Biogenic sedimentation factors of mineralization in the Neoproterozoic strata of the Baikal–Patom region

The formation environments of stratiform ore deposits in the Neoproterozoic Baikal–Patom region (BPR) have been considered. A model for the formation of the Sukhoi Log gold ore deposit in the Bodaibo zone has been put forward. The first stage is gold concentration by a chemolithotrophic bacterial community. Independently established facts suggest that bacterial communities may also have contributed to initial metal accumulation in the sediments of the Kholodnaya Pb–Zn deposit. The ore beds occur in the high-carbon sediments of the side and trough of a back-arc basin. Sedimentation (Dal’nyaya Taiga and Zhuya regional horizons) took place during the “back-arc basin–foreland basin” transition. This transition is characterized by increased sediment bioproductivity, which is clearly evidenced from the increased biophile-element content and taxonomic diversity of organic remains. Hundreds of microfossil sites in the Neoproterozoic BPR host littoral benthos (cyanobacteria and brown algae) and plankton (green algae). Most microfossils in the outer shelf, on the basin side, and in its trough belong to chemolithotrophic bacteria. These bacteria are assumed to have accumulated metals in the vent field of the back-arc basin. Studies showed the ability of microorganisms (bacteria, algae, fungi, etc.) to accumulate Fe, Mn, Au, Pb, Zn, and other metals. Bacterial communities are particularly important for metal accumulation in the vent fields of rift zones and areas of arc volcanism. All these conditions were observed in the Neoproterozoic BPR.     

Zircon–quartz–calcite segregations in carbonate–alkaline metasomatic rocks of the western Baikal region and their petrogenetic implications

Fine-grained segregations up to 5 mm in size composed of graphic intergrowths of zircon, quartz, calcite and containing up to 0.8 wt % SrO have been found in albite–riebeckite and dolomite–biotite metasomatic rocks formed after alaskite granite. They contain magnetite, titanomagnetite (25.4 wt % TiO₂), cerite-(Ce,Nd), rutile (up to 1.2 wt % Nb₂O₅), as well as rare micrograins of monazite-(Ce), bastnaesite-(Ce), and barite (up to 5.7 wt % SrO). The fine-grained structure of mineral aggregates suggests a metacolloidal nature. It is assumed that the zircon–quartz–calcite assemblage was formed due to exchange decomposition reaction between the salt phase of hydrothermal solution with predominant Na₂CO₃, elevated Zr and, to a lesser extent, Fe, Ti, LREE, Nb contents and dissolved calcium and silica compounds of a Na₂SiO₃ type.     

Early Hercynides of the Baikal–Vitim Fold System,western Transbaikal region

New data on the composition, age, structure, and geodynamic settings of the Upper Silurian–lower Middle Carboniferous rocks in the Baikal–Vitim Fold System (BVFS) are reported. These rocks make up the Early Hercynian structural stage of the BVFS, within which the Uda–Vitim, Vitimkan–Tsipa, and Turka–Kurba lithotectonic zones are recognized. The Early Hercynian stage combines rocks of two stratigraphic levels: Upper Silurian–Upper Devonian (S₂–D₃) and Upper–Devonian–Middle Carboniferous (D₃–C₂¹). On the basis of lithostratigraphic and spatiotemporal relationships between sedimentary and volcanic–sedimentary complexes of the Early Hercynian stage three formations are identified, which characterize the main tectonic regimes of the early half of the Late Paleozoic. It has been established that a common paleobasin that evolved through consecutively changing geodynamic settings at the passive and active continental margins existed in the Silurian (?)–early Middle Carboniferous in the northeastern part (in present-day coordinates) of the western Transbaikal region.     

Features of seismic activation of the Middle Baikal region, 2008–2011

Scenarios for developing focal zones of strong (M _w = 5.3) earthquakes that occurred in the Middle Baikal region in 2008 and 2011 are considered. The new (submeridional and sublatitudinal) lines of destruction of the Earth’s crust in the water area of the lake are recorded. The facts of seismoactive structures forming in the surrounding mountains (to the southeast) under typical rift conditions of movements are established, which indicates that the basin of Lake Baikal is expanding and growing due to active capturing and processing of its mountain surroundings.     

