宙早期锆石U-Pb定年及Hf同位素研究：华北克拉通古老陆壳增生及再循环的证据

古老陆壳物质的发现与鉴别是探索地球早期陆壳形成与演化历史的重要内容之一,锆石U-Pb年龄结合Hf同位素研究是该研究的重要手段。本文通过对胶北地体内一个长英质副片麻岩中的锆石开展系统的原位U-Pb定年和微量、稀土元素分析,获得了多个太古宙早期的锆石。根据这些锆石的阴极发光图像、Th/U比值及稀土元素球粒陨石标准化配分模式,它们具有典型岩浆锆石的特征,其中2个分析点给出了3413Ma和3400Ma(~3.4Ga)的锆石U-Pb年龄,7个分析点给出3547±19Ma(MSWD=1.16)的锆石U-Pb年龄,指示太古宙早期的陆壳岩浆事件;结合华北克拉通其它地区的类似研究结果,暗示华北克拉通可能曾经存在比现今出露面积更大的太古宙早期的古老陆壳。这些古老锆石的Hf同位素分析显示,它们的εHf(t)值在-6.19~0.95之间,平均为-2.54,两阶段Hf模式年龄在3737~4353Ma之间,平均值为~4.1Ga,远大于锆石的U-Pb年龄,指示华北克拉通存在~4.1Ga的地壳增生作用及古老陆壳(3.55Ga)的再循环。     

湘南尖峰岭岩体锆石U-Pb年龄、地球化学特征及成因

香花岭锡多金属矿田处于南岭西段中_晚侏罗世形成的花山_西山_香花岭_骑田岭NE向的富碱侵入岩带上,是湘南地区矿化类型最为完整的锡矿区。尖峰岭岩体为矿田内主要的成矿母岩之一。为了进一步明确尖峰岭黑云母花岗岩的岩石成因及成岩年龄,笔者对尖峰岭黑云母花岗岩开展了LA_ICP_MS锆石U_Pb测年及岩石地球化学特征分析。锆石LA_ICP_MS U_Pb测年获得206Pb/238U年龄介于(158.6±2.3)Ma~(164.8±4.5)Ma之间,加权平均年龄为(160.7±2.2)Ma(MSWD=0.8),这与香花岭锡多金属矿田的成矿时限(154~161 Ma)相吻合,表明岩体的侵位与区内多金属成矿作用均发生于中_晚侏罗世。尖峰岭岩体的主量、微量元素研究显示,尖峰岭黑云母花岗岩具有富硅、富碱及成矿元素,富LILE及Zr、Ga等部分高场强元素(HFSE),贫Ca、Mg、P、Eu特征,指示尖峰岭黑云母花岗岩属于过铝质A型花岗岩(A2型)。综合研究表明,尖峰岭黑云母花岗岩体与其周缘钨锡多金属矿床在时间、空间及成因上有密切关系。结合区域上已有的同位素年代学数据,香花岭矿区的成岩成矿作用与南岭西段同时代的其他钨锡多金属矿床形成于同一岩石圈伸展的地球动力学背景下。     

Geochemical and petrological aspects of dike intrusions in the Lycian ophiolites (SW Turkey): a case study for the dike emplacement along the Tauride Belt Ophiolites

Lycian ophiolites located in the Western Taurides, are cut at all structural levels by dolerite and gabbro dikes. The dolerite dikes from this area are both pristine and metamorphosed. The non-metamorphosed dikes are observed both in the peridotites and in the metamorphic sole rocks. Accordingly, the non-metamorphosed dikes cutting the metamorphic sole were generated after cooling of the metamorphic sole rocks. The metamorphosed dolerite dikes are only observed in the peridotites. The physical conditions and timing of the metamorphism for the metamorphosed dolerite dikes are similar to those of the metamorphic sole rocks of the Lycian ophiolites suggesting that the metamorphosed dolerite dikes were metamorphosed together with the metamorphic sole rocks. Therefore, the dike injections in the western part of the Tauride Belt Ophiolites occurred before and after the generation of the metamorphic sole rocks. All metamorphosed and non-metamorphosed dikes are considered to have the same origin and all of them are subduction-related as inferred from whole-rock geochemistry and lead isotopes. Lead isotope compositions of whole rocks of both dike groups cluster in a narrow field in conventional Pb isotope diagrams (²⁰⁶Pb/²⁰⁴Pb = 18.40–18.64; ²⁰⁷Pb/²⁰⁴Pb = 15.56–15.58; ²⁰⁸Pb/²⁰⁴Pb = 38.23–38.56) indicating a derivation from an isotopically homogeneous source. On the ²⁰⁷Pb/²⁰⁴Pb versus ²⁰⁶Pb/²⁰⁴Pb diagram, isotope compositions of the dikes plot slightly below the orogen curve suggesting contributions from mantle reservoir enriched by subducted oceanic lithosphere. Such a signature is typical of island arc magmatic rocks and supports the formation of the investigated rocks in a subduction-related environment.     

