Indications of neotectonic activity at the Barents Sea shelf

Geologic-geomorphic and structural indications of neotectonic, virtually present-day, activity at the Barents Sea shelf are considered. Wide belts of the secondary ruptures—linear zones of dynamic effects of faults with a strike-slip component in the acoustic basement—are mapped in the areas studied in detail. Some of these ruptures displace recent sediments. As a result, allochthonous blocks of Mesozoic or Paleozoic rocks occasionally barren of recent marine sediments arise under transpressional conditions. Other signs of the present-day secondary faulting include shallow-seated injection folds and a peculiar wavy topography of mud in deep areas of the bottom. The relationship of exotic submarine mounds and gas emissions in the eastern Pechora Sea with recent mud volcanoes controlled by the neotectonic activity of the Pai-Khoi-Novaya Zemlya Foldbelt under conditions of lateral compression is substantiated for the first time. A superimposed aggradational height is revealed in the most subsided portion of the Central Trench; the origin of this height is referred to the effect of seismic vibration of the seafloor that brings about partial fluidization of surficial marine mud and its ductile-viscous flow and local accumulation in a particularly favorable area of the bottom. The indications of neotectonic activity may be used as a tool for testing the tectonic concepts that are put forward.     

Mud volcanic natural phenomena in the South Caspian Basin: geology,fluid dynamics and environmental impact

The South Caspian sedimentary basin is a unique area with thick Mesozoic-Cenozoic sediments (up to 30–32 km) characterized by an extremely high fluid generation potential. The large amount of active mud volcanoes and the volumes of their gas emissions prove the vast scale of fluid generation. Onshore and offshore mud volcanoes annually erupt more than 10⁹ cubic meters of gases consisting of CH₄ (79–98%), and a small admixture of C₂H₆, C₃H₈, C₄H₁₀, C₅H₁₂, CO₂, N, H₂S, Ar, He. Mud volcanism is closely connected to the processes occurring in the South Caspian depression, its seismicity, fluctuations of the Caspian Sea level, solar activity and hydrocarbon generation.The large accumulations of gas hydrates are confined to the bottom sediments of the Caspian Sea, mud volcanoes crater fields (interval 0–0.4 m, sea depth 480 m) and to the volcanoes body at the depth of 480–800 from the sea bottom. Resources of HC gases in hydrates saturated sediments up to a depth of 100 m and are estimated at 0.2×10¹⁵–8×10¹⁵ m³. The amount of HC gases concentrated in them is 10¹¹–10¹² m³.The Caspian Sea, being an inland closed basin is very sensitive to climatic and tectonic events expressed in sea level fluctuations. During regressive stages as a result of sea level fall and the reducing of hydrostatic pressure the decomposition of gas hydrates and the releasing of a great volume of HC gases consisting mainly of methane are observed.From the data of deep drilling, seismoacoustics, and deep seismic mud volcanic activity in the South Caspian Basin started in the Lower Miocene. Activity reached its highest intensity at the boundary between the Miocene and Pliocene and was associated with dramatic Caspian Sea level fall in the Lower Pliocene of up to 600 m, which led to the isolation of the PaleoCaspian from the Eastern ParaTethys. Catastrophic reduction of PaleoCaspian size combined with the increasing scale of mud volcanic activity caused the oversaturation and intoxication of water by methane and led to the mass extinction of mollusks, fishes and other groups of sea inhabitants. In the Upper Pliocene and Quaternary mud volcanism occurred under the conditions of a semi-closed sea periodically connected with the Pontian and Mediterranean Basins. Those stages of Caspian Sea history are characterized by the revival of the Caspian organic world.Monitoring of mud volcanoes onshore of the South Caspian demonstrated that any eruption is predicted by seismic activation in the region (South-Eastern Caucasus) and intensive fluid dynamics on the volcanoes.     

