Diagenesis of Ordovician carbonates from the north-east Michigan Basin, Manitoulin Island area, Ontario: evidence from petrography, stable isotopes and fluid inclusions

Middle to Late Ordovician subtidal carbonates in the Manitoulin Island area of Ontario are predominantly limestone in composition, but non-ferroan and ferroan dolomite is a common cement as well as a selective or locally pervasive replacement phase. Integration of field, petrographic, geochemical (δ¹³C, δ¹⁸O) and fluid inclusion data indicates that lithification of these carbonates occurred during burial diagenesis, with much of the alteration controlled by regional fracturing and hydrothermal influences. Aqueous (type 1) fluid inclusions in early calcite (pre-dolomite) and dolomite are saline (> 29 wt% NaCl eq.) solutions with Ca and/or Mg in excess of Na and display homogenization temperatures with modes of 95 and 101°C, respectively. These temperatures can be explained by significantly more burial than can be accounted for either by the available stratigraphic information or by an unusually high palaeogeothermal gradient, which also is not well supported. The fluid inclusion temperatures are interpreted to have resulted from hydrothermal fluids which circulated during the burial diagenesis of these strata. Type 1 inclusions in late (post-dolomite) calcite are less saline (<19 wt% NaCl eq.) and have a bimodal distribution of homogenization temperatures with a relatively well defined low temperature peak similar to those in early calcite and dolomite and a broad higher temperature grouping with a mode at 183°C. A small proportion of methane and light hydrocarbon-bearing fluid inclusions (type 2) are present in all stages of carbonate. Dolomitizing fluids were derived from burial compaction of argillaceous sediments in the more central parts of the Michigan Basin and the updip migration of these brines along fractures to the basin margin where the carbonates of the Manitoulin Island area were dolomitized. Alternatively, migration of dolomitizing brines downward from the overlying pervasively dolomitized Silurian sequence into fractures in the Ordovician carbonates may have occurred. Integration of the aqueous fluid inclusion data into the diagenetic history of these carbonates remains equivocal because most of the inclusions are secondary or indeterminate in origin. Nevertheless, high salinities resulting from interaction with evaporitic strata and hydrothermal effects are clearly implicated although the origin of the latter remains unclear. The alteration styles of the Ordovician carbonates in the Manitoulin area are similar to those of Ordovician hydrocarbon reservoirs described from other parts of the Michigan Basin. They indicate that fracture-related diagenesis occurred on a basin-wide scale and that hydrothermal effects were important.     

Engineering geological studies and tunnel support design at Sulakyurt dam site, Turkey

This paper presents the results of engineering geological investigations and tunnel support design studies, carried out at the Sulakyurt dam site, northeast of Ankara, Turkey. The Sulakyurt dam will be used for flow control and water storage for irrigation projects. Studies were carried out both in the field and the laboratory. Field studies include engineering geological mapping, intensive discontinuity surveying, core drilling and sampling for laboratory testing. The diversion tunnel will be driven in rock mass, consisting of granite and diorite. Empirical, analytical and numerical methods were combined for safe tunnel design. Rock mass rating (RMR), Rock mass quality (Q) and Geological strength index (GSI) systems were used for empirical rock mass quality determination, site characterization and support design. The convergence–confinement method was used as analytical method and software called Phase², a 2D finite element program, was utilized as numerical method. According to the results acquired from the empirical, analytical and numerical methods, tunnel stability problems were expected in both granite and diorite rock masses. The support system, suggested by empirical methods, was applied and the performance of suggested support system was evaluated by means of numerical modelling. It was concluded that the suggested support systems were adequate, since after applying the suggested support system to granite and diorite, tunnel deformation and the yielded elements around the tunnel decreased significantly. Thus, it is suggested that for more reliable support design empirical, numerical and analytical methods should be combined.     

