The contribution of old and new water to a storm hydrograph determined by tracer addition to a whole catchment

Two tracer experiments have been carried out at an enclosed catchment in southern Norway. The catchment was brought to steady state with respect to rainfall and runoff prior to the tracer addition. A known concentration of lithium bromide was then added to the rainfall for the duration of each event. The tight control on tracer concentration and rainfall amount enabled assessment of the contribution of old and new water to runoff, the dominant flow pathways and soil water residence times during a storm event. A significant volume of ‘old’ water contributes to runoff despite the hydrologically responsive nature of the catchment and several hours of tracer injected rainfall are required before ‘new’ water becomes the dominant runoff source. After 34 h of tracer injection, ‘new’ water apparently contributes c. 83% to instantaneous flow and c. 55% of the total tracer input to the catchment has been lost in runoff. Recovery of the tracer from soil water indicates that the organic soil surface layer is the dominant flow pathway for rainwater through the catchment and that a significant pathway also exists at the soil–bedrock interface. New water is retained in deep pockets of soil for several days. Assessment of the conservative behaviour of the tracer suggests that 10–14% of the input Br⁻ is retained in the soil and the tracer is not conservative. Laboratory experiments indicate that sorption of Br⁻ to organic soil is the likely mechanism of retention. This process is probably concentration dependent and will have occurred predominantly during the initial period of tracer application. Copyright © 2000 John Wiley & Sons, Ltd.     

Effectivity of dissolved SF6 tracer for clarification of rainfall–runoff processes in a forested headwater catchment

Understanding rainfall‐runoff processes is crucial for prevention and prediction of water‐related natural disasters. Sulfur hexafluoride (SF₆) is a potential tracer, but few researches have applied it for rainfall‐runoff process studies. We observed multiple tracers including SF₆ in spring water at 1‐ to 2‐hr intervals during rainstorm events to investigate the effectivity of SF₆ tracer in rainfall–runoff studies through the clarification of rainfall–runoff process. The target spring is a perennial spring in a forested headwater catchment with an area of 0.045 km² in Fukushima, Japan. The relationship between the SF₆ concentration in spring water and the spring discharge volume was negative trend; the SF₆ concentration in spring water becomes low as the spring discharge volume increases especially during rainstorms. The hydrograph separation using SF₆ and chloride ion tracers was applied for determining the contribution of principal sources on rainfall–runoff water. It suggested more than 60% contribution of bedrock groundwater at the rainfall peak and high percentage contribution continued even in the hydrograph recession phase. Based on observed low SF₆ concentration in groundwater after heavy rainfall, the replacement of groundwater near the spring with bedrock groundwater is indicated as a mechanism for water discharge with low SF₆ concentration during rainfall events. Consequently, rainstorm events play an important role as triggers in discharging water stored in the deeper subsurface area. In addition, SF₆ tracer is concluded as one of the strongest tracers for examining rainfall–runoff process studies. And, therefore, this study provided new insights into the dynamics of groundwater and its responses to rainfall in terms of SF₆ concentration variance in water in headwater regions.     

Impacts of forest conversion and agriculture practices on water pathways in Southern Brazil

Land‐use/cover change (LUCC), and more specifically deforestation and multidecadal agriculture, is one of the various controlling factors of water fluxes at the hillslope or catchment scale. We investigated the impact of LUCC on water pathways and stream stormflow generation processes in a subtropical region in southern Brazil. We monitored, sampled and analysed stream water, pore water, subsurface water, and rainwater for dissolved silicon concentration (DSi) and ¹⁸O/¹⁶O (δ¹⁸O) signature to identify contributing sources to the streamflow under forest and under agriculture. Both forested and agricultural catchments were highly responsive to rainfall events in terms of discharge and shallow groundwater level. DSi versus δ¹⁸O scatter plots indicated that for both land‐use types, two run‐off components contributed to the stream discharge. The presence of a dense macropore network, combined with the presence of a compact and impeding B‐horizon, led to rapid subsurface flow in the forested catchment. In the agricultural catchment, the rapid response to rainfall was mostly due to surface run‐off. A 2‐component isotopic hydrograph separation indicated a larger contribution of rainfall water to run‐off during rainfall event in the agricultural catchments. We attributed this higher contribution to a decrease in topsoil hydraulic conductivity associated with agricultural practices. The chemical signature of the old water component in the forested catchment was very similar to that of the shallow groundwater and the pore soil water: It is therefore likely that the shallow groundwater was the main source of old water. This is not the case in the agricultural catchments where the old water component had a much higher DSi concentration than the shallow groundwater and the soil pore water. As the agricultural catchments were larger, this may to some extent simply be a scale effect. However, the higher water yields under agriculture and the high DSi concentration observed in the old water under agriculture suggest a significant contribution of deep groundwater to catchment run‐off under agriculture, suggesting that LUCC may have significant effects on weathering rates and patterns.     

