Tectonic Setting and Nature of the Provenance of Sedimentary Rocks in Lanping Mesozoic- Cenozoic Basin： Evidence from Geochemistry of Sandstones

The geochemical composition of sandstones in the sedimentary basin is controlled mainly by the tectonic setting of the provenance, and it is therefore possible to reveal the tectonic setting of the provenance and the nature of source rocks in terms of the geochemical composition of sandstones. The major elements, rare-earth dements and trace elements of the Mesozoic-Cenozoic sandstones in the Lanping Basin are studied in this paper, revealing that the tectonic settings of the provenance for Mesozoic-Cenozoic sedimentary rocks in the Lanping Basin belong to a passive continental margin and a continental island arc. Combined with the data on sedimentary facies and palaeogeography, it is referred that the eastern part of the basin is located mainly at the tectonic setting of the passive continental margin before Mesozoic, whereas the western part may be represented by a continental island arc. This is compatible with the regional geology data. The protoliths of sedimentary rocks should be derived from the upper continental crust, and are composed mainly of felsic rocks, mixed with some andesitic rocks and old sediment components. Therefore, the Lanping Mesozoic-Cenozoic Basin is a typical continental-type basin. This provides strong geochemical evidence for the evolution of the paleo-Tethys and theb asin-range transition.     

Surface Processes Driving Intracontinental Basin Subsidence in the Context of India–Eurasia Collision: Evidence from Flexural Subsidence Modeling of the Cenozoic Southern Tarim Basin along the West Kunlun Foreland, NW Tibetan Plateau

The India–Eurasia collision has produced a number of Cenozoic deep intracontinental basins, which bear important information for revealing the far-afield responses to the remote collision. Despite their significance, their subsiding mechanism remains the subject of debate, with end-member models attributing it to either orogenic or sedimentary load. In this study, we conduct flexural subsidence modeling with a two-dimensional finite elastic plate model on the Hotan–Mazatagh section along the southern Tarim Basin, which defines a key region in the foreland of the West Kunlun Orogen, along the NW margin of the Tibetan Plateau. The modeling results indicate that the orogenic load of West Kunlun triggers the southern Tarim Basin to subside by up to less than ~6 km, with its impact weakening towards the basin interiors until ~230 km north from the Karakax fault. The sedimentary load, consisting of Cenozoic strata, forces the basin to subside by ~2 to ~7 km. In combination with the retreat of the proto-Paratethys Sea and the paleogeographic reorganization of the Tarim Basin, we propose that surface processes, in particular a shift from an exorheic to an endorheic drainage system associated with the consequent thick sedimentary load, played a decisive role in forming deep intracontinental basins in the context of the India–Eurasia collision.     

Genesis of the Weiquan Ag–Polymetallic Deposit in East Tianshan, China: Evidence from Zircon U–Pb Geochronology and C–H–O–S–Pb Isotope Systematics

