与溢流性玄武岩有关的铜镍硫化物矿床地质地球学特征与成矿潜力分析——以广西罗城县清明山铜镍硫化物矿床为例

广西罗城县清明山铜镍硫化物矿床,镁铁质-超镁铁侵入岩与玄武岩广泛分布,时空关系密切,两者岩石化学成分丰度相同,均具有富MgO、贫SiO2、TiO2、K2O的特征,微量元素、稀土特征相同,具有成因上的联系和有先后演化的特征。含矿镁铁质岩体岩石化学成分SiO2含量为42.68～50.63%,K2O含量0.052～2.54%,TiO2含量0.326～0.63%;微量元素Rb,Ba富集,Ta、Nb亏损的特征,稀土元素含量中等ΣREE=27.56～52.36(10-6),ΣLREE/ΣHREE=7.17～12.31,(La/Yb)N=2.48～8.17,δEu=0.93～1.43,轻稀土富集,配分曲线右倾,无δEu负异常;硫同位素δ34S值4.52～17.04‰。镁铁质-超镁铁岩和铜镍硫化矿主要物质来源于幔源,有壳源混染;地质特征、地球化学特征等与美国Duluth铜镍硫化物矿床特征相同,为国内一种新的与溢流玄岩有关的岩浆铜镍硫化物矿床,资源潜力巨大。     

中国西北地区岩浆铜镍矿床地质特点与找矿潜力

西北地区是中国岩浆铜镍硫化物矿床最为发育的地区,主要有3个重要成矿期,其地质特点、成矿条件、形成标志等存在明显不同.笔者梳理了 目前诸多学者对岩浆铜镍硫化物矿床的研究工作,并结合野外实际,发现大陆裂谷是形成巨型-超大型岩浆铜镍硫化物矿床的构造背景条件,铁质系列的镁铁-超镁铁质岩体才可能形成有经济价值的岩浆铜镍硫化物矿体...     

金平镁铁质-超镁铁质岩铜镍矿床成矿条件

按构造环境控岩控矿特点,划分区内铜镍型成矿（岩）带,分析成矿条件,研究与该类矿床成矿有关的镁铁质岩、超镁铁质岩分布规律及铜镍硫化物成矿特征,指出找矿方向和建议。     

内蒙古中部镁铁质-超镁铁质岩带铜镍成矿潜力探讨

华北陆块北缘是中国铜镍(铂)硫化物矿床的重要成矿区带之一.近年来,在位于该成矿带的内蒙古中部先后发现多处铜镍矿床(点),空间上构成一条重要的镁铁质-超镁铁质岩成矿带.为了探讨该镁铁质-超镁铁质岩带内额布图、温更、克布、黄花滩及小南山等赋矿岩体的成矿潜力,笔者通过搜集和研究国内外典型铜镍硫化物矿床数据,建立有利成矿信息评...     

