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1.
This study reports measurements of the Raman spectra of Lake Baikal gas hydrates and estimations of the hydration number of methane-rich samples. The hydration number of gas hydrates retrieved from the southern Baikal Basin (crystallographic structure I) was approx. 6.1. Consistent with previous results, the Raman spectra of gas hydrates retrieved from the Kukuy K-2 mud volcano in the central Baikal Basin indicated the existence of crystallographic structures I and II. Measurements of the dissociation heat of Lake Baikal gas hydrates by calorimetry (from the decomposition of gas hydrates to gas and water), employing the hydration number, revealed values of 53.7–55.5?kJ?mol–1 for the southern basin samples (structure I), and of 54.3–55.5?kJ?mol–1 for the structure I hydrates and 62.8–64.2?kJ?mol–1 for the structure II hydrates from the Kukuy K-2 mud volcano.  相似文献   

2.
Differences in fluids origin, creation of overpressure and migration are compared for end member Neogene fold and thrust environments: the deepwater region offshore Brunei (shale detachment), and the onshore, arid Central Basin of Iran (salt detachment). Variations in overpressure mechanism arise from a) the availability of water trapped in pore-space during early burial (deepwater marine environment vs arid, continental environment), and b) the depth/temperature at which mechanical compaction becomes a secondary effect and chemical processes start to dominate overpressure development. Chemical reactions associated with smectite rich mud rocks in Iran occur shallow (∼1900 m, smectite to illite transformation) causing load-transfer related (moderate) overpressures, whereas mechanical compaction and inflationary overpressures dominate smectite poor mud rocks offshore Brunei. The basal detachment in deepwater Brunei generally lies below temperatures of about 150 °C, where chemical processes and metagenesis are inferred to drive overpressure development. Overall the deepwater Brunei system is very water rich, and multiple opportunities for overpressure generation and fluid leakage have occurred throughout the growth of the anticlines. The result is a wide variety of fluid migration pathways and structures from deep to shallow levels (particularly mud dykes, sills, laccoliths, volcanoes and pipes, fluid escape pipes, crestal normal faults, thrust faults) and widespread inflationary-type overpressure. In the Central Basin the near surface environment is water limited. Mechanical and chemical compaction led to moderate overpressure development above the Upper Red Formation evaporites. Only below thick Early Miocene evaporites have near lithostatic overpressures developed in carbonates and marls affected by a wide range of overpressure mechanisms. Fluid leakage episodes across the evaporites have either been very few or absent in most areas. Locations where leakage can episodically occur (e.g. detaching thrusts, deep normal faults, salt welds) are sparse. However, in both Iran and Brunei crestal normal faults play an important role in the transmission of fluids in the upper regions of folds.  相似文献   

3.
Differences in fluids origin, creation of overpressure and migration are compared for end member Neogene fold and thrust environments: the deepwater region offshore Brunei (shale detachment), and the onshore, arid Central Basin of Iran (salt detachment). Variations in overpressure mechanism arise from a) the availability of water trapped in pore-space during early burial (deepwater marine environment vs arid, continental environment), and b) the depth/temperature at which mechanical compaction becomes a secondary effect and chemical processes start to dominate overpressure development. Chemical reactions associated with smectite rich mud rocks in Iran occur shallow (∼1900 m, smectite to illite transformation) causing load-transfer related (moderate) overpressures, whereas mechanical compaction and inflationary overpressures dominate smectite poor mud rocks offshore Brunei. The basal detachment in deepwater Brunei generally lies below temperatures of about 150 °C, where chemical processes and metagenesis are inferred to drive overpressure development. Overall the deepwater Brunei system is very water rich, and multiple opportunities for overpressure generation and fluid leakage have occurred throughout the growth of the anticlines. The result is a wide variety of fluid migration pathways and structures from deep to shallow levels (particularly mud dykes, sills, laccoliths, volcanoes and pipes, fluid escape pipes, crestal normal faults, thrust faults) and widespread inflationary-type overpressure. In the Central Basin the near surface environment is water limited. Mechanical and chemical compaction led to moderate overpressure development above the Upper Red Formation evaporites. Only below thick Early Miocene evaporites have near lithostatic overpressures developed in carbonates and marls affected by a wide range of overpressure mechanisms. Fluid leakage episodes across the evaporites have either been very few or absent in most areas. Locations where leakage can episodically occur (e.g. detaching thrusts, deep normal faults, salt welds) are sparse. However, in both Iran and Brunei crestal normal faults play an important role in the transmission of fluids in the upper regions of folds.  相似文献   