Archaeological mounds in Marajó Island in northern Brazil: A geological perspective integrating remote sensing and sedimentology

Earthen mounds with archaeological artifacts have been well known in Marajó Island since the 19th century. Their documented dimensions are impressive, e.g., up to 20 m high, and with areas as large as 90 ha. The mounds, locally known as tesos, impose a significant relief on the very low‐lying landscape of this region, which averages 4 to 6m above present sea level. These features have been traditionally interpreted as artificial constructions of the Marajoara culture, designed for defense, cemetery purposes, or escape from flooding. Here, we provide sedimentological and geomorphological data that suggest an alternative origin for these structures that is more consistent with their monumental sizes. Rather than artificial, the Marajoara tesos seem to consist of natural morphological features related to late Pleistocene and Holocene fluvial, and possibly tidal‐influenced, paleochannels and paleobars that became abandoned as depositional conditions changed through time. Although utilized and modified by the Marajoara since at least 2000 years ago, these earthen mounds contain a significant non‐anthropogenically modified sedimentary substratum. Therefore, the large Marajoara tesos are not entirely artificial. Ancient Marajoara cultures took advantage of these natural, preexisting elevated surfaces to base their communities and develop their activities, locally increasing the sizes of these fluvial landforms. This alternative interpretation suggests less cumulative labor investment in the construction of the mounds and might have significant implications for reconstructing the organization of the Marajoara culture. © 2009 Wiley Periodicals, Inc.     

Geophysical and Geoarchaeological Investigations at Aganoa Beach,American Samoa: An Early Archaeological Site in Western Polynesia

Archaeological investigations at Aganoa, a coastal site in American Samoa, western Polynesia, revealed a marine resources exploitation base for the early inhabitants of the island. A series of 19 radiocarbon age determinations indicates the principal period of site utilization began no later than 570 B.C., and probably earlier, and lasted for about 300 years. This site is squarely in the phase identified by previous scholars as “ancestral Polynesian.” Geophysical survey in the form of long, shore‐perpendicular transects showed the accretionary history of this beach and ridge area. Surprisingly, it revealed that the earlier ridges were directly below the modern ridge (i.e., progradation of this geomorphic feature had not occurred). The survey revealed a buried paleosol with little or no disturbance, which yielded a well‐preserved assemblage of plain and decorated ceramics, stone artifacts, fishhooks, and archaeofauna. No evidence of archaeological continuity was seen between the end of the terminal Lapita occupation and the later reoccupation of the site after about A.D. 700. This study demonstrates the utility and feasibility of using ground‐penetrating radar for the discovery of deeply buried coastal sites.     

Heavy metal migration at a landfill site, Sarnia, Ontario, Canada—2: metal partitioning and geotechnical implications

Heavy metal profiles below a 15-year old sanitary landfill overlying a 30 m thick natural clay deposit are presented. Results indicate that unlike soluble species such as Cl⁻ and Na⁺ which have migrated distances up to 130 cm, Cu, Zn and Pb have migrated only up to 10 cm. The extent of Fe migration is estimated to be 20 cm. Highly reducing conditions at the interface (E_h= −130mV), coupled with the alkaline nature of the clay pore waters, have resulted in the precipitation of migrated heavy metals as carbonates. At the clay/waste interface, 88, 84 and 80% of the excess Fe, Zn and Pb, respectively, are present as secondary carbonates. This is confirmed by selective chemical dissolution analyses which also show that Fe, Zn, Pb and, to a greater extent, Cu are present in solid organic forms at the interface. Batch equilibrium studies clearly show that Cu and Pb removal from leachate is significantly increased by the presence of carbonates in the soil. For example, 75% more Pb is removed by the carbonate-rich bulk soil than the carbonate-free soil. The batch studies also show that when thepH> 5.2, removal of metal increases significantly due to precipitation as carbonates. From the results it is concluded that the presence of metal sludges in landfills lined naturally or artifically by a carbonate-rich clayey barrier reduces the rate of migration of numerous toxic transition metals and may also decrease the barrier porosity by precipitation. The decreases in porosity will be beneficial to the performance of the barrier due to reductions in both advection and diffusion.     