The Weiquan Ag-polymetallic deposit is located on the southern margin of the Central Asian Orogenic Belt and in the western segment of the Aqishan-Yamansu arc belt in East Tianshan,northwestern China. Its orebodies, controlled by faults, occur in the lower Carboniferous volcanosedimentary rocks of the Yamansu Formation as irregular veins and lenses. Four stages of mineralization have been recognized on the basis of mineral assemblages, ore fabrics, and crosscutting relationships among the ore veins. Stage I is the skarn stage(garnet + pyroxene), Stage Ⅱ is the retrograde alteration stage(epidote + chlorite + magnetite ± hematite 士 actinolite ± quartz),Stage Ⅲ is the sulfide stage(Ag and Bi minerals + pyrite + chalcopyrite + galena + sphalerite + quartz ± calcite ± tetrahedrite),and Stage IV is the carbonate stage(quartz + calcite ± pyrite). Skarnization,silicification, carbonatization,epidotization,chloritization, sericitization, and actinolitization are the principal types of hydrothermal alteration. LAICP-MS U-Pb dating yielded ages of 326.5±4.5 and 298.5±1.5 Ma for zircons from the tuff and diorite porphyry, respectively. Given that the tuff is wall rock and that the orebodies are cut by a late diorite porphyry dike, the ages of the tuff and the diorite porphyry provide lower and upper time limits on the age of ore formation. The δ~(13)C values of the calcite samples range from-2.5‰ to 2.3‰, the δ~(18)O_(H2 O) and δD_(VSMOW) values of the sulfide stage(Stage Ⅲ) vary from 1.1‰ to 5.2‰ and-111.7‰ to-66.1‰, respectively,and the δ~(13)C, δ~(18)O_(H2 O) and δD_(V-SMOW) values of calcite in one Stage IV sample are 1.5‰,-0.3‰, and-115.6‰, respectively. Carbon, hydrogen, and oxygen isotopic compositions indicate that the ore-forming fluids evolved gradually from magmatic to meteoric sources. The δ~(34)S_(V-CDT) values of the sulfides have a large range from-6.9‰ to 1.4‰, with an average of-2.2‰, indicating a magmatic source, possibly with sedimentary contributions. The ~(206)Pb/~(204)Pb, ~(207)Pb/~(204)Pb, and ~(208)Pb/~(204)Pb ratios of the sulfides are 17.9848-18.2785,15.5188-15.6536, and 37.8125-38.4650, respectively, and one whole-rock sample at Weiquan yields~(206)Pb/~(204)Pb,~(207)Pb/~(204)Pb, and ~(208)Pb/~(204)Pb ratios of 18.2060, 15.5674, and 38.0511,respectively. Lead isotopic systems suggest that the ore-forming materials of the Weiquan deposit were derived from a mixed source involving mantle and crustal components. Based on geological features, zircon U-Pb dating, and C-H-OS-Pb isotopic data, it can be concluded that the Weiquan polymetallic deposit is a skarn type that formed in a tectonic setting spanning a period from subduction to post-collision. The ore materials were sourced from magmatic ore-forming fluids that mixed with components derived from host rocks during their ascent, and a gradual mixing with meteoric water took place in the later stages.     

Chemical and isotopic characteristics and origin of spring waters in the Lanping–Simao Basin,Yunnan, Southwestern China

The chemical and isotopic characteristics (oxygen, hydrogen, and strontium) of spring waters and isotopic compositions of helium (He) and neon (Ne) in gases escaping from spring waters in the Lanping–Simao Basin are studied. A total of twenty-one spring water samples (twelve hot springs, four cold springs, and five saline springs) and eleven gas samples were collected from the study area, including one spring and one gas sample from northern Laos. It is found that saline spring waters in the study area are of chloride type, cold spring waters are of carbonate type or sulfate type, and hot spring waters are of various types. High total dissolved solids levels in saline springs are significantly related to Upper Cretaceous–Paleocene salt-bearing strata. On the basis of hydrochemical geothermometry, the reservoir temperatures (T_r) for hot springs, cold springs, and saline springs are 65.5–144.1, 37.8–64.4, and 65.1–109.0 °C, respectively, and the circulation depths of saline springs are much larger than those of hot and cold springs. The oxygen and hydrogen isotopic compositions of springs in the Lanping–Simao Basin and northern Laos are primarily controlled by meteoric waters with obvious latitude and altitude effects, and are also influenced by δ¹⁸O exchange to some extent. Most Sr²⁺ in spring waters of the study area is derived from varied sources (carbonate, evaporite, and silicate mineral dissolution), and the Sr isotopic compositions are greatly influenced by volcanic rocks. Wide distribution of crust-derived He in the Lanping–Simao Basin and northern Laos reveal that faults in these areas may not descend to the upper mantle. It is concluded that water circulation in the study area may be limited above the upper mantle, while saline springs may originate from the Upper Cretaceous–Paleocene evaporites. Hydrochemical characteristics demonstrate affinities among the Lanping–Simao Basin, northern Laos, and Yanjing, eastern Tibet, while disaffinities are observed between these areas and Tengchong on the basis of the hydrochemical characteristics and noble gas isotopic compositions.     