4.
The paper presents the results of a study on the geomorphic structure, tectonic setting, and volcanism of the volcanoes and volcanic ridges in the deep Central Basin of the Sea of Japan. The ridges rise 500–600 m above the acoustic basement of the basin. These ridges were formed on fragments of thinned continental crust along deep faults submeridionally crossing the Central Basin and the adjacent continental part of the Primorye. The morphostructures of the basin began to submerge below sea level in the Middle Miocene and reached their contemporary positions in the Pliocene. Volcanism in the Central Basin occurred mostly in the Middle Miocene–Pliocene and formed marginal-sea basaltoids with OIB (ocean island basalt) geochemical signatures indicating the lower-mantle plume origin of these rocks. The OIB signatures of basaltoids tend to be expressed better in the eastern part of the Central Basin, where juvenile oceanic crust has developed. The genesis of this crust is probably related to rising and melting of the Pacific superplume apophyse.  相似文献   

5.
A geological and geochemical study has been carried out to investigate the relationships between major mud volcano structures and deep fluid migration in the Cheleken peninsula, in the South Caspian Basin. The fluid geochemistry allowed the origin and migration of the saline waters and the hydrocarbons to be deduced along with the regional source and reservoir rocks. The emitted waters formed by the mixing of deep highly saline water from the main source rocks of the Maykop Fm with the Caspian-like pore water contained in the Pliocene reservoirs. The water composition is very similar to that emitted by the mud volcanoes in Azerbaijan, allowing comparisons to be done between the reservoirs in the western and eastern sides of the South Caspian Basin. The associated oil is derived from a mixed type II/III kerogen deposited in a sub-oxic marine environment and generated during the early oil window. The oil biomarkers indicate that the source rock is the Maykop Fm., as previously determined for the other areas of the South Caspian Basin.The spontaneous emissions, showing different morphologies, are mainly aligned along normal and transtensive fault systems, which provide effective pathways for rapid fluid ascent from deep reservoirs to the surface.  相似文献   

6.
Located at the intersection between a NW-trending slip system and NE-trending rift system in the northern South China Sea, the Qiongdongnan Basin provides key clues for us to understand the proposed extrusion of the Indochina Block along with Red River Fault Zone and extensional margins. In this paper we for the first time systematically reveal the striking structural differences between the western and eastern sector of the Qiongdongnan Basin. Influenced by the NW-trending slip faults, the western Qiongdongnan Basin developed E–W-trending faults, and was subsequently inverted at 30–21 Ma. The eastern sector was dominated by faults with NE orientation before 30 Ma, and thereafter with various orientations from NE, to EW and NW during the period 30–21 Ma; rifting display composite symmetric graben instead of the composite half graben or asymmetric graben in the west. The deep and thermal structures in turn are invoked to account for such deformation differences. The lithosphere of the eastern Qiongdongnan Basin is very hot and thinned because of mantle upwelling and heating, composite symmetric grabens formed and the faults varied with the basal plate boundary. However, the Southern and Northern Uplift area and middle of the central depression is located on normal lithosphere and formed half grabens or simple grabens. The lithosphere in the western sector is transitional from very hot to normal. Eventually, the Paleogene tectonic development of the Qiongdongnan Basin may be summarized into three stages with dominating influences, the retreat of the West Pacific subduction zone (44–36 Ma), slow Indochina block extrusion together with slab-pull of the Proto-South China Sea (36–30 Ma), rapid Indochina block extrusion together with the South China Sea seafloor spreading (30–21 Ma).  相似文献   