准噶尔盆地南缘泥火山活动及其伴生油苗的地球化学特征和意义

文中对准噶尔盆地南缘乌苏四棵树和独山子泥火山的构造背景进行了分析,指出其形成主要是由于天山北缘中新生 代沉积层中地势高低造成的水压差和地层层间压力差,导致丰富的地下水沿着背斜顶端发育的断裂带上升,与通道周围的 泥质岩石相遇,泥浆形成并喷出地表而成为泥火山。论文还对四棵树和独山子泥火山的伴生油苗进行了全油色谱和生物标 记化合物研究,对比相关烃源岩地球化学特征及前人有关研究成果,指出油样有机质均处于成熟阶段,油源可能是侏罗系 与古近系烃源岩的混合产物。研究结果对探索该区泥火山的成因和油气成藏条件具有重要意义。     

中国海域的天然气水合物资源

天然气水合物是甲烷等天然气在高压、低温条件下形成的冰状固体物质。据估算,全球天然气水合物中碳的含量等于石油、煤等化石能源中碳含量的2倍。在人类面临化石能源即将枯竭的时候,各国科学家和政府都把目光投向这一未来能替代化石能源的新能源。新生代构造演化历史、沉积条件、沉积环境等显示,南海具有生成和蕴藏巨大天然气水合物资源的条件;南海海域的地震反射剖面多处显示存在BSR反射波;2007年已钻探见到水合物样品。东海冲绳海槽在第四纪的沉积速率高(10~40cm/ka),槽坡存在泥底辟构造和断裂活动,从上新世以来发生过两次构造运动,这些对天然气水合物的形成是十分有利的;因此,中国海域的天然水合物资源是十分丰富的,在不远的将来它可能成为新的替代能源。     

Composition and exhalation flux of gases from mud volcanoes in Taiwan

Many mud volcanoes are distributed along the tectonic sutures in southern Taiwan and can be divided into five zones based on their relative positions in different tectonic domains. Most active mud volcanoes are exhaling methane-dominated gases. Nevertheless, some gases show unusual carbon dioxide-dominated and/or nitrogen-excess compositions. This implies that there are multiple sources for the gas compositions of mud volcanoes in Taiwan.For better understanding the total amount of exhalation gases and its flux, the gas flow and compositions were continuously measured in the interval of two minutes at Chung-lun (CL) bubbling mud pool for a few months. The major compositions of gases exhaling from this site were 75~90% of CO₂ and 5~12% of CH₄. The amount of gases exhaling from the mud pool can be estimated to be about 1.4 ton/year for CH₄ and 28 ton/year for CO₂, respectively. The preliminary results of exhaling gas flux from the major vents of representative active mud volcanoes, yielded an estimated total CH₄ output of the mud volcanoes in Taiwan of ca. 29 ton/year during quiescent period.     

Mud volcano eruptions and earthquakes in the Northern Apennines and Sicily, Italy

The relations between earthquakes and the eruption of mud volcanoes have been investigated at the Pede–Apennine margin of the Northern Apennines and in Sicily. Some of these volcanoes experienced eruptions or increased activity in connection with historical seismic events, showing a good correlation with established thresholds of hydrological response (liquefaction) to earthquakes. However, the majority of eruptions have been documented to be independent of seismic activity, being mud volcanoes often not activated even when the earthquakes were of suitable magnitude and the epicentre at the proper distance for the triggering. This behaviour suggests that paroxysmal activity of mud volcanoes depends upon the reaching of a specific critical state dictated by internal fluid pressure, and implies that the strain caused by the passage of seismic waves can activate only mud volcanoes in near-critical conditions (i.e., close to the eruption). Seismogenic faults, such as the Pede–Apennine thrust, often structurally control the fluid reservoirs of mud volcanoes, which are frequently located at the core of thrust-related folds. Such an intimate link enables mud volcanoes to represent features potentially suitable for recording perturbations associated with the past and ongoing tectonic activity of the controlling fault system.     

The mud volcanoes of Pakistan

Marine-geologic investigations on the Arabian Sea by Bundesanstalt für Geowissenschaften und Rohstoffe (BGR) in 1995 and 1998, and land expeditions in 1998 and 1999 to the coastal regions of the Makran Desert/Pakistan have extended the knowledge of the aerial distribution of mud volcanoes. These structures rise from under-compacted formations within the regional accretionary prism, which is built by the subduction of the oceanic crust of the Arabian Sea and its km-thick sedimentary load. The occurrence of mud volcanoes is limited to the abyssal plain near the accretionary front, to the coastal region of the Makran Desert and to a region in the interior of the Desert to the south to southeast of the so-called Hinglay Synform. The location of mud volcanoes in Pakistan is clearly tied to fault systems. Mud volcanoes are conspicuously absent on the lower slope of the accretionary prism, where thick gas hydrate layers have developed. The presence of large gas plumes emerging from the seafloor landward of the gas hydrate stability zone at water depths of less than 800 m points to a redirection of fluids from depth, which might explain the absence of mud volcanoes along the lower slope.     