The origins of the Mengye potash deposit in the Lanping–Simao Basin,Yunnan Province,Western China

The Lanping–Simao Basin (LSB) is a Mesozoic–Cenozoic continental margin rift basin in Western China. It formed during the opening and closing of the Tethys Ocean. This basin is also known as a “metal belt” as it hosts several metal deposits, besides, the Mengye potash deposit. However, the exact dates of the formation either in the Paleocene or the Cretaceous, and thus the origins of the marine, continental or mixed origins of the Mengye deposits, remain disputed. Based on the basin's evolution, materials of marine origin and/or remnant seawater should be present, but instead the salt layers of the Mengye potash deposit present typically continental lithological features. This study examines and reviews evaporative minerals, Br/Cl and I/Cl molar ratios, and isotopes of S, B, and Sr·I and I/Cl data for this area has not been previously reported. The basin's evaporative minerals are dominated by halite and sylvite. The amounts of anhydrite, chlorocalcite, langbeinite, glaserite, tachyhydrite and glauberite are small. All of these form in both marine and continental environments. The values of I and the I/Cl molar ratios of halite and sylvite are from 0.07 to 0.27 ppm, and from 0.03 to 0.11 × 10^− 6, respectively, dependent on organic substances. Br and molar Br/Cl values are from 89.08 to 555.45 ppm and from 0.06 × 10^− 3 to 0.38 × 10^− 3, respectively. All of the Br/Cl molar ratios are lower than those of seawater, and most of them are < 0.1, suggesting continental or mixed origin. Previously published δ³⁴S, δ¹¹B and ⁸⁷Sr/⁸⁶Sr values for evaporative minerals indicate a continental origin for the Mengye potash deposit. However, materials of hydrothermal origin are widely distributed in the basin and may have played an active role for the formation of the potash deposit. Thus the Mengye potash deposit could be of continental origin, with a remnant seawater trace.     

The Late Triassic I–Type Granites from the Longmu Co–Shuanghu Suture Zone in the interior of Tibetan Plateau, China: Petrogenesis and Implication for Slab Break–Off

The Jiangaidarina granitic mass(JM) is an important part of the magmatic belt in Longmu CoShuanghu Suture Zone(LSSZ) in the central Tibetan Plateau. An integrated research involving wholerock geochemistry, zircon LA-ICP-MS U-Pb ages and Hf isotopic compositions was carried out to define the timing, genesis and tectonic setting of the JM. Zircon LA-ICP-MS U-Pb ages have been obtained ranging from 210 to 215 Ma, rather than the Early Jurassic as previously thought. Fifteen granite samples contain hornblendes and show a negative correlation between P_2 O_5 and SiO_2, indicating that the JM is an I-type granite. All the granites are enriched in LREE relative to HREE, with negative Eu anomalies(Eu/Eu*=0.56-0.81), and have similar trace elements patterns, with depletion of Ba, Nb, Sr and P. These suggest that the JM was fractionated, and this is also proved by the characteristic of negative correlations between oxide elements(TiO_2, MgO, FeOt, MnO, CaO) and SiO_2. Almost all ε_(Hf)(t) values of the granites are between-10.3 and-5.8, implying that the JM has a crustal source intimately related with the South Qiangtang Block(SQB), except for one(+10.2), showing a minor contribution from mantle source.Moreover, relatively low Na_2 O/K_2 O ratios(0.42-0.93) and high A/CNK values(0.91-1.50) reflect that the JM was predominately derived from the medium-high potassium basaltic crust, interacted with greywacke. Our new geochemical data and geochronological results imply that the Late Triassic magmas were generated in a post-collisional tectonic setting, probably caused by slab break-off of the Longmu Co-Shuanghu Tethyan Ocean(LSTO). This mechanism caused the asthenosphere upwelling, formed extension setting, offered an enormous amount of heat, and provided favorable conditions for emplacement of voluminous felsic magmas. Furthermore, the LSTO could be completely closed during the Middle Triassic, succeed by continental collision and later the slab broke off in the Late Triassic.     