Quantifying aggregation and change in runoff source in accordance with catchment area increase in a forested headwater catchment

There has been a great deal of research interest regarding changes in flow path/runoff source with increases in catchment area. However, there have been very few quantitative studies taking subscale variability and convergence of flow path/runoff source into account, especially in relation to headwater catchments. This study was performed to elucidate how the contributions and discharge rates of subsurface water (water in the soil layer) and groundwater (water in fractured bedrock) aggregate and change with catchment area increase, and to elucidate whether the spatial variability of the discharge rate of groundwater determines the spatial variability of stream discharge or groundwater contribution. The study area was a 5‐km² forested headwater catchment in Japan. We measured stream discharge at 113 points and water chemistry at 159 points under base flow conditions. End‐member mixing analysis was used to separate stream water into subsurface water and groundwater. The contributions of both subsurface water and groundwater had large variability below 1 km². The contribution of subsurface water decreased markedly, while that of groundwater increased markedly, with increases in catchment area. The specific discharge of subsurface water showed a large degree of variability and decreased with catchment area below 0.1 km², becoming almost constant above 0.1 km². The specific discharge of groundwater showed large variability below 1 km² and increased with catchment area. These results indicated that the variabilities of stream discharge and groundwater contribution corresponded well with the variability of the discharge rate of groundwater. However, below 0.1 km², it was necessary to consider variations in the discharge rates of both subsurface water and groundwater. Copyright © 2016 John Wiley & Sons, Ltd.     

Precipitation‐runoff processes in Shimen hillslope micro‐catchment of Taihang Mountain,north China

Precipitation runoff is a critical hillslope hydrological process for downslope streamflow and piedmont/floodplain recharge. Shimen hillslope micro‐catchment is strategically located in the central foothill region of Taihang Mountains, where runoff is crucial for water availability in the piedmont corridors and floodplains of north China. This study analyzes precipitation‐runoff processes in the Shimen hillslope micro‐catchment for 2006–2008 using locally designed runoff collection systems. The study shows that slope length is a critical factor, next only to precipitation, in terms of runoff yield. Regression analysis also shows that runoff is related positively to precipitation, and negatively to slope length. Soil mantle in the study area is generally thin and is therefore not as critical a runoff factor as slope length. The study shows a significant difference between overland and subsurface runoff. However, that between the 0–10 and 10–20 cm subsurfaces is insignificant. Runoff hardly occurs under light rains (<10 mm), but is clearly noticeable under moderate‐to‐rainstorm events. In the hillslope catchment, vertical infiltration (accounting for 42–84% of the precipitation) dominates runoff processes in subsurface soils and weathered granite gneiss bedrock. A weak lateral flow (at even the soil/bedrock interface) and the generally small runoff suggest strong infiltration loss via deep percolation. This is critical for groundwater recharge in the downslope piedmont corridors and floodplains. This may enhance water availability, ease water shortage, avert further environmental degradation, and reduce the risk of drought/flood in the event of extreme weather conditions in the catchment and the wider north China Plain. Copyright © 2011 John Wiley & Sons, Ltd.     

Isotope hydrology of the Allt a' Mharcaidh catchment,Cairngorms, Scotland: implications for hydrological pathways and residence times

