U–Th age of the Kazantsevo (MIS 5) Horizon of the Upper Neopleistocene Ust Oda reference section,Baikal Region

For the first time, the organic sediments of the Kazantsevo Horizon (Baikal Region) were characterized geochronometrically. The ²³⁰Th/U age of the buried gyttias from the Upper Neopleistocene Ust Oda stratotypical section on the Kitoi River was determined using a new version of isochronous approximation. The assemblage of all the ²³⁰Th/U age data, which were obtained taking into account the errors in the entire range from 136 to 86 kyr, indicates that most likely gyttia age is 115–104 kyr (MIS 5d). Thus, the paleontological conclusions on the Kazantsevo age of the Ust Oda Formation with buried gyttias are confirmed. Our geochronometric data supplement and make more reliable the age model of the formation of sedimentary rocks of the Ust Oda section.     

Dating fluvial terraces by Th/U on pedogenic carbonate, Wind River Basin, Wyoming

Reliable and precise ages of Quaternary pedogenic carbonate can be obtained with ²³⁰Th/U dating by thermal ionization mass spectrometry applied to carefully selected milligram-size samples. Datable carbonate can form within a few thousand years of surface stabilization allowing ages of Quaternary deposits and surfaces to be closely estimated. Pedogenic carbonate clast-rinds from gravels of glacio-fluvial terraces in the Wind River Basin have median concentrations of 14 ppm U and 0.07 ppm ²³²Th, with median (²³⁰Th/²³²Th) = 270, making them well suited for ²³⁰Th/U dating. Horizons as thin as 0.5 mm were sampled from polished slabs to reduce averaging of long (≥10⁵ yr), and sometimes visibly discontinuous, depositional histories. Dense, translucent samples with finite ²³⁰Th/U ages preserve within-rind stratigraphic order in all cases. Ages for terraces WR4 (167,000 ± 6,400 yr) and WR2 (55,000 ± 8600 yr) indicate a mean incision rate of 0.26 ± 0.05 m per thousand years for the Wind River over the past glacial cycle, slower than inferred from cosmogenic-nuclide dating. Terrace WR3, which formed penecontemporaneously with the final maximum glacial advance of the penultimate Rocky Mountain (Bull Lake) glaciation, has an age of 150,000 ± 8300 yr indicating that it is broadly synchronous with the penultimate global ice volume maximum.     

Can 234U–230Th dating be used to date large semi‐arid tufas? Challenges from a study in the Naukluft Mountains,Namibia

The large, extensive tufa deposits of the semi‐arid Naukluft Mountains, Namibia are potentially important palaeoenvironmental indicators in an area with few proxy records. Tufas are reliable indicators of increased moisture availability, and have been shown to be amenable to ²³⁴U–²³⁰Th dating, although two challenges are detrital contamination and open‐system behaviour. Densely cemented tufa facies are good candidates for dating, minimising these problems. We report attempts to date five densely‐cemented units, which are only found rarely within the Naukluft deposits. We applied a detailed methodology using multiple subsample analysis, measurement of insoluble residues, application of ‘isochron’ mixing lines, and attempted open‐systems modelling, alongside observations of micromorphology and cathodoluminescence in order to assess the validity of any obtained dates. Surprisingly, densely cemented tufas were found not always to be suitable for dating. Two units contained detrital contamination, which could not be corrected for using a single leachate correction or ‘isochron’ methods. Two units contained ‘excess ²³⁰Th’. This could result under a closed‐system if initial (²³⁴U/²³⁸U) was sufficiently high. Alternatively this may be the result of open‐system behaviour, and loss of uranium, or incorporation of initial unsupported ²³⁰Th, which render samples unsuitable for ²³⁴U–²³⁰Th dating. Micromorphological appearance and cathodoluminescence behaviour are used to explore these possibilities. This study exemplifies the need for careful sample selection, and highlights the importance of analysing multiple subsamples from any tufa sample. The detailed methodology applied proves to be a powerful tool for identifying the range of problems that can be encountered when selecting suitable candidate samples for successful dating. It also shows that semi‐arid tufa sequences may contain very little material suitable for dating. A reliable age of c 80 ka was obtained for a banded unit within a large fluvial barrage, with less reliable dates suggesting tufa deposition during times since >350 ka through to the late Holocene. Copyright © 2010 John Wiley & Sons, Ltd.     