7.
Four mud volcanoes of several kilometres diameter named Amon, Osiris, Isis, and North Alex and located above gas chimneys on the Central Nile Deep Sea Fan, were investigated for the first time with the submersible Nautile. One of the objectives was to characterize the seafloor morphology and the seepage activity across the mud volcanoes. The seepage activity was dominated by emissions of methane and heavier hydrocarbons associated with a major thermal contribution. The most active parts of the mud volcanoes were highly gas-saturated (methane concentrations in the water and in the sediments, respectively, of several hundreds of nmol/L and several mmol/L of wet sediment) and associated with significantly high thermal gradients (at 10 m below the seafloor, the recorded temperatures reached more than 40 °C). Patches of highly reduced blackish sediments, mats of sulphide-oxidizing bacteria, and precipitates of authigenic carbonate were detected, indicative of anaerobic methane consumption. The chemosynthetic fauna was, however, not very abundant, inhibited most likely by the high and vigorous fluxes, and was associated mainly with carbonate-crust-covered seafloor encountered on the southwestern flank of Amon. Mud expulsions are not very common at present and were found limited to the most active emission centres of two mud volcanoes, where slow extrusion of mud occurs. Each of the mud volcanoes is fed principally by a main narrow channel located below the most elevated areas, most commonly in the centres of the structures. The distribution, shape, and seafloor morphology of the mud volcanoes and associated seeps over the Central Nile Deep Sea Fan are clearly tectonically controlled.  相似文献   

8.
《Marine Geology》2005,219(1):1-17
The El Arraiche field is a new mud volcano field discovered near the Moroccan shelf edge in the Gulf of Cadiz that consists of 8 mud volcanoes in water depths from 200 to 700 m. The largest mud volcano in the field (Al Idrissi mud volcano) is 255 m high and 5.4 km wide. The cluster was discovered during a survey with the RV Belgica and studied further during Leg 2 of the TTR 12 survey onboard the R/V Prof Logachev. The 2002 surveys yielded detailed multibeam bathymetry over a 700 km2 study area, dense grids of high-resolution seismic data, deep-tow sub bottom profiles, sidescan sonar mosaics over the major structures. Selected video imagery lines, video guided grab samples, dredge samples, gravity cores, and box cores were collected for groundtruthing purposes. Eight mud volcanoes in water depths from 200 to 700 m cluster around two, sub-parallel anticlines and associated active extensional faults. Rock clasts and regional seismic data locate the El Arraiche field over a Late Miocene–Pliocene extensional basin. The onset of mud volcanic activity is estimated at about 2.4 Ma and probably roots in the Cretaceous–Miocene accretionary wedge. Stacked outflows are visible up to a depth of about 500 m below the sea floor. The occurrence of long-lived mud volcanoes bear witness to continued overpressure generation at depth, either by in situ oil and gas generation or by focussed flow and accumulation in the area. Geochemical analyses of pore water from cores demonstrate the presence of thermogenic hydrocarbon processes. The activity of the mud volcanoes is indicated by the thickness of hemi-pelagic sediments covering extruded mud breccia, the occurrence of seep-typical fauna, the degree of mixing between thermogenic and biogenic hydrocarbon processes, or the depth to the base of the sulphate reduction zone. Given its structural setting and the evidence of thermogenic and biogenic hydrocarbons, the area has promising hydrocarbon potential but remains untested.  相似文献   

9.
The Dongsha Basin, circling Dongsha Island that is amid the northern margin of the South China Sea, is characterized by thin (∼0.5 km) Cenozoic sediments veneering on thick (up to 5 km) Mesozoic strata. Recently, several geophysical and geological surveys, including multiple channel reflection seismic, sub-bottom profiling and benthic dredging, have been conducted on the slope southwest to the Dongsha Island, where the water depth varies from 400 m to 2000 m. A novel discovery is numerous submarine mud volcanoes of various sizes over there, typically 50–200 m high and 0.5–5 km wide. Geophysical profiles document their unusual features, e.g., roughly undulating seafloor, high-amplitude seabed reflectivity, foggy hyperbolic diffractions up to 50 m in water column above seabed, and internal reflection chaos and wipe-out down to 2–3 km level or deeper below the seabed. Benthic dredging from the mud volcanoes gives abundant faunas of high diversity, e.g., scleractinian (stony coral), gorgonian, black coral, thiophil tubeworm, glass sponge, bryozoan etc., indicating booming chemosynthetic community, among which the Lophelia pertusa-like coral and the Euretidae-like glass sponges are the first reports in the South China Sea. Concomitantly with them, there are also abundant authigenic carbonate nodules and slabs, raw, brecciated and breccias with bio-clasts congregation. Besides, there coexist massive mudflows and allogenic coarse-grained quartz, feldspar and tourmaline most likely brought out by mud volcanism. Geochemical analysis of the bottom water samples give dissolved methane concentration up to 4 times higher than the background average. These results lend comprehensive evidences for the ongoing and historical mud volcanism. The escaping methane gas is inferred to source mainly from the Mesozoic strata. Occupying a large province of the deep water slope, ca. 1000 km2 or more, the mud volcanoes is prospective for gas hydrate and natural gas for the Dongsha Basin.  相似文献   