Rock‐Magnetic and Archaeointensity Investigation of Pottery and a Burned Floor at the Tzintzuntzan Archaeological Site,Western Mexico

We report a detailed rock‐magnetic and archaeointensity analysis of four pottery fragments and a burned floor recovered from the Tzintzuntzan archaeological site in western Mexico. Results from rock‐magnetic experiments (x‐T curves and first‐order reversal curves [FORC] diagrams) indicate the suitability of most of these materials as faithful geomagnetic field recorders. Potsherds were archaeomagnetically dated by comparing their mean intensity values against the paleosecular variation curve CALS3k, suggesting A.D. 600–941 as the most probable age range. This is younger than ¹⁴C‐dated charcoal from the same burned floor (A.D. 1294–1426). More precise age estimates will require the use of the full geomagnetic vector (declination, inclination, and intensity). Multiple reheatings of the ceramic pieces, evidenced as secondary components in Zijderveld plots, could reflect multiple heating of these objects, perhaps from use as incense burners. Our study demonstrates the potential of archaeomagnetic analysis to both date burned ceramics recovered in situ and provide insight into their use‐history.     

Site formation processes at Donggutuo: a major Early Pleistocene site in the Nihewan Basin,North China

Understanding site formation processes is crucial for interpreting archaeological context patterns and hominin behaviour as these affect the preserved condition of a site and the integrity of archaeological remains. The fluvio‐lacustrine sequences in the Nihewan Basin of North China are rich sources of early Pleistocene archaeological sites, which offer an important opportunity to investigate human evolution and adapted behaviours in East Asia. Although many Palaeolithic sites have been reported from the Nihewan Basin, North China, few of them focus on site formation processes before interpreting the hominin behaviour patterns. Here, we present a site formation study of four archaeological layers (Layers 6D, 6C, 6B and 6A) in Trench 1 from the Donggutuo (namely DGT‐T1) site in the Nihewan Basin with an age of 1.1 Ma. Through the study of sedimentary contexts, spatial distributions of artefacts and fossils, intra‐assemblage category ratios, debitage size distributions, lithic abrasion, artifact orientation and planar dip, our results show that all the layers had been disturbed by low‐energy sheet wash across the lake shore setting, but to differing extents. The post‐depositional disturbance caused by water decreased from the lower to the upper layers, from Layer 6D to Layer 6A. This indicates that the archaeological remains in DGT‐T1 have not been subject to significant natural modifications and are thus suitable for studying early hominin behaviour in North China. Copyright © 2019 John Wiley & Sons, Ltd.     

Paleoentomology and paleoecology of a possible sangamonian site near Innerkip,Ontario

A stream section near Innerkip, Ontario, exposes several meters of organic silts and peaty detritus beneath two late Wisconsinan tills. Radiocarbon dates provide a minimal middle Wisconsinan age of >50,000 yr B.P. A 250-kg bulk sample from the peat stratum was processed for vertebrates, plant macrofossils, and insects. Vertebrate remains include teeth from deer, muskrat, and vole as well as plates from a turtle shell. At least 6000 insect fragments from a minimum of 19 Coleoptera families were identified. The most common groups are hydrophilids and dytiscids (water beetles), curculionids (weevils), staphylinids (rove beetles), and carabids (ground beetles). The majority of identified beetles are associated with fresh water as aquatic predators, scavengers, or grazers, while others prefer hygric substrates and moist plant litter. The large number of plant-dependent beetles, the numerous floating and emergent aquatic plant seeds, and the presence of the associated vertebrates point toward a locally rich and varied flora and fauna, probably deposited in a well-vegetated pond. The modern distributions and ecologies of the identified fossil insects suggest temperatures similar to those found in southern Ontario today. On these grounds the Innerkip peat represents either a very warm interstadial or a possible interglacial deposit. If the latter is true this is the second presumed Sangamon-aged site known in southern Ontario.     