Pleistocene climatic change in Southern Australia and its effect on speleothem deposition in some Nullarbor caves

Activity ratios of ²³⁴U/²³⁸U, ²³⁰Th/²³⁴U, and ²³⁰Th/²³²Th have been determined for calcite, gypsum and halite speleothems from caves of the Nullarbor Plain, mostly in the area N and NW of Mundrabilla Station, for the purpose of U-series dating. All calcite speleothems contain adequate amounts of uranium for dating, but some show an excess of ²³⁰Th. Stratigraphic relationships indicate that there were at least three phases of calcium carbonate deposition in the Nullarbor caves. The calcite samples, with one possible exception, have ages in excess of ca. 400000 yrs BP. This suggests that no significant amounts of calcium carbonate deposition have taken place during the last 400ka. At present, active deposition of speleothems is restricted almost entirely to gypsum and halite. The only gypsum speleothem dated was found to have a finite age of ca. 185 ka. Six dates on a small halite speleothem containing insect and arachnid remains indicate that it formed rapidly during Holocene time.     

Chronology of Hydrothermal Activity Within the Yubileynoye Ore Field (Mid-Atlantic Ridge, 20°08′ N)

This paper reports on the integrated geochronological and geochemical methods used in studying the ore deposits and metalliferous sediments of the Yubileinoye field. This study gives the opportunity to carry out cross dating of hydrothermal deposits, including the ²³⁰Th/U dating of sulfides, the ²³⁰Th, ¹⁴C dating, and foraminiferal analysis of the sediments, and, on this basis, to reconstruct hydrothermal activity over time. It was established that the ores started forming about 100 000–123 000 years ago and were renewed 4–5 times with a frequency of 10–20 ka. As a result, the complex of pyrite-marcasite, chalcopyrite and sphalerite ores and the associated metal-bearing and ore-bearing sediments with consistent geochemical specialization were formed. The integrated geochronological and geochemical studies of the ores and sediments allow us to obtain detailed data on evolution of the hydrothermal ore-formation not only in the certain areas but also for the entire Mid-Atlantic Ridge.     

Uranium geochemistry and dating of Pacific island apatite

Uranium-series disequilibrium dating of island phosphate deposits is evaluated in terms of known associated coral ages, uranium geochemistry, and stratigraphic sequences as well as the concordance between the geochronometers ²³⁴U/²³⁸U, ²³⁰Th/²³⁴U and ²²⁶Ra/²³⁸U. U(VI) is the predominant oxidation state of uranium in island phosphorites and by analogy to the youngest surficial deposits, most of the uranium initially bound is in the form of U(VI) sorbed by surfaces from seawater. Insular deposits contain more organic matter than even very young ocean floor samples and this leads to a greater probability of reduction of available recoil uranium than occurs in marine deposits. As a consequence, R(VI) ? R(T) ? R(VI), where R represents the ²³⁴U/²³⁸U activity ratio. This situation is completely opposite from that observed for marine-origin phosphorites. We determined that a fraction of U(VI) in ancient insular phosphorites is very labile and lost to alkaline carbonate solutions with a uranium activity ratio even more depleted in ²³⁴U than the bulk R(VI).Most younger samples appear to have no more discordance between ²³⁴U/²³⁸U, ²³⁰Th/²³⁴U and ²²⁶Ra/²³⁸U than marine phosphorites of similar apparent age. Young, surficial atoll-rim apatite cements and unconsolidated phosphorites date in the range of 1500–8000 years B.P., consistent with the concept of partial submergence of low-lying coral islands prior to 2000 years B.P. Sub-surficial samples in the same environment date older at about 20,000 years B.P. Violation of the closed system assumption occurs in at least 6 out of 13 ancient (> 800,000 year) samples. Uranium-series disequilibrium dating of insular apatite shows some promise as a recorder of climatic/sea level events, but the assumptions necessary for valid ages must be carefully evaluated for each occurrence.     