粤北长江铀矿田花岗岩独居石U-Pb同位素定年及其地质意义

长江铀矿田位于诸广山复式岩体中南部,是典型的花岗岩型铀矿田.前人采用锆石U-Pb定年方法对赋矿花岗岩进行了年代学研究,但由于全岩和锆石铀含量较高,锆石往往发生了蜕晶化,可能导致锆石U-Pb定年数据散乱,影响锆石U-Pb年龄的可靠性.独居石是花岗岩中广泛存在的含铀副矿物,铀和钍含量均较高,可达10000×10-6,普通铅...     

Eclogites of the Snowbird tectonic zone: petrological and U-Pb geochronological evidence for Paleoproterozoic high-pressure metamorphism in the western Canadian Shield

Eclogite occurs within the southern domain of the East Athabasca mylonite triangle in northern Saskatchewan. Situated at the boundary between the Archean Rae and Hearne Provinces of the western Canadian Shield, the East Athabasca mylonite triangle is a fundamental exposure of the ~3,000-km-long Snowbird tectonic zone. The eclogite occurs in association with a variety of lower crustal high-pressure granulites that record a complex metamorphic history from 2.6 to 1.9 Ga. Temperatures of the eclogite facies metamorphism are constrained by garnet-clinopyroxene exchange thermometry at 920–1,000 °C. Minimum pressure conditions are recorded by the jadeite+quartz=albite geobarometer at 1.8–2.0 GPa. A near-isothermal decompression path to granulite facies conditions is inferred from retrograde reaction textures involving the formation of granulite facies assemblages such as orthopyroxene-plagioclase and pargasite-plagioclase. U-Pb IDTIMS zircon geochronology of the eclogite yields a weighted mean ²⁰⁷Pb/²⁰⁶Pb date of 1,904.0±0.3 Ma, which we interpret as the time of peak eclogite facies metamorphism. SHRIMP in situ analyses of metamorphic zircons included within omphacitic clinopyroxene support this interpretation with a weighted mean ²⁰⁷Pb/²⁰⁶Pb date of 1,905±19 Ma. Inclusion suites of high-pressure phases and the petrographic setting of zircon are a direct link between zircon growth and eclogite facies metamorphism. Zircon from one eclogite sample has older cores that are 2.54 Ga, which is a minimum age for the emplacement or earliest metamorphism of the gabbroic protolith. U-Pb rutile data indicate slow cooling at ~1°C/Ma below ~500 °C from 1.88 to 1.85 Ga. The formation and exhumation of the eclogites at ca.1.9 Ga has important implications for the tectonic significance of the Snowbird tectonic zone during the Paleoproterozoic. The eclogites described here are consistent with transport of continental crust to mantle depths during the Paleoproterozoic, followed by rapid buoyancy-driven exhumation to normal lower crustal depths.Editorial responsibility: T.L. Grove     

北大别黄土岭长英质麻粒岩的原岩、变质作用及源区热事件年龄的锆石LA-ICPMS U-Pb测年约束

本研究应用激光剥蚀技术测定了北大别黄土岭高温-高压长英质麻粒岩锆石3个结构域的U-Pb年龄.变质锆石成因的碎屑锆石域的207Pb/206Pb年龄范围为(2493±54) Ma~(2500±180) Ma, 岩浆成因的碎屑锆石域的207Pb/206Pb年龄范围为2628~2690Ma, 其最大的206Pb/238U年龄为(2790±150) Ma, 变质增生或变质重结晶锆石域的不一致线上交点年龄为(2044.7±29.3) Ma.长英质麻粒岩的矿物组合成分、主量元素地球化学, 尤其是锆石副矿物内部结构特征显示其原岩为沉积岩.这表明, 麻粒岩原岩物质来自具有复杂热历史的蚀源区, 该蚀源区曾发生过~2.8Ga的岩浆作用和~2.5Ga变质作用, 因此其原岩的沉积年龄不应早于2.5Ga.高温-高压麻粒岩相变质作用的精确年龄为(2.04±0.03) Ga, 表明黄土岭麻粒岩是一个晚古元古代超高温变质岩之残块.