Radon in “nonradonic” ground waters of the Baikal region: Spatial and temporal variations

Based on the analysis of radon concentrations in several dozen springs and wells, three groups were distinguished for the waters classified as “nonradonic.” The spatial regularities of the distribution of these groups were revealed, along with the quantitative characteristic of the anomalies and the background, in view of their belonging to the Baikal and Transbaikal hydromineral provinces of the region.     

Successive recognition of significant and strong earthquake-prone areas: The Baikal–Transbaikal region

Doklady Earth Sciences - This report continues a series of works by the authors on earthquake-prone areas recognition by the algorithmic system FCAZ. For the first time, successive earthquake-prone...     

Gas–oil fluids in the formation of travertines in the Baikal rift zone

Active participation of gas–oil fluids in the processes of mineral formation and petrogenesis in travertines of the Arshan and Garga hot springs is substantiated. The parageneses of the products of pyrolytic decomposition and oxidation of the gas–oil components of hydrothermal fluids (amorphous bitumen, graphite-like CM, and graphite) with different genetic groups of minerals crystallized in a wide range of P–T conditions were established. Travertines of the Baikal rift zone were formed from multicomponent hydrous–gas–oil fluids by the following basic mechanisms of mineral formation: chemogenic, biogenic, cavitation, fluid pyrometamorphism, and pyrolysis.     

Global geochemical mapping and its implementation in the Asia–Pacific region

“IGCP” Projects 259 (International Geochemical Mapping) and 360 (Global Geochemical Baseline) under the aegis of UNESCO's International Geochemical Correlation Program made recommendations for standardizing geochemical mapping protocols and for conducting a wide-spaced sampling of the Earth's land surface based on a Global Reference Network of approximately 5000 160×160 km cells. A pilot study has been conducted throughout China during which these recommendations were implemented. During the pilot study, 500 floodplain samples representing drainage basins ranging in area from 1000 to 6000 km² were collected throughout China and analyzed. The widely spaced sampling used for the pilot study was compared to the very dense sampling (× million samplings of sediment for all of China) used for China's Regional Geochemical National Reconnaissance Program. The geochemical maps generated from the wide-spaced sampling are strikingly similar to those generated from data based on the detailed sampling. Such low density floodplain sampling presents a relatively low-cost way to get a quick overview of the geochemistry of a large area of the Earth's surface. The implementation of this project in the Asia–Pacific region and the problems encountered are discussed in the present paper.     

Energetic and spatial characterization of seismicity in the Algeria–Morocco region

We estimate the energetic and spatial characteristics of seismicity in the Algeria–Morocco region using a variety of seismic and statistical parameters, as a first step in a detailed investigation of regional seismic hazard. We divide the region into five seismotectonic regions, comprising the most important tectonic domains in the studied area: the Moroccan Meseta, the Rif, the Tell, the High Plateau, and the Atlas. Characteristic seismic hazard parameters, including the Gutenberg–Richter b-value, mean seismic activity rate, and maximum possible earthquake magnitude, were computed using an extension of the Aki–Utsu procedure for incomplete earthquake catalogs for each domain, based on recent earthquake catalogs compiled for northern Morocco and northern Algeria. Gutenberg–Richter b-values for each zone were initially estimated using the approach of Weichert (Bull Seismol Soc Am 70:1337–1346, 1980): the estimated b-values are 1.04 ± 0.04, 0.93 ± 0.10, 0.72 ± 0.03, 0.87 ± 0.02, and 0.77 ± 0.02 for the Atlas, Meseta, High Plateau, Rif, and Tell seismogenic zones, respectively. The fractal dimension D ₂ was also estimated for each zone. From the ratio D ₂/b, it appears that the Tell and Rif zones, with ratios of 2.09 and 2.12, respectively, have the highest potential earthquake hazard in the region. The Gutenberg–Richter relationship analysis allows us to derive that in the Tell and Rif, the number of earthquake with magnitude above Mw 4.0, since 1925 normalized to decade and to square cell with 100-km sides is equal to 2.6 and 1.91, respectively. This study provides the first detailed information about the potential seismicity of these large domains, including maximum regional magnitudes, characteristics of spatial clustering, and distribution of seismic energy release.