230Th/234U dating of Holocene tufas: possibilities and problems

High-resolution chronologies in continental carbonate deposits such as tufas are required for detailed palaeoclimatic and environmental studies. This work set out to establish if high-resolution U-series dating of detritus-rich Holocene tufas is routinely possible. The study centres on a paludal Holocene tufa from southern England that already has an existing Holocene chronology, based on ¹⁴C and supported by biostratigraphy, against which to compare U-series dates. The results show that significant detrital contamination combined with low initial U concentrations, and short time for ingrowth of radiogenic ²³⁰Th make high-resolution U-series dating of Holocene tufa very difficult. Moreover, a single (²³⁰Th/²³²Th)_initial value to correct for the presence of detrital ²³⁰Th is not appropriate at the study site, a finding that may apply to most Holocene tufas. Total sample dissolution of coeval samples demonstrates considerable variability in the isotopic composition of the detritus. The total sample dissolution data are too scattered to constrain chronologies at the required resolution and may indicate the incorporation of a ²³⁰Th-rich component in the detritus.     

Th/U/U and Pa/U ages from a single fossil coral fragment by multi-collector magnetic-sector inductively coupled plasma mass spectrometry

The ²³⁰Th/²³⁴U/²³⁸U age dating of corals via alpha counting or mass spectrometry has significantly contributed to our understanding of sea level, radiocarbon calibration, rates of ocean and climate change, and timing of El Nino, among many applications. Age dating of corals by mass spectrometry is remarkably precise, but many samples exposed to freshwater yield inaccurate ages. The first indication of open-system ²³⁰Th/²³⁴U/²³⁸U ages is elevated ²³⁴U/²³⁸U_initial values, very common in samples older than 100,000 yr. For samples younger than 100,000 yr that have ²³⁴U/²³⁸U_initial values close to seawater, there is a need for age validation. Redundant ²³⁰Th/²³⁴U/²³⁸U and ²³¹Pa/²³⁵U ages in a single fossil coral fragment are possible by Multi-Collector Magnetic Sector Inductively Coupled Plasma Mass Spectrometry (MC-MS-ICPMS) and standard anion exchange column chemistry, modified to permit the separation of uranium, thorium, and protactinium isotopes from a single solution. A high-efficiency nebulizer employed for sample introduction permits the determination of both ²³⁰Th/²³⁴U/²³⁸U and ²³¹Pa/²³⁵U ages in fragments as small as 500 mg. We have obtained excellent agreement between ²³⁰Th/²³⁴U/²³⁸U and ²³¹Pa/²³⁵U ages in Barbados corals (30 ka) and suggest that the methods described in this paper can be used to test the ²³⁰Th/²³⁴U/²³⁸U age accuracy.Separate fractions of U, Th, and Pa are measured by employing a multi-dynamic procedure, whereby ²³⁸U is measured on a Faraday cup simultaneously with all minor isotopes measured with a Daly ion counting detector. The multi-dynamic procedure also permits correcting for both the Daly to Faraday gain and for mass discrimination during sample analyses. The analytical precision of ²³⁰Th/²³⁴U/²³⁸U and ²³¹Pa/²³⁵U dates is generally better than ±0.3% and ±1.5%, respectively (2 Relative Standard deviation [RSD]). Additional errors resulting from uncertainties in the decay constant for ²³¹Pa and from undetermined sources currently limit the ²³¹Pa/²³⁵U age uncertainty to about ±2.5%. U isotope data and ²³⁰Th/²³⁴U/²³⁸U ages agree with National Institute of Standards and Technology (NIST) reference materials and with measurements made by Thermal Ionization Mass Spectrometry (TIMS) in our laboratory.     