The hydrology of oxygen‐18 (¹⁸O) isotopes was monitored between 1995 and 1998 in the Allt a' Mharcaidh catchment in the Cairngorm Mountains, Scotland. Precipitation (mean δ¹⁸O=−7·69‰) exhibited strong seasonal variation in δ¹⁸O values over the study period, ranging from −2·47‰ in the summer to −20·93‰ in the winter months. As expected, such variation was substantially damped in stream waters, which had a mean and range of δ¹⁸O of −9·56‰ and −8·45 to −10·44‰, respectively. Despite this, oxygen‐18 proved a useful tracer and streamwater δ¹⁸O variations could be explained in terms of a two‐component mixing model, involving a seasonally variable δ¹⁸O signature in storm runoff, mixing with groundwater characterized by relatively stable δ¹⁸O levels. Variations in soil water δ¹⁸O implied the routing of depleted spring snowmelt and enriched summer rainfall into streamwaters, probably by near‐surface hydrological pathways in peaty soils. The relatively stable isotope composition of baseflows is consistent with effective mixing processes in shallow aquifers at the catchment scale. Examination of the seasonal variation in δ¹⁸O levels in various catchment waters provided a first approximation of mean residence times in the major hydrological stores. Preliminary estimates are 0·2–0·8 years for near‐surface soil water that contributes to storm runoff and 2 and >5 years for shallow and deeper groundwater, respectively. These ¹⁸O data sets provide further evidence that the influence of groundwater on the hydrology and hydrochemistry of upland catchments has been underestimated. Copyright © 2000 John Wiley & Sons, Ltd.     

Hydrological processes of a closed catchment‐lake system in a semi‐arid Mediterranean environment

Data collected in 4 years of field observations were used in conjunction with continuous simulation models to study, at the small‐basin scale, the water balance of a closed catchment‐lake system in a semi‐arid Mediterranean environment. The open water evaporation was computed with the Penman equation, using the data set collected in the middle of the lake. The surface runoff was partly measured at the main tributary and partly simulated using a distributed, catchment, hydrological model, calibrated with the observed discharge. The simplified structure of the developed modelling mainly concerns soil moisture dynamics and bedrock hydraulics, whereas the flow components are physically based. The calibration produced high efficiency coefficients and showed that surface runoff is greatly affected by soil water percolation into fractured bedrock. The bedrock reduces the storm‐flow peaks and the interflow and has important multi‐year effects on the annual runoff coefficients. The net subsurface outflow from the lake was calculated as the residual of the lake water balance. It was almost constant in the dry seasons and increased in the wet seasons, because of the moistening of the unsaturated soil. During the years of observation, rainfall 30% higher than average caused abundant runoff and a continuous rise in the lake water levels. The analysis allows to predict that, in years with lower than the average rainfall, runoff will be drastically reduced and will not be able to compensate for negative balance between precipitation and lake evaporation. Such highly unsteady situations, with great fluctuations in lake levels, are typical of closed catchment‐lake systems in the semi‐arid Mediterranean environment. Copyright © 2012 John Wiley & Sons, Ltd.     

The influence of preferential flow on hillslope hydrology in a semi‐arid watershed (in the Spanish Dehesas)

Preferential flow is known to influence hillslope hydrology in many areas around the world. Most research on preferential flow has been performed in temperate regions. Preferential infiltration has also been found in semi‐arid regions, but its impact on the hydrology of these regions is poorly known. The aim of this study is to describe and quantify the influence of preferential flow on the hillslope hydrology from small scale (infiltration) to large scale (subsurface stormflow) in a semi‐arid Dehesa landscape. Precipitation, soil moisture content, piezometric water level and discharge data were used to analyse the hydrological functioning of a catchment in Spain. Variability of soil moisture content during the transition from dry to wet season (September to November) within horizontal soil layers leads to the conclusion that there is preferential infiltration into the soils. When the rainfall intensity is high, a water level rapidly builds up in the piezometer pipes in the area, sometimes even reaching soil surface. This water level also drops back to bedrock within a few hours (under dry catchment conditions) to days (under wet catchment conditions). As the soil matrix is not necessarily wet while this water layer is built up, it is thought to be a transient water table in large connected pores which drain partly to the matrix, partly fill up bedrock irregularities and partly drain through subsurface flow to the channels. When the soil matrix becomes wetter the loss of water from macropores to the matrix and bedrock decreases and subsurface stormflow increases. It may be concluded that the hillslope hydrological system consists of a fine matrix domain and a macropore domain, which have their own flow characteristics but which also interact, depending on the soil matrix and macropore moisture contents. The macropore flow can result in subsurface flow, ranging from 13% contribution to total discharge for a large event of high intensity rainfall or high discharge to 80% of total discharge for a small event with low intensity rainfall or low discharge. During large events the fraction of subsurface stormflow in the discharge is suppressed by the large amount of surface runoff. Copyright © 2008 John Wiley & Sons, Ltd.     