Typical Soft–Sediment Deformation Structures Induced by Freeze/Thaw Cycles: A Case Study of Quaternary Alluvial Deposits in the Northern Qiangtang Basin,Tibetan Plateau

With the objective of establishing a distinction between deformation structures caused by freeze/thaw cycles and those resulting from seismic activity, we studied three well–exposed alluvial deposits in a section at Dogai Coring, northern Qiangtang Basin, Tibetan Plateau. Deformation is present in the form of plastic structures(diapirs, folds and clastic dykes), brittle structures(micro–faults) and cryogenic wedges. These soft–sediment deformation features(except the micro–faults) are mainly cha...     

Emplacement Ages and Petrogenesis of the Molybdenum–bearing Granites in the Jinduicheng Area of East Qinling, China: Constraints from Zircon U–Pb Ages and Hf Isotopes

The Mesozoic porphyry assemblage in the Jinduicheng area is a special molybdenum area in China, the Mo deposits, including the Jinduicheng, Balipo, Shijiawan, Huanglongpu, are distributed. The emplacement age and geochemical features of the granites in the Jinduicheng area can provide essential information for the exploration and development of the porphyry molybdenum deposit. In this study, we report LA–ICP–MS zircon U–Pb age and zircon Hf isotopic compositions of granite porphyries from the Jinduicheng area, and provide insights on the petrogensis and source characteristics of the granites. The results show that the zircon U–Pb ages of the Jinduicheng granite porphyry (143±1 Ma) and the Balipo granite (154±1 Ma), agree well with the Re–Os ages of molybdenite in the Jinduicheng molybdenum polymetallic deposit (139±3 Ma) and the Balipo molybdenum polymetallic deposit (156±2 Ma), indicating that the emplacement of granite porphyries occurred between Late Jurassic and Early Cretaceous. Zircons granite from the Jinduicheng area give the εHf(t) values mainly ranging from ?10 to ?16, and ?20 to ?24, respectively, corresponding to two–stage model ages (tDM2: mainly focused on 1.86–2.0 Ga, and 2.2–2.6 Ga, respectively) of zircons of the granite from the Jinduicheng values. The ore–forming materials are mainly derived from crust, with minor mantle substances. Zircons of the granite from the Balipo area give εHf(t) values ranging from ?18 to ?20, ?28 to ?38, and ?42 to ?44, respectively, corresponding to two–stage model ages (tDM2: mainly focused on 1.88–3.0 Ga, and 3.2–3.90 Ga, respectively). the εHf(t) values of the Jinduicheng porphyry more than that of the Balipo porphyry, and two–stage model ages (tDM2) less than that of the Balipo porphyry, shows that he source of the porphyries originated from ancient lower crustal materials in the Jinduicheng area, and mixed younger components, more younger components contributed for the source of the Jinduicheng porphyry.     

Sedimentary Response of Different Fan Types to the Paleogene–Neogene Basin Transformation in the Kuqa Depression, Tarim Basin, Xinjiang Province