Assessment of the geological and hydrogeological environment at a site of government-level conflict in Incheon, Korea

 The natural environment of an environmental conflict site in Incheon, Korea was assessed with a focus on the hydrogeological environment. Residents had made claims against a company because of health problems, including skin tumors. More specifically, the residents suspected that their drinking groundwater had been contaminated by glass fibers which had caused the health problems. Air, soil, and groundwater samples were analyzed to estimate whether environmental pollution could have caused the problems claimed by the residents. No specific evidence was found from this study to support the groundwater contamination by glass fibers, but groundwater contamination by leaked fuel oils was confirmed in the course of evaluating the glass fiber problem. Received: 16 May 1997 · Accepted: 18 August 1997     

Chemical and Mineralogical Signatures of Archaeological Features at the Mailhot‐Curran Iroquoian Site,Eastern Canada

The St. Lawrence Iroquoians built villages in southwestern Quebec (Canada) along the St. Lawrence River. They left behind longhouses, hearths, middens, and storage pits like those discovered at the Mailhot‐Curran archaeological site in Saint‐Anicet. Here, we contrast the properties of Iroquoian features with undisturbed soil to define the chemical and mineralogical signature of hearths, middens, and pits. The native soil has a neutral pH and consists of an Ah horizon overlaying a Bm horizon dominated by quartz and feldspars. In the hearths, ashes are characterized by neoformed calcite and apatite with carbonates, higher total P, and enrichment in amorphous inorganic Al, Fe, and Si. The rubified layer of hearths contain poorly crystallized Fe oxides. The mineralogy of the rubified layer is dominated by authigenetic ankerite, an Fe‐carbonate mineral identified here for the first time in Iroquoian hearths. Middens have the highest organic matter content and contain more organically complexed Al and Fe than the soil. The storage pits have low pH values and carbonate content and contain high levels of amorphous Si and total P. Our work establishes the pedologic signature of three Iroquoian features despite significant alteration of their properties by post‐occupational biogeochemical processes.     

An organic geochemical investigation of the practice of manuring at a Minoan site on Pseira Island,Crete

Lipid components in a soil profile developed in an agricultural terrace at a Minoan site on Pseira Island, Crete, were analyzed to determine whether the practice of manuring in antiquity, as inferred by distributional and temporal sherd scatter, could be confirmed through the use of biomarker compounds as proxies for manuring. Analysis of total organic carbon and the abundance of n‐alkyl lipids (n‐alkanols and fatty acids) demonstrated that while the upper part of the soil profile had received more recent inputs of vegetation‐derived organic matter, the deeper archaeological strata remained essentially undisturbed. Further analysis of 5β‐stanols, sterol components which may be utilized as fecal biomarkers, revealed a signal indicative of manuring, with human or porcine‐derived fecal material, in the lower 15 cm of the profile. Additional appraisal of epicoprostanol abundance inferred the possible practice of composting in later periods. This study represents a detection of manuring, in the oldest samples to date, using organic geochemical methods. © 2001 John Wiley & Sons, Inc.     

Floodplain formation processes and archaeological implications at the Grand Banks site,lower Grand River,southern, Ontario

Processes of floodplain development and the record of Princess Point cultural occupation (A.D. 500–1000) were examined at the Grand Banks site in the lower Grand River of southern Ontario. The Princess Point Complex of the early Late Woodland is significant because it represents the first shift to horticulture in this region in which inhabitants made significant use of floodplains. The floodplain of the lower Grand River has been constructed primarily via vertical accretion of sediment in a low energy environment conducive to limited erosion and slow burial of middle and late Holocene sediments. At this site, cultural materials are preferentially preserved in two buried soils each corresponding to relatively stable periods of valley infilling at or before 3200 B.P. and 1500 B.P. (¹⁴C years). Initial formation of the floodplain and subsequent stability of the floodplain surface can be tied to middle Holocene, and later, base-level fluctuations in Lake Erie. Understanding floodplain development is crucial in determining the linkages between settlement pattern and chronology, and, conversely, the archaeological record in floodplain settings provides important contemporary data for modeling floodplain geomorphological processes. © 1997 John Wiley & Sons, Inc.     