Ressi experimental catchment: Ecohydrological research in the Italian pre-Alps

Ressi is a small (2.4 ha) forested catchment located in the Italian pre-Alps. The site became an experimental catchment to investigate the water fluxes in the soil–plant–atmosphere continuum and the impact of vegetation on runoff generation in 2012. The elevation of the catchment ranges from 598 to 721 m a.s.l. and the climate is humid temperate. The bedrock consists of rhyolites and dacites; the soil is a Cambisol. The catchment is covered by a dense forest, dominated by beech, chestnut, maple, and hazel trees. The field set up includes measurements of the rainfall in an open area, streamflow at the outlet, soil moisture at various depths and locations, and depth to water table in six piezometers at a 5- or 10-min interval. Samples of precipitation, stream water, shallow groundwater and soil water are collected monthly for tracer analysis (stable isotopes (²H and ¹⁸O), electrical conductivity and major ions), and during selected rainfall–runoff events to determine the contribution of the various sources to runoff. Since 2017, soil and plant water samples have been collected to determine the sources of tree transpiration. Data collected in the period 2012–2016 are publicly available. Data collection is ongoing, and the data set is expected to be updated on an annual basis to include the most recent measurements.     

Near-surface water fluxes and their controls in a sloping heterogeneously layered volcanic soil beneath a supra-wet tropical montane cloud forest (NW Costa Rica)

Tropical montane cloud forests (TMCF) receive additional (‘occult’) inputs of water from fog and wind-driven rain. Together with the concomitant reduction in evaporative losses, this typically leads to high soil moisture levels (often approaching saturation) that are likely to promote rapid subsurface flow via macropores. Although TMCF make up an estimated 6.6% of all remaining montane tropical forest and occur mostly in steep headwater areas that are protected in the expectation of reduced downstream flooding, TMCF hillslope hydrological functioning has rarely been studied. To better understand the hydrological response of a supra-wet TMCF (net precipitation up to 6535 mm y⁻¹) on heterogeneously layered volcanic ash soils (Andosols), we examined temporal and spatial soil moisture dynamics and their contribution to shallow subsurface runoff and stormflow for a year (1 July 2003–30 June 2004) in a small headwater catchment on the Atlantic (windward) slope near Monteverde, NW Costa Rica. Particular attention was paid to the partitioning of water fluxes into lateral subsurface flow and vertical percolation. The presence of a gravelly layer (C-horizon) at ~25 cm depth of very high hydraulic conductivity (geometric mean: 502 mm h⁻¹) intercalated between two layers of much lower conductivity (7.5 and 15.7 mm h⁻¹ above and below, respectively), controlled both surface infiltration and delayed vertical water movement deeper into the soil profile. Soil water fluxes during rainfall were dominated by rapid lateral flow in the gravelly layer, particularly at high soil moisture levels. In turn, this lateral subsurface flow controlled the magnitude and timing of stormflow from the catchment. Stormflow amount increased rapidly once topsoil moisture content exceeded a threshold value of ~0.58 cm³ cm⁻³. Responses were not affected appreciably by rainfall intensity because soil hydraulic conductivities across the profile largely exceeded prevailing rainfall intensities.     

Field investigation and modelling of coupled stream discharge and shallow water‐table dynamics in a small Mediterranean catchment (Sardinia)

In the semi‐arid Mediterranean environment, the rainfall–runoff relationships are complex because of the markedly irregular patterns in rainfall, the seasonal mismatch between evaporation and rainfall, and the spatial heterogeneity in landscape properties. Watersheds often display considerable non‐linear threshold behavior, which still make runoff generation an open research question. Our objectives in this context were: to identify the primary processes of runoff generation in a small natural catchment; to test whether a physically based model, which takes into consideration only the primary processes, is able to predict spatially distributed water‐table and stream discharge dynamics; and to use the hydrological model to increase our understanding of runoff generation mechanisms. The observed seasonal dynamics of soil moisture, water‐table depth, and stream discharge indicated that Hortonian overland‐flow was negligible and the main mechanism of runoff generation was saturated subsurface‐flow. This gives rise to base‐flow, controls the formation of the saturated areas, and contributes to storm‐flow together with saturation overland‐flow. The distributed model, with a 1D scheme for the kinematic surface‐flow, a 2D sub‐horizontal scheme for the saturated subsurface‐flow, and ignoring the unsaturated flow, performed efficiently in years when runoff volume was high and medium, although there was a smoothing effect on the observed water‐table. In dry years, small errors greatly reduced the efficiency of the model. The hydrological model has allowed to relate the runoff generation mechanisms with the land‐use. The forested hillslopes, where the calibrated soil conductivity was high, were never saturated, except at the foot of the slopes, where exfiltration of saturated subsurface‐flow contributed to storm‐flow. Saturation overland‐flow was only found near the streams, except when there were storm‐flow peaks, when it also occurred on hillslopes used for pasture, where soil conductivity was low. The bedrock–soil percolation, simulated by a threshold mechanism, further increased the non‐linearity of the rainfall–runoff processes. Copyright © 2013 John Wiley & Sons, Ltd.     