A group of alluvial fans formed in the early Paleogene represent marginal sedimentary facies at the foot of the South Tianshan Mountain, Kuqa Depression, Tarim Basin, Xinjiang province. Two types of fans occurred in the middle–late Paleogene Kumugeliemu and Suweiyi formations: one alluvial, and the other fan delta deposited in a lacustrine setting. Within the early Neogene Jidike Formation, coastal subaqueous fans developed, probably in a deeper water lacustrine setting. The three types of fans are stacked vertically in outcrop with the sequence in ascending order: bottom alluvial, middle fan-delta, and top subaqueous. The subaqueous is a typical coarse-fan deposit occurring in the glutinite member of the Jidike Formation in some wells. Laterally, from the foreland to the lacustrine settings, the distribution pattern of sedimentary facies represents the same three fan types sequentially. The spatial distribution of these fans was controlled by the Paleogene–Neogene Basin transformation, and evolution with different types of fans developed in the Kuqa Depression in response. In the Paleogene, the Kuqa Depression was a rift basin where an alluvial fan was deposited in the foreland setting, which, by early Neogene, became a foreland basin when the lake level changed. With any rise in lake level, fan-deltas migrated from lacustrine to foreland settings, whereas when the lake level fell, fan migration was reversed. In the early Neogene, with increasing slope and rising lake level, fans progressed and covered the previous fan-delta and lacustrine mudstone. Eventually, subaqueous fans developed, forming the present spatial configuration of these three fan types.     

The Shishugou Fauna of the Middle–Late Jurassic Transition Period in the Junggar Basin of Western China

The Middle–Late Jurassic transition period is a critical period for the evolution of terrestrial vertebrates, but the global fossil record from this time is relatively poor. The Shishugou Fauna of this period has recently produced significant fossil remains of dinosaurs and other vertebrate groups, some representing the earliest known members of several dinosaurian groups and other vertebrate groups and some representing the best-known specimens of their group. These discoveries are significant for our understanding of the origin and evolution of several vertebrate lineages. Radiometric dating indicates that the fauna is aged approximately 159–164 Ma. Comparisons with other similarly-aged terrestrial faunas such as Shaximiao and Yanliao show both taxonomic similarities and differences between these faunas and indicate that the Junggar deposits might have preserved the most complete vertebrate fossil record for a Middle–Late Jurassic Laurasian terrestrial fauna.     

Petrogenesis of Early Carboniferous Ultramafic–Mafic Volcanic Rocks in the Southern Changning–Menglian Belt, Southeastern Tibetan Plateau: Implications for the Evolution of the Paleo-Tethyan Ocean

The Changning–Menglian Belt represents the main Paleo-Tethyan Suture in the southeastern Tibetan Plateau, which divides Gondwana- and Eurasia-derived continental fragments from each other. The belt contains ultramafic–mafic volcanic rocks that provide evidence of the tectonic processes which operated during the evolution of the Paleo-Tethyan Ocean. New geochemical data for Early Carboniferous volcanics in the southern Changning–Menglian Belt show that wehrlites have cumulate and poikilitic textures, and contain low-Fo (84.2–87.2) olivine, clinopyroxene with low Mg# values (79.4–85.6), and spinel with high Cr# values (67.8–72.4). Estimated equilibrium temperatures obtained using olivine-spinel Fe-Mg exchange geothermometry range from 978°C to 1373°C (mean = 1205°C; n = 3). These observations combined with a lack of reaction or melt impregnation textures indicate that these units represent magmatic cumulates rather than having formed as a result of mantle-melt reactions. Both wehrlites and basalts in the belt have subparallel rare earth element (REE)-and primitive-mantle-normalized multi-element patterns with slightly positive Nb-Ta anomalies, but negligible Eu and Zr-Hf anomalies. The volcanics have similar Sr-Nd-Pb isotopic compositions with εNd(t) values of 4.2–4.5 (mean = 4.3; n = 3) and 4.0–4.4 (mean 4.2; n = 4), respectively, and also have similar immobile element ratios, such as Nb/La, Nb/U, Th/La, Zr/Nb, Th/Ta, La/Yb, Nb/Th, Nb/Y, and Zr/Y. These characteristics indicate both units have ocean island basalt (OIB)-like geochemical affinities, consistent with the fact that the clinopyroxene in the wehrlites is compositionally similar to OIB-related cumulus clinopyroxene. This suggests that both the wehrlites and basalts were derived from similar parental magmas that underwent generally closed-system magmatic differentiation dominated by fractionation of the olivine and clinopyroxene. This parental magma was likely generated in an oceanic seamount setting from an OIB-type mantle source (i.e., asthenospheric mantle) containing garnet-spinel lherzolite material. Combing this new data with that from oceanic seamount volcano-sedimentary suites derived from previous research enables the identification of a mature late Paleozoic ocean basin between the passive northeastern Gondwanan margin and the northward-migrating microcontinent of Lanping–Simao.     