U—Series Dating of Fossil Bones：Results from Chinese Sites and Discussions on Its Reliability

Calculations,according to some open-system models,point out that while a statistically significant discrepancy between the results of two U-series methods,^230Th/^234U and ^227Th/^220Th(or ^231Pa/^235U),attests a relatively recent and important uranium migration,concordant dates cannot guarantee closes-system behavior of sample.The results of 20 fossil bones from 10 Chinese sites,19 of which are determined by two U-series methods,are given,Judging from independent age controls,8 out of the 11 concordant age sets are unacceptable,The results in this paper suggest that uranium may cycle into or out of fossil bones,such geochemical events may take place at any time and no known preserving condition may securely protect them from being affected.So for the sitew we have studied,the U-series dating of fossil bones is of limited reliability.     

洞穴地点骨化石铀系年龄可信度的讨论*

骨化石是铀不平衡系测年法广泛应用而又颇有争议的研究对象。文章通过对典型铀加入模式的计算,指出以α能谱的精度,二种铀系年龄差异的显著性表明近期内有较大量铀的迁移,但其在误差范围内的一致不能保证样品构成封闭体系。以往积累的数据表明,大多数洞穴地点骨化石给出了二法一致的铀系年龄,但钙板与下伏骨化石铀系年龄大多差异显著且与地层顺序矛盾,即使被次生碳酸盐岩包裹,多半骨化石的铀系年龄仍显著偏低于其包裹体。此外,相当一部分样品的U-Th同位素比难以用简单的铀后期加入或淋失来解释。基于对次生碳酸盐岩铀系年龄可信度的认识,骨化石总体上不构成封闭体系,所载铀系年代信息只具有限的分辨率。     

A new technique for precise uranium-series dating of travertine micro-samples

Secondary carbonate formations, such as travertine and calcareous tufa deposits, are important archives for quaternary continental climate studies and archaeology. The extremely complex growth mechanisms result in some serious problems for precise mass spectrometric uranium-series dating. Often, detrital and organic particles contaminate the carbonate and large pore volumes yield a great potential for open system behavior. We utilized microscopic, mineralogical and geochemical methods prior to sample selection to determine the abundance of primary calcite, i.e. micrite and spar. Furthermore, the state of alteration was characterized by cathodoluminescence and trace-element analysis. We conclude that travertine and calcareous tufa are appropriate for precise U-series age determination if a) micrite and/or spar are the dominant phases; b) cathodoluminescence of both phases is weak or absent; c) Fe and Al levels are low; and d) Sr concentrations are close to the average of the studied site. We mapped and sampled solely areas of major micrite/spar abundance having minor alteration for accurate U-series dating. When this new method was applied, travertines located in eastern Germany (sites Bad Langensalza, Burgtonna and Weimar-Ehringsdorf) gave single ²³⁰Th/²³⁸U-ages consistent with the lithological growth sequence and greatly improved compared to previously published chronologies. In addition, we determined ²³⁰Th/U isochron ages on bulk samples that confirm our single ages. In contrast to primary calcite, pore cements are homogeneously distributed throughout the travertine fabric and reflect early diagenetic processes and/or weathering.     

A direct comparison of C and Th ages at Searles Lake, California

Thorium-230 dating on saline of the Lower Salt unit in pluvial Searles Lake, California, shows that this unit was formed between 24,500 and 32,000 years ago. The initial apparent ¹⁴C age of the lake is estimated to be about 900 years. After correcting for nonradiogenic ²³⁰Th and for the initial ¹⁴C age, excellent agreement between ²³⁰Th and ¹⁴C ages is obtained. The reliability of ²³⁰Th dating on salt deposit opens a new way for continuation of absolute chronology below the Lower Salt in Searles Lake.     

Precise two chronometer dating of Pleistocene travertine: The Th/U and Raex/Ra(0) approach