Time-series of δ26Mg values in a headwater catchment reveal decreasing magnesium isotope variability from precipitation to runoff

Data on temporal variability in Mg isotope ratios of atmospheric deposition and runoff are critical for decreasing the uncertainty associated with construction of isotope mass balances in headwater catchments, and statistical evaluation of isotope differences among Mg pools and fluxes. Such evaluations, in turn, are needed to distinguish between biotic and abiotic contributions to Mg²⁺ in catchment runoff. We report the first annual time-series of δ²⁶Mg values simultaneously determined for rainfall, canopy throughfall, soil water and runoff. The studied 55-ha catchment, situated in western Czech Republic, is underlain by Mg-rich amphibolite and covered by mature spruce stands. Between 1970 and 1996, the site received extremely high amounts of acid deposition and fly ash form nearby coal-burning power plants. The δ²⁶Mg values of open-area precipitation (median of −0.79‰) at our study site were statistically indistinguishable from the δ²⁶Mg values of throughfall (−0.73‰), but significantly different from the δ²⁶Mg values of soil water (−0.55‰) and runoff (−0.55‰). The range of δ²⁶Mg values during the observation period decreased in the order: open-area precipitation (0.57‰) > throughfall (0.27‰) > runoff (0.21‰) > soil water (0.16‰). The decreasing variability in δ²⁶Mg values of Mg²⁺ from precipitation to soil water and runoff reflected an increasing homogenization of atmospheric Mg in the catchment and its mixing with geogenic Mg. In addition to atmospheric Mg, runoff also contained Mg mobilized from the three major solid Mg pools, bedrock (δ²⁶Mg of −0.32‰), soil (−0.28‰), and vegetation (−0.31‰). The drought of summer 2019 did not affect the nearly constant δ²⁶Mg value of runoff. Collectively, our data show that within-catchment processes buffer the Mg isotope variability of the atmospheric input.     

Hydrological processes controlling ground and surface water flow from a hypermaritime forest–peatland complex,Diana Lake Provincial Park,British Columbia,Canada

The proposed harvesting of previously undeveloped forests in north coastal British Columbia requires an understanding of hydrological responses. Hydrometric and isotopic techniques were used to examine the hydrological linkages between meteoric inputs to the surface‐groundwater system and runoff response patterns of a forest‐peatland complex. Quickflow accounted for 72–91% of peak storm discharge. The runoff ratio was lowest for open peatland areas with thick organic horizons (0·02–0·05) due to low topographic gradients and many surface depressions capable of retaining surface water. Runoff ratio increased comparatively for ephemeral surface seep flows (0·06–0·40) and was greatest in steeply sloping forest communities with more permeable soils (0·33–0·69). The dominant mechanism for runoff generation was saturated shallow subsurface flow. Groundwater fluxes from the organic horizon of seeps (1·70–1·72 m³ day^?1 m^?1) were an important component of quickflow. The homogeneous δ²H? δ¹⁸O composition of groundwater indicated attenuation of the seasonal rainfall signal by mixing during recharge. The positive correlation (r² = 0·64 and 0·38, α = 0·05) between slope index and δ¹⁸O values in groundwater suggests that the spatial pattern in the δ¹⁸O composition along the forest‐peatland complex is influenced by topography and provides evidence that topographic indices may be used to predict groundwater residence time. Copyright © 2006 John Wiley & Sons, Ltd.     