     

Energetic and spatial characterization of seismicity in the Algeria–Morocco region

We estimate the energetic and spatial characteristics of seismicity in the Algeria–Morocco region using a variety of seismic and statistical parameters, as a first step in a detailed investigation of regional seismic hazard. We divide the region into five seismotectonic regions, comprising the most important tectonic domains in the studied area: the Moroccan Meseta, the Rif, the Tell, the High Plateau, and the Atlas. Characteristic seismic hazard parameters, including the Gutenberg–Richter b-value, mean seismic activity rate, and maximum possible earthquake magnitude, were computed using an extension of the Aki–Utsu procedure for incomplete earthquake catalogs for each domain, based on recent earthquake catalogs compiled for northern Morocco and northern Algeria. Gutenberg–Richter b-values for each zone were initially estimated using the approach of Weichert (Bull Seismol Soc Am 70:1337–1346, 1980): the estimated b-values are 1.04 ± 0.04, 0.93 ± 0.10, 0.72 ± 0.03, 0.87 ± 0.02, and 0.77 ± 0.02 for the Atlas, Meseta, High Plateau, Rif, and Tell seismogenic zones, respectively. The fractal dimension D ₂ was also estimated for each zone. From the ratio D ₂/b, it appears that the Tell and Rif zones, with ratios of 2.09 and 2.12, respectively, have the highest potential earthquake hazard in the region. The Gutenberg–Richter relationship analysis allows us to derive that in the Tell and Rif, the number of earthquake with magnitude above Mw 4.0, since 1925 normalized to decade and to square cell with 100-km sides is equal to 2.6 and 1.91, respectively. This study provides the first detailed information about the potential seismicity of these large domains, including maximum regional magnitudes, characteristics of spatial clustering, and distribution of seismic energy release.     

Recent structures and tectonic regimes of the stress–strain state of the Earth’s crust in the northeastern sector of the Russian Arctic region

A comprehensive investigation aimed at determining seismotectonic types of destruction and the stress–strain state of the Earth’s crust in the main seismogenerating structures of the Arctic–Asian seismic belt is conducted for the territory of the northeastern sector of the Russian Arctic region. Based on the degree of activity of geodynamical processes, the regional principles for ranking neotectonic structures are elaborated, and neotectonic zoning is carried out based on the substantiated differentiation of the corresponding classes. Within the limits of the Laptev Sea, Kharaulakh, and Lena-Anabar segments, we analyzed I the structural–tectonic position of the most recent structures, II the deep structure parameters, III the parameters of the active fault system, and IV the parameters of the tectonic stress field, as revealed from tectonophysical analysis of Late Cenozoic fault and fold deformations. Based on the seismological data, the mean seismotectonic deformation tensors are calculated to determine, in combination with geological and geophysical data, the orientations of the principal stress axes and to reveal the structural–tectonic regularity for tectonic regimes of the stress–strain state of the Earth’s crust in the Arctic sector of the boundary between the Eurasian and North American lithospheric plates.     

Contamination of water and soil by the Erdenet copper–molybdenum mine in Mongolia

As one of the largest copper–molybdenum (Cu–Mo) mines in the world, the Erdenet Mine in Mongolia has been active since 1978 and is expected to continue operations for at least another 30 years. In this study, the potential impacts of mining activities on the soil and water environments have been evaluated. Water samples showed high concentrations of sulfate, calcium, magnesium, Mo, and arsenic, and high pH values in the order of high to low as follows: tailing water > Khangal River > groundwater. Statistical analysis and the δ²H and δ¹⁸O values of water samples indicate that the tailing water directly affects the stream water and indirectly affects groundwater through recharge processes. Soil and stream sediments are highly contaminated with Cu and Mo, which are major elements of ore minerals. Based on the contamination factor (CF), the pollution load index (PLI), and the degree of contamination (C_d), soil appears to be less contaminated than stream sediments. The soil particle size is similar to that of tailing materials, but stream sediments have much coarser particles, implying that the materials have different origins. Contamination levels in stream sediments display a tendency to decrease with distance from the mine, but no such changes are found in soil. Consequently, soil contamination by metals is attributable to wind-blown dusts from the tailing materials, and stream sediment contamination is caused by discharges from uncontained subgrade ore stock materials. Considering the evident impact on the soil and water environment, and the human health risk from the Erdenet Mine, measures to mitigate its environmental impact should be taken immediately including source control, the establishment of a systematic and continuous monitoring system, and a comprehensive risk assessment.     