Microbial methane turnover at mud volcanoes of the Gulf of Cadiz

The Gulf of Cadiz is a tectonically active area of the European continental margin and characterised by a high abundance of mud volcanoes, diapirs, pockmarks and carbonate chimneys. During the R/V SONNE expedition “GAP-Gibraltar Arc Processes (SO-175)” in December 2003, several mud volcanoes were surveyed for gas seepage and associated microbial methane turnover. Pore water analyses and methane oxidation measurements on sediment cores recovered from the centres of the mud volcanoes Captain Arutyunov, Bonjardim, Ginsburg, Gemini and a newly discovered, mud volcano-like structure called “No Name” show that thermogenic methane and associated higher hydrocarbons rising from deeper sediment strata are completely consumed within the seabed. The presence of a distinct sulphate-methane transition zone (SMT) overlapping with high sulphide concentrations suggests that methane oxidation is mediated under anaerobic conditions with sulphate as the electron acceptor. Anaerobic oxidation of methane (AOM) and sulphate reduction (SR) rates show maxima at the SMT, which was found between 20 and 200 cm below seafloor at the different mud volcanoes. In comparison to other methane seeps, AOM activity (<383 mmol m⁻² year⁻¹) and diffusive methane fluxes (<321 mmol m⁻² year⁻¹) in mud volcano sediments of the Gulf of Cadiz are low to mid range. Corresponding lipid biomarker and 16S rDNA clone library analysis give evidence that AOM is mediated by a mixed community of anaerobic methanotrophic archaea and associated sulphate reducing bacteria (SRB) in the studied mud volcanoes. Little is known about the variability of methane fluxes in this environment. Carbonate crusts littering the seafloor of mud volcanoes in the northern part of the Gulf of Cadiz had strongly ¹³C-depleted lipid signatures indicative of higher seepage activities in the past. However, actual seafloor video observations showed only scarce traces of methane seepage and associated biological processes at the seafloor. No active fluid or free gas escape to the hydrosphere was observed visually at any of the surveyed mud volcanoes, and biogeochemical measurements indicate a complete methane consumption in the seafloor. Our observations suggest that the emission of methane to the hydrosphere from the mud volcano structures studied here may be insignificant at present.     

Evaluation of earthquake-induced strain in promoting mud eruptions: the case of Shamakhi–Gobustan–Absheron areas,Azerbaijan

Although a relationship between the occurrence of large earthquakes and the eruptions of close mud volcanoes is well known, several uncertainties remain on understanding the triggering mechanisms. In the present study, we evaluate both the static and dynamic strains induced by earthquakes in the substratum of mud volcanoes. We studied the effects of two earthquakes of M _w 6.18 and 6.08 occurred in the Caspian Sea on 25 November 2000 close to Baku city, Azerbaijan. A total of 33 eruptions occurred at 24 mud volcanoes within a maximum distance of 108 km from the epicentres in the 5 years following the earthquakes. The overall eruption rate in the studied area of the 50 years before the 2000 earthquakes was 1.24 that is much smaller than the eruption rate of 6.6 of the 5 years following these earthquakes. The largest number of eruptions occurred within 2 years from the earthquakes with the highest frequency within 6 months. Our calculated earthquake-induced static effects show that crustal dilatation might have triggered only seven eruptions at a maximum distance of about 60 km from the epicentres and within 3 years. Based on our data, dynamic rather than static strain is likely to have been the dominating “promoting” factor because it affected all the studied unrest volcanoes and its magnitude was much larger.     