Interpretation of homogeneity in δ18O signatures of stream water in a nested sub-catchment system in north-east Scotland

The isotope hydrology of a set of nested sub-catchments in the north-east of Scotland has been studied to examine the mixing processes and residence times of water in the catchments. The measured δ¹⁸O in stream waters was found to be exceptionally uniform both temporally and spatially. Hydrochemical mixing analyses showed that groundwater contributes between 62 and 90% of the stream flow in all sub-catchments. Model analysis indicated that the δ¹⁸O in stream water is indicative of a highly mixed system in which near surface runoff appears to be mixed with groundwater, within the soil profile, before being released from the catchment. Small fluctuations in the stream water δ¹⁸O response are generated by a small proportion (<10%) of less-well mixed water in infiltration excess runoff during storm events. A comparative application of the model to a nearby catchment, which has a lower proportion of groundwater runoff, demonstrated contrasting behaviour, with significantly less mixing of waters occurring and a more distinct difference in the age of runoff generated by different flow paths. This highlighted that standard methods for characterization of mixing mechanisms are often insufficient and may not discriminate between systems that have retained quite distinct flow paths throughout catchment transit, and those which have been mixed at some stage. Model sensitivity analysis also indicated that the simulated mean residence time of water varies most strongly in response to different parameters compared with the δ¹⁸O response. This has implications for estimating water residence times from isotope data. Copyright © 2008 John Wiley & Sons, Ltd.     

Using stable isotopes to identify major flow pathways in a permafrost influenced alpine meadow hillslope during summer rainfall period

Global warming has leaded to permafrost degradation, with potential impacts on the runoff generation processes of permafrost influenced alpine meadow hillslope. Stable isotopes have the potential to trace the complex runoff generation processes. In this study, precipitation, hillslope surface and subsurface runoff, stream water, and mobile soil water (MSW) at different hillslope positions and depths were collected during the summer rainfall period to analyse the major flow pathway based on stable isotopic signatures. The results indicated that (a) compared with precipitation, the δ²H values of MSW showed little temporal variation but strong heterogeneity with enriched isotopic ratios at lower hillslope positions and in deeper soil layers. (b) The δ²H values of middle-slope surface runoff and shallow subsurface flow were similar to those of precipitation and MSW of the same soil layer, respectively. (c) Middle-slope shallow subsurface flow was the major flow pathway of the permafrost influenced alpine meadow hillslope, which turned into surface runoff at the riparian zone before contributing to the streamflow. (d) The slight variation of δ²H values in stream water was shown to be related to mixing processes of new water (precipitation, 2%) and old water (middle-slope shallow subsurface flow, 98%) in the highly transmissive shallow thawed soil layers. It was inferred that supra-permafrost water levels would be lowered to a less conductive, deeper soil layer under further warming and thawing permafrost, which would result in a declined streamflow and delayed runoff peak. This study explained the “rapid mobilization of old water” paradox in permafrost influenced alpine meadow hillslope and improved our understanding of permafrost hillslope hydrology in alpine regions.     

Response time and water origin in a steep nested catchment in the Italian Dolomites

In this study, we investigate the surface flow time of rise in response to rainfall and snowmelt events at different spatial scales and the main sources originating channel runoff and spring water in a steep nested headwater catchment (Rio Vauz, Italian Dolomites), characterized by a marked elevation gradient. We monitored precipitation at different elevations and measured water stage/streamflow at the outlet of two rocky subcatchments of the same size, representative of the upper part of the catchment dominated by outcropping bedrock, at the outlet of a soil‐mantled and vegetated subcatchment of similar size but different morphology, and at the outlet of the main catchment. Hydrometric data are coupled with stable isotopes and electrical conductivity sampled from different water sources during five years, and used as tracers in end‐member mixing analysis, application of two component mixing models and analysis of the slope of the dual‐isotope regression line. Results reveal that times of rise are slightly shorter for the two rocky subcatchments, particularly for snowmelt and mixed rainfall/snowmelt events, compared to the soil‐mantled catchment and the entire Rio Vauz Catchment. The highly‐variable tracer signature of the different water sources reflects the geomorphological and geological complexity of the study area. The principal end‐members for channel runoff and spring water are identified in rainfall and snowmelt, which are the dominant water sources in the rocky upper part of the study catchment, and soil water and shallow groundwater, which play a relevant role in originating baseflow and spring water in the soil‐mantled and vegetated lower part of the catchment. Particularly, snowmelt contributes up to 64 ± 8% to spring water in the concave upper parts of the catchment and up to 62 ± 11% to channel runoff in the lower part of the catchment. These results offer new experimental evidences on how Dolomitic catchments capture and store rain water and meltwater, releasing it through a complex network of surface and subsurface flow pathways, and allow for the construction of a preliminary conceptual model on water transmission in snowmelt‐dominated catchments featuring marked elevation gradients.     