10.
Mud volcanoes and gas vents in the Okhotsk Sea area   总被引:5,自引:0,他引:5  
Gas emissions from mud volcanoes on Sakhalin Island and water-column gas flares arising from cold seeps in the Okhotsk Sea appear to be related. They are likely activated by tectonic movements along the transform plate boundary separating the Okhotsk Sea Plate from the Eurasian and Amur plates. Gas vents (flares) and methane anomalies occur in the waters offshore Sakhalin Island, along with NE-SW-trending mounds and fluid escape structures on the seafloor. The intersection of the NE-striking transverse faults on land with the Central Sakhalin and Hokkaido-Sakhalin shear zones apparently determines the sites of mud volcanoes, a pattern that continues offshore where the intersection with the East Sakhalin and West Derugin shear zones determines the sites of the submarine gas vents.  相似文献   

11.
The geology of Mars and the stratigraphic characteristics of its uppermost crust (mega-regolith) suggest that some of the pervasively-occurring pitted cones, mounds, and flows may have formed through processes akin to terrestrial mud volcanism. A comparison of terrestrial mud volcanism suggests that equivalent Martian processes likely required discrete sedimentary depocenters, volatile-enriched strata, buried rheological instabilities, and a mechanism of destabilization to initiate subsurface flow. We outline five formational scenarios whereby Martian mud volcanism might have occurred: (A) rapid deposition of sediments, (B) volcano-induced destabilization, (C) tectonic shortening, (D) long-term, load-induced subsidence, and (E) seismic shaking. We describe locations within and around the Martian northern plains that broadly fit the geological context of these scenarios and which contain mud volcano-like landforms. We compare terrestrial and Martian satellite images and examine the geological settings of mud volcano provinces on Earth in order to describe potential target areas for piercement structures on Mars. Our comparisons help to evaluate not only the role of water as a functional component of geological processes on Mars but also how Martian mud volcanoes could provide samples of otherwise inaccessible strata, some of which could contain astrobiological evidence.  相似文献   

12.
High-resolution single channel and multichannel seismic reflection profiles and multibeam bathymetric and backscatter data collected during several cruises over the period 1999 to 2007 have enabled characterising not only the seabed morphology but also the subsurface structural elements of the Yuma, Ginsburg, Jesús Baraza and Tasyo mud volcanoes (MVs) in the Gulf of Cádiz at 1,050–1,250 m water depth. These MVs vary strongly in morphology and size. The data reveal elongated cone-shaped edifices, rimmed depressions, and scarps interpreted as flank failures developed by collapse, faulting, compaction and gravitational processes. MV architecture is characterised by both extrusive and intrusive complexes, comprising stacked edifices (including seabed cones and up to four buried bicones) underlain by chaotic vertical zones and downward-tapering cones suggesting feeder systems. These intrusive structures represent the upper layer of the feeder system linking the fluid mud sources with the constructional edifices. The overall architecture is interpreted to be the result of successive events of mud extrusion and outbuilding alternating with periods of dormancy. Each mud extrusion phase is connected with the development of an edifice, represented by a seabed cone or a buried bicone. In all four MVs, the stacked edifices and the intrusive complexes penetrate Late Miocene–Quaternary units and are rooted in the Gulf of Cádiz wedge emplaced during the late Tortonian. Major phases of mud extrusion and outbuilding took place since the Late Pliocene, even though in the Yuma and Jesús Baraza MVs mud volcanism started in the Late Miocene shortly after the emplacement of the Gulf of Cádiz wedge. This study shows that fluid venting in the eastern sector of the Gulf of Cádiz promoted the outbuilding of large long-lived mud volcanoes active since the Late Miocene, and which have been reactivated repeatedly until recent times.  相似文献   