In order to determine the geochemical evolution of a freshwater limestone cave system located in central Switzerland (Hell Grottoes at Baar/Zug,) young postglacial tufaceous limestone and travertine precipitates were investigated using the ²³⁰Th/²³⁴U ingrowth system. Additional analyses of further radionuclides within the ²³⁸U decay chain, i.e. ²²⁶Ra and ²¹⁰Pb, showed that the Th/U chronometer started with insignificant inherited ²³⁰Th over the entire formation period of the travertine setting (i.e. ²³⁰Th(0)=0). A contribution from detrital impurities with ²³⁰Th/²³⁴U in secular equilibrium could be precisely subtracted by applying isochron dating of cogenetic phases and recently formed travertine. The resulting precise ²³⁰Th/²³⁴U formation ages were found to be consistent with the geological stratigraphy and were furthermore used to demonstrate the applicability of the next geologically important chronometer in the ²³⁸U-decay series, based on decay of excess ²²⁶Ra normalized to the initial, i.e.²²⁶Ra_ex/²²⁶Ra(0). This system is suitable for dating phases younger than 7000 yr when the correction of a detritus component increasingly limits the precision of the ²³⁰Th/²³⁴U chronometer. Analytical solutions of the coupled ²³⁴U/²³⁰Th/²²⁶Ra radionuclide system predicted that the ²²⁶Ra_ex/²²⁶Ra(0) chronometer is independent of the actual ²³⁰Th activity build up from decay of ²³⁴U, if the systems starts with zero inherited ²³⁰Th(0). The data set confirmed this hypothesis and showed furthermore that the initially incorporated ²²⁶Ra excess must have remained almost uniform in all limestone over a period of at least 7000 yr, i.e. 4–5 half-lives of ²²⁶Ra. This is concluded because (i) the ²²⁶Ra_ex/²²⁶Ra(0) ages agreed well with those derived from ²³⁰Th/²³⁴U, (ii) all data plot within uncertainty on the ²²⁶Ra_ex/²²⁶Ra(0) decay curve and (iii) the atomic Ba/Ca ratio was found to be constant in the travertine material independent of the sample ages. Provided that such boundary conditions hold, ²²⁶Ra_ex/²²⁶Ra(0) should be applicable to materials which are suitable for ²³⁰Th/²³⁴U dating in sedimentology and oceanography, i.e. travertine, corals, phosphorites, etc., and should strongly support ²³⁰Th/²³⁴U for samples that have been formed a few thousand years ago.     

Dated Paleontological cave sites of Central Europe from Late Middle Pleistocene to early Upper Pleistocene (OIS 5 to OIS 8)

Caves are terrestrial depositories that preserve a large variety of organic and inorganic remains. These may contain important Quaternary climatic and ecological information. Most of the faunal remains, however, cannot be linked to any Interglacial or Glacial period exclusively. Reliable dating of such remains is therefore required. Experience has, however, shown that ESR dating of speleothems or ²³⁰Th/U dating of bones are of disputable value. Only TIMS-²³⁰Th/U dating of speleothems appears to yield reliable ages. Dating the bottom and top of speleothem layers permit assigning Pleistocene faunal remains to the OIS chronology if the deposition of the speleothems and the faunal remains are clearly correlated. Care must be taken to consider the depositional situation of each site before interpreting any age dates. In this paper we present an overview of all numerically dated paleontological cave sites in Central Europe between OIS 5 and OIS 8. A total of 25 strata were dated from 13 sites, most of them deposited during OIS 5; the rest belonging to OIS 6 and 7. Numerically dated paleontological sites older than OIS 8 are not known.     

A direct comparison of 14C and 230Th ages at Searles Lake,California

Thorium-230 dating on saline of the Lower Salt unit in pluvial Searles Lake, California, shows that this unit was formed between 24,500 and 32,000 years ago. The initial apparent ¹⁴C age of the lake is estimated to be about 900 years. After correcting for nonradiogenic ²³⁰Th and for the initial ¹⁴C age, excellent agreement between ²³⁰Th and ¹⁴C ages is obtained. The reliability of ²³⁰Th dating on salt deposit opens a new way for continuation of absolute chronology below the Lower Salt in Searles Lake.     