四川力马河镁铁-超镁铁质岩体的地球化学特征及成岩成矿分析

四川会理力马河镍矿是峨眉山大火成岩省最重要的岩浆硫化物矿床之一,成矿岩体为一小型锾铁-超镁铁岩侵入体,由含斜长石的超镁铁岩(包括舍长辉石橄榄岩和斜长橄榄辉石岩)和辉长岩类的镬铁质岩组成.矿床富含硫化物,成矿元素组合为铜、镍,铂族元素含量很低,没有铂族元素的工业富集,是蛾眉山大火成岩省中富铜镍贫铂族元素的代表性岩浆硫化物矿床.本文对力马河镍矿成矿岩体的镁铁、超镁铁岩及矿床中各种硫化物矿石进行了主量元素、微量元素及铂族元素含量分析.分析结果表明,力马河岩体的镁铁、超镁铁岩属拉斑玄武岩成因系列,岩石特征微量元素比值大致与高钛的峨眉山玄武岩相当、与低钛的峨眉山玄武岩有明显区分,但估计原始岩浆强不相容微量元素绝对含量大大低于高钛玄武岩,因此,其成矿岩体不是与一般的低钛或高钛峨眉山玄武岩(不包括苦橄岩在内)直接对应的深成相.岩体超镁铁岩及矿石铂族元素组成特征表现为无钌亏损的型式,钯/铱比值较小、在5左右,也显著不同于一般的峨眉山玄武岩,而类似于峨眉山大火成岩省苦橄岩的铂族元素组成.运用岩石地球化学研究方法计算,原始岩浆为苦橄质成分:MgO含量约17%、SiO2含量约48%.估计原始岩浆形成于130公里左右的深度,由类似于洋岛玄武岩岩浆源区成分的地幔经19%左右的部分熔融形成.超镁铁岩及硫化物矿石铂族元素含量一般在10-9～10-8暑级,铂族元素相对铜镍强烈亏损,铜/钯比值高于原始地幔10～100倍,铜镍铂族元素组成的原始地幔标准化曲线呈铂族元素显著亏损的“U“型.模式分析说明,导致铂族元素亏损的原因是岩浆成矿演化过程中多阶段硫化物熔离作用造成的,早期熔离出来的硫化物被丢失并造成岩浆中铂族元素亏损,其铂族元素亏损后的岩浆(第)二次硫化物熔离富集形成铂族元素亏损的矿石.     

中国岩浆铜镍矿床的形成特点与找矿方向

与幔源镁铁-超镁铁质岩浆密切相关的铜镍硫化物矿床,因深部地幔动力学机制不同在地球表壳的分布极不均衡。中国岩浆铜镍硫化物矿床分布不均匀,主要产出于板块内部或其边缘。为认识中国铜镍矿床的形成特点,进一步明确找矿方向,通过综合分析已有典型岩浆铜镍硫化物矿床,发现该类矿床基本形成于新元古代晚期、早古生代晚期及晚古生代晚期,且均无一例外地就位于板块内部或其边缘的造山带中,是硫化物熔离后的岩浆多期侵位的结果。通过系统研究岩浆铜镍矿床深部过程及地质、物探、化探、遥感有利成矿信息,结合找矿突破的最新勘查进展,指出中国西北部是岩浆铜镍硫化物矿床的重要成矿潜力地区,稳定地块边缘仍是主要的找矿方向。     

新疆北部岩浆铜镍硫化物矿床地质分布特点与成矿背景探讨

新疆北部地质构造演化复杂, 多阶段演化中岩浆活动与成矿作用规模并不均衡。而二叠纪却是天山成矿带大规模岩浆活动和金属成矿作用的高爆发期。本研究紧紧围绕镁铁-超镁铁质侵入岩体及岩浆铜镍硫化物矿床, 从地质分布特点、含矿岩体的岩浆起源、岩浆演化及成矿特点, 系统研究深部相应岩浆作用的地质背景。通过典型矿床的深入剖析, 破解制约找矿突破的控制因素, 系统阐述了板块构造与地幔柱体制叠加并存的地质特征与成矿表现。新疆北部发育了5条镁铁-超镁铁质侵入岩带, 东天山、北山及喀拉通克岩带具有较好的成矿表现, 在时间上与塔里木隐伏大火成岩省密切相关。塔里木克拉通深部熔融的地幔物质, 围绕刚性塔里木克拉通边缘不断上涌, 并与表壳物质发生交换, 随着俯冲板块的持续和减弱, 深部上涌的地幔物质不断加强, 先后形成因深部地幔物质多寡而金属聚集的不同矿床类型。围绕塔里木大火成岩省的周缘或造山带中, 是岩浆铜镍硫化物矿床重要的理论研究基地和找矿方向。     