Ordovician Proto–basin in South China and its Tectonic Implications: Evidence from the Detrital Zircon U–Pb Ages of the Ordovician in Central Hunan,China

Caledonian orogeny is another important tectonic event in South China Block after the breakup of the Rodinia supercontinent. With a view to constrain the tectonic evolution and proto–basin in South China, this paper reports the geochemical and zircon U-Pb dating data of the Ordovician strata in central Hunan, South China. Geochemical features and paleocurrent directions suggest that the lower Ordovician deposited in a passive continental margin basin with a provenance of quartzose components and...     

Genesis of the Changba–Lijiagou Giant Pb-Zn Deposit,West Qinling,Central China: Constraints from S-Pb-C-O isotopes

The extensive Changba-Lijiagou Pb-Zn deposit is located in the north of the Xihe–Chengxian ore cluster in West Qinling. The ore bodies are mainly hosted in the marble, dolomitic marble and biotite-calcite-quartz schist of the Middle Devonian Anjiacha Formation, and are structurally controlled by the fault and anticline. The ore-forming process can be divided into three main stages, based on field geological features and mineral assemblages. The mineral assemblages of hydrothermal stage I are pal...     

A Multi–fluid Constrain for the Forming of Potash Deposits in the Savannakhet Basin: Geochemical Evidence from Halite

The Khorat Plateau on the Indochina Terrane is known to have formed during the closure of the Tethys Ocean, although the origin of its potash mineral deposits is a topic of current debate. Data from a borehole on Savannakhet Basin is used in this study to re-define the evaporation processes of the study area. Geochemical analyses of halite from various borehole-derived evaporite strata have elucidated the fluid sources from which these ores formed. Measured δ11 B indicated that ore deposits formed primarily due to evaporation of seawater, although non-marine fluids affected the later stages of the evaporation process. Fluctuations in B and Br concentrations in carnallite-and sylvite-rich strata indicate the influence of fresh water. Boron concentration in carnallite unit indicated the influence of hydrothermal fluids. From the relative timings of these various fluid influxes, the evolution of these evaporates can be divided into four stages:(1) an initial marine evaporation at the beginning of the deposit's formation, where seawater(and minor fresh water) trapped on the uplifted Khorat Plateau produced sediments and salts with Br contents lower than those of normal marine-derived evaporites;(2) a transgression stage, where seawater recharged the basin;(3) a hydrothermal infiltration stage, which was coeval with the late Yanshan movement; and(4) a stage of fresh water supply, as recorded by fluctuations in B and Br contents, inferring intermittent fresh water influx into the basin. Thus, although evaporites on the Savannakhet Basin primarily formed via marine evaporation, they were also influenced to a significant degree by the addition of non–marine fresh water and hydrothermal fluids.     

Early Permian–Late Triassic Magmatism in the Tuotuohe Region of the Qinghai–Tibet Plateau: Constraints on the Tectonic evolution of the Western Segment of the Jinshajiang Suture