13.
Echo sounders served to locate a large number of shallow- and deepwater gas seeps at the bottom of all three basins of Lake Baikal during the years 2005 to 2008. A substantial proportion of the shallow gas seeps was located near the delta of the Selenga River, and at the Posolskii uplift. Deepwater gas seeps were recorded at the lake bed both inside and outside of areas where a bottom-simulating reflector was identified in seismic profiles. By monitoring the activity of gas emissions at the gas seeps, times of episodic gas ebullition could be distinguished from times of persistent gas bubble streams. A maximum gas flare height of more than 950 m above the bottom was recorded at the St. Petersburg mud volcano located in the central basin of Lake Baikal. Based on calculations from echo sounder data, the ascent velocity of gas bubbles reached 40 cm/s. In the area of gas seepage, there was a thick near-bottom layer, in which the gradient of water temperature was equal to the adiabatic gradient. This implies complete mixing of the water close to the lake bed, resulting from ascending gas bubbles released at seep sites. Analyses of vertical temperature profiles indicate possibly localized upwelling up to the lake surface when gas emissions are intensive.  相似文献   

14.
Piercement structures such as hydrothermal vent complexes, pockmarks, and mud volcanoes, are found in various geological settings but are often associated with faults or other fluid-focussing features. This article aims to investigate and understand the mechanisms responsible for the formation of piercement structures in sedimentary basins and the role of strike-slip faulting as a triggering mechanism for fluidization. For this purpose four different approaches were combined: fieldwork, analogue experiments, and mathematical modeling for brittle and ductile rheologies. The results of this study may be applied to several geological settings, including the newly formed Lusi mud volcano in Indonesia (Mazzini et al., 2007).  相似文献   

15.
Thermal measurements and hydrate mapping in the vicinity of the K-2 mud volcano in Lake Baikal have revealed a particular type of association of thermal anomalies (29–121?mW?m–2) near hydrate-forming layers. Detailed coring within K-2 showed that hydrates are restricted to two distinct zones at sub-bottom depths exceeding 70–300?cm. Temperature data from stations with hydrate recovery and degassing features all display low thermal gradients. Otherwise, the thermal gradients within the mud volcano are generally increased. These findings imply a more complicated thermal regime than often assumed for mud volcanoes, with important roles for both fluids and hydrates. The coexistence of neighbouring low and high thermal anomalies is interpreted to result from discharging and recharging fluid activity, rather than hydrate thermodynamics. It is suggested that hydrates play a key role in controlling the fluid circulation pattern at an early stage. At a later stage, the inflow of undersaturated lake water would favour the dissolution of structure I hydrates and the formation of structure II hydrates, the latter having been observed on top of structure I hydrates in the K-2 mud volcano.  相似文献   

16.
Acoustic investigations of mud volcanoes in the Sorokin Trough, Black Sea   总被引:1,自引:0,他引:1  
The Sorokin Trough (Black Sea) is characterized by diapiric structures formed in a compressional tectonic regime that facilitate fluid migration to the seafloor. We present acoustic data in order to image details of mud volcanoes associated with the diapirs. Three types of mud volcanoes were distinguished: cone-shaped, flat-topped, and collapsed structures. All mud volcanoes, except for the Kazakov mud volcano, are located above shallow mud diapirs and diapiric ridges. Beyond the known near-surface occurrence of gas hydrates, bottom simulating reflectors are not seen on our seismic records, but pronounced lateral amplitude variations and bright spots may indicate the presence of gas hydrates and free gas.  相似文献   

17.
We report on the isotopic composition of dissolved inorganic carbon (DIC) in pore-water samples recovered by gravity coring from near-bottom sediments at gas hydrate-bearing mud volcanoes/gas flares (Malenky, Peschanka, Peschanka 2, Goloustnoe, and Irkutsk) in the Southern Basin of Lake Baikal. The δ13C values of DIC become heavier with increasing subbottom depth, and vary between ?9.5 and +21.4‰ PDB. Enrichment of DIC in 13C indicates active methane generation in anaerobic environments near the lake bottom. These data confirm our previous assumption that crystallization of carbonates (siderites) in subsurface sediments is a result of methane generation. Types of methanogenesis (microbial methyl-type fermentation versus CO2-reduction) were revealed by determining the offset of δ13C between dissolved CH4 and CO2, and also by using δ13C and δD values of dissolved methane present in the pore waters. Results show that both mechanisms are most likely responsible for methane generation at the investigated locations.  相似文献   