Investigation on the geological and geotechnical factors leading to a major slope failure at a selected site on a Jordanian highway

During and after the very wet 1991/1992 winter experienced in Jordan, significant slope failures occurred along several sections of the new Irbid-Amman highway in Jordan. The topography over most of the route is hilly, and significant amounts of cut and fill were used to construct the highway. One such slope failure lies at 44+800 km on the highway south of Jerash City at a distance of about 5.0 km from Wadi Zerqa bridge. A landslide occurred downslope of the highway embankment resulting in a collapse of the most of the gabbion wall supporting the embankment. This paper deals with the overall stability of the slope at 44+800 km. It presents the geological and geotechnical studies carried out at this site, identifies the causes and mechanism of instability, and presents appropriate remedial measures. The study concluded that the landslide movement occurred within the colluvium material. It resulted primarily from excess piezometric pressures generated within the slope as a direct consequence of inadequate drainage. It is recommended to reconstruct the entire gabbion wall with its foundation seated on the sandstone that underlies the colluvium and to install a surface drainage system at the site.     

Stratigraphy and palaeoecology of a possible interglacial site,northernmost Ellesmere Island,Canada

An extensive stratigraphic section at Cape Alfred Ernest on the Wootton Peninsula, northwest Ellesmere Island contains six lithofacies which appear to record two glacial phases separated by an organic layer. (1) A lower massive gravel records a pre-ice advance outwash phase; (2) massive fine-grained sediments record a period of non-glacial marine deposition when sea-level was higher than present; (3) a massive diamicton records the advance of ice across the site; (4) intermediate stratified beds record supraglacial and proglacial outwash, and include an organic layer; (5) massive diamicton grading down-valley to stratified diamicton and then massive, sheared diamicton, overlain by laminated fine-grained sediments with dropstones, recording the last (late Wisconsinan) glaciation; (6) upward-coarsening sands and gravels record proglacial outwash and grade to raised marine deltas. Radiocarbon dates of 39270 ± 640 and > 51000 yr BP were obtained on samples from the organic layer by accelerator mass spectrometry and conventional radiocarbon dating, respectively. Palaeoecological data suggest that the organics accumulated in a wet sedge meadow environment when the climate was warmer than present. Stratigraphic considerations suggest that the organic layer represents an interglacial interval which, if valid, indicates that the site constitutes the northernmost interglacial stratigraphy in the Canadian Arctic. Alternatively, the organic layer may date to Plio-Pleistocene times.     

The Oldest Evidence for Human Habitation in the Baltic Region: A Preliminary Report on the Chronology and Archaeological Context of the Riadino‐5 Archaeological Site

We report the discovery of the oldest evidence for human presence in the southeastern Baltic Sea region. This paper presents an overview of the Riadino‐5 archaeological site in the lower course of the Šešupė River (Kaliningrad Oblast of Russia) and direct infrared stimulated luminescence (IRSL) ages for the culture‐bearing sediments from the site, which place the time of occupation well within the range of Marine Isotope Stage (MIS) 3 (ca 57–26 ka). Luminescence ages were determined using the multiple‐aliquot additive‐dose technique, applied to sand‐sized potassium feldspar. Four of the six IRSL samples from the site come from the cultural deposits, while two are from the surrounding sediments. The luminescence age of the deposits implies that human occupation of the southeastern Baltic Sea region occurred at least between 50 ka and 44 ka during the first half of MIS 3 and the Middle‐Upper Paleolithic.     

Examining Fluvial Stratigraphic Architecture Using Ground‐Penetrating Radar at the Fanta Stream Fossil and Archaeological Site,Central Ethiopia

The Fanta Stream site is an archaeological and paleontological locality in Addis Ababa, Ethiopia. The site contains a rich assemblage of fossil mammals and Acheulean artifacts of approximately 600 ka located in a rare high‐altitude context. A ground‐penetrating radar (GPR) survey was conducted in order to provide three‐dimensional imaging of the subsurface, which the authors use to interpret the geometry and distribution of fossil‐containing stratigraphic units. Utilizing the stream's natural cut bank exposure, we calibrate GPR data to known geologic units through radar facies analysis. Shallow, high‐amplitude coherent reflection geometries are attributed to volcanic tuff deposits, as these units exhibit subparallel continuous reflections consistent with planar stratified sedimentary deposition. Deeper, discontinuous reflection packages are interpreted as conglomeritic, fossil‐containing deposits. The results of the GPR survey outline the location of the Fanta Stream's paleodepositional features as well as suggest the extent of fossiliferous stratigraphic units for use in future excavations.     