In this paper we present new zircon U–Pb ages, whole-rock major and trace element analyses, and zircon Hf isotopic data for magmatic rocks in the Tuotuohe region of the western segment of the Jinshajiang suture. Our aim is to constrain the Early Permian–Late Triassic tectonic evolution of the region. Zircons from the magmatic rocks of the Tuotuohe region are euhedral–subhedral in shape and display fine-scale oscillatory zoning as well as high Th/U ratios(0.4–4.6), indicating a magmatic origin. The zircon U–Pb ages obtained using LA–ICP–MS are 281 ± 1 Ma, 258 ± 1 Ma, 244 ± 1 Ma, and 216 ± 1 Ma, which indicate magmatism in the Early Permian–Late Triassic. A diorite from Bashihubei(BSHN) has SiO2 = 57.18–59.97 wt%, Al2O3 = 15.70–16.53 wt%, and total alkalis(Na2O + K2O) = 4.46–6.34 wt%, typical of calc-alkaline and metaluminous series. A gabbro from Bashibadaoban(BSBDB) belongs to the alkaline series, and is poor in SiO2(45.46–54.03 wt%) but rich in Al2O3(16.19–17.39 wt%) and total alkalis(Na2O + K2O = 5.48–6.26 wt%). The BSHN diorite and the BSBDB gabbro both display an enrichment of LREEs and LILEs and depletion of HFSEs, and they have no obvious Eu anomaly; they have relatively low MgO contents(2.54–4.93 wt%), Mg# values of 43 to 52, and low Cr and Ni contents(8.07–33.6 ppm and 4.41–14.2 ppm, respectively), indicating they differentiated from primitive mantle magmas. They have low Nb/U, Ta/U, and Ce/Pb ratios(1.3–9.6, 0.2–0.8, and 0.1–18.1, respectively), and their initial Hf isotopic ratios range from +9.6 to +16.9(BSHN diorite) and +6.5 to +12.6(BSBDB gabbro), suggesting their primary magmas were derived mainly from the partial melting of a mantle wedge that had been metasomatized by subduction fluids. Taking all the new data together, we conclude that the western and eastern segment of the Jinshajiang suture regions underwent identical processes of evolution in the Early Permian–Late Triassic: oceanic crust subduction before the Early Permian, continental collision during the Early–Middle Triassic, and post-collisional extension from the Late Triassic.     

Trilobite Biostratigraphy of the lower Paleozoic (Cambrian–Ordovician) Joseon Supergroup, Taebaeksan Basin, Korea

In Korea,trilobites are among the most intensively studied fossil groups in the past century and provide invaluable information about lower Paleozoic stratigraphy,paleogeography,and tectonics of the Korean Peninsula. Trilobites occur in the lower Paleozoic Joseon Supergroup of the Taebaeksan Basin which was part of the Sino-Korean Craton in the Paleozoic. The Joseon Supergroup is divided into the Taebaek,Yeongwol,and Mungyeong groups. The Taebaek and Yeongwol groups are richly fossiliferous,while the Mungyeong Group is poorly fossiliferous. Contrasting trilobite faunal contents of the Taebaek and Yeongwol groups resulted in two separate biostratigraphic schemes for the Cambrian–Ordovician of the Taebaeksan Basin. A total of 22 biozones or fossiliferous horizons were recognized in the Taebaek Group; 19 zones were established in the Yeongwol Group; and four biozones were known from the Mungyeong Group. These trilobite biozones of the Taebaeksan Basin indicate the Joseon Supergroup ranges in age from the Cambrian Series 2 to Middle Ordovician and can be correlated well with the formations of North China,South China,and Australia.     

The Origin of Paleokarst in the Huanglong Formation of the Eastern Sichuan Basin: Evidence from δ13C, δ18O and 87Sr/86Sr