18.
The Bransfield Basin is a narrow and elongated active rift basin located between the Antarctic Peninsula and the South Shetland Islands. The Bransfield Basin is composed of three small basins, and two of them, the Central and Eastern Bransfield Basins, were surveyed during a recent cruise (GEBRA 93). The full swath bathymetry coverage as well as the single-channel seismic reflection and magnetic profiles that have been acquired, help us to better understand the morphostructure and recent evolution of the Bransfield Basin. Six large volcanic edifices aligned with the basin axis stick out of the sedimented seafloor of the Central Bransfield Basin. In contrast, the Eastern Bransfield Basin is characterised by four deep troughs displaying a rhombic-shape, and small, scattered volcanic cones located in the southwestern half basin. Seamount volcanism plays an important role in the formation of new crust in the Bransfield Basin. The larger seamounts of the Central Bransfield Basin are located at the intersection of the two main orthogonal sets of faults (longitudinal ENE-WSW and transversal NNW-SSE). Morphological analysis of the seamounts indicates a multi-staged volcano-tectonic construction. The distribution and shape of these edifices suggests that both volcanism and extension are concentrated at the same preferential areas through time. This might be related to the fracturation style of the continental crust. The Central and Eastern Bransfield Basins are very different in morphostructure, volcanism, and sedimentary cover. The Central Bransfield Basin shows evidence of NW-SE extensional faulting and focused active MORB-volcanism interpreted as result of incipient seafloor spreading. The Eastern Bransfield Basin is still in a rifting stage, mainly dominated by a NW-SE extension and some left-lateral strike-slip component probably related to the South Scotia Ridge.J. Acosta, J. Baraza, P. Bart, A.M. Calafat, J.L. Casamor, M. De Batist, G. Ercilla, G. Francés, E. Ramos, J.L. Sanz, and A. Tassone.  相似文献   

19.
During the MVSEIS-08 cruise of 2008, ten new mud volcanoes (MVs) were discovered on the offshore Moroccan continental margin (Gulf of Cádiz) at water depths between 750 and 1,600?m, using multibeam bathymetry, backscatter imagery, high-resolution seismic and gravity core data. Mud breccias were recovered in all cases, attesting to the nature of extrusion of these cones. The mud volcanoes are located in two fields: the MVSEIS, Moundforce, Pixie, Las Negras, Madrid, Guadix, Almanzor and El Cid MVs in the western Moroccan field, where mud volcanoes have long been suspected but to date not identified, and the Boabdil and Al Gacel MVs in the middle Moroccan field. Three main morphologies were observed: asymmetric, sub-circular and flat-topped cone-shaped types, this being the first report of asymmetric morphologies in the Gulf of Cádiz. Based on morpho-structural analysis, the features are interpreted to result from (1) repeated constructive (expulsion of fluid mud mixtures) and destructive (gravity-induced collapse and submarine landsliding) episodes and (2) interaction with bottom currents.  相似文献   

20.
The petroleum system of the Kunsan Basin in the Northern South Yellow Sea Basin is not well known, compared to other continental rift basins in the Yellow Sea, despite its substantial hydrocarbon potential. Restoration of two depth-converted seismic profiles across the Central Subbasin in the southern Kunsan Basin shows that extension was interrupted by inversions in the Late Oligocene-Middle Miocene that created anticlinal structures. One-dimensional basin modeling of the IIH-1Xa well suggests that hydrocarbon expulsion in the northeastern margin of the depocenter of the Central Subbasin peaked in the Early Oligocene, predating the inversions. Hydrocarbon generation at the dummy well location in the depocenter of the subbasin began in the Late Paleocene. Most source rocks in the depocenter passed the main expulsion phase except for the shallowest source rocks. Hydrocarbons generated from the depocenter are likely to have migrated southward toward the anticlinal structure and faults away from the traps along the northern and northeastern margins of the depocenter because the basin-fill strata are dipping north. Faulting that continued during the rift phase (∼ Middle Miocene) of the subbasin probably acted as conduits for the escape of hydrocarbons. Thus, the anticlinal structure and associated faults to the south of the dummy well may trap hydrocarbons that have been charged from the shallow source rocks in the depocenter since the Middle Miocene.  相似文献   

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