Water balance estimation under the challenge of data scarcity in a hyperarid to Mediterranean region

Water budget analyses are important for the evaluation of the water resources in semiarid and arid regions. The lack of observed data is the major obstacle for hydrological modelling in arid regions. The aim of this study is the analysis and calculation of the natural water resources of the Western Dead Sea subsurface catchment, one which is highly sensitive to rainfall resulting in highly variable temporal and spatial groundwater recharge. We focus on the subsurface catchment and subsequently apply the findings to a large‐scale groundwater flow model to estimate the groundwater discharge to the Dead Sea. We apply a semidistributed hydrological model (J2000g), originally developed for the Mediterranean, to the hyperarid region of the Western Dead Sea catchment, where runoff data and meteorological records are sparsely available. The challenge is to simulate the water budget, where the localized nature of extreme rainstorms together with sparse runoff data results in few observed runoff and recharge events. To overcome the scarcity of climate input data, we enhance the database with mean monthly rainfall data. The rainfall data of 2 satellites are shown to be unsuitable to fill the missing rainfall data due to underrepresentation of the steep hydrological gradient and temporal resolution. Hydrological models need to be calibrated against measured values; hence, the absence of adequate data can be problematic. Therefore, our calibration approach is based on a nested strategy of diverse observations. We calculate a direct surface runoff of the Western Dead Sea surface area (1,801 km²) of 3.4 mm/a and an average recharge (36.7 mm/a) for the 3,816 km² subsurface drainage basin of the Cretaceous aquifer system.     

Isotopic investigation of runoff generation in a glacierized catchment in northern Sweden

In this study, summer rainfall contributions to streamflow were quantified in the sub‐arctic, 30% glacierized Tarfala (21.7 km²) catchment in northern Sweden for two non‐consecutive summer sampling seasons (2004 and 2011). We used two‐component hydrograph separation along with isotope ratios (δ¹⁸O and δD) of rainwater and daily streamwater samplings to estimate relative fraction and uncertainties (because of laboratory instrumentation, temporal variability and spatial gradients) of source water contributions. We hypothesized that the glacier influence on how rainfall becomes runoff is temporally variable and largely dependent on a combination of the timing of decreasing snow cover on glaciers and the relative moisture storage condition within the catchment. The results indicate that the majority of storm runoff was dominated by pre‐event water. However, the average event water contribution during storm events differed slightly between both years with 11% reached in 2004 and 22% in 2011. Event water contributions to runoff generally increased over 2011 the sampling season in both the main stream of Tarfala catchment and in the two pro‐glacial streams that drain Storglaciären (the largest glacier in Tarfala catchment covering 2.9 km²). We credit both the inter‐annual and intra‐annual differences in event water contributions to large rainfall events late in the summer melt season, low glacier snow cover and elevated soil moisture due to large antecedent precipitation. Together amplification of these two mechanisms under a warming climate might influence the timing and magnitude of floods, the sediment budget and nutrient cycling in glacierized catchments. Copyright © 2012 John Wiley & Sons, Ltd.     

Groundwater–surface‐water interactions in a braided river: a tracer‐based assessment

Natural tracers (alkalinity and silica) were used to infer groundwater–surface‐water exchanges in the main braided reach of the River Feshie, Cairngorms, Scotland. Stream‐water samples were collected upstream and downstream of the braided section at fortnightly intervals throughout the 2001–2002 hydrological year and subsequently at finer resolution over two rainfall events. The braided reach was found to exert a significant downstream buffering effect on the alkalinity of these waters, particularly at moderate flows (4–8 m³ s^?1/?Q_30–70). Extensive hydrochemical surveys were undertaken to characterize the different source waters feeding the braids. Shallow groundwater flow systems at the edge of the braided floodplain, recharged by effluent streams and hillslope drainage, appeared to be of particular significance. Deeper groundwater was identified closer to the main channel, upwelling through the hyporheic zone. Both sources contributed to the significant groundwater–surface‐water interactions that promote the buffering effect observed through the braided reach. Their impact was less significant at higher flows (>15 m³ s^?1/>Q₁₀) when acidic storm runoff from the peat‐covered catchment headwaters dominated, as well as under baseflow conditions (<4 m³ s^?1/<Q₇₀), when upstream alkalinity was already buffered owing to headwater groundwater sources assuming dominance. The significant temporally and spatially dynamic influence of these groundwater–surface‐water interactions was therefore seen to have important implications for both catchment functioning and instream ecology. Copyright © 2004 John Wiley & Sons, Ltd.