Geochemical similarities between the Vesuvius, Phlegraean Fields and Stromboli Volcanoes: petrogenetic, geodynamic and volcanological implications

Summary Vesuvius and Stromboli are two active and extensively studied volcanoes that traditionally have been considered as having different styles of eruption, rock composition and tectonic setting. Data reveal close compositional affinities between these two volcanoes. The abundant 13–15 Ka old Stromboli leucite-tephritic rocks have radiogenic isotope signatures, and abundances and ratios of incompatible elements with the exception of Rb and K, which are identical to those of Vesuvius. The Phlegraean Fields also show close affinities to these volcanoes. The similarity between Stromboli leucite-tephrites and Vesuvius rocks cannot be the result of low pressure processes, given the differences between the two volcanoes in terms of structural features, eruptive behaviour and type of basement rocks. Instead, the observed geochemical signatures are likely to represent a primary magma composition and reveal a common homogeneous source for the two suites. The higher K and Rb contents in the Vesuvius rocks suggest either selective enrichment during magma ascent or a role for phlogopite melting during mantle anatexis. The most primitive rocks from Vesuvius, Phlegraean Fields and Stromboli reveal intermediate compositions between arc and intraplate volcanics. It is suggested that the mantle sources beneath these volcanoes consist of a mixture of intraplate- and slab-derived components. Intraplate material was probably provided by inflow of asthenosheric mantle into the wedge above the subducting Ionian Sea plate, either from the Apulian plate and/or from the Tyrrhenian Sea region. Fluids or melts released from the sinking slab and associated sediments generated metasomatic modification of the intraplate material, whose melting gave rise to the Stromboli, Vesuvius and Phlegraean Fields magmas. The present study demonstrates how comparative investigations of various volcanic centres from southern Italy allow clarification of a number of problems involving magma genesis and evolution, composition of mantle sources and geodynamic significance, which have been long debated and are difficult to solve if individual volcanoes are considered in isolation. Received July 20, 2000; revised version accepted March 19, 2001     

Newly discovered mud volcanoes in the Coastal Belt of Makran,Pakistan—tectonic implications

The Makran accretionary wedge has a much larger number of mud volcanoes then those reported earlier. Using high-resolution satellite images, over 70 active mud volcanoes were identified. These mud volcanoes occur within a well-defined zone; we call it the Makran zone of active mud volcanoes (MZAMV), which is parallel to the regional trend of the accretionary wedge. Mud volcanoes within the zone occur as clusters, which form linear belts parallel to the regional thrusts associated with anticlines. The MZAMV zone also includes the offshore mud volcanoes occurring in the shallow shelf area, including the recurrently emerging mud islands. Several occurrences of thick deposits of old mud volcanoes (Pleistocene or even older) are also present within this zone, which also display recognizable features that are characteristic of the fossil mud volcanoes. We propose that the MZAMV developed and evolved in response to the continued compression within the Makran accretionary wedge, which in turn, is a response of the subduction process. Mud diapirism has been an ongoing phenomena since Pleistocene or even earlier. The events of enhanced mud extrusion in mud volcanoes and/or emergence of island(s) have relevance with seismic phenomena and, therefore, may be closely monitored.     

Distribution and characters of the mud diapirs and mud volcanoes off southwest Taiwan

In order to identify the mud diapirs and mud volcanoes off SW Taiwan, we have examined ∼1500 km long MCS profiles and related marine geophysical data. Our results show ten quasi-linear mud diapirs, oriented NNE–SSW to N–S directions. Thirteen mud volcanoes are identified from the multibeam bathymetric data. These mud volcanoes generally occur on tops of the diapiric structures. Moreover, the active mud flow tracks out of mud volcanoes MV1, MV3 and MV6 are observed through the high backscatter intensity stripes on the sidescan sonar images. The heights of the cone-shaped mud volcanoes range from 65 m to 345 m, and the diameters at base from 680 m to 4100 m. These mud volcanoes have abrupt slopes between 5.3° and 13.6°, implying the mudflow is active and highly viscous. In contrast, the flat crests of mud volcanoes are due to relative lower-viscosity flows. The larger cone-shaped mud volcanoes located at deeper water depths could be related to a longer eruption history. The formation of mud diapirs and volcanoes in the study area are ascribed to the overpressure in sedimentary layers, compressional tectonic forces and gas-bearing fluids. Especially, the gas-bearing fluid plays an important role in enhancing the intrusion after the diapirism as a large amount of gas expulsions is observed. The morphology of the upper Kaoping Slope is mainly controlled by mud diapiric intrusions.     