Application of statistical approaches to analyze geological,geotechnical and hydrogeological data at a fractured-rock mine site in Northern Canada

Mine site characterization often results in the acquisition of geological, geotechnical and hydrogeological data sets that are used in the mine design process but are rarely co-evaluated. For a study site in northern Canada, bivariate and multivariate (hierarchical) statistical techniques are used to evaluate empirical hydraulic conductivity estimation methods based on traditional rock mass characterisation schemes, as well as to assess the regional hydrogeological conceptual model. Bivariate techniques demonstrate that standard geotechnical measures of fracturing are poor indicators of the hydraulic potential of a rock mass at the study site. Additionally, rock-mass-permeability schemes which rely on these measures are shown to be poor predictors of hydraulic conductivity in untested areas. Multivariate techniques employing hierarchical cluster analysis of both geotechnical and geological data sets are able to identify general trends in the data. Specifically, the geological cluster analysis demonstrated spatial relationship between intrusive contacts and increased hydraulic conductivity. This suggests promise in the use of clustering methods in identifying new trends during the early stages of hydrogeological characterization.     

Environmental geological assessment of a solid waste disposal site: a case study in Sivas, Turkey

The selection of the disposal site is probably the most important step in the development of solid waste management. In site selection, geology plays a determining role. This study evaluates the characteristics of the environment on the basis of the geological, hydrogeological and geo-engineering properties of the solid waste site of the Sivas city, Turkey. The area is underlain by the Oligocene-Miocene rocks which have limited aquifer properties. Thin Quaternary alluvium and soil cover overlie the Oligo-Miocene rocks, which are represented as well graded sand and inorganic silt of low plasticity. The Quaternary alluvium and soil cover are classified as inorganic clays having a low plasticity and the permeability varies from 1.2×10⁻⁶ to 3.11×10⁻⁶ m/s. These values are much higher than 1×10⁻⁸ m/s, which is accepted for waste disposal standards. Seepage waters have a potential to pollute the ground water and the Kızılırmak River, which is 500 m to the southwest of the waste disposal area and because the disposal site is close to the river, the potential for flash flooding poses a high pollution risk. The waste disposal area must be covered by clay layers or an impervious artificial membrane. In addition, seepage must be controlled and removed from the site.     

Geologic controls on movement of produced-water releases at US geological survey research Site A,Skiatook lake,Osage county,Oklahoma

Highly saline produced water was released from multiple sources during oil field operations from 1913 to 1973 at the USGS research Site A on Skiatook Lake in northeastern Oklahoma. Two pits, designed to hold produced water and oil, were major sources for release of these fluids at the site. Produced water spills from these and other features moved downslope following topography and downdip by percolating through permeable eolian sand and colluvium, underlying permeable sandstone, and, to a lesser extent, through shales and mudstones. Saline water penetrated progressively deeper units as it moved through the gently dipping bedrock to the north and NW. A large eroded salt scar north of the pits coincides with underlying fine-grained rocks that have retained substantial concentrations of salt, causing slow revegetation. Where not eroded, thick eolian sand or permeable sandstone bedrock is near the surface, and vegetation has been little affected or has reestablished itself after the introduced salt was flushed by precipitation. The extent of salt-contaminated bedrock extends well beyond existing surface salt scars. These results indicate that one of the legacies of surface salt spills can be a volume of subsurface salinization larger than the visible surface disturbance.     

成都平原马街遗址古洪水事件遗存考古发现与研究

2014年5月,对四川成都郫县马街遗址古洪水事件做了调查,该遗址经度为103°55 ′ 39″E,纬度为30°53′37.1″N,遗址海拔为黄海高程499.758m,遗址的2014CPMT1-T2探方中有古代生长在地下的树根1处、冲刷带来的独木舟1处、古树干9处.经光学方法鉴定,其中的古树根和古树木主要是秋枫树(Bis...