新疆北部镁铁-超镁铁质岩的PGE成矿问题

铂族元素(PGE)矿化主要与镁铁-超镁铁杂岩有关,成矿类型主要为岩浆型矿床,这类PGE矿床的形成主要依赖两个条件:一是岩浆中富含PGE;二是具备PGE从岩浆中分离和富集的机制,主要是在岩浆演化过程中硫达到饱和。新疆北部镁铁-超镁铁质杂岩发育,并产有喀拉通克、黄山、黄山东、图拉尔根4个大型铜镍矿床和香山、土墩、葫芦、白石泉等中、小型铜镍矿,以及香山西、尾亚等中型钒钛磁铁矿矿床,但迄今尚未发现成型的PGE矿床。文中通过对PGE矿床的形成机制与镁铁-超镁铁杂岩源区特征研究,探讨了北疆地区PGE矿床的成矿问题。综合分析认为,新疆北部后碰撞镁铁-超镁铁质岩的岩石类型为经过了分离结晶形成的铁质岩石系列,是PGE矿床的有利容矿岩石;矿床的Sr、Nd、Pb、O、Os和S同位素和含矿岩石地球化学特征表明,铜镍硫化物矿床含矿岩浆在岩浆演化和成矿过程中有地壳物质加入并可导致硫化物熔离作用,说明在成矿机制上也存在形成岩浆型PGE矿化的条件。新疆北部PGE矿化微弱的原因可能在于该区广泛发育的亏损型地幔源(具正的εNd值特征),这一亏损型地幔可能部分源于洋壳熔融,与产于后碰撞造山带环境、发育于"洋壳"或"不成熟"陆壳基底之上有关,由此决定了原始岩浆为贫PGE的源区,因此不利于PGE的富集成矿。     

内蒙古中部克布铜镍硫化物矿床岩石成因与成矿过程

内蒙古中部地区横跨中亚造山带与华北克拉通北缘, 区内岩浆铜镍硫化物矿床(点)广泛发育。克布矿床位于该区白云鄂博裂谷西南侧, 是近年来新发现的品位较高的铜镍化物矿床。因此, 准确厘定克布镁铁-超镁铁质岩体的形成时代, 查明岩石成因与矿床成矿过程对于进一步指导克布矿床深部铜镍找矿突破以及区域类似镁铁-超镁铁质岩体含矿性评价具有重要意义。克布岩体主要岩相由主体辉长岩相与赋矿橄榄岩相组成, 其中辉长岩相属于主体岩相而橄榄岩相则是主要赋矿岩相。岩石地球化学分析结果表明, 克布镁铁-超镁铁质岩体各岩相具有轻稀土富集、重稀土亏损的右倾型稀土配分模式, 富集Rb、Sr和Ba等元素, 亏损Nb和Ta等元素。本次研究获得克布岩体橄榄辉长岩的LA-ICP-MS锆石U-Pb年龄为267.5±1.8Ma, 为中二叠世岩浆作用的产物, 形成于古亚洲洋闭合后的碰撞后伸展环境。同位素组成研究结果表明, 克布岩体锆石ε_Hf(t)值为-4.67~2.84, (⁸⁷Sr/⁸⁶Sr)_i值为0.7062~0.7071, ε_Nd(t)值为为-10.6~-5.65。铂族元素(PGE)组成研究结果表明, 克布铜镍硫化物矿床矿石具有相对较低的Ni/Cu值, 较高的Pd/Ir值和Cu/Pd值。综合上述研究结果, 初步查明克布镁铁-超镁铁质岩体形成于古亚洲洋闭合的碰撞后伸展环境, 岩浆源区为经历了俯冲交代作用的EM Ⅰ型岩石圈地幔, 原生岩浆主要为高镁玄武质岩浆。在幔源岩浆侵位过程中经历了一定程度的地壳物质混染, 其中地壳硫的加入是促进克布镁铁-超镁铁质岩浆发生硫化物熔离并最终富集成矿的关键因素。结合最新探矿工程控制情况, 本文认为克布矿床深部铜镍成矿潜力较高, 应将晚期超镁铁质岩及深部岩浆通道作为下一步找矿工作重点。

     

内蒙古镁铁质-超镁铁质岩型铜镍矿床成矿条件与找矿远景分析

按构造环境控岩控矿特点,划分区内铜镍型矿成矿(岩)带,分析成矿条件,研究了与该类矿床成矿有关的镁铁质岩、超镁铁质岩分布规律及铜镍硫化物成矿特征,提出了找矿方向和建议.     