Rb–Sr and Sm–Nd study of granite–charnockite association in the Pudukkottai region and the link between metamorphism and magmatism in the Madurai Block

Pudukkottai region in the northeastern part of the Madurai Block exposes the garnetiferous pink granite that intruded the biotite gneiss. Charnockite patches are associated with both the rock types. Rb–Sr biotite and Sm–Nd whole-rock isochron ages indicate a regional uplift and cooling at ～550 Ma. The initial Nd isotope ratios (\(\varepsilon _{\text {Nd}}^{\mathrm {t}}=-20\) to ?22) and Nd depleted-mantle model ages (T_DM = 2.25 to 2.79 Ga) indicate a common crustal source for the pink-granite and associated charnockite, while the biotite gneiss and the charnockite within it represent an older crustal source (\(\varepsilon _{\text {Nd}}^{\mathrm {t}}= -29\) and T_DM = > 3.2 Ga). The Rb–Sr whole-rock data and initial Sr–Nd isotope ratios also help demonstrate the partial but systematic equilibration of Sr isotope and Rb/Sr ratios during metamorphic mineral-reactions resulting in an ‘apparent whole-rock isochron’. The available geochronological results from the Madurai Block indicate four major periods of magmatism and metamorphism: Neoarchaean–Paleoproterozoic, Mesoproterozoic, mid-Neoproterozoic and late-Neoproterozoic. We suggest that the high-grade and ultrahigh-temperature metamorphism was preceded by magmatism which ‘prepared’ the residual crust to sustain the high P–T conditions. There also appears to be cyclicity in the tectono-magmatic events and an evolutionary model for the Madurai Block should account for the cyclicity in the preserved records.     

Modeling the Seismicity of the Altai–Sayan–Baikal Region

Doklady Earth Sciences - Numerical modeling of the dynamics of the block structure and the resulting seismicity of the Altai–Sayan–Baikal region has been carried out. The earthquake...     

Recognition of Strong Earthquake Prone Areas in the Altai–Sayan–Baikal Region

The locations of areas prone to strong earthquakes (M ≥ 6.0) in the Altai–Sayan–Baikal region are determined. Based on a scheme of morphostructural zoning of the region and by using the CORA-3 pattern recognition algorithm, all intersections of morphostructural lineaments are separated into two classes: the highly seismic intersections in the vicinities of which strong earthquakes can occur and low seismic in the vicinities of which only earthquakes with M < 6.0 are possible. Recognition was performed for the vectors the components of which were measured values of the geological–geophysical characteristics describing the respective intersection. The result obtained allows the zones of high seismic hazard to be identified more reliably in the region.

     

Stress state and deformation of the Earth's crust in the Altai–Sayan mountain region

We present the results of tectonophysical reconstruction of natural stresses of the Earth's crust in the Altai–Sayan mountain region using cataclastic analysis of fault slips and seismic data on the focal mechanisms of earthquakes. This method allows one to obtain the parameters of the total stress tensor by invoking additional data: generalized experimental data on the brittle fracture of rocks, seismic data on the released stress of strong earthquakes, and data on the topography and density of rocks. Results of the tectonophysical reconstruction of stresses showed significant inhomogeneity of the stress state, which is manifested not only in the variation of the strike and dip of the principal axes of the stress tensor, determining changes in the geodynamic regime of the Earth's crust, but also in the close location of the regions of high and low isotropic tectonic pressure in relation to the lithostatic pressure. The variance of the ratio of tectonic pressure to lithostatic pressure is in the range of 0.59–1.31, with an average value for the region close to unity. This paper discusses internal or external mechanisms capable of generating the stress field obtained by the tectonophysical reconstruction.     