Uranium-series dating of pedogenic silica and carbonate, Crater Flat, Nevada

A ²³⁰Th-²³⁴U-²³⁸U dating study on pedogenic silica-carbonate clast rinds and matrix laminae from alluvium in Crater Flat, Nevada was conducted using small-sample thermal-ionization mass spectrometry (TIMS) analyses on a large suite of samples. Though the ²³²Th content of these soils is not particularly low (mostly 0.1-9 ppm), the high U content of the silica component (mostly 4-26 ppm) makes them particularly suitable for ²³⁰Th/U dating on single, 10 to 200 mg totally-digested samples using TIMS. We observed that (1) both micro- (within-rind) and macro-stratigraphic (mappable deposit) order of the ²³⁰Th/U ages were preserved in all cases; (2) back-calculated initial ²³⁴U/²³⁸U fall in a restricted range (typically 1.67±0.19), so that ²³⁴U/²³⁸U ages with errors of about 100 kyr (2σ) could be reliably determined for the oldest, 400 to 1000 ka rinds; and (3) though 13 of the samples were >350 ka, only three showed evidence for an open-system history, even though the sensitivity of such old samples to isotopic disruption is very high. An attempt to use leach-residue techniques to separate pedogenic from detrital U and Th failed, yielding corrupt ²³⁰Th/U ages. We conclude that ²³⁰Th/U ages determined from totally dissolved, multiple sub-mm size subsamples provide more reliable estimates of soil chronology than methods employing larger samples, chemical enhancement of ²³⁸U/²³²Th, or isochrons.     

Late Quaternary speleothem pollen in the British Isles

As with many terrestrial areas, the British Quaternary sequence is characterised by incomplete, fragmentary records, whose correlation is based on stratigraphic or biostratigraphic techniques due to the lack of radiometric ages beyond the ～40 kyr limit of ¹⁴C dating. Speleothems (secondary cave calcite deposits) offer a significant advantage over many sources of palaeoenvironmental information; they can be dated to a high precision and accuracy by uranium‐thorium (²³⁸U‐²³⁰Th) thermal ionisation and inductively coupled plasma (ICP) mass spectrometry in the time period back to 500 kyr. They may also contain sufficient well‐preserved pollen representative of contemporary vegetation above the cave to allow palaeoenvironmental reconstruction. This study adopts the novel approach of combining pollen and thermal ionisation mass spectrometric (TIMS) U‐Th dating of British speleothems to produce well‐constrained palaeoenvironmental records. We report for the first time precisely dated records of pollen assemblages from speleothems suggesting the presence of thermophilous arboreal species in phases previously considered to have been consistently cool or cold and devoid of trees. Copyright © 2007 John Wiley & Sons, Ltd.     

U-Th dating of carbonate platform and slope sediments

Absolute chronology of marine sediment beyond the ¹⁴C age range provides a test for models of climate change and has many other applications. U-Th techniques have been used for such chronology by dating corals, but extending these techniques to marine sediment is complicated by the presence of significant initial ²³⁰Th—both in detrital material and scavenged from seawater. In this study, we investigate four methods of solving the initial ²³⁰Th problem for a particular type of marine sediment—the aragonite-rich sediments of carbonate platforms and slopes. Bulk sediment U-Th analyses can be corrected for initial Th to yield ages with ≈2 to 3 kyr precision for highstand periods when sediment aragonite contents are particularly high. Uncertainty on the corrections causes inadequate precision for sediment from other periods, however. Removal of scavenged Th before analysis would enable a dramatic increase in this precision but has not proved successful despite a range of chemical leach approaches. Using heavy liquids to separate the various carbonate minerals found in Bahamas sediment enables an isochron approach to correct for initial Th, but the presence of initial Th from two sources requires correction or removal of one source of initial Th before the other is deconvolved by the isochron. Quantitative removal of detrital material before isochron analysis proves a successful approach. Such isochron data demonstrate that, although sediment remains closed to U-Th on a centimetre scale, nuclides are moved from grain to grain by α-recoil. Such intergrain exchange is expected to be observed in all sediments containing mineral grains with different U concentrations. Measured ²³⁴U/²³⁸U allows the recoil movement to be corrected and results in isochron ages with precision sometimes as low as 3 kyr. The accuracy of this approach has been proved by dating samples within the ¹⁴C age range. Sediments spanning the penultimate deglaciation have also been dated. After a small correction for bioturbation, the age for this event is found to be 135.2 ± 3.5 ka. This date is ≈8 kyr before the peak in northern hemisphere insolation and suggests that deglaciation is initiated by a mechanism in the southern hemisphere or tropics. This isochron approach shows considerable promise for dating of sediments older than this event, which will provide further information about the timing and mechanisms of global climate change.     