Fluid migration and origin of a mud volcano in the Northern Apennines (Italy): the role of deeply rooted normal faults

ABSTRACT In the foothills of the Northern Apennines mud volcanoes are locally aligned along active normal faults, which allow surface leakage of fluids derived from deep sources (>3–6 km). The chemical and isotopic analysis of the fluids of a mud volcano, coupled with the reconstruction of its geological setting, allowed an investigation of the processes of migration and fluid flow. The fault system associated with the Regnano mud volcano drains a deep Miocene reservoir (foredeep marine deposits), which supplies formation water and thermogenic methane that has migrated from underlying Mesozoic carbonates. The muds from the volcano contain late Eocene microfossils and are extruded only during paroxysmal events. They have a shallower origin (about 1 km) from the base of Tertiary marine deposits deposited upon the upper tectonic nappe of the chain (Ligurian unit). This case study suggests that normal faults are very effective in controlling surface emissions.     

Mud Volcanoes: Distribution Regularities and Genesis (Communication 2. Geological–Geochemical Peculiarities and Formation Model)

The work discusses relationships between mud volcanoes, tectonic faults, folds, and oil-and-gas deposits. The location of roots and centers of mud volcanic activity is analyzed. It proposes a new model of mud volcano formation, according to which these structures result from the development of elision systems of sedimentary basins.     

Mud volcanoes of the Black Sea as a prospecting indicator of methane gas hydrates

Relationship between methane gas hydrates and mud volcanoes in the Black Sea is considered. It is suggested that they are mainly confined to compensation troughs near mud volcanoes.     

Liquefied vs stratified sediment mobilization processes: Insight from the South of the Barbados accretionary prism

This paper discusses the nature and origin of subsurface sediment mobilization processes in deep marine clay-rich environments. In the studied area of the southern Barbados accretionary prism, new geophysical acquisitions have emphasized the spectacular widespread development of mud volcanoes that are well-developed along ramp anticlines and along sigmoidal rises with trends that are oblique to the axes of the main folds of the accretionary wedge. On some active mud volcanoes, heat-flow measurements show high positive anomalies related to high fluxes of mud transfer. The mobilized solid fraction expelled by the mud volcanoes does not originate from a unique source bed but from various formations pierced by the mud conduits and is driven by the water phase. The area studied also exhibits trends of structures corresponding to sub-circular massive local uplifts of deformed but well-preserved stratified sediments (turbidites and hemipelagics). No piercing shale diapirs have been encountered in this area. Some of these local uplift structures are complicated by the development of collapses, calderas, and superimposed mud volcanoes. Mud volcanism corresponds fundamentally to fluid displacement (water and gas), whereas massive sedimentary uplift corresponds to large vertical displacements of stratified solid levels but for which the deep cause could be partly the intrusion of mud plugs. Both are dynamic phenomena controlled by the development of overpressure at depth, contributing to sedimentary mobilizations.     

Geochemical characteristics of mud volcano fluids in the southern margin of the Junggar basin,NW China: implications for fluid origin and mud volcano formation mechanisms

Mud volcanoes can provide important information about the underlying strata, hydrocarbon accumulation, and recent neotectonic movements in an area. The fluids erupting from mud volcanoes provide important information about their formation and evolution. The ion concentration and the hydrogen and oxygen isotopes of the fluids that were erupted from the three mud volcano groups, Baiyanggou, Aiqigou, and Dushanzi, and nearby rivers in the southern margin of the Junggar basin, northwestern China, are studied. The concentrations of Na and Cl in mud volcano fluids are clearly elevated, displayed as the Na-Cl type. The δD and δ18O values of the fluids are similar between the Baiyanggou and Dushanzi mud volcanoes, which are mainly from ancient sedimentary pore water. However, the Aiqigou mud volcano is depleted in dissolved Cl and shows lower δ18O values with mixed sources, including deep pore and local meteoric water. Two types of mud volcanoes are proposed in this study. One type is low-energy mud volcanoes with a low volume of fluid of deep origin on the hillcrest, which display as mud pool/pie/hole. The other type is high-energy mud volcanoes having mixed fluid origin in the valley and formed in the shape of a mud cone (dome).     