Mg–Fe interdiffusion rates in wadsleyite and the diffusivity jump at the 410-km discontinuity

Mg–Fe interdiffusion rates have been measured in wadsleyite aggregates at 16.0–17.0 GPa and 1230–1530 °C by the diffusion couple method. Oxygen fugacity was controlled using the NNO buffer, and water contents of wadsleyite were measured by infrared spectroscopy. Measured asymmetric diffusion profiles, analyzed using the Boltzmann–Matano equation, indicate that the diffusion rate increases with increasing iron concentration and decreasing grain size. In the case of wadsleyite containing 50–90 weight ppm H₂O, the Mg–Fe interdiffusion coefficients at compositions of Mg/(Mg + Fe)=0.95 in the coarse-grained region (about 60 m) and 0.90 in the fine-grained region (about 6 m) were determined to be a D_Xmg = 0.95 (m² s^–1)=1.24 × 10^–9 exp[–172 (kJ mol^–1)/RT] and D_Xmg = 0.90 (m² s^–1)=1.77 × 10^–9 exp[–143 (kJ mol^–1)/RT], respectively. Grain-boundary diffusion rates were estimated to be about 4 orders of magnitude faster than the volume diffusion rate. Grain-boundary diffusion dominates when the grain size is less than a few tens of microns. Results for the nominally dry diffusion couple in the present study are roughly consistent with previous studies, taking into account differences in pressure and grain size, although water contents of samples were not clear in previous studies. We observed that the diffusivity is enhanced by about 1 order of magnitude in wadsleyite containing 300–2100 wt. ppm H₂O at 1230 °C, which is almost identical to the enhancement associated with a 300 °C increase in temperature. It is still not conclusive that a jump in diffusivity exists between olivine and wadsleyite because water contents of olivine in previous diffusion studies and effects of water on the olivine diffusivity are uncertain.     

Long-term electromagnetic core–mantle coupling and the Earth’s rotation acceleration in the Mesozoic Era

Growth lines in the mineralized tissues of living and fossil organisms often exhibit regular patterns that record daily, monthly, or annual cycles. Growth laminations in fossil corals and other marine invertebrates indicate long-term deceleration of the Earth’s rotation, probably largely due to tidal friction, resulting in a decline in the number of days per year over the Earth’s history. Fossils suggest the rate of decline has not been uniform, with the trend between the late Carboniferous and Cretaceous in particular departing from preceding and subsequent periods. However, insufficient data have obscured the nature and cause of the apparent halt in despinning within this time interval. Here we present new fossil geochronometer data that reveal a sustained acceleration in the Earth’s rotation in the early Mesozoic Era, lasting about 90 million years and producing a decrease in the length of day (LOD) at an average rate of about 3 ms/cy. The coincidence of this acceleration with certain geophysical events including the final assembly of Pangaea and a change in the intensity and stability of the geomagnetic field strongly suggests that its cause is rooted in the deep interior of the Earth. A similar explanation has been proposed for observed decadal variations in the Earth’s rotation. Our results suggest large-scale linkage of rotational variation, tectonics, and the geomagnetic field to core–mantle boundary (CMB) dynamics. Furthermore the newly identified acceleration in the Earth’s rotation which began at the end of the Paleozoic, and the geophysical factors that are associated with it, can ultimately bear on the causal mechanisms behind the Permo-Triassic mass extinction.     

Anoxia in the Domanik basin of the Timan–Pechora region

Analysis of the carbon isotopic composition in aryl carotenoid derivatives, including isorenieratene, in bitumen from domanikoid rocks of the sections cropping out along the Chut River revealed that they contain anomalously heavy carbon, which is determined by the formation of these compounds from green sulfur bacteria of the family Chlorobiaceae. These bacteria use the peculiar process of carbon fixing as HCO₃^? in the reversed tricarboxilic acid cycle. The fact of hydrosulfuric contamination of the photic water layer in the Domanik basin is confirmed by the plurality of data. Anoxity in shelf water of the middle Frasnian Timan–Pechora basin is evident from lithological features such as, for example, lamination of some rocks and mass death of the fauna.