Introduction

Manisa Fault is a geomorphologically distinct normal dip-slip fault, which oversees the southern edge of the Manisa Graben that is a continuum of the Gediz Graben towards the west. This study aims to determine the neotectonic activity of the Manisa Fault and the most recent time of the change in its stress condition through age-dating data obtained by using ²³⁰Th/²³⁴U dating methodology applied on the calcite coating that develops over hanging-wall of the Manisa Fault and the calcite veins that occur as fracture fillings. The age of the calcite precipitations associated with the Manisa Fault was determined to be between 307?±?203 and 444?±?101?ka by using the ²³⁰Th/²³⁴U dating method. Evaluation of the carbonate precipitations on the Manisa Fault along with the age data and the kinematic indicators ascertained that the Manisa Fault switched to a dip-slip normal faulting character from Middle Pleistocene onwards and that the region was under the effect of a NE–SW directional extensional regime. In addition, the opening rate was attempted to be determined using the roll-over anticline structure that advanced depending upon the movement of the fault on the upper horizontal strata of colluviums, which developed in association with the Manisa Fault. Along with the evaluation of the rise in the horizontal stratification in colluvium and the obtained age data, opening rate of the Manisa Fault was determined as 0.01?mm?y^?1.     

40Ar/39Ar Dating of Xuebaoding Granite in the Songpan-Garzê Orogenic Belt, Southwest China, and its Geological Significance

<正>Thus far,our understanding of the emplacement of Xuebaoding granite and the occurrence and evolution of the Songpan-Garze Orogenic Belt has been complicated by differing age spectra results.Therefore,in this study,the ~(40)Ar/~(39)Ar and sensitive high resolution ion micro-probe(SHRIMP) U-Pb dating methods were both used and the results compared,particularly with respect to dating data for Pankou and Pukouling granites from Xuebaoding,to establish ages that are close to the real emplacements.The results of SHRIMP U-Pb dating for zircon showed a high amount of U,but a very low value for Th/U.The high U amount,coupled with characteristics of inclusions in zircons,indicates that Xuebaoding granites are not suitable for U-Pb dating.Therefore,muscovite in the same granite samples was selected for ~(40)Ar/~(39)Ar dating.The ~(40)Ar/~(39)Ar age spectrum obtained on bulk muscovite from Pukouling granite in the Xuebaoding,gave a plateau age of 200.1±1.2 Ma and an inverse isochron age of 200.6±1.2 Ma.The ~(40)Ar/~(39)Ar age spectrum obtained on bulk muscovite from Pankou granite in the Xuebaoding gave another plateau age of 193.4±1.1 Ma and an inverse isochron age of 193.7±1.1 Ma. The ~(40)Ar/~(36)Ar intercept of 277.0±23.4(2σ) was very close to the air ratio,indicating that no apparent excess argon contamination was present.These age dating spectra indicate that both granites were emplaced at 200.6±1.3 Ma and 193.7±1.1 Ma,respectively.Through comparison of both dating methods and their results,we can conclude that it is feasible that the muscovite in the granite bearing high U could be used for ~(40)Ar/~(39)Ar dating without extra Ar.Based on this evidence,as well as the geological characteristics of the Xuebaoding W-Sn-Be deposit and petrology of granites,it can be concluded that the material origin of the Xuebaoding W-Sn-Be deposit might partially originate from the Xuebaoding granite group emplacement at about 200 Ma.Moreover,compared with other granites and deposits distributed in various positions in the Songpan-Garze Orogenic Belt,the Xuebaoding emplacement ages further show that the main rare metal deposits and granites in peripheral regions occurred earlier than those in the inner Songpan-Garze.Therefore,~(40)Ar/~(39)Ar dating of Xuebaoding granite will lay a solid foundation for studying the occurrence and evolution of granite and rare earth element deposits in the Songpan-Garze Orogenic Belt.