A geochemical study on mud volcanoes in the Junggar Basin, China

A comprehensive study was performed to characterize, for the first time, the mud, water, and gases released from onshore mud volcanoes located in the southern margin of the Junggar Basin, northwestern China. Chemical compositions of mud, along with the geology of the basin, suggest that a source of the mud is Mesozoic or Cenozoic shale. Oxygen and H isotope compositions of the released water suggest a local meteoric origin. Combined with the positive Eu anomalies of the water, a large ¹⁸O shift of the water suggests extensive interaction with rocks. Gases discharged from the mud volcanoes are predominantly thermogenic hydrocarbons, and the high δ¹³C values (>+20‰ VPDB) for CO₂ gases and dissolved carbonate in muddy water suggest secondary methanogenesis with CO₂ reduction after oil biodegradation.The enrichments of Eu and ¹⁸O in water and the low thermal gradient of the area suggest that the water-rock interactions possibly occur deeper than 3670 ± 200 m. On the other hand, considering the relationship to the petroleum reservoir around the mud volcanoes, the depth of the gases can be derived from about 3600 m, a depth that is greater than that generally estimated for reservoirs whose gas is characterized by ¹³C-enriched CO₂. Oil biodegradation with CO₂ reduction likely occurs at a shallower depth along the seepage system of the mud volcano. The results contribute to the worldwide data set of gas genesis in mud volcanoes. Moreover, they further support the concept that most terrestrial mud volcanoes release thermogenic gas produced in very deep sediments and may be early indicators of oil biodegradation, an important problem in the petroleum industry.     

The tectonic significance of Italian magmatism: an alternative view to the popular interpretation

The Tyrrhenian rift zone has been the site of widespread magmatism since late Tortonian times. A pronounced asymmetrical distribution, reflecting the tectonic structure, characterizes Italian magmatism. Sodic basalts occur on the western Tyrrhenian flank and transitional-MORB basalts occur in the Tyrhenian Sea. The eastern flank, however, is characterized by K-alkaline and HK- to ultra-alkaline (e.g. carbonatites and melilitites) rocks. Major trace elements and isotopic compositions allow two major magmatic lineages to be identified: one relating to a non-radiogenic basaltic end-member and the other to a mantle end-member enriched in Ca, with high LILE/HFSE ratio and high Sr isotopic ratios. Their mantle sources are located within the lithosphere thermal boundary layer (TBL) and the metasomatized phlogopite-carbonate asthenosphere at the base of the TBL, respectively. The composition and spatial distribution of volcanism and relative mantle sources tend to map the geometry of the lithospheric mantle and to define a pronounced increase in depth from less than 60 km to about 100 km across the boundary between the thinned Tyrrhenian lithosphere and the Adriatic lithosphere. A mechanism of intra-continental passive rifting, which drives mantle upwelling, is sufficient to satisfy the petrological and geochemical constraints and the observed tectonic environment without requiring a subduction plane.     

印度洋北部马克兰增生楔泥火山分布及主控因素探讨

为了探讨低角度俯冲背景下活动大陆边缘泥火山的分布及其主控因素,收集了大量印度洋北部马克兰增生楔地区的沉积地层、断裂构造及泥火山或泥底辟等资料。综合分析结果显示,研究区沉积地层主要由上、下两部分组成,其中,下部较细的半远洋泥质地层具有“东厚西薄”的特征,而上部较粗的马克兰砂地层具有高速沉积的特征。这种密度倒置且后期沉积速率很高的地层分布特征为该区泥底辟或泥火山的形成提供了物质基础。在马克兰增生楔,阿拉伯板块向欧亚板块汇聚的速率具有“东快西慢”的特点,而且东、西两侧走滑断层和泥火山发育。结合俯冲角度同样较低的地中海海岭板块汇聚速率与泥火山的分布特征认为,马克兰增生楔东、西两侧的泥火山主要受走滑断层的控制,而增生楔内部的泥火山主要受板块汇聚速率、逆冲断裂以及密度倒置等综合因素的控制,表现为“东多西少”的特征。