Wavelength-dispersive X-ray fluorescence spectrometric determination of Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites

Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.     

高压微波消解法测定醋酸纤维过滤器采集的微尘粒子中的砷镉钴铬铜铁锰镍铅钒锌

最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

硅酸盐中铁、锰、钛、钙、钾、磷、硅、铝、镁、钠、锶、铷、钡的X-射线荧光光谱定量测定

本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。     

硅酸盐类样品中硅、铁、铝、钛、锰、钙、镁、钾、钠和磷的x射线荧光光谱测定

本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。     

Viscous, cohesive, non-Newtonian, depositing, radial slurry flow

Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.     

Mountains,nations, parks,and conservation

Between 1985 and 1991, two new mountain protected areas (MTNPA) covering more than 35,000 km² and based on participatory management models — the Makalu-Barun National Park and Conservation Area, Nepal, and Qomolangma Nature Preserve, Tibet Autonomous Region — were successfully established through the collaborative efforts of Woodlands Mountain Institute and conservationists in China and Nepal. Characteristics common to both projects include the importance of establishing (1) effective rationales, (2) local support constituencies, (3) a senior advisory group, (4) a task force, (5) linkages between conservation and development, and (6) fund raising mechanisms. The lessons derived from the experiences of Woodlands Mountain Institute are of significant value to others in preserving MTNPA. Increased collaboration and communication between all interested in conservation, however, will remain a critical component for expanding mountain protected area coverage to throughout the world.     

Regional distribution of Al,B, Ba,Ca, K,La, Mg,Mn, Na,P, Rb,Si, Sr,Th, U and Y in terrestrial moss within a 188,000 km2 area of the central Barents region: influence of geology,seaspray and human activity

Five hundred and ninety-eight samples of terrestrial moss (Hylocomium splendens and Pleurozium schreberi) collected from a 188,000 km² area of the central Barents region (NE Norway, N Finland, NW Russia) were analysed by ICP-AES and ICP-MS. Analytical results for Al, B, Ba, Ca, K, La, Mg, Mn, Na, P, Rb, Si, Sr, Th, U and Y concentrations are reported here. Graphical methods of data analysis, such as geochemical maps, cumulative frequency diagrams, boxplots and scatterplots, are used to interpret the origin of the patterns for these elements. None of the elements reported here are emitted in significant amounts from the smelting industry on the Kola Peninsula. Despite the conventional view that moss chemistry reflects atmospheric element input, the nature of the underlying mineral substrate (regolith or bedrock) is found to have a considerable influence on moss composition for several elements. This influence of the chemistry of the mineral substrate can take place in a variety of ways. (1) It can be completely natural, reflecting the ability of higher plants to take up elements from deep soil horizons and shed them with litterfall onto the surface. (2) It can result from naturally increased soil dust input where vegetation is scarce due to harsh climatic conditions for instance. Alternatively, substrate influence can be enhanced by human activity, such as open-cast mining, creation of ‘technogenic deserts’, or handling, transport and storage of ore and ore products, all of which magnify the natural elemental flux from bedrock to ground vegetation. Seaspray is another natural process affecting moss composition in the area (Mg, Na), and this is most visible in the Norwegian part of the study area. Presence or absence of some plant species, e.g., lichens, seems to influence moss chemistry. This is shown by the low concentrations of B or K in moss on the Finnish and Norwegian side of the (fenced) border with Russia, contrasting with high concentrations on the other side (intensive reindeer husbandry west of the border has selectively depleted the lichen population).     

NEW SET OF LOW CONCENTRATION STANDARDS FOR LA, CE, SM, YB, LU, Y, SC, V, NB AND TA IN SILICATES

We have developed a set of four synthetic standards for the rare earth and high field strength elements designed for use in the determination of those elements in silicates. The base material is a glass nominally at the eutectic of the MgO-Al₂O₃-SiO₂ ternary system. The nominal doping level was 2 wt% of the elements as oxides. To avoid problems associated with peak interference, the elements were doped in four separate glasses.