Karst rocks from the Huanglong Formation exposed at the margin of the Eastern Sichuan Basin can be divided into four types:slightly corroded, moderately corroded porous, intensely corroded brecciated and intensely corroded and replaced secondary calcic karstic rocks. The carbon, oxygen and strontium isotope compositions of the various karst rocks are analyzed systematically and compared to rocks without karst corrosion. The results indicate that(1) the Huanglong Formation in the eastern Sichuan Basin was a restricted bay supplied and controlled by freshwater in which mudmicrite and mud-dolomicrite exhibit low δ13C and δ18O values and high 87Sr/86 Sr ratios;(2) all types of karstic rocks in the paleokarst reservoirs of the Huanglong Formation in the research area are affected by atmospheric freshwater with the δ13C and δ18O values and 87Sr/86 Sr ratios in the original formation approaching those of atmospheric freshwater, which reflects ancient hydrological conditions, fluid properties, isotopic source and the fractionation effect;(3) the intensely corroded and replaced secondary limestone is affected by a variety of diagenetic fluids, often reflected by δ13C and δ18O values, while the 87Sr/86 Sr ratios exhibit the strong degree of the corrosion;(4) after comparing the 87Sr/86 Sr ratios of each type of karst rock, the diagenetic fluids are determined to be mainly atmospheric freshwater, and depending on the strength of corrosion, and the low 87Sr/86 Sr ratio fluids in the layer will participate in the karst process. The carbon, oxygen, and strontium isotopes of different karstic reservoirs can provide meaningful geochemical information for forecasting and evaluating the development and distribution rules of the Huanglong Formation at the margin of the eastern Sichuan Basin in time and space.     

Geochronology,Mineralogy, and Geochemistry of the Tonsteins from the Permo–Carboniferous Benxi Formation,Ordos Basin,North China Craton

Tonstein layers are found worldwide in the Permo–Carboniferous coal-bearing strata. This study investigates the geochronology, mineralogy, and geochemistry of four tonstein samples from the Permo–Carboniferous Benxi Formation, Ordos Basin, North China Craton(NCC). The typical features of the studied tonsteins include thin beds, lateral continuity, angular quartz grains, and euhedral zircons with similar U-Pb ages, indicating a significant pyroclastic origin. In addition, the tonstein samples hav...     

Sedimentary Conditions of Evaporites in the Late Jurassic Xiali Formation, Qiangtang Basin: Evidence from Geochemistry Records

The Qiangtang Basin (QB), located in the central Tibetan Plateau, is a Jurassic marine basin and one of the most important prospective salt resource belts in China. In recent decades, many outcrops of gypsiferous?bed have been found in the Jurassic marine strata in the basin. Salt springs with abnormally high sodium (Na+) contents had been identified in the Late Jurassic Xiali Formation (Fm.) in the basin in the last years. However, to date, no potash or halite deposits have been identified in the QB. Gypsum outcrops and salt springs are very important?signs in the investigation of halite and potash deposits. Therefore, the Xiali Fm. is?a potentially valuable layer to evaluate for the possible presence of halite and potash deposits in the basin. However,?few studies?have explored the formation?conditions of evaporites in the unit. Here, we present detailed geochemical records from the Yanshiping section related to the study of the formation?conditions of evaporites in the Xiali Fm. of the QB. Climate proxies based on the obviously increased anion concentrations of SO42? and Cl? and the significant correlation?coefficients of Ca2+-SO42? (R = 0.985) and Na+-Cl? (R = 0.8974) reveal that the upper member of the Xiali Fm. (the upper Xiali Fm.) formed under an arid climate and evolved into the sulfate phase or early chloride phase. Provenance proxies based on the obviously increased K+ and Na+ ion concentrations and the significant correlation?coefficient of Na+-Cl? (R = 0.8974) suggest that the upper Xiali Fm. featured optimal provenance conditions for the possible formation of halite deposits. The regression and the semi-closed tidal?flat environment in the upper Xiali Fm. were favorable for the formation of potash and halite deposits. The low Mg2+ /Ca2+ values (mean value = 1.82) and significant Na+-Cl? correlation?coefficient (R = 0.8974) also suggest that the upper Xiali Fm. is the layer most likely to contain potential halite deposits. In addition, the macroscopic correlations of tectonism, provenance, paleoclimate, saliferous strata and sedimentary?environment between the QB and the adjoining Amu Darya Basin in Central Asia reveal that the two basins shared similar geologic settings that were favorable for the formation of evaporites during the Late Jurassic. Therefore, the upper Xiali Fm. is a valuable layer to explore for halite deposit and may be potentially valuable in the future exploration for potash deposits in the QB.